Views
3 years ago

High-Pressure Studies of (Mg0.9Fe0.1)2SiO4 Olivine Using Raman ...

High-Pressure Studies of (Mg0.9Fe0.1)2SiO4 Olivine Using Raman ...

High-Pressure Studies of (Mg0.9Fe0.1)2SiO4 Olivine Using Raman

High-Pressure Studies of (Mg0.9Fe0.1)2SiO4 Olivine Using Raman Spectroscopy, X-ray Diffraction, and Mössbauer Spectroscopy J. Rouquette,* ,†,§ I. Kantor, † C. A. McCammon, † V. Dmitriev, ‡ and L. S. Dubrovinsky † Bayerisches Geoinstitut, UniVersität Bayreuth, D-95440 Bayreuth, Germany, and European Radiation Synchrotron Facility (ESRF), Swiss-Norwegian Beam Lines (SNBL), BP220 38047 Grenoble CEDEX 9, France Received October 8, 2007 Introduction High-pressure studies of (Mg0.9Fe0.1)2SiO4 olivine were performed at ambient temperature using X-ray diffraction, Raman spectroscopy, and Mössbauer spectroscopy. At ∼40 GPa, a change of compressibility associated with saturation of the anisotropic compression mechanism was detected. This change is interpreted to result from the appearance of Si2O7 dimer defects, as deduced from Raman spectroscopy; the appearance of such defects also accounts for the previously reported pressure-induced amorphization observed for this material upon additional compression. Furthermore, this behavior is followed by a spin crossover of Fe 2+ that occurs over a wide pressure range, as revealed by Mössbauer spectroscopy. The magnesium-iron silicate mineral olivine, (Mg1-x- Fex)2SiO4, with x ≈ 0.1–0.2 is one of the main minerals constituting the Earth’s crust and upper mantle, 1 and its highpressure and high-temperature properties are of great interest for the earth sciences. Olivine forms a solid solution between the two end-members of this mineral series, fayalite (Fe2SiO4) and forsterite (Mg2SiO4). Mg2SiO4 transforms to modified spinel (wadsleyite) and spinel (ringwoodite) structures upon heating at ∼13.5 and ∼18 GPa, 2,3 respectively, while Fe2SiO4 directly transforms to the spinel structure at ∼8 GPa. 4 In olivine at ambient conditions (orthorhombic, space group Pbnm), 5 Si atoms are coordinated with four O atoms to form [SiO4] tetrahedra, while (Mg, Fe) atoms are surrounded by six O atoms. There are two kinds of (Mg, Fe) sites, one on the inversion center and the other on the plane of mirror symmetry (the M1 and M2 sites, respectively). * To whom correspondence should be addressed. E-mail: jerome@ lpmc.univ-montp2.fr. † Universität Bayreuth. ‡ European Radiation Synchrotron Facility. § Present address: Institut Charles Gerhardt UMR CNRS 5253, Université de Montpellier II Sciences et Techniques du Languedoc, Place E. Bataillon cc 1503, 34095 Montpellier cedex, France. (1) Ringwood, A. E. Geochim. Cosmochim. Acta 1991, 55, 2083. (2) Ringwood, A. E.; Major, A. Earth Planet. Sci. Lett. 1966, 1, 241. (3) Akimoto, S.; Fujisawa, H. J. Geophys. Res. 1968, 73, 1467. (4) Furnish, M. D.; Bassett, W. A. J. Geophys. Res., B 1983, 88, 10333. (5) Putnis, A. Introduction to Mineral Sciences; Cambridge University Press: New York, 1992; Chapter 6. Inorg. Chem. 2008, 47, 2668-2673 Application of pressure was reported to induce amorphization at ∼39 GPa for Fe2SiO4 6 and above 70 GPa for Mg2SiO4. 7 High-pressure energy-dispersive X-ray diffraction experiments have been performed for the entire series of olivine solid solutions (0 e x e 1), 8 in which a noticeable change in compressibility occurring at higher pressures for Mg- than for Fe-rich olivines (at 42 and 12 GPa for the respective end-members) was characterized. Therefore, there is a need for an extended high-pressure study of the electronic configuration of iron in olivine, as the substitution of magnesium by iron produces a noticeable downshift in the pressure required to induce the change in compressibility despite the fact that the ionic radii are quite similar (rMg 2+ ≈ 72 pm and rFe 2+ ≈ 78 pm 9–11 ). Additionally, in a high-pressure Raman spectroscopy study of a single crystal of Mg2SiO4, 12 the appearance of spectral changes upon compression was associated with the formation of Si-O-Si linkages between adjacent SiO4 tetrahedra to give Si2O7 dimers. These defects, (6) Williams, Q.; Knittle, E.; Reichlin, R.; Martin, S.; Jeanloz, R. J. Geophys. Res. [Solid Earth Planets] 1990, 95, 21549. (7) Guyot, F.; Reynard, B. Chem. Geol. 1992, 96, 411. (8) Andrault, D.; Bouhifd, M. A.; Itié, J. P.; Richet, P. Phys. Chem. Miner. 1995, 22, 99. (9) Ahrens, L. H. Geochim. Cosmochim. Acta 1952, 2, 155. (10) Pauling, L. The Nature of the Chemical Bond; Cornell University Press: Ithaca, NY, 1961. (11) Shannon, R. D. Acta Crystallogr. 1976, A32, 751. (12) Durben, D. J.; McMillan, P. F.; Wolf, G. H. Am. Mineral. 1993, 78, 1143. 2668 Inorganic Chemistry, Vol. 47, No. 7, 2008 10.1021/ic701983w CCC: $40.75 © 2008 American Chemical Society Published on Web 03/05/2008

