MAINTENANCE NOV 2011.pdf

Table of Contents 

5 IN 1 ................................................................................................................................... 6 

707 SEALER FINISH ......................................................................................................... 9 

ACETYLENE .................................................................................................................... 11 

AGGREGATE PRODUCTS (aka LAFARGE AGGREGATE 

PRODUCTS) 

ALKYD & OIL PAINTS- INCL. ALKYD PAINTS, STAINS, 

VARNISHES 

........................... 20 

........................... 27 

ALL-STATE JET FLUX (VARIOUS NUMBERS) ........................................................ 30 

ALUMINUM WELDING WIRE AND METALLIZING WIRE ................................... 35 

ARGON ............................................................................................................................ 44 

ARMSTRONG CEILING TILE ...................................................................................... 52 

BOLBAC ........................................................................................................................... 54 

BROFLOAT ..................................................................................................................... 56 

CARBON DIOXIDE/INERT GAS MIXTURE .............................................................. 57 

CARBON STEEL ELECTRODE PROSTAR/ELECTRODE 

WELDING 

........................... 66 

CARBON STEEL ELECTRODE SIDERGAS S6 ............................................................ 70 

CASTROL MULTI PURPOSE CHASSIS GREASE ...................................................... 72 

CASTROL SYNTEC BLEND 5W-20 .............................................................................. 78 

CASTROL SYNTEC BLEND 5W-30 .............................................................................. 83

CASTROL SYNTEC BLEND 10W-30 ............................................................................ 88 

CASTROL SYNTEC BLEND 10W-40 ............................................................................ 94 

CASTROL SYNTEC BLEND 20W-50 .......................................................................... 100 

CASTROL SYNTEC BLEND TRUCK 15W-40 ........................................................... 106 

CGC PLASTERS-BASECOAT AND GAUGING ....................................................... 112 

CHEVRON SRI GREASE .............................................................................................. 120 

COMET DISINFECTANT CLEANSER W CHLORINAL 

(PROFESSIONAL LINE) 

......................... 129 

COMPUCESSORIES POWER DUSTER (AKA DYMEL) .......................................... 134 

CRETE ............................................................................................................................ 139 

DEEP LUBE .................................................................................................................... 141 

DYMEL (AKA COMPUCESSORIES POWER DUSTER) .......................................... 144 

ESAB MILD STEEL COVERED ELECTRODES ......................................................... 149 

GRINDING & CUTTING WHEELS, RESINOID, CUP WHEELS, 

MOUNTED POINTS (RESINOID BINDED ABRASIVES) 

......................... 155 

HELIUM ......................................................................................................................... 160 

INDUSTRIAL ASPHALT BUR TYPE I, II, III, IV ...................................................... 167 

KOOL KUT 24 B ........................................................................................................... 173 

KRYLON INDUSTRIAL TOUGH COAT SANDABLE 

PRIMER-RED OXIDE 

LAFARGE AGGREGATE PRODUCTS (AKA AGGREGATE 

PRODUCTS) 

......................... 180 

......................... 185 

LAFARGE COLD PATCH ASPHALT ........................................................................ 192

LAFARGE HOT MIX ASPHALT (HMA) .................................................................. 198 

LAFARGE QPR - ASPHALT REPAIR ........................................................................ 204 

LAFARGE READY MIX CONCRETE (CONCRETE) ............................................... 209 

LAFARGE SAND AND GRAVEL ............................................................................... 215 

LATEX PAINTS (ALL)- INCL. LOW VOC LATEX SEMI GLOSS, 

ULTRA 9600 LATEX INTERIOR SEMI GLOSS, ENAMEL LOW 

ODOUR LOW VOC 

......................... 221 

LEPAGE PRES-TITE CONTACT CEMENT .............................................................. 224 

LUBRIPLATE NON-DETERGENT MOTOR OIL 30 ................................................ 227 

MAGNALAC PRECATALYZED LACQUER - BLACK SATIN .............................. 232 

MAGNALAC PRECATALYZED LACQUER - SATIN 35 ........................................ 238 

MAN-MADE VITREOUS CEILINGS AND WALL PANELS 

(CLASS A) 

......................... 244 

METAL ALLOY (AKA WELCO 15/WELCO 15FC) ................................................... 246 

MICROFLO .................................................................................................................... 255 

NATUREWOOD TREATED WOOD (AKA OSMOSE PRESSURE 

TREATED WOOD) 

......................... 258 

OXYGEN ........................................................................................................................ 263 

POLY FILLER RT .......................................................................................................... 271 

POLY PLASTER OF PARIS .......................................................................................... 273 

PORTLAND CEMENT ................................................................................................. 275 

POWERFLO ................................................................................................................... 282 

PRES-TITE CONTACT CEMENT ............................................................................... 284

PROPANE ...................................................................................................................... 287 

QPR - ASPHALT REPAIR ............................................................................................ 295 

RAIN-X DE-ICER WINDSHIELD WASHER FLUID ................................................. 300 

SAND AND GRAVEL ................................................................................................... 307 

SOLIDAIRE CITRUS ..................................................................................................... 313 

SOLIDAIRE GOLD ........................................................................................................ 318 

SOLIDAIRE RED ........................................................................................................... 323 

SOLIDAIRE SILVER ...................................................................................................... 328 

SOLIDAIRE SPEARMINT ............................................................................................ 333 

SOLDER ALLOYS CONTAINING LEAD ................................................................... 338 

STATICIDE INDUSTRIAL WIPES .............................................................................. 340 

SUPER GLAZE ALUMINUM ELECTRODES AND RODS 

(VARIOUS NUMBERS) 

......................... 345 

SYNKOOL 1200 ............................................................................................................. 347 

SYNTHETIC RESINOID TECHNOLOGY .................................................................. 349 

TALON RODENTICIDE PELLETS ............................................................................. 353 

TITEBOND II PREMIUM WOOD GLUE ................................................................... 359 

TREMCLAD FAST DRY PAINT- AEROSOL ............................................................ 366 

TREMCLAD FAST DRY PAINT- BRUSH ................................................................ 368 

TUBULAR ARC WELDING ELECTRODES FOR FLUX CORED, 

METAL CORED & SUBMERGED ARC WELDING 

......................... 370 

ULTRA LIFT-OFF ......................................................................................................... 373

UNIVERSAL STONE ..................................................................................................... 374 

UNLEADED GASOLINE .............................................................................................. 377 

VALVE ACTION PAINT MARKER (VARIOUS COLOURS) .................................. 390 

VALVOLINE SAE 30 NON-DETERGENT MOTOR OIL (3047) .............................. 397 

VARSOL DX 3139 SOLVENT ...................................................................................... 406 

WD-40 AEROSAL .......................................................................................................... 417 

WD-40 BULK LIQUID .................................................................................................. 421 

WD-40 SMART STRAW AEROSOL ........................................................................... 425 

WELCO 15/WELCO 15FC (AKA METAL ALLOY) ................................................... 429 

WELDING CONSUMABLES (VARIOUS-DURANICKEL, 

INCOLOY, INCONEL, INCO-CORED, MONEL, NICKEL, NILO, 

NIMONIC, NI-ROD, INCOFLUX, INCO-WELD) 

......................... 438 

WELDING ELECTRODES ............................................................................................ 456 

WELDING ELECTRODES - CARBON STEEL PROSTAR ........................................ 459 

WELDING ELECTRODES - CARBON STEEL SIDERGAS S6 .................................. 463 

WELDING ELECTRODES - MILD STEEL COVERED .............................................. 465 

WELDING ELECTRODES/RODS - ALUMINUM .................................................... 471 

WELDING RODS - W1060 (R45)-W1200 (R60) .......................................................... 473 

WELDING WIRE - ALUMINUM WELDING & METALLIZING 

WIRE 

......................... 481 

WINTERGREEN ARTIFICIAL FLAVOURING ......................................................... 490

00007443 MATERIAL SAFETY DATA SHEET Page 1 

BRODI SPECIALTY PRODUCTS LTD 

250 COCHRANE DRIVE, UNIT 9 

MARKHAM; ONTARIO; L3R 8E5 

CANADA 

PRODUCT: 5 in 1 

Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

MANUFACTURER ................................................. Brodi Specialty Products Ltd. 

250 Cochrane Drive, Unit 9 

Markham, 

Ontario 

Canada 

L3R 8E5 

905-475-6084 

PRODUCT NAME................................................... 5 in 1 

CHEMICAL FAMILY................................................ HYDROCARBONS. 

MOLECULAR WEIGHT........................................... NOT APPLICABLE. 

CHEMICAL FORMULA........................................... NOT APPLICABLE. 

TRADE NAMES & SYNONYMS.............................. 5 in 1 

PRODUCT USES.................................................... MOISTURE BARRIER. 

LAB BOOK NUMBER.............................................. F 01-093. 

Sec tio n 02: COMPOSITION/INFORMATION INGREDIENTS 

Hazardous Ingredients % Exposure Limit C.A.S.# LD/50, Route,Species LC/50 Route,Species 

HYDROTREATED MIDDLE 

DISTILLATE 

60-90 N/A 64742-46-7 NOT AVAILABLE NOT AVAILABLE 

MINERAL OIL 10-30 N/A 8042-47-5 NOT AVAILABLE NOT AVAILABLE 

DIPROPYLENE GLYCOL METHYL 

ETHER 

1-5 100 ppm 34590-94-8 5135 mg/kg ORAL - RAT NOT AVAILABLE 

PROPRIETARY COMPONENTS 1-5 

ACETONE 1-5 750 ppm 67-64-1 >9750 mg/kg ORAL - RAT >16,000 ppm (4 hr) INHAL - 

RAT 

CARBON DIOXIDE 1 - 5 5000 ppm 124-38-9 NOT APPLICABLE NOT AVAILABLE 

Sec tion 03: HAZARDS IDENTIFICATION 

ROUTE OF ENTRY: 

INGESTION............................................................. MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESS. 

INHALATION........................................................... INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLANT IS A SIMPLE 

ASPHYXIANT. 

EYE CONTACT....................................................... VAPORS MAY IRRITATE. 

SKIN ABSORPTION................................................ NO DATA AVAILABLE FOR THIS PRODUCT MIXTURE. 

SKIN CONTACT...................................................... MAY CAUSE IRRITATION. 

EFFECTS OF ACUTE EXPOSURE........................ DIZZINESS, NAUSEA. IRRITATION TO SKIN & EYES. 

EFFECTS OF CHRONIC EXPOSURE................... SOLVENTS MAY CAUSE DEFATTING DERMATITIS . 

EXPOSURE LIMIT OF MATERIAL......................... SEE SECTION 2. 

Section 04: FIRST AID MEASURES 

EMERGENCY FIRST AID PROCEDURE .............. IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 

MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND 

WATER. IF AFFECTED BY INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. 

IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION. 

Sec tio n 05: FIRE FIGHTING MEASURES 

AUTO IGNITION TEMPERATURE (°C).................. 465. 

SPECIAL PROCEDURES....................................... WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO 

PREVENT BUILD-UP IF EXPOSED TO EXTREME TEMPERATURES. FULL PROTECTIVE 

EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARTATUS SHOULD BE WORN IN A 

FIRE INVOLVING THIS MATERIAL. 

FLAMMABILITY....................................................... NOT A FLAMMABLE PRODUCT (AS PER CANADIAN AEROSOL REGULATIONS). 

IF YES, UNDER WHICH CONDITIONS ................ EXCESSIVE HEAT, SPARKS AND OPEN FLAME. 

EXTINGUISHING MEDIA........................................ WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM. 

UPPER FLAMMABLE LIMIT................................... 12.8. 

(% BY VOLUME) 

LOWER FLAMMABLE LIMIT.................................. 2.6. 

(% BY VOLUME) 

EXPLOSION DATA 

SENSITIVITY TO STATIC DISCHARGE........... NOT APPLICABLE. 

SENSITIVITY TO IMPACT................................. NOT APPLICABLE. 

HAZARDOUS COMBUSTION



Sec tio n 05: FIRE FIGHTING MEASURES 

PRODUCTS............................................................ HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS 

INCOMPLETE. 

AEROSOL FLAME PROJECTION 

CLASSIFIED AS:..................................................... 0 cm. 

FLASHBACK........................................................... NONE. 

FLASH POINT(°C),TAG CLOSED-CUP ................. LOWEST KNOWN VALUE IS ACETONE @ -18C. 

(CONCENTRATE) 

Section 06: ACCIDENTAL RELEASE MEASURES 

LEAK/SPILL............................................................. REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL, AND 

NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE. 

Sec tio n 07: HANDLING AND STORAGE 

STORAGE NEEDS.................................................. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMES. 

ENGINEERING CONTROLS.................................. VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS). 

HANDLING PROCEDURES AND EQUIPMENT..... STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C. 

SYNERGISTIC MATERIALS................................... NONE KNOWN. 

Section 08: EXPOSURE CONTROLS/PERSONAL PROTECTION 

GLOVES/ TYPE...................................................... NOT NORMALLY REQUIRED. 

RESPIRATORY/TYPE............................................ IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE RESPIRATOR 

(NIOSH/MSHATC 23C OR EQUIVALENT) IS RECOMMENDED. 

EYE/TYPE............................................................... SAFETY GLASSES. 

FOOTWEAR/TYPE................................................. NOT NORMALLY REQUIRED. 

OTHER/TYPE.......................................................... NOT REQUIRED. 

Section 09: PHYSICAL AND CHEMICAL PROPERTIES 

PHYSICAL STATE.................................................. LIQUID. 

APPEARANCE........................................................ CLEAR AMBER LIQUID. 

ODOR...................................................................... HYDROCARBON. 

ODOR THRESHOLD............................................... NOT AVAILABLE. 

VAPOUR PRESSURE(PSIG)-AEROSOL............... 90-110. 

@ 20 C 

BOILING POINT (°C)(CONC).................................. >260 deg C. 

EVAPORATION RATE............................................ LESS THAN 1. 

n-BUTYL ACETATE = 1 

VAPOUR DENSITY (AIR=1)................................... GREATER THAN 1. 

(BY WEIGHT) 

SOLUBILITY IN WATER g/L (20°C)........................ NEGLIGIBLE. 

pH............................................................................ NOT APPLICABLE. 

SPECIFIC GRAVITY (LIQUID)................................ 0.80-0.86. 

COEFFICIENT OF WATER\OIL DIST..................... NOT AVAILABLE. 

FREEZING POINT: (°C).......................................... NOT AVAILABLE. 

AEROSOL PERCENT VOLATILE........................... NOT AVAILABLE. 

(BY WEIGHT). 

Section 10: STABILITY AND REACTIVITY 

HAZARDOUS PRODUCTS OF 

DECOMPOSITION.................................................. HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS 

INCOMPLETE. 

CHEMICAL STABILITY: 

YES......................................................................... UNDER NORMAL CONDITIONS. 

NO, WHICH CONDITIONS ................................... NOT APPLICABLE. 

COMPATIBILITY WITH OTHER SUBSTANCES: 

NO, WHICH ONES ................................................ STRONG OXIDIZING AGENTS. 

REACTIVITY CONDITIONS .................................. NOT APPLICABLE. 

Section 11: TOXICOLOGICAL INFORMATION 

REPRODUCTIVE EFFECTS................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE REPRODUCTIVE EFFECTS ARE 

ANTICIPATED. 

IRRITANCY OF MATERIAL.................................... SKIN/EYE IRRITANT. 

SENSITIZING CAPABILITY OF MATERIAL........... UNKNOWN. 

CARCINOGENICITY OF MATERIAL...................... THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS CARCINOGENS BY NTP, 

(NATIONAL TOXICOLOGY PROGRAM), NOT REGULATED AS CARCINOGENS BY OSHA, 

(OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED 

BY IARC,(INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BY ACGIH 

(AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS). 

TERATOGENICITY................................................. NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENIC EFFECTS ARE 

ANTICIPATED. 

MUTAGENICITY..................................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC EFFECTS ARE 

ANTICIPATED.



Section 12: ECOLOGICAL CONSIDERATIONS 

ENVIRONMENTAL.................................................. NOT AVAILABLE. 

Section 13: DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL................................................. DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. DISPOSE OF IN 

ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS. 

Section 14: TRANSPORTATION INFORMATION 

T.D.G. CLASSIFICATION....................................... CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.2). 

D.O.T. CLASSIFICATION....................................... CONSUMER COMMODITY, ORM-D. 

Sec tion 15: REGULATORY INFORMATION 

CANADIAN REGULATIONS: 

--------------------------------------- 

WHMIS CLASSIFICATION...................................... A,D2B. 

CNFC SECTION 3.3.5............................................. LEVEL 3. 

CEPA (Canadian Enviromental Protection Act) ALL SUBSTANCES IN THIS PRODUCT ARE LISTED ON THE CANADIAN DOMESTIC 

SUBSTANCES LIST (DSL) OR ARE NOT REQUIRED TO BE LISTED. 

U.S. REGULATIONS: 

------------------------------ 

HMIS RATING HEALTH.......................................... 1 SLIGHT HAZARD. 

HMIS RATING FLAMMABILITY.............................. 1 SLIGHT HAZARD. 

HMIS RATING REACTIVITY................................... 0 MINIMAL HAZARD. 

HMIS RATING PERSONAL PROTECTION............ B. 

NFPA CODE 30B.................................................... LEVEL 3. 

SARA 313 INFORMATION:..................................... THIS PRODUCT CONTAINS NO INGREDIENTS SUBJECT TO THE REPORTING REQUIREMENTS 

OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 

1986 AND OF 40 CFR 372. . 

CAS #: CHEMICAL NAME: . 

N/A. 

CALIFORNIA PROPOSITION 65:........................... THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE 

DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: . 

WARNING: THIS PRODUCT DOES NOT INTENTIONALLY CONTAIN ANY CHEMICALS KNOWN 

TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER 

REPRODUCTIVE HARM. 

. CAS #: CHEMICAL NAME: 

. N/A. 

TSCA (Toxic Substances Control Act).................... ALL COMPONENT OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. ANY 

IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING. 

VOC (w/w%)............................................................ 5. 

Section 16: OTHER INFORMATION 

NOTICE FROM BRODI SPECIALTY PRODUCTS THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET IS PROVIDED BY BRODI 

LTD. SPECIALTY PRODUCTS LTD. FREE OF CHARGE. WHILE BELIEVED TO BE RELIABLE, IT IS 

INTENDED FOR USE BY SKILLED PERSONS AT THEIR OWN RISK. BRODI SPECIALTY 

PRODUCTS LTD. ASSUMES NO RESPONSIBILITY FOR EVENTS RESULTING OR DAMAGES 

INCURRED FROM ITS USE. THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET 

RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE 

TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS. 

PREPARED BY....................................................... MSDS Co-ordinator, (877-744-0751) ext 205, Brodi Specialty Products Ltd. 

PREPARATION DATE ........................................... Jan01/09

707 Sealer Finish 

MATERIAL SAFETY DATA SHEET Page of 

SECTION 1 - COMPANY INFORMATION 

Product usage: Floor finish 

Product type: Water based acrylic copolymer emulsion 

WHMIS Class: Not Controlled 

Hazard Rating: Health: (1) Slight; Fire (0) Insignificant; Reactivity: (0) Insignificant 

TDG Class: Not Regulated. 

TDG Class: Not Controlled 

Supplier name and address: Manufacturer’s name and address 

Corporate Chemicals & Equipment Refer to Supplier 

7 Neilson Street 

St. Catharines, ON L2M 5V9 

(905) 682-8888 Emergency Telephone# CANUTEC (613) 996-6666 

SECTION 2 - HAZARDOUS INGREDIENTS 

INGREDIENT % CAS# TOXICITY 

Diethylene Glycol Ethyl Ether < 5 111-90-0 LD50 (oral-rat) 6500 mg/kg. LC50 1820 ppm 

Tributoxyethyl Phosphate < 5 78-51-3 LD50 (oral) 6730 mg/kg/ 

Ammonia < 0.2 7664-41-7 LD50 (oral rats) 340 mg/kg. LCLo (inhalationrat) 

2000 ppm/4h. TLV (NH3) 25 ppm 

SECTION 3 - HAZARDS IDENTIFICATION 

Physical state : Liquid. Product is sold ready to use. 

Emergency overview 

MAY CAUSE EYE IRRITATION. 

Avoid contact with eyes. Wash thoroughly after handling. 

Routes of entry : Skin contact, Eye contact, Inhalation, Ingestion 

Potential acute health effects 

Eyes : Slightly irritating to the eyes. Product is sold ready to use. 

Skin : Slightly irritating to the skin. 

Inhalation : No known significant effects or critical hazards. 

Ingestion : No known significant effects or critical hazard 

Effects of Acute Exposure to: 

First Aid Procedures... 

SECTION 4 - FIRST AID MEASURES 

Skin: May cause irritation of sensitive skin 

Eyes: May cause irritating, watering of eyes and inflammation of conjunctiva. 

Ingestion: G. I. tract upsets, nausea, vomiting. 

Inhalation: If misted, may cause irritation of mucous membranes, coughing. 

Skin: Remove contaminated clothing. Wash exposed areas with running water. 

Eyes: Flush with water running water for 30 minutes lifting the upper and lower eyelids 

occasionally. Remove contact lenses. Get medical attention. 

Ingestion: Do not induce vomiting. If victim is alert and not convulsing, give 1-2 glasses of water to 

dilute material. Immediately contact local poison control centre. Vomiting should be 

induced under the direction of a physician or a poison control centre. If spontaneous


vomiting occurs, have victim lean forward with head down to avoid breathing in of 

vomitus, rinse mouth and administer more water. Immediately transport victim to an 

emergency facility. 

Inhalation: Move victim to fresh air. Give artificial respiration only if breathing has stopped. Give 

cardiopulmonary resuscitation (cpr) if there is no is no breathing and no pulse. 

Obtain medical attention immediately. 

SECTION 5 - FIRE FIGHTING MEASURES 

Flash point: Over 120 Deg. C. after drying 

Flammability: Non-Flammable 

Combustion products: After drying, oxides of carbon, nitrogen and incomplete combustion products 

To Extinguish: Water fog, carbon dioxide, dry chemical 

Other: None 

SECTION 6 - ACCIDENTAL RELEASE MEASURES 

Personal precautions : Use personal protective equipment as required. Product is sold ready to use. 

Environmental precautions : Avoid contact of large amounts of spilt material and 

runoff with soil and surface waterways. 

Methods for cleaning up : Use a water rinse for final clean-up. 

SECTION 7 - HANDLING AND STORAGE 

As with all chemicals there are known and unknown effects on humans. Minimize 

exposure of all chemicals, including this product, to skin, respiratory system, and eyes. 

Keep out of reach of children. Avoid contamination of food. 

Wash thoroughly after handling. Store in cool dry area. Do not freeze. 

SECTION 8 - EXPOSURE CONTROLS & PROTECTIVE EQUIPMENT 

Ventilation: Normal building ventilation is adequate. 

Breathing Protection: Not usually necessary 

Skin Protection: Not usually necessary 

Eye Protection: Not usually necessary 

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 

Appearance: White milk-like emulsion Density (g/ml): 1.01 

pH as is: 8.0 - 9.0 Freezing point: 0 Deg. C. 

pH use dilution: 8.0 - 9.0 Boiling Point: 100 Deg. C. 

Solubility in water: Dispersible in all proportions Evaporation Rate: Same as water. 

Odour: Slight ammonia Viscosity: As water. 

SECTION 10 - REACTIVITY & STABILITY DATA 

Product is stable. Do not mix with strong acids, alkalis; oxidizing and reducing agents. 

Do not mix with chlorine bleach. Hazardous polymerization will not occur. 

SECTION 11 - TOXICOLOGICAL INFORMATION 

Potential acute health effects 

Product AS SOLD Product AT USE DILUTION 

Eyes : Slightly irritating to the eyes. Product is sold ready to use. 

Skin : Slightly irritating to the skin. 

Inhalation : No known significant effects or critical hazards. 

Ingestion : No known significant effects or critical hazards


Potential chronic health effects 

Carcinogenic effects : No known significant effects or critical hazards. 

Mutagenic effects : No known significant effects or critical hazards. 

Teratogenic effects : No known significant effects or critical hazards. 

Reproductive effects : No known significant effects or critical hazards. 

Sensitization to Product : No known significant effects or critical hazards. 

Synergistic products 

(toxicologically) 

: Not available. 

Toxicity data 

Product/ingredient name Test Route Result Species 

ethanol, 2-(2-ethoxyethoxy)- LD50 Dermal >32 g/kg Guinea pig 

LD50 Oral 7500 mg/kg Rat 

LD50 Oral 7250 mg/kg Mouse 

LC50 Inhalation >5240 mg/m3 Rat 

Other adverse effects 

Target organs : Not available 

Ecotoxicity : Not reported 

SECTION 12 - ECOLOGICAL INFORMATION 

SECTION 13 - WASTE DISPOSAL 

Disposal method: Sanitary sewer or dry absorbent material. 

For large quantities, check with local environmental department, and government authorities. 

SECTION 14 - TRANSPORTATION INFORMATION 

Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification 

provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. 

Product AS SOLD 

TDG Classification Not regulated. 

For transport in bulk or using IMDG regulations, see shipping documents for specific transportation information 

SECTION 15 - REGULATORY INFORMATION 

MSDS Prepared by: Technical Dept. Telephone: (905) 682-8888 

SECTION 16 - OTHER INFORMATION 

References: Suppliers Material Safety Data Sheets. Preparation Date: July 1/2011 

NOTICE: The data and information presented herein are based upon tests, research and reports which are considered by us to be reliable and believed 

to be accurate. The data and information are presented without warranty, guarantee or liability on our part, and are presented to the customer for his 

own consideration, investigation and verification. If user requires independent information on ingredients in this or any other material, we recommend 

contact with Canadian Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (905 572-4400)

Product Name: MSDS No.: Date: Oct 15, 2010 

Product Name: 

Product Use: 

Chemical Name: 

Praxair Material Safety Data Sheet 

1. Chemical Product and Company Identification 

Trade Name: 

Synonym: 

Chemical Formula: Chemical Family: 

Telephone: 

Emergencies: 

Supplier 

/Manufacture: 

Phone: 

Fax: 

*Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents involving this 

product. For routine information, contact your supplier or Praxair sales representative. 

DANGER! 

ROUTES OF EXPOSURE: 

THRESHOLD LIMIT VALUE: 

INHALATION: 

2. Hazards Identification 

Emergency Overview 

Flammable gas under pressure. Can form explosive mixtures with air. Fusible plugs in top, 

bottom, or valve melt at 98 - 104 C. Do not discharge at pressures above 103 kPa. May cause 

dizziness and drowsiness. Self-contained breathing apparatus may be required by rescue 

workers. At normal temperature and pressure, commercial acetylene is a colourless gas with 

a distinctive garlic-like odour. 

EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: 

SKIN CONTACT: 

SKIN ABSORPTION: 

SWALLOWING: 

EYE CONTACT: 

Copyright © 2005, Praxair Canada Inc. Page 1 of 9

EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: 

*NOTES TO PHYSICIAN: 

Acute: 

Chronic: 

OTHER EFFECTS OF OVEREXPOSURE: 

MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: 

Oct 15, 2010 

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: 

CARCINOGENICITY: 

3. Composition and Information on Ingredients 

COMPONENTS CAS 

NUMBER 

INHALATION: 

SKIN CONTACT: 

SWALLOWING: 

EYE CONTACT: 

NOTES TO PHYSICIAN: 

4. First Aid Measures 

CONCENTRATION 

% by Mole 


Oct 15, 2010 

Aspired acetone may cause severe lung damage. If a large quantity of material has been swallowed, stomach contents 

should be evacuated quickly in a manner which avoids aspiration. Otherwise, treatment should be directed at the control 

of symptoms and the clinical condition. No specific antidote is known. 

EXTINGUISHING MEDIA: 

PRODUCTS OF COMBUSTION: 

PROTECTION OF FIREFIGHTERS: 

DANGER! 

SPECIFIC PHYSICAL AND CHEMICAL HAZARDS: 

5. Fire Fighting Measures 

FLAMMABLE : IF YES, UNDER WHAT CONDITIONS? 

SENSITIVITY TO IMPACT: 

SENSITIVITY TO STATIC DISCHARGE: 

PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS: 

FLAMMABLE LIMITS IN AIR, % by volume: 

FLASH POINT: 

AUTOIGNITION TEMPERATURE: 

LOWER: UPPER: 

6. Accidental Release Measures 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: 

Personal Precautions: 


DANGER! Flammable, high-pressure gas. 

Environmental Precautions: 

PRECAUTIONS TO BE TAKEN IN HANDLING: 

PRECAUTIONS TO BE TAKEN IN STORAGE: 

7. Handling and Storage 

OTHER HAZARDOUS CONDITIONS OF HANDLING, STORAGE, AND USE: 

Flammable high-pressure gas. 

Oct 15, 2010 

May form explosive mixtures with air. Gas can cause rapid 

suffocation due to oxygen deficiency. 

Prevent reverse flow. Reverse flow into cylinder may cause rupture. Use a check valve or 

other protective device in any line or piping from the cylinder. When returning cylinder to supplier, be sure valve is 

closed, then install valve outlet plug tightly. Never work on a pressurized system. If there is a leak, close the cylinder 

valve. Vent the system down in a safe and environmentally sound manner in compliance with all federal, provincial, and 

local laws; then repair the leak. Never place a compressed gas cylinder where it may become part of an electrical 

circuit. 

RECOMMENDED PUBLICATIONS: 

NFPA 55: Standard for the Storage, 

Use, and Handling of Compressed and Liquefied Gases in Portable Cylinders 

Guidelines for Handling Gas Cylinders and Containers 


VENTILATION/ENGINEERING CONTROLS: 

PERSONAL PROTECTION: 

LOCAL EXHAUST: 

MECHANICAL (General): 

8. Exposure Controls/Personal Protection 

INGREDIENTS CAS NUMBER LD50 LC50 


SPECIAL: 

OTHER: 

RESPIRATORY PROTECTION: 

SKIN PROTECTION: 

EYE PROTECTION: 

OTHER PROTECTIVE EQUIPMENT: 

(Species & 

Routes) 

IMMEDIATELY DANGEROUS TO LIFE AND HEALTH (IDLH): 

(Rat, 4 

hrs.) 

Exposure Limits 

Oct 15, 2010 


PHYSICAL STATE: 

BOILING POINT 

SPECIFIC 

GRAVITY: 

SPECIFIC 

GRAVITY: 

APPEARANCE & ODOUR: 

9. Physical and Chemical Properties 

FREEZING POINT: 

VAPOUR 

PRESSURE 

SOLUBILITY IN 

WATER, 

EVAPORATION 

RATE 

VAPOUR DENSITY: % VOLATILES BY 

VOLUME: 

STABILITY: 

CONDITIONS OF CHEMICAL INSTABILITY: 

INCOMPATIBILITY (materials to avoid): 

HAZARDOUS DECOMPOSITION PRODUCTS: 

HAZARDOUS POLYMERIZATION: 

CONDITIONS TO AVOID: 

CONDITIONS OF REACTIVITY: 

ACUTE DOSE EFFECTS: 

STUDY RESULTS: 

10. Stability and Reactivity 

11. Toxicological Information 

12. Ecological Information 

pH: 

MOLECULAR WEIGHT: 

COEFFICIENT OF 

WATER/OIL 

DISTRIBUTION: 

ODOUR THRESHOLD: 

Oct 15, 2010 


WASTE DISPOSAL METHOD: 

TDG/IMO SHIPPING NAME: 

13. Disposal Considerations 

14. Transport Information 

HAZARD CLASS: IDENTIFICATION #: 

SHIPPING LABEL(s): 

PLACARD (When Required): 

SPECIAL SHIPPING INFORMATION: 

WHMIS (Canada): 

International Regulations: 

EINECS: 

DSCL (EEC): 

International Lists: 

15. Regulatory Information 

PRODUCT RQ: 

Oct 15, 2010 

The following selected regulatory requirements may apply to this product. Not all such requirements are identified. Users of this 

product are solely responsible for compliance with all applicable federal, provincial, and local regulations. This product has been 

classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. 

MIXTURES: 

HAZARD RATING SYSTEM: 

HMIS RATINGS: 

2 

4 

2 

16. Other Information 


STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: 

THREADED: 

PIN-INDEXED YOKE: 

ULTRA-HIGH-INTEGRITY 

CONNECTION: 

PREPARATION INFORMATION: 

DATE: 

DEPARTMENT: 

TELEPHONE: 

DO NOT USE ADAPTERS. 

Oct 15, 2010 

Safety and Environmental Services 

905-803-1600 

Praxair Flowing Airstream 

Oct 15, 2010 


Copyright © 2005, Praxair Canada Inc. 

Oct 15, 2010 

Page 9 of 9

No Change April 18, 2011

No Change as of May 2011

SAFETY DATA SHEET 

-1- 

SDS NO. 7-E 

DATE REVISED: 07/14/2010 

This Safety Data Sheet complies with European Commission Directive 91/155/EEC, ISO 11014-1 and ANSI Z400.1 

1. PRODUCT AND COMPANY IDENTIFICATION 

Product Name: ALL-STATE JET FLUX P/N: 69080170, 69080171, 69080172 

Application: Brazing Flux 

Classification: None 

Supplier: THE ESAB GROUP, INC., 801 Wilson Avenue, Hanover, PA 17331 

Telephone No.: 1-717-637-8911, 1-800-933-7070 

Emergency No.: 1-717-637-8911 and 1-800-424-9300 (CHEMTREC) 

Web site: www.esabna.com 

2. HAZARDS IDENTIFICATION 

Emergency Overview: A clear, colorless flammable liquid with an organic odor. Can irritate the skin and eyes. Toxic if swallowed; 

may also cause blindness. Vapors are harmful if inhaled. 

Can irritate the skin and eyes Toxic if swallowed and may cause blindness due to the methyl alcohol content. Vapor can cause 

respiratory irritation and may cause headaches, nausea, and depression of the central nervous system resulting in drowsiness or 

the loss of consciousness. 

Persons with a pacemaker should not go near brazing operations until they have consulted their doctor and obtained information 

from the manufacturer of the device. 

When this product is used in a brazing process, the most important hazards are heat, radiation, electric shock and brazing fumes. 

Heat: Spatter and melting metal can cause burn injuries and start fires. 

Radiation: Arc rays can severely damage eyes or skin. 

Electricity: Electric shock can kill. 

Fumes: Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. Chronic overexposure to brazing fumes may affect pulmonary function. 

Prolonged inhalation of nickel and chromium compounds above safe exposure limits can cause cancer. 

Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible 

damage to the central nervous system, including the brain, symptoms of which may include slurred speech, 

lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. 

Flame 

Processing: 

When used with combustible gas equipment (e.g., oxy-acetylene torch), read the use and safety information for 

that equipment. 

3. COMPOSITION/INFORMATION ON INGREDIENTS 

This product is a liquid. 

Ingredients Weight % CAS# EINECS# Hazard 

classification (1) 

IARC (2) NTP (3) OSHA 

List (4) 

Acetone 25 67-64-1 200-662-2 F; R11, Xi; R36 

R66, R67 

-- -- -- 

Methyl Alcohol 20 67-56-1 200-659-6 F; R11 

T; R23/24/25- 

39/23/24/25 

-- -- -- 

Trimethylborate 55 121-43-7 204-468-9 R10, Xn; R21 -- -- -- 

(1) 

Hazard Classification according to European Council Directive 67/548/EEC, for R-phrases, see Section 16. 

(2) 

Evaluation according to the International Agency for Research on Cancer. 

1 – Human Carcinogen 2B – Possibly carcinogenic to humans 

(3) 

Classification according to the 11th Report on Carcinogens, published by the US National Toxicology Program. 

K – Known Carcinogen S – Suspect Carcinogen 

(4) 

Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA).

Product Identity: ALL-STATE JET FLUX P/N: 69080170, 69080171, 69080172 

-2- 

SDS NO. 7-E 


4. FIRST AID MEASURES 

Inhalation: If breathing has stopped, perform artificial respiration and obtain medical assistance immediately! If breathing is 

difficult, provide fresh air and call physician. 

Eye contact: To liquid or mist, flush with water for at least fifteen minutes. For radiation burns due to arc flash, see physician. To 

remove dusts or fumes flush with water for at least fifteen minutes. If irritation persists, obtain medical assistance. 

Skin contact: Immediately remove liquid from skin and wash with mild soap and water. Launder contaminated clothing before 

reusing. For skin burns from arc radiation, promptly flush with cold water. Get medical attention for burns or irritations 

that persist. To remove dust or particles wash with mild soap and water. 

Electric shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with live parts or 

wires. If not breathing, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin Cardio 

Pulmonary Resuscitation (CPR). Immediately call a physician. 

Ingestion: Call a physician or poison control center immediately. Do not induce vomiting unless directed to do so by a physician. 

General: Move to fresh air and call for medical aid. 

5. FIRE FIGHTING MEASURES 

Use CO2, dry chemical, water spray or alcohol foam. Water stream may spread the burning liquid. Vapors may travel to a source of 

ignition and flash back. Firefighters should wear full protective equipment and self-contained breathing apparatus. Keep product 

containers exposed to heat or fire cool with water stream to prevent rupture from internal pressure. 

6. ACCIDENTAL RELEASE MEASURES 

Extinguish all sources of ignition within 35 feet (11m) of spill or vapor release. Provide adequate ventilation. If spill is of significant or 

unknown quantity, use self-contained breathing apparatus during clean up. Always wear proper protective clothing to prevent skin or 

eye contact. Released product which has evaporated forms smooth, slippery surface on floors, posing an accident risk. Absorb small 

spills with sand or fuller’s earth, and place in appropriate waste container. Large spills should be diluted and pumped into approved 

containers for disposal in accordance with all local, state, and federal laws and regulations. 

Personal precautions: refer to Section 8. 

Environmental precautions: refer to Section 13. 

7. HANDLING AND STORAGE 

Handling: 

Avoid contact with skin, eyes and clothing. Do not swallow or breathe vapors produced by use of product. Wash hands after using. 

Some individuals can develop an allergic reaction to certain materials. Retain all warning and identity labels. 

Storage: 

Store in cool, dry, well-ventilated place suitable for flammable liquids. Keep away from strong oxidizers and from sources of ignition 

including sparks, static electricity or open flames. 

8. EXPOSURE CONTROL/PERSONAL PROTECTION 

Avoid exposure to brazing fumes, radiation, spatter, electric shock, heated materials and dust. 

Engineering measures: (Brazing operations) 

Ensure sufficient ventilation, local exhaust, or both, to keep brazing fumes and gases from breathing zone and general area. Keep 

working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate conductive 

parts. Check condition of protective clothing and equipment on a regular basis. 

Personal protective equipment: (Brazing operations) 

Use respirator or air supplied respirator when brazing in a confined space, or where local exhaust or ventilation is not sufficient to keep 

exposure values within safe limits. Use special care when brazing painted or coated steels since hazardous substances from the 

coating may be emitted. Wear hand, head, eyes, ear and body protection like welders gloves, helmet or face shield with filter lens, 

safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry. 

Use industrial hygiene monitoring equipment to ensure that exposure does not exceed applicable national exposure limits. The 

following limits can be used as guidance. When used with brazing products, refer to the brazing product SDS, Section 10, for 

information on brazing fumes.


-3- 

SDS NO. 7-E 


Substance CAS# ACGIH TLV (1) mg/m 3 OSHA PEL (2) mg/m 3 

Acetone 67-64-1 1188, 1782 (STEL) 

[500 ppm , 750 ppm (STEL)] 

Methyl Alcohol 67-56-1 262, 382 (STEL) 

[200 ppm, 250 ppm (STEL)] 

2400 

[1000 ppm] 

260 

[200 ppm] 

Trimethylborate 121-43-7 None None 

(1) 

Threshold Limit Values according to American Conference of Governmental Hygienists, 2010 

(2) 

Permissible Exposure Limits according to the Occupational Safety & Health Administration (USA) 

Unless noted, all values are for 8 hour time weighted averages (TWA). 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Appearance: Colorless liquid with organic odor. 

Specific Gravity: 0.855 (H2O = 1) 

Boiling Point: 58°C/137°F 

Freezing Point: -26°C/-32°F 

Vapor Pressure: 161 mm Hg 

Vapor Density: 1.6 

Evaporation Rate: 16 (vs. butyl acetate = 1) 

Solubility in Water: Decomposes at 10%. 

Flash Point: -7.7°C/18°F 

Upper/Lower Flame Limit: 36.5%/6.0% 

Auto-ignition Temperature: Not determined. 

10. STABILITY AND REACTIVITY 

General: This product is intended for normal brazing purposes. 

Stability: This product is stable under normal conditions. 

Reactivity: Contact with strong oxidizers may cause a violent reaction. 

When this product is used in a brazing process, hazardous decomposition products would include those from the volatilization, 

reaction or oxidation of the brazing consumable and of the materials from the base metal and coating. 

Refer to applicable national exposure limits for fume compounds, including those exposure limits for compounds found in Section 8 of 

this SDS and of the brazing consumable SDS. A significant amount of the chromium in the fumes can be hexavalent chromium, which 

has a very low exposure limit in some countries. Manganese and nickel also have low exposure limits that may be easily exceeded. 

Reasonably expected gaseous products would include carbon oxides, nitrogen oxides, boron oxides and ozone. Air contaminants 

around the brazing area can be affected by the brazing process and influence the composition and quantity of fumes and gases 

produced. 

11. TOXICOLOGICAL INFORMATION 

Inhalation of brazing fumes and gases can be dangerous to your health. Classification of brazing fumes is difficult because of varying 

base materials, coatings, air contamination and processes. The International Agency for Research on Cancer has classified welding 

fumes as possibly carcinogenic to humans (Group 2B). 

Acute toxicity: Acetone: LD50, oral, rat: 9,750 mg/kg; dermal, rabbit: 20,000 mg/kg; LC50 Rat : 50,100 mg/m 3 (8hr) 

Methanol: LD50, oral, rat: 5,628 mg/kg dermal, rabbit: 20 ml/kg; LC50: inhalation, rat: 64,000 ppm (4hr) Affects optic 

nerve. Irritant. 

Trimethylborate: LD50 oral, rat: 6,140 mg/kg; dermal, rabbit: 1,981 mg/kg. 

Overexposure to brazing fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes.


-4- 

SDS NO. 7-E 


Chronic toxicity: None anticipated from flux. 

Overexposure to brazing fumes may affect pulmonary function. Prolonged inhalation of nickel and chromium 

compounds above safe exposure limits can cause cancer. Overexposure to manganese and manganese 

compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the 

brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological 

disturbances and spastic gait. 

12. ECOLOGICAL INFORMATION 

Brazing consumables and materials could degrade/weather into components originating from the consumables or from the materials 

used in the brazing process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater. 

13. DISPOSAL CONSIDERATIONS 

Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal 

and local regulations. Use recycling procedures if available. 

USA RCRA: Unused product is considered an ignitable hazardous waste if discarded, RCRA ID D001. 

Prevent waste from contaminating surrounding environment. 

Residues from brazing consumables and processes could degrade and accumulate in soils and groundwater. 

14. TRANSPORT INFORMATION 

US DOT: Class: Flammable liquid Shipping Name: Flammable liquid n.o.s. (acetone, methanol) 

ID Number: UN1993 

Packing group: II 

Canada TDG: Class: Flammable liquid Shipping Name: FLAMMABLE LIQUID n.o.s. (acetone, methanol) 

ID Number: UN1993 

Packing group: II 

15. REGULATORY INFORMATION 

Read and understand the manufacturer's instructions, your employer's safety practices and the health and safety instructions on the 

label. Observe any federal and local regulations. Take precautions when brazing and protect yourself and others. 

WARNING: Brazing fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate 

ventilation. 

ELECTRIC SHOCK can kill. 

ARC RAYS and SPARKS can injure eyes and burn skin. 

Wear correct hand, head, eye and body protection. 

Canada: WHMIS classification: B2, D1B, D2A, D2B 

Canadian Environmental Protection Act (CEPA): All constituents of this product are on the Domestic Substance List (DSL). 

USA: Under the OSHA Hazard Communication Standard, this product is considered hazardous. 

This product contains or produces a chemical known to the state of California to cause cancer and birth defects (or other 

reproductive harm). (California Health & Safety Code § 25249.5 et seq.) 

United States EPA Toxic Substance Control Act: All constituents of this product are on the TSCA inventory list or are 

excluded from listing. 

CERCLA/SARA Title III 

Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs): 

Ingredient name RQ (lb) TPQ (lb) 

Acetone 5000 None 

Methanol 5000 None 

Trimethylborate None None 

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National 

Response Center and to your Local Emergency Planning Committee.


-5- 

SDS NO. 7-E 


Section 311 Hazard Class 

As shipped: Immediate, Fire hazard In use: Immediate, Fire hazard 

EPCRA/SARA Title III 313 Toxic Chemicals 

The following metallic components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA 313 

reporting. See Section 3 for weight percent. 

Ingredient name Disclosure threshold 

Methanol 1.0% de minimis concentration 

16. OTHER INFORMATION 

This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. This SDS supersedes 7-D. 

Refer to ESAB “Welding and Cutting - Risks and Measures”, F52-529 “Precautions and Safe Practices for Electric Welding and 

Cutting” and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and to: 

USA: Contact ESAB at www.esabna.com or 1-800-ESAB-123 if you have questions about this SDS. 

American National Standard Z49.1 “Safety in Welding and Cutting”, ANSI/AWS F1.5 “Methods for Sampling and Analyzing 

Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by 

Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North 

Le Jeune Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org. 

OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 

371954, Pittsburgh, PA 15250-7954. 

American Conference of Governmental Hygienists (ACGIH), Threshold Limit Values and Biological Exposure Indices, 6500 

Glenway Ave., Cincinnati, Ohio 45211, USA. 

NFPA 51B “Standard for Fire Prevention During Welding, Cutting and Other Hot Work” published by the National Fire 

Protection Association, 1 Batterymarch Park, Quincy, MA 02169. 

UK: WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of health 

and safety”. 

Germany: Unfallverhütungsvorschrift BGV D1, “Schweißen, Schneiden und verwandte Verfahren”. 

Canada: CSA Standard CAN/CSA-W117.2-01 “Safety in Welding, Cutting and Allied Processes”. 

This product has been classified according to the hazard criteria of the CPR and the SDS contains all the information 

required by the CPR. 

R-phrases: R10 – Flammable. 

R11 – Highly flammable. 

R21 – Harmful in contact with skin. 

R36 – Irritating to eyes. 

R66 – Repeated exposure may cause skin dryness or cracking. 

R67 – Vapours may cause drowsiness and dizziness. 

R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed. 

R39/23/24/25 – Toxic: danger of vary serious irreversible effects through inhalation, in contact with skin and if 

swallowed. 

ESAB requests the users of this product to study this Safety Data Sheet (S.D.S.) and become aware of product hazards and safety 

information. To promote safe use of this product a user should: 

- notify its employees, agents and contractors of the information on this S.D.S and any product hazards/safety information. 

- furnish this same information to each of its customers for this product. 

- request such customers to notify employees and customers for the same product hazards and safety information. 

The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the conditions of 

use are outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied 

is given. Contact ESAB for more information.

A Subsidiary of The ESAB Group, Inc. 


Revised: March 25, 2009 Supersedes: October 10, 2008 

Product Name: ALUMINUM WELDING WIRE AND METALLIZING WIRE 

Emergency Phone: 1-717-637-8911 or 1-800-424-9300 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

AlcoTec Wire Corporation 

2750 Aero Park Drive Traverse City, MI 49686-9263 USA Phone (231) 941-4111 

Sales and Marketing Fax (231) 941-9154 Administrative and Quality Control Fax (231) 941-1040 

alcotec@alcotec.com E-mail www.alcotec.com Web site 

SDS NO. 7994-G 

Chemical Formula: Mixture. 

Other Designations: AlcoTec ALMIGWELD (Aluminum spooled electrode) 

AlcoTec ALTIGWELD (Aluminum straight length welding rod) 

Aluminum Metallizing Wire (coils and spools) 

AlumaArc (Aluminum spooled electrode and straight length welding rod) 

Manufacturer: AlcoTec Wire Corporation, 2750 Aero Park Drive, Traverse City, MI 49686-9263 USA 

Product Use: Welding, Filler Metal, Metallizing, Brazing 

2. HAZARDS INFORMATION 

EMERGENCY OVERVIEW 

Solid, silvery, odorless. Non-flammable as supplied. Small chips, fine turnings, and dust from processing may 

ignite readily. 

Explosion/fire hazards may be present when (See Sections 5, 7 and 10 for additional information): 

Dust or fines are dispersed in the air. 

Fines or dust are in contact with other metal 

oxides (e.g., rust). 

Chips, fines, or dust are in contact with water. 

Molten aluminum is in contact with 

water/moisture or other metal oxides. 

Dust or fume from welding can cause eye, skin, or upper respiratory tract irritation; metal fume fever; lung 

diseases, neurological effects and other systemic effects. 

Potential Health Effects 

EYES: Fume can cause irritation. Ultraviolet radiation from welding can cause flash burns. 

SKIN: Can cause irritation. Ultraviolet radiation from welding can cause flash burns. 

INHALATION: Can cause respiratory tract irritation, metal fume fever, and other health effects listed below: 

Cancer hazard 

Aluminum is welded in a protective, inert atmosphere such as argon or helium using the MIG or TIG process. 

Welding processes generate welding fumes and an intense ultraviolet radiation that results in the formation of 

ozone, and oxides of nitrogen. Ultraviolet radiation from welding can also cause flash burns to the eyes and skin. 

The International Agency for Research on Cancer has classified welding fumes as possibly carcinogenic to 

humans (Group 2B). 

Exposure to low levels of ozone can cause irritation of the eyes, nose, and throat. Inhalation can cause chest 

tightness, headache, shortness of breath, cough, wheeze, nausea, and narrowing of airways. Symptoms 

disappear when removed from exposure. 

Exposure to high levels of ozone may cause acute respiratory distress with shortness of breath, pulmonary 

changes, hemorrhage, and pulmonary edema (fluid in the lungs). Symptoms of pulmonary edema may be 

delayed for one or more hours. Exposure of test animals and human tissue to high concentrations has shown 

chromosomal changes, reproductive effects, blood changes, and death from lung congestion. 

Oxides of nitrogen can cause irritation of the eyes, skin (when moist), and respiratory tract. Exposure to high 

levels of nitrogen oxides can cause delayed pulmonary edema (fluid in the lungs) which may be fatal. Nitric 

oxide can cause formation of methemoglobin, which decreases the blood’s ability to carry oxygen. Chronic 

overexposure can cause pulmonary fibrosis (scarring of the lungs). 

Overexposure to Aluminum dust/fines and fumes can cause reduced lung function and may be associated with 

neurological effects.

SAFETY DATA SHEET SDS NO. 7994-G 

Revised: March 25, 2009 Supersedes: October 10, 2008 Page 2 of 9 


Overexposure to magnesium oxide fumes can cause respiratory tract irritation and fever, chills, shortness of 

breath, and malaise (metal fume fever). Temporary symptoms can include fever, chills, nausea, vomiting, and 

muscular pain. 

Chronic exposure to inert dusts of silicon can cause increased airway resistance and contributes to chronic 

bronchitis. Intratracheal administration of silicon in rabbits produced significant pulmonary lesions. 

Exposure to zinc oxide fumes subsequent to burning, welding, and molten metal work can result in fever, 

chills, shortness of breath, and malaise (metal fume fever), and upper respiratory tract irritation. Temporary 

symptoms can include fever, chills, nausea, vomiting, and muscular pain. Exposure to dust or fines presents a 

low health risk by inhalation. 




Hexavalent chromium (Chrome VI) can cause asthma, kidney damage, primary irritant dermatitis, sensitization 

dermatitis, skin ulceration, and pulmonary edema (fluid in the lungs). Chronic inhalation or overexposure has 

been associated with lung, nasal, and gastrointestinal cancer. Hexavalent chromium is listed as carcinogenic 

to humans by IARC (Group 1)*. Chromium and some of its compounds are listed as carcinogenic by the NTP. 

Hexavalent chromium compounds may be generated during welding operations, with alloys containing 

chromium. A SIGNIFICANT AMOUNT OF THE CHROMIUM IN THE FUMES CAN BE HEXAVALENT 

CHROMIUM, WHICH HAS A VERY LOW EXPOSURE LIMIT, 0.005 mg/m 3 (5µg/m 3 ). 

The potential for overexposure to copper fume may exist when welding, flame cutting, etc. Overexposure to 

copper dust/mists can cause irritation of the eyes, skin, and upper respiratory tract. Chronic overexposure may 

result in blood disorders (anemia), and skin and hair discolorations. Overexposure to copper fume can result in 

respiratory tract irritation, nausea, and fever, chills, shortness of breath and malaise (metal fume fever). 

Nickel dust and fume can cause skin sensitization, allergic contact dermatitis, and conjunctivitis. Chronic 

inhalation of high levels of nickel can cause irritation of airways and lungs, lung fibrosis (scarring of the lungs), 

nasal septum perforation, nasal sinusitis, respiratory sensitization and asthma. Nickel compounds have been 

associated with cancer of lungs, larynx, and paranasal sinuses in humans. Nickel compounds are listed on the 

NTP and are listed as carcinogenic to humans by IARC (Group 1)*. Nickel metal is possibly carcinogenic to 

humans as defined by IARC (Group 2B)*. 

Beryllium can cause irritant dermatitis, allergic contact dermatitis, and skin granulomas. Inhalation of excessive 

levels of beryllium can result in acute pneumonitis (inflammation of the lung tissues). 

Beryllium can cause lung sensitization in susceptible individuals. Chronic inhalation of dust and fumes by 

these sensitized individuals can result in a serious, progressive disease called Chronic Beryllium Disease 

(CBD). This disease, often misdiagnosed as sarcoidosis, is an allergic condition in which the lung tissues 

become inflamed. This inflammation, sometimes accompanied with fibrosis (lung scarring), restricts the uptake 

of oxygen into the blood stream. CBD can, over time, be fatal. 

Inhalation of beryllium has produced lung tumors in animals. Beryllium is listed on the NTP and is known to be 

carcinogenic to humans by IARC (Group 1)*. (See Section 8) 

Lead inorganic dust and fume is listed as a possibly carcinogenic to humans by IARC Group 2B*. 

Overexposure to lead dust or fume can cause weakness of extremities (peripheral neuropathy), stomach 

disturbances, harm to the kidneys, liver, central nervous system, blood and blood forming tissues, and 

reproductive organs. Overexposure to lead has been associated with human reproductive effects (e.g. 

reduced fertility and damage to the fetus of exposed pregnant women). Lead is a cumulative toxic metal by 

inhalation or ingestion. 

Warning: This product contains or produces a chemical known to the State of California to cause cancer and 

birth defects (or other reproductive harm). (California Health & safety Code 25249.5 et seq.) 

Medical conditions aggravated by exposure to the product: 

Chronic lung disease, skin rashes, and asthma. 

*IARC CLASSIFICATIONS: 

Group 1: The agent is carcinogenic to humans. 

There is sufficient evidence that a casual relationship existed between exposure to the agent and 

human cancer.




Group 2B: The agent is possibly carcinogenic to humans. 

Generally includes agents for which there is limited evidence in humans in the absence of 

sufficient evidence in experimental animals. 

3. COMPOSITION INFORMATION ON INGREDIENTS 

Alloy Ingredients: (% by weight shown as a maximum or a range, except for Aluminum, which is a minimum % by weight) 

Alloy Si Fe Cu Mn Mg Cr Ni Zn Ti 

Others 

Each 1 

Others 

Total 

Al 

1100 0.95 = Si + Fe 0.05-0.20 0.05 ---- ---- ---- 0.10 ---- 0.05 0.15 99.00 

1350 0.10 0.40 0.05 0.01 ---- 0.01 ---- 0.05 ---- 0.03 3 0.10 99.50 

1188 0.06 0.06 0.005 0.01 0.01 ---- ---- 0.03 0.01 0.01 4 ---- 99.88 

1199 0.006 0.006 0.006 0.002 0.006 ---- ---- 0.006 0.002 0.002 7 ---- 99.99 

2319 0.20 0.30 5.8-6.8 0.20-0.40 0.02 ---- ---- 0.10 0.10-0.20 0.05 5 0.15 Rmnd 2 

4043 4.5-6.0 0.8 0.30 0.05 0.05 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

4047 (718) 11.0-13.0 0.8 0.30 0.15 0.10 ---- ---- 0.20 ---- 0.05 0.15 Rmnd 2 

4145 (716) 9.3-10.7 0.8 3.3-4.7 0.15 0.15 0.15 ---- 0.20 ---- 0.05 0.15 Rmnd 2 

4643 3.6-4.6 0.8 0.10 0.05 0.10-0.30 ---- ---- 0.10 0.15 0.05 0.15 Rmnd 2 

5183 0.40 0.40 0.10 0.50-1.0 4.3-5.2 0.05-0.25 ---- 0.25 0.15 0.05 0.15 Rmnd 2 

5356 0.25 0.40 0.10 0.05-0.20 4.5-5.5 0.05-0.20 ---- 0.10 0.06-0.20 0.05 0.15 Rmnd 2 

5554 0.25 0.40 0.10 0.50-1.0 2.4-3.0 0.05-0.20 ---- 0.25 0.05-0.20 0.05 0.15 Rmnd 2 

5556 0.25 0.40 0.10 0.50-1.0 4.7-5.5 0.05-0.20 ---- 0.25 0.05-0.20 0.05 0.15 Rmnd 2 

5654 0.45 = Si + Fe 0.05 0.01 3.1-3.9 0.15-0.35 ---- 0.20 0.05-0.15 0.05 0.15 Rmnd 2 

206.0 0.10 0.15 4.2-5.0 0.20-0.50 0.15-0.35 ---- 0.05 0.10 0.15-0.30 0.05 6 0.15 Rmnd 2 

C355.0 (4009) 4.5-5.5 0.20 1.0-1.5 0.10 0.40-0.6 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

A356.0 (4008, 4010) 6.5-7.5 0.20 0.20 0.10 0.25-0.45 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

357.0 6.5-7.5 0.15 0.05 0.03 0.45-0.6 ---- ---- 0.05 0.20 0.05 0.15 Rmnd 2 

Notes: 

1 

Beryllium shall not exceed 0.0003 percent. 

2 

Rmnd = remainder. 

3 

1350 may contain Gallium, 0.03% (max.), Boron 0.05% (max.), and Vanadium plus Titanium, 0.02% (max.). 

4 

1188 may contain Gallium, 0.03% (max.), and Vanadium, 0.05% (max.). 

5 

2319 contains Vanadium, 0.05-0.15% and Zirconium, 0.10-0.25%. 

6 

206.0 may contain Tin, 0.05% (max.). 

7 

1199 may contain 0.005% each (max.) of Gallium and Vanadium. 


EYES: Flush eyes with plenty of water or saline for at least 15 minutes. Consult a physician. 

SKIN: Wash thoroughly with soap and water. Consult a physician if irritation persists. 

INHALATION: Remove to fresh air. Check for clear airway, breathing, and presence of pulse. Provide CPR for 

persons without pulse or respirations. Consult a physician immediately.





FLAMMABLE PROPERTIES: Non-flammable as shipped. Small chips and dust from processing may ignite 

readily. 

FIRE/EXPLOSION: May be a potential hazard under the following conditions: 

Dusts or fines dispersed in the air can be explosive. 

Chips, fines and dust in contact with water can generate flammable/explosive hydrogen gas. These gases 

could present an explosion hazard in confined or poorly ventilated spaces. 

Fines and dust in contact with certain metal oxides (e.g., rust). A thermite reaction, with considerable heat 

generation, can be initiated by a weak ignition source. 

Molten aluminum in contact with water/moisture or other metal oxides (e.g., rust). Moisture entrapped by 

molten aluminum can be explosive. Contact of molten aluminum with other metal oxides can initiate a 

thermite reaction. 

EXTINGUISHING MEDIA: Use fire fighting methods and materials that are appropriate for surrounding fire. Use 

coarse water spray on chips or turnings. For fines, dust or molten aluminum, use 

Class D extinguishing agents. 

DO NOT USE: Halogenated extinguishing agents on small chips/fines. Do not use water in fighting fires around 

molten aluminum. 

FIRE FIGHTING INSTRUCTIONS: Fire fighters should wear NIOSH approved, positive pressure, self-contained 

breathing apparatus and full protective clothing when appropriate. 


SMALL/LARGE SPILL: If molten: Contain the flow using dry sand or salt flux as a dam. Do not use shovels or 

hand tools to halt the flow of molten aluminum. Allow the spill to cool before remelting as scrap. 


Product should be kept dry. Avoid generating dust. Avoid contact with sharp edges or heated metal. Hot and cold 

aluminum are not visually different. 

REQUIREMENTS FOR PROCESSES WHICH GENERATE DUSTS OR FINES 

If processing of these products includes operations where dust or extremely fine particulate is generated, 

obtain and follow the safety procedures and equipment guides contained in Aluminum Association Bulletin F1 

and National Fire Protection Association (NFPA) brochures listed in Section 16. Use non-sparking handling 

equipment. Cover and reseal partially empty containers. Provide grounding and bonding where necessary to 

prevent accumulation of static charges during aluminum dust handling and transfer operations. (See 

Section15). 

Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuums and 

electrostatic precipitators must not be used. Dust collection systems must be dedicated to aluminum dust only 

and should be clearly labeled as such. Do not co-mingle fines of aluminum with fines of iron, iron oxide (rust) 

or other metal oxides. 

Do not allow chips, fines or dust to contact water, particularly in enclosed areas. 

Avoid all ignition sources. Good housekeeping practices must be maintained. 

REQUIREMENTS FOR REMELTING OF ALUMINUM SCRAP MATERIAL AND/OR INGOT 

Molten aluminum and water can be an explosive combination. The risk is greatest when there is sufficient 

molten aluminum to entrap or seal off the water. Water and other forms of contamination on or contained in 

aluminum scrap or remelt ingot are known to have caused explosions in melting operations. While the 

products may have minimal surface roughness and internal voids, there remains the possibility of moisture 

contamination or entrapment. If confined, even a few drops of water can lead to violent explosions.




All tooling and containers which come in contact with molten aluminum must be preheated or specially coated 

and rust free. Molds and ladles must be preheated or oiled before casting. Any surfaces that may contact 

molten aluminum (i.e., concrete) should be specially coated. 

Drops of molten aluminum in water (e.g. from plasma arc cutting), while not normally an explosion hazard, can 

generate enough flammable hydrogen gas to present an explosion hazard. Circulation of the water and 

removal of the aluminum particles minimize the hazards. 

During melting operations, the following minimum guidelines should be observed: 

Inspect all aluminum materials before furnace charging and completely remove surface contamination such as 

water, ice, snow, deposits of grease and oil or other surface contamination resulting from weather exposure, 

shipment, or storage. 

Store materials in dry, heated areas with any cracks or cavities pointed downwards. 

Preheat and dry large or heavy items such as ingot adequately before charging into a furnace containing 

molten aluminum. This is typically done by use of a drying oven or homogenizing furnace. The drying cycle 

should bring the internal metal temperature of the coldest item of the batch to 400 0 F and then hold at that 

temperature for 6 hours. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

ENGINEERING CONTROLS: Use with adequate explosion-proof ventilation to meet the limits listed in Section 2. 

RESPIRATORY PROTECTION: Use NIOSH-approved respiratory protection [dust, fume, high efficiency dust/fume 

mask for lead, or other (organic vapor)] as specified by an Industrial Hygienist or other qualified professional if 

concentrations exceed the limits listed in Section 2. 

EYE PROTECTION: Welders should use appropriate equipment (e.g. welder's helmet, face shield, filter lens) to 

prevent eye irritation or flash burns. 

SKIN PROTECTION: Wear impervious gloves to avoid any skin injury. 

The presence of airborne beryllium has been detected during the welding of aluminum alloys with beryllium 

content at only 0.002% by weight. In accordance with OSHA 29 CFR 1910.252: Welding or cutting operations 

involving beryllium-containing base or filler metals shall be done using local exhaust ventilation and airline 

respirators unless atmospheric tests under the most adverse conditions have established that the workers' 

exposures is within the acceptable concentrations defined by 29 CFR 1910.1000. In all cases, workers in the 

immediate vicinity of the welding or cutting operations shall be protected as necessary by local exhaust 

ventilation or airline respirators. 

Good industrial hygiene practices, including reducing occupational exposures to as low as reasonably 

achievable, are recommended. Where employees are exposed to beryllium above the PEL or where excessive 

contamination of clothing with beryllium is possible, adequate protective clothing should be provided to prevent 

contamination of personal clothing. Personnel assigned to launder such clothing should be advised of 

beryllium's presence and potential health effects. 

Sampling to establish lead level exposure is advised where exposure to airborne particulate or fumes is 

possible. Consult OSHA Lead Standard 29 CFR 1910.1025 for specific health/industrial hygiene precautions 

and requirements to follow when handling lead compounds.




EXPOSURE LIMITS: 

EXPOSURE LIMITS 

(TWA in mg/m 3 unless noted) 

Component CAS No. Form ACGIH TLV OSHA PEL 

Aluminum 7429-90-5 

Beryllium and 

Beryllium 

Compounds 

Total dust, fume 

Respirable 1 

7440-41-7 All compounds as Be 0.00005 0.002, 0.005 Ceiling, 

0.025 for 30 minutes 

Chromium 7440-47-3 Metals 

Cr II compounds 

Cr IIl compounds, inorganic 

Cr VI compounds, water soluble 

Cr VI compounds, water insoluble 

Copper 7440-50-8 Fume 

Dust/mist 

0.5 

---- 

0.5 as Cr 

0.05 as Cr 

0.01 as Cr 

0.2 

1 

15 

5 

1 

0.5 as Cr 

0.5 as Cr 

0.005 as Cr VI 


Gallium 7440-55-3 None None 

Iron 7439-89-6 Oxide dust & fume (as Fe) 5 (respirable) 10 

Lead (nonvolatile) 7439-92-1 Elemental and inorganic 

compounds 

0.05 as Pb 0.05 as Pb 

Magnesium 7439-95-4 Oxide fume 10 (inhalable) 15 Total particulate 

Manganese 7439-96-5 Dust fume 0.2 5 (ceiling) 

Nickel 7440-02-0 Metal & insoluble compounds 

Soluble inorganic compounds 

Insoluble inorganic compounds 

Silicon 7440-21-3 Total dust 

Respirable 

1.5 as Ni 

0.1 as Ni inhalable 


TLV withdrawn 

---- 

0.1 

1 

1 as Ni 

1 as Ni 

1 as Ni 

Titanium 7440-32-6 Oxide dust 10 15 (total particulate) 

Vanadium 7440-62-2 Respirable dust 

Respirable fume 

Zinc 7440-66-6 Oxide fume 

Total Oxide dust 

Respirable oxide dust 

0.05 as V2O5 

---- 

---- 

2, 10 (STEL) 

15 

5 

0.5 (ceiling) as V2O5 


Zirconium 7440-67-7 5, 10 (STEL) 5 (compounds only) 

5 

15 

5




Possible hazards during processing by welding, or arc spray metallizing 

ACGIH TLV OSHA PEL 

Ozone (light, heavy work) 0.1, 0.05 ppm 0.1 ppm 

Nitric oxide 25 ppm 25 ppm 

Nitrogen dioxide 3, 5ppm (STEL) 5 ppm (ceiling) 


APPEARANCE: Solid 

BOILING POINT: Not applicable 

FREEZE-MELT POINT: 970 ° -1215 ° F (521 ° -657 ° C) 

VAPOR PRESSURE (mm): Not applicable 

VAPOR DENSITY (air = 1): Not applicable 

SOLUBILITY IN WATER: None 

SPECIFIC GRAVITY: Not determined 

DENSITY: Approximately .1 lb/in 

pH: Not applicable 

ODOR: None 

ODOR THRESHOLD (ppm): Not applicable 

COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable 


Stable under normal conditions of use, storage, and transportation as shipped. Chips, fines, dust and molten 

aluminum are considerable more reactive with the following: 

Water: Slowly generates flammable/explosive hydrogen gas and heat. Generation rate is greatly increased 

with smaller particles (e.g., fines and dusts). 

Molten aluminum can react violently/explosively with water or moisture, particularly when the water is 

entrapped. 

Heat: Oxidizes at a rate dependent upon temperature and particle size. 

Strong oxidizers: Violent reaction with considerable heat generation. 

Can react explosively with nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) when heated or 

molten. 

Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is greatly 

increased with smaller particles (e.g., fines and dusts). 

Halogenated compounds: Many halogenated hydrocarbons, including halogenated fire extinguishing agents, 

can react violently with finely divided aluminum. 

Iron oxide (rust) and other metal oxides (e.g., copper and lead oxides): A violent thermite reaction 

generating considerable heat can occur. Reaction with aluminum fines and dusts requires only very weak 

ignition sources for initiation. 

Molten aluminum can react violently without external ignition source. 

Iron powder: An explosive reaction forming hydrogen gas occurs when heated above 1470 ° F (600 ° C). 


LD50 or LCLO found for oral, dermal or inhalation routes of administration: 

Nickel: oral rat LD50: 9000 mg/kg body weight 

Silicon: oral rat LD50: 3160 mg/kg body weight 

Manganese: oral rat LD50: 9000 mg/kg body weight 

Iron: intraperitoneal rabbit LDLO: 20 mg/kg - no toxic effect noted 


ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: Not available.




13. DISPOSAL CONSIDERATION 

Collect scrap for remelting and recycling. To maintain metal purity, it may be desirable to segregate this scrap from 

other alloys. 

RCRA Status: Characterize in accordance with 40 CFR 261 or state equivalent. 


USA DOT: Not Regulated - Enter the proper freight classification, "SDS Number," and "Product Name" on the 

shipping paperwork. 

Canadian TDG Hazard Class & PIN: Not regulated. 


All electrical equipment must be suitable for use in hazardous atmospheres involving aluminum powder in 

accordance with 29 CFR 1910.307. The National Electrical Code, NFPA 70, contains guidelines for determining 

the type and design of equipment and installation, which will meet this requirement. 

U.S. Federal Regulations 

TSCA STATUS: All components of this product are listed on the TSCA inventory. 

CERCLA HAZARDOUS SUBSTANCES: Beryllium, Chromium, Chromium compounds, Copper, Lead, 

Manganese, Nickel, Zinc. 

SARA TITLE III: 

Section 311/312 Physical and Health Hazard Categories: Immediate (acute), delayed (chronic) if 

particulates/fumes are generated during processing. 

Section 313 Toxic Chemicals: Aluminum (fume/dust), Beryllium, Chromium, Copper, Lead, Manganese, Nickel, 

Vanadium (fume/dust), and Zinc (fume/dust). 

State Regulations 

PENNSYLVANIA "Special Hazardous Substance": Beryllium; Nickel; Chromium compounds, hexavalent. 

International Regulations 

CANADIAN DOMESTIC SUBSTANCES LIST: All components of this product are listed on the Canadian DSL. 

EUROPEAN COMMUNITY: All components of this product are listed on ECOIN, the European Core Inventory. 


STATUS: Changes in Section 3. 

PREPARED BY: Hazardous Materials Control Committee 

OSHA Standard 29 CFR 1910.1025 (Lead) 

OSHA Standard 29 CFR 1910.252 

ANSI 249.1, Safety in Welding and Cutting 

Aluminum Association's Bulletin F-1,"Guidelines for Handling Aluminum Fines Generated during Various 

Aluminum Fabricating Operations.” The Aluminum Association, 900 19th Street, NW, Washington, DC 20006. 

NFPA 65, Standard for Processing and Finishing of Aluminum (NFPA phone: 800-344-3555) 

NFPA 70, Standard for National Electrical Code 

NFPA 77, Standard for Static Electricity 

Guide to Occupational Exposure Values-I 997, Compiled by the American Conference of Governmental 

Industrial Hygienists (ACGIH). 

Dept. of Health and Human Services, NIOSH: Registry of Toxic Effects of Chemical Substances, 1985-86 

Edition 

Sax, N. Irving: Dangerous Properties of Industrial Materials, Van Nostrand Reinhold Co., Inc., 1984




INFORMATION HEREIN IS GIVEN IN GOOD FAITH AS AUTHORITATIVE AND VALID; 

HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, CAN BE MADE. 

LEGEND: 

ACGIH American Conference of Governmental Industrial Hygienists atm atmosphere 

AICS Australian Inventory of Chemical Substances cm centimeter 

CAS Chemical Abstract Services g gram 

CERCLA Comprehensive Environmental Response, Compensation, & Liability Act in inch 

CFR Code of Federal Regulations kg kilogram 

DOT Department of Transportation lb. pound 

DSL Domestic Substances List (Canada) m meter 

ECOIN European Core Inventory mg milligram 

EPA Environmental Protection Agency mm millimeter 

IARC International Agency for Research on Cancer n.o.s. not otherwise specified 

LC50 Lethal Concentration (50 percent kill) ppb parts per billion 

LCLo Lowest published lethal concentration ppm parts per million 

LD50 Lethal dose (50 percent kill) psia pounds/square inch absolute 

LDLo Lowest published lethal dose ug microgram 

MIG Metal Inert Gas 

NFPA National Fire Protection Association 

NIOSH National Institute for Occupational Safety and Health 

NTP National Toxology Program 

OSHA Occupational Safety and Health Administration 

PEL Permissible Exposure Limit 

PIN Product Identification Number 

RCA Resource Conservation and Recovery Act 

SARA Superfund Amendments and Reauthorization Act 

STEL Short Term Exposure Limit 

TCLP Toxic Chemicals Leachate Program 

TDG Transportation of Dangerous Goods 

TIG Tungsten Inert Gas 

TLV Threshold Limit Value 

TSCA Toxic Substances Control Act 

TWA Time weighted Average

Product Name: MSDS No.: Date: 

Product Name: 

Product Use: 

Chemical Name: 



Trade Name: 

Synonym: 

Chemical Formula: Chemical Family: 

Telephone: 

Emergencies: 

Supplier 

/Manufacture: 

Phone: 

Fax: 



CAUTION! 

ROUTES OF EXPOSURE: 


INHALATION: 



High-pressure gas. Can cause rapid suffocation. May cause dizziness and drowsiness. Selfcontained 

breathing apparatus may be required by rescue workers. 


SKIN CONTACT: 


SWALLOWING: 

EYE CONTACT: 


Copyright © 2005, Praxair Canada Inc.

*NOTES TO PHYSICIAN: 

Acute: 

Chronic: 



Oct 15, 2010 





NUMBER 

INHALATION: 

SKIN CONTACT: 

SWALLOWING: 

EYE CONTACT: 


CONCENTRATION 

% by Mole 


This product is inert. There is no specific antidote. Treatment of over-exposure should be directed at the control of 

symptoms and the clinical condition. 



FLAMMABLE : IF YES, UNDER WHAT CONDITIONS? 




CAUTION! High-pressure gas. 






FLASH POINT: 


LOWER: UPPER: 




CAUTION! High-pressure gas. 



Oct 15, 2010


Handling of Compressed Gases in Containers, 



Oct 15, 2010 


High pressure gas. Gas can 

cause rapid suffocation due to oxygen deficiency. 

Prevent reverse flow. 

Never work on a pressurized system. 

an electrical circuit. 


Safe 

Never place a compressed gas cylinder where it may become part of 

NFPA 55: Standard for the Storage, 

Use, and Handling of Compressed and Liquefied Gases in Portable Cylinders 

Guidelines for Handling Gas Cylinders and Containers 





(Species & 

Routes) 

(Rat, 4 

hrs.) 

