Process aids for the Chemical Industry. - Industrial Lubricants ...
Process aids for the Chemical Industry. - Industrial Lubricants ...
Process aids for the Chemical Industry. - Industrial Lubricants ...
You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
<strong>Process</strong> <strong>aids</strong> <strong>for</strong> <strong>the</strong> <strong>Chemical</strong> <strong>Industry</strong>.<br />
Surfactants<br />
Nonionic, anionic, cationic and amphoteric surfactants, foam control agents
Surfactants<br />
Version 2009<br />
Contents Page<br />
Welcome to Clariant 4<br />
Product Range 5<br />
Nonionic Surfactants 6<br />
Alkyl ethoxylates 6<br />
Oxo alcohol ethoxylates 6<br />
Emulsogen EPN range 6<br />
Emulsogen LCN range 6<br />
C11 oxo alcohol ethoxylates 7<br />
Alternatives to nonylphenol ethoxylates (NPEOs) 7<br />
Isodecyl ethoxylates 7<br />
Isotridecyl ethoxylates 8<br />
C12/C15 oxo alcohol ethoxylates 8<br />
O<strong>the</strong>r alcohol ethoxylates 8<br />
Natural alcohol ethoxylates 9<br />
Oleyl ethoxylates 9<br />
C16/C18 fatty alcohol ethoxylates 9<br />
Coconut fatty alcohol ethoxylates 10<br />
Lauryl ethoxylates 10<br />
Tributylphenol ethoxylates 10<br />
Nonylphenol ethoxylates 11<br />
Tristyrylphenol ethoxylates 11<br />
Ethylene oxide-propylene oxide block polymers 12<br />
Alkyl alkoxylates 13<br />
End capped alkylethoxylates 13<br />
Fatty acid polyethyleneglycol esters 13<br />
Fatty acid polyglycerol esters 14<br />
Fatty acid polyglycerol ester ethoxylates 14<br />
Castor oil ethoxylates 14<br />
Special purpose emulsifiers 15<br />
Anionic Surfactants 16<br />
Secondary alkyl sulfonates (secondary alkane sulfonates) 16<br />
Olefin sulfonates 16<br />
Alkyl sulfates 16<br />
Alkyl e<strong>the</strong>r sulfates 17<br />
Alkyl aryl e<strong>the</strong>r sulfates 17<br />
Polyglycol e<strong>the</strong>r sulfates 17<br />
Sulfosuccinic acid esters 18<br />
Fatty alkyl amine sulfosuccinamates 18<br />
Phosphoric acid esters 18<br />
Alkyl phosphonic acids 19<br />
Alkyl polyethylene glycol e<strong>the</strong>r carboxylic acids 19<br />
Fatty acid isethionates 20<br />
Fatty acid methyl taurides 20<br />
Fatty acid sarcosine and sarcoside 20<br />
Miscellaneous products 20<br />
Cationic and Amphoteric Surfactants 21<br />
Primary fatty amines 21<br />
Secondary fatty amines 21<br />
Tertiary fatty amines 22<br />
Fatty alkyl di- and polyamines 22<br />
Quaternary ammonium compounds 23<br />
Amine oxides 23<br />
Amine salts 23<br />
Betaines 24<br />
Amine ethoxylates 24<br />
Copolymerizable Emulsifiers 25<br />
Nonionic copolymerizable emulsifiers 25<br />
Anionic copolymerizable emulsifiers 25<br />
Foam Control Agents 26<br />
Polyglycol based antifoams 26<br />
Phosphate ester based antifoams 26<br />
Mineral oil based antifoams 26<br />
3
Welcome to Clariant<br />
Clariant is a global leader in <strong>the</strong> production of fine and specialty<br />
chemicals with annual sales of more than CHF 8 billion. It is domiciled<br />
and headquartered in Muttenz near Basel/Switzerland and<br />
operates worldwide on five continents. The products and services<br />
of <strong>the</strong> four divisions – Textile, Lea<strong>the</strong>r & Paper <strong>Chemical</strong>s, Pigments<br />
& Additives, Master batches and Functional <strong>Chemical</strong>s – play a<br />
decisive role in our clients’ manufacturing processes and upgrade<br />
<strong>the</strong>ir end products.<br />
Let our experienced sales representatives and technical experts<br />
collaborate with you to efficiently solve <strong>the</strong> challenges of your<br />
specific application area and tailor our products to your exact<br />
specification. What do you need?<br />
4<br />
Coatzacoalcos<br />
Clear Lake<br />
Research, development, production and sales are certified to<br />
DIN EN ISO 9001 (Quality Management)<br />
and to<br />
DIN EN ISO 14001 (Environmental Management).<br />
® = Registered trademark of Clariant<br />
Suzano<br />
Tarragona<br />
Wiesbaden<br />
Gendorf<br />
As part of Clariant's Functional <strong>Chemical</strong>s Division, one of <strong>the</strong> world's<br />
leading manufacturers of surfactants and polyglycols, <strong>the</strong> Global<br />
Business Segment Coatings and Construction <strong>Chemical</strong>s offers a<br />
broad range of anionic, nonionic, cationic and amphoteric surfactants<br />
used in <strong>the</strong> chemical industry as well as in <strong>the</strong> coating and<br />
construction industries.<br />
Our surfactants range is produced in eight major sites around <strong>the</strong> world.<br />
Shizuoka<br />
Lara
Product Range<br />
Surface active agents, or short Surfactants, are usually organic<br />
com pounds that are amphiphilic, meaning <strong>the</strong>y contain both hydrophobic<br />
and hydrophilic groups and are <strong>the</strong>re<strong>for</strong>e soluble in both<br />
organic solvents and water. They reduce <strong>the</strong> surface tension of a<br />
liquid by adsorbing at <strong>the</strong> liquid-gas interface, allowing easier<br />
spreading, and lower <strong>the</strong> interfacial tension between two liquids,<br />
e.g. between oil and water, by adsorbing at <strong>the</strong> liquid-liquid interface.<br />
Surfactants are used as emulsifiers, wetting agents, dispersants<br />
and stabilizers <strong>for</strong> different chemical and industrial applications.<br />
The selection of surfactants described in this brochure is offered<br />
<strong>for</strong> <strong>the</strong> following application areas:<br />
■ Air entraining agents <strong>for</strong> <strong>the</strong> construction industry<br />
■ Antifoaming agents<br />
■ Auxiliaries <strong>for</strong> <strong>the</strong> sugar industry<br />
■ Disinfecting agents<br />
■ Dispersing agents <strong>for</strong> pigments<br />
■ Emulsifiers <strong>for</strong> bitumen emulsions<br />
■ Emulsifiers <strong>for</strong> emulsion polymerization<br />
■ Emulsifiers <strong>for</strong> micro- and macro emulsions of fats,<br />
hydrocarbons and silicon oils<br />
Depending on <strong>the</strong> <strong>for</strong>mal charge of <strong>the</strong>ir head, surfactants can also<br />
be classified into anionic, cationic, non-ionic, and amphoteric<br />
(dual charge) groups. The product overview on <strong>the</strong> following pages<br />
is organized in this manner.<br />
Nonionic Surfactants<br />
■ Alkyl ethoxylates<br />
■ Alkyl phenol ethoxylates<br />
■ Ethylene oxide-propylene oxide<br />
block polymers<br />
■ Alcohol-EO/PO addition products<br />
■ Fatty acid ethoxylates<br />
■ Castor oil ethoxylates<br />
■ Tristyrylphenol ethoxylates<br />
Anionic Surfactants<br />
■ Sulfonates<br />
■ Sulfate esters<br />
■ Sulfosuccinates<br />
■ Phosphate esters<br />
■ Miscellaneous o<strong>the</strong>rs<br />
Nonionic and anionic copolymerizable surfactants <strong>for</strong> polymerization<br />
■ Emulsifiers <strong>for</strong> polyolefin wax emulsions<br />
■ Organophilic bentonite<br />
■ Wetting agents <strong>for</strong> adhesives<br />
■ Wetting agents <strong>for</strong> coatings, e.g. in building, construction,<br />
textile and paper<br />
■ Wetting agents <strong>for</strong> electroplating processes<br />
■ Wetting agents <strong>for</strong> emulsions, dispersions, polymers, resins<br />
■ Wetting agents <strong>for</strong> hard surfaces like ceramics, wood, plastics<br />
and metals<br />
Cationic and Amphoteric Surfactants<br />
■ Fatty amines<br />
■ Quaternary ammonium compounds<br />
■ Amine oxides<br />
■ Betaines<br />
■ Amine ethoxylates<br />
5
Nonionic Surfactants<br />
Alkyl ethoxylates<br />
Oxo alcohol ethoxylates<br />
Emulsogen EPN range<br />
Products from <strong>the</strong> Emulsogen ® EPN range serve as efficient emulsifiers<br />
which reduce <strong>the</strong> grit level during polymerization and improve dis -<br />
persion properties such as freeze-thaw stability, electrolyte resistance<br />
and sheer stability. They are suitable <strong>for</strong> emulsion polymerization of<br />
olefinic monomers or vinyl acetate toge<strong>the</strong>r with o<strong>the</strong>r vinyl esters,<br />
Emulsogen LCN range<br />
Emulsogen ® LCN is a preferred surfactant in various application fields,<br />
such as emulsion polymerization, coatings, adhesives, construction<br />
and detergents. Specifically, as emulsifier <strong>for</strong> emulsion polymerization,<br />
Emulsogen ® LCN improves <strong>the</strong> shear, temperature and electrolyte stability<br />
