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Chemistry of Precious Metals - CNTQ

Chemistry of Precious Metals - CNTQ

Chemistry of Precious Metals -

Chemistry of Precious Metals Dr S.A. COTTON Uppingham School Rutland UK BLACKIE ACADEMIC & PROFESSIONAL An Imprint of Chapman & Hall London • Weinheim • New York • Tokyo • Melbourne • Madras

  • Page 2 and 3: Published by Blackie Academic and P
  • Page 4 and 5: are not yet in compilations) but in
  • Page 6 and 7: PP 2,11 -bis(diphenylphosphinomethy
  • Page 8 and 9: vi Contents 1.8.4 Sulphide and Sulp
  • Page 10 and 11: viii Contents 2.14 Iridium(IV) Comp
  • Page 12 and 13: x Contents 4.2.2 Gold Plating and O
  • Page 14 and 15: 1 Ruthenium and osmium 1.1 Introduc
  • Page 16 and 17: there are one-dimensional chains, a
  • Page 18 and 19: Figure 1.2 The structure adopted by
  • Page 20 and 21: Table 1.2 Vibrational frequencies*
  • Page 22 and 23: Table 1.3 Bond lengths in MX6 7 " (
  • Page 24 and 25: Various routes are available for th
  • Page 26 and 27: Figure 1.5 The vibrational spectra
  • Page 28 and 29: Os2X8 2 " Os2X10 2 " (a) (b) Figure
  • Page 30 and 31: 1.3.6 Oxyhalide complexes Various a
  • Page 32 and 33: OsO4 is obtained on oxidation of an
  • Page 34 and 35: 1.5 Other binary compounds Rutheniu
  • Page 36 and 37: 2 Rhodium and iridium 2.1 Introduct
  • Page 38 and 39: All of these probably have the AlCl
  • Page 40 and 41: Ir M3IrCl6 Cs3IrBr6 MIrF6 IrO2.«H2
  • Page 42 and 43: Mixed halometallates [28] can be sy
  • Page 44 and 45: hodium in air or oxygen (300-100O 0
  • Page 46 and 47: thus recrystallizing a RhCl^ salt g
  • Page 48 and 49: Red form Oran e form g Figure 2.5 B
  • Page 50 and 51: dissociation for RhCl(PPh3)3. (It i
  • Page 52 and 53:

    Figure 2.11 Bond lengths in RhH(PPh

  • Page 54 and 55:

    Figure 2.15 Cycle for the hydrogena

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    5:1 complexes Few of the 5:1 comple

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    COCH2CH2R Figure 2.21 Probable stru

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    Figure 2.24 NMR spectrum of Rh(SH)(

  • Page 62 and 63:

    2.7.3 Alkene complexes Figure 2.27

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    2.8 Rhodium(H) complexes Until rece

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    Figure 2.33 The ESR spectrum of [Rh

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    2. The long Rh-P bonds in the terti

  • Page 70 and 71:

    Figure 2.37 Models for the metal-me

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    Figure 2.40 The staggered structure

  • Page 74 and 75:

    3 Palladium and platinum 3.1 Introd

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    ores include all six platinum metal

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    Figure 3.1 The chain structure OfQj

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    Figure 3.2 The structure of /5-PtCl

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    Table 3.3 Bond lengths in MX^ toget

  • Page 84 and 85:

    Table 3.5 Comparing bond lengths in

  • Page 86 and 87:

    Figure 3.7 The dimeric structure of

  • Page 88 and 89:

    Figure 3.9 The structure of PtS. (R

  • Page 90 and 91:

    Figure 3.11 The structure of Pd(Pcy

  • Page 92 and 93:

    Figure 3.12 Complexes produced by r

  • Page 94 and 95:

    cis-pt(PPh3)2RI (R = Me, C6F5, etc.

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    1. Addition of radical inhibitors (

  • Page 98 and 99:

    3.6.5 Isocyanide complexes A few is

  • Page 100 and 101:

    Figure 3.22 The staggered structure

  • Page 102 and 103:

    Table 4.1 Compounds of copper, silv

  • Page 104 and 105:

    Silver was formerly extracted by cy

  • Page 106 and 107:

    Anhydrous AgF is best made by fluor

  • Page 108 and 109:

    Table 4.5 Energy values 0 for gold

  • Page 110 and 111:

    It is an intensely reactive and hyg

  • Page 112 and 113:

    Table 4.6 Selected electrode potent

  • Page 114 and 115:

    Figure 4.7 The environment of silve

  • Page 116 and 117:

    Figure 4.10 The structure OfK2AgI3.

  • Page 118 and 119:

    4.7 Silver(II) complexes Stable com

  • Page 120 and 121:

    4.10 GoId(I) complexes 4.10.1 Compl

  • Page 122 and 123:

    Table 4.9 Structure and spectroscop

  • Page 124 and 125:

    Ions of the type AuX2 are found as

  • Page 126 and 127:

    L [AuL2]+ Au + Figure 4.17 A qualit

  • Page 128 and 129:

    364 Index terms Links Bond lengths

  • Page 130 and 131:

    366 Index terms Links Gold(III) com

  • Page 132 and 133:

    368 Index terms Links Bond lengths

  • Page 134 and 135:

    370 Index terms Links Iridium(III)

  • Page 136 and 137:

    372 Index terms Links Phosphine com

  • Page 138 and 139:

    374 Index terms Links Bond lengths

  • Page 140 and 141:

    376 Index terms Links Osmium(III) c

  • Page 142 and 143:

    378 Index terms Links Palladium Amm

  • Page 144 and 145:

    380 Index terms Links Palladium(II)

  • Page 146 and 147:

    382 Index terms Links Vibrational s

  • Page 148 and 149:

    384 Index terms Links Isomerism in

  • Page 150 and 151:

    386 Index terms Links Platinum(II)

  • Page 152 and 153:

    388 Index terms Links Trans-effect

  • Page 154 and 155:

    390 Index terms Links Divalent 106

  • Page 156 and 157:

    392 Index terms Links Rhodium(I) co

  • Page 158 and 159:

    394 Index terms Links Rhodium(III)

  • Page 160 and 161:

    396 Index terms Links Catalysts 30

  • Page 162 and 163:

    398 Index terms Links Ruthenium(II)

  • Page 164 and 165:

    400 Index terms Links Uses Vibratio

  • Page 166 and 167:

    402 Index terms Links Silver(I) com

  • Page 168 and 169:

    23. (a) O. Glemser, H.W. Roesky, K.

  • Page 170 and 171:

    71. E. Krausz and J. Ferguson, Prog

  • Page 172 and 173:

    126. JJ. Levison and S.D. Robinson,

  • Page 174 and 175:

    171. D.H. Farrar, P.A. Maltby and R

  • Page 176 and 177:

    14. J. Reed and P. Eisenberger, Ada

  • Page 178 and 179:

    70. K.R. Dunbar, S.C. Haefner and L

  • Page 180 and 181:

    123. L. Vaska and D.L. Catone, J. A

  • Page 182:

    170. L.F. Rhodes, J.C. Huffman and

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