Exposure Limits






SPECIAL: 

OTHER: 

RESPIRATORY PROTECTION: 

SKIN PROTECTION: 

EYE PROTECTION: 


PHYSICAL STATE: 

BOILING POINT 

SPECIFIC GRAVITY: 

SPECIFIC GRAVITY: 

APPEARANCE & ODOUR: 



VAPOUR PRESSURE 

SOLUBILITY IN WATER, 

EVAPORATION RATE 


VOLUME: 


pH: 



WATER/OIL 

DISTRIBUTION: 

ODOUR THRESHOLD: 

Oct 15, 2010

STABILITY: 

CONDITIONS OF CHEMICAL INSTABILITY: 









TDG/IMO SHIPPING NAME: 

HAZARD CLASS: 

SHIPPING LABEL(s): 


and Non-toxic 

gas. 








IDENTIFICATION #: 

PRODUCT RQ: 

Oct 15, 2010



EINECS: 

DSCL (EEC): 

International Lists: 


Oct 15, 2010 




MIXTURES: 


HMIS RATINGS: 


THREADED: 


ULTRA-HIGH-INTEGRITY 

CONNECTION: 


DO NOT USE ADAPTERS.


Praxair Flowing Airstream 

Oct 15, 2010

MATERIAL SAFETY DATA SHEET 

Armstrong World Industries, Inc. 

Environment, Health and Safety Division: Building Products 

2500 Columbia Avenue, P.O. Box 3001 

Lancaster, PA 17604 Date: 9/09 (replaces 7/09) 

Telephone (717) 396-2328 or 396-2935 

N/A = Not applicable or Not Available 

Issued By : Safety, Health and N/K = None Known or Not Known 

Industrial Hygiene Department 

Department of Transportation Information 

HMIS ( 0 = minimal hazard, 4 = severe hazard ) Shipping name : Not Classified 

Health = 1 Hazard Class : N/A 

Flammability = 0 ID No : N/A 

Reactivity = 0 Emergency Only Contact: CHEM-TEL 800-255-3924 

I. Product Information 

A. Product Name : Man-made Vitreous Fiber Ceilings and Wall Panels (Class A) - MSDS #1 

B. Chemical Name and Synonyms : N/A 

C. Chemical or Product Family : Man-made Vitreous Fibers 

II. Ingredient Information 

A. Hazardous Components C.A.S No. % OSHA PEL ACGIH TLV 

( Chemical Identity; Common Name ) Respirable: Respirable: 

Mineral Wool Fiber N/A 0-60 1 f/cc 1 f/cc 

Fibrous Glass 65997-17-3 0-13 1 f/cc 1 f/cc 

This product formulation does not contain asbestos. 

III. Physical Data 

A. Appearance and Color : Gray, pressed man-made vitreous fiber panel of various colors 

B. Boiling Point ( degrees F ) : N/A 

C. Vapor pressure ( mm Hg @ 20 degrees C ) : N/A 

D. Vapor density ( Air = 1 ) : N/A 

E. Solubility in Water : N/A 

F. Specific Gravity ( H 2O = 1 ) : N/A 

G. Percent Volatile by weight ( 30 min. @ 275 degrees F ) : N/A 

H. Evaporation Rate ( Butyl Acetate = 1 ) : N/A 

I. pH : N/A 

IV. Fire and Explosion Data 

A. Flash point : N/A 

B. Flammable Range : LEL = N/A ; UEL = N/A 

C. Extinguishing Media : Water fog, dry chemical ABC rated 

D. Special Fire Fighting Procedures : None 

E. Unusual Fire and Explosion Hazards : None

Continued : Man-made Vitreous Fiber Ceilings and Wall Panels (Class A) - MSDS #1 Date: 9/09 (replaces 7/09) 

V. Health Data 

A. Primary Route (s) of Entry: Inhalation, skin, and eye contact 

B. Target Organs: Lungs, skin and eyes 

Effects of Overexposure : 

Acute Health Effects: Products are a transient mechanical irritant to the skin, eyes and upper respiratory system. 

Refer to special protection information for handling instructions. 

Chronic Health Effects: 

Mineral Wool Fiber: Mineral wool fiber has been classified as "not classifiable as to its carcinogenicity to human" (Group 3) by 

the International Agency for Research on Cancer (IARC). 

Fibrous Glass : Fibrous glass has been classified as "not classifiable as to its carcinogenicity to human" (Group 3) by 

the International Agency for Research on Cancer (IARC). Fibrous glass is listed by NTP as 2, reasonably anticipated to 

be a carcinogen. 

C. Carcinogenicity: NTP : Yes IARC Monographs : No OSHA Regulated : No 

D. Medical Conditions Generally aggravated by Exposure: Any condition generally aggravated by respiratory and mechanical 

irritants in the air or on the skin. Pre-existing upper respiratory and lung disease such as, but not limited to bronchitis, 

emphysema, and asthma. 

E. First Aid Procedures: 

Skin: Wash with mild soap and running water 

Eyes: Flush with flowing water for at least 15 minutes and if symptoms persist, seek immediate medical attention. 

VI. Reactivity Data 

A. Stability : Material is stable 

B. Incompatibility: N/K 

C. Hazardous Decomposition Products: Carbon dioxide, and other trace pyrolysis products typical of decomposition of any 

organic chemical. 

D. Hazardous Polymerization: N/A 

VII. Spill or Leak Procedures 

A. Steps to be taken if material is released or spilled : N/A 

B. 

Recycling Information : Armstrong Ceilings can be recycled through the Armstrong Ceiling Recycling Program. For more 

information on the program, requirements and local resources, please visit www.armstrong.com/ceilings/recycling or call our 

Recycling Center at 877-276-7876, press 1 (Ceilings), then press 8. 

If the Armstrong Ceilng Recycling Program cannot be used, please dispose in accordance with federal, state and local waste 

disposal regulations 

VIII. Special Protection Information 

During the installation, be certain that the work site is well ventilated, and avoid breathing dust. 

Wear long-sleeve, loose fitting clothes, gloves and eye protection. 

Handle these materials carefully to minimize airborne dust. 

If high dust levels are anticipated during installation, such as with the use of power tools, use the appropriate NIOSH approved 

dust respirator. 

All power cutting tools must be equipped with dust collectors. 

After using these materials, wash with warm water and mild soap. Do not scratch or rub skin if it becomes irritated. 

Wash work clothes separately, and then rinse the washer. 

The information presented herein is supplied as a guide to those who handle or use this product. Safe work practices must be 

employed when working with any materials. It is important that the end user makes a determination regarding the adequacy 

of the safety procedures employed during the use of this product.

MATERIAL SAFETY DATA SHEET PAGE 1 

SECTION I - PRODUCT IDENTIFICATION AND PREPARATION INFORMATION 

PRODUCT NAME: Bolbac EFFECTIVE DATE: January 1 st , 2009 

WHMIS CLASS: Class D –1A: Very Toxic CODE NO.: 6190 

Class E: Corrosive Liquid 

T.D.G. CLASSIFICATION: Hydrochloric Acid Solution 

Class 8 UN 1789 PG: II 

MANUFACTURER NAME AND ADDRESS: BRODI SPECIALTY PRODUCTS LTD. 


MARKHAM, ONTARIO L3R 8E5 

(905) 475-6084 

MSDS PREPARED BY: MSDS CO-ORDINATOR, (877) 744-0751 EXT 205, BRODI SPECIALTY PRODUCTS LTD 

EMERGENCY PHONE: CANUTEC (613) 996 6666 

SECTION II - HAZARDOUS INGREDIENTS 

INGREDIENTS: CAS# WT% ACGIH-TLV-C LC50 LD50 

Hydrochloric acid 7647-01-0 10-30 5 ppm (7 mg/m 3 1562 ppm/4hr (Vapour Rat) 900 mg/kg (Oral Rabbit) 

SECTION III- PHYSICAL DATA 

BOILING POINT (DEG ºC): 105ºC (221ºF) SPECIFIC GRAVITY (H20=1): 1.1 

VAPOUR PRESSURE (mm Hg): (3040 @ 20ºC) based on PERCENT VOLATILE (WT%): 99% 

data for: Hydrochloric acid EVAPORATION RATE (Water=1): Similar 

VAPOUR DENSITY (AIR=1): Similar PH (AS SUPPLIED):

PRODUCT NAME: Bolbac CODE: 6190 PAGE 2 

SECTION V- REACTIVITY DATA 

CONDITIONS FOR CHEMICAL INSTABILITY: Stable 

INCOMPATIBILITY: Extremely reactive or incompatible with metals, alkalis, halogenated compounds. 

Slightly reactive to reactive with moisture. 

HAZARDOUS DECOMPOSITION: Hydrogen and chlorine gas. 

SECTION VI- TOXICOLOGICAL PROPERTIES 

ROUTE OF ENTRY: Skin contact, inhalation, ingestion 

EFFECTS OF ACUTE EXPOSURE: 

Very dangerous in case of skin contact (irritant, permeator), of eye contact (irritant), of inhalation. Corrosive to skin and eyes on 

contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. 

Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by 

coughing, choking or shortness of breath. This product may irritate eyes and skin upon contact. Inflammation of the eye is 

characterized by redness, watering and itching. Skin inflammation is characterized by itching, scaling, reddening or occasionally, 

blistering. 

EFFECTS OF CHRONIC EXPOSURE: 

SKIN: Prolonged or repeated exposure can cause drying, defatting and dermatitis. 

IRRITANCY: Hazardous by WHMIS criteria. 

RESPIRATORY TRACT SENSITIZATION: No data available. 

CARCINOGENIC EFFECTS: Insufficient data available 

TERATOGENIC EFFECTS: Insufficient data available 

MUTAGENIC EFFECTS: Insufficient data available 

SYNERGISTIC MATERIALS: Not available 

GLOVES: 

SECTION VII-PREVENTATIVE MEASURES 

Gloves (impervious). 

EYE PROTECTION: Splash goggles. 

RESPIRATORY PROTECTION: If the TLV (50 ppm) of the product or any component is exceeded a NIOSH/MSHA jointly 

approved air supplied respirator is advised in the absence of proper environmental controls. 

OTHER PROTECTIVE EQUIPMENT: As required by employer codes. 

ENGINEERING CONTROLS: General ventilation is normally adequate. Use local exhaust for elevated temperature controls. 

LEAK AND SPILL PROCEDURE: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with 

non-reactive absorbent and placed in suitable, covered-labeled containers. Prevent large spills 

from entering sewers or waterways. Contact emergency services and supplier for advice. 

WASTE DISPOSAL: Review federal, provincial and local government requirements prior to disposal. 

STORAGE REQUIREMENTS: Store in closed containers. Store away from incompatible materials. Ensure storage area has 

adequate ventilation. 

SECTION VIII- FIRST AID 

EYE: Immediately flush with water for 15 minutes. Call a doctor immediately. 

SKIN: Rinse with soap and water. Call a doctor if irritation develops and persists. Completely decontaminate clothing, shoes and 

leather goods before reuse or discard. 

INHALATION: Remove to fresh air. If symptoms persist, call a doctor. 

INGESTION: Do not induce vomiting. Rinse mouth with water, drink two or more glasses of water. Contact a doctor immediately. 

If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. 

Never give anything by mouth if victim is unconscious, is rapidly losing consciousness or is convulsing. 

DISCLAIMER: Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. No 

warranty, expressed or implied, is made and the supplier will not be liable for any losses, injuries or consequential damages, which may result 

from the use of or reliance on any information, contained in this form.


PRODUCT NAME: BROFLOAT 

SUPPLIER’S NAME: BRODI SPECIALTY PRODUCTS LTD. INFORMATION PHONE: 1-(877) 744-0751 

SUPPLIER’S ADDRESS: 250 COCHRANE DRIVE, UNIT 9, MARKHAM, ON, L3R 8E5 EFFECTIVE DATE: JANUARY 1 st , 2009 

PREPARED BY: MSDS CO-ORDINATOR (877) 744-0751 EXT 205, BRODI SPECIALTY PRODUCTS LTD. 

SECTION 1 MATERIAL IDENTIFICATION 

WHMIS CLASSIFICIATION WHMIS CLASS B3, D-2B 

CHEMICAL FORMULA MIXTURE 

MOLECULAR WEIGHT NOT APPLICABLE 

MATERIAL USE GREASE TRAP CLEANER 

SECTION 2 HAZARDOUS INGREDIENTS OF MATERIAL 

HAZARDOUS INGREDIENT ISOPARAFFIN HYDROCARBON 

APPROX. CONCENTRATION % 60-100 

CAS NOT AVAILABLE 

EXPOSURE LIMITS NOT AVAILABLE 

LD50/LC50/SPECIES/ROUTE NOT AVAILABLE 

HAZARDOUS INGREDIENT D-LIMONENE 

APPROX. CONCENTRATION % 10-40 

CAS 5989-27-5 

EXPOSURE LIMITS NOT AVAILABLE 

LD50/LC50/SPECIES/ROUTE ORAL (LD50) MG/KG: ACUTE: 4400 (RAT) 

SECTION 3 PHYSICAL DATA FOR MATERIAL 

PHYSICAL STATE LIQUID 

ODOUR AND APPEARANCE CITRUS ODOUR, YELLOW LIQUID 

ODOUR THRESHOLD (PPM) NOT AVAILABLE 

SPECIFIC GRAVITY 0.78 

VAPOUR PRESSURE (MM) NOT AVAILABLE 

VAPOUR DENSITY (AIR =1) NOT AVAILABLE 

EVAPORATION RATE NOT DETERMINED 

BOILING POINT ( 0 C) NOT DETERMINED 

FREEZING POINT ( 0 C) NOT DETERMINED 

SOLUBILITY IN WATER (20 O C) NO 

% VOLATILE (BY VOL.) >85 

PH NOT AVAILABLE 

SECTION 4 FIRE AND EXPLOSION DATA 

FLAMMABILITY COMBUSTIBLE 

MEANS OF EXTINCTION SMALL FIRE: USE DRY CHEMICALS, CO2, WATER SPRAY OR FOAM. 

LARGE FIRE: USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER JET. 

SPECIAL PROCEDURES NOT AVAILABLE 

FLASHPOINT ( O C) AND METHOD THE LOWEST KNOWN VALUE IS CLOSED CUP: 46 0 C (114.9 0 F). (TAGLIABUE). (D-LIMONENE) 

UPPER EXPLOSION LIMIT (% BY VOL.) NOT AVAILABLE 

LOWER EXPLOSION LIMIT (% BY VOL.) NOT AVAILABLE 

HAZARDOUS COMBUSTION PRODUCTS THESE PRODUCTS ARE CARBON OXIDES (CO, CO 2). 

SECTION 5 REACTIVITY DATA 

CHEMICAL STABILITY STABLE 

INCOMPATIBILITY? TO WHAT? HIGHLY REACTIVE WITH OXIDIZING AGENTS, REDUCING AGENTS. VERY SLIGHTLY TO SLIGHTLY 

REACTIVE WITH ACIDS. 

HAZARDOUS DECOMPOSITION PRODUCTS THESE PRODUCTS ARE CARBON OXIDES (CO, CO 2) AND OTHER IRRITATING GASES. 

SECTION 6 TOXICOLOGICAL PROPERTIES 

ROUTE OF ENTRY SKIN CONTACT Y/N Y 

ROUTE OF ENTRY EYE CONTACT Y/N Y 

ROUTE OF ENTRY INHALATION Y/N Y 

ROUTE OF ENTRY INGESTION Y/N Y 

EFFECTS OF ACUTE EXPOSURE THIS PRODUCT MAY IRRITATE EYES AND SKIN UPON CONTACT. INFLAMMATION OF THE EYE IS 

CHARACTERIZED BY REDNESS, WATERING AND ITCHING. SLIGHTLY DANGEROUS TO DANGEROUS IN 

CASE OF INGESTION OR INHALATION. VERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE OF SKIN 

CONTACT (IRRITANT), OF EYE CONTACT (IRRITANT). NON-CORROSIVE FOR SKIN. 

EFFECTS OF CHRONIC EXPOSURE PROLONGED OR REPEATED EXPOSURE CAN CAUSE DRYING, DEFATTING AND DERMATITIS. CAN BE 

ABSORBED THROUGH SKIN IN TOXIC AMOUNTS IF CONTACT IS REPEATED AND PROLONGED. 

SYNERGISTIC MATERIALS NOT AVAILABLE 

CARCINOGENICITY Y/N N 

REPRODUCTIVE EFFECTS Y/N N 

TERATOGENCITY Y/N N 

MUTAGENICITY Y/N N 

SECTION 7 PREVENTIVE MEASURES 

GLOVES IMPERVIOUS GLOVES 

EYEWEAR SAFETY GLASSES 

FOOTWEAR AS REQUIRED BY EMPLOYER CODE 

CLOTHING AS REQUIRED BY EMPLOYER CODE 

ENGINEERING CONTROLS GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. 

LEAK AND SPILL PROCEDURE DILUTE WITH WATER AND MOP UP, OR ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN 

APPROPRIATE WASTE DISPOSAL CONTAINER. COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT. KEEP 

AWAY FROM SOURCES OF IGNITION. STOP LEAK IF WITHOUT RISK. ABSORB WITH DRY EARTH, SAND OR 

OTHER NON-COMBUSTIBLE MATERIAL. DO NOT TOUCH SPILLED MATERIAL. PREVENT ENTRY INTO 

SEWERS, BASEMENTS OR CONFINED AREAS; DIKE IF NEEDED. ELIMINATE ALL SOURCES OF IGNITION. 

WASTE DISPOSAL CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES. 

STORAGE REQUIREMENTS COMBUSTIBLE MATERIALS SHOULD BE STORED AWAY FROM EXTREME HEAT AND AWAY FROM STRONG 

OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE. GROUND 

ALL EQUIPMENT CONTAINING MATERIAL. A REFRIGERATED ROOM WOULD BE PREFERABLE FOR 

MATERIALS WITH A FLASH POINT LOWER THAN 37.8 0 C (100 0 F). 

SECTION 8 FIRST AID MEASURES 

SKIN REMOVE CONTAMINATED CLOTHES AS QUICKLY AS POSSIBLE, PROTECTING YOUR OWN HANDS AND BODY. PLACE THE VICTIM 

UNDER A DELUGE SHOWER. IF THE CHEMICAL TOUCHES THE VICTIM'S EXPOSED SKIN, SUCH AS THE HANDS: GENTLY AND 

THOROUGHLY WASH THE CONTAMINATED SKIN WITH RUNNING WATER AND NON-ABRASIVE SOAP. BE PARTICULARLY 

CAREFUL TO CLEAN FOLDS, CREVICES, CREASES AND GROIN. COLD WATER MAY BE USED. COVER THE IRRITATED SKIN WITH 

AN EMOLLIENT. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSING. 

EYE CHECK FOR AND REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 15 

MINUTES, KEEPING EYELIDS OPEN. COLD WATER MAY BE USED. DO NOT USE AN EYE OINTMENT. SEEK MEDICAL ATTENTION. 

INHALATION REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. 

INGESTION DO NOT INDUCE VOMITING. HAVE CONSCIOUS PERSON DRINK SEVERAL GLASSES OF WATER OR MILK. SEEK IMMEDIATE 

MEDICAL ATTENTION. 

VALIDATED BY BRODI SPECIALTY PRODUCTS LTD. ON 01/01/2009.. 

WHILE THE COMPANY BELIEVES THE DATA SET FORTH HEREIN ARE ACCURATE AS OF THE DATE HEREOF, THE COMPANY MAKES NO WARRANTY WITH RESPECT THERETO AND 

EXPRESSLY DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. SUCH DATA ARE OFFERED SOLELY FOR YOU CONSIDERATION, INVESTIGATION AND VERIFICATION.

CARBON STEEL ELECTRODE PROSTAR/ELECTRODE WELDING 

Material Safety Data Sheet 

SECTION I - Material Identity 

SECTION II - Manufacturer's Information 

SECTION III - Physical/Chemical Characteristics 

SECTION IV - Fire and Explosion Hazard Data 

SECTION V - Reactivity Data 

SECTION VI - Health Hazard Data 

SECTION VII - Precautions for Safe Handling and Use 

SECTION VIII - Control Measures 

SECTION IX - Label Data 

SECTION X - Transportation Data 

SECTION XI - Site Specific/Reporting Information 

SECTION XII - Ingredients/Identity Information 


Item Name 

Part Number/Trade Name CARBON STEEL ELECTRODE 

PROSTAR/ ELECTRODE WELDING 

National Stock Number 3439011686208 

CAGE Code AB168 

Part Number Indicator A 

MSDS Number 194367 

HAZ Code B 


Manufacturer Name SIDERGAS 

Street VIALE RIMEMBRANZA #17 37010 S 

City AMBROGIO (VERNON) 

Country IT 

Emergency Phone 800-424-9300 (CHEMTREC) 

MSDS Preparer's Information 

Date MSDS Prepared/Revised 01JAN00 

Active Indicator Y 

Alternate Vendors 

Page 1 of 4 

No Changes as of April 2011 

http://www.setonresourcecenter.com/msdshazcom/htdocs/COMMON/WCD0003E/WCD0... 

4/21/2011



Appearance/Odor WELDING ELECTRODE ROLL 

Boiling Point N/A 

Melting Point N/A 

Vapor Pressure N/A 

Specific Gravity 1 

Chemical pH N/A 

Container Pressure Code 1 

Temperature Code 4 

Product State Code S 


Flash Point Method UNK 

Lower Explosion Limit UK 

Upper Explosion Limit UK 

Extinguishing Media NON-FLAMMABLE 

Special Fire Fighting Procedures WELDING ARC AND SPARKS CAN 

IGNITE COMBUSTIBLE AND 

FLAMMABLE PRODUCTS 

Unusual Fire/Explosion Hazards SEE ABOVE 


Stability N/K 

Stability Conditions to Avoid UNKNOWN 

Materials to Avoid NONE LISTED 

Hazardous Decomposition Products CARBON MONOXIDE AND CARBON 

DIOXIDE, OZONE AND NITROGEN 

OXIDES MAY BE FORMED BY THE 

RADIATION FROM THE ARC 

Hazardous Polymerization UK 

Polymerization Conditions to Avoid NONE LISTED 


Health Hazards - Acute and Chronic ELECTRIC ARC WELDING MAY 

CREATE ONE OR MORE OF THE 

FOLLOWING HEALTH HAZARDS: 

FUMES AND GASES CAN BE 

DANGEROUS TO YOUR HEALTH. 

COMMON ENTRY IS INHALATION. 

SHORT TERM OVER EXPOSURE TO 

WELDING FUMES MAY RESULT IN 

DISCOMFORT SUCH AS DIZZINESS, 

NAUSEA, OR DRYNESS OR 

IRRITATION OF NOSE, THROAT, OR 


Page 2 of 4 

4/21/2011


EYES. LONG TERM MAY FEAD TO 

SIDEROSIS, AND AFFECT 

PULMONARY FUNCTION. ARC RAYS 

CAN INJURE EYES AND BURN SKIN. 

ELECTRIC SHOCK CAN KILL 

Carcinogenity: NTP UK 

Carcinogenity: IARC UK 

Carcinogenity: OSHA UK 

Explanation of Carcinogenity NONE LISTED 

Symptoms of Overexposure SEE ABOVE 

Medical Cond. Aggrevated by Exposure NONE LISTED 

Emergency/First Aid Procedures NONE LISTED 


Steps if Material Released/Spilled WILL NOT SPILL 

Waste Disposal Method IN ACCORDANCE WITH STATE, 

LOCAL, AND FEDERAL 

REGULATIONS 

Handling and Storage Precautions NONE LISTED 

Other Precautions NONE LISTED 


Respiratory Protection USE RESPIRABLE FUME RESPIRATOR 

OR AIR SUPPLIED RESPIRATOR 

WHEN WELDING IN CONFINED 

SPACES. OR GENERAL WORK AREA 

WHEN LOCAL EXHAUST OR 

VENTILATION DOES NOT KEEP 

EXPOSURE BELOW TLV 

Ventilation LOCAL EXHAUST 

Protective Gloves WELDERS GLOVES 

Eye Protection PROTECTIVE FACE SHIELD 

Other Protective Equipment ARM PORTECTORS, APRON, HATS, 

SHOULDER PROTECTION. EYEWASH 

Work Hygenic Practices WASH HAND AFTER HANDLING 

MATERIAL 


Protect Eye NO 

Protect Skin NO 

Protect Respiratory NO 

Chronic Indicator UNKNOWN 

Contact Code UNKNOWN 

Fire Code UNKNOWN 


Page 3 of 4 

4/21/2011


Health Code UNKNOWN 

React Code UNKNOWN 



Volatile Organic Compounds (P/G) 0 

Volatile Organic Compounds (G/L) 0 


Ingredient # 01 

Ingredient Name CARBON STEEL WIRE 

CAS Number 1003 

Percent 100 

OSHA PEL 10 MG/M3 

ACGIH TLV 10 MG/M3 


Ingredient Name (MNCPD) TOTAL MANGANESE 


Percent 2 

OSHA PEL 1.0 MG/M3 

ACGIH TLV 0.2 MG/M3 


Ingredient Name (CUCPD) COPPER 


Percent 0.5 




Ingredient Name IRON 


Percent 0 




Page 4 of 4 

4/21/2011

No change as of April 2011

No changes as of April 29, 2011

No Change May 2011

No changes as of April 29, 2011

No Changes as of April 29, 2011

53100CPL 


CGC Plasters - Basecoat and Gauging 

CGC Inc. 

350 Burnhamthorpe Rd. W., 5ème étage 

Mississauga, Ontario L5B 3J1 

(905) fax 803-5600 (905) 803-5688 

Une filiale de USG Corporation 

PRODUCT(S) CGC Plasters - Basecoat and Gauging 

CHEMICAL FAMILY / 

GENERAL CATEGORY 

SYNONYMS 

SECTION 1 

CHEMICAL PRODUCT AND IDENTIFICATION 

Construction Plasters 

Product Safety: 1 (800) 507-8899 

www.usg.com 

Version Date: January 1, 2011 

Version: 7 

Formulated product containing Plaster of Paris (Calcium Sulfate Hemihydrate) 

SECTION 2 

HAZARD IDENTIFICATION 

MSDS #53-100-CPL 

Page 1 of 8 

EMERGENCY OVERVIEW: 

WARNING! 

This product is not expected to produce any unusual hazards during normal use. Exposure to high dust levels may 

irritate the skin, eyes, nose, throat, or upper respiratory tract. 

POTENTIAL HEALTH EFFECTS (See Section 11 for more information) 

ACUTE : 

Inhalation 

Eyes 

Skin None known. 

Ingestion None known. 

CHRONIC: 

Inhalation 

Eyes None known. 

Skin None known. 

Ingestion None known. 

Exposure to dust generated during the handling or use of the product may cause temporary irritation 

to eyes, skin, nose, throat, and upper respiratory tract. Persons subjected to large amounts of this 

dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and 

nasal irritation. Labored breathing may occur after excessive inhalation. If respiratory symptoms 

persist, consult physician. 

Dust can cause temporary mechanical irritation of eyes. If burning, redness, itching, pain or other 

symptoms persist or develop, consult physician. 

Exposures to respirable crystalline silica are not expected during the normal use of this product; 

however, actual levels must be determined by workplace hygiene testing. Prolonged and repeated 

exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or 

lung cancer. The development of silicosis may increase the risks of additional health effects. The risk 

of developing silicosis is dependent upon the exposure intensity and duration. 

TARGET ORGANS: Eyes, skin and respiratory system.



PRIMARY ROUTES OF ENTRY: Inhalation, eyes and skin contact. 


Page 2 of 8 

CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S) All substances listed are associated with the nature of 

the raw materials used in the manufacture of this product and are not independent components of the product 

formulation. All substances, if present, are at levels well below regulatory limits. See Section 11: Toxicology 

Information for detailed information. 

MATERIAL IARC NTP ACGIH CAL- 65 

Crystalline silica 1 1 A2 Listed 

IARC - International Agency for Research on Cancer: 1- Carcinogenic to humans; 2A Probably carcinogenic to 

humans; 2B Possibly carcinogenic to humans; 3 - Not classifiable as a carcinogen; 4 Probably not a carcinogen 

NTP National Toxicology Program (Health and Human Services Dept., Public Health Service, NIH/NIEHS): 1- 

Known to be carcinogen; 2- Anticipated to be carcinogens 

ACGIH American Conference of Governmental Industrial Hygienists: A1 Confirmed human carcinogen; A2 

Suspected human carcinogen; A3 Animal carcinogen; A4 - Not classifiable as a carcinogen; A5 Not suspected as 

a human carcinogen 

CAL-65 

Respirable crystalline silica: IARC: Group 1 carcinogen, NTP: Known human carcinogen. The weight percent of 

crystalline silica given represents total quartz and not the respirable fraction. The weight percent of respirable silica 

has not been measured in this product. 

POTENTIAL ENVIRONMENTAL EFFECTS: Toxicity studies performed with fish, aquatic invertebrates and aquatic 

plants showed no toxic effect. (See Section 12 for more information.) 

SECTION 3 

COMPOSITION, INFORMATION ON INGREDIENTS 

MATERIAL WT% CAS # 

Expanded Perlite

Ingestion 




Page 3 of 8 

Plaster of paris hardens and, if ingested, may result in obstruction of the gut, especially the pyloric 

region. Drinking gelatin solutions or large volumes of water may delay setting. 

MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such 

as, but not limited to, bronchitis, emphysema and asthma. Pre-existing skin diseases such as, but not limited to, 

rashes and dermatitis. 

NOTES TO PHYSICIAN: Treatment should be directed at the control of symptoms and the clinical condition. 

SECTION 5 

FIRE FIGHTING MEASURES 

General Fire Hazards Not expected to burn. 

Extinguishing Media Water or use extinguishing media appropriate for surrounding fire. 

Special Fire Fighting Procedures Wear appropriate personal protective equipment. See section 8. 

Unusual Fire/ Explosion Hazards None known 

Hazardous Combustion Products 

Above 1450º C - decomposes to calcium oxide (CaO) and sulfur dioxide 

(SO2). 

Flash Point Not Determined Auto Ignition Not Applicable 

Method Used Not Applicable Flammability 

Upper Flammable Limit (UFL) Not Determined Classification 

Not Applicable 

Lower Flammable Limit (LFL) Not Determined Rate of Burning Not Applicable 

SECTION 6 

ACCIDENTAL RELEASE MEASURES 

CONTAINMENT: No special precautions. Wear appropriate personal protective equipment. See section 8. 

CLEAN-UP: Use normal clean up procedures. No special precautions. 

DISPOSAL: Follow all local, state, provincial and federal regulations. Never discharge large releases directly into 

sewers or surface waters. 

SECTION 7 

HANDLING AND STORAGE 

HANDLING: Avoid dust contact with eyes and skin. Wear the appropriate eye and skin protection against dust (See 

Section 8). Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory 

protection against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Use good safety and 

industrial hygiene practices. 

STORAGE: Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities (see 

Section 10). As a dry powder, dew point conditions or other conditions causing presence of liquid will harden plaster 

of paris during storage.



SECTION 8 

EXPOSURE CONTROLS/PERSONAL PROTECTION 


Page 4 of 8 

MATERIAL WT% TLV (mg/m 3 ) PEL( mg/m 3 ) 

Expanded Perlite



Evaporation Rate (BuAc = 1) Not Applicable Molecular Weight 

Upper Flammable Limit (UFL) Not Determined VOC Content Zero g/L 

Lower Flammable Limit (LFL) Not Determined Percent Volatile Zero 

Vapor Pressure (mm Hg) Not Applicable 

STABILITY Stable. 

SECTION 10 

CHEMICAL STABILITY AND REACTIVITY 

CONDITIONS TO AVOID Contact with acids, water, high humidity. 

INCOMPATIBILITY 

HAZARDOUS POLYMERIZATION None known. 


Page 5 of 8 

~ 145 g/mole (Plaster of 

Paris) 

Acids. Exposure to water and acids must be supervised because the 

reactions are vigorous and produce large amounts of heat. 

HAZARDOUS DECOMPOSITION Above 1450º C - calcium oxide (CaO) and sulfur dioxide (SO2). 

SECTION 11 

TOXICOLOGICAL INFORMATION 

ACUTE EFFECTS: The acute oral toxicity study [OECD TG 420] of calcium sulfate dihydrate showed that this 

chemical did not cause any changes even at 2,000 mg/kg b.w. Therefore, the oral LD50 value was more than 2,000mg/kg 

b.w. for female rats. Gypsum paste applied experimentally to the eyes of rabbits was not an irritant. Gypsum 

dust particulate has shown an irritant action on mucous membranes of the respiratory tract and eyes. The sulfate ion 

has caused gastro-intestinal disturbance in humans following large oral doses. Limited studies involving the repeated 

inhalation of an (unspecified) calcium sulfate failed to identify any particular target organs in monkeys, rats and 

hamsters. No evidence of mutagenicity was found in Ames bacterial tests. 

CHRONIC EFFECTS / CARCINOGENICITY: 

Plaster of Paris: Testing of dust from USG plaster of paris has not detected respirable crystalline silica. 

Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; 

however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline 

silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable 

crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may 

increase the risks of additional health effects. Smoking in combination with silica exposures increases the risk of 

cancer. The risk of developing silicosis is dependent upon the exposure intensity and duration. 

In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall 

evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial 

circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on 

external factors affecting its biological activity or distribution of its polymorphs. 

IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic 

to humans (Group 1).



SECTION 12 

ECOLOGICAL INFORMATION 


Page 6 of 8 

ENVIRONMENTAL TOXICITY: This product has no known adverse effect on ecology. Toxicity studies performed 

with fish, aquatic invertebrates and aquatic plants showed no toxic effect. 

Ecotoxicity value Not determined. 

SECTION 13 

DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL METHOD: Dispose of material in accordance with federal, state, and local regulations. Never 

discharge directly into sewers or surface waters. Consult with environmental regulatory agencies for guidance on 

acceptable disposal practices. Slurry may plug drains. Trace amounts of residue can be flushed to a drain, using 

plenty of water. 

SECTION 14 

TRANSPORT INFORMATION 

U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated. 

Shipping Name Same as product name. 

Hazard Class Not classified. 

UN/NA # None. Not classified. 

Packing Group None. 

Label (s) Required Not applicable. 

GGVSec/MDG-Code Not classified. 

ICAO/IATA-DGR Not applicable. 

RID/ADR None. 

ADNR None. 

UNITED STATES REGULATIONS 

Act Chemical Substance Inventory. 

SECTION 15 

REGULATORY INFORMATION 

MATERIAL WT% 

3 

0 

2 

3 

0 

4 

3 

1 

3



Expanded Perlite



INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS 


Page 8 of 8 

0 

1 0 

HEALTH * 

FLAMMABILITY 

PHYSICAL HAZARD 

PERSONAL PROTECTION 

1 

NFPA Ratings: 

Health: 1 

Fire: 0 

HMIS Ratings: 

Health: 1 

Fire: 0 

0 

1 

0 = Minimal Hazard 

1 = Slight Hazard 

2 = Moderate Hazard 

3 = Serious Hazard 

Reactivity: 0 Reactivity: 1 E 4 = Severe Hazard 

E Safety glasses, gloves and dust respirator; * - Contains silica 

Key/Legend 

ANSI American National Standards Institute 

ACGIH American Conference of Governmental Industrial Hygienists 

CAA Clean Air Act 

CAS Chemical Abstracts Service (Registry Number) 

CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980 

CFR Code of Federal Regulations 

DOT United States Department of Transportation 

DSL Canadian Domestic Substances List 

EPA United States Environmental Protection Agency 

EPCRA Emergency Planning & Community Right-to-know Act 

HMIS Hazardous Materials Identification System 

IARC International Agency for Research on Cancer 

MSHA Mine Safety and Health Administration 

NDSL Canadian Non-Domestic Substances List 



OSHA Occupational Health and Safety Administration 


PPE Personal Protection Equipment 

RCRA Resource Conservation and Recovery Act 

SARA Superfund Amendments and Reauthorization Act of 1986 



UN/NA# United Nations/North America number 

WHMIS 

Prepared by: 

Product Safety 

Workplace Hazardous Material Information System 

USG Corporation 

550 West Adams Street 

Chicago, IL 60661-3637 

The information contained in this document applies to this specific material as supplied. It may not be valid for this 

suitability and completeness of this information for his/her own particular use. 

END


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION 

Chevron SRI Grease 

Product Number(s): CPS254504, CPS254510 

Synonyms: Chevron SRI Grease NLGI 2, Chevron SRI Grease OEM NLGI 2 

Company Identification 

ChevronTexaco Global Lubricants 

6001 Bollinger Canyon Rd. 

San Ramon, CA 94583 

United States of America 

www.chevron-lubricants.com 

Transportation Emergency Response 

CHEMTREC: (800) 424-9300 or (703) 527-3887 

Health Emergenc y 

ChevronTexaco Emergency Information Center: Located in the USA. Internationalcollectcalls 

accepted. (800) 231-0623 or (510) 231-0623 

ProductInformation 

email : lubemsds@ chevron.com 

Product Information: (800) LUBE TEK 

MSDS Requests: (800) 414-6737 

SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS 

COMPONENTS CAS NUMBER AMOUNT 

Distillate s, hydro tre ate d he avy paraffinic 64742-54-7 65 - 90 %weight 

Po lyure a thic ke ne r Trade secret 3 - 10 %weight 

Additive s Mixture 1 - 5 %weight 

Zinc compounds Mixture 1-5%weight

SECTION 3 HAZARDS IDENTIFICATION 

IMMEDIATE HEALTH EFFECTS 

Eye: Notexpected to cause prolonged orsignificanteye irritation. 

Skin: Contactwith the skin is notexpected to cause prolonged orsignificantirritation. Contact 

with the skin is notexpected to cause an allergic skin response. Notexpected to be harmfulto 

internal organs if absorbed through the skin. High-Pressure Equipment Information: Accidental 

high-velocity injection under the skin of materials of this type may result in serious injury. Seek 

medical attention at once should an accident like this occur. The initial wound at the injection site 

may notappearto be serious atfirst; but, if leftuntreated, could resultin disfigurementor 

amputation of the affected part. 

Inges tio n: Not expected to be harmful if swallowed. 

Inhalation: Notexpected to be harmful if inhaled. Contains a petroleum-based mineraloil. May 

cause respiratory irritation orotherpulmonary effects following prolonged or repeated inhalation 

of oil mistatairborne levels above the recommended mineraloil mistexposure limit. Symptoms 

of respiratory irritation may include coughing and difficulty breathing. 


Eye: No specific firstaid measures are required. As a precaution, remove contactlenses, if 

worn, and flush eyes with water. 

Skin: No specific firstaid measures are required. As a precaution, remove clothing and shoes if 

contaminated. To remove the materialfrom skin, apply a waterless hand cleaner, mineral oil, or 

petroleum jelly. Then wash with soap and water. Discard contaminated clothing and shoes or 

thoroughly clean before reuse. 

Ingestion: No specific firstaid measures are required. Do notinduce vomiting. As a precaution, 

get medical advice. 

Inhalation: No specific firstaid measures are required. If exposed to excessive levels of material 

in the air, move the exposed person to fresh air. Getmedicalattention if coughing or respiratory 

discomfort occurs. 

No te to Physic ians: In an accident involving high-pressure equipment, this product may be 

injected under the skin. Such an accident may result in a small, sometimes bloodless, puncture 

wound. However, because of its driving force, material injected into a fingertip can be deposited 

into the palm of the hand. Within 24 hours, there is usually a greatdealof swelling, discoloration, 

and intense throbbing pain. Immediate treatment at a surgical emergency center is 

recommended. 

SECTION 5 FIRE FIGHTING MEASURES 

FIRE CLASSIFICATION:

OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible. 

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 

FLAMMABLE PROPERTIES: 

Flashpoint: (Cleveland Open Cup) 260 C (500 F) (Min) 

Autoignition: NDA 

Flammability (Explo sive) Limits (% by volume in air): Lower: NA Upper: NA 

EXTINGUISHING MEDIA: Use waterfog, foam, dry chemicalorcarbon dioxide (CO2) to 

extinguish flames. 

PROTECTION OF FIRE FIGHTERS: 

Fire Fighting Ins tructio ns: This material will burn although it is not easily ignited. Forfires 

involving this material, do not enter any enclosed or confined fire space without proper protective 

equipment, including self-contained breathing apparatus. 

Combustion Products: Highly dependenton combustion conditions. A complex mixture of 

airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified 

organic compounds willbe evolved when this materialundergoes combustion. Combustion may 

form oxides of: Nitrogen, Zinc, Magnesium . 

SECTION 6 ACCIDENTAL RELEASE MEASURES 

Protective Measures: Eliminate allsources of ignition in vicinity of spilled material. 

Spill Management: Stop the source of the release if you can do itwithoutrisk. Contain release 

to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as 

possible, observing precautions in Exposure Controls/PersonalProtection. Use appropriate 

techniques such as applying non-combustible absorbent materials or pumping. Where feasible 

and appropriate, remove contaminated soil. Place contaminated materials in disposable 

containers and dispose of in a manner consistent with applicable regulations. Clean up spills 

immediately, observing precautions in Exposure Controls/PersonalProtection section. 

Reporting: Reportspills to local authorities and/orthe U.S. CoastGuard's NationalResponse 

Center at (800) 424-8802 as appropriate or required. 

SECTION 7 HANDLING AND STORAGE 

General Handling Info rmatio n: Avoid contaminating soil or releasing this material into sewage 

and drainage systems and bodies of water. 

Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when 

handling this material. To minimize this hazard, bonding and grounding may be necessary but 

may not, by themselves, be sufficient. Review alloperations which have the potentialof 

generating an accumulation of electrostatic charge and/ora flammable atmosphere (including 

tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, 

mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For 

more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible 

Liquids', NationalFire Protection Association (NFPA 77, 'Recommended Practice on Static 

Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003,

Protection Against Ignitions Arising Outof Static, Lightning, and Stray Currents . 

Container Warnings: Container is notdesigned to contain pressure. Do notuse pressure to 

empty containeroritmay rupture with explosive force. Empty containers retain productresidue 

(solid, liquid, and/orvapor) and can be dangerous. Do notpressurize, cut, weld, braze, solder, 

drill, grind, orexpose such containers to heat, flame, sparks, static electricity, orothersources of 

ignition. They may explode and cause injury or death. Empty containers should be completely 

drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. 

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 

GENERAL CONSIDERATIONS: 

Considerthe potentialhazards of this material(see Section 3), applicable exposure limits, job 

activities, and other substances in the work place when designing engineering controls and 

selecting personal protective equipment. If engineering controls orwork practices are not 

adequate to preventexposure to harmful levels of this material, the personalprotective 

equipmentlisted below is recommended. The usershould read and understand all instructions 

and limitations supplied with the equipment since protection is usually provided for a limited time 

orundercertain circumstances. 

ENGINEERING CONTROLS: 

Use in a well-ventilated area. 

PERSONAL PROTECTIVE EQUIPMENT 

Eye/Face Protection: No special eye protection is normally required. Where splashing is 

possible, wearsafety glasses with side shields as a good safety practice. 

Skin Protection: No special protective clothing is normally required. Where splashing is 

possible, select protective clothing depending on operations conducted, physical requirements 

and othersubstances in the workplace. Suggested materials forprotective gloves include: 

Neoprene, Nitrile Rubber, SilverShield, Viton. 

Respiratory Protection: No respiratory protection is normally required. 

If useroperations generate an oilmist, determine if airborne concentrations are below the 

occupationalexposure limitformineral oilmist. If not, wearan approved respiratorthatprovides 

adequate protection from the measured concentrations of this material. Forair-purifying 

respirators use a particulate cartridge. 

Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators 

may notprovide adequate protection. 

Occ upatio nal Expo sure Limits: 

Component Limit TWA STEL Ceiling Notation 

Distillates, hydrotreated heavy 

paraffinic 

Distillates, hydrotreated heavy 

paraffinic 

ACGIH_TLV 5 mg/m3 10 mg/m3 

OSHA_PEL 5 mg/m3

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 

Attention: the data below are typical values and do not constitute a specification. 

Color: Green 

Physical State: Semi-solid 

Odor: Petroleum odor 

pH: NA 

Vapor Pressure: 1 

Boiling Point: >371.1 C (700 F) 

Solubility: Soluble in hydrocarbons; insoluble in water 

Melting Point: 215 C (419 F) (Min) 

Specific Gravity: 0.9 @ 20 C(68 F) / 20 C(68 F) 

Viscosity: 11.8 cSt @ 100 C (212 F) (Min) 

SECTION 10 STABILITY AND REACTIVITY 

Chemical Stability: This material is considered stable under normal ambient and anticipated 

storage and handling conditions of temperature and pressure. 

Incompatibility With Other Materials: May react with strong oxidizing agents, such as 

chlorates, nitrates, peroxides, etc. 

Hazardous Decomposition Products: None known (None expected) 

Hazardo us Po lymerizatio n: Hazardous polymerization will not occur. 

SECTION 11 TOXICOLOGICAL INFORMATION 

IMMEDIATE HEALTH EFFECTS 

Eye Irritation: The Draize eye irritation mean score in rabbits for a 24-hour exposure was: 

1.67/110. 

Skin Irritation: For a 4-hour exposure, the Primary Irritation Index (PII) in rabbits is: 1.3/8. 

Skin Sensitization: This material did not cause skin sensitization reactions in a Buehler guinea 

pig test. 

Acute Dermal Toxicity: LD50: >5g/kg (rat). 

Acute Oral Toxicity: LD50: >5 g/kg (rat) 

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for 

similarmaterials orproductcomponents.

ADDITIONAL TOXICOLOGY INFORMATION: 

This productcontains petroleum base oils which may be refined by various processes including 

severe solventextraction, severe hydrocracking, orsevere hydrotreating. None of the oils 

requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 

1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual 

Reportnorhave they been classified by the InternationalAgency forResearch on Cancer (IARC) 

as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly 

carcinogenic to humans (Group 2B). 

SECTION 12 ECOLOGICAL INFORMATION 

ECOTOXICITY 

The toxicity of this materialto aquatic organisms has notbeen evaluated. Consequently, this 

material should be keptoutof sewage and drainage systems and allbodies of water. 

ENVIRONMENTAL FATE 

This material is not expected to be readily biodegradable. 

SECTION 13 DISPOSAL CONSIDERATIONS 

Oil collection services are available forused oil recycling ordisposal. Place contaminated 

materials in containers and dispose of in a mannerconsistentwith applicable 

regulations. Contactyoursales representative orlocalenvironmental orhealth authorities for 

approved disposal or recycling methods. 

SECTION 14 TRANSPORT INFORMATION 

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate 

Dangerous Goods Regulations, foradditional description requirements (e.g., technical name) and 

mode-specific or quantity-specific shipping requirements. 

DOT Shipping Name: NOT REGULATED AS A HAZARDOUS MATERIAL FOR 

TRANSPORTATION UNDER 49 CFR 

DOT Hazard Class: NOT APPLICABLE 

DOT Identification Number: NOT APPLICABLE 

DOTPackingGroup:NOTAPPLICABLE 

Additio nal Informatio n: NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT 

APPLICABLE. 

IMO/IMDG Shipping Name: NOT REGULATED AS DANGEROUS GOODS FOR 

TRANSPORTATION UNDER THE IMDG CODE 

IMO/IMDG Hazard Clas s : NOT APPLICABLE

IMO/IMDG IdentificationNumber: NOT APPLICABLE 

IMO/IMDG Pac king Gro up: NOT APPLICABLE 

SECTION 15 REGULATORY INFORMATION 

SARA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO 

2. Delayed (Chronic) Health Effects: NO 

3. Fire Hazard: NO 

4. Sudden Release of Pressure Hazard: NO 

5. Reactivity Hazard: NO 

REGULATORY LISTS SEARCHED: 

4_I1=IARC Group 1 15=SARA Section 313 

4_I2A=IARC Group 2A 16=CA Proposition 65 

4_I2B=IARC Group 2B 17=MA RTK 

05=NTP Carcinogen 18=NJ RTK 

06=OSHA Carcinogen 19=DOT Marine Pollutant 

09=TSCA 12(b) 20=PA RTK 

The following components of this materialare found on the regulatory lists indicated. 

Zinc compounds 15 

CHEMICAL INVENTORIES: 

AUSTRALIA: This material contains components that require notification before sale or 

importation into Australia. 

CANADA: All the components of this material are on the Canadian DSL or have been notified 

under the New Substance Notification Regulations, but have not yet been published in the 

Canada Gazette. 

EUROPEAN UNION: Allthe components of this material are in compliance with the EUSeventh 

AmendmentDirective 92/32/EEC. 

JAPAN: This material contains components that require notification before sale or importation into

Japan. 

KOREA: This material contains components that require notification before sale or importation 

into Korea. 

PHILIPPINES: All the components of this productare listed on the Philippine Inventory 

of Chemicals and ChemicalSubstances (PICCS). 

UNITED STATES: Allof the components of this materialare on the Toxic Substances Control Act 

(TSCA) Chemical Inventory. 

NEW JERSEY RTK CLASSIFICATION: 

Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the 

productis to be identified as follows: PETROLEUMOIL (Grease) 

WHMIS CLASSIFICATION: 

This productis notconsidered a controlled productaccording to the criteria of the Canadian 

Controlled Products Regulations. 

SECTION 16 OTHER INFORMATION 

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0 

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- PersonalProtection Equipment Index 

recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or 

published evaluations prepared by the National Fire Protection Association (NFPA) orthe 

National Paint and Coating Association (for HMIS ratings). 

REVISIONSTATEMENT: This revision updates the following sections of this MaterialSafety 

Data Sheet: 1, 2, 7, 8, 14, 15 

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: 

TLV - Thre sho ld Limit Value TWA - Time Weighted Average 

STEL - Short-term Exposure Limit PEL - Pe rmissib le Exp o sure Limit 

CAS - ChemicalAbstractService Number 

NDA - No Da ta Ava ila b le NA - No t Ap p lic a b le 

= - GreaterThan o rEqual To

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the 

ANSI MSDS Standard (Z400.1) by the ChevronTexaco Energy Research &Technology 

Company, 100 Chevron Way, Richmond, California 94802. 

The above information is based on the data of which we are aware and is believed to be 

correct as of the date hereof. Since this information may be applied under conditions 

beyond our control and with which we may be unfamiliar and since data made available 

subsequent to the date hereof may suggest mo dificatio ns o f the info rmatio n, we do no t 

assume any responsibility for the results of its use. This information is furnished upon 

condition that the person receiving it shall make his own determination of the suitability of 

the material for his particular purpose.

Page 1 of 5 

Procter & Gamble 

PGP TN 6 

2 Procter & Gamble Plaza 

Cincinnati, OH 45202 


MSDS #: ICP119EE-2 Issue Date: 6/09 

Supersedes: ICP119EE Issue Date: August 21, 2006 

SECTION I - CHEMICAL PRODUCT 

Identity: Disinfectant Powder Cleanser 

Brands: COMET Disinfectant Cleanser with Chlorinol (Professional Line) 

Emergency Telephone Number: - 1-800-332-7787 or call Local Poison Control Center 

SECTION II – COMPOSITION AND INGREDIENTS 

Chemical Name Common Name CAS No. Composition 

Range 

LD50/LC50 

Calcium carbonate Limestone 471-34-1 60-100% NA/NA 

C10-C16 alkylbenzenesulfonic 

acid sodium salt 

1,3,5-Triazine- 

2,4,6(1H,3H,5H)-trione, 1,3dichloro-, 

sodium salt 

NaLAS 68081-81-2 1-5% 0.65-1.26 g/kg 

(oral/rats) 

Sodium 

Dichlorocyanurate 

2893-78-9 0.5-1.5% 0.735 g/kg 

(oral/rats) 

Calcium hydroxide Calcium hydroxide 1305-62-0 1-5% 7.34 g/kg 

(oral/rats) 

Carbonic acid, disodium salt Sodium carbonate 497-19-8 7-13% 1.86 g/kg 

(oral, rats) 

SECTION III - HAZARDS IDENTIFICATION 

Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) 

Ingestion: Mild mucous membrane irritant. May result in gastrointestinal irritation with nausea, 

vomiting and diarrhea. 

Eye Contact: Mild eye irritant. Direct contact with eye may result in superficial, temporary irritation similar 

to 

those produced by other household detergents. 

Skin: Mild skin irritant. Prolonged skin contact or direct contact with eye may result in superficial, 

temporary irritation similar to those produced by other household detergents. 

Inhalation: Mild respiratory irritant. Unusually high exposures may cause coughing or irritation of 

nose and throat. 

Signs and Symptons of Exposure: 

Ingestion: Ingestion of larger amounts leads to emesis. 

Eye Contact: Stinging and burning of eyes can occur unless flushed immediately with water. 

Skin: Mild irritation is possible with prolonged contact. 

Inhalation: Dust irritation is possible. 

Medical Conditions Generally Known to be Aggravated by Exposure: None known. 

Potential Environmental Effects: (See Section 12 for more information).

COMET Disinfectant Cleanser with Chlorinol MSDS (Continued) Page 2 of 5 

SECTION IV - FIRST AID INFORMATION 

Emergency and First Aid Procedures: 

Ingestion: Dilute with fluids and treat symptomatically. 

Eye Contact: For accidental eye contact, flush thoroughly with water for 15 minutes. 

Skin: Wash with soap and water and discontinue use. 

Inhalation: For accidental, high level inhalation, remove to fresh air. Get medical attention if coughing 

persists. 

Note to Physician: (if applicable) 

Other: Product package has a caution statement: CAUTION: KEEP OUT OF REACH OF CHILDREN. May 

cause eye irritation. In case of eye contact, flush thoroughly with water. If irritation persists, see a physician. 

If swallowed, drink a glass of water to dilute. Do not mix with other products especially toilet bowl cleansers 

and products that contain ammonia. 

SECTION V - FIRE FIGHTING INFORMATION 

Flash Point (Method Used): N/A 

Flammable Properties: 

Upper Flammable Limit: 

Lower Flammable Limit: 

Explosive Limits: UEL: N/A LEL: N/A 

Auto-ignition Temperature: 

Hazardous Combustion Products: 

Explosion Data (Sensitivity to Mechanil Impact): 

Explosion Data (Sensitivity to Static Discharge): 

Extinguishing Media: 

Suitable: Use CO2 , water, or dry chemical. 

Unsuitable: None known. 

Protection of Firefighters 

Specifi Hazards Arising from the Material: None known. 

Protective Equipment and Precautions for Firefighters: Normal firefighting gear. 

SECTION VI - ACCIDENTAL RELEASE MEASURES 

Personal Precautions: Recommendation is to wear gloves for handling/cleanup, and dust masks if considerable 

dust is airborn. 

Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, 

STATE/PROVINCIAL AND LOCAL REGULATIONS. Product contains biodegradable surfactant. If permitted, 

flush small quantities down sewer drain with large excess of water or dispose of at landfill. 

Methods for Containment: 

Methods for Cleanup: Vacuum to remove spill and place in trash container for disposal or flush with water. Do 

not dry sweep. 

Other Information: (if applicable) 

2


SECTION VII - HANDLING AND STORAGE 

Precautions To Be Taken in Handling: Keep product dry. 

Precautions To Be Taken in Storage: Avoid moisture when storing to prevent loss of bleaching action an dto 

prevent caking. 

SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION 

Exposure Guidelines: N/A 

Engineering Controls: N/A 

Personal Protective Equipment (PPE): 

Eye/Face Protection: None required with normal use. For splash protection, use chemical goggles. 

Skin Protection: Protective gloves (rubber, neoprene) should be used for prolonged direct contact 

Respiratory Protection: None required with normal use. For bulk handling or other dusty conditions, use 

respiratory protection approved by NIOSH for dust. 

Boiling Point F: N/A 

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES 

Flash Point (Method Used): N/A 

Odor: Cedar pine scent Reserve Alkalinity: N/A 

Odor Threshold: Solubility in Water: Moderately 

Physical State: powder Decomposition Temperature: N/A 

Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): N/A 

Vapor Density (Air=1): N/A Specific Gravity/Density: ca. 1 

Boiling Point: N/A Melting/Freezing Point: N/A 

Partition Coefficient (n-octanol/water): N/A pH (1% solution): N/A 

Chemical Stability: Stable 

Conditions to Avoid: None 

Incompatible Materials: Ammonia and acids 

Hazardous Decomposition Products: Chlorine gas 

Possibility of Hazardous Reaction: None known. 

SECTION X - STABILITY AND REACTIVITY 

4


SECTION XI - TOXICOLOGICAL INFORMATION 

Calcium carbonate, an ingredient of this product, contains small amounts of crystalline silica (quartz) as a naturally 

occurring impurity. Prolonged, excessively high exposures to respirable crystalline silica may result in reduced 

lung function in some individuals. IARC has found sufficient evidence to classify crystalline silica as a carcinogen 

in animals, but there is limited evidence in humans. 

LD50 (rats oral): 9 g/kg 

ED50: 0.23 g/kg 

Product as a whole: 

CARCINOGENICITY: None known 

SENSITIZATION EFFECTS: None known 

REPRODUCTIVE EFFECTS: None known 

SYNERGISTIC EFFECTS: None known 

SECTION XII - ECOLOGICAL INFORMATION 

No concerns at relevant environemental levels. 

SECTION XIII - DISPOSAL CONSIDERATIONS 

Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, 

STATE/PROVINCIAL AND LOCAL REGULATIONS. Product contains biodegradable surfactant. If permitted, 

flush small quantities down sewer drain with large excess of water or dispose of at landfill. 

Household Use: Household quantities may be disposed of via sewer. 

Industrial Setting: Dry product can be landfilled if local restrictions allow. 

SECTION XIV - TRANSPORT INFORMATION 

Ground Transport (DOT): The finished packaged product is non hazardous under DOT. 

Air Transport (IATA): The finished packaged product is not regulated for IATA. 

Marine/Water Transport (IMDG): The finished packaged product is not regulated for IMDG. 

SECTION XV - ADDITIONAL REGULATORY INFORMATION 

All intentionally-added components of this product are listed on the US TSCA Inventory. 

This product is not subject to warning labeling under California Proposition 65. 

All ingredients are CEPA approved for import to Canada by Procter & Gamble. 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products 

Regulation (CPR) and this MSDS contains all information required by the Canadian Products Regulation. 

5


SECTION XVI - OTHER INFORMATION 

P&G Hazard Rating: Health: 1 4=EXTREME 

Flammability: 0 3=HIGH 

Reactivity: 0 2=MODERATE 

1=SLIGHT 

0=NOT SIGNIFICANT 

*N/A. - Not Applicable *N/K. - Not Known 

Data supplied is for use only in connection with occupational safety and health. 

The information contained herein has been compiled from sources considered by Procter & Gamble to be 

dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific 

material designated herein, and does not relate to the use in combination with any other material or any other 

process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to 

any property resulting from misuse of the controlled product. 

6


Product Trade Name: COMPUCESSORIES POWER DUSTER 

Chemical Family: Ethane, 1,1-Difluoro 

FSP Model No: SPXL, SPJR, SPXL2 

Distributed by: S.P. Richards Company 

P.O. Box 1266 

Smyrna, GA 30081-1266 

Phone: 1-770-436-6881 

Chemical Manufacturer: Dupont 

Address: 1007 Market Street 

Wilmington, DE 19898 USA 

Phone: 1-800-441-7515 

Product Manufacturer: Falcon Safety Products, Inc. 

Address: 25 Imclone Drive 

Branchburg, NJ 08876 

Phone: 1-908-707-4900 

Emergency Telephone USA: (800) 498-7192 

2. Composition/Information on Ingredients 

Chemical Name Wt.%Range TLV Units 

1,1-Difluoroethane 100% 

CAS #75-37-6 

3. Hazard Identification 

Potential Health Effects: 


“Dymel” 152a – CAS#75-37-6 

(“DYMEL” is a registered trademark of DuPont) 

COMPU-CESSORY – POWER DUSTER 

Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness, or death. 

Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and 

is heavier than air. Liquid contact can cause frostbite. 

Human Health Effects: 

Higher exposures may lead to irritation of nose, throat, and lungs with cough, difficulty breathing or shortness of breath, 

temporary alteration of the heart’s electrical activity with irregular pulse, palpitations, or inadequate circulation, or abnormal 

kidney function as detected by laboratory tests. Gross overexposure may be fatal. 

Medical Conditions Aggravated by Exposure: 

Individual with preexisting diseases of the central nervous, cardiovascular system, lungs, or kidneys may have 

increased susceptibility to the toxicity of excessive exposures. 

Carcinogenicity Information 

None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA 

or ACGIH as a carcinogen.



“Dymel” 152a – CAS#75-37-6 


Inhalation: If high concentrations are inhaled, immediately remove to fresh air. Keep person calm. If not breathing, 

give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately. 

Skin Contact: Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not 

rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar 

covering. Get medical attention if symptoms persist. 

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes (in case of frostbite water should 

be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation. Get medical attention if symptoms 

persist. 

Ingestion: Ingestion is not considered a potential route of exposure. 

Notes to Physicians: 

Because of possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with 

special caution only in situations of emergency life support. 

5. Firefighting Measures 

Flash Point:



“Dymel” 152a – CAS#75-37-6 


Avoid breathing vapors or mist. Keep containers closed. Use only with adequate ventilation. Avoid repeated or prolonged contact 

with eyes, skin or clothing. Wash thoroughly after handling. Do not store in direct sunlight. Store in cool dry place, away from 

heat, sparks or flames which may generate toxic decomposition products. Vapors are heavy and may concentrate in low poorly 

ventilated areas. 


Engineering Controls: Ground all equipment and cylinders before use. Do not use near any spark producing electrical 

devices such as paper shredders. 

Respiratory Protection: Use only with adequate ventilation. Keep container closed. Use approved NIOSH self-contained or 

supplied air respirators for emergencies and in situations where air may be displaced by vapors. 

Eye Protection: Use chemical protective safety glasses. 

Protective Clothing: Where there is potential for skin contact, use appropriate impervious gloves, apron, pants and jacket. 

Exposure Guidelines: Applicable Exposure Limits. 

Difluoroethane: 

PEL (OSHA) None Established 

TLV (ACGIH) None Established 

AEL (DuPont) 1000 ppm, 8 Hr. TWA 

WEEL (AIHA) 1000 ppm, 8 Hr. TWA 

NFPA, NPCA-HIMIS RATING: 

Health 1 

Flammability 4 

Reactivity 1 

Personal Protection rating to be supplied by user depending on use conditions. 


Physical Form: Liquefied Gas 

Odor: Slight Ethereal 

Boiling Point: -25°C (-13°F) 

pH: Not Applicable 

Solubility in Water: 0.28 WT% @ 25°C (77°F) and 87 psia. 

Specific Gravity: 0.909 

% Volatile by Weight: 100 

Vapor Pressure: 87 psia at 25°C (77°F) 

Density: .90 g/cc at 25°C (77°F) - Liquid 

Vapor Density (air=1): 2.4 (Air = 1.0) at 25°C (77°F) 

Color: Clear, colorless 

10. Reactivity 

Chemical Stability: Material is stable. However, avoid open flames and high temperatures. 

Hazardous Polymerization: Will not occur. 

Incompatibilities: Incompatible with alkali or alkaline earth metal –powdered Al, Zn, Be, etc. 

Decomposition Products: Decomposition products are hazardous. This material can be decomposed by high temperatures 

forming hydrofluoric acid and possibly carbonyl fluoride


Animal Data: 


“Dymel” 152a – CAS#75-37-6 


Oral ALD: >1500 mg/kg in rats Inhalation ALC, 4 hr: 383,000 ppm in rats HFC-152a has not been tested for skin and eye 

irritancy, nor for animal sensitization. Ingestion of single high doses of HFC-152a caused weight loss and lethargy. 

Carcinogenicity: 

Inhalation of high levels of HFC-152a caused labored breathing, lung irritation, lethargy, incoordination and 

loss of consciousness. Cardiac sensitization occurred in dogs exposed to a concentration of 150,000 ppm in air and 

given an intravenous epinephrine challenge. Repeated inhalation exposures caused increased urinary fluoride, reduced kidney 

weight, and reversible kidney changes. Based on an independent peer review the reversible kidney changes are considered 

artifacts of the tissue and slide processing and not a compound related effect. Animal testing demonstrate no carcinogenic activity 

nor developmental effects. No animal data are available to define reproductive effects of HFC-152a. HFC-152a has not produced 

genetic damage in bacterial cultures. There are reports indicating that HFC-152a produced genetic damage in some mammalian 

cell culture tests. A weak genotoxic effect in germ cells of Drosophila melanogaster has been reported. It has not been tested in 

animals. 


Aquatic Toxicity: 

Not Available 


Waste Disposal: Reclaim by distillation, incinerate, or remove to a permitted waste facility. Comply with Federal, 

State, and local regulations. 

This material may be a RCRA Hazardous waste upon disposal due to the ignitability characteristic. 

14. Transportation Information 

Transport for Aerosol Packaging: 

Shipping Information 

DOT/IMO 

Proper Shipping Name : 1,1-DIFLUOROETHANE 

Hazard Class : 2.1 

UN No. : 1030 

DOT/IMO Label : FLAMMABLE GAS 

Special Information : CARGO AIRCRAFT ONLY 

NOTE: Falcon Safety Products has been granted a DOT exemption that allows this product to be shipped similar to a Consumer 

Commodity (ORM-D). A copy of the DOT exemption can be obtained by calling Falcon Safety Products, Inc at 908-707-4900. 



TSCA Inventory Status : Reported/Included. 

TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 

Acute : Yes 

Chronic : No 

Fire : Yes 

Reactivity : No

Regulatory Information continued………………………. 

Pressure : Yes 

LISTS: 

SARA Extremely Hazardous Substance -No 

CERCLA Hazardous Substance -(*) 

SARA Toxic Chemicals -No 

*See Disposal Information 


“Dymel” 152a – CAS#75-37-6 


"DYMEL" 152a is a flammable gas as defined by OSHA in 29CFR 1910.1200(c). Use of this product may require compliance 

with 29CFR 1910.119, Process Safety Management of Highly Hazardous Chemicals. 

This information must be included in all MSDSs that are copied and distributed for this material. 

California V.O.C. Data: This product contains 0 grams total VOC per liter. 


NFPA, NPCA-HMIS 

NPCA-HMIS Rating 

Health : 1 

Flammability : 4 

Reactivity : 1 

WHIMIS - Canada 

Class A - Compressed Gas 

Class B-1 - Flammable Gas 

CEPA DSL: difluoroethane 

Personal Protection rating to be supplied by user depending on use 

Falcon Safety Products, Inc. expressly disclaim all express or implied warranties for merchantability and fitness for a particular 

purpose, with respect to the product or information provided herein. 

All information appearing herein is based upon data obtained from the manufacturer. While the information is believed to be 

accurate, Falcon Safety Products, Inc. makes no representation as to its accuracy of sufficiency. Conditions of use are beyond 

Falcon Safety Products, Inc. control and therefore users are responsible to verify this data under their own operating conditions to 

determine whether the product is suitable for their particular purposes and they assume all risk of their use, handling and disposal 

of the product, or from the publication, or use of, or reliance upon, information contained herein. This information relates only to 

the product designated here and does not relate to its use in combination with any other material or in any other process. This 

information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and 

experience is gained. 

Dermot McLeer Technical Manager 08/28/09 

Signature Printed Name Title Revision Date

MATERIAL SAFETY DATA SHEET PAGE 1 of 2 

SECTION I - PRODUCT IDENTIFICATION AND PREPARATION INFORMATION 

PRODUCT NAME: CRETE EFFECTIVE DATE: January 1 st , 2009 

WHMIS CLASS: Acid Descaler CODE NO.: 7269 

Class E: Corrosive Material 

Class D - Division 2B 

T.D.G. CLASSIFICATION: Hydrochloric Acid Solution 

Class 8 UN 1789 PG: II 

MANUFACTURER NAME AND ADDRESS: BRODI SPECIALTY PRODUCTS LTD. 


MARKHAM, ONTARIO L3R 8E5 

(905) 475-6084 

MSDS PREPARED BY: MSDS CO-ORDINATOR, (877) 744-0751 EXT 205, BRODI SPECIALTY PRODUCTS LTD 

EMERGENCY PHONE: CANUTEC (613) 996 6666 


INGREDIENTS: CAS# WT% ACGIH-TLV LC50 LD50 

Hydrogen chloride 7647-01-0 10-30 5 ppm C 747 ppm/4Hr (Mouse) 700 mg/kg (Oral Rabbit) 

Formic acid 64-18-6 1-5 5 ppm TWA 6200 mg/m/15M(Oral Mouse) 1100 mg/kg (Oral Rat) 

SECTION III- PHYSICAL DATA 

BOILING POINT (DEG C): 105ºC (221ºF) SPECIFIC GRAVITY (H2O=1): 1.1 

VAPOUR PRESSURE (mm Hg): Not available PERCENT VOLATILE (WT%): 99 

VAPOUR DENSITY (AIR=1): Similar EVAPORATION RATE (Water=1): Similar 

SOLUBILITY IN WATER: Soluble PH (AS SUPPLIED):

PRODUCT NAME: CRETE CODE: 7269 PAGE 2 of 2 

SECTION V- REACTIVITY DATA 

CONDITIONS FOR CHEMICAL INSTABILITY: Stable 

INCOMPATIBILITY: Metals and Halogen compounds. 

HAZARDOUS DECOMPOSITION: Hydrogen, chlorine and fluoride gases. 

SECTION VI- TOXICOLOGICAL PROPERTIES 

ROUTE OF ENTRY: Skin contact, inhalation, ingestion 

EFFECTS OF ACUTE EXPOSURE: 

Very dangerous in case of skin contact (irritant, permeator), of eye contact (irritant), of inhalation. Corrosive to skin and eyes on 

contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. 

Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by 

coughing, choking or shortness of breath. This product may irritate eyes and skin upon contact. Inflammation of the eye is 

characterized by redness, watering and itching. Skin inflammation is characterized by itching, scaling, reddening or occasionally, 

blistering. 

EFFECTS OF CHRONIC EXPOSURE: 

SKIN: Prolonged or repeated exposure can cause drying, defatting and dermatitis. 

IRRITANCY: Hazardous by WHMIS criteria. 

RESPIRATORY TRACT SENSITIZATION: No data available 

CARCINOGENIC EFFECTS: Insufficient data available 

TERATOGENIC EFFECTS: Insufficient data available 

MUTAGENIC EFFECTS: Insufficient data available 

SYNERGISTIC MATERIALS: Not available 

SECTION VII-PREVENTATIVE MEASURES 

GLOVES: Gloves (impervious). 

EYE PROTECTION: Splash goggles. 

RESPIRATORY PROTECTION: If the TLV (50 ppm) of the product or any component is exceeded a NIOSH/MSHA jointly 

approved air supplied respirator is advised in the absence of proper environmental controls. 

OTHER PROTECTIVE EQUIPMENT: As required by employer codes. 

ENGINEERING CONTROLS: General ventilation is normally adequate. Use local exhaust for elevated temperature controls. 

LEAK AND SPILL PROCEDURE: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with 

no- reactive absorbent and placed in suitable, covered labeled containers. Prevent large spills 

from entering sewers or waterways. Contact emergency services and supplier for advice. 

WASTE DISPOSAL: Review federal, provincial and local government requirements prior to disposal. 

STORAGE REQUIREMENTS: Store in closed containers. Store away from incompatible materials. Ensure storage area has 

adequate ventilation. 

SECTION VIII- FIRST AID 

EYE: Immediately flush with water for 15 minutes. Call a doctor immediately. 

SKIN: Flush with soap and water. Call a doctor if irritation develops and persists. Completely decontaminate clothing, shoes and 

leather goods before reuse or discard. 

INHALATION: Remove to fresh air. If symptoms persist, call a doctor. 

INGESTION: Do not induce vomiting. Rinse mouth with water, then drink one or more glasses of water. Contact a doctor immediately. 

If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. 

Never give anything by mouth if victim is unconscious, is rapidly losing consciousness or is convulsing. 

DISCLAIMER: Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. No 

warranty, expressed or implied, is made and the supplier will not be liable for any losses, injuries or consequential damages, which may result 

from the use of or reliance on any information, contained in this form.

No Change April 18, 2011 

DEEP LUBE (Aerosol) Page 1 of 3 

MSDS Preparation Date: February 21, 2007 


======================================================================================= 

SECTION I - PRODUCT IDENTIFICATION 

======================================================================================= 

Product name: DEEP LUBE 

Chemical family: Aerosolized mixture. 

Product use/class: Used as a penetrant, and to lubricate and protect metal surfaces from corrosion 

Supplier’s name and address: Manufacturer’s name and address: 

DEEP LUBE OF CANADA Refer to Supplier. 

7 Hiscott St. 

St. Catharines, ON, L2R 1C7 

Telephone: 905-704-1158 

Emergency Tel. #: 905-651-1420 WHMIS CLASS: A, B5, D2B 

======================================================================================= 


======================================================================================= 

LC 50 / 4 Hrs LD 50 mg/kg 

Ingredients CAS# wt.% (Rat, inh.) (Oral, rat) (Rabbit, dermal) 

Aliphatic petroleum oil 8052-41-3 40 - 50 > 5500 mg/m 3 > 5000 > 3000 

Petroleum based oil 64742-65-0 40 - 50 N/Av > 5000 > 5000 

A70–Hydrocarbon propellant 68476-85-7 12 – 17 N/Av N/Ap N/Ap 

======================================================================================= 

SECTION III - PHYSICAL DATA 

======================================================================================= 

Physical State, odour and appearance: Light amber liquid aerosol, lemon odour. 

Coefficient of water/oil distribution: N/Av Odour threshold: N/Av 

Viscosity (Centistokes @ 40 o C): 7.06 (liquid concentrate) Specific gravity: 0.787 

Vapour pressure (PSI @ 70 o C): 60.0. Boiling point: N/Av 

Melting / Freezing point: N/Av pH: N/Av 

Vapour density (Air = 1): >1 Evaporation rate (BuAe = 1): N/Av 

Volatiles, %: 70.0 Solubility in water: Insoluble. 

Absolute pressure of container: 345 kPa @ 21.1 o C 

======================================================================================= 

SECTION IV - FIRE AND EXPLOSION DATA 

======================================================================================= 

Conditions of flammability: Flammable aerosol. 

Flash point (Method): 10 o C / 50 o F (TAG OPEN CUP A.S.T.M. D-1310) (liquid concentrate) 

Upper flammable limit %: 9.7 (liquid concentrate) 

Lower flammable limit %: 1.9 (liquid concentrate) 

Flame projection length: > 15 cm but < 100 cm. 

Flashback observed: No 

Auto-ignition temperature: N/Av 

Means of extinction: Use foam, carbon dioxide, dry chemical or water fog. Do not use water jet, as this may spread burning 

material. 

Sensitivity to mechanical impact/static discharge: May be sensitive to static discharge. Not expected to be sensitive to 

mechanical impact. 

Special Fire Fighting Procedures: Wear self-contained, positive pressure breathing apparatus (SCBA) and complete 

personal protective equipment. Move containers from fire area if it can be done without risk. Water spray may only be 

useful in cooling equipment exposed to heat and flame. Shield personnel to protect from venting or rupturing cans. 

Avoid spreading burning liquid with water spray used for cooling purposes. 

Unusual Fire and Explosion Hazards: Contents under pressure. Container may explode if heated. Vapours are heavier 

than air and collect in low-lying areas. The vapours may travel considerable distances and flashback to a distant source of 

ignition. Liquid concentrate may float and can be re-ignited at the water’s surface. 

Hazardous Combustion Products: Carbon oxides, sulfur oxides, nitrogen oxides, phosphorous oxides and other toxic and 

irritating fumes and smoke.



======================================================================================= 

SECTION V - REACTIVITY DATA 

======================================================================================= 

Stability: Stable under ambient pressure and temperature. Hazardous polymerization will not occur. 