of polymer dispersions. At <strong>the</strong> same time, it can be used in inverse<br />
emulsion polymerization of water soluble monomers in hydrocarbons<br />
and in emulsions of oils, fats, silicon oils, polyolefin waxes, alkyd resins,<br />
acrylates, vinyl chloride and ethylene, in acrylic and styrene/acrylic<br />
dispersions as well as in butadiene/styrene latex. Emulsogen ® EPN<br />
also finds widespread use in pigment preparations, paints and coatings<br />
as a dispersing and wetting agent.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® EPN 118 Alkyl polyglycol e<strong>the</strong>r with 11 EO Approx. 80 % Liquid 62 – 65 (3)* Approx. 15<br />
Emulsogen ® EPN 287 Alkyl polyglycol e<strong>the</strong>r with 28 EO Approx. 70 % Liquid - Approx. 18<br />
Emulsogen ® EPN 407 Alkyl polyglycol e<strong>the</strong>r with 40 EO Approx. 70 % Liquid - Approx. 18<br />
mineral oils etc. As a medium foaming wetting agent in aqueous solutions,<br />
emulsions, architectural paints, industrial and wood coatings,<br />
Emulsogen ® LCN reduces <strong>the</strong> surface tension of <strong>the</strong> aqueous medium<br />
and improves <strong>the</strong> wetting of hard surfaces. It is an efficient dispersing<br />
and wetting agent in aqueous pigment preparations and can be added<br />
to emulsion paints to improve <strong>the</strong> scrub resistance.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® LCN 070 Alkyl polyglycol e<strong>the</strong>r with 7 EO Approx. 100 % Liquid 54 – 56 (1) Approx. 13<br />
Emulsogen ® LCN 088 Alkyl polyglycol e<strong>the</strong>r with 8 EO Approx. 80 % Liquid 62 – 65 (1)* Approx. 13<br />
Emulsogen ® LCN 118 Alkyl polyglycol e<strong>the</strong>r with 11 EO Approx. 80 % Liquid 62 – 65 (3)* Approx. 15<br />
Emulsogen ® LCN 158 Alkyl polyglycol e<strong>the</strong>r with 15 EO Approx. 80 % Liquid 69 – 71 (3)* Approx. 16<br />
Emulsogen ® LCN 217 Alkyl polyglycol e<strong>the</strong>r with 21 EO Approx. 70 % Liquid - Approx. 17<br />
Emulsogen ® LCN 287 Alkyl polyglycol e<strong>the</strong>r with 28 EO Approx. 70 % Liquid - Approx. 18<br />
Emulsogen ® LCN 407 Alkyl polyglycol e<strong>the</strong>r with 40 EO Approx. 70 % Liquid - Approx. 18<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
6<br />
Emulsion Poly -<br />
merization, Paints<br />
and Coatings<br />
Emulsion Poly -<br />
meri zation, Paints,<br />
Coatings, Adhes -<br />
ives, Construction,<br />
<strong>Industrial</strong> Cleaning<br />
Formulations,<br />
Textile, Paper and<br />
Lea<strong>the</strong>r <strong>Chemical</strong>s,<br />
Mining <strong>Chemical</strong>s<br />
and Metal Working
Main applications <strong>for</strong> <strong>the</strong> Genapol ® C11 oxo alcohol ethoxylates<br />
UD range are liquid scouring<br />
agents, fat dispersants and dissolving agents, hand washing pastes,<br />
high pressure, all-purpose, liquid and industrial cleaning agents as<br />
well as wetting agents and emulsifiers.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® UD 030 C 11 oxo alcohol ethoxylate with 3 EO Approx. 100 % Liquid 37 – 41 (2) Approx. 9<br />
Genapol ® UD 050 C 11 oxo alcohol ethoxylate with 5 EO Approx. 100 % Liquid 66 – 69 (2) Approx. 11<br />
Genapol ® UD 070 C 11 oxo alcohol ethoxylate with 7 EO Approx. 100 % Liquid 52 – 55 (1)* Approx. 13<br />
Genapol ® UD 079 C 11 oxo alcohol ethoxylate with 7 EO Approx. 90 % Liquid 52 – 55 (1)* Approx. 13<br />
Genapol ® UD 080 C 11 oxo alcohol ethoxylate with 8 EO Approx. 100 % Liquid 62 – 65 (1) Approx. 13<br />
Genapol ® UD 088 C 11 oxo alcohol ethoxylate with 8 EO Approx. 80 % Liquid 62 – 65 (1)* Approx. 13<br />
Genapol ® UD 110 C 11 oxo alcohol ethoxylate with 11 EO Approx. 100 % Liquid paste 62 – 65 (3) Approx. 15<br />
Alternatives to Nonylphenol Ethoxylates (NPEOs)<br />
Readily biodegradable and free of any additional biocides, <strong>the</strong> Emulsogen ® LCN series is an ideal alternative to NPEOs in <strong>the</strong> application<br />
areas of wetting of surfaces and pigments, emulsifiers <strong>for</strong> hydrocarbons, oils and waxes of W/O and O/W-type, dispersing agents <strong>for</strong><br />
pigments and emulsifiers <strong>for</strong> polymerization.<br />
➔<br />
➔<br />
➔<br />
➔<br />
➔<br />
Isodecyl ethoxylates<br />
Due to its excellent wetting action, especially in <strong>the</strong> low-temperature<br />
range, and marked degreasing and emulsifying properties, Genapol ®<br />
ID 060 is a suitable raw material and mixture component <strong>for</strong> <strong>the</strong> manufacture<br />
of universal cleaners in every <strong>for</strong>m.<br />
➔<br />
➔<br />
➔<br />
➔<br />
➔<br />
Detergents,<br />
I&I, Cleaners,<br />
Emulsion<br />
Polymerization,<br />
Paints and<br />
Coatings<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® ID 060 Isodecyl ethoxylate with 6 EO Approx. 100 % Liquid 70 – 72 (2) Approx. 12 Detergents<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
➔<br />
➔<br />
7
Due to <strong>the</strong>ir excellent surface-active properties, Genapol ® X grades<br />
have numerous uses. With superb wetting capabilities, especially in<br />
<strong>the</strong> low-temperature range, and marked degreasing and emulsifying<br />
properties, <strong>the</strong>y are suitable raw materials and mixture components<br />
<strong>for</strong> <strong>the</strong> manufacture of universal cleaners in every <strong>for</strong>m, wax and<br />
silicone emulsions. Genapol ® X 060 offers very strong degreasing<br />
action, while Genapol ® Isotridecyl ethoxylates<br />
X 080 is mainly used to remove pigmented<br />
Genapol ® C12/C15 Oxo alcohol ethoxylates<br />
OX types are used in washing powders (HDP), liquid detergents<br />
(HDL), all purpose cleaners (APC), and o<strong>the</strong>r liquid cleaners,<br />
wetting agents, emulsifiers and industrial cleaners.<br />
8<br />
contamination. Genapol ® X 080 also offers excellent wetting properties.<br />
Genapol ® X 1003 is used in emulsion polymerization to reduce<br />
coagulation and to improve electrolyte resistance and freeze/ thaw<br />
stability or as emulsifier <strong>for</strong> bitumen emulsions. Added to pigment<br />
preparations, Genapol ® X 1005 improves <strong>the</strong> stability and reduces <strong>the</strong><br />
viscosity and thixotropic behaviour of pigment preparations.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® X 030 C13 oxo alcohol ethoxylate with 3 EO Approx. 100 % Liquid 39 – 41 (2) Approx. 7<br />
Genapol ® X 050 C13 oxo alcohol ethoxylate with 5 EO Approx. 100 % Liquid 59 – 62 (2) Approx. 10<br />
Genapol ® X 060 C13 oxo alcohol ethoxylate with 6 EO Approx. 100 % Liquid 64 – 66 (2) Approx. 11<br />
Genapol ® X 065 C13 oxo alcohol ethoxylate with 6 EO Approx. 100 % Liquid 68 – 71 (2) Approx. 11<br />
Genapol ® X 080 C13 oxo alcohol ethoxylate with 8 EO Approx. 100 % Liquid >45 (1) 74 – 76 (2) Approx. 13<br />
Genapol ® X 090 C13 oxo alcohol ethoxylate with 9 EO Approx. 100 % Liquid 62 – 65 (1) Approx. 13<br />
Genapol ® X 100 C13 oxo alcohol ethoxylate with 10 EO Approx. 100 % Liquid (pasty) 81 – 85 (2) Approx. 14<br />
Genapol ® X 150 C13 oxo alcohol ethoxylate with 15 EO Approx. 100 % Waxy - Approx. 15<br />
Genapol ® X 159 C13 oxo alcohol ethoxylate with 15 EO Approx. 90 % Clear to hazy liquid - Approx. 15<br />
Genapol ® X 250 C13 oxo alcohol ethoxylate with 25 EO Approx. 100 % Waxy - Approx. 18<br />
Genapol ® X 407 C13 oxo alcohol ethoxylate with 40 EO Approx. 70 % Liquid - Approx. 18<br />
Genapol ® X 1000 C13 oxo alcohol ethoxylate with 100 EO Approx. 100 % Solid - Approx. 19<br />
Genapol ® X 1003 C13 oxo alcohol ethoxylate with 100 EO Approx. 35 % Liquid - Approx. 19<br />
Genapol ® 1879 C13 oxo alcohol ethoxylate Approx. 40 % Liquid - Approx. 15<br />
Genapol ® 3214 C13 oxo alcohol ethoxylate Approx. 25 % Liquid - Approx. 18<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® OX 070 C12/C15 oxo alcohol ethoxylate with 7 EO Approx. 100 % Liquid paste Approx. 73 (2) Approx. 12<br />
Genapol ® OX 080 C12/C15 oxo alcohol ethoxylate with 8 EO Approx. 100 % Pasty 75 – 78 (2) Approx. 13<br />
Genapol ® OX 100 C12/C15 oxo alcohol ethoxylate with 10 EO Approx. 100 % Pasty 62 – 65 (1) Approx. 14<br />
O<strong>the</strong>r alcohol ethoxylates<br />
Genapol ® GS 080 is used in emulsion polymerization of vinyl acetate<br />
toge<strong>the</strong>r with acrylates, vinyl chloride or ethylene to prevent <strong>the</strong> poly-<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
<strong>Industrial</strong><br />
Cleaning,<br />
Metal Working,<br />
