Topics in Current Chemistry

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VIII Preface leading scientists present modern research trends in comprehensive reviews which not only provide a deep insight into the specific subjects, but are also written in a style that enables researchers from related fields and graduate students to follow the interesting presentations.I am convinced that the contributions in the present and in the companion volumes demonstrate the attractiveness and the great potential for applications of metal compounds and that a more detailed understanding of the photophysical properties will open pathways for new developments. Regensburg, Germany April 2004 Hartmut Yersin
Contents Triplet Emitters for OLED Applications. Mechanisms of Exciton Trapping and Control of Emission Properties H. Yersin .................................................... 1 Luminescent Cyclometalated Diimine Platinum(II) Complexes: Photophysical Studies and Applications S.-W. Lai · C.-M. Che . . ........................................ 27 Photophysical Properties of Three-Dimensional Transition Metal Tris-Oxalate Network Structures A. Hauser · M.E. von Arx · V.S. Langford · U. Oetliker · S. Kairouani A. Pillonnet. . ................................................ 65 Excited States and Optical Spectroscopy of Nitronyl Nitroxides and their Lanthanide and Transition Metal Complexes G. Bussi›re · R. Beaulac · H. BØlisle · C. Lescop · D. Luneau · P. Rey C.Reber .................................................... 97 Electronic Spectroscopy and Photoreactivity of Transition Metal Complexes: Quantum Chemistry and Wave Packet Dynamics C. Daniel .................................................... 119 Spectra, Energy Levels and Energy Transfer in High Symmetry Lanthanide Compounds P.A. Tanner . . ................................................ 167 Author Index Volumes 201-241 ................................. 279 Subject Index ............................................... 291
Page 1 and 2: 241 Topics in Current Chemistry Edi
Page 3 and 4: Transition Metal and Rare Earth Com
Page 5 and 6: Volume Editor Prof. Dr. Hartmut Yer
Page 7: Preface For a long time, the proper
Page 11 and 12: Contents of Volume 214 Transition M
Page 13 and 14: 120 C. Daniel 4.1 Dissociative vs N
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Page 17 and 18: 124 C. Daniel Zeta with polarizatio
Page 19 and 20: 126 C. Daniel The difficulty for th
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Page 23 and 24: 130 C. Daniel racy will be produced
Page 25 and 26: 132 C. Daniel [12] has been applied
Page 27 and 28: 134 C. Daniel tation of ground stat
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Page 31 and 32: 138 C. Daniel @U=@Q þ KU ¼ 0 ð4
Page 33 and 34: 140 C. Daniel packet, the centre of
Page 35 and 36: Table 1 Calculated electronic allow
Page 37 and 38: 144 C. Daniel Table 2 Calculated el
Page 39 and 40: 146 C. Daniel Scheme 6 (B3LYP) calc
Page 41 and 42: 148 C. Daniel Scheme 7 sponding to
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Page 45 and 46: 152 C. Daniel 3.4 Spin-Orbit Effect
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Top Curr Chem (2004) 241:97--118 DO
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Excited States and Optical Spectros
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Top Curr Chem (2004) 241:27--63 DOI
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Luminescent Cyclometalated Diimine
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66 A. Hauser et al. ceptor, play an
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68 A. Hauser et al. serve as therma
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70 A. Hauser et al. Fig. 4 Single c
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72 A. Hauser et al. are superimposa
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74 A. Hauser et al. and the finesse
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76 A. Hauser et al. Fig. 10 Mechani
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78 A. Hauser et al. k et D ¼ X A w
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80 A. Hauser et al. Fig. 14 FLN spe
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82 A. Hauser et al. The intrinsic l
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84 A. Hauser et al. Fig. 15 Quantum
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86 A. Hauser et al. Fig. 17 Scheme
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88 A. Hauser et al. Fig. 20 a Trans
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94 A. Hauser et al. below 2 K, the
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96 A. Hauser et al. 19. Sugano S, T
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168 P.A. Tanner 14 Conclusions ....