Incompatible materials: Strong oxidizing agents. 

Conditions of reactivity: Stable under ambient pressure and temperature. Avoid heat, sparks, flame, and incompatible 

material. 

Hazardous decomposition products: None known. Refer to ‘Hazardous combustion products’, Section 4. 

======================================================================================= 

SECTION VI - TOXICOLOGICAL PROPERTIES 

======================================================================================= 

*** Routes of exposure and acute/chronic effects *** 

Exposure limit: 

ACGIH - TLV: Aliphatic petroleum oil (Stoddard solvent) – 100 ppm; Petroleum based oil – 5 mg/m 3 (As Oil mist, mineral); 

A70-Hydrocarbon propellant (L.P.G.) – 1000 ppm (As ‘Aliphatic hydrocarbon gases’). 

OSHA - PEL: Aliphatic petroleum oil (Stoddard solvent) – 500 ppm; Petroleum based oil – 5 mg/m 3 (As Oil mist, mineral).; 

A70-Hydrocarbon propellant (L.P.G.) – 1000 ppm. 

Inhalation: Inhalation may cause irritation to the nose, throat and upper respiratory tract. Symptoms may include headache, 

nausea, vomiting, dizziness, drowsiness and other symptoms of central nervous system depression. In extremely high 

concentrations, product may act as an asphyxiant and cause increased breathing and pulse rates, fatigue, nausea, 

vomiting and unconsciousness. 

Skin: Contact with liquid may cause mild to moderate irritation. If sprayed directly onto the skin, symptoms of frostbite 

may be experienced including numbness, prickling and itching. 

Eyes: Exposure to high vapor concentrations or contact with liquid may cause mild irritation. Symptoms may include 

tearing and redness. If product is sprayed directly into the eyes, contact could cause freezing of the eye. 

Ingestion: Ingestion is not a typical route of exposure for an aerosol. However, if the product is sprayed directly into 

mouth, it may cause irritation to the mouth, throat and stomach. Symptoms may include nausea, vomiting and diarrhea. 

Ingestion could cause aspiration of the chemical into the lungs. Aspiration can result in life-threatening lung injury. 

Chronic effect: Prolonged or repeated exposure may cause drying and cracking of the skin (dermatitis). 

Carcinogenicity: None of the ingredients are classified as carcinogenic by IARC or ACGIH. 

Reproductive effects, Teratogenicity, Mutagenicity: None known. 

Sensitization to material: Not expected to cause allergic skin or respiratory sensitization reactions. 

Synergistic materials: N/Av. 

Conditions aggravated by exposure: Pre-existing skin and respiratory disorders. 

======================================================================================= 

SECTION VII - FIRST AID 

======================================================================================= 

Inhalation: Remove patient from contaminated area. If breathing has stopped, give artificial respiration. If breathing is 

difficult, give oxygen by qualified medical personnel only. Obtain medical attention. 

Skin: Remove contaminated clothing. Wash skin thoroughly with mild soap and lukewarm, running water. Obtain 

medical attention if irritation persists. Launder contaminated clothing. 

Eyes: Immediately flush eyes with lukewarm water for at least 15 minutes. Obtain medical attention if irritation persists. 

Ingestion: If swallowed, do NOT induce vomiting. Obtain medical attention immediately! If vomiting occurs naturally, 

have victim lean forward to reduce the risk of aspiration into the lungs. Never give anything by mouth to an 

unconscious or convulsing person. 

======================================================================================= 

SECTION VIII - PREVENTIVE MEASURES 

======================================================================================= 

Spill, leak or release: Spill unlikely from aerosol cans. If leaks do occur, restrict access to spill area. Wear appropriate 

protective equipment. Eliminate all sources of heat, sparks, flame and ignition. Ventilate area of release. Leaking cans 

should be placed in plastic bag or open pail until pressure has dissipated. Absorb any spilled liquid concentrate with 

inert, non-combustible absorbent material (e.g. sand), then place absorbent material in a suitable, closed and labelled 

container for later disposal (see below). Do not allow to enter sewers or confined spaces. Notify the appropriate 

authorities as required. 

Waste disposal: Handle according to recommendations listed below. Do not puncture or incinerate cans. Improper disposal 

can cause damage to the environment. Dispose of in accordance with all applicable government Regulations.



======================================================================================= 

SECTION VIII - PREVENTIVE MEASURES CONTINUED 

======================================================================================= 

*** PROTECTIVE EQUIPMENT *** 

Respiratory protection: For prolonged exposures or if the TLV is exceeded, wear NIOSH-approved respirator. Advice 

should be sought from respiratory protection specialists. 

Ventilation: Use in well-ventilated area. General or local exhaust ventilation may be required. 

Protective gloves: Gloves impervious to the material are recommended. Advice should be sought from glove suppliers. 

Eye protection: Safety goggles are recommended to prevent mists from entering the eyes. 

Other protective equipment: An eyewash station and safety shower should be made available in the immediate working 

area. Impervious clothing and rubber boots, and any other safety equipment may also be required, as per workplace 

standards. 

*** STORAGE & HANDLING *** 

Storage and handling conditions: 

Handling: This material is a flammable, harmful aerosol. Wear protective equipment during handling. Use in well ventilated 

area. Avoid contact with eyes, skin and clothing. Avoid inhalation. Wearing contact lenses is inadvisable. Keep away 

from children. Do not use near sources of heat, flame, sparks or ignition sources. Ground all equipment during handling. 

Do not puncture or incinerate cans. Use caution when opening containers. Keep away from incompatibles. Keep the cap 

on the can when not in use, to protect the release valve. Wash thoroughly after handling. 

Storage: Store in a cool (less than 48.9 o C), dry, well-ventilated area away from incompatibles, heat and flame. No smoking in 

the area. Inspect containers periodically for damage or leaks. 

Special Shipping Information – Canadian Transportation of Dangerous Goods Regulations (TDGR): 

Proper Shipping Name: AEROSOLS 

UN No.: UN1950 

Primary Class(es): 2.1 

Subsidiary Class(es): None. 

Packing Group: Not applicable 

Other Shipping Information: This product may be shipped by ground within Canada, as a ‘Consumer commodity’ or a 

‘Limited Quantity’. Refer to the TDGR Section 1.17 for additional Limited Quantity and Consumer Commodity 

requirements, if shipping under this exemption. 

======================================================================================= 

SECTION IX - PREPARATION INFORMATION 

======================================================================================= 

Prepared by: ICC The Compliance Center Inc. for Deep Lube of Canada 

Telephone number: 905-704-1158 (Deep Lube of Canada) 

Preparation date: February 21, 2007. 

Additional notes or references: 

Abbreviations: 

ACGIH: American Conference of Governmental Industrial Hygienists 

A.S.T.M.: American Society for Testing and Materials 

CAS: Chemical Abstract Services 

IARC: International Agency for Research on Cancer 

inh: Inhalation 

N/Ap: not applicable 

N/Av: not available 

NIOSH: National Institute of Occupational Safety and Health 

OSHA: Occupational Safety & Health Administration 

PEL: Permissible Exposure Limit 

RTECs: Registry of Toxic Effects of Chemical Substances 

TLV: Threshold Limit Values 

WHMIS: Workplace Hazardous Materials Information System 

Reference: 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2006. 

2. International Agency for Research on Cancer Monographs, searched 2007. 

3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2007 (Chempendium and 

RTECs). 

4. Material Safety Data Sheet from manufacturer. 

END OF DOCUMENT


Product Trade Name: COMPUCESSORIES POWER DUSTER 

Chemical Family: Ethane, 1,1-Difluoro 

FSP Model No: SPXL, SPJR, SPXL2 

Distributed by: S.P. Richards Company 

P.O. Box 1266 

Smyrna, GA 30081-1266 

Phone: 1-770-436-6881 

Chemical Manufacturer: Dupont 

Address: 1007 Market Street 

Wilmington, DE 19898 USA 

Phone: 1-800-441-7515 

Product Manufacturer: Falcon Safety Products, Inc. 

Address: 25 Imclone Drive 

Branchburg, NJ 08876 

Phone: 1-908-707-4900 

Emergency Telephone USA: (800) 498-7192 

2. Composition/Information on Ingredients 

Chemical Name Wt.%Range TLV Units 

1,1-Difluoroethane 100% 

CAS #75-37-6 

3. Hazard Identification 



“Dymel” 152a – CAS#75-37-6 


COMPU-CESSORY – POWER DUSTER 

Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness, or death. 

Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and 

is heavier than air. Liquid contact can cause frostbite. 

Human Health Effects: 

Higher exposures may lead to irritation of nose, throat, and lungs with cough, difficulty breathing or shortness of breath, 

temporary alteration of the heart’s electrical activity with irregular pulse, palpitations, or inadequate circulation, or abnormal 

kidney function as detected by laboratory tests. Gross overexposure may be fatal. 

Medical Conditions Aggravated by Exposure: 

Individual with preexisting diseases of the central nervous, cardiovascular system, lungs, or kidneys may have 

increased susceptibility to the toxicity of excessive exposures. 

Carcinogenicity Information 

None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA 

or ACGIH as a carcinogen.



“Dymel” 152a – CAS#75-37-6 


Inhalation: If high concentrations are inhaled, immediately remove to fresh air. Keep person calm. If not breathing, 

give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately. 

Skin Contact: Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not 

rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar 

covering. Get medical attention if symptoms persist. 

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes (in case of frostbite water should 

be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation. Get medical attention if symptoms 

persist. 

Ingestion: Ingestion is not considered a potential route of exposure. 

Notes to Physicians: 

Because of possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with 

special caution only in situations of emergency life support. 

5. Firefighting Measures 

Flash Point:



“Dymel” 152a – CAS#75-37-6 


Avoid breathing vapors or mist. Keep containers closed. Use only with adequate ventilation. Avoid repeated or prolonged contact 

with eyes, skin or clothing. Wash thoroughly after handling. Do not store in direct sunlight. Store in cool dry place, away from 

heat, sparks or flames which may generate toxic decomposition products. Vapors are heavy and may concentrate in low poorly 

ventilated areas. 


Engineering Controls: Ground all equipment and cylinders before use. Do not use near any spark producing electrical 

devices such as paper shredders. 

Respiratory Protection: Use only with adequate ventilation. Keep container closed. Use approved NIOSH self-contained or 

supplied air respirators for emergencies and in situations where air may be displaced by vapors. 

Eye Protection: Use chemical protective safety glasses. 

Protective Clothing: Where there is potential for skin contact, use appropriate impervious gloves, apron, pants and jacket. 

Exposure Guidelines: Applicable Exposure Limits. 

Difluoroethane: 

PEL (OSHA) None Established 

TLV (ACGIH) None Established 

AEL (DuPont) 1000 ppm, 8 Hr. TWA 

WEEL (AIHA) 1000 ppm, 8 Hr. TWA 

NFPA, NPCA-HIMIS RATING: 

Health 1 


Reactivity 1 

Personal Protection rating to be supplied by user depending on use conditions. 


Physical Form: Liquefied Gas 

Odor: Slight Ethereal 

Boiling Point: -25°C (-13°F) 

pH: Not Applicable 

Solubility in Water: 0.28 WT% @ 25°C (77°F) and 87 psia. 

Specific Gravity: 0.909 

% Volatile by Weight: 100 

Vapor Pressure: 87 psia at 25°C (77°F) 

Density: .90 g/cc at 25°C (77°F) - Liquid 

Vapor Density (air=1): 2.4 (Air = 1.0) at 25°C (77°F) 

Color: Clear, colorless 

10. Reactivity 

Chemical Stability: Material is stable. However, avoid open flames and high temperatures. 


Incompatibilities: Incompatible with alkali or alkaline earth metal –powdered Al, Zn, Be, etc. 

Decomposition Products: Decomposition products are hazardous. This material can be decomposed by high temperatures 

forming hydrofluoric acid and possibly carbonyl fluoride


Animal Data: 


“Dymel” 152a – CAS#75-37-6 


Oral ALD: >1500 mg/kg in rats Inhalation ALC, 4 hr: 383,000 ppm in rats HFC-152a has not been tested for skin and eye 

irritancy, nor for animal sensitization. Ingestion of single high doses of HFC-152a caused weight loss and lethargy. 

Carcinogenicity: 

Inhalation of high levels of HFC-152a caused labored breathing, lung irritation, lethargy, incoordination and 

loss of consciousness. Cardiac sensitization occurred in dogs exposed to a concentration of 150,000 ppm in air and 

given an intravenous epinephrine challenge. Repeated inhalation exposures caused increased urinary fluoride, reduced kidney 

weight, and reversible kidney changes. Based on an independent peer review the reversible kidney changes are considered 

artifacts of the tissue and slide processing and not a compound related effect. Animal testing demonstrate no carcinogenic activity 

nor developmental effects. No animal data are available to define reproductive effects of HFC-152a. HFC-152a has not produced 

genetic damage in bacterial cultures. There are reports indicating that HFC-152a produced genetic damage in some mammalian 

cell culture tests. A weak genotoxic effect in germ cells of Drosophila melanogaster has been reported. It has not been tested in 

animals. 


Aquatic Toxicity: 

Not Available 


Waste Disposal: Reclaim by distillation, incinerate, or remove to a permitted waste facility. Comply with Federal, 

State, and local regulations. 

This material may be a RCRA Hazardous waste upon disposal due to the ignitability characteristic. 

14. Transportation Information 

Transport for Aerosol Packaging: 

Shipping Information 

DOT/IMO 

Proper Shipping Name : 1,1-DIFLUOROETHANE 

Hazard Class : 2.1 

UN No. : 1030 

DOT/IMO Label : FLAMMABLE GAS 

Special Information : CARGO AIRCRAFT ONLY 

NOTE: Falcon Safety Products has been granted a DOT exemption that allows this product to be shipped similar to a Consumer 

Commodity (ORM-D). A copy of the DOT exemption can be obtained by calling Falcon Safety Products, Inc at 908-707-4900. 



TSCA Inventory Status : Reported/Included. 

TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 

Acute : Yes 

Chronic : No 

Fire : Yes 

Reactivity : No

Regulatory Information continued………………………. 

Pressure : Yes 

LISTS: 

SARA Extremely Hazardous Substance -No 

CERCLA Hazardous Substance -(*) 

SARA Toxic Chemicals -No 

*See Disposal Information 


“Dymel” 152a – CAS#75-37-6 


"DYMEL" 152a is a flammable gas as defined by OSHA in 29CFR 1910.1200(c). Use of this product may require compliance 

with 29CFR 1910.119, Process Safety Management of Highly Hazardous Chemicals. 

This information must be included in all MSDSs that are copied and distributed for this material. 

California V.O.C. Data: This product contains 0 grams total VOC per liter. 


NFPA, NPCA-HMIS 

NPCA-HMIS Rating 

Health : 1 

Flammability : 4 

Reactivity : 1 

WHIMIS - Canada 

Class A - Compressed Gas 

Class B-1 - Flammable Gas 

CEPA DSL: difluoroethane 

Personal Protection rating to be supplied by user depending on use 

Falcon Safety Products, Inc. expressly disclaim all express or implied warranties for merchantability and fitness for a particular 

purpose, with respect to the product or information provided herein. 

All information appearing herein is based upon data obtained from the manufacturer. While the information is believed to be 

accurate, Falcon Safety Products, Inc. makes no representation as to its accuracy of sufficiency. Conditions of use are beyond 

Falcon Safety Products, Inc. control and therefore users are responsible to verify this data under their own operating conditions to 

determine whether the product is suitable for their particular purposes and they assume all risk of their use, handling and disposal 

of the product, or from the publication, or use of, or reliance upon, information contained herein. This information relates only to 

the product designated here and does not relate to its use in combination with any other material or in any other process. This 

information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and 

experience is gained. 

Dermot McLeer Technical Manager 08/28/09 

Signature Printed Name Title Revision Date


-1- 

SDS NO. 7989-I 




Product Name: ESAB MILD STEEL COVERED ELECTRODES 

Application: Arc Welding 

Classification: AWS A5.4 


Telephone No.: 1-717-637-8911, 1-800-933-7070 




Emergency Overview: Coated metal rods in varying colors. These products are normally not considered hazardous as shipped. 

Gloves should be worn when handling to prevent contaminating hands with product dust. 

These products contain titanium dioxide which is possibly carcinogenic. These products contain quartz, but normally not in an 

inhalable fraction. Quartz can cause silicosis and may cause cancer. 

Avoid eye contact or inhalation of dust from these products. Skin contact is normally no hazard but should be avoided to prevent 

possible allergic reactions. 

Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor and obtained 

information from the manufacturer of the device. 

When these products are used in a welding process, the most important hazards are heat, radiation, electric shock and welding 

fumes. 




Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. 





These products are preparations of core wire with extruded coating. 

Ingredients CAS# EINECS# 

Hazard 

classification (1) IARC (2) (3) 

NTP 

OSHA 

List (4) 

Aluminum Oxide 1344-28-1 215-691-6 No -- -- -- 

Calcium Carbonate 1317-65-3 215-279-6 No -- -- -- 

Calcium Fluoride 7789-75-5 232-188-7 No -- -- -- 

Cellulose 9004-34-6 232-674-9 No -- -- -- 

Iron and Iron Oxides 7439-89-6 231-096-4 No -- -- -- 

Manganese 7439-96-5 231-105-1 No -- -- -- 

Mineral Silicates All considered to be quartz 

Bentonite Clays 1302-78-9 215-108-5 No -- -- -- 

Chlorite 14808-60-7 238-878-4 T; R45 1 K -- 

Feldspar 14808-60-7 238-878-4 T; R45 1 K -- 

Hectorite 14808-60-7 238-878-4 T; R45 1 K -- 

Pyrropholite 14808-60-7 238-878-4 T; R45 1 K -- 

Wollanstanite 14808-60-7 238-878-4 T; R45 1 K -- 

Zircon 14808-60-7 238-878-4 T; R45 1 K -- 

Potassium Titanate 12030-97-6 234-748-6 No -- -- -- 

Silicate Binder (Potassium Silicate) 1312-76-1 215-199-1 No -- -- -- 

Silicate Binder (Sodium Silicate) 1344-09-8 215-687-4 No -- -- -- 

Silicon 7440-21-3 231-130-8 No -- -- --

Product Identity: ESAB MILD STEEL COVERED ELECTRODES 

-2- 




Hazard 


NTP 

OSHA 

List (4) 

Silicon Dioxide 14808-60-7 238-878-4 T; R45 1 K -- 

Sodium Titanate 12034-34-3 234-802-9 No -- -- -- 

Titanium Oxide 13463-67-7 236-675-5 No ## -- -- 

Zirconium Compounds -- -- No -- -- -- 

(1) 


(2) 



(3) 



(4) 

Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA). 

## Presently designated to become 2B with publication of monograph. 

Product Trade Name Mn CaCO3 CaF2 Si SiO2 

APPROXIMATE COMPOSITION (Wt. %) 

Silicate 

Binder 

TiO2 

Mineral 

Silicates 

Cellulose FexOy Al2O3 

ESAB 

6010 1-2 -- -- --


-3- 




No specific recommendations for welding consumables. Welding arcs and sparks can ignite combustible and flammable 

materials. Use the extinguishing media recommended for the burning materials and fire situation. Wear self-contained breathing 

apparatus as fumes or vapors may be harmful. 


Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a container. 

Wear proper protective equipment while handling these materials. Do not discard as refuse. 




Handling: 

Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to dust. Do not 

ingest. 


Storage: 

Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions. 


Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust. 

Engineering measures: 

Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and general area. 

Keep working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate 

conductive parts. Check condition of protective clothing and equipment on a regular basis. 

Personal protective equipment: 

Use respirator or air supplied respirator when welding or brazing in a confined space, or where local exhaust or ventilation is not 

sufficient to keep exposure values within safe limits. Use special care when welding painted or coated steels since hazardous 

substances from the coating may be emitted. Wear hand, head, eyes, ear and body protection like welders gloves, helmet or 

face shield with filter lens, safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry. 


following limits can be used as guidance. For information about welding fume analysis refer to Section 10. 

Substance CAS# ACGIH TLV (1) mg/m 3 

OSHA PEL (2) mg/m 3 

Aluminum Oxide (as Al) 1344-28-1 1** 15*, 5** 

Calcium Carbonate 1317-65-3 Withdrawn 15*, 5** 

Calcium Fluoride (as F) 7789-75-5 2.5 2.5 

Cellulose 9004-34-6 10 15*, 5** 

Iron and Iron Oxides 7439-89-6 5** 10 (fume) 

Manganese & 

Manganese compounds (as Mn) 

Mineral Silicates (no exposure anticipated) 

All substances with CAS of 14808-60-7 are quartz. 

7439-96-5 0.2 5 Ceiling 

Bentonite Clays 1302-78-9 None None 

Chlorite Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Feldspar Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Hectorite Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Pyrropholite Silica-Crystalline- 

14808-60-7 0.025** 10 mg/m 

Quartz 

3 ** 

%SiO2+2 

Wollanstanite Silica-Crystalline- 

14808-60-7 0.025** 10 mg/m 

Quartz 

3 ** 

%SiO2+2 

Zircon Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Potassium Titanate (powder) 12030-97-6 None None


-4- 





Silicate Binder (Potassium Silicate 

& Sodium Silicate) 

1312-76-1 

1344-09-8 

None None 

Silicon (nuisance dust) 7440-21-3 Withdrawn 15*, 5** 

Silicon Dioxide (quartz) 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Sodium Titanate (powder) 12034-34-3 None None 

Titanium Oxide 13463-67-7 10 15* 

Zirconium & Zirconium Compounds 7440-67-7 5 , 10 (STEL) 5 

(1) 


(2) 



* Total dust, ** Respirable fraction, *** Inhalable fraction. 

NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the COMPOSITION 

TABLE in Section 3. 


Appearance: Solid, non-volatile with varying color 

Melting point: >1300°C / >2300ºF 


General: These products are only intended for normal welding purposes. 

Stability: These products are stable under normal conditions. 

Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas. 

When these products are used in a welding process, hazardous decomposition products would include those from the volatilization, 

reaction or oxidation of the materials listed in Section 3 and those from the base metal and coating. 

The amount of fumes generated from manual metal arc welding varies with welding parameters and dimensions but is generally no more 

than 5 to 15 g/kg consumable. Fumes from these products may contain compounds of the following chemical elements: Fe, O, Mn, Zr, 

F, Na, Si, K, Ca, Al, Mg and Ti. The rest is not analyzed, according to available standards. 

Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in Section 

8. Manganese has a low exposure limit, in some countries, that may be easily exceeded. 

Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the welding 

area can be affected by the welding process and influence the composition and quantity of fumes and gases produced. 


Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult because of varying 



Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or irritation 

of the nose, throat or eyes. 

Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Overexposure to manganese and manganese 



disturbances and spastic gait. Inhalable quartz is a respiratory carcinogen; however, the process of welding converts 

crystalline quartz to the amorphous form which is not considered to be a carcinogen. 


Welding consumables and materials could degrade/weather into components originating from the consumables or from the materials 

used in the welding process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater. 


Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal and local 

regulations. Use recycling procedures if available. 

USA RCRA: These products are not considered hazardous waste if discarded. 

Residues from welding consumables and processes could degrade and accumulate in soils and groundwater. Welding slag from these 

products typically contain mainly the following components originating from the coating of the electrode: Fe, O, Mn, Zr, F, Na, Si, K, Ca, 

Al, Mg and Ti.


-5- 




No international regulations or restrictions are applicable. 



label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others. 

WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate ventilation. 




Canada: WHMIS classification: Class D; Division 2, Subdivision A 

Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic Substance List (DSL). 

USA: Under the OSHA Hazard Communication Standard, these products are considered hazardous. 

These products contain or produce a chemical known to the state of California to cause cancer and birth defects (or other 


United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or are 





Product is a solid solution in the form of a solid article. -- -- 


Response Center and to your Local Emergency Planning Committee. 


As shipped: Immediate In use: Immediate delayed 





Manganese 1.0% de minimis concentration 


This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. This SDS supersedes 7989-H. 

Refer to ESAB “Welding and Cutting - Risks and Measures”, F52-529 “Precautions and Safe Practices for Electric Welding and Cutting” 

and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and to: 



Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by Welding 

and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North Le Jeune 

Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org. 


371954, Pittsburgh, PA 15250-7954. 




Protection Association, 1 Batterymarch Park, Quincy, MA 02169.


-6- 



UK: WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of health and 

safety”. 



These products have been classified according to the hazard criteria of the CPR and the SDS contains all the information 


R-phrases: R45 – May cause cancer. 

ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product hazards and safety 

information. To promote safe use of these products a user should: 

- notify its employees, agents and contractors of the information on this SDS and any product hazards/safety information. 

- furnish this same information to each of its customers for these products. 


The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the conditions of use 

are outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied is 

given. Contact ESAB for more information.



Resinoid Bonded Abrasives 

MSDS #1/2 

Product Identity / Trade Name: Grinding and Cutting Wheels, Resinoid (Type 1, Type 27, Type 28, Type 29), 

Cup Wheels (Type 11) Cones and Plugs (Type 16, Type 17 and Type 18), 

Mounted Points, UA-MTX, UA-GFX, A36F, A54F. 

Product Use: Abrasive materials used for cutting and grinding metals, concrete, masonry and building materials. 

Manufacturer: Mailing Address Physical Address 

United Abrasives, Inc. United Abrasives, Inc. 

P.O. Box 75 185 Boston Post Road 

Willimantic, CT 06226 North Windham, CT 06256 

Internet: www.unitedabrasives.com 

Information Phone: (860) 456-7131 Emergency Phone: (860) 456-7131 

MSDS Date of Preparation: December 1, 2009 


This product is a black, brown or reddish colored solid wheel with no odor. 


Dust may cause eye and respiratory irritation. Dust particles may cause abrasive injury to the eyes. 


Hazardous Component CAS # % 

Aluminum Oxide 1344-28-1 0-95 

and/or Silicon Carbide 409-21-2 0-95 

and/or Zirconium Oxide 1314-23-4 0-80 

and/or Cubitron N/A 0-20 

and/or Titanium Dioxide 13463-67-7 0-5 

Cured Phenolic Resin N/A 1-30 

and/or Woven Fiberglass N/A 0-20 

and/or Calcium Carbonate 1317-65-3 0-5 

and/or Calcium Compounds N/A 0-15 

and/or Barium Sulfate 7727-43-7 0-15 

and/or Sulfur 7704-34-9 0-5 

and/or Zinc Sulfide 1314-98-3 0-15 

and/or Magnesium Oxide 1309-48-4 0-5 

and/or Iron Oxide 1309-37-1 0-5 

and/or Graphite 7782-42-5 0-5 

and/or Iron Pyrite 12068-85-8 0-20 

and/or Floride Compounds N/A 1-15 

and/or Potassium Fluoroborate 14075-53-7 0-5 

Chromic Acid 1308-38-9 0-2


Page 2 of 5 

United Abrasives MSDS #1/2 

Resinoid Bonded Abrasives (12/09) 

Ingestion: If grinding dust is swallowed, seek medical attention. 

Inhalation: If overexposed to grinding dust, remove victim to fresh air and get medical attention. 

Eye Contact: Flush eyes thoroughly with water, holding open eyelids. Get medical attention if irritation persists. 

Obtain immediate medical attention for foreign body in the eye. 

Skin Contact: Wash dust from skin with soap and water. Launder contaminated clothing before reuse. 


Extinguishing Media: Use any media that is appropriate for the surrounding fire. 

Special Firefighting Procedures: None needed. 

Unusual Fire and Explosion Hazards: This product is not combustible, however, consideration must be given to 

the potential fire/explosion hazards from the base material being processed. Many materials create 

flammable/explosive dusts or turnings when machined or ground. 

Hazardous Combustion Products: None known. 


Pick up, sweep up or vacuum and place in a container for disposal. Minimize generation of dust. Notify authorities as 

required by local, state and federal regulations. 


Recommended Work Practices: Use only with adequate ventilation. Avoid breathing dust. Wash thoroughly after 

handling and use, especially before eating, drinking or smoking. Refer to ANSI B7.1, Safety Requirements for the 

Use, Care and Protection of Abrasive Wheels for additional information. Consider potential exposure to components 

of the base materials or coatings being ground. Refer to OSHA’s substance specific standards for additional work 

practice requirements where applicable. 

Storage: Store in accordance with ANSI B7.1. Protect abrasive wheels from damage.


Page 3 of 5 



Exposure Guidelines: 

Hazardous Component OSHA PEL ACGIH TLV 

Aluminum Oxide 15 mg/m 3 (total dust) 1 mg/m 3 (respirable) (as Al metal) 

Silicon Carbide 15 mg/m 3 (total dust) 10 mg/m 3 (inhalable) 

Zirconium Oxide (as zircomium 

5 mg/m 

compounds) 

3 

5mg/m 3 

10 mg/m3 STEL 

Cubitron None Established None Established 

Titanium Dioxide 15 mg/m 3 (total dust) 10 mg/m 3 

Cured Phenolic Resin None Established None Established 

Woven Fiberglass 15 mg/m 3 (total dust) 1 f/cc 

Calcium Carbonate 15 mg/m 3 (total dust) None Established 

Calcium Oxide 5 mg/m 3 

2mg/m 3 

Barium Sulfate 15 mg/m 3 (total dust) 10 mg/m 3 

Sulfur None Established None Established 

Zinc Sulfide None Established None Established 

Magnesium Oxide 15 mg/m 3 (total dust) 10 mg/m 3 (inhalable) 

Iron Oxide 10 mg/m 3 (fume) 5 mg/m 3 (respirable) 

Graphite 15 mg/m 3 (total dust) 2 mg/m 3 (respirable) 

Iron Pyrite None Established None Established 

Cryolite (as fluorides) 2.5 mg/m 3 

2.5 mg/m 3 

Potassium Fluoroborate (as fluorides) 2.5 mg/m 3 

2.5 mg/m 3 

Note: Consider also components of base materials and coatings being ground. 

Ventilation: Use local exhaust or general ventilation as required to minimize exposure to dust and maintain the 

concentration of contaminants below the TLVs. 

Respiratory Protection: Use NIOSH approved respirator if exposure limits are exceeded or where dust exposures 

are excessive. Consider the potential for exposure to components of the coatings or base material being ground in 

selecting proper respiratory protection. Refer to OSHA’s specific standards for lead, cadmium, etc. where 

appropriate. Selection of respiratory protection depends on the contaminant type, form and concentration. Select 

and use respirators in accordance with OSHA 1910.134 and good industrial hygiene practice. 

Gloves: Cloth or leather gloves recommended. 

Eye Protection: Safety goggles or face shield over safety glasses with side shields. 

Other: Protective clothing as needed to prevent contamination of personal clothing. Hearing protection may be 

required. 


Boiling Point: Not Applicable Vapor Pressure: (mm Hg) Not Applicable 

Solubility in Water: Insoluble Vapor Density: (Air = 1) Not Applicable 

Specific Gravity: Not Applicable Evaporation Rate: Not Applicable 

Melting Point: Not Applicable Flash Point: Non-Combustible 

Flammable Limits: LEL: Not Applicable UEL: Not Applicable 

Appearance and Odor: Black, brown or reddish colored solid wheel with no odor.


Page 4 of 5 



Stability: Stable 

Incompatibility: None known. 

Hazardous Decomposition Products: Dust from grinding could contain ingredients listed in Section 3 and other, 

potentially more hazardous components of the base material being ground or coatings applied to the base material. 



HEALTH HAZARDS: 

Ingestion: None expected under normal use conditions. Swallowing large pieces may cause obstruction of the 

gastrointestinal tract. 

Inhalation: Dust may cause respiratory irritation. 

Eye: Dust may cause eye irritation. Dust particles may cause abrasive injury to the eyes. 

Skin: None expected under normal use conditions. Rubbing product across the skin may cause mechanical irritation 

or abrasions. 

Sensitization: This material is not known to cause sensitization. 

Chronic: Long-term overexposure to respirable dust may cause lung damage (fibrosis) with symptoms of coughing, 

shortness of breath and diminished breathing capacity. Chronic effects may be aggravated by smoking. Prolonged 

overexposure to fluorides may cause a bone condition, fluorosis. Prolonged exposure to elevated noise levels 

during operations may affect hearing. A greater hazard, in most cases, is the exposure to the dust/fumes from the 

material or paint/coatings being ground. Most of the dust generated during grinding is from the base material being 

ground and the potential hazard from this exposure must be evaluated. 

Carcinogenicity: Titanium Dioxide is listed by IARC as a group 2B Carcinogen (suspected human carcinogen). 

None of the other components is listed as a carcinogen or potential carcinogen by OSHA, NTP or IARC. 

Medical Conditions Aggravated by Exposure: Employees with pre-existing respiratory disease may be at risk 

from exposure. 

Acute Toxicity Values: 

This product and its components are not acutely toxic. The only acute toxicity data available for the components are 

listed below. 

Zinc Sulfide: LD50 oral rat >15,000 mg/kg 

LD50 dermal rat > 2 g/kg 

Cryolite: LD50 Oral rat >5g/kg 


No ecological data is available for this product. No hazards to the environment are expected from this product. 

However, consideration must be given to potential environment effects of the base material being processed. 


Dispose in accordance with all applicable local, state/provincial and federal regulations. Local regulations may be 

more stringent than regional and national requirements. It is the responsibility of the waste generator to determine 

the toxicity and physical characteristics of the material to determine the proper waste identification and disposal in 

compliance with applicable regulations.


DOT Hazardous Materials Description: 

Proper Shipping Name: Not Regulated 

UN Number: None 

Hazard Class/Packing Group: None 

Labels Required: None 


SARA Section 311/312 Hazard Categories: Not Applicable 

Page 5 of 5 



SARA Section 313: Some products contain the following toxic chemicals subject to the reporting requirements of 

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 (Toxic 

Chemical Release Reporting): 

Zinc Sulfide* 

(as zinc compounds) 

*Only in Type 29 Challenger Flexible Grinding/Blending Wheels 

1314-98-3 0-5% 

California Proposition 65: WARNING You create dust when you cut, sand, drill or grind materials such as wood, 

paint, cement, masonry or metal. This dust often contains chemicals known to cause cancer, birth defects or other 

reproductive harm. 

Canadian WHMIS Classification: Not a controlled product. This product meets the definition of a "manufactured 

article" under the WHMIS regulations. 

This product has been classified under the CPR and this MSDS discloses information elements required by the 

CPR. 


NFPA Hazard Rating: Health: 1 

Fire: 0 

Reactivity: 0 

Date Previous Revision: 12/13/06 

Date This Revision: 12/1/09 

Revision Summary: Section 5: Moved Flammable Limits to Section 9; Section 8: Updated Exposure Limits; 

Comprehensive Review 

Prepared By: Denese A. Deeds, CIH IH&SC Inc., Woodbridge, CT 06525 

The preceding information is believed to be correct and current as of the date of preparation of this Material Safety 

Data Sheet. Since the use of this information and the conditions of use of this product are not within the control of 

United Abrasives, Inc., it is the user’s obligation to assure safe use of this product.

Product Name: Helium MSDS No.: E-4602-K Date: Oct. 15, 2010 

Product Name: Helium 

Product Use: Many 

Chemical Name: Helium 



Trade Name: 

Synonym: 

Chemical Formula: He Chemical Family: (Rare Gas) Noble Gas 

Telephone: 

Emergencies: * 1-800-363-0042 

Supplier 

/Manufacture: 

Phone: 

Fax: 

Helium 

Helium-4 

Praxair Canada Inc. 

1 City Centre Drive 

Suite 1200 

Mississauga, ON L5B 1M2 

905-803-1600 

905-803-1682 



CAUTION! 



High-pressure gas. Can cause rapid suffocation. May cause dizziness and drowsiness. Selfcontained 

breathing apparatus may be required by rescue workers. Odour: None. 

ROUTES OF EXPOSURE: Inhalation. 

THRESHOLD LIMIT VALUE: TLV-TWA Data from 2007 Guide to Occupational Exposure Values (ACGIH). TLV-TWAs 

should be used as a guide in the control of health hazards and not as fine lines between safe and dangerous 

concentrations. 


INHALATION: 

SKIN CONTACT: 


SWALLOWING: 

EYE CONTACT: 

Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may cause 

headaches, drowsiness, dizziness, excitation, excess salivation, vomiting, and 

unconciousness. Lack of oxygen can kill. 

No harm expected. 


This product is a gas at normal temperature and pressure. 



None known. 


None known. 


Product Name: Helium MSDS# E-4602-K Date: Oct. 15, 2010 


Repeated or prolonged exposure is not known to aggravate medical condition. 


None currently known. 


Not listed as carcinogen by OSHA, NTP or IARC. 



NUMBER 

CONCENTRATION 

% by Mole 

Helium 7440-59-7 100 


INHALATION: 

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical 

attention immediately. 

SKIN CONTACT: 

Wash with soap and water. 

SWALLOWING: 


EYE CONTACT: 

Flush with water. 


There is no specific antidote. Treatment of over-exposure should be directed at the control of symptoms and the clinical 

condition. 



FLAMMABLE : IF YES, UNDER WHAT CONDITIONS? Not applicable. 

This product cannot catch fire. Use media appropriate for surrounding fire. 


None. 


CAUTION! High-pressure gas. Asphxiant. Effects are due to lack of oxygen. Evacuate all personnel from danger area. 

Immediately deluge cylinders with water from maximum distance until cool; then move them away from fire 

area if without risk. Self-contained breathing apparatus may be required by rescue workers. 


Gas cannot catch fire. Container may rutpure due to heat of fire. No part of a container should be subjected to a 

temperature higher than 52 C. Most containers are provided with a pressure relief device designed to vent contents 

when they are exposed to elevated temperature. 


Avoid impact against container. 


Not applicable. 




Firefighters should wear self-contained breathing apparatus and full fire-fighting turnout gear. 


FLASH POINT: Not applicable. 


LOWER: Not applicable. 

UPPER: Not applicable. 





CAUTION! High-pressure gas. Evacuate all personnel from danger area. Use self-contained breathing apparatus 

where needed. Shut off flow if you can do so without risk. Ventilate area or move cylinder to a wellventilated 

area. Test for sufficient oxygen, especially in confined spaces, before allowing reentry. 


Prevent waste from contaminating the surrounding environment. Keep personnel away. Discard any product, residue, 

disposable container, or liner in an environmentally acceptable manner, in full compliance with federal, provincial, and 

local regulations. If necessary, call your local supplier for assistance. 



Protect cylinders from damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Never 

attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. Never insert an object (e.g., wrench, 

screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap 

wrench to remove over-tight or rusted caps. Open valve slowly. If valve is hard to open, discontinue use and contact 

your supplier. For other precautions, see Section 16. 

For additional information on storage and handling, refer to Compressed Gas Association (CGA) pamphlet P-1, Safe 

Handling of Compressed Gases in Containers, available from the CGA. Refer to Section 16 for the address and phone 

number along with a list of other available publications. 


Store and use with adequate ventilation. Firmly secure cylinders upright to keep them from falling or being knocked 

over. Screw valve protection cap firmly in place by hand. Store only where temperature will not exceed 52 C. Store full 

and empty cylinders separately. Use a first-in, first-out inventory system to prevent storing full cylinders for long periods. 


High pressure gas. Use piping and equipment adequately designed to withstand pressures to be encountered. Gas 

can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve after 

each use; keep closed even when empty. Prevent reverse flow. Reverse flow into cylinder may cause rupture. Use a 

check valve or other protective device in any line or piping from the cylinder. When returning cylinder to supplier, be 

sure valve is closed, then install valve outlet plug tightly. Never work on pressurized system. If there is a leak, close 

the cylinder valve. Vent the system down in a safe and environmentally sound manner in compliance with all federal, 

provincial, and local laws; then repair the leak. Never place a compressed gas cylinder where it may become part 

of an electrical circuit. 




Additional information on storage, handling, and use of this product is provided in NFPA 55: Standard for the Storage, 

Use, and Handling of Compressed and Liquefied Gases in Portable Cylinders, published by the National Fire 

Protection Association. 

See also Praxair publication P-14-153, Guidelines for Handling Gas Cylinders and Containers. Obtain from your local 

supplier. 



Helium 7440-59-7 Not 

applicable. 





SPECIAL: 

OTHER: 

Use a local exhaust system, if necessary, to maintain an adequate supply 

of oxygen in the worker's breathing zone. 

Under certain conditions, general exhaust ventilation may be 

acceptable to control concentration of asphyxiant gases in the 

worker's breathing zone. 

None. 

None. 

RESPIRATORY PROTECTION: Use air supplied respirator when working in confined space or 

where local exhaust or ventilation does not keep exposure below 

the TLVs of welding fumes if welding with helium. Select in 

accordance with the provincial regulations or guidelines. 

Selection should also be based on the current CSA standards 

Z94.4, "Selection, care and use of respirators". Respirators 

should be approved by NIOSH and MSHA. 

SKIN PROTECTION: Wear work gloves when handling cylinders. 

EYE PROTECTION: Wear safety glasses when handling cylinders. 


(Species & 

Routes) 

(Rat, 4 

hrs.) 

Not 

available. 


Simple asphyxiant. 





Select in accordance with the current CSA standard Z94.3, 

"Industrial Eye and Face Protection", and any provincial 

regulations, local bylaws or guidelines. 

Metatarsal shoes for cylinder handling. Protective clothing where 

needed. Cuffless trousers should be worn outside the shoes. 

Select in accordance with the current CSA standard Z195, 

"Protective Foot Wear", and any provincial regulations, local 

bylaws or guidelines. 



PHYSICAL STATE: Gas. (Compressed Gas.) 

BOILING POINT 

SPECIFIC 

GRAVITY: 

LIQUID ( Water = 1) 

SPECIFIC 

GRAVITY: 

VAPOUR 

(air = 1) 

-268.9°C 

APPEARANCE & ODOUR: Colourless. 



VAPOUR 

PRESSURE 

-272 C 

Not applicable. SOLUBILITY IN 

WATER, 

Negligible. 

0.14 g/ml @21.1 C 

EVAPORATION 

RATE 

(Butyl Acetate=1): 

VAPOUR DENSITY: 0.000165 g/ml @21.1 C % VOLATILES BY 

VOLUME: 

Odourless. 



100% (v/v). 


pH: Not applicable. 



WATER/OIL 

DISTRIBUTION: 

4 g/mole 


ODOUR THRESHOLD: Odourless. 

STABILITY: 

The product is stable. 

CONDITIONS OF CHEMICAL INSTABILITY: None. 








None known. 

None currently known. Product is inert. 

None. 


Will not occur. 

None known. 

None known. 

Helium is a simple asphyxiant. The welding process may generate hazardous fumes and 

gases. (See section 16) 


No adverse ecological effects expected. This product does not contain any Class I or Class II ozone-depleting chemicals. 

The components of this mixture are not listed as marine pollutants by TDG Regulations. 


TDG/IMO SHIPPING NAME: Helium, Compressed 


Do not attempt to dispose of residual or unused quantities. Return cylinder to 

supplier. 




HAZARD CLASS: CLASS 2.2: 

Non-flammable 

and non-t o x i c 

gas. 

SHIPPING LABEL(s): Non-flammable, non-toxic gas 



IDENTIFICATION #: UN1046 PRODUCT RQ: 

Non-flammable, non-toxic gas 

Cylinders should be transported in a secure position, in a well-ventilated vehicle. Cylinders transported in an enclosed, 

nonventilated compartment of vehicle can present serious safety hazards. 


CLASS A: Compressed gas. 





This product is on the DSL list. 


EINECS: Not available. 

This product is not classified according to the EU regulations. 

DSCL (EEC): 

International Lists: No products were found. 


MIXTURES: 

When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, 

unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. 

Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. 

Remember, gases and liquids have properties which can cause serious injury or death. 


HMIS RATINGS: 

HEALTH 

FLAMMABILITY 


0 

0 

2 


THREADED: 

0 - 3000 psig CGA-580 

3001 - 5500 psig CGA-680 

5501 - 7500 psig CGA-677 


CGA-930 

ULTRA-HIGH-INTEGRITY CGA-716 

CONNECTION: 

Use the proper CGA connections. DO NOT USE ADAPTERS. Additional limited-standard connections may apply. 

See CGA pamphlets V-1 and V-7 listed below. 



Ask your supplier about free Praxair safety literature as referred to in this MSDS and on the label for this product. Further 

information about this product can be found in the following pamphlets published by the Compressed Gas Association, 

Inc. (CGA), 4221 Walney Road, 5th Floor, Chantilly, VA 20151-2923, Telephone (703) 788-2700, Fax (703) 961-1831, 

website: www.cganet.com. 

AV-1 Safe Handling and Storage of Compressed Gas 

G-9.1 Commodity Specification for Helium 

P-1 Safe Handling of Compressed Gases in Containers 

P-14 Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmosphere 

SB-2 Oxygen-Deficient Atmospheres 

SB-8 Use of Oxy-Fuel Gas Welding and Cutting Apparatus 

V-1 Compressed Gas Cylinder Valve Inlet and Outlet Connections 

V-7 Standard Method of Determining Cylinder Valve Outlet Connections for Industrial Gas Mixtures 

--- Handbook of Compressed Gases, Fourth Edition 

Praxair asks users of this product to study this MSDS and become aware of product hazards and safety information. To 

promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this 

MSDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of 

the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety 

information. 


DATE: 

DEPARTMENT: 

TELEPHONE: 

October 15, 2010 


905-803-1600 

The opinions expressed herein are those of qualified experts within Praxair Canada Inc. We believe that the information 

contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and the 

conditions of use of the product are not within the control of Praxair Canada Inc., it is the user's obligation to determine the 

conditions of safe use of the product. 

Praxair Canada Inc. requests the users of this product to study this Material Data Sheet (MSDS) and become aware of 

product hazards and safety information. To promote safe use of this product, a user should (1) notify its employees, 

agents and contractors of the information on this MSDS and any product hazards and safety nformation, (2) furnish this 

same information to each of its customers for the product, and (3) request such customers to notify their employees and 

customers for the product of the same product hazards and safety information. 

Other trademarks used herein are trademarks or registered trademarks of their respective owners. 


Praxair and the Flowing Airstream design are trademarks of 


Copyright © 2007, Praxair Technology, Inc. 

All rights reserved. 



Suite 1200 


Page 7 of 7


FOR 

KOOL KUT 24 B 

WHMIS – NOT CONTROLLED NOT CONTROLLED 

SECTION 1: PRODUCT IDENTIFICATION AND USE 

PRODUCT USE: CUTTING FLUID PRODUCT CODE: 6149B 

MANUFACTURER AND SUPPLIER: FORSYTHE LUBRICATION ASSOCIATES LTD. 

120 CHATHAM STREET 

HAMILTON, ONTARIO 

L8P 2B5 (905) 525-7192 

SECTION 2: HAZARDOUS INGREDIENTS 

ONLY THE INGREDIENTS PRECEDED BY A ** ARE CONTROLLED UNDER WHMIS 

% HAZARDOUS INGREDIENTS UN/CAS # LC 50 LD 50-ORAL LD 50-DERMAL 

(RATS) (RABBITS) 

>73.0 PETROLEUM OIL 64742-65-0, >5000 mg/kg 

64742-58-1 

192 (COC) AUTO IGNITION POINT C: NOT DETERMINED 

LOWER FLAMMABLE LIMIT (%VOL): NOT DETERMINED UPPER FLAMMABLE LIMIT (%VOL): NOT DETERMINED 

COMBUSTION PRODUCTS: OXIDES OF CARBON & SULPHUR, HYDROGEN SULFIDE & HYDROGEN CHLORIDE. 

No Change April 18, 2011 

SENSITIVITY TO IMPACT: NONE SENSITIVITY TO STATIC DISCHARGE: NOT DETERMINED 

SPECIAL PROCEDURES: TOXIC FUMES MAY BE EVOLVED ON BURNING OR EXPOSURE TO HEAT. USE WATERSPRAY TO COOL FIRE EXPOSED 

CONTAINERS AND AS A PROTECTIVE SCREEN.

PRODUCT CODE 06149 

SECTION 5: REACTIVITY DATA 

CHEMICAL STABIILTY? YES ( X ) CONDITIONS? CONDITIONS TO AVOID: HIGH TEMPERATURES 

NO ( ) 

INCOMPATIBILITY WITH YES ( X ) SPECIFY? STRONG OXIDIZING AGENTS AND HALOGENS 

OTHER PRODUCTS? NO ( ) 

REACTIVITY, UNDER WHAT CONDITIONS? NON REACTIVE 

Page 2 

HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, SULFUR, HYDROGEN SULFIDE, HYDROGEN CHLORIDE & CARBONYL 

CHLORIDE. 

SECTION 6: TOXICOLOGICAL PROPERTIES 

ROUTE OF ENTRY: SKIN ( X ) EYES ( X ) INHALATION ( ) INGESTION ( ) 

EFFECTS OF ACUTE EXPOSURE TO PRODUCT: 

CONTACT WITH EYES MAY CAUSE MILD IRRITATION. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD IRRITATION 

AND POSSIBLY DERMATITIS. LOW TOXICITY ON INGESTION HAS A LAXATIVE EFFECT. 

EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: 

NO FURTHER EFFECTS OF LONG-TERM EXPOSURE ARE EXPECTED. 

LD 50 – (ORAL) : >5,000 mg/kg EXPOSURE LIMITS: 5 mg/m3 (TLV/TWA), 10 mg/m3 (TLV/STEL) 

LD 50 – (DERMAL): NOT AVAILABLE IRRITANCY OF PRODUCTS: SLIGHT 

LC 50 – (INHALATION): NOT AVAILABLE 

SENSITIZATION: NON SENSITIZER MUTAGENICITY: NONE 

REPRODUCTIVE TOXICITY: NONE CARCINOGENICITY: NON CARCINOGENIC 

TERATOGENICITY: NON TERATOGENIC SYNERGISTIC PRODUCTS: NONE 

ADDITIONAL INFORMATION: THIS IS AN UNTESTED MIXTURE. THE TOXICOLOGICAL INFORMATION SUPPLIED IS BASED ON THE MOST 

HAZARDOUS INGREDIENT.

PRODUCT CODE 06149 

SECTION 7: PREVENTATIVE MEASURES 

Page 3 

PERSONAL PROTECTIVE EQUIPMENT: AVOID CONTACT WITH SKIN AND EYES. WEAR GOGGLES OR FACE SHIELD AND IMPERVIOUS GLOVES 

WHEN HANDLING. 

ENGINEERING CONTROLS: USE WITH ADEQUATE VENTILATION AND KEEP AIRBORNE CONCENTRATIONS WITHIN THE 

RECOMMENDED LIMITS. 

LEAK AND SPILL PROCEDURES: ABSORB RESIDUE WITH AN INERT ABSORBENT. SHOVEL INTO WASTE CONTAINER AND DISPOSE. 

PREVENT MATERIAL FROM ENTERING DRAINS, SEWERS OR WATERWAYS. ABSORB RESIDUE WITH 

AN INERT ABSORBENT. SHOVEL INTO WASTE CONTAINER AND DISPOSE. 

WASTE AND DISPOSAL: USE STANDARD WASTE DISPOSAL PROCEDURES IN ACCORDANCE WITH LOCAL, PROVINCIAL AND 

FEDERAL REGULATIONS. 

HANDLING PROCEDURES 

AND EQUIPMENT: DO NOT CONTAMINATE DOMESTIC OR IRRIGATION WATER SUPPLIES, LAKES, STREAMS, PONDS 

OR RIVERS. 

STORAGE REQUIREMENTS: STORE IN COOL, WELL VENTILATED AREA. 

SPECIAL SHIPPING INFORMATION: NOT REGULATED BY TDGR. 

SECTION 8: FIRST AID MEASURES 

EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. SEEK MEDICAL ADVICE IF IRRITATION DEVELOPS. 

SKIN CONTACT: WASH WITH PLENTY OF SOAP AND WATER. SEEK MEDICAL ADVICE IF IRRITATION DEVELOPS. REMOVE 

CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. 

INHALATION: REMOVE VICTIM TO FRESH AIR. 

ASPIRATION / INGESTION: DO NOT INDUCE VOMITING, SEEK MEDICAL ATTENTION. 

SECTION 9: PREPARATION DATE OF MSDS 

PREPARED BY : OPERATIONS REVISION DATE: DECEMBER 2008 

SUPERSEDES: JANUARY 2005 

WARRANTY: 

ALL TECHNICAL INFORMATION, RECOMMENDATIONS AND STATEMENTS CONTAINED HEREIN ARE BASED ON TESTS WE BELIEVE TO BE 

RELIABLE. IT IS OFFERED IN GOOD FAITH BUT WITHOUT GUARANTEE. WE MAKE NO WARRANTY EXPRESSED OR IMPLIED AS TO THE 

SUITABILITY OF OUR PRODUCT FOR ANY PARTICULAR USE IN OPERATIONS NOT UNDER OUR DIRECT CONTROL. LIABILITY IS LIMITED TO THE 

NET PURCHASE PRICE OF THE PRODUCT. THIS WARRANTY IS EXCLUSIVE OF ALL OTHER WARRANTIES EXPRESSED OR IMPLIED AND NO 

STATEMENT OR RECOMMENDATION NOT CONTAINED HEREIN SHALL APPLY UNLESS COVERED BY AGREEMENT SIGNED BY AUTHORIZED 

OFFICERS OF FORSYTHE LUBRICATION ASSOCIATES LTD. 

FORSYTHE LUBRICATION ASSOCIATES LTD. 

120 CHATHAM ST., HAMILTON, ONTARIO, CANADA L8P 2B5 

TEL: (905) 525-7192 FAX: (905) 525-7024

342 

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS 

% by Weight CAS Number Ingredient Units Vapor Pressure 

14 74-98-6 Propane 

ACGIH TLV 2500 PPM 760 mm 

OSHA PEL 1000 PPM 

13 106-97-8 Butane 



7 108-88-3 Toluene 


OSHA PEL 100 PPM (Skin) 

OSHA PEL 150 PPM (Skin) STEL 

1.0 100-41-4 Ethylbenzene 

ACGIH TLV 100 PPM 7.1 mm 

ACGIH TLV 125 PPM STEL 


OSHA PEL 125 PPM STEL 

6 1330-20-7 Xylene 





1 67-63-0 2-Propanol 




36 67-64-1 Acetone 




5 110-19-0 Isobutyl Acetate 



10 14807-96-6 Talc 

ACGIH TLV 2 mg/m3 as Resp. Dust 

OSHA PEL 2 mg/m3 as Resp. Dust 

1 471-34-1 Calcium Carbonate 

ACGIH TLV 10 mg/m3 as Dust 

OSHA PEL 15 mg/m3 Total Dust 

OSHA PEL 5 mg/m3 Respirable Fraction 


ROUTES OF EXPOSURE 

INHALATION of vapor or spray mist. 

EYE or SKIN contact with the product, vapor or spray mist. 

EFFECTS OF OVEREXPOSURE 

EYES: Irritation. 

SKIN: Prolonged or repeated exposure may cause irritation. 

INHALATION: Irritation of the upper respiratory system. 

HMIS Co des 

Health 2* 


Reactivity 0 

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. 

Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive 

systems. 

SIGNS AND SYMPTOMS OF OVEREXPOSURE 

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. 

Redness and itching or burning sensation may indicate eye or excessive skin exposure. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE 

None generally recognized. 

CANCER INFORMATION 

For complete discussion of toxicology data refer to Section 11. 

page 2 of 5

342 


EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 

SKIN: Wash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. 

INGESTION: Do not induce vomiting. Get medical attention immediately. 


FLASH POINT 

LEL UEL EXTINGUISHING MEDIA 

Propellant < 0 °F 

1.0 12.8 Carbon Dioxide, Dry Chemical, Foam 

UNUSUAL FIRE AND EXPLOSION HAZARDS 

Containers may explode when exposed to extreme heat. 

Application to hot surfaces requires special precautions. 

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately 

apparent. Obtain medical attention. 

SPECIAL FIRE FIGHTING PROCEDURES 

Full protective equipment including self-contained breathing apparatus should be used. 

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure 

build-up and possible autoignition or explosion when exposed to extreme heat. 


STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove all sources of ignition. Ventilate the area. 

Remove with inert absorbent. 


STORAGE CATEGORY 

Not Available 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE 

Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. 

During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off 

stoves, electric tools and appliances, and any other sources of ignition. 

Consult NFPA Code. Use approved Bonding and Grounding procedures. 

Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, 

and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. 


PRECAUTIONS TO BE TAKEN IN USE 

Use only with adequate ventilation. 

Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. 

Wash hands after using. 

This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels 

only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are 

ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). 

VENTILATION 

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. 

Refer to OSHA Standards 1910.94, 1910.107, 1910.108. 

RESPIRATORY PROTECTION 

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator 

approved by NIOSH/MSHA for protection against materials in Section 2. 

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this 

product, underlying paint, or the abrasive. 

PROTECTIVE GLOVES 

None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical 

resistant gloves. 

EYE PROTECTION 

Wear safety spectacles with unperforated sideshields. 

OTHER PRECAUTIONS 

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. 

page 3 of 5

342 


PRODUCT WEIGHT 6.49 lb/gal 777 g/l 


BOILING POINT

342 


ECOTOXICOLOGICAL INFORMATION 

No data available. 


WASTE DISPOSAL METHOD 

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. 

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. 

Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. 


US Ground (DOT) 

May be classed as Consumer Commodity, ORM-D 

UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) 

Canada (TDG) 


UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) 

IMO 

May be shipped as Limited Quantity 

UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U 


SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION 

CAS No. CHEMICAL/COMPOUND % by WT % Element 

108-88-3 Toluene 7 

100-41-4 Ethylbenzene 0.9 

1330-20-7 Xylene 6 

CALIFORNIA PROPOSITION 65 

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. 

TSCA CERTIFICATION 

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. 


This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the 

MSDS contains all of the information required by the CPR. 

The above info rmation pertains to this product as currently formulated, and is based on the info rmation available at this time. Addition of reducers or other 

additives to this pro duc t may s ubstantially alter the c o mpositio n and hazards o f the pro duc t. Sinc e c o nditio ns o f us e are o utside o ur c o ntro l, we make no 

warranties, express or implied, and assume no liability in c onnec tion with any use of this information. 

page 5 of 5

342 

02 00 



PRODUCT NUMBER 

342 

PRODUCT NAME 

KRYLON® Industrial TOUGH COAT Sandable Primer, Red Oxide 

MANUFACTURER'S NAME 

THE SHERWIN-WILLIAMS COMPANY 

KRYLON PRODUCTS GROUP 

Cleveland, OH 44115 

Telephone Numbers and Websites 

Product Information (800) 247-3266 

www.kpg-industrial.com 

Regulatory Information (216) 566-2902 

www.paintdocs.com 

Medical Emerg enc y (216) 566-2917 

Transportation Emergenc y* (800) 424-9300 

* 

for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) 

DATE OF PREPARATION 

Jun 30, 2009 

page 1 of 5

342 


% by Weight CAS Number Ingredient Units Vapor Pressure 

14 74-98-6 Propane 



13 106-97-8 Butane 



7 108-88-3 Toluene 


OSHA PEL 100 PPM (Skin) 

OSHA PEL 150 PPM (Skin) STEL 

1.0 100-41-4 Ethylbenzene 





6 1330-20-7 Xylene 





1 67-63-0 2-Propanol 




36 67-64-1 Acetone 




5 110-19-0 Isobutyl Acetate 



10 14807-96-6 Talc 

ACGIH TLV 2 mg/m3 as Resp. Dust 

OSHA PEL 2 mg/m3 as Resp. Dust 

1 471-34-1 Calcium Carbonate 

ACGIH TLV 10 mg/m3 as Dust 

OSHA PEL 15 mg/m3 Total Dust 

OSHA PEL 5 mg/m3 Respirable Fraction 


ROUTES OF EXPOSURE 

INHALATION of vapor or spray mist. 

EYE or SKIN contact with the product, vapor or spray mist. 

EFFECTS OF OVEREXPOSURE 

EYES: Irritation. 

SKIN: Prolonged or repeated exposure may cause irritation. 

INHALATION: Irritation of the upper respiratory system. 

HMIS Co des 

Health 2* 


Reactivity 0 

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. 

Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive 

systems. 

SIGNS AND SYMPTOMS OF OVEREXPOSURE 

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. 

Redness and itching or burning sensation may indicate eye or excessive skin exposure. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE 

None generally recognized. 

CANCER INFORMATION 

For complete discussion of toxicology data refer to Section 11. 

page 2 of 5

342 


EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 

SKIN: Wash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. 

INGESTION: Do not induce vomiting. Get medical attention immediately. 


FLASH POINT 

LEL UEL EXTINGUISHING MEDIA 

Propellant < 0 °F 

1.0 12.8 Carbon Dioxide, Dry Chemical, Foam 

UNUSUAL FIRE AND EXPLOSION HAZARDS 

Containers may explode when exposed to extreme heat. 

Application to hot surfaces requires special precautions. 

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately 

apparent. Obtain medical attention. 

SPECIAL FIRE FIGHTING PROCEDURES 

Full protective equipment including self-contained breathing apparatus should be used. 

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure 

build-up and possible autoignition or explosion when exposed to extreme heat. 


STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove all sources of ignition. Ventilate the area. 

Remove with inert absorbent. 


STORAGE CATEGORY 

Not Available 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE 

Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. 

During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off 

stoves, electric tools and appliances, and any other sources of ignition. 

Consult NFPA Code. Use approved Bonding and Grounding procedures. 

Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, 

and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. 


PRECAUTIONS TO BE TAKEN IN USE 

Use only with adequate ventilation. 

Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. 

Wash hands after using. 

This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels 

only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are 

ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). 

VENTILATION 

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. 

Refer to OSHA Standards 1910.94, 1910.107, 1910.108. 

RESPIRATORY PROTECTION 

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator 

approved by NIOSH/MSHA for protection against materials in Section 2. 

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this 

product, underlying paint, or the abrasive. 

PROTECTIVE GLOVES 

None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical 

resistant gloves. 

EYE PROTECTION 

Wear safety spectacles with unperforated sideshields. 

OTHER PRECAUTIONS 

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. 

page 3 of 5

342 


PRODUCT WEIGHT 6.49 lb/gal 777 g/l 


BOILING POINT

342 


ECOTOXICOLOGICAL INFORMATION 

No data available. 


WASTE DISPOSAL METHOD 

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. 

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. 

Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. 


US Ground (DOT) 


UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) 

Canada (TDG) 


UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) 

IMO 

May be shipped as Limited Quantity 

UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U 


SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION 

CAS No. CHEMICAL/COMPOUND % by WT % Element 

108-88-3 Toluene 7 

100-41-4 Ethylbenzene 0.9 

1330-20-7 Xylene 6 

CALIFORNIA PROPOSITION 65 

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. 

TSCA CERTIFICATION 

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. 


This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the 

MSDS contains all of the information required by the CPR. 

The above info rmation pertains to this product as currently formulated, and is based on the info rmation available at this time. Addition of reducers or other 

additives to this pro duc t may s ubstantially alter the c o mpositio n and hazards o f the pro duc t. Sinc e c o nditio ns o f us e are o utside o ur c o ntro l, we make no 

warranties, express or implied, and assume no liability in c onnec tion with any use of this information. 

page 5 of 5


Section 1: PRODUCT AND COMPANY INFORMATION 

Product Name(s): Lafarge Cold Patch Asphalt 


MSDS: Lafarge Cold Patch Asphalt 

Product Identifiers: Lafarge Cold Patch Asphalt (Cold Patch Asphalt), Hot Mix Cold Lay Asphalt, Cold 

Asphalt Paving Material, Cold Mix Asphaltic Concrete, Cold Mix Asphalt. 

Manufacturer: Information Telephone Number: 

Lafarge North America Inc. 703-480-3600 (9am to 5pm EST) 

12018 Sunrise Valley Drive, Suite 500 Emergency Telephone Number: 

Reston, VA 20191 1-800-451-8346 (3E Hotline) 

Product Use: Cold patch asphalt is used for repairing asphalt pavement, driveways, parking lots and 

other surface, base, or sub-base pavement applications. 

Note: This MSDS covers many types of cold patch asphalt. Individual composition of 

hazardous constituents will vary between types of asphalt. 

Section 2: COMPOSITION/INFORMATION ON INGREDIENTS 

Component 

Percent 

(By Weight) 

CAS 

Number 

OSHA PEL -TWA 

(mg/m 3 ) 

ACGIH TLV- 

TWA (mg/m 3 ) 

LD50 

(rat, oral) LC50 

Aggregate 90-95 Various NA NA NA NA 

Asphalt Cement (as Fume) < 10 8052-42-4 NA 0.5 NA NA 

#2 Fuel Oil (as Vapor & Aerosol) 0-5 68476-30-2 2000 100 (I) 12g/kg NA 

Kerosene (as Vapor) 0-5 8008-20-6 NA 200 15g/kg NA 

Crystalline Silica 

(as Quartz) 

varies 14808-60-7 

[(10) / (%SiO2+2)] (R); 

[(30) / (%SiO2+2)] (T) 

0.025 (R) NA NA 

Note: Cold patch asphalt is a mixture of gravel or rock, sand and asphalt cement. It may also contain small 

amounts of asphalt modifiers (e.g. anti-striping agents, hydrated lime), fly ash, slag, fibers (synthetic or 

organic), color pigment and other recycled material (e.g. ceramics, plastic, glass, etc.). 

Section 3: HAZARD IDENTIFICATION 

WARNING 

Toxic - Harmful by inhalation. 

(Contains crystalline silica) 

Irritant: Causes eye, skin and inhalation irritation 

Use proper engineering controls, work practices, 

and personal protective equipment. 

Read MSDS for details. 

Eye 

Protection 

Emergency Overview: Cold patch asphalt is a black colored granular solid that has a petroleum odor. 

Prolonged or repeated skin contact can cause drying of the skin which may produce 

irritation or dermatitis. If heated, hot product will cause severe thermal burns. When 

heated, this product may release toxic hydrogen sulfide (H 2S) vapors. 

Gloves 

Page 1 of 6 Revised: 03/01/11

Section 3: HAZARD IDENTIFICATION (continued) 



Eye Contact: Cutting, crushing or grinding hardened asphalt will release dust. Airborne dust may 

cause immediate or delayed irritation or inflammation. Eye contact with cold patch 

asphalt can cause moderate eye irritation, redness, and itching. Eye exposures 

require immediate first aid to prevent damage to the eye. If heated, hot product will 

cause severe thermal burns. 

Skin Contact: Cold patch asphalt may cause dry skin, discomfort, irritation, and dermatitis. 

Repeated contact may cause skin irritation from abrasion and asphalt cement. If 

heated, hot product will cause severe thermal burns. 

Inhalation (acute): Cutting, crushing or grinding hardened asphalt will release dust. Breathing dust may 

cause nose, throat or lung irritation, including choking, depending on the degree of 

exposure. When heated, cold patch asphalt may release irritating fumes or vapors 

such as smoke, carbon dioxide, carbon monoxide, unburned hydrocarbons. 

Hydrogen sulfide and other sulfur-containing gases can evolve from this product at 

elevated temperatures. Exposure to fumes or vapors may cause irritation of the 

nose and throat, and symptoms such as headache, dizziness, loss of coordination, 

and drowsiness. 

Inhalation (chronic): Risk of injury depends on duration and level of exposure. 

Silicosis: This product contains trace amounts of crystalline silica. Cutting, crushing or 

grinding hardened asphalt or other crystalline silica-bearing materials will release 

respirable crystalline silica. Prolonged or repeated inhalation of respirable crystalline 

silica from this product can cause silicosis, a seriously disabling and fatal lung 

disease. 

Carcinogenicity: Cold patch asphalt is not listed as a carcinogen by IARC or NTP; however, cold 

patch asphalt contains trace amounts of crystalline silica that is classified by IARC 

and NTP as known human carcinogen. 

Ingestion: Do not chew or ingest cold patch asphalt. Ingestion may result in nausea, vomiting, 

diarrhea and restlessness. Chewing asphalt has caused gastrointestinal effects. 

Stomach obstructions have been reported in individuals who have chewed and 

swallowed asphalt. 

Medical Conditions 

Aggravated by Exposure: 


Individuals with preexisting skin conditions can be aggravated by exposure. 

Eye Contact: For contact with cold patch asphalt, rinse eyes thoroughly with water for at least 15 

minutes. Seek medical attention. For contact with hot product, flush with large 

amounts of water for at least 15 minutes. Immediately call a physician. 

Skin Contact: Wash with cool water and a pH neutral soap or a mild skin detergent. Do not use 

solvents or thinners to remove product from skin. Seek medical attention for rash, 

irritation, and dermatitis. 

For contact with hot product, immerse or flush skin with cold water for at least 15 

minutes. Call a physician. Do not attempt to remove solidified product, since 

removal may cause further tissue injury. 


Section 4: FIRST AID MEASURES (continued) 


Inhalation: Move person to fresh air. Seek medical attention for discomfort or if coughing or 

other symptoms do not subside. 

Ingestion: Do not induce vomiting. If conscious, have person drink plenty of water. Seek 

medical attention or contact poison control center immediately. 

Section 5: FIREFIGHTING MEASURES 

Flashpoint & Method: NA 

General Hazard: Combustible solid. 

Avoid breathing fumes. 

Extinguishing Media: Use extinguishing media 

appropriate for surrounding 

fire. 

Upper/Lower 

NA 

Flammable Limit: 


Firefighting Equipment: A SCBA is recommended to 

limit exposures to combustion 

products when fighting any 

fire. 

Combustion Products: Toxic gases produced in fire, 

Auto-Ignition 

Temperature: NA 

such as CO, CO2, and H2S. 

General: Use a shovel to scrape up product and place it into suitable containers for recovery 

or disposal. Do not wash cold patch asphalt down sewage and drainage systems or 

into bodies of water (e.g. streams). Wear appropriate protective equipment as 

described in Section 8. 

Waste Disposal Method: Dispose of cold patch asphalt according to Federal, State, Provincial and Local 

regulations. 

Section 7: HANDLING AND STORAGE 

General: Cold patch asphalt is heavy and poses risks such as sprains and strains to the 

back, arms, shoulders and legs during lifting and mixing. Handle with care and use 

appropriate control measures. Do not stand on stockpiles of cold patch asphalt, they 

may be unstable. 

Usage: 

Cutting, crushing or grinding hardened asphalt or other crystalline silica-bearing 

materials will release respirable crystalline silica. Use all appropriate measures of 

dust control or suppression, and Personal Protective Equipment (PPE) described in 

Section 8 below. 

Avoid contact with skin, eyes and clothing. Use additional precautions when 

handling hot product. Maintain employee exposure levels below established 

regulatory limits. Do not allow hot product to contact skin. Use all appropriate 

Personal Protective Equipment (PPE) described in Section 8 below. 

Storage: Store in properly closed containers that are appropriately labeled and in a cool wellventilated 

area. Do not expose to heat, open flames, strong oxidizers or other 

source of ignition. 

Storage Temperature: Store away from heat, all ignition sources and open flames. 

Clothing: Remove and launder clothing that is soiled with asphalt. Thoroughly wash hands 

and exposed skin after exposure to cold patch asphalt. 


Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION 

Engineering Controls: 


Respiratory 

Protection: 


Under ordinary conditions, engineering controls are not required. Use local exhaust 

or general dilution ventilation when using at elevated temperatures or during 

activities that generate fumes, to maintain levels below exposure limits. 

Under ordinary conditions no respiratory protection is required. Wear a NIOSH 

approved respirator that is properly fitted and is in good condition when exposed to 

dust or fumes above exposure limits. 

Eye Protection: Wear ANSI approved glasses, safety goggles, or face shield when handling cold 

patch asphalt to prevent contact with eyes. 

Skin Protection: Wear leather or cloth work gloves to prevent skin contact and insulated gloves when 

handling hot product. Thoroughly wash hands and other exposed skin after 

exposure to cold patch asphalt. 

Foot Protection: Wear ANSI approved hard-toed safety boots when handling cold patch asphalt. 


Physical State: Granular solid. Evaporation Rate: NA. 

Appearance: Black solid. pH (in water): NA. 

Odor: Slight petroleum odor. Boiling Point: NA. 

Vapor Pressure: NA. Freezing Point: NA. 

Vapor Density: NA. Viscosity: NA. 

Specific Gravity: NA. Solubility in Water: Insoluble 


Stability: Stable. Avoid contact with incompatible materials, excessive heat, sources of 

ignition and open flame. 

Incompatibility: Cold patch asphalt is incompatible with strong acids or bases, and oxidizing agents 

such as nitrates, chlorates and peroxides. 

Hazardous Polymerization: None. 

Hazardous Decomposition: When heated may liberate hydrogen sulfide and various hydrocarbons. 

Section 11 and 12: TOXICOLOGICAL AND ECOLOGICAL INFORMATION 

For questions regarding toxicological and ecological information refer to contact information in Section 1. 


Dispose of waste and containers in compliance with applicable Federal, State, Provincial and Local regulations. 

Section 14: TRANSPORT INFORMATION 

This product is not classified as a Hazardous Material under U.S. DOT or Canadian TDG regulations. 


Section 15: REGULATORY INFORMATION 

OSHA/MSHA Hazard 

Communication: 


This product is considered by OSHA/MSHA to be a hazardous chemical and should 

be included in the employer's hazard communication program. 

CERCLA/SUPERFUND: This product is not listed as a CERCLA hazardous substance. 

EPCRA SARA Title III: This product has been reviewed according to the EPA Hazard Categories 

promulgated under Sections 311 and 312 of the Superfund Amendment and 

Reauthorization Act of 1986 and is considered to be an acute health hazard 

(irritation). 

EPRCA SARA 

This product contains none of the substances subject to the reporting requirements 

Section 313: 

of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 

1986 and 40 CFR Part 372. 

RCRA: If discarded in its purchased form, this product would not be a hazardous waste 

either by listing or characteristic. However, under RCRA, it is the responsibility of 

the product user to determine at the time of disposal, whether a material containing 

the product or derived from the product should be classified as a hazardous waste. 

TSCA: This product and/or its components are listed on the Toxic Substances Control Act 

(TSCA) inventory. 

California Proposition Crystalline silica (airborne particulates of respirable size) is a substance known by 

65: 

the State of California to cause cancer. 

WHMIS/DSL: Products containing crystalline silica are classified as D2A and are subject to 

WHMIS requirements. 



> Greater than NA Not Applicable 

< Less than NFPA National Fire Protection Association 

ACGIH American Conference of Governmental 

Industrial Hygienists 

CAS No Chemical Abstract Service number 

Comprehensive Environmental 

CERCLA Response, Compensation and Liability 

Act 

NIOSH 

National Institute for Occupational Safety 

and Health 

NTP National Toxicology Program 

OSHA 

Occupational Safety and Health 

Administration 

CFR Code for Federal Regulations PEL Permissible Exposure Limit 

CL Ceiling Limit pH Negative log of hydrogen ion 

DOT U.S. Department of Transportation PPE Personal Protective Equipment 

EST Eastern Standard Time R Respirable Particulate 

HEPA High-Efficiency Particulate Air RCRA Resource Conservation and Recovery Act 

HMIS 

Hazardous Materials Identification 

System 

SARA 

Superfund Amendments and 

Reauthorization Act 

IARC 

International Agency for Research on 

Cancer 

T 

TDG 

Total Particulate 

Transportation of Dangerous Goods 

LC50 Lethal Concentration TLV Threshold Limit Value 

LD50 Lethal Dose TWA Time Weighted Average (8 hour) 

mg/m 3 

MSHA 

Milligrams per cubic meter 

Mine Safety and Health Administration 

WHMIS 

Workplace Hazardous Materials 

Information System 


Section 16: OTHER INFORMATION (continued) 


This MSDS (Sections 1-16) was revised on March 1, 2011. 