Crop Protection,<br />
Mining,<br />
Emulsion<br />
Polymerization,<br />
Silicone and<br />
Wax Emulsions<br />
Detergents,<br />
I&I,<br />
Cleaners<br />
mer dispersion from coagulation, as emulsifier <strong>for</strong> paraffin waxes to<br />
produce stable wax emulsions and as emulsifier in fiber preparations.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® GS 080 Blend of alkyl ethoxylates with 8 EO Approx. 100 % Waxy 83 – 85 (2) Approx. 12 Emulsion<br />
Polymerization
Natural alcohol ethoxylates<br />
Oleyl ethoxylates<br />
The Genapol ® O range is used in emulsion polymerization of vinyl<br />
acetate toge<strong>the</strong>r with acrylates, vinyl chloride or ethylene as well as<br />
in acrylate and acrylate/styrene dispersions to prevent <strong>the</strong> polymer<br />
dispersion from coagulation and to improve <strong>the</strong> electrolyte resistance<br />
and freeze/thaw stability. As an emulsifier <strong>for</strong> waxes and organic<br />
C16/18 fatty alcohol ethoxylates<br />
The Genapol ® T grades find widespread use as detergents in heavyduty<br />
washing powders, as dispersing agents and solubilizers, as<br />
wetting agents <strong>for</strong> industrial applications in aqueous solutions, as<br />
emulsifiers <strong>for</strong> O/W - emulsions of oils, fats, paraffin, polyolefin waxes<br />
and silicone oil emulsions and as emulsifiers <strong>for</strong> emulsion polymerization.<br />
In powder <strong>for</strong>m, <strong>the</strong>y can be applied as a binder <strong>for</strong> granula-<br />
solvents, <strong>the</strong>se products help to produce stable emulsions. Fur<strong>the</strong>r -<br />
more, <strong>the</strong>y can be applied as a wetting agent and detergent in industrial<br />
cleaning <strong>for</strong>mulations, as a dispersing agent in pigment<br />
preparations and as emulsifier <strong>for</strong> textile auxiliaries and detergents.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® O 020 Oleyl alcohol ethoxylate with 2 EO Approx. 100 % Liquid 35 – 38 (2) Approx. 5<br />
Genapol ® O 050 Oleyl alcohol ethoxylate with 5 EO Approx. 100 % Liquid 67 – 69 (2) Approx. 9<br />
Genapol ® O 080 Oleyl alcohol ethoxylate with 8 EO Approx. 100 % Liquid paste >40 (1) 79 – 81 (2) Approx. 11<br />
Genapol ® O 100 Oleyl alcohol ethoxylate with 10 EO Approx. 100 % Pasty > 75 (1) 49 – 51 (3) Approx. 12<br />
Genapol ® O 200 Oleyl alcohol ethoxylate with 20 EO Approx. 100 % Waxy 74 – 76 (3) Approx. 15<br />
Metal Working,<br />
Emulsion<br />
Polymerization,<br />
Detergents,<br />
Textile<br />
tions and in tablet processing or coating. Genapol ® T 250 Powder also<br />
serves as a wetting agent <strong>for</strong> solid admixtures in <strong>the</strong> construction<br />
industry, improving <strong>the</strong> wetting of <strong>the</strong> fine particles of <strong>the</strong> dry plaster<br />
or mortar and thus <strong>the</strong> plastification, workability and overall per<strong>for</strong>mance<br />
of <strong>the</strong> plaster or mortar.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® T 080 C16 /18 fatty alcohol ethoxylate with 8 EO Approx. 100 % Waxy 83 – 85 (2) Approx. 11<br />
Genapol ® T 110 C16 /18 fatty alcohol ethoxylate with 11 EO Approx. 100 % Waxy 84 – 90 (1) 60 – 63 (3) Approx. 13<br />
Genapol ® T 150 C16 /18 fatty alcohol ethoxylate with 15 EO Approx. 100 % Waxy 71 – 73 (3) Approx. 14<br />
Genapol ® T 200 C16 /18 fatty alcohol ethoxylate with 20 EO Approx. 100 % Waxy 75 – 77 (3) Approx. 15<br />
Genapol ® T 250 p C16 /18 fatty alcohol ethoxylate with 25 EO Approx. 100 % Powder 77 – 79 (3) Approx. 16<br />
Genapol ® T 500 C16 /18 fatty alcohol ethoxylate with 50 EO Approx. 100 % Waxy - Approx. 18<br />
Genapol ® T 500 p C16 /18 fatty alcohol ethoxylate with 50 EO Approx. 100 % Powder - Approx. 18<br />
Genapol ® T 800 C16 /18 fatty alcohol ethoxylate with 80 EO Approx. 100 % Waxy - Approx. 19<br />
Genapol ® T 800 p C16 /18 fatty alcohol ethoxylate with 80 EO Approx. 100 % Powder - Approx. 19<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
<strong>Industrial</strong><br />
Emulsions,<br />
Emulsion<br />
Polymerization,<br />
Wax Emulsions,<br />
Detergents,<br />
Cosmetic<br />
Formulations<br />
9
Genapol ® Coconut fatty alcohol ethoxylates<br />
C grades are applied as wetting agents, emulsifiers, allpurpose<br />
and special cleaners, powder and liquid detergents, and<br />
industrial cleaning agents.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® C 100 Coconut fatty alcohol ethoxylate with 10 EO Approx. 100 % Pasty 89 – 92 (1) Approx. 14<br />
Genapol ® C 200 Coconut fatty alcohol ethoxylate with 20 EO Approx. 100 % Waxy 76 – 78 (3) Approx. 16<br />
Lauryl ethoxylates<br />
Genapol ® LA grades are frequently used as thickeners <strong>for</strong> surfactant<br />
systems such as shampoos, shower gels and liquid soaps, as emulsifiers,<br />
solubilizers, fat dispersants and dissolving agents.<br />
10<br />
Detergents, Crop<br />
Protection<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® LA 030 C12/C14 fatty alcohol ethoxylate with 3 EO Approx. 100 % Liquid 53 – 55 (2) Approx. 8<br />
Genapol ® LA 050 C12/C14 fatty alcohol ethoxylate with 5 EO Approx. 100 % Liquid 70 – 73 (2) Approx. 11<br />
Genapol ® LA 070 C12/C14 fatty alcohol ethoxylate with 7 EO Approx. 100 % Liquid 53 – 59 (1) Approx. 12<br />
Genapol ® LA 080 C12/C14 fatty alcohol ethoxylate with 8 EO Approx. 100 % Pasty 60 – 68 (1) Approx. 13<br />
Genapol ® LA 100 C12/C14 fatty alcohol ethoxylate with 10 EO Approx. 100 % Pasty 85 – 87 (2) Approx. 14<br />
Tributylphenol ethoxylates<br />
Products from <strong>the</strong> Sapogenat ® range are used e.g. in pigment preparations,<br />
electroplating processes, as emulsifier <strong>for</strong> waxes and solvents,<br />
<strong>for</strong> polymer dispersions and in emulsion polymerization.<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
Detergents,<br />
I&I, Cleaners,<br />
Cosmetics<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Sapogenat ® T 060 Tributylphenol ethoxylate with 6 EO Approx. 100 % Liquid 53 – 56 (2) Approx. 10<br />
Sapogenat ® T 080 Tributylphenol ethoxylate with 8 EO Approx. 100 % Liquid 60 – 68 (2) Approx. 11<br />
Sapogenat ® T 110 Tributylphenol ethoxylate with 11 EO Approx. 100 % Liquid 42 – 44 (1) Approx. 13<br />
Sapogenat ® T 130 Tributylphenol ethoxylate with 13 EO Approx. 100 % Liquid 62 – 64 (1) Approx. 14<br />
Sapogenat ® T 139 Tributylphenol ethoxylate with 13 EO Approx. 90 % Liquid 62 – 64 (1)* Approx. 14<br />
Sapogenat ® T 180 Tributylphenol ethoxylate with 18 EO Approx. 100 % Waxy 61 – 64 (3) Approx. 15<br />
Sapogenat ® T 300 Tributylphenol ethoxylate with 30 EO Approx. 100 % Waxy - Approx. 17<br />
Sapogenat ® T 500 Tributylphenol ethoxylate with 50 EO Approx. 100 % Waxy - Approx. 18<br />
Emulsion Poly -<br />
merization,<br />
Wetting Agent<br />
in Construction,<br />
Coatings,<br />
Adhesives,<br />
Electroplating<br />
<strong>Process</strong>es
Nonyphenol ethoxylates<br />
The Arkopal ® N grades are used as an emulsifier in emulsion polymerization,<br />
as wax emulsifier, in pigment pastes and as stabilizer in paints<br />
and coatings. They are resistant to metal salts, offer good dispersing<br />
properties and, depending on <strong>the</strong> degree of ethoxylation, excellent<br />
Tristyrylphenol ethoxylates<br />
Emulsogen ® TS grades are an excellent dispersing agent <strong>for</strong> organic<br />
pigments and carbon black to produce stable, free flowing pigment<br />
preparations with high solid contents and with low viscosities. Used<br />
in paints and coatings <strong>for</strong>mulations, Emulsogen ® TS improves <strong>the</strong><br />
wetting and surface action. As wetting agents, Arkopal ® N 090 and<br />
Arkopal ® N 100 are <strong>the</strong> most effective grades. The excellent emulsifying<br />
properties of a number of Arkopal ® N grades fur<strong>the</strong>rmore allow<br />
<strong>the</strong> preparation of stable emulsions.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Arkopal ® N 040 Nonylphenol ethoxylate with 4 EO ca. 100 % Liquid 36 – 38 (2) ca. 9<br />
Arkopal ® N 060 Nonylphenol ethoxylate with 6 EO ca. 100 % Liquid 61 – 63 (2) ca. 11<br />
Arkopal ® N 070 Nonylphenol ethoxylate with 7 EO ca. 100 % Liquid 70 – 72 (2)<br />
Arkopal ® N 080 Nonylphenol ethoxylate with 8 EO ca. 100 % Liquid 32 – 34 (1) 76 – 78<br />
ca. 12<br />
(2)<br />
Arkopal ® N 090 Nonylphenol ethoxylate with 9 EO ca. 100 % Liquid 52 – 54 (1) ca. 13<br />