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170 P.A. Tanner ration, the stoichi
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172 P.A. Tanner Fig. 2 a Plot of la
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174 P.A. Tanner with smaller unit c
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176 P.A. Tanner Oh for elpasolites.
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178 P.A. Tanner Fig. 4a-g Infrared,
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180 P.A. Tanner Table 2 (continued)
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182 P.A. Tanner Table 3 Comparison
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184 P.A. Tanner belled. The unit ce
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186 P.A. Tanner sion curve for this
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188 P.A. Tanner so that B ð4Þ 0
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190 P.A. Tanner coordinates. One of
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192 P.A. Tanner
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194 P.A. Tanner where Wl ¼ ½Š l
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196 P.A. Tanner
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198 P.A. Tanner electric dipole mom
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200 P.A. Tanner respectively, where
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202 P.A. Tanner modified form in mo
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204 P.A. Tanner M00;f 1;q ¼ X n ½
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206 P.A. Tanner The sign of the int
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208 P.A. Tanner try notation of Gri
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210 P.A. Tanner Finally, it is note
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212 P.A. Tanner The actual assignme
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214 P.A. Tanner Fig. 13 35 K Raman
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216 P.A. Tanner terial, so that the
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218 P.A. Tanner Fig. 14a-c Electron
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220 P.A. Tanner 2 6 X 6 l;m;n 6 4
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222 P.A. Tanner allowed, and in var
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224 P.A. Tanner Table 7 Calculated
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226 P.A. Tanner Fig. 16 Lowest f-d,
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228 P.A. Tanner Fig. 18a, b 10 K f-
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230 P.A. Tanner It is interesting t
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232 P.A. Tanner Table 9 Selected en
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234 P.A. Tanner Fig. 20 Plots of Sl
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236 P.A. Tanner values are obtained
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238 P.A. Tanner X ½B k qCk q i ð
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240 P.A. Tanner their calculation h
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242 P.A. Tanner 13 Energy Transfer
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244 P.A. Tanner Table 11 (continued
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246 P.A. Tanner Fig. 24a-j Energy t
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248 P.A. Tanner Table 13 Structural
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250 P.A. Tanner s=6, although the c
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252 P.A. Tanner ask 2 ¼ 1 4 h es;a
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254 P.A. Tanner The HLO model has g
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256 P.A. Tanner Fig. 25a, b Lumines
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258 P.A. Tanner when excitation is
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260 P.A. Tanner Fig. 26 a Partial e
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262 P.A. Tanner 13.4.3 Upconversion
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264 P.A. Tanner ! 4 I15=2aG8½ŠD 0
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266 P.A. Tanner Fig. 27 a Power dep
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268 P.A. Tanner The study of f-d tr
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270 P.A. Tanner 41. Knudsen GP, Vos
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272 P.A. Tanner 119. Malta OL, Gouv
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274 P.A. Tanner 207. Tanner PA, Mak
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276 P.A. Tanner 290. Hehlen MP, Gü
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278 P.A. Tanner 379. Berry ME, May
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2 H. Yersin trix molecules with sub
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4 H. Yersin into substates, the tot
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6 H. Yersin Fig. 2 Example of an op
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8 H. Yersin 3 Exciton Formation and
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10 H. Yersin gram is simplified and
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12 H. Yersin to-matrix charge trans
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14 H. Yersin triplet excitons, are
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16 H. Yersin tions, but also induce
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18 H. Yersin 5 Photophysical Proper
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20 H. Yersin 5.3 Phosphorescence De
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22 H. Yersin 5.6 Electronic Charge
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24 H. Yersin 3. Tai WP, Inoue K, Oh
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26 H. Yersin 71. Wohlgenannt M, Tan
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280 Author Index Volumes 201-241 Br
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282 Author Index Volumes 201-241 Ga
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284 Author Index Volumes 201-241 Ko
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286 Author Index Volumes 201-241 Mu
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288 Author Index Volumes 201-241 Sh
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290 Author Index Volumes 201-241 Wu
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292 Subject Index DMCT 1, 12 DNA 56
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294 Subject Index Resonant energy t
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