An electronic version of this MSDS is available at: www.lafarge-na.com under the Sustainability section. 

Lafarge North America Inc. (LNA) believes the information contained herein is accurate; however, LNA makes no 

guarantees with respect to such accuracy and assumes no liability in connection with the use of the information 

contained herein which is not intended to be and should not be construed as legal advice or as insuring 

compliance with any federal, state or local laws or regulations. Any party using this product should review all such 

laws, rules, or regulations prior to use, including but not limited to US and Canada Federal, Provincial and State 

regulations. 

NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR 

PURPOSE, OR OTHERWISE. 




Product Name(s): Lafarge Hot Mix Asphalt (HMA) 

MSDS: Lafarge Hot Mix Asphalt 

Product Identifiers: Lafarge Hot Mix Asphalt, HMA, Hot Mix Asphalt Concrete (HMAC), Blacktop, Tarmac, 

Hot Mix Paving Material, Hot Laid Asphaltic Cement, Bituminous Concrete, 

SuperPave Mixes, DuraPhaltTM, DuraPhaltTM HM, DuraWay TM , DuraTough TM , 

DuraPlay TM , DuraTint TM , DuraWhisper TM , DuraCycle TM , DuraClime TM , Dense Friction 

Course (DFC), Heavy Duty Binder Course (HDBC), Medium Duty Binder Course 

(MDBC), Open Friction Course (OFC), Stone Matrix Asphalt (SMA). 





Product Use: HMA is used for paving roads, driveways, parking lots and other surface, base, or 

sub-base applications. 

Note: This MSDS covers many types of HMA. Individual composition of hazardous 

constituents will vary between types of asphalt. 


Component 

Percent 

(By Weight) 

CAS 

Number 

OSHA PEL -TWA 

(mg/m 3 ) 

ACGIH TLV- 

TWA (mg/m 3 ) 

LD50 

(rat, oral) LC50 

Aggregate 90-95 Various NA NA NA NA 

Asphalt Cement (as Fume) < 10 8052-42-4 NA 0.5 (I) NA NA 

Crystalline Silica 

(as Quartz) 

varies 14808-60-7 

[(10) / (%SiO2+2)] (R); 

[(30) / (%SiO2+2)] (T) 

0.025 (R) NA NA 

Note: HMA is a mixture of gravel or rock, sand and asphalt cement. It may also contain small amounts of asphalt 

modifiers (e.g. anti-striping agents, hydrated lime), RAP, fly ash, slag, fibers (synthetic or organic), color 

pigment and other recycled material (e.g. ceramics, plastic, glass, etc.). 


WARNING 

Hot product can cause burns. 


Hot Product can release Hydrogen Sulfide gas; 

Product contains crystalline silica. 

Irritant: Causes eye, skin and inhalation irritation. 

Use proper engineering controls, work practices, 

and personal protective equipment. 


Eye 

Protection 

Gloves 




Emergency Overview: HMA is a black colored granular solid that has a petroleum odor. Hot product will 

cause severe thermal burns. If burned by hot product, cool affected area immediately 

with cool water. Do not attempt to remove solidified material from skin. Seek medical 

attention. When heated, this product may release toxic hydrogen sulfide (H2S). 

Prolonged or repeated skin contact can cause drying of the skin which may produce 

irritation or dermatitis. 


Eye Contact: Hot product will cause severe thermal burns. Eye contact with HMA fumes can cause 

moderate eye irritation, redness, and itching. Airborne dust may cause immediate or 

delayed irritation or inflammation. Eye exposures require immediate first aid to 

prevent damage to the eye. 

Skin Contact: Direct contact with HMA will cause severe thermal burns. Repeated or prolonged 

contact to HMA may cause dry skin, discomfort, irritation, itching and dermatitis. 

Inhalation (acute): Hot HMA releases irritating fumes or vapors such as smoke, carbon dioxide, carbon 

monoxide, unburned hydrocarbons. Hydrogen sulfide and other sulfur-containing 

gases can evolve from this product at elevated temperatures. Exposure to fumes or 

vapors may cause irritation of the nose and throat, and symptoms such as headache, 

dizziness, loss of coordination, and drowsiness. Cutting, crushing or grinding 

hardened asphalt will release dust. Breathing dust may cause nose, throat or lung 

irritation, including choking, depending on the degree of exposure. 


Silicosis: This product contains trace amounts of crystalline silica. Under normal use and 

application HMA does not release crystalline silica. However, cutting, crushing or 

grinding hardened asphalt or other crystalline silica-bearing materials will release 

respirable crystalline silica. Prolonged or repeated inhalation of respirable crystalline 

silica from this product can cause silicosis, a seriously disabling and fatal lung 

disease. 

Carcinogenicity: HMA is not listed as a carcinogen by IARC or NTP; however, HMA contains trace 

amounts of crystalline silica that is classified by IARC and NTP as known human 

carcinogen. 

Ingestion: Do not chew or ingest HMA. Hot product will cause thermal burns. Ingestion may 

result in nausea, vomiting, diarrhea and restlessness. Chewing asphalt has caused 

gastrointestinal effects. Stomach obstructions have been reported in individuals who 

have chewed and swallowed asphalt. 

Medical Conditions 

Aggravated by Exposure: Individuals with preexisting skin conditions can be aggravated by exposure. 




Eye Contact: For contact with hot material, flush with large amounts of cool water for at least 15 

minutes. Immediately call a physician. For contact with cold material or dust, rinse 

eyes thoroughly with water for at least 15 minutes, including under lids, to remove all 

particles. Seek medical attention for abrasions. 

Skin Contact: Wash with cool water and a pH neutral soap or a mild skin detergent. Do not use 

solvents or thinners to remove material form skin. Seek medical attention for burns, 

rash, irritation, and dermatitis. 

For contact with hot material, immerse or flush skin with cold water for at least 15 

minutes. Call a physician. Do not attempt to remove solidified material, since removal 

may cause further tissue injury. 






Flashpoint & Method: > 200°F (93.3°C) 

General Hazard: Combustible solid. 

Avoid breathing fumes. 

Extinguishing Media: Use extinguishing media 

appropriate for surrounding 

fire. 

Upper/Lower 

NA 

Flammable Limit: 


Firefighting Equipment: A SCBA is recommended to 

limit exposures to combustion 


fire. 

Combustion Products: Toxic gases produced in fire, 

Auto-Ignition 

Temperature: NA 

such as CO, CO2, and H2S. 

General: Use a shovel to scrape up material and place material into suitable containers for 

recovery or disposal. Do not wash HMA down sewage and drainage systems or into 

bodies of water (e.g. streams). Wear appropriate protective equipment as described 

in Section 8. 

Waste Disposal Method: Dispose of HMA according to Federal, State, Provincial and Local regulations. 


General: Handle with care and use appropriate control measures. Avoid contact with skin, 

eyes and clothing. Use additional precautions when handling hot material. Maintain 

employee exposure levels below established regulatory limits. Do not allow hot 

material to contact skin. Use all appropriate Personal Protective Equipment (PPE) 

described in Section 8 below. 

Usage: Cutting, crushing or grinding hardened asphalt or other crystalline silica-bearing 

materials will release respirable crystalline silica. Use all appropriate measures of 

dust control or suppression, and Personal Protective Equipment (PPE) described in 

Section 8 below. 

Concentrations of hydrogen sulfide (H2S) can be generated and accumulate in 

storage tanks and bulk transport compartments which may require additional 

precautions and procedures during loading and unloading. 


Section 7: HANDLING AND STORAGE (continued) 


Storage: Do not expose to open flames, strong oxidizers or other source of ignition. 

Clothing: Remove and launder clothing that is soiled with asphalt. Thoroughly wash hands and 

exposed skin after exposure to HMA. 


Engineering Controls: Use local exhaust or general dilution ventilation when using at elevated temperatures 

or during activities that generate dust or fumes, to maintain levels below exposure 

limits. 


Respiratory Under ordinary conditions no respiratory protection is required. Wear a NIOSH 

Protection: approved respirator that is properly fitted and is in good condition when exposed to 

dust or fumes above exposure limits. 

Eye Protection: Wear ANSI approved glasses, safety goggles, or face shield when handling HMA to 

prevent contact with eyes. 

Skin Protection: Wear leather or cloth work gloves to prevent skin contact and insulated gloves when 

handling hot material. Thoroughly wash hands and other exposed skin after exposure 

to HMA. 


Physical State: Granular solid. Evaporation Rate: NA. 

Appearance: Black solid. pH (in water): NA. 

Odor: Slight petroleum odor. Boiling Point: NA. 


Vapor Density: NA. Viscosity: NA. 

Specific Gravity: 2.0-2.5 Solubility in Water: Insoluble 


Stability: Stable. Avoid contact with incompatible materials, excessive heat, sources of ignition 

and open flame. 

Incompatibility: HMA is incompatible with strong acids or bases, and oxidizing agents such as 

nitrates, chlorates and peroxides. 

Hazardous Polymerization: None. 

Hazardous Decomposition: When heated may liberate hydrogen sulfide and various hydrocarbons. 










OSHA/MSHA Hazard This product is considered by OSHA/MSHA to be a hazardous chemical and should 

Communication: be included in the employer's hazard communication program. 


EPCRA This product has been reviewed according to the EPA Hazard Categories 

SARA Title III: promulgated under Sections 311 and 312 of the Superfund Amendment and 

Reauthorization Act of 1986 and is considered to be an acute health hazard 

(irritation). 

EPRCA This product contains none of the substances subject to the reporting requirements of 

SARA Section 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 

1986 and 40 CFR Part 372. 


either by listing or characteristic. However, under RCRA, it is the responsibility of the 

product user to determine at the time of disposal, whether a material containing the 

product or derived from the product should be classified as a hazardous waste. 

TSCA: This product and/or its components are listed on the Toxic Substances Control Act 

(TSCA) inventory. 

California Proposition 65: Crystalline silica (airborne particulates of respirable size) is known by the State of 

California to cause cancer. 

WHMIS/DSL: Products containing crystalline silica are classified as D2A and are subject to WHMIS 

requirements. 






ACGIH 

American Conference of Governmental 



CAS No Chemical Abstract Service number NIOSH 


and Health 




Act 

OSHA 








HMIS 


System 

SARA 



IARC 


Cancer 

SCBA 

T 

TDG 

Self-Contained Breathing Apparatus 





mg/m 3 

MSHA 



WHMIS 










regulations. 




No changes as of May 2011 

Product Discontinued



Product Name(s): Lafarge Ready Mix Concrete (Concrete) 

MSDS: Lafarge Ready Mix Concrete 

Product Identifiers: Ready Mix Concrete, Concrete Ready Mix, Portland Cement Concrete, Ready Mix 

Stucco, Ready Mix Grout, Ready Mix, Concrete, Freshly Mixed Concrete, Colloidal 

Concrete, Permeable Concrete, Shotcrete, Gunite, Polymer-Portland Cement 

Concrete, Colored Concrete, Flowable Fill, Roller-Compacted Concrete, Fiber 

Reinforced Concrete, Weathermix, UltraCurb TM , UltraDrive TM , UltraFlo-Fil TM , 

UltraHorizontal TM , UltraFooting TM , UltraPatio TM , UltraStamp TM , UltraTilt TM , 

UltraVertical TM , Agrifarge TM Plus, Agrifarge TM RP, Agrifarge TM 20, 25, 30, 32, 

ArteviaColor TM , Chronolia TM , Extensia TM , Agilia ® Screed C. 





Product Use: Concrete is widely used as a structural component in construction applications. 

Note: This MSDS covers many types of Concrete. Individual composition of hazardous 

constituents will vary between types of Concrete. 


Component 

Percent (By 

Weight) 

CAS Number 

OSHA PEL -TWA 

(mg/m 3 ) 

ACGIH TLV- 

TWA (mg/m 3 ) 

LD50 (mouse) LC50 Crystalline Silica 0-90 14808-60-7 

[(10) / (%SiO2+2)] (R); 

[(30) / (%SiO2+2)] (T) 

0.025 (R) NA NA 

Calcium Carbonate* 25-65 1317-65-3 15 (T); 5 (R) 3 (R); 10 (T) NA NA 

Portland Cement* 10-30 65997-15-1 15 (T); 5 (R) 1 (R) NA NA 

Calcium Hydroxide 15-25 1305-62-0 15 (T); 5 (R) 5 (T) 7300 mg/kg (oral) NA 

Fly Ash 0-20 68131-74-8 NA NA NA NA 

Calcium Oxide 0-5 1305-78-8 5 (T) 2 (T) 

3059 mg/kg 

(intraperitoneal) 

NA 

Magnesium Oxide 0-4 1309-48-4 15 (T) 10 (I) NA NA 

Calcium Sulfate* 0-2 13397-24-5 15 (T); 5 (R) 10 (I) NA NA 

Particulate Not 

Otherwise Regulated 

- NA 15 (T); 5 (R) 10 (T); 3 (R) NA NA 

Note: Exposure limits for components noted with an * contain no asbestos and



Emergency Overview: Unhardened concrete is an odorless semi-fluid, flowable, granular paste of varying 

color and texture. It is not combustible or explosive. Exposure of sufficient duration to 

wet concrete can cause serious, potentially irreversible tissue (skin, eye, respiratory 

tract) damage due to chemical (caustic) burns, including third degree burns. 


Eye Contact (acute): Concrete may cause immediate or delayed irritation or inflammation. Eye contact with 

wet concrete can cause moderate eye irritation, chemical burns and blindness. Eye 

exposures require immediate first aid and medical attention to prevent significant 

damage to the eye. 

Skin Contact (acute): Concrete may cause dry skin, discomfort, irritation, severe burns, and dermatitis. 

Burns: Exposure of sufficient duration to wet concrete can cause serious, potentially 

irreversible damage to skin, eye, respiratory and digestive tracts due to chemical 

(caustic) burns, including third degree burns. A skin exposure may be hazardous 

even if there is no pain or discomfort. 

Dermatitis: Unhardened concrete is capable of causing dermatitis by irritation and allergy. Skin 

affected by dermatitis may include symptoms such as, redness, itching, rash, scaling, 

and cracking. 

Irritant dermatitis is caused by the physical properties of concrete including alkalinity 

and abrasion. 

Sensitization: Allergic contact dermatitis is caused by sensitization to hexavalent chromium 

(chromate) present in concrete. The reaction can range from a mild rash to severe 

skin ulcers. Persons already sensitized may react to the first contact with wet 

concrete. Others may develop allergic dermatitis after years of repeated contact with 

wet concrete. 

Inhalation (acute): Breathing dust may cause nose, throat lung or mucous membrane irritation, including 

choking, depending on the degree of exposure. Inhalation of high levels of dust can 

cause chemical burns to the nose, throat and lungs. 


Silicosis: This product contains crystalline silica. Prolonged or repeated inhalation of respirable 

crystalline silica from this product can cause silicosis, a seriously disabling and fatal 

lung disease. See Note to Physicians in Section 4 for further information. 

Carcinogenicity: Concrete is not listed as a carcinogen by IARC or NTP; however, concrete contains 

trace amounts of crystalline silica and hexavalent chromium which are classified by 

IARC and NTP as known human carcinogens. 

Autoimmune Some studies show that exposure to respirable crystalline silica (without silicosis) or 

Disease: that the disease silicosis may be associated with the increased incidence of several 

autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus 

erythematosus, rheumatoid arthritis and diseases affecting the kidneys. 

Tuberculosis: Silicosis increases the risk of tuberculosis. 

Renal Disease: Some studies show an increased incidence of chronic kidney disease and end-stage 

renal disease in workers exposed to respirable crystalline silica. 




Ingestion: Do not ingest concrete. Although ingestion of small quantities of concrete is not 

known to be harmful, large quantities can cause chemical burns in the mouth, throat, 

stomach, and digestive tract. 

Medical Conditions Individuals with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary 

Aggravated by Exposure: disease) or sensitivity to hexavalent chromium can be aggravated by exposure. 


Eye Contact: Rinse eyes thoroughly with water for at least 15 minutes, including under lids, to 

remove all particles. Seek medical attention for abrasions and burns. 

Skin Contact: Wash with cool water and a pH neutral soap or a mild skin detergent. Seek medical 

attention for rash, burns, irritation, dermatitis, and prolonged unprotected exposures 

to wet concrete. 





Note to Physician: The three types of silicosis include: 


Flashpoint & Method: Non-combustible 

General Hazard: Avoid breathing dust. 

Wet concrete is caustic. 

Extinguishing Media: Use extinguishing 

media appropriate for 

Simple chronic silicosis – which results from long-term exposure (more than 

20 years) to low amounts of respirable crystalline silica. Nodules of chronic 

inflammation and scarring provoked by the respirable crystalline silica form in 

the lungs and chest lymph nodes. This disease may feature breathlessness 

and may resemble chronic obstructive pulmonary disease (COPD). 

Accelerated silicosis – occurs after exposure to larger amounts of respirable 

crystalline silica over a shorter period of time (5-15 years). Inflammation, 

scarring, and symptoms progress faster in accelerated silicosis than in 

simple silicosis. 

Acute silicosis – results from short-term exposure to very large amounts of 

respirable crystalline silica. The lungs become very inflamed and may fill with 

fluid, causing severe shortness of breath and low blood oxygen levels. 

Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more 

common in the accelerated form. Progressive massive fibrosis results from severe 

scarring and leads to the destruction of normal lung structures. 

Firefighting Equipment: Concrete poses no firerelated 

hazard. A SCBA is 

recommended to limit 

exposures to combustion 


fire. 

surrounding fire. Combustion Products: None. 




General: Place spilled material into a container. Avoid contact with skin. Wear appropriate 

protective equipment as described in Section 8. Scrape wet concrete and place in 

container. Allow material to dry or solidify before disposal. Do not wash concrete 

down sewage and drainage systems or into bodies of water (e.g. streams). 

Waste Disposal Method: Dispose of concrete according to Federal, State, Provincial and Local regulations. 


Usage: Cutting, crushing or grinding hardened cement, concrete or other crystalline silicabearing 

materials will release respirable crystalline silica. Use all appropriate 

measures of dust control or suppression, and Personal Protective Equipment (PPE) 


Storage Temperature: Unlimited. Storage Pressure: Unlimited. 

Clothing: Promptly remove and launder clothing that is wet with concrete. Thoroughly wash 

skin after exposure to wet concrete. 


Engineering Controls: Use local exhaust or general dilution ventilation or other suppression methods to 

maintain dust levels below exposure limits. 




dust above exposure limits. 

Eye Protection: Wear ANSI approved glasses or safety goggles when handling wet concrete to 

prevent contact with eyes. Wearing contact lenses, when using concrete, is not 

recommended. 

Skin Protection: Wear gloves, boot covers and protective clothing impervious to water to prevent skin 

contact. Do not rely on barrier creams, in place of impervious gloves. Remove 

clothing and protective equipment that becomes saturated with wet cement and 

immediately wash exposed areas. 


Physical State: Semi-fluid, Flowable, granular 

paste. 

Evaporation Rate: NA. 

Appearance: Variety of color (usually gray) pH (in water): 12 – 13 

Odor: None. Boiling Point: NA 


Vapor Density: NA. Viscosity: Varies. 

Specific Gravity: 1.9 – 2.4 Solubility in Water: Slightly (0.1 - 1.0%) 




Stability: Hardened concrete is stable. Avoid contact with incompatible materials. 

Incompatibility: Wet concrete is alkaline and is incompatible with acids, ammonium salts and 

aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon 

tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. 

Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine 

trifluoride, manganese trifluoride, and oxygen difluoride. 

Hazardous Polymerization: None. Hazardous Decomposition: None. 













Reauthorization Act of 1986 and is considered a hazardous chemical and a delayed 

health hazard. 



1986 and 40 CFR Part 372. 





TSCA: Portland cement and crystalline silica are exempt from reporting under the inventory 

update rule. 

California Crystalline silica (airborne particulates of respirable size) and Chromium (hexavalent 

Proposition 65: compounds) are substances known by the State of California to cause cancer. 

WHMIS/DSL: Products containing crystalline silica and calcium carbonate are classified as D2A, E 

and are subject to WHMIS requirements. 






ACGIH 






and Health 




Act 

OSHA 








HMIS 


System 

SARA 



IARC 


Cancer 

T 

TDG 





mg/m 3 

MSHA 



WHMIS 



This MSDS (Section 1) was revised on March 1, 2011. 







regulations. 





Product Name(s): Sand and Gravel 


MSDS: Sand and Gravel 

Product Identifiers: Natural Sand, River Sand Screenings, Aggregates, Bank Sand and Gravel, Crushed 

Gravel, Round Gravel, Concrete Sand, Asphalt Sand, Mason Sand, Fill Sand, Golf 

Course Sand, Base Material, Dense Graded Aggregate, Quartz, Gravel, Crushed 

Rock, Crushed Stone 





Product Use: Sand and gravel are aggregates used in the manufacture of bricks, mortar, cement, 

concrete, plasters, paving materials, and other construction applications. Sand and 

gravel are distributed in bags, totes and bulk shipment. 

DO NOT use this product for abrasive blasting. This material safety data sheet and 

the information contained herein were not developed for abrasive blasting. 

Note: This MSDS covers many types of sand and gravel. Individual composition of 

hazardous constituents will vary between sand and gravel types. 


Component 

Percent 

(By Weight) 

CAS 

Number 

OSHA PEL -TWA 

(mg/m 3 ) 

ACGIH TLV-TWA 

(mg/m 3 ) 

Crystalline Silica (quartz) 50-99 14808-60-7 [(10) / (%SiO2+2)] (R); 

[(30) / (%SiO2+2)] (T) 

0.025 (R) NA NA 

Particulate Not Otherwise 

Regulated 

- NA 5 (R); 15 (T) 3 (R); 10 (T) NA NA 

Warning: Crystalline silica exists in several forms, the most common of which is quartz. If 

crystalline silica (quartz) is heated to more than 870º C it can change to a form of 

crystalline silica known as tridymite, and if crystalline silica (quartz) is heated to more 

than 1470º C it can change to a form of crystalline silica known as cristobalite. 

Crystalline silica as tridymite and cristobalite are more fibrogenic than crystalline silica 

as quartz. The OSHA PEL for crystalline silica as tridymite and cristobalite is one-half 

the PEL for crystalline silica (quartz); the ACGIH TLV for crystalline silica as 

cristobalite is 0.025 mg/m 3 (R). 


WARNING 



DO NOT use for Sand Blasting. 

Use proper engineering controls, work 

practices, and Personal Protective Equipment 

(PPE) to prevent exposure to dust. 


Respiratory 

Protection 

Page 1 of 6 Revised: 03/01/11 

LD50 

Eye 

Protection 

LC50



Emergency Overview: Sand and gravel are a white or light grey/brown sold material and is odorless. It is not 

combustible or explosive. A single, short-term exposure to sand and gravel presents 

little or no hazard. 


Eye Contact: Eye contact to airborne dust may cause immediate or delayed irritation or 

inflammation. Eye exposures require immediate first aid and medical attention to 

prevent significant damage to the eye. 

Skin Contact: Sand and gravel may cause dry skin, abrasions, discomfort, and irritation. 

Inhalation (acute): Breathing dust may cause nose, throat or lung irritation, including choking, depending 

on the degree of exposure. 





Carcinogenicity: Crystalline silica is classified by IARC and NTP as a known human carcinogen. 








Ingestion: Do not ingest sand or gravel. Although ingestion of small quantities of sand or gravel 

is not known to be harmful, large quantities can cause intestinal distress. 


Aggravated by Exposure: disease) can be aggravated by exposure. 



remove all particles. Seek medical attention for abrasions. 


attention for rash or irritation. 


















surrounding fire. 













Firefighting Equipment: Sand and gravel poses no 

fire-related hazard. A SCBA 

is recommended to limit 



fire. 

Combustion Products: None. 

General: Place spilled material into a container. Avoid actions that cause the sand or gravel to 

become airborne. Avoid inhalation of dust. Wear appropriate protective equipment 

as described in Section 8. Do not wash sand or gravel down sewage and drainage 

systems or into bodies of water (e.g. streams). 

Waste Disposal Method: Dispose of sand and gravel according to Federal, State, Provincial and Local 

regulations. 


General: Stack bagged material in a secure manner to prevent falling. Bagged sand and 

gravel is heavy and poses risks such as sprains and strains to the back, arms, 

shoulders and legs during lifting and mixing. Handle with care and use appropriate 

control measures. 

Engulfment hazard. To prevent burial or suffocation, do not enter a confined space, 

such as a silo, bin, bulk truck, or other storage container or vessel that stores or 

contains sand or gravel. Sand or gravel can buildup or adhere to the walls of a 

confined space. The sand or gravel can release, collapse or fall unexpectedly. 

Usage: This product is NOT to be used for abrasive blasting. 

Cutting, crushing or grinding hardened cement, concrete or other crystalline silicabearing 




Housekeeping: Avoid actions that cause the sand or gravel to become airborne during clean-up such 

as dry sweeping or using compressed air. Use HEPA vacuum or thoroughly wet 

with water to clean-up dust. Use PPE described in Section 8 below. 


Clothing: Remove and launder clothing that is dusty before it is reused. 










Eye Protection: Wear ANSI approved glasses or safety goggles when handling dust to prevent 

contact with eyes. Wearing contact lenses when using sand or gravel, under dusty 

conditions, is not recommended. 

Skin Protection: Wear gloves in situations where abrasion from sand or gravel may occur. Remove 

clothing and protective equipment that becomes dusty and launder before reusing. 


Physical State: Granular Solid. Evaporation Rate: NA. 

Appearance: White or light gray/brown. pH (in water): Neutral 

Odor: None. Boiling Point: >1000 o C 

Vapor Pressure: NA. Freezing Point: None, solid. 

Vapor Density: NA. Viscosity: None, solid. 

Specific Gravity: 2.7 Solubility in Water: Insoluble 


Stability: Stable. Avoid contact with incompatible materials. 

Incompatibility: Sand and gravel dissolve in hydrofluoric acid, producing corrosive silicon tetrafluoride 

gas. Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine 














Section 15: REGULATORY INFORMATION (continued) 








1986 and 40 CFR Part 372. 





TSCA: Crystalline silica is exempt from reporting under the inventory update rule. 

California Crystalline silica (airborne particulates of respirable size) is known by the State of 

Proposition 65: California to cause cancer. 

WHMIS/DSL: Sand and gravel may be subject to WHMIS depending on the intended use and 

worker exposure. Sand and gravel containing crystalline silica is classified as D2A, 





ACGIH 






and Health 




Act 

OSHA 








HMIS 


System 

SARA 



IARC 


Cancer 

T 

TDG 





mg/m 3 

MSHA 



WHMIS 













regulations. 




No Change as of May 2011

04132010 MATERIAL SAFETY DATA SHEET : 00000102 PAGE:1 

PRODUCT : LEPAGE PRES-TITE CONTACT CEMENT 

SECTION 01: PRODUCT INFORMATION 

HENKEL CONSUMER ADHESIVES 

6685 KENNEDY ROAD,UNIT 1 

MISSISSAUGA, ONTARIO CANADA L5T 3A5 

(440) 937-7000 

MANUFACTURER.....................HENKEL CONSUMER ADHESIVES_____ 

6685 KENNEDY ROAD, UNIT 1 

MISSISSAUGA, ONTARIO 

CANADA ; L5T 3A5 

(440) 937-7000 

AFTER HOURS - CANUTEC (613) 996-6666 

WHMIS CLASSIFICATION WHMIS.......B2 D2B. D2B, D2A, E. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT 

CLASSIFICATION WHMIS IT IS EXEMPT FROM WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS 

CLASSIFICATION WHMIS PRODUCTS ACT). 

CLASSIFICATION WHMIS 

CLASSIFICATION 

T.D.G. CLASSIFICATION............ADHESIVES, CLASS 3, UN 1133, PKG GRP II. WHEN THIS PRODUCT IS LABELLED AS 

A CONSUMER COMMODITY IT IS EXEMPT FROM T.D.G. REGULATIONS 

PRODUCT NAME.....................LEPAGE PRES-TITE CONTACT CEMENT 

CHEMICAL FAMILY..................CONTACT CEMENT 

MATERIAL USE.....................WOODWORKING ADHESIVE 


HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES 

Solvent naptha (petroleum), 30-60 TLV: 300ppm 8hrTWA 64742-89-8 >5g/kg,oral,rat Not available 

light aliphatic PEL: 500ppm 8hrTWA >3.16g/kg,skin, 

rabbit 

Magnesium oxide 1-5 PEL-TWA: 15 mg/m3 1309-48-4 810 mg/kg___________ Not available 

TLV-TWA: 10 mg/m3 oral,mouse 

2-Butanone 10-30 PEL-TWA: 200 ppm 78-93-3 2.7g/kg,oral,rat 23.5g/m3/8hr., 

4.0g/kg,oral,mouse rat 

6.5g/kg,skin,rabbit 

Toluene 10-30 TLV-TWA:188mg/m3 108-88-3 2.6-7.5g/kg,oral,rat 8800 ppm,4hr,rat 

PEL-TWA:375mg/m3 14.1ml/kg,skin,rbt 

SECTION 03: PHYSICAL DATA 

PHYSICAL STATE...................Liquid 

APPEARANCE & ODOUR...............Yellowish liquid. Solvent odour 

ODOUR THRESHOLD (ppm)............Not available 

VAPOUR PRESSURE (mm Hg)..........Not available 

VAPOUR DENSITY (AIR=1)...........3.0 

BY VOLUME 

BY WEIGHT 

EVAPORATION RATE.................>1 (Butyl Acetate = 1) 

BOILING POINT (deg C)............66 deg C 

pH...............................Not available 

SPECIFIC GRAVITY.................0.830 

SOLUBILITY IN WATER (% W/W)......Insoluble 

COEFFICIENT OF WATER/OIL.........Not available 

DISTRIBUTION 

SECTION 04: FIRE & EXPLOSION DATA 

FLAMMABILITY.....................EXTREMELY FLAMMABLE 

IF YES, UNDER WHICH..............Excessive heat, sparks and open flame. Vapours may cause flash fires. 

CONDITIONS? Vapours may ignite explosively. 

AUTO IGNITION TEMPERATURE........> 250 deg C 

EXTINGUISHING MEDIA..............Carbon dioxide, dry chemical, foam 

SPECIAL PROCEDURES...............Fire fighters should be equipped with self-contained breathing apparatus 

to protect against potentially toxic and irritating fumes. A solid stream 

of water directed on hot and/or burning material may cause violent 

frothing. 

FLASH POINT (C), METHOD..........-12 deg C, CC 

LOWER FLAMMABLE LIMIT (% VOL)....1.0 

UPPER FLAMMABLE LIMIT (% VOL)....10.0 

HAZARDOUS COMBUSTION PRODUCTS....Hydrocarbons and traces of chlorine compounds. Oxides of carbon (CO,CO2). 

Smoke 


YES........................Stable, hazardous polymerization will not occur. Under normal conditions 

NO, WHICH CONDITIONS ? 

COMPATIBILITY WITH OTHER 

SUBSTANCES:




YES 

NO, WHICH ONES?............Strong oxidizing agents 

REACTIVITY CONDITIONS ? 

HAZARDOUS PRODUCTS OF............Smoke. Chlorine compounds. Oxides of carbon (CO,CO2) at high temperatures. 

DECOMPOSITION 


SKIN CONTACT...............Can cause drying and defatting of skin leading to irritation and 

dermatitis. May cause irritation, especially on prolonged contact. 

SKIN ABSORPTION............May be absorbed by the skin. 

EYE CONTACT................Vapours cause tearing. May cause moderate to severe irritation. Causes 

corneal damage. 

INHALATION.................High vapour concentrations are irritating to the eyes and the respiratory 

tract. May cause headaches and dizziness; are anaesthetic. May affect 

central nervous system. 

INGESTION..................Vomiting presents an aspiration hazard and may result in chemical 

pneumonia, pulmonary edema or hemorrhage. Can cause gastro-intestinal 

irritation, nausea, vomiting and diarrhea. Product may be toxic if 

ingested. 

EFFECTS OF ACUTE EXPOSURE........Refer to route of entry. 

EFFECTS OF CHRONIC EXPOSURE......Dermatitis. Deliberate and repeated inhalation may result in teratogenic 

and embryonic toxic effects. May aggravate existing eye, skin, and lung 

conditions. 

LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2) 

ROUTE 

LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2). 

ROUTE 

EXPOSURE LIMIT OF MATERIAL.......Not available 

IRRITANCY OF MATERIAL............Eye irritation:. Moderate to severe. Skin irritation:. Components of this 

formulation known to cause irritation. 

SENSITIZING CAPABILITY OF........Refer to route of entry 

MATERIAL 

CARCINOGENICITY OF MATERIAL......Not indicated 

MUTAGENICITY OF MATERIAL.........Not available 

REPRODUCTIVE EFFECTS.............Risk of abortion in animal. Teratogenic and fetotoxic effects have not 

been clearly demonstrated in humans. 

TERATOGENICITY OF MATERIAL.......Refer to route of entry. 

SYNERGISTIC MATERIALS............Not available 


GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber). 

RESPIRATORY/TYPE...........None required under normal use. Use a NIOSH/MSHA approved respirator 

whenever mist or spray is generated. 

EYE/TYPE...................Safety glasses with side-shields 

FOOTWEAR/TYPE..............Standard work shoes. 

CLOTHING/TYPE..............Standard work clothes. 

VENTILATION REQUIREMENTS.........Use adequate local exhaust ventilation. Explosion-proof exhaust ventilation 

LEAK/SPILL.......................Eliminate all sources of ignition. Evacuate all non-essential personnel. 

Follow all applicable fire and explosion precautions during the spill 

response procedure. Clean up spills immediately. For small spills:. Absorb 

residual material with sand, or other absorbent material. For large 

spills:. Dike area to prevent spreading. Isolate product until disposal. 

WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since 

emptied container retains product residues all labelled hazard precautions 

must be observed. 

HANDLING PROCEDURES AND..........Use adequate ventilation. Keep away from heat, sparks, and open flame. 

EQUIPMENT Wear chemical splash goggles, gloves, and protective clothing. 

SPECIAL SHIPPING INSTRUCTIONS....Ship in accordance with applicable Transportation of Dangerous Goods (TDG) 

regulations. Protect against physical damage. 


EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids 

apart to ensure flushing of entire surface. Washing within 1 minute is 

essential to achieve maximum effectiveness. 

INGESTION........................Dilute with large quantities of water or milk. DO NOT induce vomiting. Get 

immediate medical attention. Never give anything by mouth to an 

unconscious person. 

INHALATION.......................Remove victim to fresh air. If not breathing qualified personnel should 

administer artificial respiration. Get medical attention. 

SKIN CONTACT.....................Remove contaminated clothing. Wash affected area with water and soap. Seek 

medical attention if irritation occurs or persists. 

SECTION 09: PREPARATION INFORMATION 

PREPARED BY:.....................Regulatory Affairs 

TELEPHONE NUMBER:................(440)937-7000




DISCLAIMER2:.....................All information, recommendations, and suggestions appearing herein 

concerning our product are based upon tests and data believed to be 

reliable. However, it is the user's responsibility to determine the 

safety, toxicity, and suitability for his own use of the product described 

herein. Since the actual use by others is beyond our control, no 

guarantee, express or implied, is made by Henkel Consumer Adhesives as to 

the effects of such use, the results obtained, or the safety and toxicity 

of the product nor does Henkel Consumer Adhesives assume any liability 

arising out of use, by others, of the product referred to herein. The 

information herein is not to be construed as absolutely complete since 

additional information may be necessary or desirable when particular or 

exceptional conditions or circumstan ces exist or because of applicable 

laws or government regulations. 

PREPARATION DATE.................MAY 12/2006 Rev 4/ 2010 

CANUTEC EMERGENCY (613) 996-6666

Page 1 of 5 


__________________________________________________________________________________________ 

SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE 

COMPANY/UNDERTAKING 

LUBRIPLATE® Lubricants Co. Emergency Telephone Number: 

129 Lockwood St. 1-800-255-3924-CHEM-TEL (24 hour) 

Newark, NJ 07105 Telephone Number for information: 

1-973-589-9150 

SUBSTANCE: LUBRIPLATE NON-DETERGENT MOTOR OIL 30 

TRADE NAMES/SYNONYMS: 

PRODUCT USE: Petroleum lubricating oil 

CREATION DATE: 06/14/2007 

REVISION DATE: 03/03/2009 

__________________________________________________________________________________________ 


COMPONENT: Solvent dewaxed heavy paraffinic distillates 

CAS NUMBER: 64742-65-0 

EC NUMBER (EINECS): 265-169-7 

PERCENTAGE: 75-80 

COMPONENT: Residual oils (petroleum), solvent dewaxed 

CAS NUMBER: 64742-62-7 

EC NUMBER (EINECS): 265-166-0 

PERCENTAGE: 20-25 

NOTE: The IP 346 value of the mineral oil is less than 3% 

__________________________________________________________________________________________ 


POTENTIAL HEALTH EFFECTS: 

INHALATION: 

SHORT TERM EXPOSURE: Irritation 

LONG TERM EXPOSURE: Lung damage 

SKIN CONTACT: 


LONG TERM EXPOSURE: Irritation, skin disorders 

EYE CONTACT: 


LONG TERM EXPOSURE: No information available 

INGESTION: 

SHORT TERM EXPOSURE: Diarrhea, difficulty breathing 


LONG TERM EXPOSURE: no information on significant adverse effects 

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS): 

Health–1 

Flammability – 1 

Reactivity – 0 

Page 2 of 5 

Not a Controlled Product under (WHMIS) – Canada Special Protection: See Section 8 

__________________________________________________________________________________________ 


INHALATION: Vapor pressure is very low and inhalation at room temperature is not a problem. If overcome 

by vapor from hot product, immediately remove from exposure and call a physician. 

SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water. If injected by 

high pressure under skin, regardless of the appearance or its size, contact a physician IMMEDIATELY. Delay 

may cause loss of affected part of body. 

EYE CONTACT: Flush eyes with clear water for 15 minutes or until irritation subsides. If irritation persists, 

consult a physician. 

INGESTION: If ingested, call a physician immediately. Do not induce vomiting. 

__________________________________________________________________________________________ 


FIRE AND EXPLOSION HAZARDS: Slight fire hazard 

EXTINGUISHING MEDIA: Foam, dry chemical, carbon dioxide or water spray (fog) 

FIRE FIGHTING: Cool exposed containers with water. Use air-supplied breathing equipment for enclosed or 

confined spaces. 

HAZARDOUS COMBUSTION PRODUCTS: 

Thermal decomposition products or combustion: oxides of carbon, oxides of sulphur 

UNUSUAL FIRE AND EXPLOSION HAZARDS: Do not store or mix with strong oxidants. Empty 

containers contain residue. Do not cut, drill, grind, or weld, as they may explode. 

__________________________________________________________________________________________ 


OCCUPATIONAL RELEASE: Recover liquid, wash remainder with suitable petroleum solvent or add 

absorbent. Keep petroleum products out of sewers and watercourses. Advise authorities if product has entered 

or may enter sewers and watercourses.

Page 3 of 5 

__________________________________________________________________________________________ 


STORAGE: Store and handle in accordance with all current regulations and standards. Keep container tightly 

closed. Keep away from heat, sparks, and flame. See original container for storage recommendations. Keep 

separated from incompatible substances. 

__________________________________________________________________________________________ 



White mineral oil: 

MINERAL OIL MIST: 

5mg/m 3 UK OES TWA 

10mg/m 3 UK OES STEL 

VENTILATION: Provide local exhaust ventilation system. Ensure compliance with applicable exposure 

limits. 

EYE PROTECTION: Wear splash resistant safety goggles. Provide an emergency eye wash fountain and 

quick drench shower in the immediate work area. 

CLOTHING: Wear appropriate chemical resistant clothing. 

GLOVES: Wear appropriate chemical resistant (nitrile) gloves. 

RESPIRATOR: Consider the need for appropriate protective equipment, such as self-contained breathing 

apparatus, adequate masks and filters. 

__________________________________________________________________________________________ 


PHYSICAL STATE: liquid 

APPEARANCE: transparent 

COLOUR: amber 

PHYSICAL FORM: oil 

ODOR: mineral oil odor 

BOILING POINT: >288 C 

FREEZING POINT: Not available 

FLASH POINT: 252 C (COC) 

LOWER FLAMMABLE LIMIT: 0.9% by volume 

UPPER FLAMMABLE LIMIT: 7.0% by volume 

AUTO IGNITION: not available 

VAPOUR PRESSURE: 5 

SPECIFIC GRAVITY (water=1): 0.88 

DENSITY: not available 

WATER SOLUBILITY: negligible 

pH: not available

VOLATILITY: not available 

ODOR THRESHOLD: not available 

EVAPORATION RATE:

AIR TRANSPORT IATA: No classification assigned. 

AIR TRANSPORT ICAO: No classification assigned. 

MARITIME TRANSPORT IMDG: No classification assigned. 

Page 5 of 5 

__________________________________________________________________________________________ 


EUROPEAN REGULATIONS: 

EC CLASSIFICATION (CALCULATED): Not classified as dangerous. 

__________________________________________________________________________________________ 


The above information is furnished without warranty, expressed or implied, except that it is accurate to 

the best knowledge of LUBRIPLATE Lubricants Company. The data on these sheets relates only to the 

specific material designated herein. LUBRIPLATE Lubricants Company assumes no legal responsibility 

for use or reliance upon this data.

No Change May 2011

No Change May 2011


Armstrong World Industries, Inc. 

Environment, Health and Safety Division: Building Products 

2500 Columbia Avenue, P.O. Box 3001 

Lancaster, PA 17604 Date: 9/09 (replaces 7/09) 

Telephone (717) 396-2328 or 396-2935 

N/A = Not applicable or Not Available 

Issued By : Safety, Health and N/K = None Known or Not Known 

Industrial Hygiene Department 

Department of Transportation Information 

HMIS ( 0 = minimal hazard, 4 = severe hazard ) Shipping name : Not Classified 

Health = 1 Hazard Class : N/A 

Flammability = 0 ID No : N/A 

Reactivity = 0 Emergency Only Contact: CHEM-TEL 800-255-3924 

I. Product Information 

A. Product Name : Man-made Vitreous Fiber Ceilings and Wall Panels (Class A) - MSDS #1 

B. Chemical Name and Synonyms : N/A 

C. Chemical or Product Family : Man-made Vitreous Fibers 

II. Ingredient Information 

A. Hazardous Components C.A.S No. % OSHA PEL ACGIH TLV 

( Chemical Identity; Common Name ) Respirable: Respirable: 

Mineral Wool Fiber N/A 0-60 1 f/cc 1 f/cc 

Fibrous Glass 65997-17-3 0-13 1 f/cc 1 f/cc 

This product formulation does not contain asbestos. 

III. Physical Data 

A. Appearance and Color : Gray, pressed man-made vitreous fiber panel of various colors 

B. Boiling Point ( degrees F ) : N/A 

C. Vapor pressure ( mm Hg @ 20 degrees C ) : N/A 

D. Vapor density ( Air = 1 ) : N/A 

E. Solubility in Water : N/A 

F. Specific Gravity ( H 2O = 1 ) : N/A 

G. Percent Volatile by weight ( 30 min. @ 275 degrees F ) : N/A 

H. Evaporation Rate ( Butyl Acetate = 1 ) : N/A 

I. pH : N/A 

IV. Fire and Explosion Data 

A. Flash point : N/A 

B. Flammable Range : LEL = N/A ; UEL = N/A 

C. Extinguishing Media : Water fog, dry chemical ABC rated 

D. Special Fire Fighting Procedures : None 

E. Unusual Fire and Explosion Hazards : None

Continued : Man-made Vitreous Fiber Ceilings and Wall Panels (Class A) - MSDS #1 Date: 9/09 (replaces 7/09) 

V. Health Data 

A. Primary Route (s) of Entry: Inhalation, skin, and eye contact 

B. Target Organs: Lungs, skin and eyes 

Effects of Overexposure : 

Acute Health Effects: Products are a transient mechanical irritant to the skin, eyes and upper respiratory system. 

Refer to special protection information for handling instructions. 

Chronic Health Effects: 

Mineral Wool Fiber: Mineral wool fiber has been classified as "not classifiable as to its carcinogenicity to human" (Group 3) by 

the International Agency for Research on Cancer (IARC). 

Fibrous Glass : Fibrous glass has been classified as "not classifiable as to its carcinogenicity to human" (Group 3) by 

the International Agency for Research on Cancer (IARC). Fibrous glass is listed by NTP as 2, reasonably anticipated to 

be a carcinogen. 

C. Carcinogenicity: NTP : Yes IARC Monographs : No OSHA Regulated : No 

D. Medical Conditions Generally aggravated by Exposure: Any condition generally aggravated by respiratory and mechanical 

irritants in the air or on the skin. Pre-existing upper respiratory and lung disease such as, but not limited to bronchitis, 

emphysema, and asthma. 

E. First Aid Procedures: 

Skin: Wash with mild soap and running water 

Eyes: Flush with flowing water for at least 15 minutes and if symptoms persist, seek immediate medical attention. 

VI. Reactivity Data 

A. Stability : Material is stable 

B. Incompatibility: N/K 

C. Hazardous Decomposition Products: Carbon dioxide, and other trace pyrolysis products typical of decomposition of any 

organic chemical. 

D. Hazardous Polymerization: N/A 

VII. Spill or Leak Procedures 

A. Steps to be taken if material is released or spilled : N/A 

B. 

Recycling Information : Armstrong Ceilings can be recycled through the Armstrong Ceiling Recycling Program. For more 

information on the program, requirements and local resources, please visit www.armstrong.com/ceilings/recycling or call our 

Recycling Center at 877-276-7876, press 1 (Ceilings), then press 8. 

If the Armstrong Ceilng Recycling Program cannot be used, please dispose in accordance with federal, state and local waste 

disposal regulations 

VIII. Special Protection Information 

During the installation, be certain that the work site is well ventilated, and avoid breathing dust. 

Wear long-sleeve, loose fitting clothes, gloves and eye protection. 

Handle these materials carefully to minimize airborne dust. 

If high dust levels are anticipated during installation, such as with the use of power tools, use the appropriate NIOSH approved 

dust respirator. 

All power cutting tools must be equipped with dust collectors. 

After using these materials, wash with warm water and mild soap. Do not scratch or rub skin if it becomes irritated. 

Wash work clothes separately, and then rinse the washer. 

The information presented herein is supplied as a guide to those who handle or use this product. Safe work practices must be 

employed when working with any materials. It is important that the end user makes a determination regarding the adequacy 

of the safety procedures employed during the use of this product.


Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards .This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard 

Communication Standard (29 CFR 1910.1200). Other government regulations must be reviewed for applicability to these products. 

WARNING: PRODUCT COMPONENTS PRESENT HEALTH AND SAFETY HAZARDS. READ AND UNDERSTAND THIS MATERIAL SAFETY DATA 

SHEET (M.S.DS.). ALSO, FOLLOW YOUR EMPLOYER’S SAFETY PRACTICES. This product may contain Chromium and/or Nickel which are listed 

by OSHA, NTP, or IARC as being a carcinogen or potential carcinogen. Use of this product may expose you or others to fumes and gases at levels 

exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational Safety and Health 

Administration (OSHA) The information contained herein relates only to the specific product. If the product is combined with other materials, all 

component properties must be considered. BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS. MATERIAL SAFETY DATA SHEETS ARE 

AVAILABLE FROM HARRIS PRODUCTS GROUP 513-754-2000 www.harrisproductsgroup.com 

STATEMENT OF LIABILITY-DISCLAIMER 

To the best of the Harris Products Group knowledge, the information and recommendations contained in this publication are reliable and accurate as of the 

date prepared. However, accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied, 

is made by Harris Products Group. as to the absolute correctness or sufficiency of any representation contained in this and other publications; Harris 

Products Group. assumes no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this and 

other publications, or that other or additional measures may not be required under particular or exceptional conditions or circumstances . Data may be 

changed from time to time.. 

PART I What is the material and what do I need to know in an emergency? 

1. PRODUCT IDENTIFICATION 

TRADE NAME (AS LABELED): HARRIS AMERICAN LFB / FC 

(formerly Welco 15 and Welco 15FC) 

CHEMICAL NAME/CLASS: Metal Alloy 

SYNONYMS: Not Applicable 

PRODUCT USE: Metal Brazing 

DOCUMENT NUMBER: 0123 

SUPPLIER/MANUFACTURER'S NAME: HARRIS PRODUCTS GROUP 

ADDRESS: 4501 Quality Place, Mason, Ohio 45040 

EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 

BUSINESS PHONE: 513-754-2000 FAX 513-754-8778 

DATE OF PREPARATION: July 20, 2010 

2. NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS 

These products consist of metal rods, some with a thin coating of flux on them. The exact amount of coating on each rod is unknown. It can be reasonably 

estimated that there is less than 1% of each of the flux constituents present on any given rod when compared to the mass of the rod itself. The composition 

values given for the flux coating are the composition of the flux when the rods are flux-coated. 

CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR 

ACGIH-TLV OSHA-PEL OTHER 

TWA STEL TWA STEL IDLH 

mg/m 3 

COMPONENT 1: METAL RODS 

Copper 

(exposure limits are 

for “Copper fume, as 

Cu”) 

7440-50-8 56 62 0.2 (fume) 

1 (dusts & 

mists) 

mg/m 3 

mg/m 3 

NE 0.1 

(fume) 

1 (dusts & 

mists) 

® 

mg/m 3 

mg/m 3 

mg/m 3 

NE 100 NIOSH REL: 

TWA = 0.1 

DFG MAK: 

TWA = 0.1 (Inhalable Fraction) 

PEAK = 2 MAK 30 min., average 

value 

Carcinogen: EPA-D 

NE = Not Established. See Section 16 for Definitions of Terms Used. 

NOTE (1): The ACGIH has an established exposure limit for Welding Fumes, Not Otherwise Classified. The Threshold Limit Value is 5 mg/m 3 . NIOSH 

classifies welding fumes as carcinogens. Single values shown are maximum, unless otherwise noted. 

Harris American LFB/FC (formerly WELCO 15-15 FC) EFFECTIVE DATE: December 16, 2003 

PAGE 1 OF 9

NOTE (2): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in 

accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. 

2. NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS (Continued) 


COMPONENT 1: METAL RODS (continued) 

Zinc 

Exposure limits given are 

for Zinc oxide, Fume & 

Dust 

ACGIH-TLV OSHA-PEL NIOSH OTHER 


mg/m 3 

7440-66-6 Balance 5 (fume) 

10 (dust) 

mg/m 3 

10 

(fume) 


PAGE 2 OF 9 

mg/m 3 

5 (fume) 

5 (total dust) 

15 (dust, 

respirable 

dust) 

5 (dust, 

respirable 

dust, 

Vacated 

1989 PEL) 

mg/m 3 

10 (fume, 

Vacated 

1989 PEL) 

mg/m 3 

mg/m 3 

500 NIOSH RELs: 

TWA = 5 (fume & dusts) 

STEL = 10 (fume), 15 

(ceiling, 15 minutes, 

dusts) 

DFG MAKs: 

TWA = 1.5 (Respirable 

fraction, fume) 


Tin 7440-31-5 0.30-1.5 2 NE 2 NE 100 NIOSH REL: 2 

Manganese 

(exposure limits are for 

Manganese, elemental 

and inorganic 

compounds, and fume 

as Mn) 

Iron 


iron oxide dust and fume 

[Fe2O3], as Fe) 

7439-96-5 0.50 0.2 NE 1 (vacated 

1989 PEL) 

1309-37-1 1.0 5, A4 (Not 

Classifiable 

as a Human 

Carcinogen) 

Silicon 7440-21-3 0.50 10 NE 15 (Total 

dust) 

5 (Respirable 

fraction) 

10 (Total 

dust) 

(vacated 

1989 PEL) 

COMPONENT 2: FLUX COATING ON RODS 

5 (ceiling) 

3 (vacated 

1989 PEL) 


TWA = 1 

STEL = 3 

DFG MAK: 

TWA = 0.5 (Inhalable 

Fraction) 

PEAK = 10 MAK 30 min., 

average value 

DFG MAK Pregnancy 

Risk Classification: C 


NE 10 NE 2500 NIOSH REL: 

TWA = 5 

DFG MAK: 

TWA = 6 (Respirable 

Fraction) 

Carcinogen: IARC-3, 

TLV-A4 

NE NE NIOSH REL: 

TWA = 10 (Total dust; 5 

(Respirable fraction) 

Boric Acid 10043-35-3 50-80 NE NE NE NE NE NE 

Methacrylate/Aliphatic & 

Naphthenic Hydrocarbon 

Compound 

Proprietary NE NE NE NE NE NE 

Borax Glass 

(the exposure limits are 

for Borates, anhydrous) 

1303-96-4 10-30 1 NE 10 (Vacated 

1989 PEL) 


TWA = 1 





accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

3. HAZARD IDENTIFICATION 

EMERGENCY OVERVIEW: This product consists of bare or coated, odorless, solid bronze rods. There are no immediate 

health hazards associated with this product. This product is not flammable nor reactive. If involved in a fire, this product 

may generate irritating fumes and a variety of metal oxides. Emergency responders must wear personal protective 

equipment suitable for the situation to which they are responding. 

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: 

During brazing operations, the most significant route of overexposure 

is via inhalation of fumes. 

INHALATION: Inhalation is not anticipated to be a significant route of 

over-exposure to the rods. Inhalation of large amounts of particulates 

generated by this product during metal processing operations may 

result in irritation. Inhalation of copper oxide and zinc oxide fumes 

can cause metal fume fever. Initial symptoms of metal fume fever 

can include a metallic or sweet taste in the mouth, dryness or 

irritation of the throat, and coughing. Later symptoms (after 4-48 

hours) can include sweating, shivering, headache, fever, chills, 

thirstiness, muscle aches, nausea, vomiting, weakness, and 

tiredness. Repeated over-exposures, via inhalation, to the dusts or 

fumes generated by this product during brazing operations may have 

adverse effects on the lungs with possible pulmonary edema and 

emphysema (life-threatening lung injuries). Chronic over-exposure to 

Copper dust may cause tiredness, stuffiness, diarrhea, and vomiting. 

Refer to Section 10 (Stability and Reactivity) for information on the 

specific composition of brazing fumes and gases. 

CONTACT WITH SKIN or EYES: Contact of the rod form of this 

product with the skin is not anticipated to be irritating. Rare cases of 

allergic contact dermatitis have been reported in people working with 

copper dust. Contact with the rod form of this product can be 

physically damaging to the eye (i.e., foreign object). Fumes 

generated during brazing operations can be irritating to the skin and 

eyes. Symptoms of skin over-exposure may include irritation and 

redness; prolonged or repeated skin over-exposures may lead to 

allergic contact dermatitis. Contact with the molten rods will burn 

contaminated skin or eyes. 

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM 

HEALTH 

FLAMMABILITY 

REACTIVITY 

PROTECTIVE EQUIPMENT 

EYES RESPIRATORY HANDS BODY 

See 

Section 8 

(BLUE) 

(RED) 

(YELLOW) 

For routine industrial applications for the rods 

0 

0 

0 

X 

See 

Section 8 

See Section 16 for Definition of Ratings 

SKIN ABSORPTION: Skin absorption is not known to be a 

significant route of over-exposure for any component of this product. 

INGESTION: Ingestion is not anticipated to be a route of occupational exposure for this product. 

INJECTION: Though not a likely route of occupational exposure for this product, injection (via punctures or lacerations in the 

skin) may cause local reddening, tissue swelling, and discomfort. 

HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Symptoms associated with overexposure 

to this product and the fumes generated during brazing operations are as follows: 

ACUTE: The chief acute health hazard associated with this product would be the potential for irritation of contaminated skin 

and eyes when exposed to fumes during brazing operations. Inhalation of large amounts of particulates generated by this 

product during metal processing operations may result in irritation. Inhalation of copper oxide and zinc oxide fumes can 

cause metal fume fever. Inhalation of large amounts of particulates generated by this product during metal processing 

operations can result in pneumoconiosis (a disease of the lungs). Contact with the molten material will burn contaminated 

skin or eyes. Severe ingestion over-exposure to Copper (a component of this product) may be fatal. 

CHRONIC: Chronic skin over-exposure to the fumes of this product during brazing operations may produce dermatitis (red, 

inflamed skin). Chronic over-exposure to Copper dust may cause tiredness, stuffiness, diarrhea, vomiting, discoloration of 

the skin and eyes, and kidney and liver disorder. Additionally, rare cases of allergic contact dermatitis have been reported in 

people working with copper dust. Refer to Section 11 (Toxicological Information) for further information. 

TARGET ORGANS: For fumes: Skin, eyes, respiratory system, kidney and liver. 


PAGE 3 OF 9

PART II What should I do if a hazardous situation occurs? 

4. FIRST-AID MEASURES 

Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if 

necessary. Take a copy of label and MSDS to health professional with victim. 

SKIN EXPOSURE: If fumes generated by Brazing operations involving this product contaminate the skin, begin 

decontamination with running water. If molten material contaminates the skin, immediately begin decontamination with cold, 

running water. Minimum flushing is for 15 minutes. Victim must seek medical attention if any adverse reaction occurs. 

EYE EXPOSURE: If fumes generated by Brazing operations involving this product enter the eyes, open victim's eyes while 

under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. 

Victim must seek immediate medical attention. 

INHALATION: If fumes generated by Brazing operations involving this product are inhaled, remove victim to fresh air. If 

necessary, use artificial respiration to support vital functions. 

INGESTION: Ingestion is not a likely route of exposure for the rods. If the flux is swallowed, CALL PHYSICIAN OR 

POISON CONTROL CENTER FOR THE MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless 

directed by medical personnel. Have victim rinse mouth with water if conscious. Never induce vomiting or give diluents 

(milk or water) to someone who is unconsciousness, having convulsions, or unable to swallow. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory disorders, pancreas and liver disorders may 

be aggravated by prolonged over-exposures to the dusts or fumes generated by these products. 

RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. 

5. FIRE-FIGHTING MEASURES 

FLASH POINT: Not flammable. 

AUTOIGNITION TEMPERATURE: Not flammable. 

NFPA RATING 

FLAMMABLE LIMITS (in air by volume, %): 

Lower (LEL): Not applicable. 

FLAMMABILITY 

Upper (UEL): Not applicable. 

0 

FIRE EXTINGUISHING MATERIALS: 

Water Spray: YES Carbon Dioxide: YES 

HEALTH 0 0 

Halon: YES Foam: YES 

Dry Chemical: YES Other: Any "ABC" Class 

UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire, this 

product may generate irritating fumes and a variety of metal compounds. The 

molten material can present a significant thermal hazard to firefighters. 

Explosion Sensitivity to Mechanical Impact: Not sensitive. 

Explosion Sensitivity to Static Discharge: Not sensitive. 

SPECIAL FIRE-FIGHTING PROCEDURES: Not applicable for these products. 


SPILL AND LEAK RESPONSE: Not applicable 

OTHER 

See Section 16 for 

Definition of Ratings 

REACTIVITY 

PART III How can I prevent hazardous situations from occurring 

7. HANDLING and STORAGE 

WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. 

Wash thoroughly after handling this product. Do not eat or drink while handling this product. Use in a well ventilated 

location. Use ventilation and other engineering controls to minimize potential exposure to this product. 

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. 

Avoid breathing fumes of this product during brazing operations. Open containers on a stable surface. Packages of this 

product must be properly labeled. When this product is used during brazing operations, follow the requirements of the 

Federal Occupational Safety and Health Welding and Cutting Standard (29 CFR 1910 Subpart Q) and the safety standards 

of the American National Standards Institute for welding and cutting (ANSI Z49.1). 


PAGE 4 OF 9

7. HANDLING and STORAGE (Continued) 

STORAGE AND HANDLING PRACTICES (continued): Store packages in a cool, dry location. Storage in an atmosphere 

that is wet, moist, or highly humid may lead to corrosion of this product. Store away from incompatible materials (see 

Section 10, Stability and Reactivity). 

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Not applicable. 

8. EXPOSURE CONTROLS - PERSONAL PROTECTION 

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained 

below the limits provided in Section 2 (Composition and Information on Ingredients). Prudent practice is to ensure 

eyewash/safety shower stations are available near areas where this product is used. 

RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in Section 2 

(Composition and Information on Ingredients). If respiratory protection is needed (i.e., a Weld Fume Respirator or Air-Line 

Respirator for brazing in confined spaces), use only protection authorized in 29 CFR 1910.134 or applicable State 

regulations. Respiratory Protection is recommended to be worn during brazing operations. Use supplied air respiration 

protection if oxygen levels are below 19.5% or are unknown. The following are NIOSH recommendations for respirator 

selection for welding fumes (which would also be applicable for brazing operations), based on NIOSH REL: 

CONCENTRATION RESPIRATORY EQUIPMENT FOR WELDING FUMES 

At Concentrations above the NIOSH REL, or where there is no REL, at any Detectable Concentration: Any self-contained 

breathing apparatus that has a full facepiece and is operated in a pressure-demand or other 

positive-pressure mode; or any supplied-air respirator that has a full facepiece and is operated in 

a pressure-demand or other positive-pressure mode in combination with an auxiliary selfcontained 

breathing apparatus operated in pressure-demand or other positive-pressure mode. 

Escape: Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted 

organic vapor canister having a high-efficiency particulate filter; or any appropriate escape-type, 

self-contained breathing apparatus 

NOTE: IDLH Concentration: Potential NIOSH carcinogen. [Not determined yet]. 

EYE PROTECTION: Safety glasses. When these products are used in conjunction with Brazing, wear safety glasses, 

goggles, or face-shield with filter lens of appropriate shade number (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). 

If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian Standards. 

HAND PROTECTION: Wear gloves for routine industrial use. When these products are used in conjunction with Brazing, 

wear gloves that protect from sparks and flame (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). If necessary, refer 

to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada. 

BODY PROTECTION: Use body protection appropriate for task. If a hazard of injury to the feet exists due to falling objects, 

rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical 

hazards, as described in U.S. OSHA 29 CFR 1910.136. 

9. PHYSICAL and CHEMICAL PROPERTIES 

The following information is for Copper, a main component of this product, unless otherwise indicated: 

RELATIVE VAPOR DENSITY (air = 1): Not applicable. EVAPORATION RATE (nBuAc = 1): Not applicable. 

SPECIFIC GRAVITY (water = 1): 8.3-8.5 g/cc (For product) pH: Not applicable. 

SOLUBILITY IN WATER: Insoluble. ODOR THRESHOLD: Not applicable. 

VAPOR PRESSURE, mm Hg @ 20 C: Not applicable. BOILING POINT: 2595°C (4703°F) 

FREEZING/MELTING POINT: 1600-1900°C (871-1038°F) [For product] 

COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable. 

The following information is for Zinc, a main component of this product: 


SPECIFIC GRAVITY (water = 1): 7.14 pH: Not applicable. 



FREEZING/MELTING POINT: 149°C (786°F) 

COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable 

The following information is for the product: 

APPEARANCE AND COLOR: This product consists of bare or coated, odorless bronze rods. 

HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinctive characteristic of this 

product. 


PAGE 5 OF 9

10. STABILITY and REACTIVITY 

STABILITY: Stable. 

DECOMPOSITION PRODUCTS: Thermal decomposition products can include copper and zinc compounds and a variety of 

metal oxides. 

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids, strong oxidizers, some halogenated 

compounds. 

HAZARDOUS POLYMERIZATION: Will not occur. 

CONDITIONS TO AVOID: Uncontrolled exposure to extreme temperatures, incompatible materials. 

PART IV Is there any other useful information about this material? 


TOXICITY DATA: Presented below are human toxicological data available for the components of this product present in 

concentration greater than 1%. Other data for animals are available for the components of this product, but are not 

presented in this Material Safety Data Sheet. 

BORIC ACID: 

Skin Irritancy (human) = 15 mg/ 3 days/ 

intermittent; mild 

LD (oral, human) = 37 mg/kg/ boron as boric acid 

LD (skin, infant) = 210 mg/kg/ boron as boric acid 

TDLo (oral, child) = 500 mg/kg; gastrointestinal 

effects 

LDLo (oral, man) = 429 mg/kg; cardiovascular, 

systemic effects 

LDLo (oral, woman) = 200 mg/kg 

BORIC ACID (continued): 

TDLo (oral, infant) = 800 mg/kg/ 4 weeks/ 

intermittent 

LDLo (oral, infant) = 934 mg/kg 

LDLo (skin, infant) = 1200 mg/kg 

LDLo (skin, child) = 4000 mg/kg/ 4 days 

LDLo (skin, man) = 2430 mg/kg 

LDLo (skin, child) = 1500 mg/kg 

LDLo (subcutaneous, infant) = 1100 mg/kg 

TDLo (unreported, man) = 170 mg/kg; 

gastrointestinal effects 

LDLo (unreported, man) = 147 mg/kg 

COPPER: 

TDLo (oral, human) = 120 g/kg; gastrointestinal 

tract effects 

ZINC: 

Skin Irritancy (human) = 300 g/ 3 days/ 


TCLo (inhalation, human) = 124 mg/m 3 / 50 

minutes; pulmonary system, skin effects 

SUSPECTED CANCER AGENT: The components of this product are listed as follows: 

MANGANESE: EPA-D, Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available). 

COPPER: EPA-D, Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available). 

The other components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and 

CAL/OSHA and therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies. 

IRRITANCY OF PRODUCT: This product’s dusts or fumes may be irritating to contaminated skin and eyes. Fumes may be 

irritating to the respiratory system. 

SENSITIZATION TO THE PRODUCT: Rare cases of allergic contact dermatitis have been reported in people working with 

copper dust. 

REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its 

components on the human reproductive system. 

Mutagenicity: This product is not reported to produce mutagenic effects in humans. Animal mutation data are available 

for the Boric Acid component of this product; these data were obtained during clinical studies on specific animal tissues 

exposed to high doses of this compound. 

Embryotoxicity This product is not reported to produce embryotoxic effects in humans. 

Teratogenicity: This product is not reported to cause teratogenic effects in humans. Clinical studies on test animals 

exposed to relatively high doses of the Copper component of this product indicate teratogenic effects. 

Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. Clinical studies on test 

animals exposed to relatively high doses of the Boric Acid and Copper components of this product indicate adverse 

reproductive effects. 

A mutagen is a chemical, which causes permanent changes to genetic material (DNA) such that the changes will propagate 

through generational lines. An embryotoxin is a chemical, which causes damage to a developing embryo (i.e., within the first eight 

weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical, which 

causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is 

any substance, which interferes in any way with the reproductive process. 

BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) associated with the 

components of this product. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory disorders, kidney and liver disorders may be 

aggravated by prolonged over-exposures to the dusts or fumes generated by this product. 



PAGE 6 OF 9


ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. 

ENVIRONMENTAL STABILITY: The components of this product are expected to persist in the environment for an extended 

period of time. Copper and Zinc will react with water and air to form a variety of stable oxides. Additional environmental data 

are available as follows: 

ZINC: Solubility: Insoluble in water. Biological Half-Life for normal humans 162-500 days. Bioconcentration: The Bioconcentration Factor in edible 

portions of Crassostrea virgina, adult oyster) is 16,700 (total zinc). 

COPPER: Solubility: Insoluble. There is no evidence of any biotransformation for copper compounds. Copper is accumulated by all plants and animals. 

BCF Algae = 12; plants = 1,000; invertebrate = 1,000, fish = 667 and fish =200(Soluble copper salts). 

EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not expected to cause adverse effects on plant or 

animal life. Specific data on test animals are available but are not presented in this Material Safety Data Sheet. 

EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may cause adverse effects on aquatic life. Additional 

environmental data are available as follows: 

BORIC ACID: 

LC50 (trout eggs) = 100 ppm/ soft 

LC50 (trout eggs) = 79 ppm/ hard 

LC50 (catfish eggs) = 155 ppm/ soft 

LC50 (catfish eggs) = 22 ppm/ hard 

LC50 (goldfish eggs) = 46 ppm/ soft 

LC50 (goldfish eggs) = 75 ppm/ hard 

LC50 (Daphnia magna) = 133 mg/L/ 48 hours 

COPPER: Copper is concentrated by plankton by 1000 or more. Copper 

may concentrate to toxic levels in the food chain. 

ZINC: Odorless zinc poisoning causes inflamed gills in fish. Laboratory 

studies of Atlantic salmon, rainbow trout, carp, and goldfish have shown 

avoidance reactions by these fish to zinc in water. 


PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local 

regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your 

local hazardous waste regulatory authority. 

EPA WASTE NUMBER: Not applicable to waste consisting only of this product. 

14. TRANSPORTATION INFORMATION 

THIS PRODUCT IS NOT HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION. 

PROPER SHIPPING NAME: Not applicable. 

HAZARD CLASS NUMBER and DESCRIPTION: Not applicable. 

UN IDENTIFICATION NUMBER: Not applicable. 

PACKING GROUP: Not applicable. 

DOT LABEL(S) REQUIRED: Not applicable. 

NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: Not applicable. 

MARINE POLLUTANT: No component of this product is designated as a marine pollutant by the Department of 

Transportation (49 CFR 172.101, Appendix B). 

TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not considered 

as dangerous goods, per regulations of Transport Canada. 


ADDITIONAL U.S. REGULATIONS: 

U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of 

Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows: 

CHEMICAL NAME SARA 302 

(40 CFR 355, Appendix A) 

SARA 304 

(40 CFR Table 302.4) 

SARA 313 

(40 CFR 372.65) 

Copper No Yes Yes 

Manganese No No Yes 

Zinc No Yes Yes (fume or dust) 

U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component 

of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may 

apply, per 40 CFR 370.20. 

U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. 

U.S. CERCLA REPORTABLE QUANTITY (RQ): Copper = 5000 lbs; Zinc = 1000 lbs. (for metal particles under 100 

micrometers in diameter). 


PAGE 7 OF 9

15. REGULATORY INFORMATION (Continued) 

ADDITIONAL U.S. REGULATIONS (continued): 

OTHER U.S. FEDERAL REGULATIONS: Not applicable. 

U.S. STATE REGULATORY INFORMATION: The components of this product are covered under specific State regulations, 

as denoted below: 

Alaska-Designated Toxic and Hazardous 

Substances: Copper Fume, Dust, & Mist, 

Manganese, Tin. 

California-Permissible Exposure Limits for 

Chemical Contaminants: Copper, Manganese, 

Silicon, Tin. 

Florida-Substance List: Copper Fume, Dust, & 

Mist, Manganese, Tin, Zinc. 

Illinois-Toxic Substance List: Copper, 

Manganese, Silicon, Zinc. 

Kansas-Section 302/313 List: Copper, 

Manganese, and Zinc. 

Massachusetts-Substance List: Copper, 

Manganese, Tin, Zinc. 

Michigan-Critical Materials Register: Copper. 

Minnesota-List of Hazardous Substances: 

Copper Dust & Mists, Manganese, Silicon, Tin. 

Missouri-Employer Information/Toxic 

Substance List: Copper, Manganese, Silicon, 

Tin. 

New Jersey-Right to Know Hazardous 

Substance List: Copper, Manganese, Tin, Zinc. 

North Dakota-List of Hazardous Chemicals, 

Reportable Quantities: Copper, Zinc. 

Pennsylvania-Hazardous Substance List: 

Copper, Manganese, Silicon, Tin, Zinc. 

Rhode Island-Hazardous Substance List: 

Copper Fume, Dust, & Mist, Manganese, 

Silicon, Tin, Zinc. 

Texas-Hazardous Substance List: Copper 

Fume, Manganese. 

West Virginia-Hazardous Substance List: 

Copper Fume, Manganese. 

Wisconsin-Toxic and Hazardous Substances: 


CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This 

product may contain chemicals, and when used for welding or brazing may produce fumes or gases containing 

chemicals, known to the State of California to cause cancer, and/or birth defects (or other reproductive harm.) 

LABELING (Precautionary Statements): CAUTION! 

WARNING: PROTECT yourself and others. Read and understand this information. 

FUMES AND GASES can be hazardous to your health. 

HEAT RAYS (INFRARED RADIATION) from flame or hot metal can injure your eyes. 

Before Use, read and understand the manufacturer’s instructions. Material Safety Data Sheets (MSDSs), and your 

employer’s safety policies. 

Keep your head out of the fumes. 

Use enough ventilation, exhaust at the flame, or both, to keep fumes and gases from your breathing zone and the 

general area. 

Wear correct eye, ear, and body protection. 

See American National Standard Z49.1 Safety in Welding, Cutting, and Allied Processes, published by the American 

Welding Society, 550 N.W. LeJeune Road, Miami, Florida 33126. OSHA Safety and Health Standards, available 

from the U.S. Government Printing Office, Washington, DC 20402. 

DO NOT REMOVE THIS INFORMATION. 

ADDITIONAL CANADIAN REGULATIONS: 

CANADIAN DSL/NDSL INVENTORY STATUS: The components of these products are on the DSL Inventory. 

OTHER CANADIAN REGULATIONS: Not applicable. 

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No components are on 

the CEPA Priority Substance Lists. 

CANADIAN WHMIS SYMBOLS: Not applicable. 


PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc. 

9163 Chesapeake Drive, San Diego, CA 92123-1002 

858/565-0302 

DATE OF PRINTING: August 26, 2010 

This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard (29 CFR 1910.1200). Other government regulations 

must be reviewed for applicability to this product. The information contained herein relates only to the specific product. If the product is combined with 

other materials, all component properties must be considered. To the best of the Harris Products Group knowledge, the information and 

recommendations contained in this publication are reliable and accurate as of the date of issue. However, accuracy, suitability, or completeness are not 

guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by Harris Products Group. as to the absolute correctness or 

sufficiency of any representation contained in this and other publications; J.W. Harris Co., Inc. assumes no responsibility in connection therewith; nor 

can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances. Data may be 

changed from time to time. Be sure to consult the latest edition. 


PAGE 8 OF 9

DEFINITIONS OF TERMS 

A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: 

CAS #: This is the Chemical Abstract Service Number, which uniquely identifies each constituent. 

EXPOSURE LIMITS IN AIR: 

ACGIH - American Conference of Governmental Industrial Hygienists, a 

professional association which establishes exposure limits. TLV - 

Threshold Limit Value - an airborne concentration of a substance, which 

represents conditions under which it is generally believed that nearly all 

workers, may be repeatedly exposed without adverse effect. The duration 

must be considered, including the 8-hour Time Weighted Average (TWA), 

the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling 

Level (C). Skin absorption effects must also be considered. 

OSHA - U.S. Occupational Safety and Health Administration. 

PEL - Permissible Exposure Limit - This exposure value means exactly 

the same as a TLV, except that it is enforceable by OSHA. The OSHA 

Permissible Exposure Limits are based in the 1989 PELs and the June, 

1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 

40191). Both the current PELs and the vacated PELs are indicated. The 

phrase, “Vacated 1989 PEL,” is placed next to the PEL, which was 

vacated by Court Order. IDLH - Immediately Dangerous to Life and 

Health - This level represents a concentration from which one can escape 

within 30-minutes without suffering escape-preventing or permanent 

injury. The DFG - MAK is the Republic of Germany’s Maximum Exposure 

Level, similar to the U.S. PEL. NIOSH is the National Institute of 

Occupational Safety and Health, which is the research arm of the U.S. 

Occupational Safety and Health Administration (OSHA). NIOSH issues 

exposure guidelines called Recommended Exposure Levels (RELs). 

When no exposure guidelines are established, an entry of NE is made for 

reference. 

HAZARD RATINGS: 

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health 

Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or 

chronic exposure hazard); 2 (moderate acute or significant chronic 

exposure hazard); 3 (severe acute exposure hazard; onetime 

overexposure can result in permanent injury and may be fatal); 4 

(extreme acute exposure hazard; onetime overexposure can be fatal). 