Arkopal ® N 100 Nonylphenol ethoxylate with 10 EO ca. 100 % Liquid 62 – 65 (1) ca. 13<br />
Arkopal ® N 110 Nonylphenol ethoxylate with 11 EO ca. 100 % Liquid 71 – 74 (1) ca. 14<br />
Arkopal ® N 130 Nonylphenol ethoxylate with 13 EO ca. 100 % Liquid Paste 83 – 86 (1) ca. 14<br />
Arkopal ® N 150 Nonylphenol ethoxylate with 15 EO ca. 100 % Paste 92 – 95 (1) 61 – 63<br />
ca. 15<br />
(3)<br />
Arkopal ® N 200 Nonylphenol ethoxylate with 20 EO ca. 100 % Paste 70 – 73 (3) ca. 16<br />
Arkopal ® N 208 Nonylphenol ethoxylate with 20 EO ca. 80 % Liquid 70 – 73 (3)* ca. 16<br />
Arkopal ® N 230 Nonylphenol ethoxylate with 23 EO ca. 100 % Waxy 73 – 75 (3) ca. 16<br />
Arkopal ® N 238 Nonylphenol ethoxylate with 23 EO ca. 80 % Liquid 73 – 75 (3)* ca. 16<br />
Arkopal ® N 300 Nonylphenol ethoxylate with 30 EO ca. 100 % Waxy 76 – 78 (3) ca. 17<br />
Arkopal ® N 307 Nonylphenol ethoxylate with 30 EO ca. 70 % Liquid 76 – 78 (3)* ca. 17<br />
Arkopal ® N 308 Nonylphenol ethoxylate with 30 EO ca. 80 % Liquid 76 – 78 (3)* ca. 17<br />
Arkopal ® N 1000 Nonylphenol ethoxylate with 100 EO ca. 100 % Waxy - ca. 19<br />
compatibility of pigments and minerals with polymers and binders,<br />
prevents skinning of emulsion polymers in paints and improves <strong>the</strong>ir<br />
shelf life and stability.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® TS 100 Tristyrylphenol ethoxylate with 10 EO Approx. 100 % Liquid 65 – 69 (2) Approx. 10<br />
Emulsogen ® TS 160 Tristyrylphenol ethoxylate with 16 EO Approx. 100 % Liquid 58 – 62 (1) Approx. 13<br />
Emulsogen ® TS 200 Tristyrylphenol ethoxylate with 20 EO Approx. 100 % Waxy 55 – 60 (3) Approx. 14<br />
Emulsogen ® TS 290 Tristyrylphenol ethoxylate with 29 EO Approx. 100 % Waxy 67 – 69 (3) Approx. 15<br />
Emulsogen ® TS 540 Tristyrylphenol ethoxylate with 54 EO Approx. 100 % Waxy 72 – 74 (3) Approx. 17<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
Emulsion<br />
Poly merization,<br />
Pigment Pastes,<br />
Paints and<br />
Coatings,<br />
Wax Emulsions<br />
Detergents<br />
Emulsifier <strong>for</strong><br />
Crop Protection,<br />
Dispersing Agent<br />
<strong>for</strong> Pigments<br />
and Biocides<br />
11
Ethylene oxide-propylene oxide block polymers<br />
Emulsogen ® 4084 is used in emulsion polymerization of polyvinyl<br />
acetate, acrylate and styrene/acrylate dispersions to stabilize <strong>the</strong><br />
rheological behaviour of <strong>the</strong> polymer dispersions and to improve<br />
<strong>the</strong> electrolyte and shear stability.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® 4084 EO-PO block polymer with 60 % EO Approx. 100 % Waxy 68 – 70 (3) Approx. 12 Emulsion Polymerization<br />
Low-foaming Genapol ® PF 10, 20, 40 and 80 grades are used as a<br />
surfactant and defoamer in detergents and cleaning agents. They are<br />
also used as an emulsifier in emulsion polymerization, improving <strong>the</strong><br />
emulsion stability and preventing foam during <strong>the</strong> spray drying of<br />
dispersion powders. As a wetting agent in aqueous coatings, <strong>the</strong>y<br />
reduce <strong>the</strong> surface tension of <strong>the</strong> coating <strong>for</strong>mulation, improve <strong>the</strong><br />
stability and shelf life and <strong>the</strong> adhesion of <strong>the</strong> coating onto <strong>the</strong> coated<br />
surface. They also serve as intermediate in chemical reactions.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® PF 10 EO-PO block polymer with 10 % EO Approx. 100 % Liquid 34 – 37 (2) Approx. 2<br />
Genapol ® PF 20 EO-PO block polymer with 20 % EO Approx. 100 % Liquid 55 – 58 (2) Approx. 4 Wetting Agent<br />
Genapol ® PF 30 EO-PO block polymer with 30 % EO Approx. 100 % Liquid - Approx. 6<br />
Genapol ® PF 40 EO-PO block polymer with 40 % EO Approx. 100 % Liquid 66 – 69 (2) Approx. 8<br />
Genapol ® PF 80 EO-PO block polymer with 80 % EO Approx. 100 % Waxy 69 – 72 (3) Genapol<br />
Approx. 16<br />
® PF 80 P EO-PO block polymer with 80 % EO Approx. 100 % Powder 69 – 72 (3) Wetting and Foam<br />
Control Agent<br />
Wetting Agent and<br />
Emulsifier, <strong>Chemical</strong><br />
Intermediate<br />
Emulsifier, Wetting<br />
and Dispersing Agent<br />
Approx. 16<br />
Wetting Agent<br />
<strong>for</strong> Construction,<br />
Emulsifier<br />
Because of its interfacial activity and low foaming behaviour, Genapol ®<br />
ED 3030 is especially suitable <strong>for</strong> <strong>the</strong> manufacture of low foaming<br />
cleaners. Due to its good lubricity, Genapol ® B is used <strong>for</strong> <strong>the</strong> manufacture<br />
of aqueous metal working fluids in combination with suitable<br />
corrosion inhibitors. Genapol ® ED 3030 is resistant against water<br />
hardness, metal salts, acids and alkalis in practice-orientated concentrations.<br />
Genapol ® ED 3060 is a low-foaming wetting and disper-<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® ED 3030 Ethylenediamine EO-PO block polymer Approx. 100 % Liquid 52 – 55 (2) Approx. 9 Detergents<br />
Genapol ® B Ethylenediamine EO-PO block polymer Approx. 100 % Liquid 52 – 55 (2) Approx. 9 Metal Working<br />
Genapol ® ED 3060 Ethylenediamine EO-PO block polymer Approx. 100 % Liquid 27 – 30 (2) Approx. 6<br />
Genapol ® PN 30 Ethylenediamine EO-PO block polymer Approx. 100 % Liquid 27 – 30 (2) Compatabilizer <strong>for</strong> Pig -<br />
ments, Paints and Coatings<br />
Approx. 6 Metal Working<br />
12<br />
Genapol ® PF 80 Powder can also be added to solid admixtures in<br />
<strong>the</strong> construction industry to improve <strong>the</strong> wetting and redispersing of<br />
<strong>the</strong> powder, resulting in higher plastification and improved workability<br />
and overall per<strong>for</strong>mance of <strong>the</strong> plaster. Genapol ® PF 30 can be applied<br />
as a wetting agent and emulsifier <strong>for</strong> oils, waxes, paraffin and silicones,<br />
as emulsifier <strong>for</strong> emulsion polymerization of acrylic monomers,<br />
styrene and vinyl acetate, as lubricant <strong>for</strong> polymers and resin processing<br />
and as reactant <strong>for</strong> polye<strong>the</strong>rs, polyesters and polyurethanes.<br />
sing agent <strong>for</strong> aqueous paints and coatings, in particular <strong>for</strong> white<br />
emulsion paints tinted with waterborne pigment preparations. It functions<br />
as paint stabilizer and tinting strength enhancer, improving<br />
<strong>the</strong> compatibility of pigments and minerals with polymers and binders<br />
and preventing rub-out effects and flocculation of organic pigments<br />
during drying of <strong>the</strong> paint film. Genapol ® PN 30 is a low foaming<br />
lubricant <strong>for</strong> syn<strong>the</strong>tic metal working fluids.<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance
Alkyl alkoxylates<br />
The low-foaming Genapol ® EP and PL grades are suitable <strong>for</strong> rinsing<br />
<strong>aids</strong>, detergents <strong>for</strong> dishwashers and bottle-rinsing machines and<br />
industrial cleaning <strong>for</strong>mulations. They also serve as low foaming<br />
End capped alkylethoxylates<br />
Genapol ® BE grades are especially suitable <strong>for</strong> <strong>the</strong> manufacture of<br />
low foaming cleaners and rinse <strong>aids</strong> <strong>for</strong> automatic dish-washing.<br />
Fatty acid polyethyleneglycol esters<br />
Genagen ® C and O 100 serve as emulsifier and dispersing agent,<br />
plasticizer in polymer films and coatings and as antistatic agent.<br />
wetting agent <strong>for</strong> pigment pastes and preparations as well as <strong>for</strong><br />
wood coatings, architectural paints and industrial coatings.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® EP 0244 C10/C12 fatty alcohol EO-PO adduct Approx. 100 % Liquid 22 – 25 (1) 35 – 38 (2) n.a.<br />
Genapol ® EP 1022 Isodecanol EO-PO adduct Approx. 100 % Liquid 87 – 91 (1) n.a.<br />
Genapol ® EP 1024 Isodecanol EO-PO adduct Approx. 100 % Liquid 20 – 25 (1) 57 – 58 (2) n.a.<br />
Genapol ® EP 2464 Lauryl alcohol EO-PO adduct Approx. 100 % Liquid 29 – 31 (1) 42 – 44 (2) n.a.<br />
Genapol ® EP 2544 C12/C15 oxoalcohol EO-PO adduct Approx. 100 % Liquid 31 – 33 (2) n.a.<br />
Genapol ® EP 2564 C12/C15 oxoalcohol EO-PO adduct Approx. 100 % Liquid 25 – 31 (1) 43 – 45 (2) n.a.<br />
Genapol ® EP 2584 C12/C15 oxoalcohol EO-PO adduct Approx. 100 % Liquid 39 – 42 (1) 47 – 49 (2) n.a.<br />
Genapol ® EP 2552 C12/C15 oxoalcohol EO-PO adduct Approx. 100 % Liquid 39 – 41 (2) n.a.<br />