LIINA KANGUR High-Pressure Spectroscopy Study of Chromophore ...
tymri.ut.ee
PDF [DOWNLOAD] How to Lower High Blood Pressure using Cayenne Pepper Mr Nigel Thomas BOOK ONLINE
ibrahimisra
GET PDF Study Smarter, Not Harder (Reference Series) GET PDF
Donovang4t4
BEST PDF Natural High Blood Pressure Solutions: Lower Your Blood Pressure Naturally Using Diet And Natural Remedies Without Medication Melody Ambers READ ONLINE
billiyancik
PDF [DOWNLOAD] Natural High Blood Pressure Solutions: Lower Your Blood Pressure Naturally Using Diet And Natural Remedies Without Medication Melody Ambers [DOWNLOAD] ONLINE
hurryeas
PDF DOWNLOAD High Blood Pressure Lowered Naturally - Your Arteries Can Clean Themselves BOOK ONLINE
dizexu
PDF DOWNLOAD The High Blood Pressure Solution: Natural Prevention and Cure With the K Factor BOOK ONLINE
purkilar
PDF FREE DOWNLOAD High Blood Pressure for Dummies FOR IPAD
dadolitemi
Pressure Cleaning: The Ultimate Pressure Washer Guide
marcking
PDF FREE DOWNLOAD Eat to Beat High Blood Pressure TRIAL EBOOK
purkilar
PDF DOWNLOAD Natural Cures for High Blood Pressure TRIAL EBOOK
lurkeyir
PDF [DOWNLOAD] Controlling High Blood Pressure the Natural Way: Don t Let the "Silent Killer" Win David Carroll [DOWNLOAD] ONLINE
alexandresese
PDF Case Studies in Hypnotherapy READ ONLINE
ya.barnabas
READ DAC Study Guide For Advanced Placement European History GET PDF
bevperry
BEST PDF Mayo Clinic on High Blood Pressure: Taking charge of your hypertension TRIAL EBOOK
dadolitemi
BEST PDF Study Skills for Learning Disabled and Struggling Students: Grades 6-12 (4th Edition) TRIAL EBOOK
albericinnya
PDF FREE DOWNLOAD Mayo Clinic on High Blood Pressure (Mayo Clinic on Health) FOR IPAD
yizaxehoda
BEST PDF Study Problems to Federal Income Taxation of Corporations (University Casebook Series)( 3rd. edition) TRIAL EBOOK
momchil986
GET PDF High Blood Pressure: Safe alternatives without drugs (Thorsons Natural Health) FULL ONLINE
elx4rtg
PDF [FREE] DOWNLOAD The Magnesium Solution for High Blood Pressure (The Square One Health Guides) Jay S. Cohen TRIAL EBOOK
kaydenthomson6578
PDF DOWNLOAD Diet for a Strong Heart: Dietary Guidelines for the Prevention of High Blood Pressure, Heart.... BOOK ONLINE
yulitaged
PDF [FREE] DOWNLOAD High Blood Pressure: Safe alternatives without drugs (Thorsons Natural Health) Leon Chaitow READ ONLINE
kambiloase
PDF FREE DOWNLOAD Reversing Hypertension: A Vital New Program to Prevent, Treat, and Reduce High Blood Pressure BOOK ONLINE
xocasad
DOWNLOAD NOW Study Simpler: Study Skills Development BOOK ONLINE
chase.aydan
BEST PDF 25 Natural Ways To Lower Blood Pressure BOOK ONLINE
yulitaged
PDF DOWNLOAD High Blood Pressure Lowered Naturally: Your Arteries Can Clean Themselves READ ONLINE
dizexu
DOWNLOAD NOW Study Course In Homoeopathy BOOK ONLINE
jed2018
EBOOK ONLINE Study Guide To Accompany Breastfeeding And Human Lactation (Coates, Study Guide for Breastfeeding and Human Lactation) BOOK ONLINE
yosef878999
PDF DOWNLOAD Lower Cholesterol: Use nuts and seeds to naturally lower your BMI, blood pressure and cholesterol TRIAL EBOOK
joakimimes
BEST PDF Diet for a Strong Heart: Michio Kushi s Macrobiotic Dietary Guidelines for the Prevention of High Blood Pressure, Heart Attack, and Stroke BOOK ONLINE
yulitaged