Flammability Hazard: 0 (minimal hazard); 1 (materials that require 

substantial pre-heating before burning); 2 (combustible liquid or solids; 

liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC 

flammable liquids with flash points below 38 C [100 F]); 4 (Class IA 

flammable liquids with flash points below 23 C [73 F] and boiling points 

below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material 

that can become unstable at elevated temperatures or which can react 

slightly with water); 2 (materials that are unstable but do not detonate or 

which can react violently with water); 3 (materials that can detonate when 

initiated or which can react explosively with water); 4 (materials that can 

detonate at normal temperatures or pressures). 

NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 

(material that on exposure under fire conditions would offer no hazard 

beyond that of ordinary combustible materials); 1 (materials that on 

exposure under fire conditions could cause irritation or minor residual 

injury); 2 (materials that on intense or continued exposure under fire 

conditions could cause temporary incapacitation or possible residual 

injury); 3 (materials that can on short exposure could cause serious 

temporary or residual injury); 4 (materials that under very short exposure 

causes death or major residual injury). Flammability Hazard and 

Reactivity Hazard: Refer to definitions for “Hazardous Materials 

Identification System”. 

FLAMMABILITY LIMITS IN AIR: 

Much of the information related to fire and explosion is derived from the 

National Fire Protection Association (NFPA). Flash Point - Minimum 

temperature at which a liquid gives off sufficient vapors to form an 

ignitable mixture with air. Autoignition Temperature: The minimum 

temperature required to initiate combustion in air with no other source of 

ignition. LEL - the lowest percent of vapor in air, by volume, that will 

explode or ignite in the presence of an ignition source. UEL - the highest 

percent of vapor in air, by volume, that will explode or ignite in the 

presence of an ignition source. 

TOXICOLOGICAL INFORMATION: 

Human and Animal Toxicology: Possible health hazards as derived 

from human data, animal studies, or from the results of studies with 

similar compounds are presented. Definitions of some terms used in this 

section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the 

exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of 

the exposed animals; ppm concentration expressed in parts of material 

per million parts of air or water; mg/m 3 concentration expressed in weight 

of substance per volume of air; mg/kg quantity of material, by weight, 

administered to a test subject, based on their body weight in kg. Other 

measures of toxicity include TDLo, the lowest dose to cause a symptom 

and TCLo the lowest concentration to cause a symptom; TDo, LDLo, 

and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) 

to cause lethal or toxic effects. Cancer Information: The sources are: 

IARC - the International Agency for Research on Cancer; NTP - the 

National Toxicology Program, RTECS - the Registry of Toxic Effects of 

Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate 

chemicals on a scale of decreasing potential to cause human cancer with 

rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other 

Information: BEI - ACGIH Biological Exposure Indices, represent the 

levels of determinants which are most likely to be observed in specimens 

collected from a healthy worker who has been exposed to chemicals to 

the same extent as a worker with inhalation exposure to the TLV. 

Ecological Information: EC is the effect concentration in water. BCF = 

Bioconcentration Factor, which is used to determine if a substance will 

concentrate in lifeforms which consume contaminated plant or animal 

matter. Coefficient of Oil/Water Distribution is represented by log Kow 

or log Koc and is used to assess a substance’s behavior in the 

environment. 

REGULATORY INFORMATION: 

This section explains the impact of various laws and regulations on the 

material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is 

the U.S. Department of Transportation. SARA is the Superfund 

Amendments and Reauthorization Act. TSCA is the U.S. Toxic 

Substance Control Act. CERCLA (or Superfund) refers to the 

Comprehensive Environmental Response, Compensation, and Liability 

Act. Labeling is per the American National Standards Institute (ANSI 

Z129.1). CANADA: CEPA is the Canadian Environmental Protection 

Act. WHMIS is the Canadian Workplace Hazardous Materials 

Information System. TC is Transport Canada. DSL/NDSL are the 

Canadian Domestic/Non-Domestic Substances Lists. The CPR is the 

Canadian Product Regulations. This section also includes information 

on the precautionary warnings, which appear, on the materials package 

label. 


PAGE 9 OF 9

BRODI SPECIALTY PRODUCTS LTD. 


SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Product Name: MICROFLO Date Prepared: January 1 st , 2009 

Product Number: 0931-23-002B Emergency Phone: 1-(800) 228-5635 

Chemical Family: Halogenated hydrocarbons Information Phone: 1-(877) 744-0751 

Molecular Weight: Not Applicable Supplier's Name: Brodi Specialty Products Ltd. 

Chemical Formula: Not Applicable Supplier's Address: 250 Cochrane Drive, Unit 9, Markham, ON, L3R 8E5 

Trade names and synonyms: 0931-23-002B Powerflo Prepared By: MSDS Co-ordinator, (877) 744-0751 ext 205, Brodi Specialty Products Ltd. 

Product Uses: Degreaser /Cleaner 

Formula/lab book #: Form – 9910-2-251 

SECTION 2: COMPOSTITION/INFORMATION INGREDIENTS 

Hazardous Ingredients % Exposure Limit C.A.S # LD/50 Route, Species LD/50 Route, Species 

1,1,1,2 – Tetrafluoroethane 60-100 1000 ppm 811-97-2 Not Available 567000 ppm (4hr) INHAL- RAT 

Acetone 1-5 750ppm 67-64-1 9750 mg/kg ORAL-RAT 16,000 ppm (4hr) INHAL-RAT 

SECTION 3: HAZARDS IDENTIFICATION 

Route of Entry 

INGESTION………………………………………….….…....Product is a gas, therefore, ingestion is not likely a route of exposure 

INHALATION……………………………………………….…Propellant is a simple asphyxiant 

EYE CONTACT…………………………………………..…...May cause irritation 

SKIN ABSORBTION……………………………………..……No data available for this product mixture 

SKIN CONTACT………………………………………….…...May cause irritation. May cause frostbite 

EFFECTS OF ACUTE EXPOSURE…………………..…….Dizziness, nausea, irritation to skin and eyes 

EFFECTS OF CHRONIC EXPOSURE………………….…..None known 

EXPOSURE LIMIT OF MATERIAL……………………………See section 2 


EMERGENCY FIRST AID PROCEDURE…In case of eye contact, flush immediately with plenty of water for at least 15 minutes and get medical attention. 

For skin, wash thoroughly with soap and water. If affected by inhalation of vapour or spray mist, remove to fresh air. If swallowed do not induce vomiting, get medical attention 

SECTION 5: FIRE FIGHTING MEASURES 

AUTO IGNITION TEMPERATURE (°C) ………………….…465 

SPECIAL PROCEDURES…………………………….………Water from fogging nozzles may be used to cool closed containers to prevent build up if exposed to extreme 

temperatures. 

Full protective equipment including self contained breathing apparatus should be worn in a fire involving this material. 

FLAMMABILITY………………………………………………...Not a flammable product (as per Canadian aerosol regulations) 

IF YES UNDER WHAT CONDITIONS?...............................Excessive heat, sparks and open flame 

EXTINGUISHING MEDIA…………………………………......Water, carbon dioxide, dry chemical, foam. 

UPPER FLAMMABLE LIMIT (% BY VOLUME)………….....12.8 

LOWER FLAMMABLE LIMIT (% BY VOLUME)…………….1 


SENSITIVITY TO DISCHARGE……………………….….…..Not applicable 

SENSITIVITY TO IMPACT……………………….………...…Not applicable 

HAZARDOUS COMBUSTION PRODUCTS………………...Hydrocarbon fumes and smoke, carbon monoxide where combustion is incomplete 

AEROSOL FLAME PROTECTION 

CLASSIFIED AS………………………………………………..0 cm 

FLASHBACK……………………………………………………NONE 

FLASH POINT (°C). TAG CLOSED –CUP………………….NONE. LOWEST KNOWN VALUE IS ACETONE @ - 18C 

(CONCENTRATE) 

SECTION 6: ACCIDENTAL RELEASE MEASURES 

LEAK/SPILL…………………………………………….…Remove all sources of ignition, use an inert absorbent material, and non – sparking tools. Ventilate area prevent from 

entering a watercourse. 

SECTION 7: HANDLING AND STORAGE 

STORAGE NEEDS………………………….……………………Keep away from heat, sparks, and open flames. 

ENGINEERING CONTROLS…………………………………...Ventilation – local (mechanical if used indoors on a continous basis) 

HANDLING PROCEDURES AND EQUIPMENT…………….Store in a cool, well ventilated area not to exceed 50 °C 

SYNERGISTIC MATERIALS……………………………………None Known 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

GLOVES/TYPE………………………………………………….…Wear chemical resistant gloves 

RESPIRATORY/TYPE……………………………………………If used indoors on a continuous basis, use of a cartridge type respirator (NIOSH/MSHATC 23C or 

equivalent) is recommended 

EYE/TYPE………………………………………………………..Safety glasses 

FOOTWEAR/TYPE……………………………………….………Not normally required 

OTHER/TYPE…………………………………………….……….Not required 

Microflo MSDS Page 1 of 2

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 

PHYSICAL STATE………………………….…..…..………………Aerosol 

APPEARANCE……………………………….……..……………….Colourless 

ODOR………………………………………….……………………..Ethereal 

ODOR THRESHOLD……………………..…..………..………...Not available 

VAPOUR PRESSURE (PSIG)-AEROSOL AT 20 °C….…….…65-75 

BOILING POINT (°C)(CONC)…………………………….….....57 

EVAPORATION RATE n-BUTYL ACETATE = 1………………..Not available 

VAPOUR DENSITY (AIR=1)………………..….…………......…Greater than 1 

(BY WEIGHT) 

SOLUBILITY IN WATER g/l (20°C)………………………….…..0.15 

pH…………………………………………………………………….Not available 

SPECIFIC GRAVITY (LIQUID)…………………………………..Not available 

COEFFICIENT OF WATER/OIL DIST…………………..……..Not available 

FREEZING POINT: (°C)………………………………………….-117 

AEROSOL PERCENT VOLATILE(BY WEIGHT)………………100 

SECTION 10: STABILITY AND REACTIVITY 

HAZARDOUS PRODUCTS OF DECOMPOSITION………... Hydrocarbon fumes and smoke. Carbon monoxide where combustion is incomplete. 


YES……………………………………………………………..….Under normal conditions 

NO, WHICH CONDITIONS?…………………………………….Not applicable 


NO, WHICH ONES?................................................................Strong oxidizing agents 

REACTIVITY CONDITIONS?..................................................Not applicable 

HAZARDOUS POLYMERIZATION……………………………..Will not occur 

SECTION 11: TOXICOLOGICAL INFORMATION 

REPRODUCTIVE EFFECTS…………………………………..No information is available and no adverse reproductive effects are anticipated 

IRRITATION OF MATERIAL………………………………….Skin/eye irritant 

SENSITIZING CAPABILITY OF MATERIAL………………..Unknown 

CARCINOGENICITY OF MATERIAL………………………...The ingredients of this product are not listed as carcinogens by NTP. (National Toxicology program), 

not regulated as carcinogens by OSHA (Occupational Safety and Health Administration), and have not 

been evaluated by IARC (International Agency for Research on Cancer), nor by ACGIH( American 

Conference of Governmental Industrial Hygienists). 

TERATOGENICITY……………………………. …………….....No information is available and no adverse teratogenic effects are anticipated. 

MUTAGENICITY……………………………………………..…No information is available and no adverse mutagenic effects are anticipated 

SECTION 12: ECOLOGICAL CONSIDERATIONS 

ENVIRONMENTAL………………………………………………..Not available 

SECTION 13: DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL………………………………………………Do not puncture or incinerate containers, even when empty. Dispose of in accordance with local, provincial, 

and 

federal regulations. 

SECTION 14: TRANSPORTATION INFORMATION 

T D G CLASSIFICATION…………………………………….Consumer commodity (aerosols, UN1950, class 2.2) 

D O T CLASSIFICATION…………………………….……..Consumer commodity ORM-D 

SECTION 15: REGULATORY INFORMATION 

CANADIAN REGULATIONS 

WHMIS CLASSIFICATION……………………….……….….….A,D2B 

CNFC SECTION 3.3.5…………………………..............….……LEVEL 1 

CEPA (CANADIAN ENVIRONMENTAL PROTECTION ACT)…All substances in this product are listen on the Canadian domestic substances list. (DSL) or are not required 

to be listed. 

U.S REGULATIONS 

HMIS RATING HEALTH…………………………………………..1 slight hazard 

HMIS RATING FLAMMABILITY………………………………….0 minimal hazard 

HMIS RATING REACTIVITY……………………………………..1 slight hazard 

HMIS RATING PERSONAL PROTECTION…………………....B 

NFPA COE 30B……………………………………………………Level 1 

SARA 313 INFORMATION………………………………………This product contains no ingredients subject to the reporting requirements of section 313 of the emergency 

planning and community right-to-know act of 1986 and of 40 CFR 372 

CAS # CHEMICAL NAME 

N/A 

CALIFORNIA PROPOSITION 65………………………………..The following statement is made in order to comply with the California safe drinking water and toxic 

enforcement 

act of 1986. Warning this product does not intentionally contain any chemicals known to the state of 

California to 

cause cancer, birth defects, or other reproductive harm. 

CAS# CHEMICAL NAME 

N/A 

TSCA (TOXIC SUBSTANCES CONTROL ACT) …………….All components of this product are listed on the TSCA inventory any impurities present in this product are 

exempt 

from listing. 

VOC (w/w%)……………………………………………………….o. 


. 


Osmose MATERIAL SAFETY DATA SHEET 

MATERIAL SAFETY DATA SHEET: NATUREWOOD TREATED WOOD 

SECTION I 

MSDS NUMBER: 220-osm 

MSDS CODE: OSM 

SYNONYMS: N/A 

MANUFACTURED BY: Licensees/Customers of Osmose, Inc. 

DIVISION: WPD 

EPA REGISTRATION NUMBER: N/A 

EMERGENCY PHONE: 716-882-5905 

OTHER CALLS: 770-233-4200 

ADDRESS: 980 Ellicott Street, Buffalo, NY 14209 

MSDS PREPARED BY: Teri Muchow 

DATE PREPARED: April 4, 2006 

DATE LAST REVISED: December 2, 2010 (replaces November 9, 2009) 

IMPORTANT INFORMATION 

Do Not Burn Preserved Wood 

Do Not Use Preserved Wood As Mulch 

Treated Or Untreated Wood Dust May Cause Eye, Skin & Respiratory Irritation 

Some Wood Species May Cause Allergic Skin Or Respiratory Effects In Sensitized Individuals 

Wear Dust Mask & Goggles and Cover Skin When Cutting Or Sanding Wood 

Wear Gloves When Working With Treated or Untreated Wood 

Prolonged Contact with Treated Wood During Construction or Other Extensive or Abrasive Handling May Cause Skin 

Irritation, and in Extreme Circumstances Can Result in Chemical Burns. 

Some Preservative May Migrate Into The Soil/Water Or Dislodge From Wood 

For Additional Product Information, Visit www.osmosewood.com 

TRADE NAME: NatureWood 

SECTION II – HAZARDOUS INGREDIENTS/IDENTITY INFORMATION 

INGREDIENT NAME CAS OSHA PEL/TWA ACGIH TLV/TWA % 

Wood/Wood Dust (This represents the maximum 

amount of wood dust that could be generated if 

the wood was completely machined. Exposure 

limits are for all species except western red 

cedar, which has a TLV of 0.5 mg/m 3 N/A 15 mg/m 

) 

3 (Total Dust) 

5 mg/m 3 1 mg/m 

(Respirable dust) 

3 (Inhalable) > 90% 

Monoethanolamine (MEA) 141-43-5 3 ppm TWA 

3 ppm TWA 

< 6% 

6 mg/m3 TWA 

6 ppm STEL 

Copper complex expressed as Copper Oxides Proprietary 0.1 mg/m3 TWA (fume) 0.2 mg/m3 TWA (fume) < 2.5% 

This product contains one of the below listed Quaternary Ammonium compounds depending on which preservative is used at the 

treating plant. 

Alkyl dimethyl benzyl ammonium chloride 68391-01-5 N/A N/A < 1% 

Didecyl dimethyl ammonium chloride 7173-51-5 N/A N/A < 1% 

Didecyl dimethyl ammonium carbonate and 

Didecyl dimethyl ammonium bicarbonate 

Proprietary None Established None Established < 1% 

In certain west coast species of wood the MEA may be replaced with ammonia or a combination of ammonia and MEA. The 

ammonia may then be present in the following quantity. 

Ammonia (expressed as NH3) 1336-21-6 50 ppm 25 ppm TLV 

35 ppm STEL 

< 1% 

Depending on the additives applied to the treating solution, this wood may also contain < 1% of CLEANWOOD MOLD INHIBITOR. 

CLEANWOOD contains the following ingredients, which are present in the wood at ppm levels. None of these ingredients are 

classified as carcinogens. 

5-Chloro-2-methyl-4-isothiazolin-3-one 26172-55-4 N/A N/A 13 – 27 ppm 

2-Methyl-4-isothiazolin-3-one 2682-20-4 N/A N/A 5 – 10 ppm 

Magnesium chloride 7786-30-3 N/A N/A 12 – 24 ppm 

Magnesium nitrate 10377-60-3 N/A N/A 22 – 45 ppm 

Depending on the additives applied to the treating solution, this wood may also contain


PERCENTAGE OF ACTIVE INGREDIENTS PER RETENTION LEVEL 

0.15 pcf 0.20 pcf 0.40 pcf 0.60 pcf 

Copper complex expressed as Copper Oxides 0.24 – 0.30 0.32 – 0.40 0.65 – 0.79 0.96 – 1.18 

Quaternary Ammonium Compound 0.13 – 0.15 0.16 – 0.20 0.32 – 0.40 0.48 – 0.58 

SECTION III - CHEMICAL CHARACTERISTICS 

PERCENT VOLATILE THEORETICAL VOC 

BOILING MELTING FREEZING SPECIFIC GRAVITY BY VOLUME 

CONTENT 

POINT 

POINT 

POINT 

(H20 = 1) 

(PERCENT OF WEIGHT) 

Not Applicable Not Applicable Not Applicable Not Available Not Applicable Not Applicable 

WEIGHT PER 

VAPOR 

VAPOR 

EVAPORATION RATE 

GALLON pH: PRESSURE 

DENSITY DENSITY 

BASIS (N-BUAC) = 1 

Not Applicable Not Applicable Not Applicable Not Applicable Not Available Not Applicable 

SOLUBILITY IN WATER: Not Applicable REACTIVITY IN WATER: Not Applicable 

APPEARANCE AND ODOR: Solid Wood, appearance may vary; ammoniacal wood odor possible. 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 

FLASH POINT METHOD FLAMMABLE LIMITS IN AIR (%) AUTOIGNITION TEMPERATURE 

N/A N/A N/A N/A 

NFPA CODES HEALTH 1 HMIS CODES: HEALTH 1 

FLAMMABILITY 1 FLAMMABILITY 1 

REACTIVITY 0 REACTIVITY 0 

OTHER N/A PROTECTION B 

EXTINGUISHER MEDIA: Use water to wet down wood and to reduce the likelihood of ignition or dispersion of dust into the air. 

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should wear full protective clothing including self-contained breathing apparatus. 

Combustion products may yield irritating and toxic fumes and gases including organic chloride, aldehydes, amines, hydrogen chloride, 

ammonia, copper compounds, oxygen, boric oxide, oxides of carbon and nitrogen. 

UNUSUAL FIRE AND EXPLOSION HAZARDS: Wood is combustible, and wood dusts may form explosive mixtures with air in the 


SECTION V - REACTIVITY DATA 

IS THIS CHEMICAL STABLE UNDER NORMAL CONDITIONS OF HANDLING/STORAGE (Y/N)? Yes 

CONDITIONS TO AVOID (REGARDING STABILITY): Keep away from excessive heat, sparks and open flame. Keep away from 

incompatible materials. 

INCOMPATIBILITY (MATERIALS TO AVOID): Strong acids, alkalies and oxidizing agents. 

HAZARDOUS DECOMPOSITION PRODUCTS: Combustion products may yield irritating and toxic fumes and gases including organic 

chloride, aldehydes, amines, hydrogen, ammonia, copper compounds, oxygen, boric oxide, oxides of carbon and nitrogen. 

HAZARDOUS POLYMERIZATION POSSIBLE (Y/N)? No 

CONDITIONS TO AVOID (REGARDING POLYMERIZATION): N/A 

SECTION VI - HEALTH HAZARDS 

EMERGENCY OVERVIEW: WARNING! Wood dust may form explosive mixture with air. Wood dusts may cause irritation to the eyes, 

skin and respiratory tract. 

ROUTES OF ENTRY: Dermal, Inhalation. 

SIGNS AND SYMPTOMS OF ACUTE OVEREXPOSURE: 

EYES: Contact with wood and/or wood dust may cause irritation to the eyes, regardless of treatment. 

Symptoms can include irritation, redness, scratching of the cornea, and tearing. 

SKIN: Prolonged contact with treated wood and/or treated wood dust, especially when freshly treated at the 

plant, may cause irritation to the skin, and in extreme circumstances may cause chemical burns. 

Abrasive handling or rubbing of the treated wood may increase skin irritation. Some wood species, 

regardless of treatment, may cause dermatitis or allergic skin reactions in sensitized individuals. 

INGESTION: Ingestion of wood or wood dust is unlikely. If ingestion does occur, gastrointestinal irritation may result 

from both treated and untreated wood. Certain species of wood and their dusts may contain natural 

toxins, which can also have adverse effects in humans. 

NatureWood 

Page 2 of 5


INHALATION: Wood dust, treated and untreated, is irritating to the nose, throat and lungs. Symptoms may include 

nasal dryness, deposits or obstructions in the nasal passages, coughing, sneezing, dryness and 

soreness of throat and sinuses, hoarseness, and wheezing. Prolonged or repeated inhalation of wood 

dusts may cause respiratory irritation, recurrent bronchitis and prolonged colds. Some species may 

cause allergic respiratory reactions with asthma-like symptoms in sensitized individuals. Prolonged 

exposure to wood dusts by inhalation has been reported to be associated with nasal and paranasal 

cancer. 

CHRONIC OVEREXPOSURE: Prolonged exposure to wood dusts by inhalation has been reported to be associated with nasal 

and paranasal cancer. Some wood species may cause dermatitis or allergic skin reactions in sensitized individuals. 

CHEMICAL LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN?: NatureWood treated wood and its components are 

not listed as carcinogens by ACGIH, NIOSH, or IARC. ACGIH, NIOSH and IARC classify wood dust as a human carcinogen or 

occupational carcinogen. This classification is based on an increased incidence of nasal and paranasal cancers in people 

exposed to wood dusts. 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Pre-existing eye, respiratory system and skin conditions. 

TOXICITY: While acute toxicity testing has not been performed on the treated wood, the following information is available on 

the chemical components that may have been used in the treating of Naturewood. 

Monoethanolamine 

Copper complex 

(CAS #141-43-5) 

(expressed as Copper oxides) 

Oral LD50 Rat: 1720 mg/kg 

Oral LD50 Rat: 1350 mg/kg 

Oral LD50 Mouse: 700 mg/kg 

Inhalation LC50 Rat: 2000 ppm/4H 

Dermal LD50 Rabbit: 1 mg/kg 

Dusts as mists as Cu: 100 mg/m3 IDLH (related to copper) 

IDLH: 30 ppm 

Didecyl dimethyl ammonium chloride 

Alkyl dimethyl benzyl ammonium chloride 

(CAS #7173-51-5) 

(CAS #68391-01-5) 

Oral LD50 Rat: 84 mg/kg Oral LD50 Mouse: 268 mg/kg Oral LD50 Rat: 735 mg/kg for males and females combined 

Dermal LD50 Rat: 3350 mg/kg for males and females combined 

Didecyl dimethyl ammonium carbonate and Didecyl dimethyl ammonium bicarbonate* (CAS Proprietary) 

Oral LD50 (rat): 245 mg/kg 

Skin Irritation (rabbit): Corrosive 

Photosensitization (Guinea pig): Not a sensitizer or photoallergen 

EMERGENCY AND FIRST AID PROCEDURES 

EMERGENCY PHONE NUMBER OF MANUFACTURER: 716-882-5905 

1. INHALATION: If dusts are inhaled, remove person to fresh air. If symptoms persist, get medical attention. 

2. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical attention if symptoms persist. 

3. SKIN CONTACT: For skin contact, wash immediately with soap and water. Continue flushing skin with water for 15 minutes. If 

irritation persists, get medical attention. If wood splinters are injected under the skin, get medical attention 

immediately. 

4. INGESTION: If the material is swallowed, get immediate medical attention or advice – Do not induce vomiting. 

NOTE TO PHYSICIAN: Respiratory ailments and pre-existing eye and skin conditions may be aggravated by exposure to wood dust. 

US DOT SHIPPING DESCRIPTION: Not regulated. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Avoid working with freshly treated wet wood. If not possible, wear long 

sleeve shirt, long pants and gloves when working with freshly treated wet wood. Clothing should be removed and replaced if it becomes 

wet due to contact with freshly treated wood. Avoid contact of wood and wood dusts with skin and eyes. Avoid inhalation of airborne 

contaminants as a result of cutting or sawing treated wood. Do not eat, drink or smoke when handling this material or in areas where 

dusts of this product are present. 

OTHER PRECAUTIONS: Do not generate airborne dusts in the presence of an ignition source when sawing, cutting or grinding wood. 

Wash hands after handling and before eating. Maintain good housekeeping procedures, such as sweeping regularly to avoid accumulation 

of dusts. Store away from excessive heat, sparks and open flame. 

NatureWood 

Page 3 of 5


STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No containment procedures are needed as this product 

cannot spill or leak the preservative. Keep away from sparks and flame. Wear appropriate protective equipment and clothing during 

clean-up. Wet down accumulated dusts prior to sweeping or vacuuming in order to prevent explosion hazards. Sweep up or vacuum 

small pieces and dusts and place in appropriate container for disposal. Gather larger pieces by an appropriate method. Avoid the 

generation of airborne dusts during clean up. To avoid the inhalation of dusts during clean up, a dust mask is recommended. 

WASTE DISPOSAL METHODS: Although no EPA Waste Numbers are applicable for this product’s components, you must test your 

waste to determine if it meets applicable definitions of hazardous waste and for State requirements. Dispose of waste material according 

to local, State and Federal regulations. 

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: Wear a dust mask when cutting, grinding or sanding wood and when cleaning up wood dust. 

VENTILATION REQUIREMENTS: Provide good ventilation when cutting, grinding or sanding wood. Whenever possible these 

operations should be performed outdoors. 

PROTECTIVE GLOVES: Wear chemical resistant (rubber, neoprene or nitrile) gloves when handling freshly treated wood at the 

treating plant. Otherwise, wear puncture resistant work gloves, such as leather. 

EYE PROTECTION: Wear safety glasses with side shields when handling, cutting, sanding or grinding this material. Use a 

face shield during processes that may generate excessive dusts and splinters. 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Eye wash fountain is recommended. 

WORK/HYGIENIC PRACTICES: Launder work clothes frequently. 

SECTION IX – EXOLOGICAL INFORMATION 

ECOTOXICITY: This product is not expected to leach harmful amounts of preservative into the environment. 

While ecotoxicity testing has not been performed on the treated wood, the following information is available on the chemical 

components that may have been used in the treating of Naturewood. 

Monoethanolamine (CAS #141-43-5) 

LC50 (96 hr) goldfish: 170.0 mg/l 

EC50 (30 min) Photobacterium phosphoreum: 13.7 mg/l Microtox test 

Copper Complex (Proprietary) 

LC50 (96hr) fathead minnow: 23 ug/L (20 mg CaCO3/L) LC50 (96hr) water flea: 10 ug/L (45 mg CACO3/L) 

LC50 (96hr) rainbow trout: 13.8 ug/L (juveniles) LC50 (96hr) water flea: 200 ug/L (226 mg CaCO3/L 

LC50 (96hr) bluegill: 236 – 892 ug/L (adults – related to copper) – related to copper) 

LC50 (72hr) freshwater algae: 120 ug/L (related to copper) 

Didecyl dimethyl ammonium carbonate and Didecyl dimethyl ammonium bicarbonate* (CAS Proprietary 

LC50 (rainbow trout – 96 hour – Static): 0.810 mg/l EC50 (Daphnia magna – 48 hour – Static): 0.073 mg/l 

LC50 (bluegill sunfish – 96 hour – Static/Renewal): 0.28 mg/l LC50 (mysid shrimp – 96 hour – static): 0.066 mg/l 

LC50 (Sheepshead Minnow – 96 hour Static/Renewal): 1.110 mg/l 

ENVIRONMENTAL FATE: No information available 

SECTION X - REGULATORY INFORMATION: 

SECTION 302: 

N/A 

SECTION 304: 

N/A 

SARA/TITLE III ;SECTION 312 - HAZARD CATEGORIES: 

Immediate (Acute) Health: No Reactive Hazard: No 

Delayed (Chronic) Health: No Sudden Release of Pressure: No 

Fire Hazard: No 

SARA/SECTION 313 SUPPLIER NOTIFICATION: 

This product contains a chemical which is either listed in Section 313 or is included in a chemical category listed in Section 313, and may 

be present at or above de minimis concentrations. The following listed chemicals are present: 

- Copper Oxide (CAS #1317-39-1) as a Copper Compound 

For percent of copper oxide in the product, refer to the PERCENTAGE OF ACTIVE INGREDIENTS PER RETENTION LEVEL table in 

Section II of the MSDS. According to 40 CFR 372.65(c)(5)(d), “Notifications are not required in the following instances: (1) If a mixture or 

trade name product contains no toxic chemical in excess of the applicable de minimis concentration as specified in 372.38(a).” If you refer 

to this section, it describes de minimis concentrations as “the toxic chemical is in a concentration in the mixture which is below 1 percent of 

the mixture.” As the copper oxide levels in NATUREWOOD are below 1% for 0.15 pcf, 0.25 pcf and 0.40 pcf, this Supplier Notification is 

only applicable to wood treated to a 0.60 pcf retention. 

NatureWood 

Page 4 of 5


CALIFORNIA PROPOSITION 65: 

WARNING: Drilling, sawing, sanding or machining wood products generates wood dust, a substance known to the State of California to 

cause cancer. Avoid inhaling wood dust or use a dust mask or other safeguards for personal protection. CALIFORNIA HEALTH AND 

SAFETY CODE - SECTION 25249.6. 

N/A = Not Applicable 

HAZARDOUS MATERIALS INFORMATION SYSTEM (HMIS) 

PERSONAL PROTECTION INDEX 

NOTICE: The information herein is given in good faith but no warranty, expressed or implied, is made, and Osmose, Inc. 

expressly disclaims liability from reliance on such information. 

Information on this form is furnished for the purpose of compliance with the Occupational Safety and Health Act of 

1970 and shall not be used for any other purpose. Use or dissemination of all or any part of this information for any 

other purpose may result in a violation of law or constitute grounds for legal action. 

NatureWood 

Page 5 of 5

Product Name: Oxygen MSDS No.: E-4638-I Date: Oct. 15, 2010 

Product Name: Oxygen 

Product Use: Many. 

Chemical Name: Oxygen 



Trade Name: 

Synonym: 

Chemical Formula: O2 Chemical Family: Permanent Gas. 

Telephone: 

Emergencies: * 1-800-363-0042 

Supplier 

/Manufacture: 

Phone: 

Fax: 

Oxygen, Medipure® 

Dioxygen 



Suite 1200 


905-803-1600 

905-803-1682 



WARNING! 



High pressure, oxidizing gas. Vigorously accelerates combustion. Self-contained breathing 

apparatus may be required by rescue workers. 

ROUTES OF EXPOSURE: Inhalation. 





INHALATION: 

SKIN CONTACT: No harm expected. 


SWALLOWING: 

EYE CONTACT: 


Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may 

cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing 

oxygen at higher pressure increases the likelihood of adverse effects within a shorter time 

period. Breathing pure oxygen under pressure may cause lung damage and also central 

nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and 

hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing of 

oxygen under pressure may cause prolongation of adaptation to darkness and reduced 

peripheral vision. 

No evidence of adverse effects from available information. 


No evidence of adverse effects from available information.

Product Name: Oxygen MSDS# E-4638-I Date: Oct. 15, 2010 




See "Notes to Physician", in the "First Aid" section. 


See "Notes to Physician", in the "First Aid" section. 


None currently known. 





NUMBER 

CONCENTRATION 

% by Mole 

Oxygen 7782-44-7 100 


INHALATION: 

If inhaled, remove to fresh air. If not breathing, give artificial respiration. Keep patient warm and at rest. Get medical 

attention. Advise the physician that the victim has been exposed to high concentration of oxygen. 

SKIN CONTACT: 


SWALLOWING: 


EYE CONTACT: 



Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and rest. Animal studies 

suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increase the 

susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E 

deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause 

alveolar collapse following absorption of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of 

the eardrum and obstruction of the paranasal sinuses may produce “vacuum-type” headache. Newborn premature 

infants exposed to high oxygen concentrations may suffer delayed retinal damage, which can progress, to retinal 

detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to 100% oxygen 

under greater that atmospheric pressure, particularly in individuals whose retinal circulation has been previously 

compromised. 

All individuals exposed for only periods to oxygen at high pressure and all that exhibit overt oxygen toxicity should have 

ophthalmologic examination. 



FLAMMABLE : No. IF YES, UNDER WHAT CONDITIONS? Vigorously accelerates 

combustion. 

Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e., safety shower) is the 

preferred extinguishing media for clothing fires. 


None. 




WARNING! Evacuate all personnel from danger area. Immediately deluge cylinders with water from maximum distance 

until cool; then move them away from fire area if without risk. 


Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. 

Container may rupture due to heat of fire. Vapours are extremely irritating. Contact may cause burns to skin and eyes. 

No part of a container should be subjected to a temperature higher than 52 C. See incompatibility in Section 10. Most 

containers are provided with a pressure relief divice designed to vent contents when they are exposed to elevated 

temperature. Smoking, flames and electrric sparks in the presence of enriched oxygen atmospheres are potential 

explosion hazards. 








FLASH POINT: Not applicable. 


LOWER: Not applicable. 

UPPER: Not applicable. 





WARNING! Shut off flow if you can do so without risk. Ventilate area or move cylinder to a well-ventilated area. 

Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface, 

greasy clothes, or other combustible material. 


Discard any product, residue, disposable container, or liner in an environmentally acceptable manner, in full compliance 

with federal, provincial, and local regulations. If necessary call your local supplier. 



Use piping and equipment adequately designed to withstand pressures to be encountered. Ground all equipment. 

Store and use with adequate ventilation at all times. Use only in a closed system constructed of corrosion resistant 

materials. NOTE: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in 

any lines or piping from the cylinder to prevent reverse flow. For additional information refer to CGA pamphlet P-1. (See 

section 16 for more details). 

WHEN USED IN WELDING AND CUTTING: Read and understand the namufacturer's instructions and the 

precautionary label on the product. See American Standard Z49.1 "Safety in Welding and Cutting" published by the 

American Welding Society, P.O. Box 351040, Miami, Florida, 33135. 

Note: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the 



supervision of personnel experienced in the use of underwater breathing gas mixtures. Become familiar with the 

effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken. 


Store and use with adequate ventilation. Separate flammable cylinders from oxygen, chlorine, and other oxidizers by at 

least 6 m or use a barricade of non-combustible material. This barricade should be at least 1.5 m high and have a fire 

resistance rating of at least ½ hour. Firmly secure cylinders upright to keep them from falling or being knocked over. 

Screw valve protection cap firmly in place by hand. Post “No Smoking or Open Flames” signs in storage and use areas. 

There must be no sources of ignition. All electrical equipment in storage areas must be explosion-proof. Storage areas 

must meet national electric codes for Class 1 hazardous areas. Store only where temperature will not exceed 52 C. 

Store full and empty cylinders separately. Use a first-in, first-out inventory system to prevent storing full cylinders for 

long periods. For additional information refer to CGA pamphlet P-2305(for welding and cutting). See section 16. 


High-pressure, oxidizing gas. Use piping and equipment adequately designed to withstand pressures to be 

encountered. Vigorously accelerates combustion. Keep oil, grease, and combustibles away. Store and use with 

adequate ventilation at all times. Close valve after each use; keep closed even when empty. Prevent reverse flow. 

Reverse flow into cylinder may cause rupture. Use a check valve or other protective device in any line or piping from the 

cylinder. When returning cylinder to supplier, be sure valve is closed, then install valve outlet plug tightly. Never work 

on a pressurized system. If there is a leak, close the cylinder valve. Vent the system down in a safe and 

environmentally sound manner in compliance with all federal, provincial, and local laws; then repair the leak. Never 

place a compressed gas cylinder where it may become part of an electrical circuit. 






supplier. 



Oxygen 7782-44-7 Not 

applicable. 




SPECIAL: 

Use a local exhaust system, if necessary, to prevent increased oxygen 

concentration and, in welding, to keep hazardous fumes and gases below 

applicable TLVs in the worker's breathing zone. 

General exhaust ventilation may be acceptable if it can maintain a 

supply of air that is not too rich in oxygen an, during welding, can 

keep hazardous fumes and gases below the applicable TLVs in 

the worker's breathing zone. 

None. 

(Species & 

Routes) 


(Rat, 4 

hrs.) 

Not 

applicable. 


None. 







OTHER: None. 

RESPIRATORY PROTECTION: None required under normal use. However, air-supplied 

respirators are required while working in confined spaces with this 

product. For welding, use air-purifying or air-supplied respirators, 

as appropriate, where local or general exhaust ventilation is 

inadequate. Adequate ventilation must keep worker exposure 

below applicable TLVs for fumes, gases and other by-products of 

welding with oxygen. Selection should be based on the current 

CSA standard Z94.4 “Selection, Care, and Use of Respirators”. 

Respirators should be approved by NIOSH and MSHA. 

SKIN PROTECTION: Wear work gloves when handling cylinders. 



PHYSICAL STATE: Gas. 

BOILING POINT 

SPECIFIC 

GRAVITY: 


SPECIFIC 

GRAVITY: 

VAPOUR 

(air = 1) 

-182.96°C (-297.3°F) 












VAPOUR 

PRESSURE 

-218.78°C 

(-361.8°F) 

Not applicable. SOLUBILITY IN 

WATER, 

Negligible. 

EVAPORATION 

RATE 



VOLUME: 

Odourless. 



100% (v/v). 





WATER/OIL 

DISTRIBUTION: 

32 g/mole 


ODOUR THRESHOLD: Ordourless. 

STABILITY: 


CONDITIONS OF CHEMICAL INSTABILITY: Compatibility with plastics should be 

confirmed prior to use. 





Combustible materials, asphalt, flammable 

materials, especially oils and greases. 

Oxygen reacts with many materials. 

None. 

Will not occur.







None known. 

None known. 

The welding process may generate hazardous fumes and gases. See Sections 10 and 16 

for additional information. 

At atmospheric concentration and pressure, oxygen poses no toxicity hazards. At high concentrations, newborn 

premature infants may suffer delayed retinal damage (retrolental fibroplasia) that can progress to retinal detachment and 

blindness. Retinal damage may also occur in adults exposed to 100% oxygen for extended periods (24 to 48 hours) or at 

greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. 

All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have 

ophthalmologic examinations. 

At two or more atmospheres, toxicity to the Central Nervous System (CNS) occurs. Symptoms include nausea, vomiting, 

dizziness or vertigo, muscle twitching, vision changes, and loss of consciousness and generalized seizures. At three 

atmospheres, CNS toxicity occurs in less than two hours; at six atmospheres, in only a few minutes. 

Patients with chronic obstructive pulmonary disease retain carbon dioxide abnormally. If oxygen is administered, raising 

their blood oxygen concentration, their breathing becomes depressed and retained carbon dioxide rises to a dangerous 

level. 

Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases 

the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E 

deficiency may increase susceptibility to oxygen toxicity. 

Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly, 

occlusion of the eustachians tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may 

produce vacuum-type headache. 






TDG/IMO SHIPPING NAME: Oxygen, Compressed 

HAZARD CLASS: CLASS 2.2(5.1): 

Non-Flammable and 

Non-Toxic gas, 

Oxidizing material. 




supplier. 


UN1072 PRODUCT RQ: Any accidental 

release in a 

quantity that 

could pose a 

danger to public 

safety or any 

sustained 

release of 10 

minutes or 

more.


SHIPPING LABEL(s): Special/Oxidizer with Class 2 at bottom. 



Special/Oxidizer with Class 2 at bottom. 





CLASS C: Oxidizing material. 








R8- Contact with combustible material may cause fire. 

DSCL (EEC): 


MIXTURES: 






HMIS RATINGS: 

HEALTH 

FLAMMABILITY 



THREADED: 

0-3000 psig CGA-540 

3001-4000 CGA-577 

4001-5500 CGA-701 


CGA-870 

ULTRA-HIGH-INTEGRITY CGA-714 

CONNECTION: 









AV-1 Safe Handling and Storage of Compressed Gases 

AV-8 Characteristics and Safe Handling of Cryogenic Liquid and Gaseous Oxygen 

G-4 Oxygen 

G-4.1 Cleaning Equipment for Oxygen Service 

G-4.3 Commodity Specification for Oxygen 


P-2 Characteristics and Safe Handling of Medical Gases 

P-14 Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmospheres 

SB-8 Use of Oxy-Fuel Gas Welding and Cutting Apparatus 







information. 


















Suite 1200 

Mississauga, ON L5B 1M2


SECTION I — PRODUCT INFORMATION 

POLY FILLER RT 

PTM & W INDUSTRIES, INC. PHONE NUMBER: (562)946-4511 

10640 S. PAINTER AVE. CHEMICAL TRANSPORTATION EMERGENCY: 

SANTA FE SPRINGS, CA. 90670-4092 CHEMTREC (800) 424-9300 

DATE OF PREPARATION: 2/9/2007 SUPERSEDES: 6/9/2005 

PROPER SHIPPING NAME .... : 

CONTAINS ..... : NOT REGULATED 

Plastic Material liquid, N.O.I. NOT REGULATED 

HAZARD CLASS...................... : N.A. 

UN NUMBER ........................... : N.A. 

PACKAGING GROUP.............. : N.A. 

HAZARD LABEL(S) ................. : N.A. 

HMIS CODES: RATINGS: 

HEALTH.....................= 2 0 = MINIMAL 3 = SERIOUS 

FLAMMABILITY .........= 2 1 = SLIGHT 4 = SEVERE 

REACTIVITY..............= 2 2 = MODERATE 

PERSONAL PROTECTION RATING TO BE SUPPLIED BY USER DEPENDING ON 

USE CONDITIONS. 

SECTION II — PRODUCT/COMPOSITION 

THE PRECISE COMPOSITION OF THIS PRODUCT IS PRIVILEGED INFORMATION. A MORE 

COMPLETE DISCLOSURE CAN BE PROVIDED TO A HEALTH, SAFETY, OR REGULATORY 

PROFESSIONAL IF REQUIRED. 

NO. COMPONENT CAS. NO. PERCENT 

1 STYRENE 100-42-5 < 16% 

NOTE: CONTAINS MATERIAL(S) REGULATED AS DUST HAZARDS, DISPERSED IN A NON-HAZARDOUS FORM. 

IF DUST IS RECREATED, APPROPIATE RESPIRATORY AND/OR EXPLOSION PRECAUTIONS MUST STILL BE USED. 

SECTION III — HAZARD STATUS 

NO. CANCER REPRO-TOX TARGET ORGANS ACGIH/TLV OSHA/PEL 

1 IARC 2B NO LIVER, KID,LUNG 50mg/M 3 50mg/M 3 

SECTION IV — REGULATORY STATUS 

A. CAL SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT OF 1986 

NO. CHEMICAL NAME CAS. NO. CANCER/REPRO.TOX QUANTITY 

THIS PRODUCT MAY CONTAIN TRACES OF, OR OTHER PROP. 65 LISTED CHEMICALS 

AS IMPURITIES. HOWEVER, NONE ARE USED AS INGREDIENTS. 

B. CERCLA — 40 CFR 302.4 

RELEASES EXCEEDING THE REPORTABLE QUANTITY (RQ) MUST BE REPORTED TO THE 

NATIONAL RESPONSE CENTER. (800)424-8802 

RQ BASED ON PRESENCE OF STYRENE > 6250 LBS. 

C. OSHA — 29 CFR 302.4 

ACCORDING TO OSHA CRITERIA THE FOLLOWING COMPONENT(S) ARE HAZARDOUS: 

1 STYRENE 100-42-5 < 16% 

D. RCRA — 40 CFR 261.33 

A RCRA D001 IGNITABLE WASTE, FLASH POINT< 140F, "A HIGH TOC NON-WASTEWATER 

E. SARA TITLE III — 52 CFR 13378, 52 CFR 21152 

NO. RQ(lbs.) TPQ(lbs.) SEC.313 313 CAT. 311/312 

(•1) (•2) (•3) (•4) (•5) 

1 1000 NOT LISTED YES NONE H1, H2, 

P3,P5 

OTHER SARA SUBSTANCE(S) IF PRESENT ARE ALL BELOW THE DE MINIMUS 

CONCENTRATION(S). 

•1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC. 302 

•2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC. 302 

•3 = TOXIC CHEMICAL, SEC. 313 (INDIVIDUAL CHEMICAL LISTED) 

•4 = TOXIC RELEASE INVENTORY FORM CATEGORY SEC. 313 (40 CFR 372.65 C) 

•5 = HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING 

H1 = IMMED. (ACUTE) HEALTH HAZARD H2 = DELAYED (CHRONIC) HEALTH HAZARD 

P3 = FIRE HAZARD P4 = SUDDEN PRESSURE RELEASE HAZARD P5 = REACTIVE HAZ. 

POLYFILLER RT MSDS # 170 1 2 

No change April 21, 2011

SECTION VIII — REACTIVITY DATA 

STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS. UNSTABLE AT 

ELEVATED TEMPERATURES. 

INCOMPATIBILITY: STRONG OXIDIZING AGENTS, STRONG LEWIS OR MINERAL ACIDS, 

AND STRONG MINERAL AND ORGANIC BASES / ESPECIALLY ALIPHATIC AMINES. 

HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES, ALDEHYDES, ACIDS, 

PHENOLICS, AND OTHER UNKNOWN COMPOUNDS. 

SECTION IX — SPILL OR LEAK PROCEDURES 

IF MATERIAL IS SPILLED: AVOID CONTACT WITH MATERIAL. PERSONS NOT WEARING 

PROPER PROTECTIVE EQUIPMENT (SEE BELOW) SHOULD BE EXCLUDED FROM THE 

AREA UNTIL CLEAN UP IS COMPLETE. DIKE AREA TO PREVENT SPILL SPREADING 

AND SCOOP UP EXCESS TO RECOVERY CONTAINERS. ABSORB REMNANT ON 

NONCOMBUSTIBLE MATERIAL SUCH AS CLAY AND SHOVEL INTO CONTAINERS FOR 

DISPOSAL. 

WASTE DISPOSAL METHOD: DISPOSE OF WASTE IN ACCORDANCE WITH FEDERAL, 

STATE, AND LOCAL REGULATIONS. 

SECTION X — SPECIAL PROTECTION INFORMATION 

RESPIRATORY PROTECTION: NOT NORMALLY NECESSARY UNLESS THE MATERIAL IS 

BEING USED IN SUCH A WAY AS TO PRODUCE DUST, MIST, VAPOR, FUMES, OR 

SMOKE, IN WHICH CASE NIOSH APPROVED RESPIRATORY PROTECTION SHOULD BE 

USED. 

VENTILATION: SHOULD BE SUFFICIENT TO CONTROL ANY DUST, MIST, VAPOR OR 

FUMES PRODUCED BY PROCESSING OR HANDLING METHOD. BREATHING OF VAPOR 

MUST BE AVOIDED. 

HAND PROTECTION: IMPERVIOUS GLOVES, NEOPRENE OR RUBBER GLOVES. 

EYE PROTECTION: SPLASH PROOF GOGGLES OR SAFETY GLASSES WITH SIDE 

SHIELDS. 

OTHER PROTECTIVE EQUIPMENT: CLEAN, BODY COVERING CLOTHING AND 

FOOTWEAR. 

SECTION XI — SPECIAL PRECAUTIONS 

AVOID SKIN AND EYE CONTACT. 

AVOID BREATHING VAPOR, MIST OR FUMES. 

ENSURE THAT ALL CONTAINERS ARE PROPERLY LABELED TO PREVENT ACCIDENTAL 

INGESTION OR IMPROPER DISPOSAL. 

RESEAL PARTLY USED CONTAINERS. 

WASH WITH SOAP AND WATER BEFORE EATING, DRINKING OR USING TOILET 

FACILITIES. 

STORE UNDER COOL, DRY CONDITIONS AND AWAY FROM OPEN FLAMES AND HIGH 

TEMPERATURES. 

OBSERVE CONDITIONS OF GOOD INDUSTRIAL HYGIENE AND SAFE WORKING 

PRACTICE. 

We believe that the information contained herein is correct as of the date of this 

Material Safety Data Sheet. Since the use of this information and these opinions and 

the conditions of use of this product are not within the control of PTM & W, it is the 

user's obligation to determine the conditions of safe use of the product. 

PTM & W makes no warranty, expressed or implied regarding the accuracy of these 

data. PTM & W assumes no responsibility for injury from the use of the product 

described herein. Further, there are many federal, state, and local laws and 

regulations governing chemical products and it is beyond the scope of this MSDS to 

determine which of these apply and it is the responsibility of the user to determine 

how these effect their use of the product. 

F. TSCA — 44 CFR 59764 

ALL COMPONENTS LISTED. 

G. VOC — SCAQMD RULES 

NO. CHEMICAL QUANTITY VP mm HG gms./l. @ 20ºC 

1 SYTRENE 16 5 160 

SECTION V — PHYSICAL DATA 

PHYSICAL STATE ......: PUTTY 

COLOR........................: WHITE 

SP. GR. .......................: 1.63 

DENSITY.....................: 13.6 lbs./gal. 

SECTION VI — FIRE AND EXPLOSION HAZARD DATA 

FLASH POINT : 89-90°F (FOR STYRENE) 

FLAMMABILITY CLASSIFICATION: NON FLAMMABLE SOLID PER HMR 49CFR §173.124 

MARINE POLLUTANT PER HMR 49CFR §171.8 & §171.4(c) 

EXTINGUISHING MEDIA: WATER FOG, DRY CHEMICAL, CARBON DIOXIDE, OR FOAM. 

NOTE: EITHER ATMOSPHERE-SUPPLY OR AIR-PURIFYING RESPIRATORS SHOULD BE 

AVAILABLE FOR FIRE FIGHTERS (20 CFR 1910.134). 

SECTION VII — HEALTH HAZARD DATA 

EFFECTS OF OVEREXPOSURE: 

ACUTE: 

EYES: PRODUCT IS MODERATELY IRRITATING TO THE EYES. 

SKIN: PRODUCT IS MODERATELY IRRITATING TO THE SKIN AND MAY CAUSE SKIN 

SENSITIZATION. 

INHALATION: BECAUSE OF ITS LOW VOLATILITY THIS PRODUCT IS NOT LIKELY TO BE 

AN INHALATION HAZARD. 

INGESTION: PRODUCT IS CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL 

TOXICITY. 

CHRONIC: 

NO SPECIFIC HAZARDS KNOWN TO PTM & W. PREXISTING EYE, SKIN OR LUNG 

DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. 

EMERGENCY AND FIRST AID PROCEDURES: 

EYES: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 

MINUTES. GET MEDICAL ATTENTION. 

SKIN: WASH AFFECTED AREA IMMEDIATELY WITH LARGE AMOUNTS OF SOAP AND 

WATER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. CONTACT 

A PHYSICIAN IF IRRITATION OCCURS. 

INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS 

DIFFICULT. GET MEDICAL ATTENTION. 

INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. CALL 

A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN 

UNCONSCIOUS PERSON. 

POLYFILLER RT MSDS # 170 3 4


Product Discontinued 04/19/2011 

PRODUCT : POLY PLASTER OF PARIS 


HENKEL CORPORATI ON 

6685 KENNEDY ROAD, SUI TE #1 


(905) 696-2770 

MANUFACTURER.....................HENKEL CORPORATI ON 

6685 KENNEDY ROAD, SUI TE #1 



(905) 696-2770 


WHMIS CLASSIFICATION.............NONE 

T.D.G. CLASSIFICATION............NOT REGULATED 

PRODUCT NAME.....................POLY PLASTER OF PARIS 

CHEMICAL FAMILY..................CALCIUM SULFATE 

MATERIAL USE.....................FINE SURFACE FILLER 



Considered non-hazardous as Not available 

per WHMIS regulations. 


PHYSICAL STATE...................Solid 

APPEARANCE & ODOUR...............White powder 

ODOUR THRESHOLD (ppm)............Not applicable 

VAPOUR PRESSURE (mm Hg)..........Not applicable 

VAPOUR DENSITY (AIR=1)...........Not applicable 

BY VOLUME 

BY WEIGHT 

EVAPORATION RATE.................Not applicable 

BOILING POINT (deg C)............Not applicable 

pH...............................1%. 7.3 




DISTRIBUTION 

SPECIFIC GRAVITY 

SOLUBILITY IN WATER (% W/W) 

COEFFICIENT OF WATER/OIL 

DISTRIBUTION 


FLAMMABILITY.....................Not applicable 

IF YES, UNDER WHICH 

CONDITIONS 

EXTINGUISHING MEDIA..............Water fog 


to protect against potentially toxic and irritating fumes. 

FLASH POINT (C), METHOD..........Not applicable 

AUTO IGNITION TEMPERATURE........Not available 

UPPER FLAMMABLE LIMIT (% VOL)....Not applicable 

LOWER FLAMMABLE LIMIT (% VOL)....Not applicable 

HAZARDOUS COMBUSTION PRODUCTS....None known 


SENSITIVITY TO STATIC............No 

DISCHARGE 

SENSITIVITY TO IMPACT......No 



YES........................Stable under normal temperature and pressure. 

NO, WHICH CONDITIONS 


SUBSTANCES: 

YES 

NO, WHICH ONES ............Strong oxidizing agents 

REACTIVITY CONDITIONS ..........Product is stable; hazardous polymerization will not occur. 

HAZARDOUS PRODUCTS OF............Oxides of calcium. Oxides of sulphur at elevated temperatures. 

DECOMPOSITION


PRODUCT : POLY PLASTER OF PARIS 


ROUTE OF ENTRY: 

SKIN CONTACT...............Prolonged or repeated contact may cause dryness and moderate irritation. 

SKIN ABSORPTION............Unlikely to be absorbed through skin. 

EYE CONTACT................Particulate irritant. May cause redness and tearing. 

INHALATION.................Product readily produces dust. Inhalation of dust may cause irritation of 

the respiratory tract. 

INGESTION..................Plaster hardens when wetted and if ingested may result in obstruction. 


EFFECTS OF CHRONIC EXPOSURE......None known 

LD 50 OF MATERIAL, SPECIES &.....Not available 

ROUTE 

LC 50 OF MATERIAL, SPECIES &.....Not available 

ROUTE 


IRRITANCY OF MATERIAL............Refer to route of entry 

SENSITIZING CAPABILITY OF........None known 

MATERIAL 

CARCINOGENICITY OF MATERIAL......No 

REPRODUCTIVE EFFECTS.............Not indicated 

SYNERGISTIC MATERIALS............Not applicable 


GLOVES/ TYPE...............Gloves are not normally required for foreseeable conditions of use. During 

prolonged contact impervious gloves should be worn. 


whenever dust is generated. 

EYE/TYPE...................Safety glasses are optional. 



VENTILATION REQUIREMENTS.........Use adequate general ventilation. 

LEAK/SPILL.......................Normal precautions for "nuisance dust" should be observed. Avoid dust 

accumulation. Pick up solids and put in a dust bin. Use approved dust 

respirator. Use explosion proof vacuum equipment where appropriate. 

WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. 

HANDLING PROCEDURES AND..........Avoid breathing dust. 

EQUIPMENT 

STORAGE NEEDS....................Avoid high airborne dust concentrations. Prevent accumulations of dust. 

Store in a cool and dry place, for product integrity. 

SPECIAL SHIPPING INSTRUCTIONS....Not regulated. Protect against physical damage. 


EYE CONTACT......................Immediately flush eyes with large amounts of water until irritation 

subsides. If irritation persists, get medical attention. 

INGESTION........................No toxic effects are anticipated upon ingestion of this material. However 

we advise that a medical opinion be sought. 

INHALATION.......................Remove to fresh air. If symptoms develop, seek medical attention. 





TELEPHONE NUMBER:................(440) 937-7000 






guarantee, express or implied, is made by Henkel Corporation as to 


of the product nor does Henkel Corporation assume any liability 






PREPARATION DATE.................FEB 26/2008 


LEHIGH SOUTHWEST CEMENT COMPANY 


FOR 

PORTLAND CEMENT 

1. PRODUCT/COMPANY IDENTIFICATION 

Supplier: Chemical Family: Calcium Compounds 

Lehigh Southwest Cement Company 

12667 Alcosta Blvd. #400 Chemical Name and Synonyms: 

San Ramon, CA 94583 

Phone (925) 244-6500 

Fax (925) 244-6525 

Contact Number: 

(USE SALES OFFICE PHONE NUMBER) 

REVISED DATE: August, 2009 

Portland Cement (CAS # 65997-15-1), Hydraulic 

Cement Types I, I (WRA), II, III, V 

Trade Name and Synonyms: 

Lehigh Portland Cement Types I, II, III, V 

Lehigh Plastic Cement 

2. EMERGENCY AND FIRST AID 

EMERGENCY INFORMATION: Portland cement is a light gray or white powder. When in 

contact with moisture in eyes or on skin, or when mixed with 

water, portland cement becomes highly caustic (pH > 12) and 

will damage or burn (as severely as third-degree) the eyes or 

skin. Inhalation may cause irritation to the moist mucous 

membranes of the nose, throat and upper respiratory system or 

may cause or may aggravate certain lung diseases or conditions. 

Use exposure controls or personal protection methods described 

in Section 10. 

EYES: Immediately flush eye thoroughly with water. Continue 

flushing eye for at least 15 minutes, including under lids, to 

remove all particles. Call physician immediately. 

SKIN: Wash skin with cool water and pH-neutral soap or a mild 

detergent. Seek medical treatment if irritation or inflammation 

develops or persists. Seek immediate medical treatment in the 

event of burns. 

INHALATION: Remove person to fresh air. If breathing is difficult, administer 

oxygen. If not breathing, give artificial respiration. Seek 

medical help if coughing and other symptoms do not subside. 

Inhalation of large amounts of portland cement require 

immediate medical attention. 

INGESTION: Do not induce vomiting. If conscious, have the victim drink 

plenty of water and call a physician immediately. 

ACCIDENTIAL RELEASE MEASURES Clean up spilled material without causing it to become airborne

or mixed with water to limit potential harm. Wear appropriate 

personal protective equipment. Dispose of waste material 

according to local, state or federal regulations.

3. COMPOSITION INFORMATION 

DESCRIPTION: This product consists of finely ground portland cement clinker 

mixed with a small amount of gypsum (calcium sulfate 

dihydrate). The portland cement clinker is made by heating to a 

high temperature a mixture of substances such as limestone, 

sand, clay and shale. Portland cement is essentially hydraulic 

calcium silicates contained in a crystalline mass, not separable 

into individual components. Major compounds are: 

3CaO•SiO2 Tricalcium Silicate CAS #12168-85-3 

2CaO•SiO2 Dicalcium Silicate CAS #10034-77-2 

3CaO•Al2O3 Tricalcium Aluminate CAS #12042-78-3 

4CaO•Al2O3•Fe2O3 Tetracalcium 

CAS #12068-35-8 

aluminoferrite 

CaSO4•2H2O Calcium Sulfate 

dihydrate (Gypsum) 

4. HAZARDOUS INGREDIENTS 

CAS #7778-18-9 

(CAS #13397-24-5) 

OSHA PEL 

ACGIH TLV-TWA 

NIOSH REL 

COMPONENT 

(8-Hour TWA) 

(1995-1996) 

(8-Hour TWA) 

-------------------- ------------------------- ------------------------ ------------------------ 

Portland Cement (CAS #65997-15-1) 5 mg respirable dust/m 

50 to 95% by weight 

3 

15 mg total dust/m 3 


Calcium sulfate (CAS #7778-18-9) 

[Gypsum (CAS #13397-24-5)] 


Iron oxide (CAS #1309-37-1) 


Calcium carbonate (CAS #1317-65-3) 


Magnesium oxide (CAS #1309-48-4) 


Calcium oxide (CAS #1305-78-8) 

0 to 5% 1 by weight 

Crystalline silica (CAS #14808-60-7) 


TRACE INGREDIENTS: 

5 mg respirable dust/m 3 


10 mg/m 3 

5 mg respirable dust/m 3 



5 mg/m 3 

10 mg of respirable dust/m 3 

% SiO2 + 2 

30 mg of total dust/m 3 

% SiO2 + 2 

250 million particles/ft 3 

% SiO2 + 5 


5 mg/m 3 



2 mg/m 3 

0.05 mg respirable quartz/m 3 

0.05 mg respirable quartz 

dust/m 3 

Due to the use of substances mined from the earth’s crust, trace amounts of naturally occurring, 

potentially harmful constituents may be detected during chemical analysis. Portland cement may 

contain up to 0.75% insoluble residue. A small amount of this residue includes free crystalline silica. 

Portland cement also may contain trace (


POTENTIAL HEALTH EFFECTS: NOTE: Potential health effects may vary depending upon the 

duration and degree of exposure. To reduce or eliminate health 

hazards associated with this product, use exposure controls or 

personal protection methods as described in Section 10. 

EYE CONTACT: (Acute/Chronic) Exposure to airborne dust may cause 

immediate or delayed irritation or inflammation of the cornea. 

Eye contact by larger amounts of dry powder or splashes of wet 

portland cement may cause effects ranging from moderate eye 

irritation to chemical burns and blindness. 

SKIN CONTACT: (Acute) Exposure to dry portland cement may cause drying of 

the skin with consequent mild irritation or more significant 

effects attributable to aggravation of other conditions. 

Discomfort or pain cannot be relied upon to alert a person to a 

hazardous skin exposure. 

(Chronic) Dry portland cement coming in contact with wet skin 

or exposure to wet portland cement may cause more severe skin 

effects, including thickening, cracking or fissuring of the skin. 

Prolonged exposure can cause severe skin damage in the form of 

chemical (caustic) burns. 

(Acute/Chronic) Some individuals may exhibit an allergic 

response upon exposure to portland cement. The response may 

appear in a variety of forms ranging from a mild rash to severe 

skin ulcers. 

INHALATION: (Acute) Exposure to portland cement may cause irritation to the 

moist mucous membranes of the nose, throat and upper 

respiratory system. Pre-existing upper respiratory and lung 

diseases may be aggravated by inhalation of portland cement. 

(Chronic) Inhalation exposure to free crystalline silica may 

cause delayed lung injury including silicosis, a disabling and 

potentially fatal lung disease, and/or cause or aggravate other 

lung diseases or conditions. 

INGESTION: (Acute/Chronic) Internal discomfort or ill effects are possible if 

large quantities are swallowed. 

CARCINOGENIC POTENTIAL: Portland cement is not recognized as a carcinogen by NTP, 

OSHA, or IARC. However, it may contain trace amounts of 

heavy metals recognized as carcinogens by these organizations. 

In addition, IARC classifies crystalline silica, a trace constituent, 

as a known human carcinogen (Group I). NTP has characterized 

respirable silica as "reasonably anticipated to be a carcinogen.” 

(See also Section 13.)

APPEARANCE/ODOR: Gray, white or colored 

powder, odorless 

6. PHYSICAL/CHEMICAL DATA 

PHYSICAL STATE: Solid (Powder) 

BOILING POINT: > 1000°C MELTING POINT: Not applicable 

VAPOR PRESSURE: Not applicable VAPOR DENSITY: Not applicable 

pH (IN WATER) (ASTM D 

1293-95) 

SPECIFIC GRAVITY (H2O 

= 1.0): 

12 to 13 SOLUBILITY IN WATER: Slightly soluble (0.1% to 1.0%) 

3.15 EVAPORATION RATE: Not applicable 

7. FIRE AND EXPLOSION 

FLASH POINT: None LOWER EXPLOSIVE LIMIT: None 

AUTO IGNITION 

TEMPERATURE: 

Not combustible UPPER EXPLOSIVE LIMIT: None 

FLAMMABLE LIMITS Not applicable SPECIAL FIRE FIGHTING 

PROCEDURES: 

EXTINGUISHING MEDIA: Not combustible UNUSUAL FIRE AND EXPLOSION 

HAZARDS: 

HAZARDOUS 

COMBUSTION 

PRODUCTS: 

None 

8. STABILITY AND REACTIVITY DATA 

STABILITY: Product is stable. Keep dry until used. 

CONDITIONS TO AVOID: Unintentional contact with water. Contact with water will result 

in hydration and produces (caustic) calcium hydroxide. 

INCOMPATIBILITY: Wet portland cement is alkaline. As such, it is incompatible 

with acids, ammonium salts and aluminum metal. 

HAZARDOUS DECOMPOSITION: Will not occur. 


9. PRECAUTIONS FOR HANDLING, STORAGE AND DISPOSAL 

HANDLING AND STORAGE Keep dry until used. Handle and store in a manner so that 

airborne dust does not exceed applicable exposure limits. Use 

adequate ventilation and dust collection. Use exposure control 

and personal protection methods as described in Section 10. 

SPILL: Use dry clean-up methods that do not disperse dust into the air 

or entry into surface water. Material can be used if not 

contaminated. Place in an appropriate container for disposal or 

use. Avoid inhalation of dust and contact with skin and eyes. 

Use exposure control and personal protection methods as 

described in Section 10. 

None 

None

DISPOSAL: Comply with all applicable local, state and federal regulations 

for disposal of unusable or contaminated materials. Dispose of 

packaging/containers according to local, state and federal 

regulations. 


RESPIRATORY PROTECTION: Use local exhaust or general dilution ventilation to control dust 

levels below applicable exposure limits. Minimize dispersal of 

dust into the air. 

If local or general ventilation is not adequate to control dust 

levels below applicable exposure limits or when dust causes 

irritation or discomfort, use MSHA/NIOSH approved 

respirators. 

EYE PROTECTION: Wear safety glasses with side shields or goggles to avoid contact 

with the eyes. In extremely dusty environments and 

unpredictable environments, wear tight-fitting unvented or 

indirectly vented goggles to avoid eye irritation or injury. 

Contact lenses should not be worn when handling cement or 

cement containing products. 

SKIN PROTECTION: Wear impervious abrasion- and alkali-resistant gloves, boots, 

long-sleeved shirt, long pants or other protective clothing to 

prevent skin contact. Promptly remove clothing dusty with dry 

portland cement or clothing dampened with moisture mixed with 

portland cement, and launder before re-use. If contact occurs, 

wash areas contacted by material with pH neutral soap and 

water. 

11. TRANSPORTATION DATA 

Portland cement is not hazardous under U.S. DOT regulations. 

12. TOXICOLOGICAL AND ECOLOGICAL INFORMATION 

For a description of available, more detailed toxicological and ecological information, contact Lehigh Cement 

Company. 

Status under US OSHA Hazard Communication 

Rule 29 CFR 1910.1200: 

Status under CERCLA/Superfund, 40 CFR 117 

and 302: 

Hazard Category under SARA (Title III), 

Sections 311 and 312: 

13. OTHER REGULATORY INFORMATION 

Portland cement is considered a hazardous chemical under this 

regulation and should be included in the employer's hazard 

communication program. 

Not listed. 

Portland cement qualifies as a hazardous substance with delayed 

health effects. 

Status under SARA (Title III), Section 313: Maybe subject to reporting requirements under Section 313. 

Contact sales office for further information.

Status under TSCA (as of May 1997): Some substances in portland cement are on the TSCA inventory 

list. 

Status under the Federal Hazardous Substances 

Act: 

Portland cement is a hazardous substance subject to statutes 

promulgated under the subject act. 

Status under California Proposition 65: This product contains crystalline silica, a substance known to the 

State of California to cause cancer. This product also may 

contain trace amounts of heavy metals known to the State of 

California to cause cancer, birth defects or other reproductive 

harm. 


This MSDS provides information on various types of portland cement products. A particular product’s composition 

may vary from sample to sample. The information provided herein is believed by Lehigh Cement Company to be 

accurate at the time of preparation or prepared from sources believed to be reliable. Health and safety precautions in 

this data sheet may not be adequate for all individuals or situations. Users have the responsibility to comply with all 

laws and procedures applicable to the safe handling and use of the product, to determine the suitability of the 

product for its intended use, and to understand possible hazards associated with mixing portland cement with other 

materials. This product neither contains nor is directly manufactured with any controlled ozone depleting 

substances, Class I and II. SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE 

PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING 

THE ACCURACY OF ANY INFORMATION PROVIDED BY LEHIGH CEMENT COMPANY. 

ABBREVIATIONS 

ACGIH American Conference of Governmental Industrial Hygienists 

ASTM American Society for Testing and Materials 

CAS Chemical Abstract Service 

CERCLA Comprehensive Environmental Response, Compensation and Liability Act 

CFR Code of Federal Regulations 

ft 3 Cubic foot 

IARC International Agency for Research on Cancer 

m 3 Cubic meter 

mg Milligram 

MSHA Mine Safety and Health Administration 





REL Recommended Exposure Limit 



TSCA Toxic Substance Control Act 

TWA Time Weighted Average

BRODI SPECIALTY PRODUCTS LTD. 


SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Product Name: POWERFLO Date Prepared: December 1, 2008 

Product Number: 0931-23-002B Emergency Phone: 1-(800) 228-5635 

Chemical Family: Halogenated hydrocarbons Information Phone: 1-(877) 744-0751 

Molecular Weight: Not Applicable Supplier's Name: Brodi Specialty Products Ltd. 

Chemical Formula: Not Applicable Supplier's Address: 250 Cochrane Drive, Unit 9, Markham, ON, L3R 8E5 

Trade names and synonyms: 0931-23-002B Powerflo Prepared By: MSDS Co-ordinator, (877) 744-0751 ext 205, Brodi Specialty Products Ltd. 

Product Uses: Degreaser /Cleaner 

Formula/lab book #: Form – 9910-2-251 

SECTION 2: COMPOSTITION/INFORMATION INGREDIENTS 

Hazardous Ingredients % Exposure Limit C.A.S # LD/50 Route, Species LD/50 Route, Species 

1,1,1,2 – Tetrafluoroethane 60-100 1000 ppm 811-97-2 Not Available 567000 ppm (4hr) INHAL- RAT 

Acetone 1-5 750ppm 67-64-1 9750 mg/kg ORAL-RAT 16,000 ppm 94hr) INHAL-RAT 

SECTION 3: HAZARDS IDENTIFICATION 

Route of entry 

INGESTION………………………………………….….…....Product is a gas, therefore, ingestion is not likely a route of exposure 

INHALATION……………………………………………….…Propellant is a sinple asphyxiant 

EYE CONTACT…………………………………………..…...May cause irritation 

SKIN ABSORBTION……………………………………..……No data available for this product mixture 

SKIN CONTACT………………………………………….…...May cause irritation. May cause frostbite 

EFFECTS OF ACUTE EXPOSURE…………………..…….Dizziness, nausea, irritation to skin and eyes 

EFFECTS OF CHRONIC EXPOSURE………………….…..None known 

EXPOSURE LIMIT OF MATERIA……………………………See section 2 


EMERGENCY FIRST AID PROCEDURE………….……..In case of eye contact, flush immediately with plenty of water for at least 15 minutes and get medical attention. 

For skin, wash thoroughly with soap and water. If affected by inhalation of vapour or spray mist, remove to fresh air. If swallowed; do not induce vomiting, get medical attention 

SECTION 5: FIRE FIGHTING MEASURES 

AUTO IGNITION TEMPERATURE (°C) ………………….…465 

SPECIAL PROCEDURES…………………………….………Water from fogging nozzles may be used to cool closed containers to prevent build up if exposed to extreme 

temperatures. 

Full protective equipment including self contained breathing apparatus should be worn in a fire involving this material. 

FLAMMABILITY………………………………………………...Not a flammable product (as per Canadian aerosol regulations) 

IF YES UNDER WHAT CONDITIONS?...............................Excessive heat, sparks and open flame 

EXTINGUISHING MEDIA…………………………………......Water, carbon dioxide, dry chemical, foam. 

UPPER FLAMMABLE LIMIT (% BY VOLUME)………….....12.8 

LOWER FLAMMABLE LIMIT (% BY VOLUME)…………….1 


SENITIVITY TO DISCHARGE……………………….….…..Not applicable 

SENSITIVITY TO IMPACT………………………………...…Not applicable 

HAZARDOUS COMBUSTION PRODUCTS………………...Hydrocarbon fumes and smoke, carbon monoxide where combustion is incomplete 

SECTION 6: ACCIDENTAL RELEASE MEASURES 

LEAK/SPILL…………………………………………….…Remove all sources of ignition, use an inert absorbent material, and non – sparking tools. Ventilate area prevent from 

entering a watercourse. 

SECTION 7: HANDLING AND STORAGE 

STORAGE NEEDS………………………….……………………Keep away from heat, sparks, and open flames. 

ENGINEERING CONTROLS…………………………………...Ventilation – local (mechanical if used indoors on a continous basis) 

HANDLING PROCEDURES AND EQUIPMENT…………….Store in a cool, well ventilated area not to exceed 50 °C 

SYNERGISTIC MATERIALS……………………………………None Known 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

GLOVES/TYPE………………………………………………….…Wear chemical resistant gloves 

RESPIRATORY/TYPE……………………………………………If used indoors on a continuous basis, use of a cartridge type respirator (NIOSH/MSHATC 23C or 

equivalent) is recommended 

.EYE/TYPE………………………………………………………..Safety glasses 

FOOTWEAR/TYPE……………………………………….………Not normally required 

OTHER/TYPE…………………………………………….……….Not required 

Powerflo MSDS Page 1 of 2

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 

PHYSICAL STATE………………………….…..…..………………Aerosol 

APPEARANCE……………………………….……..……………….Colourless 

ODOR………………………………………….……………………..Ethereal 

ODOR THRESHOLD……………………..…..………..………...Not available 

VAPOUR PRESSURE (PSIG)-AEROSOL AT 20 °C….…….…65-75 

BOILING POINT (°C)(CONC)…………………………….….....57 

EVAPORATION RATE n-BUTYL ACETATE = 1………………..Not available 

VAPOUR DENSITY (AIR=1)………………..….…………......…Greater than 1 

(BY WEIGHT) 

SOLUBILITY IN WATER g/l (20°C)………………………….…..0.15 

pH…………………………………………………………………….Not available 

SPECIFIC GRAVITY (LIQUID)…………………………………..Not available 

COEFFICIENT OF WATER/OIL DIST…………………..……..Not available 

FREEZING POINT: (°C)………………………………………….-117 

AEROSOL PERCENT VOLATILE(BY WEIGHT)………………100 

SECTION 10: STABILITY AND REACTIVITY 

HAZARDOUS PRODUCTS OF DECOMPOSITION………... Hydrocarbon fumes and smoke. Carbon monoxide where combustion is incompletw. 