Genapol ® PL 120 Alcohol EO-PO adduct Approx. 100 % Liquid 31 – 34 (2) n.a.<br />
Detergents,<br />
Paints and<br />
Coatings<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genapol ® BE 2410 Lauryl ethoxylate with 10 EO, Approx. 85 % Liquid 26 – 28 (1) n.a<br />
butyl-end capped .<br />
Genapol ® BE 2805 Coconut fatty alkyl ethoxylate with Approx. 100 % Liquid 19 – 21 (2) 5 EO, butyl-end capped<br />
n.a.<br />
Genapol ® BE 2810 Coconut fatty alkyl ethoxylate with Approx. 85 % Liquid 28 – 30 (1) 10 EO, butyl-end capped<br />
n.a.<br />
<strong>Industrial</strong><br />
Cleaning<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Genagen ® C 100 C12/C14 fatty acid polyglycol ester with 10 EO Approx. 100 % Liquid 65 – 68 (2) Approx. 13<br />
Genagen ® O 100 C16/C18 fatty acid polyglycol ester with 10 EO Approx. 100 % Liquid Approx. 66 (2) Approx. 12<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
Emulsifier,<br />
Dispersing Agent,<br />
Plasticizer in<br />
Polymer Films,<br />
Antistatic Agent<br />
13
Fatty acid polyglycerol esters<br />
These products are particularly suitable <strong>for</strong> <strong>the</strong> manufacture of high<br />
viscous to paste-like water-in-oil emulsions based on mineral oil,<br />
petrolatum, fatty acid esters etc., and as a co-emulsifier in combination<br />
with hydrophilic emulsifiers <strong>for</strong> <strong>the</strong> manufacture of O/W emulsions.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® OG Diglycerol oleate Approx. 100 % Liquid n.a. n.a.<br />
Hostacerin ® DGI Diglycerol diisostearate Approx. 100 % Liquid n.a. n.a.<br />
Hostacerin ® DGMS Diglycerol monostearate Approx. 100 % Pellets n.a. n.a.<br />
Fatty acid polyglycerol ester ethoxylates<br />
Hostacerin ® DGSB is used as a co-emulsifier <strong>for</strong> creamy O/W emulsions.<br />
Since Hostacerin ® DGSB shows strong thickening action, no fur<strong>the</strong>r<br />
cetyl alcohol or stearyl alcohol is needed. Hostacerin ® DGL is a O/W<br />
Castor oil ethoxylates<br />
Emulsogen ® EL is used as a nonionic component <strong>for</strong> emulsifier combinations<br />
<strong>for</strong> <strong>for</strong>mulating a number of biocides in <strong>the</strong> <strong>for</strong>m of selfemulsifying,<br />
liquid concentrates. Emulsogen ® EL 360 also serves as<br />
14<br />
W/O Emulsifiers,<br />
Wetting and<br />
Dispersing Agent<br />
emulsifier with excellent emulsifying capacity. Since this emulsifier is<br />
liquid at room temperature, creams and lotions can be processed cold.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Hostacerin ® DGSB Diglycerol distearate ethoxylated with 4 EO Approx. 100 % Waxy n.a. n.a.<br />
Hostacerin ® DGL Diglycerol laurate ethoxylated with 10 EO Approx. 100 % Liquid n.a. n.a.<br />
O/W Emulsifiers<br />
<strong>for</strong> Personal Care<br />
a dispersing agent <strong>for</strong> organic pigments in aqueous preparations or<br />
solvents. Emulsogen® HCO and HCP are used <strong>for</strong> solubilizing e<strong>the</strong>ric<br />
oils and fragrances in hydro-alcoholic solutions and aqueous solutions.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® EL 200 Castor oil ethoxylate with 20 EO Approx. 100 % Liquid n.a. Approx. 10<br />
Emulsogen ® EL 360 Castor oil ethoxylate with 36 EO Approx. 100 % Liquid n.a. Approx. 13<br />
Emulsogen ® EL 400 Castor oil ethoxylate with 40 EO Approx. 100 % Liquid n.a. Approx. 13<br />
Emulsogen ® EL 540 Castor oil ethoxylate with 54 EO Approx. 100 % Liquid n.a. Approx. 14<br />
Emulsogen ® HCO 040 Hydrogenated castor oil ethoxylate<br />
with 40 EO<br />
Approx. 100 % Paste n.a. Approx. 13<br />
Emulsogen ® HCO 060 Hydrogenated castor oil ethoxylate<br />
with 60 EO<br />
Approx. 100 % Paste n.a. Approx. 15<br />
Emulsogen ® HCP 049 Hydrogenated castor oil ethoxylate<br />
with 40 EO<br />
Approx. 90 % Liquid n.a. Approx. 15<br />
Emuslifiers <strong>for</strong><br />
Crop Protection<br />
and Metal Working,<br />
Dispersing Agents<br />
<strong>for</strong> Pigments<br />
Emulsifiers<br />
<strong>for</strong> Cosmetic<br />
Emulsions
Special purpose emulsifiers<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Cloud point (°C) HLB value Application<br />
Emulsogen ® 3896 Fatty alcohol ethoxylate Approx. 100 % Waxy 73 – 75 (3) Approx. 15<br />
Emulsogen ® A<br />
Emulsogen<br />
Fatty acid polyethylene glycol ester Approx. 100 % Liquid n.a. n.a.<br />
® IO Octyl phenol polyglycol e<strong>the</strong>r Approx. 100 % Liquid 61 – 63 (2) Emulsogen<br />
n.a.<br />
® LP Fatty alcohol polyethylene glycol e<strong>the</strong>r Approx. 100 % Liquid 69 – 72 (2) n.a.<br />
Emulsogen ® M Fatty alcohol polyethylene glycol e<strong>the</strong>r Approx. 100 % Liquid 66 – 68 (2) n.a.<br />
Emulsogen ® Emulsifiers <strong>for</strong> Oils,<br />
Waxes, Paraffins,<br />
Polyolefins, Hydrocarbons<br />
and<br />
Esters in <strong>Industrial</strong><br />
Emulsions<br />
SRO Rape oil sorbitol ester Approx. 100 % Liquid n.a. n.a. W/O Emulsifier<br />
<strong>for</strong> Personal Care<br />
* (1) 1 g in 100 cm 3 distilled water (2) 5g in 25cm 3 25% aqueous BDG (3) 1 g in 100 cm 3 10% aqueous NACI solution *relative to <strong>the</strong> active substance<br />
15
Anionic Surfactants<br />
Secondary alkyl sulfonates (secondary alkane sulfonates)<br />
The Hostapur ® SAS series can be used as an emulsifier in <strong>the</strong> poly -<br />
merization of E-PVC as well as in <strong>the</strong> production of styrene/butadiene<br />
and of acrylonitrile/butadiene rubber. The Hostapur ® SAS range is also<br />
Olefin sulfonates<br />
Hostapur ® OS liquid is used as emulsifier in emulsion polymerization<br />
of styrene/butadiene latex, styrene/butadiene rubber and acrylate and<br />
styrene/acrylate dispersions. It also serves as air entraining agent in<br />
concrete, especially <strong>for</strong> road pavements, mortar and plasters to im -<br />
prove <strong>the</strong> resistance against ice pressure during freezing. Hostapur ®<br />
OS liquid is particularly stable against calcium ions and, compared<br />
to o<strong>the</strong>r air entraining agents such as sodium alkyl sulfates, Hostapur ®<br />
Alkyl sulfates<br />
Emulsogen ® EPA 1954 is used as an emulsifier <strong>for</strong> emulsion polymerization,<br />
allowing <strong>the</strong> production of polymer dispersions with controlled<br />
particle size and low coagulation during <strong>the</strong> polymerization process.<br />
16<br />
a suitable emulsifier in <strong>the</strong> polymerization of vinyl acetate and comonomers,<br />
in <strong>the</strong> polymerization of acrylates and styrene/acrylates and<br />
in <strong>the</strong> polymerization of styrene/butadiene latex.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostapur ® SAS 30 Secondary alkyl sulfonate, Na salt Approx. 30 % Liquid<br />
Hostapur ® SAS 60 Secondary alkyl sulfonate, Na salt Approx. 60 % Paste<br />
Hostapur ® SAS 93 Secondary alkyl sulfonate, Na salt Approx. 93 % Waxy pellets<br />
Wetting Agent, Emulsifier <strong>for</strong> Poly -<br />
meri zation, Antistatic Agent, Surfactant<br />
<strong>for</strong> Heavy Duty Liquid Detergents<br />
OS liquid is more efficient and requires lower dosages. The powder<br />
<strong>for</strong>m Hostapur ® OSB is also used as air entraining and wetting agent<br />
<strong>for</strong> mortars and plasters based on cement, gypsum or lime. Rapidly<br />
soluble and highly efficient, it leads to a faster wetting of <strong>the</strong> solid<br />
particles, enables fast air-entrainment and develops mirco foam at<br />
a controllable air content of 20 - 35% in a short period of time.<br />
Fur<strong>the</strong>r more, it improves <strong>the</strong> plasticity and workability of plasters.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostapur ® OS Liquid C14/C16 alpha-olefin sulfonate, Na salt Approx. 42 % Liquid<br />
Hostapur ® OSB C14/C16 alpha-olefin sulfonate, Na salt Approx. 90 % Powder<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsion Polymerization (e.g. E-PVC),<br />
Wetting Agent <strong>for</strong> Hard Surface and<br />
Carpet Cleaners<br />
Air Entraining Agent <strong>for</strong> Construction<br />
Emulsogen ® EPA 1954 C12/C14 alkyl sulfate, Na salt Approx. 29 % Liquid Emulsion Polymerization (e.g. E-PVC)
Alkyl e<strong>the</strong>r sulfates<br />
In emulsion polymerization of monomers like styrene, acrylic acid<br />
esters, methacrylic acid esters and vinyl acetate, Emulsogen ® EPA<br />
073 or LA 083 are used as an emulsifier <strong>for</strong> <strong>the</strong> production of polymer<br />