YES……………………………………………………………..….Under normal conditions 

NO, WHICH CONDITIONS?…………………………………….Not applicable 


NO, WHICH ONES?................................................................Strong oxidizing agents 

REACTIVITY CONDITIONS?..................................................Not applicable 

HAZARDOUS POLYMERIZATION……………………………..Will not occur 

SECTION 11: TOXICOLOGICAL INFORMATION 

REPRODUCTIVE EFFECTS…………………………………..No information is available and no adverse reproductive effects are anticipated 

IRRITATION OF MATERIAL………………………………….Skin/eye irritant 

SENSITIZING CAPABILITY OF MATERIAL………………..Unknown 

CARCINOGENICITY OF MATERIAL………………………...The ingredients of this product are not listed as carcinogens by NTP. (National Toxicology program), 

not regulated as carcinogens by OSHA (Occupational Safety and Health Administration), and have not 

been evaluated by IARC (International Agency for Research on Cancer), nor by ACGIH( American 

Conference of Governmental Industrial Hygenists). 

TERATOGENICITY……………………………. …………….....No information is available and no adverse teratogenic effects are anticipated. 

MUTAGENICITY……………………………………………..…No information is available and no adverse mutagenic effects are anticipated 

SECTION 12: ECOLOGICAL CONSIDERATIONS 

ENVIRONMENTAL………………………………………………..Not available 

SECTION 13: DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL………………………………………………Do not puncture or incinerate containers, even when empty. Dispose of in accordance with local, provincial, 

and 

federal regulations. 

SECTION 14: TRANSPORTATION INFORMATION 

T D G CLASSIFICATION…………………………………….Consumer commodity (aerosols, UN1950, class 2.2) 

D O T CLASSIFICATION…………………………….……..Consumer commodity ORM-D 

SECTION 15: REGULATORY INFORMATION 

CANADIAN REGULATIONS 

WHMIS CLASSIFICATION……………………….……….….….A,D2B 

CNFC SECTION 3.3.5…………………………..............….……LEVEL 1 

CEPA (CANADIAN ENVIRONMENTAL PROTECTION ACT)…All substances in this product are listen on the Canadian domestic substances list. (DSL) or are not required 

to be listed. 

U.S REGULATIONS 

HMIS RATING HEALTH…………………………………………..1 slight hazard 

HMIS RATING FLAMMABILITY………………………………….0 minimal hazard 

HMIS RATING REACTIVITY……………………………………..1 slight hazard 

HMIS RATING PERSONAL PROTECTION…………………....B 

NFPA COE 30B……………………………………………………Level 1 

SARA 313 INFORMATION………………………………………This product contains no ingredients subject to the reporting requirements of section 313 of the emergency 

planning and community right-to-know act of 1986 and of 40 CFR 372 

CAS # CHEMICAL NAME 

N/A 

CALIFORNIA PROPOSITION 65………………………………..The following statement is made in order to comply with the California safe drinking water and toxic 

enforcement 

act of 1986. Warning this product does not intentionally contain any chemicals known to the state of 

California to 

cause cancer, birth defects, or other reproductive harm. 

CAS# CHEMICAL NAME 

N/A 

TSCA (TOXIC SUBSTANCES CONTROL ACT) …………….All components of this product are listed on the TSCA inventory any impurities present in this product are 

exempt 

from listing. 

VOC (w/w%)……………………………………………………….o. 

Powerflo MSDS Page 2 of 2




HENKEL CONSUMER ADHESIVES 

6685 KENNEDY ROAD,UNIT 1 


(440) 937-7000 

MANUFACTURER.....................HENKEL CONSUMER ADHESIVES_____ 

6685 KENNEDY ROAD, UNIT 1 



(440) 937-7000 


WHMIS CLASSIFICATION WHMIS.......B2 D2B. D2B, D2A, E. WHEN THIS PRODUCT IS LABELLED AS A CONSUMER PRODUCT 

CLASSIFICATION WHMIS IT IS EXEMPT FROM WHMIS REGULATIONS. (SEE SECTION 12(f) OF THE HAZARDOUS 

CLASSIFICATION WHMIS PRODUCTS ACT). 

CLASSIFICATION WHMIS 

CLASSIFICATION 

T.D.G. CLASSIFICATION............ADHESIVES, CLASS 3, UN 1133, PKG GRP II. WHEN THIS PRODUCT IS LABELLED AS 

A CONSUMER COMMODITY IT IS EXEMPT FROM T.D.G. REGULATIONS 

PRODUCT NAME.....................LEPAGE PRES-TITE CONTACT CEMENT 

CHEMICAL FAMILY..................CONTACT CEMENT 

MATERIAL USE.....................WOODWORKING ADHESIVE 



Solvent naptha (petroleum), 30-60 TLV: 300ppm 8hrTWA 64742-89-8 >5g/kg,oral,rat Not available 

light aliphatic PEL: 500ppm 8hrTWA >3.16g/kg,skin, 

rabbit 

Magnesium oxide 1-5 PEL-TWA: 15 mg/m3 1309-48-4 810 mg/kg___________ Not available 

TLV-TWA: 10 mg/m3 oral,mouse 

2-Butanone 10-30 PEL-TWA: 200 ppm 78-93-3 2.7g/kg,oral,rat 23.5g/m3/8hr., 

4.0g/kg,oral,mouse rat 

6.5g/kg,skin,rabbit 

Toluene 10-30 TLV-TWA:188mg/m3 108-88-3 2.6-7.5g/kg,oral,rat 8800 ppm,4hr,rat 

PEL-TWA:375mg/m3 14.1ml/kg,skin,rbt 


PHYSICAL STATE...................Liquid 

APPEARANCE & ODOUR...............Yellowish liquid. Solvent odour 

ODOUR THRESHOLD (ppm)............Not available 

VAPOUR PRESSURE (mm Hg)..........Not available 

VAPOUR DENSITY (AIR=1)...........3.0 

BY VOLUME 

BY WEIGHT 

EVAPORATION RATE.................>1 (Butyl Acetate = 1) 

BOILING POINT (deg C)............66 deg C 

pH...............................Not available 




DISTRIBUTION 


FLAMMABILITY.....................EXTREMELY FLAMMABLE 

IF YES, UNDER WHICH..............Excessive heat, sparks and open flame. Vapours may cause flash fires. 

CONDITIONS? Vapours may ignite explosively. 

AUTO IGNITION TEMPERATURE........> 250 deg C 

EXTINGUISHING MEDIA..............Carbon dioxide, dry chemical, foam 


to protect against potentially toxic and irritating fumes. A solid stream 

of water directed on hot and/or burning material may cause violent 

frothing. 

FLASH POINT (C), METHOD..........-12 deg C, CC 

LOWER FLAMMABLE LIMIT (% VOL)....1.0 

UPPER FLAMMABLE LIMIT (% VOL)....10.0 

HAZARDOUS COMBUSTION PRODUCTS....Hydrocarbons and traces of chlorine compounds. Oxides of carbon (CO,CO2). 

Smoke 


YES........................Stable, hazardous polymerization will not occur. Under normal conditions 

NO, WHICH CONDITIONS ? 


SUBSTANCES:




YES 

NO, WHICH ONES?............Strong oxidizing agents 

REACTIVITY CONDITIONS ? 

HAZARDOUS PRODUCTS OF............Smoke. Chlorine compounds. Oxides of carbon (CO,CO2) at high temperatures. 

DECOMPOSITION 


SKIN CONTACT...............Can cause drying and defatting of skin leading to irritation and 

dermatitis. May cause irritation, especially on prolonged contact. 

SKIN ABSORPTION............May be absorbed by the skin. 

EYE CONTACT................Vapours cause tearing. May cause moderate to severe irritation. Causes 

corneal damage. 

INHALATION.................High vapour concentrations are irritating to the eyes and the respiratory 

tract. May cause headaches and dizziness; are anaesthetic. May affect 

central nervous system. 

INGESTION..................Vomiting presents an aspiration hazard and may result in chemical 

pneumonia, pulmonary edema or hemorrhage. Can cause gastro-intestinal 

irritation, nausea, vomiting and diarrhea. Product may be toxic if 

ingested. 


EFFECTS OF CHRONIC EXPOSURE......Dermatitis. Deliberate and repeated inhalation may result in teratogenic 

and embryonic toxic effects. May aggravate existing eye, skin, and lung 

conditions. 

LD 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2) 

ROUTE 

LC 50 OF MATERIAL, SPECIES &.....See hazardous ingredients section (2). 

ROUTE 


IRRITANCY OF MATERIAL............Eye irritation:. Moderate to severe. Skin irritation:. Components of this 

formulation known to cause irritation. 

SENSITIZING CAPABILITY OF........Refer to route of entry 

MATERIAL 

CARCINOGENICITY OF MATERIAL......Not indicated 

MUTAGENICITY OF MATERIAL.........Not available 

REPRODUCTIVE EFFECTS.............Risk of abortion in animal. Teratogenic and fetotoxic effects have not 

been clearly demonstrated in humans. 

TERATOGENICITY OF MATERIAL.......Refer to route of entry. 

SYNERGISTIC MATERIALS............Not available 


GLOVES/ TYPE...............Wear impervious gloves (in neoprene or rubber). 


whenever mist or spray is generated. 

EYE/TYPE...................Safety glasses with side-shields 



VENTILATION REQUIREMENTS.........Use adequate local exhaust ventilation. Explosion-proof exhaust ventilation 

LEAK/SPILL.......................Eliminate all sources of ignition. Evacuate all non-essential personnel. 

Follow all applicable fire and explosion precautions during the spill 

response procedure. Clean up spills immediately. For small spills:. Absorb 

residual material with sand, or other absorbent material. For large 

spills:. Dike area to prevent spreading. Isolate product until disposal. 

WASTE DISPOSAL...................In accordance with municipal, provincial and federal regulations. Since 

emptied container retains product residues all labelled hazard precautions 

must be observed. 

HANDLING PROCEDURES AND..........Use adequate ventilation. Keep away from heat, sparks, and open flame. 

EQUIPMENT Wear chemical splash goggles, gloves, and protective clothing. 

SPECIAL SHIPPING INSTRUCTIONS....Ship in accordance with applicable Transportation of Dangerous Goods (TDG) 

regulations. Protect against physical damage. 


EYE CONTACT......................Immediately flush with water for a minimum of 15 minutes holding lids 

apart to ensure flushing of entire surface. Washing within 1 minute is 

essential to achieve maximum effectiveness. 

INGESTION........................Dilute with large quantities of water or milk. DO NOT induce vomiting. Get 

immediate medical attention. Never give anything by mouth to an 

unconscious person. 

INHALATION.......................Remove victim to fresh air. If not breathing qualified personnel should 

administer artificial respiration. Get medical attention. 





TELEPHONE NUMBER:................(440)937-7000









guarantee, express or implied, is made by Henkel Consumer Adhesives as to 


of the product nor does Henkel Consumer Adhesives assume any liability 






PREPARATION DATE.................MAY 12/2006 Rev 4/ 2010 


Product Name: Propane MSDS No.: E-4646-J Date: Oct. 15, 2010 

Product Name: Propane 

Product Use: Many. 

Chemical Name: Propane 



Trade Name: 

Synonym: 

Chemical Formula: C3H8 Chemical Family: Alkane 

Telephone: 

Emergencies: * 1-800-363-0042 

Supplier 

/Manufacture: 

Phone: 

Fax: 

Liguefied Petroleum Gas 

Dimethylmethane, propyl hydride, 

propylhydride 



Suite 1200 


905-803-1600 

905-803-1682 



DANGER! 



Flammable liquid and gas under pressure. Can form explosive mixtures with air. May cause 

frostbite. Can cause rapid suffocation. May cause dizziness and drowsiness. Self-contained 

breathing apparatus may be required by rescue workers. Odour: Faintly disagreeable. 

ROUTES OF EXPOSURE: Inhalation. Skin contact. Eye contact. 





INHALATION: 

SKIN CONTACT: 


SWALLOWING: 

EYE CONTACT: 

Asphyxiant. Effects are due to lack of oxygen. Moderate concentrations may cause 

headaches, drowsiness, dizziness, excitation, excess salivation, vomiting, and 

unconciousness. Lack of oxygen can kill. 

No harm expected from vapour. Liquid may cause frostbite. 


This product is a gas at normal temperature and pressure. Frostbite of the lips and 

mouth may result from contact with liquid. 

No harm expected from vapour. Liquid may cause frostbite. 



Product Name: Propane MSDS# E-4646-J Date: Oct. 15, 2010 


WORKING WITH WELDING AND CUTTING MAY CREATE ADDITIONAL HEALTH HAZARDS. FUMES AND GASES 

can be dangerous to your health and may cause serious lung disease.* Keep your head out of the fumes. Do not 

breathe fumes and gases caused by the process. Use enough ventilation, local exhaust, or both to keep fumes and 

gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the 

equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, metals etc. Get a 

Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory 

protection is needed. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness 

or irritation of nose, throat, or eyes. 


Contact with liquid may cause frostbite. At very high concentrations may produce cardiac arrhythmia or arrest due to 

sensitization of the heart to adrenalin and nor-adrenalin. Exposure to fluorocarbon thermal decomposition products may 

produce flu-like symptoms including chills, fever, weakness, muscular aches, headache, chest discomfort, sore throat, 

and dry cough. Complete recovery usually occurs within 24 hours after exposure. 


A knowledge of the available toxicology information and of the physical and chemical properties of the material 

suggests that overexposure is unlikely to aggravate existing medical conditions. 


In a study conducted in 1948, dogs breathed varying mixtures of hydrocarbons and oxygen for 10 minutes. Of a group 

of dogs exposed to propane, all (3 of 3) showed myocardial sensitivity to injected epinephrine hydrochloride as 

determined by electrocardiogram (EKG) readings. No direct evidence is known of propane-induced cardiac 

sensitization in humans. 





NUMBER 

CONCENTRATION 

% by Mole 

Propane 74-98-6 100 


INHALATION: 

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical 

attention. 

SKIN CONTACT: 

For exposure to liquid, immediately warm frostbite area with warm water not to exceed 41 C. In case of massive 

exposure, remove contaminated clothing while showering with warm water. Call a physician. 

SWALLOWING: 

This product is a gas at normal temperature and pressure. Frostbite of the lips and mouth may result from contact with 

liquid. 

EYE CONTACT: 

For contact with the liquid, immediately flush eyes throughly with warm water for at least 15 minutes. Hold the eyelids 

open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. See a physician, preferably an 

ophthalmologist, immediately. 


There is no specific antidote. Treatment of over-exposure should be directed at the control of symptoms and the clinical 

condition. This material may be a cardiac sensitizer, avoid use of epinephrine. 




CO2, dry chemical, water spray or fog. 



FLAMMABLE : Yes. IF YES, UNDER WHAT CONDITIONS? Forms explosive mixtures with air 

and oxidizing agents. 


These products are carbon oxides (CO, CO2). 

DANGER! Evacuate all personnel from danger area. Immediately cool cylinders with water spray from maximum 

distance taking care not to extinguish flames. Remove ignition source if without risk. If flames are 

accidentally extinguished. Explosive re-ignition may occur; therefore, appropriate measures should be taken; 

e.g., total evacuation. Reapproach with extreme caution. Use self-contained breathing apparatus. Stop 

flow of gas if without risk while continuing cooling water spray. Remove all containers from area if without 

risk. Allow fire to burn out. 


Flammable gas. Forms explosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do 

not extinguish flames due to possibility of explosive re-ignition. Vapours form from this product and may travel or be 

moved by air currents an ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static 

discharges, or other ignition sources at locations distant from product handling point. Explosive atmospheres may 

linger. Before entering area, especially confined areas, check atmosphere with approved device. No part of a container 

should be subjected to temperature higher than 52 C. Most containers are provided with a pressure relief device 

designed to vent contents when they are exposed to elevated temperature. 




Possible, ground container. 





LOWER: 2.1 

UPPER: 9.5 

FLASH POINT: CLOSED CUP: -104°C (-155.2°F). 

(Tag.) 

450°C (842°F) 




DANGER! Immediately evacuate all personnel from danger area. Forms explosive mixtures with air. Use selfcontained 

breathing apparatus and protective clothing where needed. Remove all sources of ignition if 

without risk. Reduce vapours with fog or fine water spray. Shut off leak if without risk. Ventilate area of 

leak or move leaking container to well ventilated area. Flammable vapours may spread from spill. 

Before entering area, especially confined areas, check atmosphere with appropriate device. 




Prevent waste from contaminating the surrounding environment. Keep personnel away. Discard any product, residue, 

disposable container, or liner in an environmentally acceptable manner, in full compliance with federal, provincial, and 

local regulations. If necessary, call your local supplier for assistance. 



Protect cylinders from damage. Use a suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Never 

attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. Never insert an object (e.g., wrench, 

screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap 

wrench to remove over-tight or rusted caps. Open valve slowly. If valve is hard to open, discontinue use and contact 

your supplier. For other precautions, see Section 16. 

For additional information on storage and handling, refer to Compressed Gas Association (CGA) pamphlet P-1, Safe 

Handling of Compressed Gases in Containers, available from the CGA. Refer to Section 16 for the address and phone 

number along with a list of other available publications. 


Store and use with adequate ventilation. Separate flammable cylinders from oxygen, chlorine, and other oxidizers by at 

least 6 m or use a barricade of non-combustible material. This barricade should be at least 1.5 m high and have a fire 

resistance rating of at least ½ hour. Firmly secure cylinders upright to keep them from falling or being knocked over. 

Screw valve protection cap firmly in place by hand. Post "No Smoking or Open Flames" signs in storage and use areas. 

There must be no sources of ignition. All electrical equipment in storage areas must be explosion-proof. Storage areas 

must meet national electric codes for Class 1 hazardous areas. Store only where temperature will not exceed 52 C. 

Store full and empty cylinders separately. Use a first-in, first-out inventory system to prevent storing full cylinders for 

long periods. 


Flammable high-pressure gas. Use only in a closed system. Use piping and equipment adequately designed to 

withstand pressures to be encountered. Use only spark-proof tools and explosion-proof equipment. Keep away from 

heat, sparks, and open flame. May form explosive mixtures with air. Ground all equipment. Gas can cause rapid 

suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve after each use; keep 

closed even when empty. Prevent reverse flow. Reverse flow into cylinder may cause rupture. Use a check valve or 

other protective device in any line or piping from the cylinder. When returning cylinder to supplier, be sure valve is 

closed, then install valve outlet plug tightly. Never work on a pressurized system. If there is a leak, close the cylinder 

valve. Vent the system down in a safe and environmentally sound manner in compliance with all federal, provincial, and 

local laws; then repair the leak. Never place a compressed gas cylinder where it may become part of an electrical 

circuit. 






supplier. 



(Species & 

Routes) 

Propane 74-98-6 Not 

applicable. 

(Rat, 4 

hrs.) 

Not 

available. 


1000 ppm 











SPECIAL: 

OTHER: 

An explosion-proof local exhaust system is acceptable. See SPECIAL. 

Inadequate. 

See SPECIAL. 

Use only in a closed system. 

See SPECIAL. 

RESPIRATORY PROTECTION: Use respirable fume respirator or air supplied respirator when 

working in confined space or where local exhaust or ventilation 

does not keep exposure below TLV. Select in accordance with 

the provincial regulations or guidelines. Selection should also be 

based on the current CSA standards Z94.4, "Selection, care and 

use of respirators". Respirators should be approved by NIOSH 

and MSHA. 

SKIN PROTECTION: Wear work gloves when handling cylinders to prevent exposure to 

liquid. Wear welding gloves for welding. 



PHYSICAL STATE: Gas. (Compressed Gas.) 

BOILING POINT 

SPECIFIC 

GRAVITY: 


SPECIFIC 

GRAVITY: 

VAPOUR 

(air = 1) 

-42.03°C (-43.7°F) 

0.59 @ 45 C 

1.55 












VAPOUR 

PRESSURE 

SOLUBILITY IN 

WATER, 

EVAPORATION 

RATE 


VAPOUR DENSITY: 1.55 % VOLATILES BY 

VOLUME: 

-187.68°C 

(-305.8°F) 

852.5 kPa (@ 

20°C) 

Negligible. 

>1 compared to 

(Butyl Acetate = 1) 

100% (v/v). 

Odour: Faintly disagreeable 




WATER/OIL 

DISTRIBUTION: 

44.097 g/mole 


ODOUR THRESHOLD: Not available. 






STABILITY: 


CONDITIONS OF CHEMICAL INSTABILITY: Not available. 


Oxidizing agents. Chlorine dioxide. 


Thermal decomposition or burning may 

produce carbon monoxide/carbon dioxide. 


Will not occur. 



None known. 

None. 

None. 


Possible cardiac sensitization to epinephrine; see section 2. The welding process may 

generate hazardous fumes and gases. (See section 2, 10, 15 and 16) 






TDG/IMO SHIPPING NAME: Liquefied Petroleum Gases 

HAZARD CLASS: CLASS 2.1: 

Flammable gas. 


supplier. 



SHIPPING LABEL(s): Flammable gas 



Flammable gas 

UN1978, 

or UN 

1075 

PRODUCT RQ: 

Any accidental 

release in a 

quantity that 

could pose a 

danger to public 

safety or any 

sustained 

release of 10 

minutes or 

more. 







CLASS B-1: Flammable gas. 








This product is not classified according to the EU regulations. 

DSCL (EEC): 



MIXTURES: 






HMIS RATINGS: 

HEALTH 

FLAMMABILITY 


1 

4 

2 


THREADED: 

CGA-510 (gas withdrawal) 

CGA-555 (liquid withdrawal) 


Not available. 

ULTRA-HIGH-INTEGRITY Not available. 

CONNECTION: 







AV-1 Safe Handling and Storage of Compressed Gas 


P-14 Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmosphere 

SB-2 Oxygen-Deficient Atmospheres 


V-7 Standard Method of Determining Cylinder Valve Outlet Connections for Industrial Gas Mixtures 






information. 




DATE: 

DEPARTMENT: 

TELEPHONE: 

October 15, 2010 


905-803-1600 


















Suite 1200 


Page 8 of 8

No changes as of May 2011 

Product Discontinued

PRODUCT NO LONGER 

AVAILABLE APRIL 15, 2011


Product Name(s): Sand and Gravel 



Product Identifiers: Natural Sand, River Sand Screenings, Aggregates, Bank Sand and Gravel, Crushed 

Gravel, Round Gravel, Concrete Sand, Asphalt Sand, Mason Sand, Fill Sand, Golf 

Course Sand, Base Material, Dense Graded Aggregate, Quartz, Gravel, Crushed 

Rock, Crushed Stone 





Product Use: Sand and gravel are aggregates used in the manufacture of bricks, mortar, cement, 

concrete, plasters, paving materials, and other construction applications. Sand and 

gravel are distributed in bags, totes and bulk shipment. 

DO NOT use this product for abrasive blasting. This material safety data sheet and 

the information contained herein were not developed for abrasive blasting. 

Note: This MSDS covers many types of sand and gravel. Individual composition of 

hazardous constituents will vary between sand and gravel types. 


Component 

Percent 

(By Weight) 

CAS 

Number 

OSHA PEL -TWA 

(mg/m 3 ) 

ACGIH TLV-TWA 

(mg/m 3 ) 

Crystalline Silica (quartz) 50-99 14808-60-7 [(10) / (%SiO2+2)] (R); 

[(30) / (%SiO2+2)] (T) 

0.025 (R) NA NA 

Particulate Not Otherwise 

Regulated 

- NA 5 (R); 15 (T) 3 (R); 10 (T) NA NA 

Warning: Crystalline silica exists in several forms, the most common of which is quartz. If 

crystalline silica (quartz) is heated to more than 870º C it can change to a form of 

crystalline silica known as tridymite, and if crystalline silica (quartz) is heated to more 

than 1470º C it can change to a form of crystalline silica known as cristobalite. 

Crystalline silica as tridymite and cristobalite are more fibrogenic than crystalline silica 

as quartz. The OSHA PEL for crystalline silica as tridymite and cristobalite is one-half 

the PEL for crystalline silica (quartz); the ACGIH TLV for crystalline silica as 

cristobalite is 0.025 mg/m 3 (R). 


WARNING 



DO NOT use for Sand Blasting. 

Use proper engineering controls, work 

practices, and Personal Protective Equipment 

(PPE) to prevent exposure to dust. 


Respiratory 

Protection 

Page 1 of 6 Revised: 03/01/11 

LD50 

Eye 

Protection 

LC50



Emergency Overview: Sand and gravel are a white or light grey/brown sold material and is odorless. It is not 

combustible or explosive. A single, short-term exposure to sand and gravel presents 

little or no hazard. 


Eye Contact: Eye contact to airborne dust may cause immediate or delayed irritation or 

inflammation. Eye exposures require immediate first aid and medical attention to 

prevent significant damage to the eye. 

Skin Contact: Sand and gravel may cause dry skin, abrasions, discomfort, and irritation. 

Inhalation (acute): Breathing dust may cause nose, throat or lung irritation, including choking, depending 

on the degree of exposure. 





Carcinogenicity: Crystalline silica is classified by IARC and NTP as a known human carcinogen. 








Ingestion: Do not ingest sand or gravel. Although ingestion of small quantities of sand or gravel 

is not known to be harmful, large quantities can cause intestinal distress. 


Aggravated by Exposure: disease) can be aggravated by exposure. 



remove all particles. Seek medical attention for abrasions. 


attention for rash or irritation. 


















surrounding fire. 













Firefighting Equipment: Sand and gravel poses no 

fire-related hazard. A SCBA 

is recommended to limit 



fire. 

Combustion Products: None. 

General: Place spilled material into a container. Avoid actions that cause the sand or gravel to 

become airborne. Avoid inhalation of dust. Wear appropriate protective equipment 

as described in Section 8. Do not wash sand or gravel down sewage and drainage 

systems or into bodies of water (e.g. streams). 

Waste Disposal Method: Dispose of sand and gravel according to Federal, State, Provincial and Local 

regulations. 


General: Stack bagged material in a secure manner to prevent falling. Bagged sand and 

gravel is heavy and poses risks such as sprains and strains to the back, arms, 

shoulders and legs during lifting and mixing. Handle with care and use appropriate 

control measures. 

Engulfment hazard. To prevent burial or suffocation, do not enter a confined space, 

such as a silo, bin, bulk truck, or other storage container or vessel that stores or 

contains sand or gravel. Sand or gravel can buildup or adhere to the walls of a 

confined space. The sand or gravel can release, collapse or fall unexpectedly. 

Usage: This product is NOT to be used for abrasive blasting. 

Cutting, crushing or grinding hardened cement, concrete or other crystalline silicabearing 




Housekeeping: Avoid actions that cause the sand or gravel to become airborne during clean-up such 

as dry sweeping or using compressed air. Use HEPA vacuum or thoroughly wet 

with water to clean-up dust. Use PPE described in Section 8 below. 


Clothing: Remove and launder clothing that is dusty before it is reused. 










Eye Protection: Wear ANSI approved glasses or safety goggles when handling dust to prevent 

contact with eyes. Wearing contact lenses when using sand or gravel, under dusty 

conditions, is not recommended. 

Skin Protection: Wear gloves in situations where abrasion from sand or gravel may occur. Remove 

clothing and protective equipment that becomes dusty and launder before reusing. 


Physical State: Granular Solid. Evaporation Rate: NA. 

Appearance: White or light gray/brown. pH (in water): Neutral 

Odor: None. Boiling Point: >1000 o C 

Vapor Pressure: NA. Freezing Point: None, solid. 

Vapor Density: NA. Viscosity: None, solid. 

Specific Gravity: 2.7 Solubility in Water: Insoluble 


Stability: Stable. Avoid contact with incompatible materials. 

Incompatibility: Sand and gravel dissolve in hydrofluoric acid, producing corrosive silicon tetrafluoride 

gas. Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine 














Section 15: REGULATORY INFORMATION (continued) 








1986 and 40 CFR Part 372. 





TSCA: Crystalline silica is exempt from reporting under the inventory update rule. 

California Crystalline silica (airborne particulates of respirable size) is known by the State of 

Proposition 65: California to cause cancer. 

WHMIS/DSL: Sand and gravel may be subject to WHMIS depending on the intended use and 

worker exposure. Sand and gravel containing crystalline silica is classified as D2A, 





ACGIH 






and Health 




Act 

OSHA 








HMIS 


System 

SARA 



IARC 


Cancer 

T 

TDG 





mg/m 3 

MSHA 



WHMIS 













regulations. 




DR 


acc. to ISO/DIS 11014 

Page 7/8 

Printing date 01/21/2009 Reviewed on 09/10/2008 

Trade name: SOLDER ALLOYS CONTAINING LEAD 

15 Regulations 

USA The following information relates to product regulation specific to the USA. 

SARA (Superfund Amendments and Reauthorization Act) 

Section 355 (extremely hazardous substances): 

None of the ingredient is listed. 

Section 313 (Specific toxic chemical listings): 

7439-92-1 lead 

7440-36-0 antimony 

7440-50-8 copper 

7440-22-4 silver 

TSCA (Toxic Substances Control Act): 

All ingredients are listed or exempt from listing. 

(Contd. of page 6) 

Califo rnia Propo sitio n 65 

Chemicals known to cause cancer: 

WARNING: This product contains a chemical(s) known to the State of California to cause cancer. 

Chemicals known to cause reproductive toxicity: 

WARNING: This product contains a chemical(s) known to the State of California to cause birth defects and/or other 

reproductive harm. 

Carcino genicity categories 

EPA (Environmental Protection Agency) 

7439-92-1 lead B2 

IARC (International Agency for Research on Cancer) 

7439-92-1 lead 2B 

NTP (National Toxicology Program) 

None of the ingredients is listed. 

NIOSH-Ca (National Institute for Occupational Safety and Health) 


OSHA-Ca (Occupational Safety & Health Administration) 


CANADA: The following information relates to product regulation specific to Canada. 

Wo rkplac e Hazardous Materials Identific atio n (WHMIS): 

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products 

Regulation (CPR) and the MSDS contains all of the information required by the CPR. 

WHMIS Classification: D2A 

EUROPEAN UNION 

The following information relates to product regulation specific to the directives of the European Union. (Contd. on page 8) 

USA

DR 


acc. to ISO/DIS 11014 

Page 8/8 

Printing date 01/21/2009 Reviewed on 09/10/2008 

Trade name: SOLDER ALLOYS CONTAINING LEAD 

Risk phrases: 

Harmful by inhalation and if swallowed. 

Danger of cumulative effects. 

Possible risk of impaired fertility. 

Safety phrases: 

Keep out of the reach of children. 

Wear suitable protective clothing and gloves. 

If swallowed, seek medical advice immediately and show this container or label. 

Dispose of this material and its container to hazardous or special waste collection point. 

Special labeling of certain preparatio ns: 

Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. 

(Contd. of page 7) 

* 16 Other info rmatio n 

The information co ntained here in is based on data considered acc urate and is o ffered solely fo r informatio n, 

consideration and investigation. Kester extends no warranties, makes no representations and assumes no 

responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this 

Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any 

process. All chemical products should be used only by, or under the direction of, technically qualified personnel who 

are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication 

regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for 

hazard information. 

Abbreviations and acronyms: 

ADR: Ac cord europ en sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International Carriage of 

Dangerous Goods by Road) 

RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the International 

Transport of Dangerous Goods by Rail) 

IMDG: Inte rnatio nal Maritime Co de for Dangero us Goo ds 

DOT: US Department of Transportation 

IATA: International Air Transport Ass oc iation 

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) 

ICAO: International Civil Aviation Organization 

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) 

GHS: Globally Harmonized System of Classification and Labelling of Chemicals 

NFPA: National Fire Protection Association (USA) 

HMIS: Hazardous Materials Identific ation System (USA) 

WHMIS: Workplace Hazardous Materials Information System (Canada) 

LC50: Lethal conc entration, 50 perc ent 

LD50: Lethal dose, 50 perc ent 

* Data co mpared to the previo us versio n altered. 

USA

ACL Incorporated IW-50 Anti-Static Wipes 

MSDS Information 

Section 1 CHEMICAL PRODUCT SECTION 

Product Name: STATICIDE ® Industrial Wipes 

Product Number: #IW-50 

Manufacturer: ACL Incorporated For Chemical Emergency, 

1960 E. Devon Avenue Spill, Leak, Fire Exposure, 

Elk Grove Village, IL 60007 Or Accident Call INFOTRAC 

PH: (01) 847.981.9212 [U.S.A.] DAY OR NIGHT (01) 800.535.5053 

FAX: (01) 847.981.9278 [U.S.A.] 

Section 2 INFORMATION ON HAZARDOUS INGREDIENTS 

CHEMICAL C.A.S. Number Weight % 

Deionized Water 7732-18-5 55-60 

Isopropanol 67-63-0 30-40 

Ethanol 64-17-5 < 1 

OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): 

Exposure Limits 8 Hours TWA (PPM) 

OSHA PEL ACGIH TLV Supplier 

Isopropanol 400 ppm 400 ppm 

Ethanol 1000 ppm 1000 ppm 

Section 3 HAZARD IDENTIFICATION 

Emergency Overview: 


Inhalation: May cause headaches, dizziness and nausea if excessively inhaled. 

Eyes: Will irritate eyes 

Skin: May dry skin. 

Ingestion: Not normal route of entry. Nausea and diarrhea are possible. 

Section 4 FIRST AID MEASURES 

Inhalation: Move to fresh air and contact a physician if necessary. 

Eye Contact: Flush eyes with large amounts of water for 15 minutes or until 

irritation subsides. If irritation persists, get medical attention. 

Skin Contact: Wash with soap and water. 

Ingestion: Not normal route of entry. Drink copious amounts of water/milk, and 

seek medical attention. 

Page 1 of 5


Section 5 FIRE FIGHTING MEASURES 

Flash Point & Method: 20°C – Penske Martens. 

Flammable Limits: LEL: 2 UEL: 12 

Autoignition Temperature: NIF 

General Hazard: If package is opened, the contents will burn. 

Fire Fighting Instructions: NA 

Fire Fighting Equipment: NA 

Hazardous Combustion Products: Carbon Oxides, Nitrogen Oxides 

Section 6 ACCIDENTAL RELEASE MEASURES 

Land spill: If package is damaged, treat as flammable and remove sources of ignition. 

Pick up and place in disposal container. If packaging is intact, product may be used before 

discarding. 

Water spill: NA 

Section 7 HANDLING AND STORAGE 

Handling: Keep away from heat sources. Keep container closed when not in use. Store in 

cool, well ventilated place out of direct sunlight and away from incompatible 

materials 

Storage Temperatures: Ambient 

Storage Pressure: Atmospheric 

General: Observe good housekeeping practices. Follow all MSD sheet and Label 

warnings even after container is emptied. 

Section 8 EXPOSURE CONTROL / PERSONAL PROTECTION 

Engineering Controls: Local exhaust ventilation acceptable 

See section 2 for component exposure guidelines. 

Personal Protection: With proper usage, none is required. 

Respirator: None 

Hand Protection: None 

Eye Protection: None 

Page 2 of 5


Section 9 PHYSICAL AND CHEMICAL PROPERTIES 

Density…………………NE pH………………………….… NE 

Boiling Point……….. … Liquid = 80°C % Volatile……………………< 5 

Freezing Point……… …NE % Solids……………………..NE 

Vapor Density (Air=1)…2.1 est Evaporation Rate (H2O=1)…> 1 

Solubility in Water……Miscible MolecularWeight……………NE 

Odor…………………..Alcohol Appearance: Applicator saturated with 

clear liquid. 

Section 10 STABILITY AND REACTIVITY 

General: Stable. Polymerization will not occur. 

Incompatible Materials and Conditions to Avoid: Strong Acids, strong bases, oxidizing 

agents 

Hazardous Decomposition: NE 

Section 11 TOXICOLOGY INFORMATION 

Results of Component Toxicity Test Performed: 

Acute dermal toxicity (LD50) :


Section 14 TRANSPORTATION INFORMATION 

U.S. DOT Information 

Proper Shipping Name: Non Hazardous Material 

Hazard Class: NA 

IATA 

Proper Shipping Name: NON HAZARDOUS MATERIAL 

Hazard Class: NA 

Section 15 REGULATORY INFORMATION 

United States Federal Regulations: 

MSDS complies with the OSHA Hazard Communication Rule, 29 CFR 1910.1200. 

CERCLA/Superfund, 40 CFR 117, 302: 

---None of the chemicals are Section 302 hazards --- 

SARA Superfund and Reauthorization Act of 1986 Title III sections 302, 311,312 and 313: 

Section 302 – Extremely hazardous substances (40 CFR 355): 

---None of the chemicals are Section 302 hazards --- 

Section 311/312 – Material Safety Data Sheet Requirements (40 CFR 370): 

(X ) By our hazard evaluation, this product is non-hazardous. 

( ) By our hazard evaluation, this product is hazardous. It should 

be reported under the following EPA hazard. 

( ) Immediate (acute) health hazard 

( ) Delayed (chronic) health hazard 

( ) Sudden release of pressure hazard 

( ) Reactive hazard 

Section 313 – List of Toxic Chemicals (40CFC 372): 

This product contains the following chemicals ( at level of 1% or greater) 

which are found on the 313 list of Toxic Chemicals. 

Chemical C.A.S. NUMBER WEIGHT % 

---None of the chemicals are 313 Toxic Chemicals --- 

Toxic Substance Control Act (TSCA): All substances are TSCA listed. 

Resource Conservation and Recovery Act (RCRA 40 CFR 261) Subpart C & D: 

Refer to Section 13 for RCRA classification. 

Federal Water Pollution Control Act, Clean Water Act, 40 CFR 401.15 (formerly section 

307) 40 CFR 116 (formerly section 311) 

This product contains the following chemicals which are listed: 

CHEMICAL C.A.S. NUMBER WEIGHT % 

---None of the chemicals are Listed --- 

Clean Air Act: --- No Information --- 

Page 4 of 5


STATE REGULATIONS: 

California Proposition 65: --- None of the chemicals are on the Proposition 65 list--- 

INTERNATIONAL REGULATIONS: 

Canada WHMIS: This product has been classified in accordance with the hazard criteria of 

the CPR and the MSDS contains all the information required by the CPR. 

Europe EINECS Numbers: Isopropyl Alcohol #200-661-7 

Ethanol # 200-578-6 

Sections 16 OTHER INFORMATION 

LABEL INFORMATION: 

For Shipping Label information refer to section 14 

Product label warnings are as follows (Comparable CHIP Safety & Risk phrases are noted): 

Flammable (R10) 

Keep out of the reach of children (S2) 

NFPA HAZARD RATING: 

(3) Fire (1 ) Health (0 ) Reactivity 

REVISION DATES, SECTIONS, REVISED BY: 

15-Mar-92, Original release date 

02-APR-01, Reviewed 

16-MAR-04, Revised and Reviewed all Sections, MKB 

ABBREVIATIONS USED IN THIS DOCUMENT: 

NE – Not Established, NA – Not Applicable, NIF – No Information Found 

ABRIDGED LIST OF REFERENCES: 

Code of Federal Regulations (CFR) 

The Sigma-Aldrich Library of Regulatory and Safety Data 

Chemical Guide and OSHA Hazardous Communication Standard 

The Environmental Protection Agency (www.epa.gov) 

ANSI Standard: ANSI Z400.1-1998 

Merck Index 

To the best of our knowledge, the information contained herein is accurate. However, neither ACL 

STATICIDE nor any of its subsidiaries assumes any liability whatsoever for the accuracy or 

completeness of the information contained herein. Final determination of suitability of any material is the 

sole responsibility of the user. All materials may present unknown hazards and should be used with caution. 

Although certain hazards are described herein, we cannot guarantee that these are the only hazards which 

exist. 

Page 5 of 5

Boo ho 

Date: 7/19/2010 MSDS No.: CAN-W400-C 

Trade Name: Super Glaze Aluminum Wires/Rods 

Sizes: All 

Supersedes: 8/1/07 

M A T E R I A L S A F E T Y D A T A S H E E T 

For Welding Consumables and Related Products 

Conforms to Workplace Hazardous Materials Information System (WHMIS) Rev. November, 1988 

Section I & II - Preparation and Product Information 

Product Type: Aluminum Electrodes and Rods 

The Lincoln Electric Company of Canada LP 

179 Wicksteed Avenue 

Toronto, Ontario M4G 2B9 CANADA 

Phone: (416) 421-2600 

Products: Super Glaze 1100, 4043, 4047, 5087, 5183, 5356, 

5554, 5556, 5754 

Prepared by The Lincoln Electric Company, Cleveland, Ohio, USA 

(216) 481-8100, on the date shown above. 

Section III - Hazardous Ingredients (1) 

I M P O R T A N T ! 

This section covers the materials from which this product is manufactured. The fumes and gases produced during welding with the normal use of this 

product are covered by Section VII; see it for industrial hygiene information. 

CAS Number shown is representative for the ingredients listed. 

(1) The term “hazardous” in “Hazardous Ingredients” should be interpreted as a term required and defined in the Hazardous Products Act and does 

not necessarily imply the existence of any hazard. 

TLV 

Ingredients: CAS No. Wt. % mg/m 3 

LD50 LC50 mg/m 

(Route/Species) 

3 


Aluminum wire 100 10* 

Nominal wire composition: 

Aluminum 7429-90-5 87 - 100 10** Not Available Not Available 

Silicon (4043 and 4047 only) 7440-21-3 5 - 13 10* Not Available Not Available 

Magnesium (5087, 5183, 5356, 5554, 5556, 5754 only) 7439-95-4 < 5 10* 

230 mg/kg LDLo 

(oral/dog) 

Not Available 

Manganese (5087, 5183, 5356, 5554, 5556, 5754 only) 7439-96-5 < 1 0.2 

9 g/kg 

(oral/rat) 

2.3 LCLo 

(inhalation/human) 

Copper (1100 only) 7440-50-8 < 0.5 0.2(a) 

0.12 mg/kg LDLo 

(oral/human)gastrointestinal 

Not Available 

Chromium (5087, 5183, 5356, 5554, 5556 only) 7440-47-3 < 0.5 0.5(b) 


(intravenous/rat)tumorigenic Not Available 

Zirconium (5087 only) 7440-67-7 < 0.5 5 Not Available Not Available 

Notes: 

(*) Not listed. Nuisance value maximum is 10 milligrams per cubic meter. 

(**) TLV for aluminum welding fume is 5 mg/m 3 . 

(a) Values are for copper fume. 

(LDLo, LCLo) Lowest published toxic concentration. 

(b) The OSHA PEL for chromium (VI) is 5 micrograms (0.005 

milligrams) per cubic meter. The TLV for water soluble 

chromium (VI) is 0.05 milligrams per cubic meter and the 

TLV for insoluble chromium (VI) is 0.01 milligrams per 

cubic meter. 

Section IV - Physical Data 

Physical data such as odor, vapor pressure, density, evaporation rate and freezing or boiling points are not listed as they are not applicable to 

this product and its use. 

Section V - Hazard Data 

Non Flammable; Welding arc and sparks can ignite combustibles and flammable products. See CSA W117.2 Section 9.7 as referenced in 

Section VIII. Product is inert, no special handling or spill procedures required. 

Rev 9/07 (CONTINUED ON SIDE TWO)

Product: Super Glaze Aluminum Wires/Rods 

Date: 7/19/2010 

Section VI - Health Hazard Data and Toxicological Properties 

Acute Lethality Values: LC50 means the concentration of a substance in air that when administered by means of inhalation over a specified length of time 

in an animal assay, is expected to cause the death of 50% of a defined animal population. 

LD50 means the single dose of a substance that, when administered by a defined route in an animal assay, is expected to cause the death of 50% of 

a defined animal population. 

Threshold Limit Value: The ACGIH recommended general limit for Welding Fume NOS - (Not Otherwise Specified) is 5 mg/m 3 . 

The TLV-TWA is the time-weighted average concentration for a normal 8-hour workday and a 40 hour workweek, to which nearly all workers may be 

repeatedly exposed, day after day, without adverse effect. See Section VII for specific fume constituents which may modify this TLV. Threshold Limit 

Values are figures published by the American Conference of Government Industrial Hygienists. 

Effects of Overexposure: Electric arc welding may create one or more of the following health hazards: 

Fumes and Gases can be dangerous to your health. Common entry is by inhalation. Other possible routes are skin contact and ingestion. 

Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or irritation of 

nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema). 

Long-term (chronic) overexposure to welding fumes may affect pulmonary function. Bronchitis and some lung fibrosis have been 

reported. Chromates may cause ulceration and perforation of the nasal septum. Liver damage and allergic reactions, including skin 

rash, have been reported. Chromates contain the hexavalent form of chromium. Hexavalent chromium and its compounds are on the 

IARC (International Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a cancer risk to humans. 

Arc Rays can injure eyes and burn skin. Skin cancer has been reported. 

Electric Shock can kill. If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such as 

sitting, kneeling or lying, or if there is a high risk of unavoidable or accidental contact with workpiece, use the following equipment: Semiautomatic DC 

Welder, DC Manual (Stick) Welder, or AC Welder with Reduced Voltage Control. 

Section VII - Reactivity Data 

Hazardous Decomposition Products: Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon 

the metal being welded, the process, procedure and electrodes used. 

Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal 

being welded (such as paint, plating, or galvanizing), the number of welders and the volume of the worker area, the quality and amount of ventilation, the 

position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon 

vapors from cleaning and degreasing activities.) 

When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in 

Section III. Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the materials shown in 

Section III, plus those from the base metal and coating, etc., as noted above. 

Reasonably expected fume constituents of this product would include: Primarily aluminum oxide; secondarily magnesium oxide (for 5356, 5087, 

5183, 5554, 5556, 5754) and complex oxides of silicon (for 4043 and 4047). 

Maximum fume exposure guideline and PEL for this product is 5.0 milligrams per cubic meter. 

Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. 

Determine the composition and quantity of fumes and gases to which workers are exposed by taking an air sample from inside the welder's helmet if worn or 

in the worker's breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1, F1.2, F1.3 and F1.5, available from the 

American Welding Society, 550 N.W. LeJeune Road, Miami, FL 33126. 

Section VIII - Preventive Measures and Precautions for Safe Handling and Use 

Read and understand the manufacturer's instruction and the precautionary label on the product. Request Lincoln Safety Publication E205. See Canadian 

Standards Association Standard CSA-W117.2 "Safety in Welding, Cutting, and Allied Processes" published by the Canadian Standards Association, 178 

Rexdale Blvd., Rexdale, Ontario M9W1R3 for more details on many of the following: 

Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases from the worker's breathing zone and the general area. 

Train the welder to keep his head out of the fumes. Keep exposure as low as possible. 

Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or general work area when local exhaust 

or ventilation does not keep exposure below TLV. 

Eye Protection: Wear helmet or use face shield with filter lens shade number 12 or darker. Shield others by providing screens and flash goggles. 

Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See W117.2. 

At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark 

substantial clothing. Train the welder not to permit electrically live parts or electrodes to contact skin or clothing or gloves if they are wet. Insulate from work 

and ground. 

Disposal Information: Discard any product, residue, disposable container, or liner as ordinary waste in an environmentally acceptable manner according to 

Federal, State and Local regulations unless otherwise noted. No applicable ecological information available. 

Section IX - Emergency and First Aid Procedures 

Call for medical aid. Employ first aid techniques recommended by the Canadian Red Cross. IF BREATHING IS DIFFICULT give oxygen. IF NOT 

BREATHING employ CPR (Cardiopulmonary Resuscitation) techniques. IN CASE OF ELECTRICAL SHOCK, turn off power and follow recommended 

treatment. In all cases call a physician.

Synkool 1200 

Synthetic coolant 

1-5 Monoethanolami 3-5 2050 mg/kg 1000 mg/kg 

10-30 * 6 8 

Vapor density

SLIGHT Allow victim to rest in a well-ventilated area. Seek immediate medical attention 

HAZARDOUS INHALATION: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing. If breathing is difficult, administer 

oxygen. If victim is not breathing, perform mouth-to-mouth resuscitation. 

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, 

keeping eyelids open. Finish by rinsing thoroughly with running water to avoid possible infection 

material 

have conscious person drink several glasses of water or milk, INDUCE VOMITING. 

Ensure eyewash station is proximal to work station. 


CORROSIVITY Slightly corrosive to corrosive in presence of aluminum, zinc and copper. 

Not a TDG controlled 

REACTIVITY: Slightly reactive with oxidizing agents, acids. Slightly reactive with reducing agents, organic 

materials, metals. 

9


_____________________I. PRODUCT IDENTIFICATION_________________ 

TRADE NAME (as labeled) (SRT) Synthetic Resinoid Technology 

MANUFACTURER’S NAME: Pearl Abrasive Company 

Address (complete mailing address) 6210 South Garfield Avenue 

Commerce, CA 90040 

Phone number for additional Information: (562) 927-5561 

Date prepared or revised: January 1, 2011 

_____________________II. HAZARDOUS INGREDIENTS_____________________ 

Chemical Names CAS Numbers Percent* Exposure limits in air (give units) 

ACGIH TLV OSHA PEL OTHER (SPECIFY) 

Aluminum Base Abrasive 76-1 10mg/m3 11mg/m3 ______________ 

Al2O3 1344-28-1 

ZrO2 1314-23-4 

TiO2 13463-67-7 

Fe2O3 1309-37-1 

SiO2 65997-17-3 

Na2O 

Na3AlF6 15096-52-3 

Resin (Phenolic) 9003-34-3 18-1 NAIF NAIF ______________ 

Glass Fiber Reinforcement 65997-17-3 3-1 10mg/m3 NAIF ______________ 

Others 3-1 

It should be noted that use of this product generates dust, particles and fumes both from this product and from the material being 

worked on. Safety precautions for this product and for the product being worked on should be reviewed and used. 

_________________________III. PHYSICAL PROPERTIES____________________ 

Physical State: Solid with no votality and sublimation. 

Boiling point of range, ºF N.A. 

Vapor Pressure, mmHg at 20ºC kPa (20ºC) 

Decomposition Point: 300ºC or over (hardened phenol resin product) 

pH and its levels: Solid, not applicable 

Density: 2.08 g/cm 3 

Appearance and Odor Colored molded (yellow-brown, black-brown) solid with a slight resin 

color. 

Alkali Resistance: Strength degradation is accelerated by alkaline grinding fluid.

HOW TO DETECT THIS SUBSTANCE* (warming properties of substance as a gas, vapor, Dust, or mist) 

Product may give off a phenolic odor during use. 

* Note a required category 

NOTE: all required categories should be addressed. If any item is not applicable, or no information is 

available, the space must be marked to indicate that. 

This voluntary form is provided by CAL/OSHA to assist MSDS preparers and users. Any format may be 

used as long as it contains all the information. 

NAIF – NO APPLICABLE INFORMATION FOUND 

N.A. – NOT APPLICABLE 

_______________________________IV. FIRE AND EXPLOSION_________________________ 

Flash Point: Flame resistant 

Ignition Point: No spontaneous ignition 

Flammable limits in air, volume % lower level (LEL) N.A. Upper Level (UEL) N.A. 

Fire extinguishing materials: 

xx water spray xx carbon dioxide other 

xx foam xx dry chemical 

Specific firefighting procedures: Wear respiratory protectors. 

Unusual fire and explosion hazards: Gases generated under heating contain hazardous substances. 

__________________________V. HEALTH HAZARD INFO.___________________ 

ROUTES OF EXPOSURE: Mineral dust produced during the grinding process. 

Health Effect: Prolonged absorption of dust generated during grinding operations may 

induce pneumoconiosis. 

Safety Effect: Sparks generated during grinder use may cause burn and fire. 

Possible Emergency Overview: Injury or death accidents due to direct attached on the human body of 

Broken and scattered grinding wheel fragments. 

Physical and Chemical Hazards: Grinding wheel fragments broken and scattered around grinding 

operations. If they stride the human body, it may cause serious injury 

or death. 

_____________________________________________________________________________________ 


Acute: During use (grinding) coughing and shortness of breath may occur. May cause irritation to eyes. 

Chronic: Repeated use (grinding) may affect breathing capacity. 

______________________________________________________________________________________

FIRST AID: EMERGENCY PROCEDURES 

Eye Contact: If dust enters the eyes, wash the eyes immediately with clean running water. Do not 

press hard nor rub them. Get medical treatment if necessary. 

Skin Contact: Flush with soapsuds etc. after the end of operations. 

Inhalation: In the case of dust inhalation, remove the victim immediately to a place of fresh air. 

Gargle (wash) with water. Get medical treatment if necessary. 

Ingestion: Give large amounts of moisture and induce vomiting. Get medical treatment if 

necessary. 

______________________________________________________________________________________ 

SUSPECTED CANCER AGENT? 

NO xx This product’s Ingredients are not found in the lists below. 

YES: _______Federal OSHA ________NTP ___________IARC 

California employers using Cal/OSHA-registered carcinogens must register with Cal/OSHA. The 

Cal/OSHA and Federal OSHA carcinogen lists are similar. 

EXPOSURE CONTROLS: 

Allowable Levels: Class 2 dust, inhalable dust – 1mg/m 3 

Total dust = 4 mg/m 3 

Control Levels: 2.9 mg/m 3 (as mineral dust) 

_________________________VI. REACTIVITY DATA________________________ 

Stability: xx stable unstable 

Incompatibility (materials to avoid): None 

Possible Environment Effect: Grinding wastes (including dust & mist) are discharged in 

trace amounts during cutting, grinding, etc. 

Hazardous decomposition products: N.A. 

Hazardous Polymerization: May occur xx Will not occur 

Conditions to avoid: High temperature, high humidity. 

______________VII. SPILL, LEAK AND DISPOSAL PROCEDURES___________ 

Spill response procedures (include employee protection measures): 

Use cleanup procedure to prevent spreading of dust. 

Preparing wastes for disposal (container types, neutralization, etc.) 

Disposal of waste in a manner consistent with applicable federal, state and local laws. 

NOTE: Byproducts of use need to be disposed of lawfully. 

NOTE: Dispose of all waste in accordance with the federal, state and local regulations

_________________VIII. SPECIAL HANDLING INFORMATION______________ 

Installation Measures: As dust-proof measures, install dust collectors or arrange 

general exhaust if necessary. Dust collectors may generate 

and absorb sparks directly. 

Respiratory protectors: Dust masks passing national tests. 

Protective goggles: Complete protection type dust goggles. 

Protective gloves: Spark proof gloves. 

Protective clothes: Work clothes of spark-proof materials. 

Others: Soundproof ear plugs, helmets, safety shoes, etc. 

Transportation information: Take care to avoid water soaking and packing case damage. 

Place in boxes resistant to some degrees of pressure and 

shock. Avoid rough handling to prevent grinding wheel from 

breakage. Transport free from turnover, fall, other impact, etc. 

___________________IX. REGULATORY INFORMATION____________________ 

Industrial Safety and Health Law, Industrial Safety and Health Law Regulation 

Industrial Safety and Health Law, Industrial Safety and Health Law Enforcement Ordinance 

Industrial Safety and Health Law, Specific Chemical Substance Injury Prevention Regulation 

Industrial Safety and Health Law, Lead Poisoning Prevention Regulation 

Dust Injury Prevention Regulation 

Safety and Hygiene Special Education Regulation 

Grinding Machine etc. Structure Standards 

Fire Service Law 

_________________________X. OTHER INFORMATION_____________________ 

References: Nippon Resibon Corporation, Production HQ 

Technology Department, Technology Section 

Telephone: 81-577-73-3316 (key) 

Facsimile: 81-577-73-5704 (key) 

Of the descriptions, figures for contents, physical and chemical properties, etc. are no guaranteed figures. 

While hazards and harmfulness assessment has been prepared based on materials, information data, etc. 

available as of the date hereof, all materials have not been covered. Sufficient caution is recommended for 

handling. 

______________________________________________________________________________________


Page 1 of 6 

Date of Issue: June 2008 

Section 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER 

Product Name: TALON RODENTICIDE PELLETS 

Other Names: Product code: A10976C 

Recommended Use: Rodenticide 

Company Details: Syngenta Crop Protection Pty Limited 

ABN 33 002 933 717 

Address: Level 1, 2-4 Lyonpark Road 

MCQUARIE PARK NSW 2113 

AUSTRALIA 

Telephone Number: (02) 8876 8444 

Emergency Telephone Number: 24 hours - 1800 033 111 

Section 2: HAZARDS IDENTIFICATION 

Hazard Classification: Not classified as hazardous according to the criteria of NOHSC 

Risk Phrases: None Allocated. 

Safety Phrases: -- 

SUBSTANCE 

Section 3: COMPOSITION / INFORMATION ON INGREDIENTS 

Chemical Identity of Pure Substance: Brodifacoum 

Synonym: PP581 

CAS Number: 56073-10-0 

MIXTURE 

Chemical Identity of Ingredients CAS No Proportion 

(% w/w) 

Brodifacoum 

56073-10-0 0.005 

Other ingredients determined not to be hazardous 

-- 

To 100

Syngenta Crop Protection Pty Ltd Page 2 of 6 

TALON Rodenticide Pellets June 2008 

Description of Necessary 

First Aid Measures: 


If poisoning occurs, contact a doctor or Poisons Information Centre. 

Phone Australia 131 126. Vitamin K1 (Phytomenadione) is 

antidotal. 

Swallowed: If swallowed, seek medical advice immediately and 

show this container or label. Do not induce vomiting. 

Eye: Rinse immediately with plenty of water, also under the 

eyelids, for at least 15 minutes. Remove contact 

lenses. Immediate medical attention is required. 

Skin: Take off all contaminated clothing immediately. Wash 

off immediately with plenty of water. Wash 

contaminated clothing before re-use. 

Inhaled: Remove to fresh air. Keep patient warm and at rest. If 

breathing is irregular or stopped, administer artificial 

respiration. 

Poisoning Symptoms: Symptoms of poisoning are typical of anticoagulants. In severe 

cases there may be bruising, haematomas of the joints, blood in the 

faeces and urine. An antidote, Vitamin K1 (phytomenadione BP), 

should only be administered under the direction of a doctor who has 

access to a hospital laboratory. Doctors should refer to the leaflet 

'The treatment of Anticoagulant Rodenticide Poisoning. Advice to 

Physicians', available in an emergency by contacting 1800 033 111. 

Medical Advice: NOTE TO PHYSICIANS AND VETERINARIANS 

Brodifacoum, the active constituent of TALON Rodenticide Pellets, 

is a long lasting anticoagulant chemical, which if ingested by 

humans, domestic animals or pets, can reduce the clotting power of 

the blood and haemorrhage may result. Vitamin K1 

(Phytomenadione) should be administered urgently by medical, 

appropriate para-medical personnel or veterinarians. If 

administered intravenously the injection must be given slowly. 

Section 5: FIRE FIGHTING MEASURES 

Suitable Extinguishing Media: Extinguishing media - small fires 

Use water spray, alcohol-resistant foam, dry chemical or 

carbon dioxide extinguisher. DO NOT use direct jet of water. 

Extinguishing media - large fires 

Use alcohol-resistant foam or water spray. DO NOT use 

direct jet of water. 

Hazards from Combustion 

Products: 

Special Protective Precautions 

and Equipment for Fire Fighters: 

As the product contains combustible organic components, 

fire will produce dense black smoke containing hazardous 

products of combustion which may be toxic and irritant. 

When fighting a major fire wear self-contained breathing 

apparatus and protective clothing.



Emergency Procedures: 

Methods and Materials for 

Containment and Clean Up: 

Section 6: ACCIDENTIAL RELEASE MEASURES 

In case of spillage it is important to take all steps necessary to 

Avoid eye and skin contact. 

Avoid contamination of waterways 

1) Keep all bystanders away. 

2) Wear full-length clothing and PVC gloves. 

3) Reposition any leaking containers so as to minimise further 

leakage. 

4) For a product spill: Sweep powder concentrate into a pile. 

5) For a prepared spray spill: Dam and absorb spill with an 

absorbent material (e.g. sand or soil) 

6) Shovel the absorbed material or powder concentrate into 

drums. 

7) Decontaminate the spill area with detergent and water and 

rinse with water. 


Precautions for Safe Handling: Poisonous if swallowed. Do not inhale dust. Do not touch bait 

- use scoop or measure. If on skin and after each baiting, 

wash thoroughly with soap and water. 

Conditions for Safe Storage: Containers which have held bait should not be used for any 

other purpose. Store in the closed original container in a dry, 

cool, well ventilated area out of direct sunlight. Keep out of the 

reach of children and pets. 

Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 

ALWAYS READ AND FOLLOW THE LABEL INSTRUCTIONS AND WARNINGS 

National Exposure Standards: No official exposure standards have been set for any 

ingredients of this product. 

Syngenta Exposure Standards: Brodifacoum 8 hr TWA 0.002 mg/m³ 

Biological Limit Values: No biological limit allocated. 

Engineering Controls: No special controls needed. 

Personal Protective Equipment: Only use protective equipment bearing the mark of the 

Standards Association of Australia.




Appearance: Emerald Green Pellets Boiling Point/Range: Not applicable 

Odour: No odour Melting Point: Not available 

pH: Not applicable Solubility in water Not soluble 

Vapour Pressure: Not available Specific Gravity or 

Density: 

0.6 - 0.7 g/cm 3 

Flash point: Does not flash Explosive properties: Not explosive 

Upper and Lower 

Flammable (Explosive) 

Limits in Air: 

Not highly flammable Oxidising properties: Not oxidising 

Combustibility: Combustible C2 

Ignition Temperature: Not available Corrosiveness: Not corrosive 


Chemical Stability: Stable under standard conditions. 

Conditions to Avoid: None known. 

Incompatible Materials: None known. 

Hazardous Decomposition 

Products 

Hazardous Reactions: None known. 

Combustion or thermal decomposition will evolve smoke. 

Section 11: TOXICOLOGICAL INFORMATION 

Health Effects from Likely Routes of Exposure: 

Acute: Swallowing: LOW TOXICITY 

LD 50 > 5,000 mg/kg Derived from components 

Chronic 

: 

Skin contact: LOW TOXICITY 

Tests on rabbits indicate this product is NOT HARMFUL following skin 

contact LD50 > 2,000 mg/kg 

NOT IRRITANT (rabbit) 

NOT A SKIN SENSITISER 

Eye contact: SLIGHT IRRITANT (rabbit) 

Inhalation: Inhalation is not a likely route of exposure. 

No long term risks to man are associated with this material when handled and used as 

directed on the label. Brodifacoum, the active ingredient of Talon, did not show 

carcinogenic, teratogenic or mutagenic effects effects in animal experiments.



Section 12: ECOLOGICAL INFORMATION 

Ecotoxicity: Practically non toxic to fish LC50 Rainbow trout, >1,000 mg/l , 96 h, Derived 

from components. 

Persistence and 

Degradability: 

Practically non toxic to algae EC50 (72 h) Scenedesmus subspicatus 

>1,000 mg/mL 

Practically non toxic to aquatic invertebrates EC50 = >1,000 mg/l (Daphnia 

magna (water flea)) 

Practically non-toxic to soil dwelling organisms LC50 (14 d) = >1,000 

mg/kg soil (Eisenia foetida) 

Practically non-toxic to bees 

Brodifacoum is practically insoluble in water, but is persistant in water. Slow 

degradation in soil. 

Mobility Brodifacoum has low mobility in soil. 

Environmental 

Fate (Exposure): 

Bioaccumulative 

Potential: 

Incorporated into organic molecules. 

Brodifacoum has low potential for bioaccumulation. 


Disposal Methods and Containers: Dispose of empty containers and unused or untaken baits 

by burying in an approved dump. 

Special Precautions for Landfill or 

Incineration: 



LAND TRANSPORT Not a dangerous good 

ADG 

UN Number: None allocated Packing Group: None allocated 

UN Proper Shipping 

Name: 

None allocated Special Precautions 

for User: 

None allocated 

Class: None allocated Hazchem Code: None allocated 

Subsidiary Risk: None allocated



SEA TRANSPORT Not a dangerous good 

IMDG 



Name: 


for User: 



Subsidiary Risk: 

AIR TRANSPORT Not a dangerous good 

IATA-DGR 



Name: 


for User: 



Subsidiary Risk: None allocated 

APVMA Product Number: 33896 

Poisons Schedule (SUSDP): 6 



Date of preparation or last revision: June 2008 

Source of Data: The information provided in this SDS is sourced from Syngenta internal studies 

which have been conducted according to Regulatory requirements including OECD and CIPAC 

Guidelines and EC Directives. A comprehensive package of toxicological and environmental data 

for the active ingredients of this product has been submitted to the government health and 

environment authorities and has been evaluated by expert toxicologists and environmental 

scientists. 

Note: This product is a registered agricultural chemical and must, therefore, be used in 

accordance with the container label directions 

CONTACT POINT: Regulatory Affairs Manager, Syngenta Crop Protection Pty Limited 

(02) 8876 8444 

24 HOURS EMERGENCY CONTACT: 1800 033 111 

This Material Safety Data Sheet summarises our best knowledge of the health and safety hazard information of 

the product and how to safely handle and use the product in the workplace. Each user should read this SDS 

and consider the information in the context of how the product will be handled and used in the workplace 

including in conjunction with other products. 

If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the 

user should contact this company. 

® Registered trademark of a Syngenta Group Company

No Change May 2011

No Change May 2011


MSDS NO: 415889 

REVISED: April 30, 2009 

TW 3575 

For U.S. Manufactured or Distributed Welding Consumables and Related Products. May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200 and Superfund 

Amendments and Reauthorization Act (SARA) of 1986 Public Law 99-499. Standard must be consulted for specific requirements. 

SECTION 1 IDENTIFICATION 

Manufacturer/Supplier Name: HOBART BROTHERS COMPANY Telephone No: (937) 332-4000 

Address: 101 TRADE SQUARE EAST, TROY, OH 45373 Emergency No: (800) 424-9300 

Website: www.hobartbrothers.com 

Product Type: TUBULAR ARC WELDING ELECTRODES FOR FLUX CORED, METAL CORED AND COMPOSITE SUBMERGED ARC WELDING 

GROUP A: Product For: Gas Shielded Carbon and Low Alloy Steel 

Trade Name: EXCEL-ARC 71; FABCO 80D2, 82HD, 85, 90, 825, E70T-1C, E70T-9C H8, HORNET, RXR, RXR-XLS, TR70, XL-71; FABCOR 80XLS, 86R, 96, 702; FABDUAL T9M, T91M; FLUX- 

COR 2, 3, 7,9XT, 37, 80A1, 90D3; GALVACOR; GALVALLOY; METAL-COR 3, 3S, 6, 6L, 8, 80D2, EH14S, EL12KS, EM12KS, EN-VISION; METALLOY 70, 70R, 70X, 71,76, 80D2, 

A1S, A3S, CO2, EH14S, EL12KS, EM12KS, EM13KS, X-CEL; PIPEMASTER MC70; SPEED-ALLOY 70, 71, 71A, 71A1, 71-V, 719, 75, 95D2, 105D2; SPEED-COR 6; SUPER-COR; 

SUPER TUF-COR; TM-11, 22, 37, 55, 71 XTR, 72, 73, 75A1, 81A1, 91D3, 95D2, 105D2, 711M, 791, 811A1, RX7; TRIPLE-7, 8; TUF-COR 1, 5, 75A1, 95D2, 105D2; 

VERSATILE; VERTI-COR I, II, III, 71, 81A1 

GROUP B: Product For: Self-Shielded Carbon Steel 

Trade Name: FABSHIELD 4, 21B, 23, 31, 55, 120C, 7027, HSR; SELF-SHIELD 3, 4, 7, 11, 11GS; SPEED-SHIELD 11, GS; TM- 33R, 44, 77, 121, 123, 133 

GROUP C: Product For: Carbon and Low Alloy Steel 

Trade Name: DURASHIELD 8-11; EDGE; FABCO 81K2-C, 83, 91, 91K2-C, 107G, 110, 110K3-M, 115, 803, HICOR, XTREME 120, B2, B3; FABCOR 209, 1100; FABSHIELD 3Ni1, 71K6, 

81N1, 81N2, 811K6, 7018, OFFSHORE 71Ni, XLNT-6, XLR-8, X80; FLUX-COR 80B2, 80Ni1, 80Ni2, 80W, 90B3, 90K2, 90Ni2, 100K3, 110K3; FORMULA XL8Ni1, XL8Ni1-C, 

XL525, XL550, GD5; HOBART CBC-1; MATRIX; MEGAZORD; METAL-COR 80B2, 80Ni1, 80Ni2, 80Ni3, 90, 90B3, 100, 110, B2S, B3S, F2S, MAXIM, N1S, N2S, N3S, N4S, WS; 

METALLOY 80B2, 80N1, 80N2, 80N3, 80W, 90, 90B3, 100, 100G, 110, 120S, B2S, B3S, F2S, N1S, N2S, N3S, N4S, VANTAGE, VANTAGE CVN, VANTAGE D2, VANTAGE Ni1, 

WS; PREMIER 70; PW-201; PIPEMASTER F100-K2, F101-K2, F110-N1, F71, FS71-K6, FS71Ni1, FS 81-Ni2, MC90, MC100; SELF-SHIELD 8; SPEED-ALLOY 71-VC, 81B2L-V, 

81Ni1-V, 81Ni2-V, 81W, 81W-V, 85, 85C1, 85C2, 85C3, 91B3, 91B3L, 91B3L-V, 91B3-V, 91-V, 92S, 95, 100F3-S, 111-V, 112-S, 115, 125, 712, 712M, 790, 4130-V; TM- 

78K6, 81B2, 81N1, 81N2, 81W, 85B2L, 85N1, 85N2, 85N3, 91B3, 91B3L, 91K2, 91N2, 95K2, 95M-B3, 101K3, 105K3, 111K3, 115, 125K4, 770, 771, 71HYN, 772, 811B2, 

811N1, 811N2, 811N3, 811W, 880, 881K2, 910, 911B3, 911N2, 991K2, 101, 101K3-C, 1101K3-M, 4130; TUF-COR 85B2L, 85Ni1, 85Ni2, 85Ni3, 95B3, 95K2, 105K3, 115, 

125K4; VERTI-COR 70, 72, 81B2, 81Ni1, 81Ni2, 81W, 91B3, 91K2, 91Ni2, 110K3-M, 1101K3-C, IINi1 

GROUP D: Product For: Corrosion Resisting Steel 

Trade Name: ARC STAR 409; FABCOR 409; FABLOY 409, 409T, 439; FABTUF 250, 960; METAL-COR 409, 409Cb, 439; METALLOY 18CrCb, 409, 409Cb, MCW430NbL, 439; POWERCORE 

91; RSC-409; SPEED-ALLOY 5055; TM B6, B9 


IMPORTANT - This section covers the hazardous materials from which this product is manufactured. The fumes and gases produced during welding with normal use of this product are also addressed 

in Section 5. The term "hazardous" in this section should be interpreted as a term required and defined in OSHA Hazard Communication Standard (29 CFR Part 1910.1200). 

GROUP - % WEIGHT EXPOSURE LIMIT (mg/m 3 ) 

HAZARDOUS INGREDIENTS A B C D CAS NO. OSHA PEL ACGIH TLV 

IRON+ 75-98 75-95 75-95 75-95 7439-89-6 5 R* 5 R* (Fe2O3) {A4} 

IRON OXIDE --- ---

71Ni, XLNT-6; SELF-SHIELD 8 (12) Present only in MATRIX; METAL-COR MAXIM; METALLOY VANTAGE, VANTAGE CVN, VANTAGE D2, VANTAGE Ni1 R* - Respirable Fraction I* - Inhalable Fraction 

** - Ceiling Limit *** - Short Term Exposure Limit + - As a nuisance particulate covered under "Particulates Not Otherwise Regulated" by OSHA or "Particulates Not Otherwise Classified" by ACGIH 

++ - Crystalline silica is bound within the product as it exists in the package. However, research indicates silica is present in welding fume in the amorphous (noncrystalline) form # - Reportable 

material under Section 313 of SARA ### - Reportable material under Section 313 of SARA as dust or fume {A1} - Confirmed Human Carcinogen per ACGIH {A2} - Suspected Human Carcinogen per 

ACGIH {A3} - Confirmed Animal Carcinogen with Unknown Relevance to Humans per ACGIH {A4} - Not Classifiable as a Human Carcinogen per ACGIH {A5} - Not Suspected as a Human Carcinogen 

per ACGIH (noncrystalline) form - Listed under ACGIH Notice of Intended Changes for Mn in 2009 - Limit of 0.02 mg/m 3 is proposed for Respirable Mn in 2010 by ACGIH - NIOSH 

Recommended Exposure Limit (REL) TWA and STEL 

The exposure limit for welding fume has been established at 5 mg/m 3 with OSHA's PEL. The individual complex compounds within the fume may have lower exposure limits than the general 

welding fume PEL. An Industrial Hygienist, the OSHA Permissible Exposure Limits for Air Contaminants (29 CFR 1910.1000), and the ACGIH Threshold Limit Values should be consulted to 

determine the specific fume constituents present and their respective exposure limits. 

SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS 

Welding consumables applicable to this sheet are solid and nonvolatile as shipped. 

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA 

Welding consumables applicable to this sheet as shipped are nonreactive, nonflammable, nonexplosive and essentially nonhazardous until welded. Welding arcs and sparks can ignite combustibles 

and flammable products. See American National Standard Z49.1 referenced in Section 7. 

SECTION 5 - REACTIVITY DATA - HAZARDOUS DECOMPOSITION/INDUSTRIAL HYGIENE INFORMATION 

Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedures and electrodes used. Most fume 

ingredients are present as complex oxides and compounds and not as pure metals. 

Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating or 

galvanizing), the number of welders and the volume of the work area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence 

of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). When the electrode is consumed, the fume and gas decomposition products 

generated are different in percent and form from the ingredients listed in Section 2. Decomposition products of normal operation include those originating from the volatilization, reaction or 

oxidation of the materials shown in Section 2, plus those from the base metal and coating, etc., as noted above. Reasonably expected constituents of the fume would include: Complex oxides of iron, 

manganese, silicon and titanium. Groups A and B may also contain calcium oxides. Groups A, B and C may have fluorides present. Groups A, C, and D may also contain molybdenum. Groups A, B, 

and C may also contain aluminum. Groups B and C may also contain barium. Groups A and C may also contain copper. Groups C and D may also contain chromium and nickel. Group B may also 

contain magnesium, lithium and strontium. Group C may also contain cobalt. Group C may also contain antimony trioxide. 

Monitor for the materials identified in Section 2. Fumes from the use of this product may contain: manganese, fluorspar or fluorides, barium, chromium and nickel compounds, calcium oxide, 

copper, silica, amorphous silica fume, lithium, strontium, cobalt and antimony trioxide whose exposure limits are lower than the 5 mg/m 3 PEL for general welding fume. Gaseous reaction 

products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. One recommended way to determine the composition and 

quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder's helmet if worn or in the worker's breathing zone. [See ANSI/AWS F1.1, available from the 

"American Welding Society", P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3 "Evaluating Contaminants in the Welding Environment - A Sampling Strategy Guide", which gives additional 

advice on sampling.] 

SECTION 6 - HEALTH HAZARD DATA 


Electric arc welding may create one or more of the following health hazards: 

ARC RAYS can injure eyes and burn skin. 

ELECTRIC SHOCK can kill. See Section 7. 

FUMES AND GASES can be dangerous to your health. 

PRIMARY ROUTES OF ENTRY are the respiratory system, eyes and/or skin. 

SHORT-TERM (ACUTE) OVEREXPOSURE EFFECTS: 

Welding Fumes - May result in discomfort such as dizziness, nausea or dryness or irritation of nose, throat or eyes. Iron, Iron Oxide - None are known. Treat as nuisance dust or fume. Manganese - 

Metal fume fever characterized by chills, fever, upset stomach, vomiting, irritation of the throat and aching of body. Recovery is generally complete within 48 hours of the overexposure. Titanium 

Dioxide - Irritation of respiratory system. Silica (Amorphous) - Dust and fumes may cause irritation of the respiratory system, skin and eyes. Fluorides - Fluoride compounds evolved may cause skin 

and eye burns, pulmonary edema and bronchitis. Molybdenum, Cerium Oxide - Irritation of the eyes, nose and throat. Calcium Oxide - Dust or fumes may cause irritation of the respiratory system, 

skin and eyes. Aluminum Oxide - Irritation of the respiratory system. Magnesium, Magnesium Oxide - Overexposure to the oxide may cause metal fume fever characterized by metallic taste, 

tightness of chest and fever. Symptoms may last 24 to 48 hours following overexposure. Barium - Aching eyes, rhinitis, frontal headache, wheezing, laryngeal spasms, salivation or anorexia. Nickel, 

Nickel Compounds - Metallic taste, nausea, tightness in chest, metal fume fever, allergic reaction. Chromium - Inhalation of fume with chromium (VI) compounds can cause irritation of the 

respiratory tract, lung damage and asthma-like symptoms. Swallowing chromium (VI) salts can cause severe injury or death. Dust on skin can form ulcers. Eyes may be burned by chromium (VI) 

compounds. Allergic reactions may occur in some people. Copper - Metal fume fever characterized by metallic taste, tightness of chest and fever. Symptoms may last 24 to 48 hours following 

overexposure. Strontium Compounds - Strontium salts are generally non-toxic and are normally present in the human body. In large oral doses, they may cause gastrointestinal disorders, vomiting 

and diarrhea. Lithium Compounds - Overexposure may cause tremor and nausea. Cobalt - Pulmonary irritation, cough, dermatitis, weight loss. Antimony Compounds - Irritation of nose, throat, 

eyes and skin. 

LONG-TERM (CHRONIC) OVEREXPOSURE EFFECTS: 

Welding Fumes - Excess levels may cause bronchial asthma, lung fibrosis, pneumoconiosis or "siderosis." Iron, Iron Oxide Fumes - Can cause siderosis (deposits of iron in lungs) which some 

researchers believe may affect pulmonary function. Lungs will clear in time when exposure to iron and its compounds ceases. Iron and magnetite (Fe3O4) are not regarded as fibrogenic materials. 

Manganese - Long-term overexposure to manganese compounds may affect the central nervous system. Symptoms may be similar to Parkinson's disease and can include slowness, changes in 

handwriting, gait impairment, muscle spasms and cramps and less commonly, tremor and behavioral changes. Employees who are overexposed to manganese compounds should be seen by a 

physician for early detection of neurologic problems. Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central nervous 

system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. Titanium Dioxide - Pulmonary irritation 

and slight fibrosis. Silica (Amorphous) - Research indicates that silica is present in welding fume in the amorphous form. Long term overexposure may cause pneumoconiosis. Noncrystalline forms of 

silica (amorphous silica) are considered to have little fibrotic potential. Fluorides - Serious bone erosion (Osteoporosis) and mottling of teeth. Molybdenum, Cerium Oxide - Prolonged overexposure 

may result in loss of appetite, weight loss, loss of muscle coordination, difficulty in breathing and anemia. Calcium Oxide - Prolonged overexposure may cause ulceration of the skin and perforation of 

the nasal septum, dermatitis and pneumonia. Aluminum Oxide - Pulmonary fibrosis and emphysema. Magnesium, Magnesium Oxide - No adverse long term health effects have been reported in the 

literature. Barium - Long term overexposure to soluble barium compounds may cause nervous disorders and may have deleterious effects on the heart, circulatory system and musculature. Nickel, 

Nickel Compounds - Lung fibrosis or pneumoconiosis. Studies of nickel refinery workers indicated a higher incidence of lung and nasal cancers. Chromium - Ulceration and perforation of nasal 

septum. Respiratory irritation may occur with symptoms resembling asthma. Studies have shown that chromate production workers exposed to hexavalent chromium compounds have an excess of 

lung cancers. Chromium (VI) compounds are more readily absorbed through the skin than chromium (III) compounds. Good practice requires the reduction of employee exposure to chromium (III) 

and (VI) compounds. Copper - Copper poisoning has been reported in the literature from exposure to high levels of copper. Liver damage can occur due to copper accumulating in the liver 

characterized by cell destruction and cirrhosis. High levels of copper may cause anemia and jaundice. High levels of copper may cause central nervous system damage characterized by nerve fiber 

separation and cerebral degeneration. Strontium Compounds - Strontium at high doses is known to concentrate in bone. Major signs of chronic toxicity, which involve the skeleton, have been 

labeled as "strontium rickets". Lithium Compounds - May be considered as potentially teratogenic. Cobalt - Repeated overexposure to cobalt compounds can produce reduced pulmonary function, 

diffuse nodular fibrosis of lungs and respiratory hypersensitivity. Antimony Compounds - Metal fume fever, dermatitis, keratitis, conjunctivitis and ulceration and perforation of the nasal septum. 

Avoid conditions in which fresh hydrogen will react with antimony to form stibine which is extremely toxic. 

415889 April 30, 2009 Page 2 of 3

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing impaired lung functions (asthma-like conditions). Persons with a pacemaker should not go near welding and cutting 

operations until they have consulted their doctor and obtained information from the manufacturer of the device. Respirators are to be worn only after being medically cleared by your companydesignated 

physician. 

EMERGENCY AND FIRST AID PROCEDURES: Call for medical aid. Employ first aid techniques recommended by the American Red Cross. Eyes & Skin: If irritation or flash burns develop after 

exposure, consult a physician. 

CARCINOGENICITY: Chromium VI compounds, nickel compounds and silica (crystalline quartz) are classified as IARC Group 1 and NTP Group K carcinogens. Titanium dioxide compounds, antimony 

trioxide compounds and cobalt compounds are classified as IARC Group 2B carcinogens. Chromium VI compounds, cobalt compounds, nickel compounds, silica (crystalline quartz) and welding fumes 

must be considered as carcinogens under OSHA (29 CFR 1910.1200). 

CALIFORNIA PROPOSITION 65: For Group C and D products: WARNING: This product contains or produces a chemical known to the State of California to cause cancer and birth defects (or other 

reproductive harm). (California Health & Safety Code Section 25249.5 et seq.) For Group A and B products: WARNING: This product, when used for welding or cutting, produces fumes or gases 

which contain chemicals known to the State of California to cause birth defects and, in some cases, cancer. (California Health & Safety Code Section 25249.5 et seq.) 

SECTION 7 - PRECAUTIONS FOR SAFE HANDLING & USE/APPLICABLE CONTROL MEASURES 

Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1; Safety in Welding and Cutting published by the American 

Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29 CFR 1910), U.S. Government Printing Office, Washington, DC 20402 for more detail on any of the following. 

VENTILATION: Use enough ventilation, local exhaust at the arc or both to keep the fumes and gases below PEL/TLVs in the worker's breathing zone and the general area. Train the welder to keep his 

head out of the fumes. 

RESPIRATORY PROTECTION: Use NIOSH approved or equivalent fume respirator or air supplied respirator when welding in confined space or where local exhaust or ventilation does not keep 

exposure below PEL/TLVs. 

EYE PROTECTION: Wear helmet or use face shield with filter lens. As a rule of thumb begin with Shade Number 14. Adjust if needed by selecting the next lighter and/or darker shade number. 

Provide protective screens and flash goggles, if necessary, to shield others. 

PROTECTIVE CLOTHING: Wear hand, head and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1. At a minimum this includes welder's gloves 

and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection as well as dark nonsynthetic clothing. Train the welder not to touch live electrical parts and to insulate 

himself from work and ground. 

PROCEDURE FOR CLEANUP OF SPILLS OR LEAKS: Not applicable 

WASTE DISPOSAL: Prevent waste from contaminating surrounding environment. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full 

compliance with Federal, State and Local regulations. 

SPECIAL PRECAUTIONS (IMPORTANT): Maintain exposure below the PEL/TLVs. Use industrial hygiene monitoring to ensure that your use of this material does not create exposures which exceed 

PEL/TLVs. Always use exhaust ventilation. Refer to the following sources for important additional information: ANSI Z49.1 from the American Welding Society, P.O. Box 351040, Miami, FL 33135 and 

OSHA (29 CFR 1910) from the U.S. Department of Labor, Washington, DC 20210. 

Hobart Brothers Company believes this data to be accurate and to reflect qualified expert opinion regarding current research. However, Hobart Brothers Company cannot make any expressed or 

implied warranty as to this information. 

415889 April 30, 2009 Page 3 of 3

Ultra Lift-Off 

Use: Floor Stripper 

Code: FH441J, P, D 


Flexo Products Limited 4777 Kent Avenue, Niagara Falls, ON L2H 1J5 

Phone: (905) 354-2723 Fax: (905) 354-1301 Web Site: www.flexoproducts.com 

Date of MSDS: February 14, 2011 

WHMIS: D2B, E 

TDG: Not Regulated 

HMIS: Health -2, Flammability - 0, Reactivity – 0, PPE - B 

Emergency Telephone # 

CANUTEC 613-996-6666 

I - HAZARDOUS INGREDIENTS 

Chemical Name Wt/Wt % CAS # LD50 (mg/kg) LC50 

Glycol Carbitol 10-30 112-34-5 3384 oral rat not available 

2-Aminoethanol 10-30 141-43-5 172 oral rat not available 

II - PHYSICAL DATA 

Physical State: liquid Viscosity: 6.0 cps Vapour Pressure: not available 

Oil/Water Factor: not available Appearance: clear colourless pH: 12.5 ± 0.5 

Vapour Density: not available Evaporation Rate: similar Odour: moderate 

Specific Gravity: 1.0 ± 0.04 Boiling Point ( o C): 94 Odour Threshold: not available 

Freezing Point ( o C): < 0 

III - FIRE AND EXPLOSION DATA 

Conditions of Flammability: not available UFL: not available 

Flash Point and Test Method: not applicable LFL: not available 

Sensitivity to Static Discharge or Mechanical Impact: not available Hazardous Combustion Products: not available 

Means of Extinction: chemical foam, carbon dioxide, dry chemical Auto-Ignition Temperature: oxides of carbon 

IV - REACTIVITY DATA 

Conditions of Chemical Instability: stable Conditions of Reactivity: not applicable 

Incompatible Substances: strong oxidizers, acids Hazardous Decomposition Products: not available 

Storage Requirements: store in closed containers away from incompatible materials. 

V - TOXICOLOGICAL PROPERTIES 

Synergistic Materials: not available Route(s) of Entry: skin, eyes, ingestion, inhalation 

Irritancy of Product: high Sensitization: not available 

Acute Effects Chronic Effects 

Eye: contact may cause severe irritation or chemical burns Carcinogen: none known 

Skin: may cause severe irritation or chemical burns Teratogen: none known 

Inhalation: highly irritating to the respiratory system Mutagen: none known 

Ingestion: can cause vomiting, headache & medical problems Reproductive Toxin: none known 

Prolonged or Repeated Exposure: Skin: Can cause drying, defatting & dermatitis. 

VI - FIRST AID MEASURES 

Eye Contact: Immediately flush with water for 15 minutes. If irritation persists, contact a physician. 

Skin Contact: Immediately flush with water for 15 minutes. Contact a physician if irritation develops. 

Completely decontaminate clothing, shoes and leather, or discard. 

Inhalation: Remove to fresh air. If symptoms persist, contact a physician. 

Ingestion: Do not induce vomiting. Rinse mouth with water, then drink one glass of water. Contact a physician 

immediately. Never give anything by mouth if victim is unconscious, is rapidly losing consciousness or is 

convulsing. 

VII - PROTECTIVE EQUIPMENT 

Personal Protective Equipment: Eyes: safety glasses recommended Skin: impermeable gloves recommended 

Respiratory: not normally required if good ventilation is maintained 

Ventilation: general ventilation normally adequate 

VIII - SPECIAL MEASURES 

For Leaks or Spills: Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled 

containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. 

Waste Disposal: Review all Federal, Provincial and local regulations prior to disposal. 

This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the 

accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control. User is responsible to evaluate all 

available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 

FH441


Date of Issue: June 15, 2009 

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION 

Product Name: UNIVERSAL STONE 

Manufacturer: 

ZIELINSKY INDUSTRIES 

50 Barkensweg 

D-26670 Uplenden, 

Germany 

Phone: +49 (0) 4956 / 9188-0 

Fax: +49 (0) 4956 / 91 88-98 

SECTION 2 - PRODUCT DESCRIPTION 

PRODUCT NAME: UNIVERSAL STONE 

GENERAL DESCRIPTION: Surface Cleaner 

CHEMICAL NATURE: Surfactant Blend 

SECTION 3 - PRODUCT COMPOSITION & HAZARDS IDENTIFICATION 

This product contains no hazardous ingredients and is free of PCBs, PCTs, and chlorinated 

organic compounds. 

NFPA HAZARD IDENTIFICATION SYSTEM 


0=Least 

1=Slight HEALTH = 0 

2=Moderate FIRE = 0 

3=High REACTIVITY = 0 

4=Severe EQUIPMENT = 0 

EYES: May Cause Irritation. 

SKIN: No danger. 

INHALATION: No danger. 

INGESTION: No danger. 

SECTION 4 - FIRST AID MEASURES 

GENERAL ADVICE: Product contains no hazardous ingredients. Consult a physician. Show 

this data sheet to the doctor in attendance. 

IN CASE OF EYE CONTACT: Immediately flush with plenty of water for at least 15 minutes. If 

irritation persists have eyes examined and treated by medical personnel. 

IN CASE OF SKIN CONTACT: Irritation uncommon. If irritation occurs remove contaminated 

clothing and footwear. Wash material off the skin with plenty of water. 

IF INHALED: No treatment needed. 

IF SWALLOWED: Drink water to dilute. Do not induce vomiting. Never give anything by mouth 

to an unconscious person. Consult a physician. 

1

SECTION 5 - FIRE AND EXPLOSION DATA 

LOWER FLAMMABILITY LIMITS: (% In Air) Not pertinent 

FLASH POINT: (And Method) Not pertinent 

IGNITION TEMPERATURE Not pertinent 

FLAMMABILITY CLASSIFICATION: Not flammable 

UNUSUAL FIRE/EXPLOSION HAZARDS: In case of fire, product may form soot. 

RECOMMENDED EXTINGUISHING MEDIA: Water spray, Foam with water 

SPECIAL FIRE FIGHTING PROCEDURES: None known 

SECTION 6 - ACCIDENTAL RELEASE MEASURES 

PERSONAL PRECAUTIONS: No special measures necessary. 

ENVIRONMENTAL PRECAUTIONS: Biodegradable. No special measures necessary. 

WASTE DISPOSAL PROCEDURES: Dispose of this product or its residues in accordance with 

all local, state and federal requirements. 

SECTION 7 - HANDLING AND STORAGE 

HANDLING: No special measures necessary. 

STORAGE: No special measures necessary. 

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION 

No components with workplace control parameters. No special measures necessary. 

APPEARANCE 

FORM: Solid at room temperature. 

COLOR: White 

ODOR: Soapy 

PHYSICAL DATA 

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 

MELTING POINT: Not determined 

BOILING POINT: 100 C 

FLASH POINT: 200 C 

POINT OF IGNITION: Not determined 

DENSITY --- 

VAPOR PRESSURE AT 20C: (MM of HG) Not pertinent 

VAPOR DENSITY: (Air = 1) Not pertinent 

SOLUBILITY IN WATER: Miscible 

EVAPORATION RATE: Not determined 

pH: 8.3 

SECTION 10 - REACTIVITY DATA 

STABILITY: Stable under normal conditions 

CONDITIONS TO AVOID: None known 

INCOMPATIBILITY WITH OTHER MATERIALS: None known 

HAZARDOUS DECOMPOSITION MATERIALS: None known 

HAZARDOUS REACTIONS: None known 

HAZARDOUS POLYMERIZATION: Will not occur 

2

SECTION 11 - TOXICOLOGICAL INFORMATION 

The product is non toxic according to the general classification guidelines of the EEC. 

ACUTE TOXICITY: Non-toxic 

EFFECTS OF OVEREXPOSURE: Ingestion: No effect if ingested in small amounts. 

IRRITATION AND CORROSION: No data available 

CHRONIC EXPOSURE: No data available 

OTHER EFFECTS OF OVER EXPOSURE: None known 

SECTION 12 - ECOLOGICAL INFORMATION 

ORGANIC CARBON CONTENT: 104mg carbon/g product 

BIOELIMINATION AND BIODEGRADATION 

METHOD: OECD 302 B with determination of mineralization, EMPA Standard Operating 

Procedure (SOP 720); 4L batch. 

EMPA ASESSMENT: Bioelimination after 14 days of 97% and mineralization after 28 days of 

84%, is therefore easily biodegradable. At 496mg/L the product has not inhibited the action of 

nitrifying bacteria. 

SECTION 13 - DISPOSAL CONSIDERATIONS 

Dispose of this product or its residues in accordance with all local, state and federal requirements. 

No additional precautions. 

SECTION 14 - TRANSPORT INFORMATION 

The product is safe to transport as per EEC regulations. 

SECTION 15 - REGULATORY INFORMATION 

The product contains no harmful ingredients as per EEC regulations. Special labeling not 

required. 

SECTION 16 - OTHER INFORMATION 

The information gathered about the product through experiments is for safety requirements only. 

The information is not a guarantee of product performance nor a warrantee. 

3

Product Name: UNLEADED GASOLINE 

Revision Date: 16Mar2009 

Page 1 of 13 

______________________________________________________________________________________________________________________ 



PRODUCT 

Product Name: (see Section 16 for Synonyms) UNLEADED GASOLINE 

Product Description: Hydrocarbons and Additives 

MSDS Number: 8522 

Intended Use: Fuel 

COMPANY IDENTIFICATION 

Supplier: Imperial Oil Products Division 

240 4th Avenue 

Calgary, ALBERTA. T2P 3M9 Canada 

24 Hour Environmental / Health Emergency 519-339-2145 

Telephone 

Transportation Emergency Phone Number 519-339-2145 

Product Technical Information 1-800-268-3183 

Supplier General Contact 1-800-567-3776 

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS 

Reportable Hazardous Substance(s) or Complex Substance(s) 

Name CAS# Concentration* Acute Toxicity 

GASOLINE 86290-81-5 > 99% None 

METHYL-TERT-BUTYL ETHER 1634-04-4 0 - 15% Dermal Lethality: LD50 > 

10.0 g/kg (Rabbit); Inhalation 

Lethality: LC50 23576 ppm 

(Rat); Oral Lethality: LD50 

4.0 g/kg (Rat) 

Hazardous Constituent(s) Contained in Complex Substance(s) 


BENZENE 71-43-2 0 - 1.5% Dermal Lethality: LD50 > 9.4 

g/kg (Rabbit); Inhalation 



0.93 g/kg (Rat) 

CUMENE 98-82-8 0 - 1% Dermal Lethality: LD50 10.6 





Cyclohexane 110-82-7 0 - 1% Dermal Lethality: LD50 > 18 

g/kg (Rabbit); Oral Lethality: 

12 g/kg (Rat) 

ETHYL BENZENE 100-41-4 0 - 3% Dermal Lethality: LD50 15 





n-Hexane 110-54-3 0 - 3% Dermal Lethality: LD50 

3.295 g/kg (Rabbit); 

Inhalation Lethality: LC50 

97469 ppm (Rat); Oral



Page 2 of 13 

______________________________________________________________________________________________________________________ 

Lethality: LD50 28.7 g/kg 

(Rat) 

Naphthalene 91-20-3 0 - 1% Dermal Lethality: LD50 > 20 


LD50 0.49 g/kg (Rat) 

TOLUENE 108-88-3 0 - 20% Dermal Lethality: LD50 

12.10 g/kg (Rabbit); 

Inhalation Lethality: LC50 

8000 ppm (Rat); Oral 

Lethality: LD50 5.0 g/kg (Rat) 

XYLENES 1330-20-7 0 - 10% Dermal Lethality: LD50 4.5 





* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 

Note: The concentration of the components shown above may vary substantially. In certain countries, benzene content 

may be limited to lower levels. Oxygenates such as tertiary-amyl-methyl ether, ethanol, di-isopropyl ether, and ethyltertiary-butyl 

ether may be present. Because of volatility considerations, gasoline vapor may have concentrations of 

components very different from those of liquid gasoline. The major components of gasoline vapor are: butane, 

isobutane, pentane, and isopentane. The reportable component percentages, shown in the composition/information on 

ingredients section, are based on API's evaluation of a typical gasoline mixture. 


This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). 

PHYSICAL/CHEMICAL EFFECTS 

FLAMMABLE. Material can release vapours that readily form flammable mixtures. Vapour accumulation could 

flash and/or explode if ignited. Material can accumulate static charges which may cause an incendiary 

electrical discharge. 

HEALTH EFFECTS 

May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated 

and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous 

system depression. High-pressure injection under skin may cause serious damage. Prolonged and repeated 

exposure to benzene may cause serious injury to blood forming organs and is associated with anaemia and to 

the later development of acute myelogenous leukaemia (AML). 

Target Organs: Blood and/or blood-forming organs | 

NFPA Hazard ID: Health: 1 Flammability: 3 Reactivity: 0 

HMIS Hazard ID: Health: 1* Flammability: 3 Reactivity: 0 

Note: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. 

Health studies have shown that chemical exposure may cause potential human health risks which may vary from 

person to person. 


INHALATION



Page 3 of 13 

______________________________________________________________________________________________________________________ 

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use 

adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek 

immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use 

mouth-to-mouth resuscitation. 

Skin Contact 

Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing 

before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the 

appearance of the wound or its size, the individual should be evaluated immediately by a physician as a 

surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early 

surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. 

Eye Contact 

Flush thoroughly with water. If irritation occurs, get medical assistance. 

Ingestion 

Seek immediate medical attention. Do not induce vomiting. 

NOTE TO PHYSICIAN 

If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. 

PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE 

Benzene- Individuals with liver disease may be more susceptible to toxic effects. 


EXTINGUISHING MEDIA 

Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish 

flames. 

Inappropriate Extinguishing Media: Straight streams of water 

FIRE FIGHTING 

Fire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the 

vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from 

entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and 

in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed 

surfaces and to protect personnel. 

Unusual Fire Hazards: EXTREMELY FLAMMABLE. Vapour is flammable and heavier than air. Vapour may 

travel across the ground and reach remote ignition sources, causing a flashback fire danger. 

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion 

products, Oxides of carbon 

FLAMMABILITY PROPERTIES 

Flash Point [Method]: -40C (-40F) [ ASTM D-92] 

Flammable Limits (Approximate volume % in air): LEL: 1.4 UEL: 7.6 

Autoignition Temperature: >250°C (482°F) 

SECTION 6 ACCIDENTAL RELEASE MEASURES



Page 4 of 13 

______________________________________________________________________________________________________________________ 

Notification Procedures 

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable 

regulations. 

PROTECTIVE MEASURES 

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if 

required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the 

Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for 

Personal Protective Equipment. 

SPILL MANAGEMENT 

Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if 

you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or 

walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapoursuppressing 

foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. 

Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: 

Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with 

suitable absorbent. 

Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak 

if you can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas 

of fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the 

advice of a specialist before using dispersants. 

Water spill and land spill recommendations are based on the most likely spill scenario for this material; 

however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction 

and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be 

consulted. Note: Local regulations may prescribe or limit action to be taken. 

ENVIRONMENTAL PRECAUTIONS 

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, 

sewers, basements or confined areas. 


HANDLING 

Avoid breathing mists or vapour. Avoid contact with skin. Use non-sparking tools and explosion-proof 

equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not 

siphon by mouth. Use only with adequate ventilation. Use proper bonding and/or earthing procedures. Do not 

use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or 

unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static 

electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact 

with container. Do not use electronic devices (including but not limited to cellular phones, computers, 

calculators, pagers or other electronic devices etc) in or around any fuelling operation or storage area unless 

the devices are certified intrinsically safe by an approved national testing agency and to the safety standards 

required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. 

Material can accumulate static charges which may cause an electrical spark (ignition source). 

Static Accumulator: This material is a static accumulator. 

STORAGE 

Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. Keep container



Page 5 of 13 

______________________________________________________________________________________________________________________ 

closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, 

well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and 

bonded. Drums must be earthed and bonded and equipped with self-closing valves, pressure vacuum bungs 

and flame arresters. 

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 

Substance Name Form Limit/Standard Note Source 

BENZENE STEL 2.5 ppm Skin ACGIH 

BENZENE TWA 0.5 ppm Skin ACGIH 

CUMENE TWA 50 ppm ACGIH 

Cyclohexane TWA 100 ppm ACGIH 

ETHYL BENZENE STEL 125 ppm ACGIH 

ETHYL BENZENE TWA 100 ppm ACGIH 

GASOLINE STEL 200 ppm Supplier 

GASOLINE TWA 100 ppm Supplier 

GASOLINE Vapour. TWA 300 mg/m3 100 ppm Supplier 

METHYL-TERT-BUTYL ETHER TWA 50 ppm ACGIH 

n-Hexane TWA 50 ppm Skin ACGIH 

Naphthalene STEL 15 ppm Skin ACGIH 

Naphthalene TWA 10 ppm Skin ACGIH 

TOLUENE TWA 20 ppm ACGIH 

XYLENES STEL 150 ppm ACGIH 

XYLENES TWA 100 ppm ACGIH 

NOTE: Limits/standards shown for guidance only. Follow applicable regulations. 

ENGINEERING CONTROLS 

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. 

Control measures to consider: 

Use explosion-proof ventilation equipment to stay below exposure limits. 


Personal protective equipment selections vary based on potential exposure conditions such as applications, 

handling practices, concentration and ventilation. Information on the selection of protective equipment for use 

with this material, as provided below, is based upon intended, normal usage. 

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a 

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator 

selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of 

respirators to be considered for this material include: 

Half-face filter respirator 

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. 

Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, 

gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. 

Hand Protection: Any specific glove information provided is based on published literature and glove



Page 6 of 13 

______________________________________________________________________________________________________________________ 

manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. 

Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use 

conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material 

include: 

If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with 

forearms is likely, wear gauntlet-style gloves. 

Eye Protection: If contact is likely, safety glasses with side shields are recommended. 

Skin and Body Protection: Any specific clothing information provided is based on published literature or 

manufacturer data. The types of clothing to be considered for this material include: 

If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. 

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after 

handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective 

equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. 

Practise good housekeeping. 

ENVIRONMENTAL CONTROLS 

See Sections 6, 7, 12, 13. 


Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional 

data. 

GENERAL INFORMATION 

Physical State: Liquid 

Colour: Clear (May Be Dyed) 

Odour: Petroleum/solvent 

Odour Threshold: N/D 

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION 

Relative Density (at 15 C): 0.73 

Flash Point [Method]: -40C (-40F) [ ASTM D-92] 


Autoignition Temperature: >250°C (482°F) 

Boiling Point / Range: 35C (95F) - 210C (410F) 

Vapour Density (Air = 1): 3.2 at 101 kPa 

VAPOUR PRESSURE: > 26.6 kPa (200 mm Hg) at 20°C | 76 kPa (570 mm Hg) at 38 C - 103 kPa (772.5 

mm Hg) at 38C 

Evaporation Rate (N-Butyl Acetate = 1): > 10 

pH: N/A 

Log Pow (n-Octanol/Water Partition Coefficient): > 3 

Solubility in Water: Negligible 

Viscosity:



Page 7 of 13 

______________________________________________________________________________________________________________________ 


STABILITY: Material is stable under normal conditions. 

CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. 

Materials To Avoid: Halogens, Strong Acids, Alkalies, Strong oxidizers 

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. 



Acute Toxicity 

Route of Exposure Conclusion / Remarks 

INHALATION 

Toxicity (Rat): LC50 > 5000 mg/m³ Minimally Toxic. Based on test data for structurally similar 

materials. 

Irritation: No end point data. Elevated temperatures or mechanical action may form vapours, 

mist, or fumes which may be irritating to the eyes, nose, throat, or 

lungs. Based on assessment of the components. 

Ingestion 

Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar 

materials. 

Skin 

Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar 

materials. 

Irritation: No end point data. Mildly irritating to skin with prolonged exposure. Based on test 

data for structurally similar materials. 

Eye 

Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test 


CHRONIC/OTHER EFFECTS 

For the product itself: 

Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon 

vapours in the same boiling range as this product can produce adverse kidney effects in male rats. However, 

these effects were not observed in similar studies with female rats, male and female mice, or in limited studies 

with other animal species. Additionally, in a number of human studies, there was no clinical evidence of such 

effects at normal occupational levels. In 1991, The U.S. EPA determined that the male rat kidney is not useful 

for assessing human risk. Vapour concentrations above recommended exposure levels are irritating to the 

eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other 

central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from 

vomiting may cause chemical pneumonitis or pulmonary edema. 

Contains: 

BENZENE: Caused cancer (leukemia), damage to the blood-producing system, and serious blood disorders 

from prolonged, high exposure based on human epidemiology studies. Caused genetic effects and effects on 

the immune system in laboratory animal and some human studies. Caused toxicity to the fetus in laboratory 

animal studies. 

CUMENE: Repeated inhalation exposure of cumene vapour produced damage in the kidney of male rats only.



Page 8 of 13 

______________________________________________________________________________________________________________________ 

These effects are believed to be species specific and are not relevant to humans. GASOLINE UNLEADED: 

Carcinogenic in animal tests. Chronic inhalation studies resulted in liver tumours in female mice and kidney 

tumours in male rats. Neither result considered significant for human health risk assessment by the United 

States EPA and others. Did not cause mutations in-vitro or in-vivo. Negative in inhalation developmental studies 

and reproductive tox studies. Inhalation of high concentrations in animals resulted in reversible central nervous 

system depression, but no persistent toxic effect on the nervous system. Non-sensitizing in test animals. 

Caused nerve damage in humans from abusive use (sniffing). METHYL TERTIARY BUTYL ETHER (MTBE): 

Carcinogenic in animal tests. Inhalation exposure to high concentrations resulted in higher than expected 

mortality in male mice due to urinary tract obstructions and female mice displayed benign liver tumours. 

Inhalation exposure to high concentrations resulted in higher than expected mortality in male rats due to 

progressive kidney damage as well as increased benign and malignant kidney tumours, and benign testicular 

tumours. Did not cause mutations in-vitro or in-vivo. Rabbits exposed to high vapour concentrations did not 

have any offspring with adverse developmental effects. Mice exposed to high vapour concentrations (maternally 

toxic) had offspring with embryo/fetal toxicity and birth defects. Rats exposed to high vapour concentrations did 

not display any treatment-related effects in a two generation reproduction study.The significance of the animal 

findings at high exposures are not believed to be directly related to potential human health hazards in the 

workplace. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red 

blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance 

of these findings to humans is uncertain. 

N-HEXANE: Prolonged and/or repeated exposures to n-Hexane can cause progressive and potentially 

irreversible damage to the peripheral nervous system (e.g. fingers, feet, arms, legs, etc.). Simultaneous 

exposure to Methyl Ethyl Ketone (MEK) or Methyl Isobutyl Ketone (MIBK) and n-Hexane can potentiate the risk 

of adverse effects from n-Hexane on the peripheral nervous system. n-Hexane has been shown to cause 

testicular damage at high doses in male rats. The relevance of this effect for humans is unknown. TOLUENE : 

Concentrated, prolonged or deliberate inhalation may cause brain and nervous system damage. Prolonged 

and repeated exposure of pregnant animals (> 1500 ppm) have been reported to cause adverse fetal 

developmental effects. ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these 

findings to humans is uncertain. 

XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on 

the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these 

findings to humans has not been determined. 

Additional information is available by request. 

CMR Status: 

Chemical Name CAS Number List Citations 

BENZENE 71-43-2 1, 4, 5 

CUMENE 98-82-8 4 

Cyclohexane 110-82-7 4 

ETHYL BENZENE 100-41-4 3, 4 

GASOLINE 86290-81-5 3, 4 

METHYL-TERT-BUTYL ETHER 1634-04-4 4 

n-Hexane 110-54-3 4 

Naphthalene 91-20-3 3, 4 

TOLUENE 108-88-3 4 

XYLENES 1330-20-7 4 

--REGULATORY LISTS SEARCHED-- 

1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 

2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2



Page 9 of 13 

______________________________________________________________________________________________________________________ 


The information given is based on data available for the material, the components of the material, and similar materials. 

ECOTOXICITY 

Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic 

environment. 

MOBILITY 

More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and 

wastewater solids. 

Less volatile component -- Low solubility and floats and is expected to migrate from water to the land. 

Expected to partition to sediment and wastewater solids. 

PERSISTENCE AND DEGRADABILITY 

Biodegradation: 

Majority of components -- Expected to be inherently biodegradable 

Atmospheric Oxidation: 

More volatile component -- Expected to degrade rapidly in air 

BIOACCUMULATION POTENTIAL 

Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may 

reduce the bioconcentration or limit bioavailability. 


Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable 

laws and regulations, and material characteristics at time of disposal. 

DISPOSAL RECOMMENDATIONS 

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised 

incineration at very high temperatures to prevent formation of undesirable combustion products. 

Regulatory Disposal Information 

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain 

residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty 

drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty 

containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor 

and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, 

DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR 

OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. 


LAND (TDG) 

Proper Shipping Name: GASOLINE 

Hazard Class & Division: 3 

UN Number: 1203



Page 10 of 13 

______________________________________________________________________________________________________________________ 

Packing Group: II 

Marine Pollutant: MP: 100 % weight PP: 0 % weight 

Special Provisions: 17 

LAND (DOT) 



ID Number: 1203 


ERG Number: 128 

Label(s): 3 

Transport Document Name: UN1203, GASOLINE, 3, PG II 

SEA (IMDG) 

Proper Shipping Name: MOTOR SPIRIT or GASOLINE or PETROL 


EMS Number: F-E, S-E 

UN Number: 1203 


Label(s): 3 

Transport Document Name: UN1203, MOTOR SPIRIT or GASOLINE or PETROL, 3, PG II, (-40°C c.c.) 

AIR (IATA) 





Label(s): 3 

Transport Document Name: UN1203, GASOLINE, 3, PG II 


WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic 

Material 

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the 

(M)SDS contains all the information required by the Controlled Products Regulations. 

CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have 

been notified under CEPA. 

National Chemical Inventory Listing: AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA 

The Following Ingredients are Cited on the Lists Below: 


BENZENE 71-43-2 6 

CUMENE 98-82-8 6 

Cyclohexane 110-82-7 6



Page 11 of 13 

______________________________________________________________________________________________________________________ 

ETHYL BENZENE 100-41-4 6 

METHYL-TERT-BUTYL ETHER 1634-04-4 6 

n-Hexane 110-54-3 6 

Naphthalene 91-20-3 1, 6 

TOLUENE 108-88-3 6 

XYLENES 1330-20-7 1, 6 


1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 

2 = TSCA 5a2 4 = TSCA 6 6 = NPRI 


N/D = Not determined, N/A = Not applicable 

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: 

Revision Changes: 

Section 04: First Aid Skin - Header was modified. 

Section 04: First Aid Eye - Header was modified. 

Section 04: First Aid Ingestion - Header was modified. 

Section 06: Notification Procedures - Header was modified. 

Section 10: Materials To Avoid - Header was modified. 

Section 11: Ingestion Acute Lethality - Header was modified. 

Section 09: Vapour Pressure - Header was modified. 

Section 05: Hazardous Combustion Products was modified. 

Section 14: Sea (IMDG) - Header was modified. 

Section 15: National Chemical Inventory Listing - Header was modified. 

Section 15: National Chemical Inventory Listing was modified. 

Section 16: Synonyms was modified. 

Section 16: Health Hazards - Header was modified. 

Section 16: Physical Hazards - Header was modified. 

Section 11: Chronic Tox - Component - WHMIS was modified. 

Section 08: OEL Table - Substance Name Column - Header was added. 

Section 08: OEL Table - Form Column - Header was added. 

Section 08: OEL Table - Limit Column - Header was added. 

Section 08: OEL Table - Notation Column - Header was added. 

Section 08: OEL Table - Source Column - Header was added. 

Section 13: Regulatory Disposal Information - Header was added. 

Section 13: Regulatory Disposal Information - Header was deleted. 

Section 08: OEL Table - Form Column - Header was deleted. 

Section 08: OEL Table - Limit Column - Header was deleted. 

Section 08: OEL Table - Notation Column - Header was deleted. 

Section 08: OEL Table - Source Column - Header was deleted. 

Section 08: OEL Table - Substance Name Column - Header was deleted. 

SYNONYMS: ESSO PREMIUM GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA DYED, ESSO 

EXTRA MIDGRADE GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA, EXXON MIDGRADE GASOLINE, 

ESSO MIDGRADE GASOLINE, ESSO REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89 DCA, 

EXXON REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89, EXXON PREMIUM GASOLINE, 

GASOLINE REGULAR UNLEADED RUL87 DYED, GASOLINE MIDGRADE UNLEADED MUL89 DCA DYED, 

GASOLINE REGULAR UNLEADED RUL87, GASOLINE PREMIUM UNLEADED PUL91, GASOLINE RBOB



Page 12 of 13 

______________________________________________________________________________________________________________________ 

BLENDSTOCK P91, GASOLINE RBOB BLENDSTOCK R87, GASOLINE MIDGRADE UNLEADED MUL89 LDCA, 

GASOLINE MIDGRADE UNLEADED MUL89 LDCA DYED, GASOLINE REGULAR UNLEADED RUL87 DCA, 

GASOLINE PREMIUM UNLEADED PUL91 LDCA, GASOLINE PREMIUM UNLEADED PUL91 LDCA DYED, 

GASOLINE PREMIUM UNLEADED PUL91 DCA DYED, GASOLINE REGULAR UNLEADED RUL87 DCA DYED, 

GASOLINE PREMIUM UNLEADED PUL91 DCA, Isooctane, UNLEADED AUTOMOTIVE GASOLINE 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

Precautionary Label Text: 

WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material 

Health Hazards 

May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and 

cause lung damage. May cause central nervous system depression. 

Target Organs: Blood and/or blood-forming organs | 

Physical Hazards 

FLAMMABLE. Material can accumulate static charges which may cause an incendiary electrical discharge. Material 

can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. 

PRECAUTIONS 

Avoid breathing mists or vapour. Avoid contact with skin. Use non-sparking tools and explosion-proof equipment. 

Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not siphon by mouth. Use 

only with adequate ventilation. Use proper bonding and/or earthing procedures. 

FIRST AID 

INHALATION: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. 

Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek 

immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-tomouth 

resuscitation. 

Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. 

Oral: Seek immediate medical attention. Do not induce vomiting. 

Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing 

before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of 

the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even 

though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first 

few hours may significantly reduce the ultimate extent of injury. 

FIRE FIGHTING MEDIA 

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. 

SPILL/LEAK 

Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you 

can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam 

may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to 

containers. Recover by pumping or with suitable absorbent. 

Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you 

can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and



Page 13 of 13 

______________________________________________________________________________________________________________________ 

explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a 

specialist before using dispersants. 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate 

and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the 

document is the most current available from an official Imperial Oil distribution system. The information and 

recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy 

itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be 

consulted to insure proper health, safety and other necessary information is included on the container. Appropriate 

warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly 

prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is 

not permitted. 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

DGN: 5007481 (1006754) 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

Copyright 2002 Imperial Oil Limited, All rights reserved 

Prepared By: Imperial Oil Limited, IH and Product Safety

Section 1: Product and Company Identification 


Product Name: Valve Action® Paint Marker 

Revision Date: February 25, 2009 

Page 1 of 6 

Product Name: Valve Action® Paint Marker – Brown, Purple, White, Yellow, Red, Black, Orange, Blue, Green, 

Gold, Light Green, Pink, Silver, Light Blue 

Product Code: 96809 (brown), 96817 (purple), 96820 and 96800 (white), 96821 and 96801 (yellow), 96822 

and 96802 (red), 96823 and 96803 (black), 96824 and 96807 (orange), 96825 and 96805 

(blue), 96826 and 96806 (green), 96827 (gold), 96828 (light green), 96830 (pink), 96835 (light 

blue), 96832 and 96804 (silver) 

Product Use: Marker for metal, wood, glass, plastic, rubber, cardboard and paper. 

Manufacturer: LA-CO Industries, Inc. 

1201 Pratt Boulevard 

Elk Grove Village, IL. 

60007-5746 

E-mail Contact: customer_service@laco.com 

Phone Number: (847) 956-7600 

Fax: (847) 956-9885 

24-hour Emergency: CHEMTREC: (800) 424-9300 

Section 2: Hazards Identification 

Protective 

Clothing 

Not Required for 

Normal Use 

NFPA Rating 

(USA) 

EC Classification 

Not Classified as 

Dangerous 

WHMIS 

(Canada) 

Transportation 

Not Controlled Not Regulated 

Emergency Overview: The paint inside the marker contains components which are flammable and considered hazardous 

by inhalation of vapors, eye and skin contact. Exposure to hazardous or dangerous substances is 

not expected when handling this product for its intended use. 

Potential Health Effects: ACUTE (short term): 

This MSDSonly pertains to Product containing 

the prefix "N" on the date/lot code printed on 

the label of on each Valve Action Paint Marker. 

Appearance, Color and Odor: Marker containing less than 10 mL of various colored paint. 

Organic solvent odor. 

USA: This product is not a hazardous material as defined by 29 CFR1910.1200, OSHA Hazard 

Communication Evaluation. This product meets the definition of an “article”. 

Canada: This is not a controlled product under WHMIS. This product meets the definition of a 

“manufactured article” and is not subject to the regulations of the Hazardous Products Act. 

European Communities (EC): This product is not classified as dangerous according to Directive 

1999/45/EC and its amendments. 

Relevant Route(s) of Exposure: Skin contact. 

Inhalation: Exposure to hazardous substances by inhalation is not expected with normal use of the marker. 

Ingestion: Not an expected route of occupational exposure. Acute oral toxicity of the component substances 

is low. 

Skin: Normal use of marker will not result in harmful effects. The paint may cause irritation when in 

contact with the skin. 

Eye: Not an expected route of occupational exposure. Liquid and concentrated vapors can irritate the 

eyes.

Section 2: Hazards Identification, continued 

Medical Conditions Aggravated 

by Exposure: 

Interactions With Other 

Chemicals: 




Page 2 of 6 

CHRONIC (long term): 

Long-term health effects are not expected with normal use of the marker. Prolonged or repeated 

contact of the paint to skin may result in defatting and drying of skin and may result in dermatitis. 

Preexisting skin disorders may be aggravated by repeated exposure to the liquid in the marker. 

Not available 

Potential Environmental Effects: Not available 

Section 3: Composition / Information on Ingredients 

Chemical Name CAS No. Wt.% EINECS / ELINCS Symbol Risk Phrases 

1-methoxypropan-2-ol 107-98-2 40 - 70 203-539-1 None R10 

Ethanol 64-17-5 10 - 16 200-578-6 F R11 

2-methoxy-1-propanol 1589-47-5 0.5 – 2.5 216-455-5 T; Xi R10 - Repr. Cat. 2; 

R61 - R37/38-41 

Isopropyl alcohol 67-63-0 0.5 – 2.5 200-661-7 F; Xi R11 - R36 - R67 

Ethyl Acetate 141-78-6 0.1 – 1.1 205-500-4 F; Xi R11; R36; R66; R67 

See Section 16 for the full text of the R-phrases above. 

Section 4: First Aid Measures 

Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air and obtain 

medical advice. 

Eye Contact: No effects expected. If irritation occurs, flush contaminated eye(s) with lukewarm, gently flowing 

water for 5 minutes. If irritation persists, obtain medical advice. 

Skin Contact: No health effects expected. If irritation does occur, flush with lukewarm, gently flowing water for 5 

minutes. If irritation persists, obtain medical advice. 

Ingestion: If irritation or discomfort occurs, obtain medical advice immediately. 

Section 5: Fire Fighting Measures 

Flammable Properties: Paint contained within the markers is flammable. 

Suitable extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide, or alcohol-resistant 

foam. For large fires, use carbon dioxide, dry chemical powder, alcohol-resistant 

foam or polymer foam. Firefighting foams are the extinguishing agent of choice for 

most flammable liquid fires. Use water spray to cool fire-exposed containers. 

Unsuitable extinguishing Media: Not available 

Explosion Data: 

Sensitivity to Mechanical Impact: Not applicable 

Sensitivity to Static Discharge: Not applicable 

Specific Hazards arising from the Chemical: If involved in a fire, combustion may produce toxic and irritating fumes and gases. 

Protective Equipment and precautions for 

firefighters: 

NFPA Health: 0 

Flammability: 1 

Instability: 0 

Self-contained breathing apparatus and protective clothing should be worn. 

Remove all unprotected personnel.

Section 6: Accidental Release Measures 




Page 3 of 6 

Personal Precautions: If large volumes of liquid paint are released, wear protective gloves, goggles and clothing. 

Ventilate the area. Monitor the workplace air for harmful concentrations of vapors and take 

appropriate precautions if concentrations in air exceed workplace exposure limits. 

Environmental Precautions: Prevent the product from entering sewers or waterways. 

Methods for Containment: If large volumes of liquid paint are released, stop the leak if it is safe to do so. Contain spilled 

paint with earth, sand, or absorbent material which does not react with spilled material. 

Methods for Clean-up: Clean up spills immediately. Shut off or extinguish all sources of ignition. Immediately soak 

spilled material with water. Soak up spill with absorbent material which does not react with 

spilled chemical. Put material in suitable, covered, labeled containers. Contaminated 

absorbent material may pose the same hazards as the spilled product. Dispose of any 

contaminated, unusable product as described in Section 13 of this SDS. 

Section 7: Handling and Storage 

Handling: Avoid breathing vapors. Do not use near sources of extreme heat. Keep out of reach of 

children. 

Storage: Store in a cool, dry area, out of direct sunlight and away from heat, flames and ignition 

sources. Keep markers closed when not in use. 

Section 8: Exposure Controls/Personal Protection 

Exposure Guidelines 

Measurable airborne concentrations of the component substances, listed in Section 3, are not expected when the markers are used for 

their intended purpose. Consult local authorities for acceptable exposure limits. 

Exposure Controls 

Engineering Controls: Not required for normal use. 

Personal Protection: 

Eye/Face Protection: Not required for normal use. In case of accidental release of large quantities of paint, wear 

goggles. 

Skin Protection: Not required for normal use. In case of accidental release of large quantities of paint, wear 

gloves. 

Respiratory Protection: Not required for normal use. 

General Hygiene Measures: Avoid breathing vapors. Do not ingest. Avoid contact of the paint to skin and eyes. Keep out 

of reach of children.

Section 9: Physical and Chemical Properties 




Page 4 of 6 

Physical State: Solid, containing liquid paint. Flash Point & method: 31°C (88°F) setaflash for 1methoxypropan-2-ol 

Appearance, Color and Cylindrical marker; various colors, Autoignition Temperature: 287°C (594°F) for 1- 

Odor: 

mild odor of organic solvent. 

methoxypropan-2-ol 

Odor Threshold: Not available Flammability Limits in Air: LEL: 1.5 

UEL: 13.74 at 151°C for 1methoxypropan-2-ol 

pH: Not applicable Vapor Pressure: 11.8 for 1-methoxypropan-2-ol 

Specific Gravity: 0.98 – 1.13 Vapor Density: 3.12 for 1-methoxypropan-2-ol 

Partition coefficient: 

(n-octanol/water) 

Not available Evaporation Rate:

Section 12: Ecological Information 

Ecotoxicity: Not available 

Persistence/Degradability: Not available 

Bioaccumulation/Accumulation: Not available 

Mobility: Not available 

Section 13: Disposal Considerations 




Page 5 of 6 

Waste Disposal Method: Do NOT dump into any sewers, on the ground or into any body of water. Store material for 

disposal as indicated in Section 7 Handling and Storage. 

The conditions of use, storage and disposal of this product are beyond our control and may be 

beyond our knowledge. For this and other reasons, LA-CO Industries, Inc. does not assume 

responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any 

way connected with the handling, storage, use or disposal of this product. 

USA: Dispose of in accordance with local, state and federal laws and regulations. 

Canada: Dispose of in accordance with local, provincial and federal laws and regulations. 

EC: Waste must be disposed of in accordance with relevant EC Directives and national, regional and 

local environmental control regulations. For disposal within the EC, the appropriate code 

according to the European Waste Catalogue (EWC) should be used. 

Section 14: Transport Information: 

U.S. Hazardous Materials Regulation (DOT 49CFR): Not regulated, this product conforms to small quantity exception of DOT 

49CFR173.4. 

Canadian Transportation of Dangerous Goods (TDG): Not regulated 

ADR/RID: Not regulated 

IMDG: Not regulated 

Marine Pollutants: Not applicable 

ICAO/IATA: Not regulated 

Section 15: Regulatory Information 

USA 

TSCA Status: All component substances are listed on the TSCA inventory. 

SARA Title III 

Sec. 302/304: 

Sec: 311/312: 

Sec. 313: 

CERCLA RQ: 

None 

Flammable 

None 

Not applicable 

California Prop 65: Not applicable 

State Right-to-Know Lists : 1-methoxypropan-2-ol can be found on the following state right to know lists: California, 

New Jersey, Pennsylvania, Minnesota, Massachusetts. 

Ethyl Acetate can be found on the following state right to know lists: Massachusetts, New 

Jersey, Pennsylvania. 

Titanium dioxide can be found on the following state right to know lists: New Jersey, 

Pennsylvania, Massachusetts.

Section 15: Regulatory Information, continued 




Page 6 of 6 

Canada This product has been classified in accordance with the hazard criteria of the Controlled 

Products Regulations and the MSDS contains all the information required by the Controlled 

Products Regulations. 

WHMIS Classification: 

(for workplace exposures) 

New Substance Notification 

Regulations: 

Not controlled. Product meets the definition of a “manufactured article” and is not subject 

to the regulations of the Hazardous Products Act. 

All component substances are listed on Canada’s Domestic Substances List (DSL). 

NPRI Substances: Ethyl Acetate is a NPRI reportable substance. 

EC Classification for the 

Substance/Preparation 

European Inventories: All component substances are listed in EINECS. 

Section 16: Other Information 

Full Text of R-phrases appearing in 

Section 2: 

Preparation Information: 

Symbol: This product is not classified as dangerous according to Directive 1999/45/EC and its 

amendments. 

R10: Flammable. 

R11: Highly Flammable. 

R36: Irritating to eyes 

R37/38: Irritating to respiratory system and skin. 

R41: Risk of serious damage to eyes. 

R61: May cause harm to the unborn child. 

R66: Repeated exposure may cause skin dryness or cracking. 

R67: Vapors may cause drowsiness and dizziness. 

Prepared by: LEHDER Environmental Services Limited (519) 336-4101 

www.lehder.com 


Disclaimer: While LEHDER Environmental Services Limited believes that the data set forth herein is 

accurate, as of the date hereof, LEHDER makes no warranty with respect thereto and 

expressly disclaims all liability for reliance thereon. Such data is offered solely for your 

consideration, investigation and verification. 

Manufacturer Disclaimer: The information contained herein is based on data available to us and is accurate and 

reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes 

no representations as to its completeness or accuracy. Information is supplied on 

condition that persons receiving such information will make their own determination as to 

its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be 

responsible for damages of any nature whatsoever resulting from the use of or reliance 

upon the information contained herein.

Product Name: VARSOL DX 3139 SOLVENT 

Revision Date: 28 May 2010 

Page 1 of 11 

______________________________________________________________________________________________________________________ 



PRODUCT 


Product Description: Aliphatic Hydrocarbon 

MSDS Number: 4079 

Intended Use: Solvent 

COMPANY IDENTIFICATION 

Supplier: IMPERIAL OIL CHEMICALS DIVISION 

240 4th Avenue S.W. 

CALGARY, ALBERTA. T2P 3M9 Canada 

24 Hour Environmental / Health Emergency 519-339-2145 

Telephone 

Transportation Emergency Phone Number 519-339-2145 

Product Technical Information 1-800-663-4109 

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS 

Reportable Hazardous Substance(s) or Complex Substance(s) 


DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 50.0 - 80.0% Dermal Lethality: LD50 > 

3160 mg/kg (Rabbit); Oral 

Lethality: LD50 > 15000 

mg/kg (Rat) 

STODDARD SOLVENT 8052-41-3 20.0 - 50.0% Dermal Lethality: LD50 > 2.0 


LD50 > 5.0 g/kg (Rat) 

Hazardous Constituent(s) Contained in Complex Substance(s) 


NONANE 111-84-2 1.0 - 5.0% None 

PSEUDOCUMENE (1,2,4-TRIMETHYLBENZENE) 95-63-6 < 2.0% Inhalation Lethality: LC50 

3662 ppm (Rat); Oral 

Lethality: LD50 5.0 g/kg (Rat) 

XYLENES 1330-20-7 < 0.3% Dermal Lethality: LD50 4.5 





* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 


This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). 

PHYSICAL/CHEMICAL EFFECTS 

Combustible. Material can release vapours that readily form flammable mixtures. Vapour accumulation could 

flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.



Page 2 of 11 

______________________________________________________________________________________________________________________ 

HEALTH EFFECTS 

If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. 

May cause central nervous system depression. 

NFPA Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 

HMIS Hazard ID: Health: 1* Flammability: 2 Reactivity: 0 

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert 

advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary 

from person to person. 


INHALATION 

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use 

adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek 

immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use 

mouth-to-mouth resuscitation. 

SKIN CONTACT 

Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing 

before reuse. 

EYE CONTACT 

Flush thoroughly with water. If irritation occurs, get medical assistance. 

INGESTION 

Seek immediate medical attention. Do not induce vomiting. 

NOTE TO PHYSICIAN 

If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. 


EXTINGUISHING MEDIA 

Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish 

flames. 

Inappropriate Extinguishing Media: Straight streams of water 

FIRE FIGHTING 

Fire Fighting Instructions: FLAMMABLE. Evacuate area. Prevent run-off from fire control or dilution from 

entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and 

in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed 

surfaces and to protect personnel. 

Unusual Fire Hazards: Vapour is flammable and heavier than air. Vapour may travel across the ground and 

reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should 

consider protective equipment indicated in Section 8.



Page 3 of 11 

______________________________________________________________________________________________________________________ 

Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon 

FLAMMABILITY PROPERTIES 

Flash Point [Method]: 42C (108F) [ ASTM D-56] 


Autoignition Temperature: 261°C (502°F) 


NOTIFICATION PROCEDURES 

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable 

regulations. 

PROTECTIVE MEASURES 

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if 

required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the 

Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for 

Personal Protective Equipment. 

SPILL MANAGEMENT 

Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if 

you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or 

walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapoursuppressing 

foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. 

Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: 

Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with 

suitable absorbent. 

Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the 

Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from 

the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed 

the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to 

evaporate. Seek the advice of a specialist before using dispersants. 

Water spill and land spill recommendations are based on the most likely spill scenario for this material; 

however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction 

and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be 

consulted. Note: Local regulations may prescribe or limit action to be taken. 

ENVIRONMENTAL PRECAUTIONS 

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, 

sewers, basements or confined areas. 


HANDLING 

Avoid contact with skin. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated 

material. Use only with adequate ventilation. Prevent small spills and leakage to avoid slip hazard. Material 

can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding 

and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static



Page 4 of 11 

______________________________________________________________________________________________________________________ 

accumulation. Consult local applicable standards for guidance. Additional references include American 

Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or 

National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 

(Electrostatics - Code of practice for the avoidance of hazards due to static electricity). 

Loading/Unloading Temperature: [Ambient] 

Transport Temperature: [Ambient] 

Transport Pressure: [Ambient] 

Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, 

static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a 

semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive 

or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, 

presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid. 

STORAGE 

The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep 

container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store 

in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, 

transfer containers and associated equipment should be grounded and bonded to prevent accumulation of 

static charge. 

Storage Temperature: [Ambient] 

Storage Pressure: [Ambient] 

Suitable Containers/Packing: Tank Cars; Tank Trucks; Barges; Drums 

Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Stainless Steel; Cast Iron; 

Copper Bronze; Inorganic Zinc Coatings; Polyamide Epoxy; Polyethylene 

Unsuitable Materials and Coatings: Butyl Rubber; Natural Rubber 

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 

Substance Name Form Limit/Standard Note Source 

NONANE TWA 200 ppm ACGIH 

PRODUCT Vapour. RCP - 102 ppm 600 Total Supplier 

TWA 

mg/m3 Hydrocarbon 

s 

PSEUDOCUMENE (1,2,4- 

TRIMETHYLBENZENE) 

TWA 25 ppm ACGIH 

STODDARD SOLVENT TWA 100 ppm ACGIH 

XYLENES STEL 150 ppm ACGIH 

XYLENES TWA 100 ppm ACGIH 

NOTE: Limits/standards shown for guidance only. Follow applicable regulations. 

ENGINEERING CONTROLS 

The level of protection and types of controls necessary will vary depending upon potential exposure conditions. 

Control measures to consider: 

Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-



Page 5 of 11 

______________________________________________________________________________________________________________________ 

proof ventilation equipment. 


Personal protective equipment selections vary based on potential exposure conditions such as applications, 

handling practices, concentration and ventilation. Information on the selection of protective equipment for use 

with this material, as provided below, is based upon intended, normal usage. 

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a 

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator 

selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of 

respirators to be considered for this material include: 

Half-face filter respirator 

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. 

Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, 

gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. 

Hand Protection: Any specific glove information provided is based on published literature and glove 

manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. 

Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use 

conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material 

include: 

If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with 

forearms is likely, wear gauntlet-style gloves. 

Eye Protection: If contact is likely, safety glasses with side shields are recommended. 

Skin and Body Protection: Any specific clothing information provided is based on published literature or 

manufacturer data. The types of clothing to be considered for this material include: 

If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. 

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after 

handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective 

equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. 

Practise good housekeeping. 

ENVIRONMENTAL CONTROLS 

See Sections 6, 7, 12, 13. 


Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional 

data. 

GENERAL INFORMATION 

Physical State: Liquid 

Form: Clear 

Colour: Colourless 

Odour: Mild Petroleum/Solvent 

Odour Threshold: N/D



Page 6 of 11 

______________________________________________________________________________________________________________________ 

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION 

Relative Density (at 15.6 C): 0.779 

Density: 779 kg/m³ (6.5 lbs/gal, 0.78 kg/dm³) 

Flash Point [Method]: 42C (108F) [ ASTM D-56] 


Autoignition Temperature: 261°C (502°F) 

Boiling Point / Range: 161C (322F) - 198C (388F) 

Vapour Density (Air = 1): 4.9 at 101 kPa 

Vapour Pressure: 0.262 kPa (1.97 mm Hg) at 20°C 

Evaporation Rate (n-butyl acetate = 1): 0.19 

pH: N/A 

Log Pow (n-Octanol/Water Partition Coefficient): N/D 

Solubility in Water: Negligible 

Viscosity: 1.08 cSt (1.08 mm2/sec) at 40°C | 1.27 cSt (1.27 mm2/sec) at 25C 

Oxidizing Properties: See Hazards Identification Section. 

OTHER INFORMATION 

Freezing Point: 5000 mg/kg Minimally Toxic. Based on test data for structurally similar 

materials. 

Skin 

Toxicity: LD50 > 3160 mg/kg Minimally Toxic. Based on test data for structurally similar 

materials. 

Irritation: Data available. Mildly irritating to skin with prolonged exposure. Based on test



Page 7 of 11 

______________________________________________________________________________________________________________________ 


Eye 

Irritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on test 


CHRONIC/OTHER EFFECTS 

For the product itself: 

Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory 

tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous 

system effects including death. Prolonged and/or repeated skin contact with low viscosity materials may defat 

the skin resulting in possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during 

ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. 

Contains: 

XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on 

the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these 

findings to humans has not been determined. 

Additional information is available by request. 

CMR Status: None. 


NONANE 111-84-2 4 



95-63-6 4 

STODDARD SOLVENT 8052-41-3 4 

XYLENES 1330-20-7 4 


1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 

2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 


The information given is based on data available for the material, the components of the material, and similar materials. 

ECOTOXICITY 

Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic 

environment. 

MOBILITY 

Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater 

solids. 

PERSISTENCE AND DEGRADABILITY 

Biodegradation: 

Material -- Expected to be readily biodegradable. 

Hydrolysis: 

Material -- Transformation due to hydrolysis not expected to be significant. 

Photolysis:



Page 8 of 11 

______________________________________________________________________________________________________________________ 

Material -- Transformation due to photolysis not expected to be significant. 

Atmospheric Oxidation: 

Material -- Expected to degrade rapidly in air 

OTHER ECOLOGICAL INFORMATION 

VOC (EPA Method 24): 6.501 lbs/gal 


Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable 

laws and regulations, and material characteristics at time of disposal. 

DISPOSAL RECOMMENDATIONS 

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised 

incineration at very high temperatures to prevent formation of undesirable combustion products. 

REGULATORY DISPOSAL INFORMATION 

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain 

residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty 

drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty 

containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor 

and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, 

DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR 

OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. 


LAND (TDG) 

Proper Shipping Name: PETROLEUM DISTILLATES, N.O.S 



Packing Group: III 

LAND (DOT) 


Hazard Class & Division: COMBUSTIBLE LIQUID 

ID Number: 1268 


ERG Number: 128 

Label(s): NONE 

Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE LIQUID, PG III 

Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material 

varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid. 

This material is not regulated under 49 CFR in a container of 450 litre/119 gallon capacity or less when 

transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically 

listed as a hazardous substance. 

SEA (IMDG) 


Hazard Class & Division: 3



Page 9 of 11 

______________________________________________________________________________________________________________________ 

EMS Number: F-E, S-E 



Label(s): 3 

Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, PG III, (42°C c.c.) 

AIR (IATA) 





Label(s) / Mark(s): 3 

Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, PG III 


WHMIS Classification: Class B, Division 3: Combustible Liquids 

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the 

(M)SDS contains all the information required by the Controlled Products Regulations. 

CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have 

been notified under CEPA. 

NATIONAL CHEMICAL INVENTORY LISTING: AICS, IECSC, DSL, EINECS, ENCS, KECI, PICCS, TSCA 

The Following Ingredients are Cited on the Lists Below: 


NONANE 111-84-2 1, 5 



95-63-6 6 

XYLENES 1330-20-7 1, 6 


1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 

2 = TSCA 5a2 4 = TSCA 6 6 = NPRI 


N/D = Not determined, N/A = Not applicable 

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: 

Revision Changes: 

Section 04: First Aid Eye - Header was modified. 

Section 04: First Aid Ingestion - Header was modified.



Page 10 of 11 

______________________________________________________________________________________________________________________ 

Section 06: Notification Procedures - Header was modified. 

Section 01: Company Mailing Address was modified. 

Section 11: Acute Toxicity Table Header was modified. 

Section 09: Physical State was modified. 

Section 11: Inhalation - Header was modified. 

Section 09: Evaporation Rate - Header was modified. 

Section 09: Vapour Pressure - Header was modified. 

Section 07: Handling and Storage-Handling was modified. 

Section 07: Handling and Storage-Storage Phrases was modified. 

Section 01: Company Mailing Address was modified. 

Hazard Identification: Physical/Chemical Hazard was modified. 

Section 07: Static Accumulator was modified. 

Section 07: Suitable Materials and Coatings - Header was modified. 

Section 07: Materials/Coatings - Suitable was modified. 

Section 07: Materials/Coatings - Unsuitable was modified. 

Section 09 Viscosity was modified. 

Section 09 Viscosity was modified. 

Section 15: National Chemical Inventory Listing - Header was modified. 

Hazard Identification: Hazards Note was modified. 

Composition: Component table was modified. 

Section 16: Health Hazards - Header was modified. 

Section 16: Physical Hazards - Header was modified. 

Section 16: CA Prepared by - Header was modified. 

Composition: Component table was modified. 

Section 08: Exposure Limits Table was modified. 

Section 16: Physical Hazards additional was modified. 

Section 16: First Aid Inhalation - Header was modified. 

Section 16: Precautions was modified. 

Section 16: Precautionary Label Text - Header was modified. 

Section 09: Oxidizing Properties was modified. 

Section 15: Canadian List Citations Table was modified. 

Section 11: Tox List Cited Table was modified. 

Section 09: Physical State was modified. 

Section 13: Regulatory Disposal Information - Header was modified. 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

PRECAUTIONARY LABEL TEXT: 

WHMIS Classification: Class B, Division 3: Combustible Liquids 

HEALTH HAZARDS 

If swallowed, may be aspirated and cause lung damage. 

PHYSICAL HAZARDS 

Combustible. Material can accumulate static charges which may cause an ignition. 

PRECAUTIONS 

Avoid contact with skin. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Use 

only with adequate ventilation. Use proper bonding and/or earthing procedures.However, bonding and earthing may not 

eliminate the hazard from static accumulation. 

FIRST AID 

Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use 

adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate 

medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth



Page 11 of 11 

______________________________________________________________________________________________________________________ 

resuscitation. 

Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. 

Oral: Seek immediate medical attention. Do not induce vomiting. 

Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing 

before reuse. 

FIRE FIGHTING MEDIA 

Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. 

SPILL/LEAK 

Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you 

can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam 

may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to 

containers. Recover by pumping or with suitable absorbent. 

Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills 

as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use 

containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If 

the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect 

shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate 

and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the 

document is the most current available from an official Imperial Oil distribution system. The information and 

recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy 

itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be 

consulted to insure proper health, safety and other necessary information is included on the container. Appropriate 

warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly 

prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is 

not permitted. 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

DGN: 5004216 (1013968) 

----------------------------------------------------------------------------------------------------------------------------------------------------- 

Copyright 2002 Imperial Oil Limited, All rights reserved 

Prepared by: Imperial Oil Limited, Solvents

MANUFACTURER/SUPPLIER: 

US Office: 

WD-40 Company 

1061 Cudahy Place 

San Diego, CA 92110 

WD-40 



Information Phone #: (619) 275-1400 

Emergency Phone # 24 hr: 

Chemtrec: (800) 424-9300 – 

Designated for use only in the event of chemical 

emergencies involving a spill, leak, fire exposure or 

accident involving chemicals. 

PRODUCT NAME: WD-40 Aerosol 

PRODUCT USE: Cleaner, lubricant. 

MSDS DATE OF PREPARATION: March 13, 2010 

Page 1 of 4 

Canadian Office: 

WD-40 Products [Canada] Ltd. 

P.O. Box 220 

Toronto, Ontario M9C 4V3 




Canutec: (613) 996-6666 – 



accident involving chemicals 

DANGER! Harmful or fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use 

with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. 


PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact. 

ACUTE EFFECTS: 

INGESTION: This product has low oral toxicity. Swallowing of the liquid contents may cause irritation, nausea, 

vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause 

chemical pneumonitis. 

EYES: Contact may be mildly irritating to eyes. May cause redness and tearing. 

SKIN: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. 

INHALATION: High concentrations may cause nasal and respiratory irritation and central nervous system effects 

such as headache, dizziness and nausea. May aggravate existing respiratory conditions such as asthma. Intentional 

abuse may be harmful or fatal. 

CHRONIC EFFECTS: None expected. 

SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS 

Ingredient CAS Number Percent 

Aliphatic Petroleum Distillates 64742-47-8 

64742-88-7 

45-50% 

Petroleum Base Oil 64742-58-1 

64742-53-6 

64742-56-9 

64742-65-0 

30-35% 

Non-Hazardous Ingredients Proprietary


Page 2 of 4 

WD-40 Aerosol 

03/13/10 

For Medical Emergencies Call 1-888-324-7596 (24 hours/day) 

INGESTION: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 

Safety Hotline at 1-888-324-7596 immediately. 

EYE CONTACT: Flush thoroughly with water. Get medical attention if irritation persists. 

SKIN CONTACT: Wash with soap and water. If irritation develops and persists, get medical attention. 

INHALATION: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms 

develop and persist. 


EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding 

amounts of water. Burning product will float on the surface and spread fire. 

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should always wear positive pressure self-contained 

breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect 

against bursting containers. 

UNUSUAL FIRE/EXPLOSION HAZARDS: Contents under pressure. Aerosol containers may burst under fire 

conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 


SPILL RESPONSE: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and 

ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain 

and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report 

spills to authorities as required. 


HANDLING: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use 

with adequate ventilation. Keep away from heat, sparks and open flames. Wash thoroughly with soap and water 

after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. 

Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out 

of the reach of children. 

STORAGE: Do not store above 120 F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. 

SECTION 8 EXPOSURE CONTROLE/PERSONAL PROTECTION 

OCCUPATIONAL EXPOSURE LIMITS: 

Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended 

Petroleum Base Oil 5 mg/m3 TWA ACGIH TLV 

10 mg/m3 STEL ACGIH TLV 

Non-Hazardous Ingredients None Established 

Surfactant None Established 

Carbon Dioxide 5000 ppm TWA, 30,000 ppm STEL ACGIH TLV 

The Following Controls are Recommended for Normal Consumer Use of this Product 

Engineering Controls: Use in a well-ventilated area. 


Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. 

Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin 

contact is likely. 

Respiratory Protection: None needed for normal use with adequate ventilation.

Page 3 of 4 

WD-40 Aerosol 

03/13/10 

For Bulk Processing or Workplace Use the Following Controls are Recommended 

Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that 

occupational exposure limits. 


Eye Protection: Safety goggles recommended where eye contact is possible. 

Skin Protection: Wear chemical resistant gloves. 

Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, 

wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and 

concentration. Follow applicable regulations and good Industrial Hygiene practice. 

Work/Hygiene Practices: Wash with soap and water after handling. 

SECTION 9 PHYSICAL DATA 

APPEARANCE AND ODOR: Light amber liquid with a mild odor. 

Boiling Point: 361 - 369 F (183 - 187°C) Specific Gravity: 0.8 – 0.82 @ 60 F 

Solubility in Water: Insoluble pH: Not Applicable 

Vapor Pressure: 95-115 PSI @ 70 F Vapor Density: Greater than 1 

Percent Volatile: 70-75% VOC: 412 grams/liter (49.5%) 

Coefficient of Water/Oil Not Determined Kinematic 2.79-2.96cSt @ 100 F 

Distribution: 

Flash Point: 122 F (49°C) Tag Open Cup 

(concentrate) 

Pour Point: -63 C (-81.4 F ) ASTM D-97 

Viscosity: 

Flammable Limits: 

(Solvent Portion) 


LEL: 0.6% UEL: 8.0% 

STABILITY: Stable 

INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. Do not puncture or incinerate 

containers. 

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. 


The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the 

ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. 

None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a 

reproductive hazard. 

No data is currently available. 



WASTE DISPOSAL METHOD: If this product becomes a waste, it would be expected to meet the criteria of a 

hazardous waste based on flammability. However, it is the responsibility of the generator to determine at the time of 

disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local 

regulations. 


U.S. DOT Hazard Classification: Consumer Commodity, ORM-D

Canadian TDG Classification: Limited Quantity 

IMDG Code Hazard Classification: UN1950, Aerosols, 2.1. 

U.S. FEDERAL REGULATIONS: 


Page 4 of 4 

WD-40 Aerosol 

03/13/10 

CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills 

are reportable to the National Response Center under the Clean Water Act and many states have more stringent release 

reporting requirements. Report spills as required under federal, state and local regulations. 


Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure 

Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 

Reporting requirements: None 

Section 302 Extremely Hazardous Substances (TPQ): None 

EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA 

inventory. 


Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List 

or exempt from notification 

Canadian WHMIS Classification: Class B-5 (Flammable Aerosol). 

This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS 

contains all of the information required by the CPR. 


HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 

(minimal hazard) 

Revision Date: 03/13/10 Supersedes: 08/25/09 

Prepared By: Industrial Health & Safety Consultants, Inc. 1-203-929-3473 

This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The 

foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients 

are advised to confirm in advance of need that data is correct. Standards change without notice. It is the 

responsibility of the recipient to insure that their personnel have been notified of any changes which may affect 

them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as 

to the safe use of this product. User should refer to applicable laws before use. 

N/D = Not Determined N/E = Not Established N/A = Not Applicable



P.O. Box 220 


WD-40 





Canutec: (613) 996-6666 




PRODUCT NAME: WD-40 Bulk Liquid 



Page 1 of 4 

US Office: 

WD-40 Company 






Chemtrec: (800) 424-9300 




DANGER! Harmful or fatal if swallowed. Combustible Liquid. Avoid eye contact. Use with adequate ventilation. 

Keep away from heat, sparks and all other sources of ignition. 




INGESTION: This product has low oral toxicity. Swallowing may cause irritation, nausea, vomiting and diarrhea. 

This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis. 










64742-88-7 

45-50% 


64742-53-6 

64742-56-9 

64742-65-0 

30-35% 


Page 2 of 4 

WD-40 Bulk Liquid 

03/06/11 












breathing apparatus and full protective clothing. Cool fire-exposed containers with water. 

UNUSUAL FIRE/EXPLOSION HAZARDS: Combustible liquid and vapor. Vapors are heavier than air and may 

travel along surfaces to remote ignition sources and flash back. 



ventilate area. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill 

area thoroughly. Report spills to authorities as required. 




after handling. Keep containers closed when not in use. Keep out of the reach of children. 

STORAGE: Store away from heat, flames and incompatible materials. 



Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended 








Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. 



Respiratory Protection: None needed for normal use with adequate ventilation. 






Skin Protection: Wear chemical resistant gloves.

Page 3 of 4 


03/06/11 









Vapor Pressure: 1 psi @38 C (100 F) ASTM 

D323 

Vapor Density: Greater than 1 


Coefficient of Water/Oil 

Distribution: 

Not Determined Kinematic Viscosity: 2.79-2.96cSt @ 100 F 

Flash Point: 122 F (49°C) Tag Open Cup Flammable Limits: 


LEL: 0.6% UEL: 8.0% 




INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. 













regulations. 


U.S. DOT Hazard Classification: Excepted from Hazmat (49CFR 173.150 (F)) in non-bulk packagings. Bulk 

Packagings: Combustible Liquid, n.o.s. (contains Petroleum Distillates), NA1993, PG III 

Canadian TDG Classification: Not regulated as a dangerous good when packages in a small means of containment 

(See 1.33 Class 3, Flammable Liquids: General Exemption). 

IMDG Code Hazard Classification: UN1268, Petroleum Distillates, n.o.s. 3, PG III.



Page 4 of 4 


03/06/11 





Hazard Category For Section 311/312: Acute Health, Fire Hazard 





inventory. 




Canadian WHMIS Classification: Class B-3 (Combustible Liquid). 




HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 2 (moderate hazard), Physical Hazard – 0 












US Office: 

WD-40 Company 



WD-40 





Chemtrec: (800) 424-9300 – 




PRODUCT NAME: WD-40 Smart Straw Aerosol 



Page 1 of 4 

Canadian Office: 


P.O. Box 220 





Canutec: (613) 996-6666 – 




DANGER! Harmful or fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use 

with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. 




INGESTION: This product has low oral toxicity. Swallowing of the liquid contents may cause irritation, nausea, 

vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause 

chemical pneumonitis. 










64742-88-7 

45-50% 


64742-53-6 

64742-56-9 

64742-65-0 

30-35% 



Page 2 of 4 

WD-40 Aerosol 

03/13/10 












breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect 

against bursting containers. 

UNUSUAL FIRE/EXPLOSION HAZARDS: Contents under pressure. Aerosol containers may burst under fire 

conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 



ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain 

and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report 

spills to authorities as required. 




after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. 

Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out 

of the reach of children. 

STORAGE: Do not store above 120 F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. 



Aliphatic Petroleum Distillates 100 ppm TWA ACGIH TLV 

1200 mg/m3 TWA Manufacturer Recommended 





Carbon Dioxide 5000 ppm TWA, 30,000 ppm STEL ACGIH TLV 




Eye Protection: Avoid eye contact. Safety glasses or goggles recommended.