dispersions with controlled particle size and very low grit levels at<br />
high solid contents. Added as wetting agent to inorganic and organic<br />
pigment preparations, Emulsogen ® EPA 073 or LA 083 enable <strong>for</strong>-<br />
Alkyl aryl e<strong>the</strong>r sulfates<br />
In emulsion polymerization, <strong>the</strong> use of Hostapal ® BV grades enables<br />
<strong>the</strong> production of polymer dispersions with controlled particle size,<br />
low coagulation and high stability against electrolytes, time and temperature.<br />
Hostapal ® BV types are a particularly suitable emulsifier in<br />
<strong>the</strong> polymerization of vinyl acetate toge<strong>the</strong>r with o<strong>the</strong>r vinyl esters,<br />
acrylates, vinyl chloride and ethylene, <strong>for</strong> acrylic and styrene/acrylic<br />
dispersions and <strong>for</strong> butadiene/styrene latex. Hostapal ® BV conc. also<br />
Polyglycol e<strong>the</strong>r sulfates<br />
Emulsogen ® PF 20 S is used as an emulsifier in emulsion polymerization,<br />
particularly in <strong>the</strong> manufacture of acrylate and styrene/acrylate<br />
dispersions.<br />
mulations with high pigment loads at low viscosity, high temperature<br />
stability and long shelf life. Emulsogen ® EPA 073 is also suitable to<br />
produce stable, low foaming emulsions of organic solvents, hydrocarbons,<br />
oils and waxes in water. Zeliquid® LP 2 finds widespread<br />
use in industrial applications as wetting agent, dispersing agent and<br />
emulsifier.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsogen ® EPA 073 Alkyl e<strong>the</strong>r sulfate with 7 EO, Na salt Approx. 28 % Liquid<br />
Emulsogen ® LA 083 Alkyl e<strong>the</strong>r sulfate with 8 EO, ammonium salt Approx. 30 % Liquid Emulsion Polymerization, Pigment Preparations<br />
Genapol ® LRO Liquid C12/C14 alkyl e<strong>the</strong>r sulfate with 2 EO, Na salt Approx. 27 % Liquid<br />
Genapol ® LRO paste C12/C14 alkyl e<strong>the</strong>r sulfate with 2 EO, Na salt Approx. 68 % Pasty<br />
Zeliquid ® Emulsion Polymerization, Pigment<br />
Preparations, Emulsifier<br />
Emulsion Polymerization, Air Entraining Agents<br />
<strong>for</strong> Construction, Hair Care Products<br />
LP 2 Lauryl e<strong>the</strong>r sulfate with 3 EO, Approx. 50 % Liquid<br />
Air Entraining Agent <strong>for</strong> Concrete and Mortars,<br />
ammonium salt + organ. solvent<br />
Dispersing Agent, Emuslifier<br />
functions as dispersing agent <strong>for</strong> inorganic and organic pigments<br />
such as titanium dioxide, iron oxides, metal pigments, polycyclic<br />
organic pigments and metal complex pigments <strong>for</strong> pigment pastes<br />
and pigment preparations in paper printing inks, textile printing pastes,<br />
ink-jet inks and in coatings and paints. In addition, Hostapal ® BV<br />
conc. can be employed as an emulsifier <strong>for</strong> oils and organic solvents.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostapal ® BV conc. Tributyl phenol e<strong>the</strong>r sulfate with 7 EO, Na salt Approx. 50 % Pasty<br />
Hostapal ® BV Liquid Tributyl phenol e<strong>the</strong>r sulfate with 7 EO, Na salt Approx. 17 % Liquid<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsion Polymerization,<br />
Dispersing Agent<br />
Emulsogen ® PF 20 S Polyalkylene glycol e<strong>the</strong>r sulfate, ammonium salt Approx. 50 % Liquid Emulsion Polymerization<br />
(acrylate and styrene/acrylate dispersions)<br />
17
Sulfosuccinic acid esters<br />
Emulsogen ® SF 8 serves as wetting agent <strong>for</strong> emulsion polymers, as<br />
foaming agent <strong>for</strong> carpet back sizing with e.g. SB-Latexes, as a cake<br />
dewatering aid, as wetting agent <strong>for</strong> waterborne paints and coatings<br />
with low VOC contents and as wetting agent <strong>for</strong> textile applications.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsogen ® SF 8 Diisooctyl sulfosuccinate, Na salt Approx. 50 % Liquid<br />
Fatty alkyl amine sulfosuccinamates<br />
Emulsogen ® TAS is used as a wetting agent, dispersing agent and<br />
emulsifier in various applications. Added as a dispersing agent <strong>for</strong><br />
inorganic pigments, Emulsogen ® TAS stabilizes and reduces <strong>the</strong> viscosity<br />
of <strong>the</strong> dispersion by electrostatic stabilization. In paper and<br />
Phosphoric acid esters<br />
Hostaphat ® CC 100 and CS 120 are highly effective anionic emulsifiers<br />
<strong>for</strong> O/W creams and lotions which contain a broad spectrum of oils<br />
and emollients, especially <strong>for</strong> stable water-resistant sun-care <strong>for</strong>mulations.<br />
Hostaphat ® KL 340 D and KW 340 D are especially suitable<br />
O/W emulsifiers <strong>for</strong> polar oils and UV filters. Hostaphat ® L 327 can<br />
be used as wetting and dispersing agent <strong>for</strong> pigment preparations of<br />
minerals and organic pigments, emulsifier <strong>for</strong> fats, waxes, hydrocarbons<br />
and in emulsion polymerization, antistatic agent in fiber prepa-<br />
18<br />
Emulsion Polymerization, Wetting Agent,<br />
Dispersing Agent<br />
textile coatings, particularly in carpet back sizing, Emulsogen TAS<br />
disperses <strong>the</strong> fillers (calcium carbonate and o<strong>the</strong>r minerals), stabilizes<br />
<strong>the</strong> styrene/butadiene latex and wets <strong>the</strong> coated surface.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsogen ® TAS Tallow alkyl amine sulfosuccinamate, Na salt Approx. 36 % Liquid Wetting Agent, Dis per sing Agent<br />
rations. Hostaphat ® MDAH is used as wetting and dispersing agent<br />
<strong>for</strong> pigment dispersions to increase <strong>the</strong> colour intensity in colour<br />
bases and as a stabilizer <strong>for</strong> aqueous metallic pigment pastes to protect<br />
<strong>the</strong> metal particles from corrosion. Hostaphat ® 1306 serves as<br />
emulsifier in emulsion polymerization, as dispersing agent <strong>for</strong> pigments<br />
in aqueous dispersions and as wetting agent and detergent<br />
in vehicle and metal cleaning and textile finishing processes.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostaphat ® CC 100 Cetyl phosphoric acid ester, acid <strong>for</strong>m Approx. 100 % Powder<br />
Hostaphat ® CS 120 Mono-/distearyl phosphoric acid ester, Approx. 92 % Waxy<br />
acid <strong>for</strong>m<br />
Hostaphat ® O/W Emulsifier (Triglycerides, Mineral<br />
Oils) <strong>for</strong> Cosmetic Emulsions<br />
Dispersing Agent <strong>for</strong> Mineral Pigments<br />
in Polymers<br />
KL 340 D Lauryl polyethoxy (4 EO) phosphoric acid<br />
ester, Na salt<br />
Approx. 90 % Liquid O/W and W/O Emulsifier<br />
continued on next page
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostaphat ® KL 340 N Lauryl polyethoxy (4 EO) phosphoric acid<br />
ester, Na salt<br />
Approx. 90 % Liquid O/W and W/O emulsifier<br />
Hostaphat ® KW 340 D Stearyl polyethoxy (4 EO) phosphoric acid<br />
ester, Na salt<br />
Approx. 90 % Liquid<br />
Hostaphat ® KW 340 N Stearyl polyethoxy (4 EO) phosphoric acid<br />
ester, Na salt<br />
Approx. 90 % Liquid<br />
Hostaphat ® L 327 Phosphoric acid ester of lauryl ethoxylate Approx. 95 % Liquid<br />
(2 EO) and polyethylene glycol<br />
Hostaphat ® MDAH Mono-/di-2-ethylhexyl phosphoric acid Approx. 98 % Liquid<br />
ester, acid <strong>for</strong>m<br />
Hostaphat ® Wetting and Dispersing Agent,<br />
Emulsion Polymerization<br />
Dispersing Agent <strong>for</strong> Organic<br />
Pigments in Ball Point Pens<br />
1306 Isotridecylpolyoxethyl (6 EO) phosphoric Approx. 96 % Liquid<br />
Emulsion Polymerization, Pigment<br />
acid mono/diester, acid <strong>for</strong>m<br />
Preparations, Detergents<br />
Alkyl phosphonic acids<br />
Hostaphat ® OPS grades are used as a dispersing agent <strong>for</strong> preparations<br />
of metal pigments such as aluminium or bronze and <strong>for</strong> inorganic<br />
pigments and titanium dioxide in mineral oils and organic solvents.<br />
Emulsogen ® CLA and COL grades are emulsifiers with corrosion inhibiting<br />
properties and can also be used <strong>for</strong> liquid acidic and alkaline toilet<br />
cleaners, as special surfactant <strong>for</strong> liquid cleaners and as foam booster.<br />
Hostaphat ® OPS improves <strong>the</strong> compatibility of aqueous pigment<br />
preparations with solvent-borne coatings such as alkyd resins.<br />
The product also helps to disperse titanium dioxide in polyolefins.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostaphat ® OPS 30 n-Octane phosphonic acid dissolved in water Approx. 30 % Pasty<br />
Hostaphat ® OPS 75 E n-Octane phosphonic acid + ethanol/water Approx. 75 % Liquid<br />
Hostaphat ® OPS 80 P n-Octane phosphonic acid + i-propanol/water Approx. 80 % Liquid<br />
Hostaphat ® OPS 100 n-Octane phosphonic acid Approx. 100 % Waxy<br />
Alkyl polyethylene glycol e<strong>the</strong>r carboxylic acids<br />
Dispersing Agents<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsogen ® CLA 030 Fatty alcohol polyoxethylene carboxylic acid with 3 EO Approx. 90 % Liquid<br />
Emulsogen ® COA 070 Fatty alcohol polyoxethylene carboxylic acid with 7 EO Approx. 90 % Liquid<br />
Emulsogen ® COL 020 Fatty alcohol polyoxethylene carboxylic acid with 2 EO Approx. 90 % Liquid<br />
Emulsogen ® COL 050 Fatty alcohol polyoxethylene carboxylic acid with 5 EO Approx. 94 % Liquid<br />
Emulsogen ® COL 080 Fatty alcohol polyoxethylene carboxylic acid with 8 EO Approx. 90 % Liquid<br />
Emulsogen ® COL 100 Fatty alcohol polyoxethylene carboxylic acid with 10 EO Approx. 90 % Liquid<br />
Metal Working,<br />
Detergents<br />
19
Fatty acid isethionates<br />
Hostapon ® SCI is a mild, high-foaming, anionic surfactant suited <strong>for</strong><br />
use in syndet bars, combo bars, liquid soaps and a variety of o<strong>the</strong>r<br />
Fatty acid methyl taurides<br />
Arkopon ® T 8015 is used <strong>for</strong> anionic bitumen emulsions and pigment<br />
preparations of inorganic pigments e.g. <strong>for</strong> titanium dioxide, enabling<br />
high pigment loads, low viscosity and high tinting strengths.<br />
Fatty acid sarcosine and sarcoside<br />
Because of its excellent physiological properties and neutral taste<br />
Medialan ® LD is widely used as a foaming agent in dental care<br />
preparations, especially in tooth-pastes.<br />
Miscellaneous products<br />
20<br />
personal care products. It also functions as antistatic agent <strong>for</strong> polymers,<br />
air entraining agent and emulsifier in silicone emulsions.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Hostapon ® SCI-65 Coconut fatty acid isethionate, Na salt Approx. 65 % Flakes Personal Care, Construction, Polymerization<br />
Hostapon ® CT paste has very good foaming capacity, foam stabilizing<br />
effect and additionally possesses very good lime soap dispersing<br />
capacity, and also acts as cleansing and degreasing surfactant.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Arkopon ® T 8015 Oleic acid methyl tauride, Na salt Approx. 40 % Pasty Dispersing Agent<br />
O/W-Bitumen Emulsions<br />
Hostapon ® TPHC Oleic acid methyl tauride, Na salt Approx. 60 % Powder<br />
Hostapon ® CT Paste Coconut fatty acid methyl tauride, Na salt Approx. 30 % Pasty Cosmetic Emulsions<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Medialan ® LD Lauroyl sarcoside, Na salt Approx. 30 % Liquid Foaming Agent in Dental Care<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Emulsogen ® E Mixture of alkyl aryl polyglycol e<strong>the</strong>r and Approx. 85% Liquid<br />
fatty amine salt, NPEO-containing<br />
Wetting Agent with Corrosion Inhibiting<br />
Properties <strong>for</strong> De-watering Fluids
Cationic and Amphoteric Surfactants<br />
Primary fatty amines<br />
Primary fatty Genamin ® grades are mainly used as raw material <strong>for</strong><br />
<strong>the</strong> manufacture of fatty amine ethoxylates and fatty amine salts. They<br />
also serve as antistatic agents, flotation agents, anti-caking agents,<br />
Secondary fatty amines<br />
Secondary fatty amines are a raw material <strong>for</strong> <strong>the</strong> chemical-technological<br />
industry, specifically used as starting material <strong>for</strong> quaternary<br />
ammonium compounds.<br />
corrosion inhibitors, additives <strong>for</strong> <strong>the</strong> textile and lea<strong>the</strong>r industry as<br />
well as <strong>for</strong> pigments, and as resin emulsifier.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genamin ® 8 R 100 D Octylamine, dist. Approx. 99 % Liquid<br />
Genamin ® 12 R 100 D Dodecylamine, dist. Approx. 99 % Solid<br />
Genamin ® 14 R 100 D Tetradecylamine, dist. Approx. 99 % Solid<br />
Genamin ® CC 100 Coconut fatty amine Approx. 96 % Liquid<br />
Genamin ® CC 100 D Coconut fatty amine, dist. Approx. 99 % Liquid<br />
Genamin ® OL 100 Soybean alkyl amine Approx. 96 % Liquid pasty<br />
Genamin ® OL 100 D Soybean alkyl amine, dist. Approx. 99 % Liquid pasty<br />
Genamin ® SH 100 Stearylamine Approx. 96 % Solid<br />
Genamin ® SH 100 D Stearylamine, dist. Approx. 99 % Solid<br />
Genamin ® TA 100 Tallow fatty amine Approx. 96 % Solid<br />
Genamin ® TA 100 D Tallow fatty amine, dist. Approx. 99 % Solid<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genamin ® CS 200 Dicoconut fatty amine Approx. 80 % Pasty wax<br />
Genamin ® SH 200 Distearylamine Approx. 86 % Pasty wax<br />
Cationic Emulsifier in Acidic<br />
Solutions, Bitumen Emulsions,<br />
Cationic Wax Emulsions, Pigments,<br />
<strong>Chemical</strong> Intermediates<br />
Intermediates <strong>for</strong> chemical reactions<br />
21
Tertiary fatty amines<br />
Dimethyl fatty alkylamines are valuable raw materials <strong>for</strong> <strong>the</strong> manufacture<br />
of quaternary ammonium compounds, betaines and amine oxides.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genamin ® 10 R 302 D Dimethyldecylamine, dist. Approx. 99 % Liquid<br />
Genamin ® 14 R 302 D Dimethyltetradecylamine, dist. Approx. 99 % Liquid<br />
Genamin ® 16 R 302 D Dimethylhexadecylamine, dist. Approx. 99 % Liquid<br />
Genamin ® 18 R 302 D Dimethyloctadecylamine, dist. Approx. 99 % Liquid pasty<br />
Genamin ® 20/22 R 302 D Dimethyl-eicosyl-/docosylamine, dist. Approx. 99 % Solid<br />
Genamin ® CC 302 D Dimethyl coconut fatty amine, dist. Approx. 99 % Liquid<br />
Genamin ® CS 302 D Dimethyl coconut fatty amine, dist. Approx. 99 % Liquid<br />
Genamin ® LA 302 D Dimethyllaurylamine, dist. Approx. 99 % Liquid<br />
Genamin ® SH 302 D Dimethylstearylamine, dist. Approx. 99 % Liquid<br />
Genamin ® TA 302 D C16/18 fatty alkyl dimethyl amine, dist. Approx. 98 % Liquid<br />
Genamin ® 10 R 301 D Didecylmethylamine, dist. Approx. 99 % Liquid<br />
Genamin ® SH 301 Distearylmethylamine Approx. 95 % Solid<br />
Hostarex ® A 324 Triisooctylamine Approx. 95 % Liquid<br />
Hostarex ® A 327 Tri-n-octyl-/n-decylamine Approx. 95 % Liquid<br />
Fatty alkyl di- and polyamines<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genamin ® LAP 100 D Laurylpropylenediamine, dist. Approx. 92 % Solid<br />
Genamin ® OLP 100 Soybean propylenediamine Liquid<br />
Genamin ® TAP 100 Tallow fatty propylenediamine Approx. 80 % Solid<br />
Genamin ® 3119 N,N-bisaminopropyl tallow fatty amine Liquid<br />
22<br />
<strong>Chemical</strong> Intermediate<br />
<strong>for</strong> Quats, Cationic Wax<br />
Emulsions, Pigment Additives,<br />
Mining <strong>Chemical</strong>s<br />
Asphalt Emulsions, Pigment<br />
<strong>Process</strong>ing, Dispersing Aids, Crop<br />
Protection, <strong>Chemical</strong> Intermediates,<br />
Detergents, Textile Softeners,<br />
Oil Exploration <strong>Chemical</strong>s
Quaternary ammonium compounds<br />
As quaternary fatty ammonium salts are compounds with strong<br />
bactericidal and fungicidal action, Dodigen ® grades find widespread<br />
use in disinfectant cleaners and also help to control algae, <strong>for</strong> instance<br />
in cooling water and swimming baths. In cosmetics, Präpagen ® and<br />
Dodigen ® grades are used e.g. in <strong>the</strong> <strong>for</strong>mulation of hair care products.<br />
In <strong>the</strong> textile industry, Präpagen ® and Dodigen ® grades are<br />
Amine oxides<br />
Amine oxides are good surfactants and, unlike fatty alkyl ammonium<br />
salts, can be used toge<strong>the</strong>r with anionic compounds without impairment<br />
of <strong>the</strong>ir surface-active properties. Our Genaminox ® grades are<br />
used especially in <strong>the</strong> detergent industry, where <strong>the</strong>y serve primarily<br />
Amine salts<br />
used as softeners, re-wetting and antistatic and antibacterial finishing<br />
agents and have proved to be successful levelling agents and<br />
retarders in acrylic fibre dyeing. O<strong>the</strong>r applications include <strong>the</strong> use as<br />
acid inhibitors, emulsifiers, dispersing agents, vulcanization accelerators,<br />
antistatic agents and auxillaries in paint applications.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Präpagen ® 3445 Di-tallow-fatty-alkyldimethyl<br />
ammonium chloride<br />
70 – 72 % Liquid Detergents, Organophile Bentonite<br />
Präpagen ® 4317 Triethanolamine esterquat 87 – 91 %* Liquid Detergents, Organophile Bentonite<br />
Dodigen ® 226** Coconut-alkyldimethyl benzylammonium 50 – 52 % Liquid<br />
chloride<br />
Dodigen ® 1611** Alkyldimethylbenzyl ammonium chloride 50 – 52 % Liquid<br />
Dodigen ® Disinfection, Phase Transfer<br />
Catalysts<br />
3519** Didecylmethylalkoxi-ammonium propionate 68 – 72 % Liquid<br />
* Dry solids, 105 °C, 2 h ** Sale by Lonza AG, Basel<br />
as foam stabilizers, in liquid acid and alkaline toilet cleaners, solubilizing<br />
agents and skin protective components in washing-up liquids<br />
and carpet shampoos, and cosmetics, where <strong>the</strong>y function as foam<br />
stabilizers and emulsifiers.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genaminox ® CSL C12/C18 coconut fatty alkyl dimethyl amine oxide Approx. 30 % Liquid<br />
Genaminox ® LA C12/C14 alkyl dimethyl amine oxide Approx. 30 % Liquid<br />
Genaminox ® MY C14 alkyl dimethyl amine oxide Approx. 30 % Liquid<br />
Genaminox ® 1216 C12/C16 alkyl dimethyl amine oxide Approx. 30 % Liquid<br />
Trade name <strong>Chemical</strong> name Appearance (20 °C) Application<br />
Air Entraining Agents<br />
in Concrete, Detergents,<br />
Personal Care<br />
Genamin ® CC 500 A Coconut fatty amine acetate Solid Car Rinse Aids,<br />
Genamin ® CC 500 E Coconut fatty amine oleate Pasty Mining <strong>Chemical</strong>s<br />
23
Betaines<br />
Betaines act as cationic surfactants and in alkaline solutions as<br />
inner neutral salts. They are often used in cosmetics.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C) Application<br />
Genagen ® CAB 818 Alkyl amidopropyl sulfo betaine Approx. 30 % Liquid Cosmetics<br />
Amine ethoxylates<br />
Their specific surface active properties make <strong>the</strong> Genamin ® grades<br />
a valuable basis and additive <strong>for</strong> <strong>the</strong> chemical technical industry.<br />
They can be used to manufacture textile auxiliaries (e.g. products<br />
<strong>for</strong> dyeing), as mineral oil additives, in crop protection products and<br />
pesticides, and as raw materials <strong>for</strong> cosmetics and adhesives.<br />
24<br />
Genamin ® grades can be combined with all types at nonionic and<br />
cationic surfactants, and are compatible with anionic products on<br />
a case-by-case level. The Genamin ® grades are resistant to most<br />
chemicals at typical concentrations used and insensitive to water<br />
hardness.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C)<br />
Genamin ® C 020 C8/C18 coconut fatty amine ethoxylate with 2 EO Approx. 100 % Liquid<br />
Genamin ® C 050 C8/C18 coconut fatty amine ethoxylate with 5 EO Approx. 100 % Liquid<br />
Genamin ® C 100 C8/C18 coconut fatty amine ethoxylate with 10 EO Approx. 100 % Liquid<br />
Genamin ® C 150 C8/C18 coconut fatty amine ethoxylate with 15 EO Approx. 100 % Liquid<br />
Genamin ® C 200 C8/C18 coconut fatty amine ethoxylate with 20 EO Approx. 100 % Liquid<br />
Genamin ® O 020 sp Oleyl amine ethoxylate with 2 EO Approx. 100% Liquid<br />
Genamin ® O 050 Oleyl amine ethoxylate with 5 EO Approx. 100% Liquid<br />
Genamin ® O 080 Oleyl amine ethoxylate with 8 EO Approx. 100% Liquid<br />
Genamin ® O 200 Oleyl amine ethoxylate with 20 EO Approx. 100% Liquid<br />
Genamin ® S 020 sp Stearyl amine ethoxylate with 2 EO Approx. 100 % Solid<br />
Genamin ® S 080 Stearyl amine ethoxylate with 8 EO Approx. 100 % Liquid<br />
Genamin ® S 100 Stearyl amine ethoxylate with 10 EO Approx. 100 % Liquid<br />
Genamin ® S 150 Stearyl amine ethoxylate with 15 EO Approx. 100 % Liquid<br />
Genamin ® S 200 Stearyl amine ethoxylate with 20 EO Approx. 100 % Liquid<br />
Genamin ® S 250 Stearyl amine ethoxylate with 25 EO Approx. 100 % Solid<br />
Genamin ® T 100 Tallow fatty alkyl amine ethoxylate with 10 EO Approx. 100 % Liquid<br />
Genamin ® T 150 Tallow fatty alkyl amine ethoxylate with 15 EO Approx. 100 % Liquid
Copolymerizable Emulsifiers<br />
Classic anionic and non-ionic emulsifiers stabilize <strong>the</strong> emulsion by<br />
physical interaction. However, <strong>the</strong>se surfactants desorb at high shear<br />
<strong>for</strong>ces or because of electrolytes which <strong>the</strong>n in turn leads to coagulation<br />
of <strong>the</strong> latex particles.<br />
In order to avoid migration and nest <strong>for</strong>mation in <strong>the</strong> polymer film,<br />
Nonionic copolymerizable emulsifiers<br />
Anionic copolymerizable emulsifiers<br />
Clariant has developed a range of copolymerizable emulsifiers, which<br />
chemically bond to <strong>the</strong> polymer, inhibiting migration in <strong>the</strong> film and<br />
resulting in higher latex stability. Additionally, freeze-thaw stability<br />
and shear stability are significantly improved. The products are also<br />
less water absorbant and enable hydrophobic coating surfaces.<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C)<br />
Emulsogen ® R 208 Vinyl polyoxyalkylene glycol e<strong>the</strong>r with 20 EO Approx. 80 % Liquid<br />
Emulsogen ® R 506 Vinyl polyoxyalkylene glycol e<strong>the</strong>r with 50 EO Approx. 60 % Liquid<br />
Emulsogen ® RAL 307 Allyl polyoxyalkylene glycol e<strong>the</strong>r with 30 EO Approx. 70 % Liquid<br />
Trade name <strong>Chemical</strong> name Active content Appearance (20 °C)<br />
Emulsogen ® APG 2019 Allyl phenylpolyol e<strong>the</strong>r sulfate with 20 EO, ammonium salt Approx. 90 % Liquid<br />
Emulsogen ® APS 100 Allyl polyoxyalkylene sulfate with 10 EO, ammonium salt Approx. 100 % Liquid<br />
25
Foam Control Agents<br />
Polyglycol based antifoams<br />
Trade name Ionicity Flash Point Appearance (20 °C) Application<br />
Antimussol ® FN Nonionic >100 °C Liquid Anionic and Cationic Surfactant Formulations, Polycarboxylate<br />
E<strong>the</strong>rs in Construction, Emulsion Polymers<br />
Antimussol ® TW Nonionic >100 °C Liquid Waste Water Treatment<br />
Antimussol ® 3470 Nonionic >100 °C Liquid Nonionic Surfactant Formulations<br />
Antimussol ® 3472 N Cationic >100 °C Liquid Anionic Surfactant Formulations<br />
Phosphate ester based antifoams<br />
Trade name Ionicity Flash Point Appearance (20 °C) Application<br />
Antimussol ® TIP Anionic Approx. 27 °C Liquid Phosphorus Containing Defoamer <strong>for</strong> Emulsion Polymerization<br />
and o<strong>the</strong>r <strong>Industrial</strong> Applications, Water Treatment<br />
Mineral oil based antifoams<br />
Trade name Ionicity Flash Point Appearance (20 °C) Application<br />
Antimussol ® AC Anionic >100 °C Powder Construction <strong>Industry</strong><br />
Antimussol ® MC Anionic >100 °C Liquid<br />
Antimussol ® MN Anionic >100 °C Liquid<br />
Antimussol ® NS 22 Anionic About 120 °C Liquid<br />
Antimussol ® W 06 Anionic About 70 °C Liquid<br />
Antimussol ® Paints and Coatings,<br />
Emulsion Polymers,<br />
Adhesives, Construction<br />
Z 70 Anionic About 120 °C Liquid<br />
26
Exactly your chemistry.<br />
Clariant International Ltd.<br />
Functional <strong>Chemical</strong>s Division<br />
www.clariant.com<br />
Clariant International Ltd.<br />
Functional <strong>Chemical</strong>s Division<br />
<strong>Industrial</strong> and Consumer Care Business<br />
Coatings and Construction <strong>Chemical</strong>s<br />
EBR 5275 01/09<br />
Marketing<br />
Rothausstrasse 61<br />
4132 Muttenz<br />
Switzerland<br />
Phone: +41 61 469 7793<br />
Fax: +41 61 469 7585<br />
Research & Development<br />
Brüningstrasse 50<br />
Building D561<br />
65926 Frankfurt am Main<br />
Germany<br />
Phone: +49 69 305 6308<br />
Fax: +49 69 305 16504<br />
www.ipc.clariant.com<br />
e-mail:ipc@clairant.com<br />
® = Registered trade mark<br />
This in<strong>for</strong>mation is based on our present state of knowledge and is intended to<br />
provide general notes on our products and <strong>the</strong>ir uses. It should not <strong>the</strong>re<strong>for</strong>e<br />
be construed as guaranteeing specific properties of <strong>the</strong> products described on<br />
<strong>the</strong>ir suitability <strong>for</strong> a particular application. Any existing industrial property rights<br />
must be observed. The quality of our products is guaranteed under our General<br />
Conditions of Sale.<br />
Copyright © Clariant International AG, 2008