Page 3 of 4 

WD-40 Aerosol 

03/13/10 



Respiratory Protection: None needed for normal use with adequate ventilation. 






Skin Protection: Wear chemical resistant gloves. 









Vapor Pressure: 95-115 PSI @ 70 F Vapor Density: Greater than 1 


Coefficient of Water/Oil Not Determined Kinematic 2.79-2.96cSt @ 100 F 

Distribution: 

Flash Point: 122 F (49°C) Tag Open Cup 

(concentrate) 


Viscosity: 

Flammable Limits: 



LEL: 0.6% UEL: 8.0% 


INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. Do not puncture or incinerate 

containers. 













regulations.


U.S. DOT Hazard Classification: Consumer Commodity, ORM-D 

Canadian TDG Classification: Limited Quantity 

IMDG Code Hazard Classification: UN1950, Aerosols, 2.1. 



Page 4 of 4 

WD-40 Aerosol 

03/13/10 





Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure 





inventory. 




Canadian WHMIS Classification: Class B-5 (Flammable Aerosol). 




HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 
















by OSHA, NTP, or IARC as being a carcinogen or potential carcinogen. Use of this product may expose you or others to fumes and gases at levels 

exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational Safety and Health 

Administration (OSHA) The information contained herein relates only to the specific product. If the product is combined with other materials, all 

component properties must be considered. BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS. MATERIAL SAFETY DATA SHEETS ARE 

AVAILABLE FROM HARRIS PRODUCTS GROUP 513-754-2000 www.harrisproductsgroup.com 


To the best of the Harris Products Group knowledge, the information and recommendations contained in this publication are reliable and accurate as of the 

date prepared. However, accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied, 

is made by Harris Products Group. as to the absolute correctness or sufficiency of any representation contained in this and other publications; Harris 

Products Group. assumes no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this and 

other publications, or that other or additional measures may not be required under particular or exceptional conditions or circumstances . Data may be 

changed from time to time.. 



TRADE NAME (AS LABELED): HARRIS AMERICAN LFB / FC 

(formerly Welco 15 and Welco 15FC) 



PRODUCT USE: Metal Brazing 






DATE OF PREPARATION: July 20, 2010 

2. NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS 

These products consist of metal rods, some with a thin coating of flux on them. The exact amount of coating on each rod is unknown. It can be reasonably 

estimated that there is less than 1% of each of the flux constituents present on any given rod when compared to the mass of the rod itself. The composition 

values given for the flux coating are the composition of the flux when the rods are flux-coated. 




mg/m 3 

COMPONENT 1: METAL RODS 

Copper 

(exposure limits are 

for “Copper fume, as 

Cu”) 

7440-50-8 56 62 0.2 (fume) 

1 (dusts & 

mists) 

mg/m 3 

mg/m 3 

NE 0.1 

(fume) 

1 (dusts & 

mists) 

® 

mg/m 3 

mg/m 3 

mg/m 3 

NE 100 NIOSH REL: 

TWA = 0.1 

DFG MAK: 

TWA = 0.1 (Inhalable Fraction) 

PEAK = 2 MAK 30 min., average 

value 






PAGE 1 OF 9



2. NOMINAL COMPOSITION and INFORMATION ON INGREDIENTS (Continued) 


COMPONENT 1: METAL RODS (continued) 

Zinc 

Exposure limits given are 

for Zinc oxide, Fume & 

Dust 

ACGIH-TLV OSHA-PEL NIOSH OTHER 


mg/m 3 

7440-66-6 Balance 5 (fume) 

10 (dust) 

mg/m 3 

10 

(fume) 


PAGE 2 OF 9 

mg/m 3 

5 (fume) 

5 (total dust) 

15 (dust, 

respirable 

dust) 

5 (dust, 

respirable 

dust, 

Vacated 

1989 PEL) 

mg/m 3 

10 (fume, 

Vacated 

1989 PEL) 

mg/m 3 

mg/m 3 


TWA = 5 (fume & dusts) 

STEL = 10 (fume), 15 

(ceiling, 15 minutes, 

dusts) 

DFG MAKs: 

TWA = 1.5 (Respirable 

fraction, fume) 


Tin 7440-31-5 0.30-1.5 2 NE 2 NE 100 NIOSH REL: 2 

Manganese 


Manganese, elemental 

and inorganic 

compounds, and fume 

as Mn) 

Iron 


iron oxide dust and fume 

[Fe2O3], as Fe) 

7439-96-5 0.50 0.2 NE 1 (vacated 

1989 PEL) 

1309-37-1 1.0 5, A4 (Not 

Classifiable 

as a Human 

Carcinogen) 

Silicon 7440-21-3 0.50 10 NE 15 (Total 

dust) 

5 (Respirable 

fraction) 

10 (Total 

dust) 

(vacated 

1989 PEL) 

COMPONENT 2: FLUX COATING ON RODS 

5 (ceiling) 

3 (vacated 

1989 PEL) 


TWA = 1 

STEL = 3 

DFG MAK: 


Fraction) 


average value 





TWA = 5 

DFG MAK: 


Fraction) 


TLV-A4 


TWA = 10 (Total dust; 5 

(Respirable fraction) 

Boric Acid 10043-35-3 50-80 NE NE NE NE NE NE 

Methacrylate/Aliphatic & 

Naphthenic Hydrocarbon 

Compound 

Proprietary NE NE NE NE NE NE 

Borax Glass 

(the exposure limits are 

for Borates, anhydrous) 

1303-96-4 10-30 1 NE 10 (Vacated 

1989 PEL) 


TWA = 1 





accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.


EMERGENCY OVERVIEW: This product consists of bare or coated, odorless, solid bronze rods. There are no immediate 

health hazards associated with this product. This product is not flammable nor reactive. If involved in a fire, this product 

may generate irritating fumes and a variety of metal oxides. Emergency responders must wear personal protective 

equipment suitable for the situation to which they are responding. 


During brazing operations, the most significant route of overexposure 


INHALATION: Inhalation is not anticipated to be a significant route of 

over-exposure to the rods. Inhalation of large amounts of particulates 

generated by this product during metal processing operations may 

result in irritation. Inhalation of copper oxide and zinc oxide fumes 

can cause metal fume fever. Initial symptoms of metal fume fever 

can include a metallic or sweet taste in the mouth, dryness or 

irritation of the throat, and coughing. Later symptoms (after 4-48 

hours) can include sweating, shivering, headache, fever, chills, 

thirstiness, muscle aches, nausea, vomiting, weakness, and 

tiredness. Repeated over-exposures, via inhalation, to the dusts or 

fumes generated by this product during brazing operations may have 

adverse effects on the lungs with possible pulmonary edema and 

emphysema (life-threatening lung injuries). Chronic over-exposure to 

Copper dust may cause tiredness, stuffiness, diarrhea, and vomiting. 


specific composition of brazing fumes and gases. 

CONTACT WITH SKIN or EYES: Contact of the rod form of this 

product with the skin is not anticipated to be irritating. Rare cases of 

allergic contact dermatitis have been reported in people working with 

copper dust. Contact with the rod form of this product can be 

physically damaging to the eye (i.e., foreign object). Fumes 

generated during brazing operations can be irritating to the skin and 

eyes. Symptoms of skin over-exposure may include irritation and 

redness; prolonged or repeated skin over-exposures may lead to 

allergic contact dermatitis. Contact with the molten rods will burn 

contaminated skin or eyes. 


HEALTH 

FLAMMABILITY 

REACTIVITY 



See 

Section 8 

(BLUE) 

(RED) 

(YELLOW) 

For routine industrial applications for the rods 

0 

0 

0 

X 

See 

Section 8 



significant route of over-exposure for any component of this product. 

INGESTION: Ingestion is not anticipated to be a route of occupational exposure for this product. 




to this product and the fumes generated during brazing operations are as follows: 


and eyes when exposed to fumes during brazing operations. Inhalation of large amounts of particulates generated by this 

product during metal processing operations may result in irritation. Inhalation of copper oxide and zinc oxide fumes can 

cause metal fume fever. Inhalation of large amounts of particulates generated by this product during metal processing 

operations can result in pneumoconiosis (a disease of the lungs). Contact with the molten material will burn contaminated 

skin or eyes. Severe ingestion over-exposure to Copper (a component of this product) may be fatal. 

CHRONIC: Chronic skin over-exposure to the fumes of this product during brazing operations may produce dermatitis (red, 

inflamed skin). Chronic over-exposure to Copper dust may cause tiredness, stuffiness, diarrhea, vomiting, discoloration of 

the skin and eyes, and kidney and liver disorder. Additionally, rare cases of allergic contact dermatitis have been reported in 

people working with copper dust. Refer to Section 11 (Toxicological Information) for further information. 

TARGET ORGANS: For fumes: Skin, eyes, respiratory system, kidney and liver. 


PAGE 3 OF 9





SKIN EXPOSURE: If fumes generated by Brazing operations involving this product contaminate the skin, begin 



EYE EXPOSURE: If fumes generated by Brazing operations involving this product enter the eyes, open victim's eyes while 



INHALATION: If fumes generated by Brazing operations involving this product are inhaled, remove victim to fresh air. If 


INGESTION: Ingestion is not a likely route of exposure for the rods. If the flux is swallowed, CALL PHYSICIAN OR 

POISON CONTROL CENTER FOR THE MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless 

directed by medical personnel. Have victim rinse mouth with water if conscious. Never induce vomiting or give diluents 

(milk or water) to someone who is unconsciousness, having convulsions, or unable to swallow. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory disorders, pancreas and liver disorders may 

be aggravated by prolonged over-exposures to the dusts or fumes generated by these products. 



FLASH POINT: Not flammable. 


NFPA RATING 



FLAMMABILITY 


0 



HEALTH 0 0 



UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire, this 

product may generate irritating fumes and a variety of metal compounds. The 

molten material can present a significant thermal hazard to firefighters. 



SPECIAL FIRE-FIGHTING PROCEDURES: Not applicable for these products. 


SPILL AND LEAK RESPONSE: Not applicable 

OTHER 



REACTIVITY 




Wash thoroughly after handling this product. Do not eat or drink while handling this product. Use in a well ventilated 

location. Use ventilation and other engineering controls to minimize potential exposure to this product. 


Avoid breathing fumes of this product during brazing operations. Open containers on a stable surface. Packages of this 

product must be properly labeled. When this product is used during brazing operations, follow the requirements of the 

Federal Occupational Safety and Health Welding and Cutting Standard (29 CFR 1910 Subpart Q) and the safety standards 

of the American National Standards Institute for welding and cutting (ANSI Z49.1). 


PAGE 4 OF 9

7. HANDLING and STORAGE (Continued) 

STORAGE AND HANDLING PRACTICES (continued): Store packages in a cool, dry location. Storage in an atmosphere 

that is wet, moist, or highly humid may lead to corrosion of this product. Store away from incompatible materials (see 

Section 10, Stability and Reactivity). 

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Not applicable. 






(Composition and Information on Ingredients). If respiratory protection is needed (i.e., a Weld Fume Respirator or Air-Line 

Respirator for brazing in confined spaces), use only protection authorized in 29 CFR 1910.134 or applicable State 

regulations. Respiratory Protection is recommended to be worn during brazing operations. Use supplied air respiration 

protection if oxygen levels are below 19.5% or are unknown. The following are NIOSH recommendations for respirator 

selection for welding fumes (which would also be applicable for brazing operations), based on NIOSH REL: 

CONCENTRATION RESPIRATORY EQUIPMENT FOR WELDING FUMES 

At Concentrations above the NIOSH REL, or where there is no REL, at any Detectable Concentration: Any self-contained 

breathing apparatus that has a full facepiece and is operated in a pressure-demand or other 

positive-pressure mode; or any supplied-air respirator that has a full facepiece and is operated in 

a pressure-demand or other positive-pressure mode in combination with an auxiliary selfcontained 

breathing apparatus operated in pressure-demand or other positive-pressure mode. 

Escape: Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted 

organic vapor canister having a high-efficiency particulate filter; or any appropriate escape-type, 

self-contained breathing apparatus 

NOTE: IDLH Concentration: Potential NIOSH carcinogen. [Not determined yet]. 

EYE PROTECTION: Safety glasses. When these products are used in conjunction with Brazing, wear safety glasses, 

goggles, or face-shield with filter lens of appropriate shade number (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). 

If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian Standards. 

HAND PROTECTION: Wear gloves for routine industrial use. When these products are used in conjunction with Brazing, 

wear gloves that protect from sparks and flame (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). If necessary, refer 

to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada. 

BODY PROTECTION: Use body protection appropriate for task. If a hazard of injury to the feet exists due to falling objects, 

rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical 

hazards, as described in U.S. OSHA 29 CFR 1910.136. 


The following information is for Copper, a main component of this product, unless otherwise indicated: 


SPECIFIC GRAVITY (water = 1): 8.3-8.5 g/cc (For product) pH: Not applicable. 



FREEZING/MELTING POINT: 1600-1900°C (871-1038°F) [For product] 


The following information is for Zinc, a main component of this product: 


SPECIFIC GRAVITY (water = 1): 7.14 pH: Not applicable. 



FREEZING/MELTING POINT: 149°C (786°F) 

COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable 


APPEARANCE AND COLOR: This product consists of bare or coated, odorless bronze rods. 

HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinctive characteristic of this 

product. 


PAGE 5 OF 9



DECOMPOSITION PRODUCTS: Thermal decomposition products can include copper and zinc compounds and a variety of 

metal oxides. 

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids, strong oxidizers, some halogenated 

compounds. 


CONDITIONS TO AVOID: Uncontrolled exposure to extreme temperatures, incompatible materials. 






BORIC ACID: 

Skin Irritancy (human) = 15 mg/ 3 days/ 


LD (oral, human) = 37 mg/kg/ boron as boric acid 

LD (skin, infant) = 210 mg/kg/ boron as boric acid 

TDLo (oral, child) = 500 mg/kg; gastrointestinal 

effects 

LDLo (oral, man) = 429 mg/kg; cardiovascular, 

systemic effects 

LDLo (oral, woman) = 200 mg/kg 

BORIC ACID (continued): 

TDLo (oral, infant) = 800 mg/kg/ 4 weeks/ 

intermittent 

LDLo (oral, infant) = 934 mg/kg 

LDLo (skin, infant) = 1200 mg/kg 

LDLo (skin, child) = 4000 mg/kg/ 4 days 

LDLo (skin, man) = 2430 mg/kg 

LDLo (skin, child) = 1500 mg/kg 

LDLo (subcutaneous, infant) = 1100 mg/kg 

TDLo (unreported, man) = 170 mg/kg; 

gastrointestinal effects 

LDLo (unreported, man) = 147 mg/kg 

COPPER: 

TDLo (oral, human) = 120 g/kg; gastrointestinal 

tract effects 

ZINC: 

Skin Irritancy (human) = 300 g/ 3 days/ 


TCLo (inhalation, human) = 124 mg/m 3 / 50 

minutes; pulmonary system, skin effects 


MANGANESE: EPA-D, Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available). 

COPPER: EPA-D, Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available). 



IRRITANCY OF PRODUCT: This product’s dusts or fumes may be irritating to contaminated skin and eyes. Fumes may be 


SENSITIZATION TO THE PRODUCT: Rare cases of allergic contact dermatitis have been reported in people working with 

copper dust. 



Mutagenicity: This product is not reported to produce mutagenic effects in humans. Animal mutation data are available 

for the Boric Acid component of this product; these data were obtained during clinical studies on specific animal tissues 

exposed to high doses of this compound. 



exposed to relatively high doses of the Copper component of this product indicate teratogenic effects. 


animals exposed to relatively high doses of the Boric Acid and Copper components of this product indicate adverse 

reproductive effects. 






BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) associated with the 


MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory disorders, kidney and liver disorders may be 




PAGE 6 OF 9



ENVIRONMENTAL STABILITY: The components of this product are expected to persist in the environment for an extended 

period of time. Copper and Zinc will react with water and air to form a variety of stable oxides. Additional environmental data 

are available as follows: 

ZINC: Solubility: Insoluble in water. Biological Half-Life for normal humans 162-500 days. Bioconcentration: The Bioconcentration Factor in edible 

portions of Crassostrea virgina, adult oyster) is 16,700 (total zinc). 

COPPER: Solubility: Insoluble. There is no evidence of any biotransformation for copper compounds. Copper is accumulated by all plants and animals. 

BCF Algae = 12; plants = 1,000; invertebrate = 1,000, fish = 667 and fish =200(Soluble copper salts). 

EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not expected to cause adverse effects on plant or 

animal life. Specific data on test animals are available but are not presented in this Material Safety Data Sheet. 

EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may cause adverse effects on aquatic life. Additional 

environmental data are available as follows: 

BORIC ACID: 

LC50 (trout eggs) = 100 ppm/ soft 

LC50 (trout eggs) = 79 ppm/ hard 

LC50 (catfish eggs) = 155 ppm/ soft 

LC50 (catfish eggs) = 22 ppm/ hard 

LC50 (goldfish eggs) = 46 ppm/ soft 

LC50 (goldfish eggs) = 75 ppm/ hard 

LC50 (Daphnia magna) = 133 mg/L/ 48 hours 

COPPER: Copper is concentrated by plankton by 1000 or more. Copper 

may concentrate to toxic levels in the food chain. 

ZINC: Odorless zinc poisoning causes inflamed gills in fish. Laboratory 

studies of Atlantic salmon, rainbow trout, carp, and goldfish have shown 

avoidance reactions by these fish to zinc in water. 





EPA WASTE NUMBER: Not applicable to waste consisting only of this product. 


THIS PRODUCT IS NOT HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION. 









TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not considered 








SARA 304 

(40 CFR Table 302.4) 

SARA 313 

(40 CFR 372.65) 



Zinc No Yes Yes (fume or dust) 





U.S. CERCLA REPORTABLE QUANTITY (RQ): Copper = 5000 lbs; Zinc = 1000 lbs. (for metal particles under 100 

micrometers in diameter). 


PAGE 7 OF 9








Manganese, Tin. 


Chemical Contaminants: Copper, Manganese, 

Silicon, Tin. 


Mist, Manganese, Tin, Zinc. 


Manganese, Silicon, Zinc. 


Manganese, and Zinc. 


Manganese, Tin, Zinc. 

Michigan-Critical Materials Register: Copper. 


Copper Dust & Mists, Manganese, Silicon, Tin. 


Substance List: Copper, Manganese, Silicon, 

Tin. 


Substance List: Copper, Manganese, Tin, Zinc. 


Reportable Quantities: Copper, Zinc. 


Copper, Manganese, Silicon, Tin, Zinc. 


Copper Fume, Dust, & Mist, Manganese, 

Silicon, Tin, Zinc. 








product may contain chemicals, and when used for welding or brazing may produce fumes or gases containing 

chemicals, known to the State of California to cause cancer, and/or birth defects (or other reproductive harm.) 

LABELING (Precautionary Statements): CAUTION! 

WARNING: PROTECT yourself and others. Read and understand this information. 







general area. 







CANADIAN DSL/NDSL INVENTORY STATUS: The components of these products are on the DSL Inventory. 


CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No components are on 

the CEPA Priority Substance Lists. 





858/565-0302 

DATE OF PRINTING: August 26, 2010 





guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by Harris Products Group. as to the absolute correctness or 

sufficiency of any representation contained in this and other publications; J.W. Harris Co., Inc. assumes no responsibility in connection therewith; nor 




PAGE 8 OF 9






professional association which establishes exposure limits. TLV - 

Threshold Limit Value - an airborne concentration of a substance, which 

represents conditions under which it is generally believed that nearly all 

workers, may be repeatedly exposed without adverse effect. The duration 

must be considered, including the 8-hour Time Weighted Average (TWA), 

the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling 

Level (C). Skin absorption effects must also be considered. 


PEL - Permissible Exposure Limit - This exposure value means exactly 

the same as a TLV, except that it is enforceable by OSHA. The OSHA 

Permissible Exposure Limits are based in the 1989 PELs and the June, 

1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 

40191). Both the current PELs and the vacated PELs are indicated. The 

phrase, “Vacated 1989 PEL,” is placed next to the PEL, which was 

vacated by Court Order. IDLH - Immediately Dangerous to Life and 

Health - This level represents a concentration from which one can escape 

within 30-minutes without suffering escape-preventing or permanent 

injury. The DFG - MAK is the Republic of Germany’s Maximum Exposure 

Level, similar to the U.S. PEL. NIOSH is the National Institute of 

Occupational Safety and Health, which is the research arm of the U.S. 

Occupational Safety and Health Administration (OSHA). NIOSH issues 

exposure guidelines called Recommended Exposure Levels (RELs). 

When no exposure guidelines are established, an entry of NE is made for 

reference. 


HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health 

Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or 

chronic exposure hazard); 2 (moderate acute or significant chronic 

exposure hazard); 3 (severe acute exposure hazard; onetime 

overexposure can result in permanent injury and may be fatal); 4 

(extreme acute exposure hazard; onetime overexposure can be fatal). 

Flammability Hazard: 0 (minimal hazard); 1 (materials that require 

substantial pre-heating before burning); 2 (combustible liquid or solids; 

liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC 

flammable liquids with flash points below 38 C [100 F]); 4 (Class IA 

flammable liquids with flash points below 23 C [73 F] and boiling points 

below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material 

that can become unstable at elevated temperatures or which can react 

slightly with water); 2 (materials that are unstable but do not detonate or 

which can react violently with water); 3 (materials that can detonate when 

initiated or which can react explosively with water); 4 (materials that can 

detonate at normal temperatures or pressures). 

NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 

(material that on exposure under fire conditions would offer no hazard 

beyond that of ordinary combustible materials); 1 (materials that on 

exposure under fire conditions could cause irritation or minor residual 

injury); 2 (materials that on intense or continued exposure under fire 

conditions could cause temporary incapacitation or possible residual 

injury); 3 (materials that can on short exposure could cause serious 

temporary or residual injury); 4 (materials that under very short exposure 

causes death or major residual injury). Flammability Hazard and 

Reactivity Hazard: Refer to definitions for “Hazardous Materials 

Identification System”. 

FLAMMABILITY LIMITS IN AIR: 

Much of the information related to fire and explosion is derived from the 

National Fire Protection Association (NFPA). Flash Point - Minimum 

temperature at which a liquid gives off sufficient vapors to form an 

ignitable mixture with air. Autoignition Temperature: The minimum 

temperature required to initiate combustion in air with no other source of 

ignition. LEL - the lowest percent of vapor in air, by volume, that will 

explode or ignite in the presence of an ignition source. UEL - the highest 

percent of vapor in air, by volume, that will explode or ignite in the 


TOXICOLOGICAL INFORMATION: 

Human and Animal Toxicology: Possible health hazards as derived 

from human data, animal studies, or from the results of studies with 

similar compounds are presented. Definitions of some terms used in this 

section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the 

exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of 

the exposed animals; ppm concentration expressed in parts of material 

per million parts of air or water; mg/m 3 concentration expressed in weight 

of substance per volume of air; mg/kg quantity of material, by weight, 

administered to a test subject, based on their body weight in kg. Other 

measures of toxicity include TDLo, the lowest dose to cause a symptom 

and TCLo the lowest concentration to cause a symptom; TDo, LDLo, 

and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) 

to cause lethal or toxic effects. Cancer Information: The sources are: 

IARC - the International Agency for Research on Cancer; NTP - the 

National Toxicology Program, RTECS - the Registry of Toxic Effects of 

Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate 

chemicals on a scale of decreasing potential to cause human cancer with 

rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other 

Information: BEI - ACGIH Biological Exposure Indices, represent the 

levels of determinants which are most likely to be observed in specimens 



Ecological Information: EC is the effect concentration in water. BCF = 

Bioconcentration Factor, which is used to determine if a substance will 

concentrate in lifeforms which consume contaminated plant or animal 

matter. Coefficient of Oil/Water Distribution is represented by log Kow 

or log Koc and is used to assess a substance’s behavior in the 

environment. 

REGULATORY INFORMATION: 


material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is 

the U.S. Department of Transportation. SARA is the Superfund 

Amendments and Reauthorization Act. TSCA is the U.S. Toxic 

Substance Control Act. CERCLA (or Superfund) refers to the 

Comprehensive Environmental Response, Compensation, and Liability 

Act. Labeling is per the American National Standards Institute (ANSI 

Z129.1). CANADA: CEPA is the Canadian Environmental Protection 

Act. WHMIS is the Canadian Workplace Hazardous Materials 

Information System. TC is Transport Canada. DSL/NDSL are the 

Canadian Domestic/Non-Domestic Substances Lists. The CPR is the 

Canadian Product Regulations. This section also includes information 

on the precautionary warnings, which appear, on the materials package 

label. 


PAGE 9 OF 9


Reference – MSDS 

Date – June 2009 

1. PRODUCT IDENTIFICATION & COMPANY INFORMATION 

Product name: 

Various grades of welding and metal spraying consumable carrying the trademarks 

DURANICKEL, INCOLOY, INCONEL, INCO-CORED, INCO-WELD, 

MONEL, Nickel, NILO, NIMONIC, NI-ROD, INCOFLUX 

Full list given in tables 2.1-.2.4 

Other/generic names: 

Product use: 

Filler Metal, Flux, Flux Cored, Welding Electrode, Weldstrip, & Thermal Spray (TSW) 

Welding & metal spraying consumables, See applicable product technical data sheets on website 

for information of typical scope of use and application, not all products are suitable for all processes 

or applications. 

Filler Metal Used for joining and overlaying, using GTAW, GMAW, Plasma and SAW (with suitable 

flux) welding processes 

Flux Cored Used for joining and overlaying, using GMAW welding processes 

Welding Electrode Used for joining and overlaying, using SMAW welding process 

Weldstrip Used for overlaying, (with suitable flux) for submerged arc or electroslag welding 

process 

INCOFLUX Flux used for joining or overlaying with appropriate filler metal or weldstrip for 

submerged arc or electroslag welding process 

Thermal Spray(TSW) Used to apply nickel alloy coating by a variety of thermal spray process 

Manufacturer: 

1401 Burris Road, Newton, 

North Carolina 28658 

United States 

For more information Tel +1 828-465-0352 

Fax +1 828-464-8993 

Email info@smwpc.com 

Special Metals Welding Products Company 

c /o Special Metals Wiggin Ltd 

Wiggin Works, Holmer Road, 

Hereford, UK, HR4-9SL 

Tel +44 (0)1432 382200 

Fax +44 (0)1432 264030 

Email sales.uk@smwpc.com 

www.specialmetalswelding.com 

Emergency telephone +1 828-465-0352 +44 (0)1432 382200 


Information on ingredients is given in Table 1 and the compositions of individual products in the alloy families or categories listed 

above are given in the product composition tables 2.1-2.4. Please refer to the appropriate alloy name or designation. 


EMERGENCY OVERVIEW: Silver to gray metal wire or strip. (Welding Electrode are flux coated, Flux Cored has a flux 

center; flux is granular powder). Not normally considered hazardous as shipped. Ends and edges can be sharp and gloves 

should be worn when handling. 

POTENTIAL HEALTH HAZARDS 

Skin: Although not normally hazardous, some individuals can develop allergic skin reactions to nickel and other 

metallic ingredients. Ends of wire and edges of strips may be sharp and can cause cuts. 

During welding and spraying - Fumes generated may be irritating to the skin. UV radiation produced can 

cause burns (ray burn). Hot metal can cause burns. 

Eyes: As shipped, product does not pose a hazard to the eyes however ends of wire and edges of strip are sharp 

and can cause cuts. 

During welding and spraying - Fumes generated can be irritating to the eye. Ends of wire may be sharp and 

can cause cuts or hot and cause burns. UV radiation produced can cause burns (arc eye). 

www.specialmetalswelding.com Page 1 of 11

Inhalation: Fumes generated by welding and spraying processes can be irritating and toxic. 

Ingestion: Not a likely route of entry. Metal ingestion can cause toxic effects. 




Delayed effects: Inhalation of welding or spraying fumes may cause damage to the lungs and respiratory tract including but 

not limited to fibrosis of the lung which can reduce lung capacity and produce difficulty breathing. Cobalt and 

Nickel are animal carcinogens and inhalation of fumes and dusts should be avoided. Prolonged inhalation 

of Manganese fumes and dusts may cause irreversible damage to the nervous system resulting in 

Parkinson’s Disease-like symptoms (tremors, weakness, paralysis, etc.) 

Nickel Cobalt 

EC Label No 231-111-4 231-158-0 

Index No 028-002-00-7 028-001-00-9 

Designation: Xn Harmful Xn Harmful 

Risk Phrases: R40 Possible risk of irreversible effects 

R43 May cause sensitization by skin contact 

R42/43 May cause sensitization by inhalation and 

skin contact 

R53 May cause long-term adverse effects in 

aquatic environments 


Skin: Wash skin with soap and water to remove any metallic particles. If a rash or burn develops, seek medical 

attention. 

Eyes: Flush particles from eyes with clean water for at least 15 minutes. If irritation persists or burn develops, 

seek medical attention. 

Inhalation: Remove from exposure. If respiratory irritation persists, seek medical attention. 

Ingestion: If metallic particles are swallowed, seek medical assistance. 

Advice to physician: Treat symptomatically. 


FLAMMABLE PROPERTIES 

Flash Point & Method Solid material – No flash point 

Autoignition Temperature: Not flammable 

Flame Propagation Rate (solids): Not flammable 

OSHA Flammability Class: None – solid material 

Extinguishing Media: Use agent appropriate for surrounding fire. 

Unusual Fire And Explosion Hazards: None 

Special Fire Fighting Precautions/Instructions: Wear self-contained breathing apparatus. Hazardous metallic fumes can be 

generated in a fire. 

Nonflammable except for packaging, however sparks from welding or grinding in user operations could ignite flammable or 

combustible liquids, vapors and solids. 


IN CASE OF SPILL OR OTHER RELEASE: Wear proper protective clothing. Pick up spilled articles and place into container. 


Normal Handling: Under normal circumstances the materials do not produce any hazardous products and as such 

do not require any special precautions. However, see Section 10 "STABILITY AND 

REACTIVITY". The transient handling of the materials would not be expected to produce any 

sensitization but it is good practice to use gloves for handling. The normal precautions for 

handling heavy objects with possible sharp edges should also be observed. 

Personal hygiene - Apply good standards, wash hands after use and before eating. 



Storage Recommendations: Store in a dry place and protect from contamination with other materials. 




ENGINEERING CONTROLS: Provide general ventilation and local exhaust ventilation when welding, spraying, cutting or 

grinding to maintain concentrations of metal dusts and/or fumes below allowable exposure values. 

Maintain exposures below the published exposure levels. Use industrial hygiene air monitoring to ensure that your use of this 

material does not create exposures that exceed the recommended exposure limits. Refer to the following sources for important 

additional information: 

In U.S.A.: 29 CFR 1910, ANSI Z49.1, American Welding Society, OSHA, U.S. Dept of Labor 

In Canada: Canadian Standards Association, CAN/CSA - W17.2-M87 

In UK: Current exposure limits under Health & Safety Executive EH40 are given in table 2. 

PERSONAL PROTECTIVE EQUIPMENT 

Skin Protection: Wear gloves, face protection and flame retardant clothing, do not expose skin to the heat, 

radiation and spatter from welding or spraying operations. 

Eye Protection: Eye protection, to the appropriate national standard, is recommended when welding, cutting, 

spraying or grinding. Do not expose eyes to the heat and radiation from welding operations, 

use appropriate grade optical filters (welding glass) for welding or spraying process 

operations. 

Respiratory Protection: Respiratory protection is necessary when exposure limits for airborne contaminants are 

exceeded during welding, grinding or cutting operations. Use air-supplied respirator in 

confined spaces. 

In the USA, use only NIOSH-approved respirators in accordance with 29 CFR 1910.134, or 

other nationally approved respirators. 

In the EU, if required use protection to EN136 (full face respirators), EN140 (half mask 

respirators), EN149 (filtered half masks (disposable)) or other appropriate EN standard. In 

the rest of the world use respiratory protection to the appropriate national standard. 

Additional Recommendations: Source of running water to wash skin and eyes 

Wear ear protection to the appropriate national standards where high levels of noise are 

experienced. 

Exposure Guidelines See Appendix 1 


Filler Metal, Weld 

Strip and Thermal 

Spray Wire 

Appearance: Grey to silver or 

bronze metal 

Welding Electrode Flux Cored Wire Flux 

Varies grey, black, 

brown coating with 

metallic silver inner 

Metallic silver outer 

with flux core 

Varies grey, brown, 

green particles 

Physical State: Solid Solid Solid Solid (Powder) 

Molecular Weight: Mixture Mixture Mixture Mixture 

Chemical Formula: Mixture Mixture Mixture Mixture 

Odor: Odorless Odorless Odorless Odorless 

Specific Gravity (water = 1.0): 8 – 9 4-7 5 - 8 

Bulk Density 

0.8 – 1.1 

Solubility In Water (wt. %): Insoluble Insoluble Insoluble Insoluble 

Melting Point: > 2300F (1260 ºC) > 1800F (>1000 o C) > 1800F (>1000 o C) > 1800F (>1000 o C) 

Flash Point None None None None 

Other physical and chemical properties, e.g. as described in 91/155/EEC and in the Approved Code of Practice, ref. 11, have no 

safety implications in relation to these materials. 


These consumables are stable and no hazardous decomposition products are formed upon exposure to water or the atmosphere. 

Nickel can react with carbon monoxide in reducing atmospheres to form nickel carbonyl, an extremely toxic gas. 






Nickel and cobalt are classified as Category 3 carcinogens. The exposure route of concern is inhalation. 

As shipped, these complex alloys in massive form have no known toxicological properties other than causing allergic reactions in 

individuals sensitive to the metal(s) contained in the alloys. However, dust from flux or user-generated dusts and fumes may on 

contact with the skin or eyes produce mechanical irritation. Chronic exposures coupled with sweat could cause dermatitis (skin) or 

conjunctivitis (eyes). 

Excessive inhalation of dust or user-generated fumes from welding or metal spraying may, depending on the specific features of 

the process used, pose a long-term health hazard. The International Agency for Research on Cancer (IARC) has concluded that 

welding fumes are possibly carcinogenic to humans. 

The ingredients of fumes and gases generated in welding, metals spraying and grinding will depend on the base metal and the 

details of the specific process being used. Ingredients may include metals, metal oxides, chromates, fluorides, carbon monoxide, 

ozone, and oxides of nitrogen. Phosgene can be produced if chlorinated solvent vapors are present in user operations. 

More detailed toxicological information is given in APPENDIX 1 

Composition of typical welding fume given in table 3.1 – 3.7, 

Contamination or surface preparations etc can affect the composition of the produced fume. 

Metals Spraying - Many variations of process are available; refer to table 2.1 in association with guidance from equipment 

manufacturers for likely constituents of produced fume. 

DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS: 

Chromium The International Agency for Research on Cancer (IARC) considers hexavalent chromium to be a carcinogen 

(lung, nasal) but does not have adequate evidence for chromium metal and trivalent chromium. Fumes have 

been associated with lung fibrosis. 

Iron Prolonged inhalation of iron oxide fumes can lead to siderosis, which presents as a benign pneumoconiosis. 

Molybdenum Repeated inhalation of fumes has caused kidney damage, respiratory irritation and liver damage in animals. 

Nickel Nickel metal is “reasonably anticipated to be a human carcinogen” (National Toxicology Program’s 10 th 

Report). IARC states that nickel metal is possibly carcinogenic to humans. Epidemiological studies of workers 

exposed to nickel powders, dusts and fumes in the nickel alloy and stainless steel producing industries do not 

indicate a significant respiratory cancer hazard. 

Inhalation of nickel powder produced malignant tumors in rodent studies. Single intratracheal installations of 

nickel powder at levels close to the LD50 have caused malignancies in hamsters. 

Can cause skin sensitization in susceptible individuals through prolonged contact with skin. 

Niobium No data available. 


As a solid metal object, Filler Metal products are not considered toxic to aquatic species. 

Flux (being of mineral constituents) from flux coated electrodes, flux cored wire and flux may degrade over time. 

Observe national and local standards for fume extraction systems 


Unused consumable wastes are normally collected to recover metal values. 

Dispose of fume, flux, slag, weld grinding residues, over-spray etc, from the work area, or from filters, in accordance with national, 

federal, state or local regulations. Refer to this MSDS, Table 3.1-3.7, for possible contents of collected fumes and other materials. 

These may be in the form of dust requiring special health precautions. Nickel is regulated in many countries as hazardous to the 

environment. Other metals may be regulated in specific jurisdictions. In UK most alloyed material would be regarded as special 

waste. Observe all National, State, and local environmental regulations. 

Packaging - Dispose of by recycling 


No special precautions are necessary for the transport of these materials. 


Classification and labelling requirements 

Alloys containing less than 1% of nickel or cobalt are not classified as "dangerous for supply". Alloys containing more than 1% of 

either metal are classified as the metals themselves (see Section 3). However, in recognition of their essentially non-hazardous 

nature, these alloys in the massive form are not required to be labelled as hazardous. 


Product Labeling - UK Manufacture 




WARNING: PROTECT YOURSELF AND OTHERS. READ AND UNDERSTAND THIS LABEL. TAKE PRECAUTIONS WHEN WELDING. ASK FOR YOUR EMPLOYER’S 

SAFETY PRACTICES WHICH SHOULD BE BASED ON MANUFACTURER’S HAZARD DATA 

Fumes and gases can be dangerous to your health. Arc rays can injure eyes and burn skin. Electric shock can kill. Read and understand the manufacturer’s instructions 

and your employer’s safety practices. Keep your head out of the fumes. Use enough ventilation or exhaust at the arc to keep fumes and gases from your breathing zone, 

and the general area. Wear correct eye, ear and body protection. Do not touch live electrical parts. 

DO NOT REMOVE THIS LABEL 

Product Labeling – USA Manufacture 

PROTECT YOURSELF AND OTHERS – READ AND UNDERSTAND THIS LABEL – TAKE PRECAUTIONS WHEN WELDING – ASK FOR YOUR EMPLOYER’S SAFETY 

PRACTICES WHICH SHOULD BE BASED ON MANUFACTURERS HAZARD DATA AVAILABLE TO HIM 

Fumes and gas as can be dangerous to your health. Arc rays can injure eyes and burn skin. Electric shock can kill. Read and understand the manufacturer’s instructions 

and your employers safety practices. Keep your head out of the fume. Use enough ventilation, exhaust at the arc or both, to keep fumes and gases from your breathing 

zone, and the general area. Wear correct eye ear and body protection. Do not touch live electrical parts. See WMA publication 236 hazards from welding fume available 

from the manufacturer. 


- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 

WARNING POSSIBLE CANCER HAZARD OR LUNG DAMAGE IF INHALED – MAY CAUSE ALLERGIC REACTION – MAY CONTAIN FLUORIDES 

PROTECT YOURSELF AND OTHERS – before use, read and understand this label, the manufacturer’s instructions, Material Safety Data Sheets [MSDS’s], and your 

employer’s safety practices, which should be based on the manufacturer’s hazard data available to him. See American National Standard Z49.1, Safety in Welding and 

Cutting and OSHA Safety and Health Standards 29CFR1910. 

FUMES AND GAS can be dangerous to your health. Skin sensitization, irritation of skin, eye and respiratory tract, neurological damage, or death can result from over 

exposure. Keep your head out of the fumes. Use ventilation, preferably local exhaust ventilation, adequate to keep the concentration of the fumes and gases below the 

exposure limits. Special attention to ventilation is required in confined, small or crowded spaces. If adequate ventilation is not available, wear appropriate respiratory 

protection. Wash skin after contact with dust or fumes. 

Arc rays can injure eyes and burn skin. Electric shock can kill. Do not touch live electrical parts. Wear correct eye, ear and body protection 


SARA SECTION 313 SUPPLIER NOTIFICATION: 

Individual consumables covered by this MSDS may contain the following toxic chemicals subject to the reporting requirements of 

Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: Chromium, Copper, 

Manganese, and Nickel. Refer to “Section 2” of this MSDS for the filler metal name and the percent by weight, and “Table 1” for 

the CAS Number for each chemical. 


Current Issue Date: June 2009 

Previous Issue Date: None 

Changes to MSDS From Previous Issue Are Due To: Change of format which includes additional information 

MSDS prepared by Special Metals technical department in compliance with directive 91/115/EEC, 93/112/EEC and HSE (UK) 

Welding Information Sheet No.1 and is provided in good faith based upon the experience and knowledge of the company. It 

should not be taken as a guarantee of alloy properties for ordering these materials. Users should make their own assessment of 

workplace risks as required by other health and safety legislation 

Trademarks DURANICKEL©, INCOLOY©, INCONEL©, INCOFLUX©, INCO-WELD©, MONEL©, NILO©, NIMONIC©, NI-ROD©, 

686CPT© & 725NDUR© are trademarks of the Special Metals Group of Companies 

Bibliography: 

1. U.S. National Toxicology Program - 10th Report On Carcinogens 

2. Health and Safety Executive UK - EH40 - Occupational exposure limits; EH42 - Monitoring Strategies for toxic substances; 

EH44 - Dust the Workplace - general principles of protection; EH54 - Assessment of Exposure to Fume from Welding and 

Allied Processes; EH55 - The Control of Exposure to Fume from Welding, Brazing and Similar Processes; EH60 - Nickel and 

its inorganic compounds. 

3. EH Health and Safety Executive's publications (www.hse.gov.uk) 

4. HSC. Information approved for the classification, packaging and labeling of dangerous substances for supply and 

conveyance by road. 





5. European Commission Directive 5/3/91 - 91/155/EEC. 

6. European Commission Directive 10/12/93 - 93/112/EEC. 

7. Twelfth adaptation of Council Directive 67/548/EEC - 91/325/EEC. 

8. Sixth amendment of Council Directive 67/548/EEC - 79/831/EEC. 

9. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 No. 1689. 

10. International Agency for Research on Cancer. Monographs on the evaluation of carcinogenic risks to humans. Vol 49 

Chromium Nickel and Welding, 1990. 

11. Approved Code of Practice. ISBN 0 7176 0859X. 

12. European Norm - EN 1811. 

Table 2.1 

Nominal Composition (Weight %) Of 

Filler Metal, Thermal Spray Wires and Weldstrips Covered By This MSDS 

Trade Name Al Cr Co Cu Fe Mn Mo Ni Nb Si Ti W 

DURANICKEL ® 301 & 301TSW 

INCOLOY 

4 - - - - - - 94 - 1 1 - 

® 65 

INCONEL 

- 21 - 2 30 1 3 42 - - 1 - 

® 52 

INCONEL 

Table 2.3 

Composition Of Flux-Cored Welding Wires Covered By This MSDS 


Weight % Ca0 CaF2 C Cr Fe Mn MnO Mo NaAlF6 Na2O Nb Ni SiO2 TiO2 K2ZrF6 ZrO2 

INCO-CORED© 625 AP 1-5 15-20 1-5 5-10 1-5 1-5 50-60 0.1-0.5 5-10 

INCO-CORED© 625 DH 1-5 15-20 1-5 5-10 1-5 1-5 50-60 0.1-0.5 5-10 

INCO-CORED© 82 AP 15-20 1-5 1-5 1-5 57-63 0.1-0.5 5-10 

INCO-CORED© 82 DH 15-20 1-5 1-5 1-5 1-5 1-5 57-63 0.1-0.5 5-10 1-5 1-5 

NI-ROD© FC55 7-13 1-5 30-60 1-5 1-5 30-60 



Table 2.4 

Composition Of Flux Covered By This MSDS 

Product Name Al2O3 CaF2 CaO Cr2O3 MgO Mn MnO Nb Ni K2SiO3 K2O SiO2 NaAlF6 TiO2 ZrO2 K2ZrF6 NaF Others 

INCOFLUX® 4 60-100 1-5 1-5 1-5 1-5 3-7 1-5 

INCOFLUX® 5 60-100 10-30 1-5 1-5 3-7 

INCOFLUX® 6 15-40 40-70 3-7 1-5 1-5 3-7 3-7 

INCOFLUX® 7 15-40 40-70 1-5 1-5 3-7 5-20 Fe3O4 1-5 

INCOFLUX® 8 60-100 10-30 1-5 1-5 3-7 Fe3O4 1-5 

INCOFLUX® 9 1-5 15-20 28-33 2-6 28-33 4-8 

INCOFLUX® 10 85-95 CaTiO3 

INCOFLUX® ESS1 10-15 65-80 10-15 3-8 3-7 1-5 1-5 1-5 1-3 1-5 3-7 Cr 1-5 

INCOFLUX® ESS2 5-10 65-80 3-8 3-7 2-7 1-5 1-5 1-5 1-5 2-7 2-7 1-6 1-6 Cr 1-5 

INCOFLUX® ESS3 20-40 45-70 5-15 

INCOFLUX® ESS4 5-10 65-80 5-10 3-7 2-7 1-5 1-5 1-5 2-7 1-6 Cr 1-5 

INCOFLUX ® NT100 15-40 40-70 3-7 1-5 1-5 3-7 3-7 

INCOFLUX Cu 0-5 

Na20 0-5 

® NT110 30-70 10-40 0-20 5-20 0-10 0-10 

Na2Si4O9 5-20 

INCOFLUX ® NT120 26-33 30-35 0-5 2-4 1-5 1-5 2-4 4-7 8-13 1-6 CaSiO3 1-5 

Cr 0-5 

Fe 1-6 

Mo 1-6 

Na2O 2-4 

Na2Si4O9 1-6 

INCOFLUX CaCO3 0-10 

Na2O 0-5 

® SAS1 30-70 10-40 0-10 0-5 0-5 5-20 0-10 0-10 

Na2Si4O9 5-20 

INCOFLUX ® SAS2 35-45 35-45 2-8 5- 

1-5 CaSiO3 5-15 

10 

Cr 2-6 

CaTiO3 5-15 

www.specialmetalswelding.com Page 7 of 11 

NiMg 

1-5 

1-5

Table 2.5 - Nominal Composition (Weight %) Of 

Stainless Steel Filler Metal Covered By This MSDS 


Aluminum Filler Metal Covered By This MSDS 

Trace impurities and minor addition material names not listed above may also appear. 


Copper Filler Metal Covered By This MSDS 


Trade Name Fe Cr Ni Mo Mn Si 

INCO-WELD© 308, 308H, 308L, 308LSi 61-68 19-22 9-11





Table 2.2 

Composition (Weight %) 

Of Flux Coated Electrodes Covered By This MSDS 

PRODUCT NAME Al Al203 BaCO3 BaF2 C CaCO3CaF2 Cr Co Cu Fe Fe2O3 K2O K2SiO3 Li2Co3 Mn MnO Mo Nb Ni SiO2 NaAlF6 Na2SiO3 SrCO3 Ti TiO2 W 

INCOLOY ® 135 5-10 15-40 1-5 15-40 1-5 1-5 30-60 0.1-1 5-10 1-5 1-5 1-5 

INCONEL ® 112 & 112T 5-10 15-40 1-5 5-10 1-5 40-70 1-5 5-10 1-5 1-5 

INCONEL ® 112AC 5-10 15-40 1-5 1-3 1-5 5-10 1-5 40-70 1-5 5-10 1-5 1-5 

INCONEL ® 117 5-10 15-40 5-10 1-5 0.5-2 5-10 40-70 0-5-2 5-10 1-5 1-5 

INCONEL ® 122 5-10 1-5 15-40 1-5 10-30 40-70 0.1-1 5-10 1-5 1-5 1-5 

INCONEL ® 152 1-5 10-30 5-10 1-5 1-5 40-70 0.1-1 5-10 1-5 1-5 1-5 

INCONEL ® 152M 1-5 10-30 5-10 1-5 1-5 40-70 0.1-1 5-10 1-5 1-5 1-5 

INCONEL ® 152MSS 1-5 20-30 5-10 2-4 1-5 40-70 5-10 1-5 1-5 1-10 

INCONEL ® 182 & 182T 5-10 10-30 5-10 1-5 1-5 1-5 40-70 0.1-1 1-10 1-5 1-5 1-5 

INCO-WELD ® 686CPT ® 1-5 3-7 10-30 10-30 30-60 1-5 3-7 1-5 

INCO-WELD ® A 5-10 10-30 6-12 1-5 1-5 1-5 30-60 0.1-2 5-10 1-5 3-7 

INCO-WELD ® B 5-10 3-7 10-30 7-13 1-5 1-5 1-5 30-60 0.1-2 1-5 

INCO-WELD ® C 1-5 1-5 10-30 30-60 1-5 1-5 5-10 1-5 1-5 1-5 5-10 

INCO-WELD ® C-276 1-5 10-30 1-5 3-7 1-5 10-30 30-60 0.1-1 5-10 1-5 5-10 1-5 

INCO-WELD ® G3 15-25 1-3 15-21 4-8 45-55 3-6 1-10 1-5 0-2 

MONEL ® 187 & 187N 5-10 1-5 40-70 0.7-0.9 1-5 15.40 1.5 5-10 1-5 1-5 1-5 

MONEL ® 190 & 190N 1-5 1-5 1-5 15-40 1-5 40-70 1-5 5-10 1-5 1-5 1-5 

Nickel 141 & 141N 1-5 5-10 40-70 0.5-2 5-10 1-5 1-5 

NI-ROD ® 1-5 0-1 1-5 1-5 1-5 1-5 1-5 60-100 1-5 7-13 

NI-ROD ® 44 1-5 1-5 1-5 1-5 1-5 30-60 7-13 30-60 7-13 

NI-ROD ® 55 1-5 1-5 1-5 30-60 1-5 30-60 7-13 

NI-ROD ® 55X 1-5 1-5 1-5 1-5 1-5 30-60 1-5 30-60 5-10 

NI-ROD ® 60 1-5 1-5 1-5 1-5 30-60 30-60 7-13 

NI-ROD ® 99X 1-5 1-5 1-5 1-5 1-5 1-5 1-5 60-100


Table 3.1 

Composition Of Welding Fume For Filler Metal Wires Covered By This MSDS (Weight %) 

Si Ti Al Fe Mn Ni Cr Mo Nb Cu Co 

INCOLOY ® 65 0.2 0.6 0.2 23 0.4 39 19 2


Table 3.4 

Composition Of Welding Fume For Stainless Steel Welding Wires Covered By This MSDS (Weight %) 

Fe Mn Ni Cr Cu Mo 

INCO-WELD© 308, 308H, 308L, 

308LSi 

40.30 4.10 6.30 11.10 0.16 0.06 

INCO-WELD© 309, 309H, 309L, 

33.50 7.00 7.00 16.30 0.16 0.33 

309LSi 

INCO-WELD© 309LMo 

INCO-WELD© 310 34.50 4.20 10.00 16.50 0.16 0.06 

INCO-WELD© 312 34.00 7.10 6.20 18.50 0.10 0.06 

INCO-WELD© 316, 316L, 316LSi 31.00 7.10 6.50 8.50 0.70 1.80 

INCO-WELD© 347 34.5 5.70 6.20 10.20 0.17 0.14 

318 31.00 7 6.5 9 0.16 1.8 

410 35 3 5.5 

18/8/Mn 40.3 8.20 6.20 11.20 0.15 1.06 

Table 3.5 

Composition Of Welding Fume For Low Alloy Steel Welding Wires Covered By This MSDS (Weight %) 

Fe Mn Ni Cr Cu Pb 

A15 / A18 55 6.5 1.1 

A31 62 16 1.5 

A32 55 9 0.2 1.5 2 03 

A33 53 6 0.3 2 2.2 0.5 

Table 3.6 

Composition Of Welding Fume For Aluminum Alloy Welding Wires Covered By This MSDS 

Fe Mn Ni Cr Cu Al203 

INCO-WELD© 1050 1 0.1 0.2 90 

INCO-WELD© 4043 2 0.1 0.40 80 

INCO-WELD© 4047 2 0.1 0.4 80 

INCO-WELD© 5356 1 0.1 0.50 83 

INCO-WELD© 5556 1 0.1 0.40 80 

Table 3.7 

Composition Of Welding Fume For Copper Alloy Welding Wires Covered By This MSDS 

Fe Mn Ni Cr Cu 

INCO-WELD© Cu 0.30 0.60 0.10 0.10 75 

INCO-WELD© CuSi-A 0.20 1.00 0.20 0.10 73 

INCO-WELD© C12 0.30 0.10 0.10 0.10 75 

INCO-WELD© C13 2.00 0.10 0.20 0.10 80 

INCO-WELD© C26 5.0 1.00 0.50 0.10 75 



Date – June 2009

Appendix 1 

INGREDIENTS, TOXICOLOGICAL AND EXPOSURE LIMIT INFORMATION 

Page 1 of 7 




The following information is primarily directed to the ingredients of the complex alloys listed in table 2.1, 2.2, 2.3, 2.5, 2.6, and 2.7. Although it is the user's responsibility to assess end products, intermediates, or fugitive 

emissions arising out of the use of these alloys, information is also provided for common fume ingredients. UK EH40 limits for the ingredients are shown in italics at the end of each section. 

Ingredient 

Symbol Name 

EINECS 

Number 

CAS 

Number 

Exposure Limits (1) : Comments 

Al Aluminum 7429-90-5 TLV: 10 mg/m 3 (Metal dust); 5 mg/m 3 (Welding fumes) 

PEL: 15 mg/m 3 (Total metal dust); 5 mg/m 3 (Metal dust – 

respirable fraction) 

LD50: Not Available 

EH40 - Aluminum metal: 

Total inhalable dust OES 10 mg/m 3 (8 hours TWA),Total 

respirable dust OES 4 mg/m 3 (8 hours TWA) 

Al2O3 Aluminum Oxide 

(Alumina) 

1344-28-1 TLV: 10 mg/m 3 

PEL: 15 mg/m 3 (Total dust); 

5 mg/m 3 (respirable) 


EH40 Total inhalable dust OES 10 mg/m 3 (8 hours TWA),Total 


BaCO3 Barium Carbonate 513-77-9 TLV: 0.5 mg/m3 (Soluble compounds, as Ba) 

PEL: 0.5 mg/m3 (Soluble compounds, as Ba) 

LD50: 418 mg/kg, rat, oral 

EH40 OES 0.5 mg/m3 BaF2 Barium Flouride 7787-32-8 

(soluble compounds, as Ba) 

TLV: 0.5 mg/m3 (Soluble compounds, as Ba) 

PEL: 0.5 mg/m3 (Soluble compounds, as Ba) 


EH40 OES 0.5 mg/m3 (soluble compounds, as Ba) 

C Carbon 7440-44-0 TLV: 3.5 mg/m 3 (As carbon black) 

PEL: 3.5 mg/m 3 (As carbon black) 

LD50: 440 mg/kg, mouse, intravenous 

CaCO3 Calcium 

Carbonate 

1317-65-3 TLV: 10 mg/m 3 

PEL: 15 mg/m 3 (Total dust); 

5 mg/ m 3 (Respirable fraction) 

LD50: 6,450 mg/kg, rat, oral 

EH40: Total inhalable dust OES 10 mg/m 3 (8 hours TWA),Total 


Aluminum is not readily absorbed through the skin or the GI tract and only poorly through the lungs. Foreign 

literature between 1958 and 1962 reported cases of severe and sometimes fatal pulmonary fibrosis in 

workers exposed to aluminum dust. In one of the fatal cases, the worker developed fibrosis and 

encephalopathy after 13.5 years of exposure to aluminum dust. 

In rodent studies and currently in US industry, no fibrosis or encephalopathy have been reported from the 

inhalation of aluminum powder. Acute exposure to alumina fume may cause bronchial irritation; however 

reports of pulmonary fibrosis and emphysema in alumina abrasive workers are no longer seen, owing to 

improved environmental control. 

Acute exposure to this material may cause bronchial irritation; however reports of pulmonary fibrosis and 

emphysema of alumina abrasive workers are no longer seen, owing to improved environmental control. 

Excessive inhalation can produce a benign pneumoconiosis called Baritosis. Ingestion can cause excessive 

salivation, vomiting, colic, violent diarrhea, convulsive tremors progressing to muscular paralysis, increased 

blood pressure, internal hemorrhages in the kidneys and G.I tract, and possible hypokalemia. 

Inhalation may cause irritation of the respiratory tract. Ingestion can cause severe gastrointestinal distress 

with vomiting, diarrhea, and abdominal pain. Barium and fluoride absorption can result in muscle (including 

cardiac) and nerve irregularities with potassium and calcium deficiencies. Chronic exposures may cause 

Fluorosis (Chronic fluoride intoxication) with symptoms of digestive disturbances such as vomiting, loss of 

appetite, diarrhea, or constipation. 

Inhalation that is prolonged and repeated at excessive levels may lead to benign pneumoconiosis. No 

effects have been found for ingestion. 

This compound is considered non-toxic. Inhalation of particulates could cause mild irritation of the 

respiratory tract. Though used as an antacid, ingestion of large amounts could lead to intestinal blockage.

CaF2 Calcium Fluoride 

(Fluorspar) 

7789-75-5 TLV: 2.5 mg/m 3 (as F) 

PEL: 2.5mg/m 3 (as F) 

LD50: 4,250mg/kg, rat, oral 

CaO Calcium Oxide 1305-78-8 TLV: 2 mg/m 3 , as Calcium Oxide 

PEL: 5 mg/m 3 , as Calcium Oxide 

LD50: Not Known 

CaSiO3 Calcium 

Metasilicate 

EH40: Total inhalable dust OES 2 mg/m 3 (8 hours TWA 

1344-95-2 TLV: 10 mg/m3 (Dust) 

PEL: 15 mg/m3 (Total dust) 

5 mg/m3 (Respirable) 


EH40: Total inhalable dust OES 10 mg/m3 (8 hours TWA),Total 

respirable dust OES 4 mg/m3 (8 hours TWA) 

Co Cobalt 231-158-0 7440-48-4 TLV: 0.02 mg/m 3 (Dust & fume as Co) 

PEL: 0.1 mg/m 3 (As Co metal) 


EH40 OES 0.1 mg/m 3 (8 hours TWA) 

Cr Chromium 231-157-5 7440-47-3 TLV: 0.5 mg/m 3 

PEL: 1.0 mg/m 3 (Metal as Cr) 


EH40: 

Chromium VI compounds (as Cr) 

OES 0.05 mg/m 3 (8 hours TWA) 

Chromium II compounds (as Cr) 


Chromium III compounds (as Cr) 


Chromium 


Cr2O3 Chromic Oxide 1308-38-9 TLV: 0.5 mg/m 3 , as Cr 

PEL: 0.5 mg/m 3 (Metal as Cr) 






Inhalation of welding fumes containing calcium fluoride can cause irritation of the respiratory tract. Ingestion 

of soluble fluorides can produce symptoms of vomiting, abdominal pain, diarrhea, convulsions, muscular 

weakness and other signs of neurological problems. Chronic exposures may cause Fluorosis (Chronic 

fluoride intoxication) with symptoms of digestive disturbances such as vomiting, loss of appetite, diarrhea, or 

constipation. 

May cause skin, eye and mucous membrane irritation. Inhalation of dust or fume may cause respiratory 

irritation. Repeated exposure can cause damage to the nasal septum, pneumonia and dermatitis. 

Long Term cumulative inhalation of calcium metasilicate may cause restriction of the large airways. May 

cause minor skin and eye irritation. The International Agency for Research on Cancer (IARC) has concluded 

that calcium metasilicate is a questionable carcinogen with experimental tumorigenic data in animals. Not 

classifiable as a human carcinogen according to IARC. 

Asthmatic symptoms and pulmonary fibrosis occurring in the tungsten carbide industry may be related to the 

inhalation of metallic cobalt dust. Evidence of polycythemia (an increase in the total red cell mass of the 

blood in the body) and altered thyroid, kidney and liver function have also been found. Excessive inhalation 

of metallic cobalt has produced cardiac changes in miniature swine. Eye contact may cause conjunctivitis. 

Symptoms of excessive ingestion may be a sensation of hotness with vomiting, diarrhea and nausea along 

with the potential for causing damage to blood, heart, thyroid and pancreas. Repeated skin contact can 

cause sensitivity and allergic skin rashes. Cobalt powders have caused tumors at the site of injection in 

rodents. However, studies of cobalt-containing prostheses do not suggest a significant risk for humans. 

Chromium metal is relatively nontoxic. Chromium metal and insoluble salts are said to be involved in 

fibrosis of the lungs. When the metal is heated to a high temperature, fumes produced may be damaging to 

the lungs if inhaled. The International Agency for Research on Cancer has concluded that the evidence for 

carcinogenicity in humans and animals is inadequate for chromium metal and trivalent chromium 

compounds, but sufficient for hexavalent chromium compounds. Fumes from welding chromium-containing 

stainless steel or certain chromium-containing rods can trigger eczematous eruptions on the palms of the 

hands of chromium-sensitized individuals. 

Trivalent chromium compounds (such as Cr2O3) are considered to exhibit a low degree of toxicity. 

Excessive concentrations of airborne dust may irritate the nose, throat, and respiratory tract. Prolonged 

overexposure may result in pulmonary changes. Skin and eye contact may cause irritation. The U.S. 

National Toxicology Program (NTP) has concluded that there is sufficient evidence that certain chromium 

compounds were carcinogenic to humans. However, the International Agency for Research on Cancer 

(IARC) has stated that there is inadequate evidence for carcinogenicity to humans or animals for trivalent 

chromium compounds.

Cu Copper 231-159-6 7440-50-8 TLV: 1 mg/m 3 (Dusts & mists, as Cu), 

0.2 mg/m 3 (Fume) 

PEL: 1 mg/m 3 (Dusts & mists, as Cu), 

0.1 mg/m 3 (Fume as Cu) 

LD50: 35 mg/kg, mouse, intraperitoneal 

EH40: Fume OES 0.2 mg/m 3 (8 hours TWA) 

Dusts & mists (as Cu) OES 1.0 mg/m 3 (8 hours TWA), 

2.0 mg/m 3 (15 minute reference period) 

Fe/ Fe203 Iron 231-096-4 7439-89-6 TLV: No limit set (For Fe2O3 fume the TLV is 5 mg/m 3 as Fe) 

PEL: No limit set (For Fe2O3 dust & fume the PEL is 10 mg/m 3 

as Fe) 


Fe3O4 Ferrosoferric 

Oxide 

EH40 Iron Oxide, fume (as Fe) OES 5.0 mg/m3 (8 hours TWA), 

10 mg/m3 (15 minute reference period) 

1317-61-9 TLV: No limit set 

(For Fe2O3 fume, 5 mg/m3 as Fe) 

PEL: No limit set 

(For Fe2O3 dust and fume, 5 mg/m3 as Fe) 


K2O Potassium Oxide 12136-45-7 TLV: 2 mg/m 3 Ceiling value as KOH 

PEL: 2 mg/m 3 Ceiling value as KOH 


K2SiO3 Potasium Silicate 1312-76-1 TLV: Not Established 

PEL: Not Established 

LD50: >1000 mg/kg, oral, rat 

K2ZrF6 Potassium 

Fluozirconate 

16923-95-8 TLV: 2.5 mg/m 3 (Fluorides, as F) 

PEL: 2.5 mg/m 3 (Fluorides, as F) 

LD50: 98 mg/kg, mouse, oral 





Copper metal dust and fume may be irritating to the respiratory tract. In user operations where copper fume 

is generated, inhalation of the fume can result in symptoms of "Metal Fume Fever" such as chills, fever and 

sweating. A few instances of allergic skin rashes have been reported in workers with skin exposure to 

metallic copper. In the eyes, copper metal as a foreign body can provoke an inflammatory reaction resulting 

in pus formation in the conjunctiva, cornea or sclera. Ingestion of copper metal may cause gastrointestinal 

upset. Wilson's disease can occur in certain individuals with a rare, inherited metabolic disorder 

characterized by retention of excessive amounts of copper in the liver, brain, kidneys and corneas. These 

deposits eventually lead to tissue necrosis and fibrosis, causing a variety of clinical effects, especially liver 

disease and neurological changes. Wilson's disease is progressive and, if untreated, leads to fatal liver 

failure. 

Inhalation of the excessive oxide fumes or dusts can lead to irritation of the respiratory tract. Prolonged 

inhalation of iron oxide for periods of 6 to 10 years is known to cause siderosis which appears to be a 

benign pneumoconiosis. Prolonged eye contact with the metal dust could cause rust brown colored spots 

forming around the particles and if left for several years, permanent damage could result. 

Inhalation of excessive amounts can lead to irritation of the respiratory tract. Chronic inhalation of iron oxide 

for periods of 6 - 10 years is known to cause siderosis which seems to be a benign pneumoconiosis. No 

data found on ingestion. 

No toxicity data was found on potassium oxide, but it is expected to have effects similar to sodium peroxide 

which is highly irritating to the skin, eyes and the mucous membranes of the respiratory tract. 

Silicates are generally considered to have low systemic toxicity, however due to their alkaline nature they 

may cause corrosive effects on mucous membranes. Eye exposure can cause irritation, redness, tearing 

and blurred vision. Prolonged eye exposure may lead to chronic conjunctivitis. Skin exposure may cause 

local slight irritation. Repeated contact may lead to dermatitis. Inhalation of mist or fume can cause irritation 

of the nasal and respiratory passages. Ingestion can produce gastrointestinal irritation, nausea, vomiting, 

diarrhea, accompanied by potentially severe tissue damage. No known chronic effects have been noted. 

Inhalation of welding fumes containing fluorides can cause irritation of the respiratory tract. Ingestion of 

soluble fluorides can produce symptoms of vomiting, abdominal pain, diarrhea, convulsions, muscular 

weakness and other signs of neurological problems. Nose bleeds, skin irritation, tissue damage and slow 

healing scars can result if exposure is excessive. Chronic exposures may cause Fluorosis (Chronic fluoride 

intoxication) with symptoms of digestive disturbances such as vomiting, loss of appetite, diarrhea, or 

constipation.

LiCO3 

Li2CO3 

Lithium Carbonate 554-13-2 TLV: No limit set 


LD50: Oral 525 mg/kg, rat 

Dermal LD 50, > 2000 mg/kg, rat 

MgO Magnesium Oxide 1309-48-4 TLV: 10 mg/m 3 (As fume) 

PEL: 15 mg/m 3 (Total dust or fume) 


EH40 Total inhalable dust OES 10 mg/m 3 (8 hours TWA),Total 

fume and respirable dust OES 4 mg/m 3 (8 hours TWA) 

Mn Manganese 231-105-1 7439-96-5 TLV: 0.2 mg/m 3 elemental and inorganic compounds, as Mn 

PEL: 5 mg/m 3 (Ceiling, as Mn compounds); 

5 mg/m 3 (Fume, as Mn) 


EH40 Manganese and its inorganic compounds (as Mn) OES 

0.5 mg/m3 MnO Manganous Oxide 1344-43-0 

(8 hours TWA) 

TLV: 0.2 mg/m3 (as Mn) 

PEL: 1mg/m3 (fume) 5mg/m3 (Stel, Ceiling) 

LD50: >50mg/kg, intratracheal rat. 

Mo Molybdenum 231-107-2 7439-96-7 TLV: 10 mg/m 3 (Insoluble and metal compounds, as Mo) 

PEL: 15 mg/m 3 (Insoluble compounds, total dust as Mo) 


EH40 - Molybdenum compounds (as Mo): 

Soluble - OES 5.0 mg/m 3 (8 hours TWA), 10 mg/m 3 (15 

minute reference period) 

Insoluble - OES 10 mg/m 3 (8 hours TWA), 20 mg/m 3 (15 

minute reference period) 





Contact with skin or eyes may cause irritation. Ingestion may cause acute local tissue damage. Some 

studies of pregnant mice and rats indicated an association between lithium ingestion and birth defects but 

only at dose levels large enough to produce signs of severe maternal toxicity. Although data for the 1970's 

and early 1980's suggested an increase in cardiovascular defects in babies born to women on lithium 

carbonate therapy, more recent studies have not found any association between lithium exposure and birth 

defects. Exposure to lithium in industrial settings is not considered to pose a risk to human health. NIOSH 

studied 25 workers exposed to lithium-containing dust at air concentrations exceeding 10 Mg/M3 (nuisance 

dust limit) and found that typical industrial exposure to lithium will not result in blood levels sufficiently high to 

produce toxicity in either adults or their offspring. 

Inhalation of fumes can irritate the nose and throat. Excessive inhalation can cause metal fume fever with 

flue-like symptoms such as fever, body aches, vomiting, etc. Fumes of magnesium may irritate the 

eyes and skin. On ingestion the oxide will act as an antacid and laxative. 

Excessive inhalation or ingestion of manganese can produce manganese poisoning. Chronic exposures 

can lead to neurological problems such as apathy, drowsiness, weakness, spastic gait, paralysis, and other 

neurological problems resembling Parkinsonism. These symptoms can become progressive and permanent 

if not treated. Excessive inhalation of fumes may cause "Metal Fume Fever" with its flu-like symptoms, such 

as chills, fever, body aches, vomiting, sweating, etc. 

Excessive inhalation or ingestion of manganese and manganese compounds can produce manganese 

poisoning. Chronic exposures can lead to neurological problems such as apathy, drowsiness, weakness, 

spastic gait, paralysis, and other neurological problems resembling Parkinsonism. These symptoms can 

become progressive and permanent if not treated. Inhalation of fumes may bring about "metal fume fever" 

with symptoms such as chills and fever, upset stomach, vomiting, dryness of throat, cough, weakness, and 

aching of the head and body. 

Molybdenum and its insoluble compounds are reported to have a low toxicity. High dietary intake may 

produce a gout-like disease and high blood uric acid. Inhalation of fumes has caused kidney damage, 

respiratory irritation and liver damage in animals. Skin and eye contact may cause irritation.

Na20 Sodium Oxide 1313-59-3 TLV: 2 mg/m 3 (ceiling level as NaOH) 

PEL: 2mg/m 3 ( as NaOH) 


Na2Si4O9/ 

Na2Si03 

Sodium Silicate 1344-09-8 TLV: Not Established 

PEL: Not Established 

LD50: 1153 mg/kg, oral, rat 

Na2AlF6 Sodium Aluminum 

Fluoride 

(Sodium 

Fluoaluminate) 




NaF Sodium Flouride 7681-49-4 TLV: 2.5 mg/m 3 (as F) 

PEL: 2.5 mg/m 3 (as F) 

LD50: 0.18g/kg, rat, oral 

Nb Niobium 231-113-5 7440-03-1 TLV: No limit set 







Sodium oxide, in powder form, is highly corrosive to moist skin, eyes, and the mucous membranes of the 

digestive and respiratory tracts due to its reaction with water to form sodium hydroxide. Inhalation of dusts 

may cause symptoms that vary from mild irritation to destructive burns depending on exposure. Ingestion 

can cause immediate burning of the mouth, esophagus, and stomach; swelling of surround tissues, 

vomiting; and rapid, faint pulse with cold, clammy skin. Death can result. Skin contact causes slippery, 

soapy feeling that may not be immediately painful even though skin damage begins at contact. This contact 

can lead to chemical burns, tissue corrosion, ulceration, loss of nails and hair, and permanent scarring if not 

immediately washed off. The cornea of the eye will begin corroding on contact and can lead to temporary or 

permanent corneal opacification producing blindness. Chronic low level skin exposures to sodium hydroxide 

may result in dermatitis. Sodium hydroxide is reported to have caused carcinoma of the esophagus 12 to 42 

years after ingestion. 

Silicates are generally considered to have low systemic toxicity, however due to their alkaline nature they 

may cause corrosive effects on mucous membranes. Eye exposure can cause severe irritation, redness, 

tearing and blurred vision. Skin exposure may cause slight irritation. Inhalation of mist or fume can cause 

irritation of the nasal and respiratory passages. Ingestion may produce gastrointestinal irritation, nausea, 

vomiting, diarrhea and abnormal kidney function. No known chronic effects have been noted. 

Excessive inhalation of dust may cause irritation of the nose, throat and respiratory tract. Ingestion causes 

severe gastrointestinal distress with salivation, nausea, vomiting, diarrhea, and pain. Also may cause 

muscular weakness, tremors, convulsions, loss of consciousness, and death. Prolonged exposure to 

fluorides can cause skeletal abnormalities and digestive tract disturbances. Prolonged or repeated skin 

contact can produce dermatitis. 

Sodium fluoride is very poisonous. Ingestion of less than 1 gram can cause nausea and vomiting, salivation, 

diarrhea, weakness, spasms of limbs, and stupor. Ingestion of 5 to 10 

grams has proven fatal. Symptoms of possible lethal exposure include muscular weakness, tremors, 

convulsions, collapse, and difficulty breathing to respiratory and cardiac failure. This chemical is 

irritating to the eyes, nose and respiratory system. Long-term exposure can cause skeletal abnormalities 

(Fluorosis) to develop. This can include bone densification and calcification of certain ligaments 

along with stiffness of the spinal column. Mottling of tooth enamel is also possible. 

Also known as Columbium (Cb), there is almost no information on the toxicity of this metal or its fumes. 

Russian medical literature has described early chest x-ray changes in welders and chemical workers 

handling niobium and tantalum, but no specific data has been found. It is expected that the metal dust and 

fumes could cause irritation to the skin, eyes and respiratory tract upon acute exposure.

Ni Nickel 

R43 

231-111-4 7440-02-0 TLV: 1.5 mg/m 3 as metal (Inhalable Fraction) 

PEL: 1 mg/m 3 for metal and insoluble compounds as Ni 

LD50: >9,000 mg/kg, rat, oral 

EH40 - Nickel and its inorganic compounds (except nickel 

carbonyl): Water soluble nickel compounds (as nickel) 

OES 0.1 mg/m 3 (8hours TWA). Nickel & water in-soluble 

nickel compounds (as Ni) OES 0.5 mg/m 3(8-hour TWA) 

Si Silicon 231-130-8 7440-21-3 TLV: 10 mg/m 3 

PEL: 10 mg/m 3 Total dust; 

5 mg/m 3 Respirable fraction 

LD50: 3,160 mg/kg, rat, oral in amorphous form 

SiO2 Silicon Dioxide 

Silica 

SrCO3 Strontium 

Carbonate 

EH40 Total inhalable dust OES 10 mg/m 3 (8 hours TWA). 

Total respirable dust OES 4 mg/m 3 (8 hours TWA). 

60676-86-0 TLV: 10 mg/m 3 (Metal dust); 5 mg/m 3 (Welding fumes) 

PEL: 15 mg/m 3 (Total metal dust); 5 mg/m 3 (Metal dust - 

respirable fraction) 


EH40: Silica, fused respirable dust, OES 0.08 mg/m 3 (8-hour 

TWA) 




Ti Titanium 231-142-3 7440-32-6 TLV: No limit set 



EH40 - As Titanium dioxide: 

Total inhalable dust OES 10 mg/m 3 (8 hours TWA), 

Total respirable dust OES 4 mg/m 3 (8 hours TWA) 





The U.S. National Toxicology Program (NTP) 10th Report on Carcinogens has listed "metallic nickel" as 

"reasonably anticipated to be a human carcinogen" and "nickel compounds" as "known human 

carcinogens". "Nickel Alloys" were reviewed but not listed. The International Agency for Research on Cancer 

(IARC) concluded that nickel compounds were carcinogenic to humans and that metallic nickel is possibly 

carcinogenic to humans. Epidemiological studies of workers exposed to nickel powder and to dust and fume 

generated in the production of nickel alloys and of stainless steel have not indicated the presence of a 

significant respiratory cancer hazard. 

The inhalation of nickel powder has not resulted in an increased incidence of malignant tumors in rodents. 

Repeated intratracheal instillation of nickel powder produced an increased incidence of malignant lung 

tumors in rats, but did not produce an increased incidence in hamsters when administered at the maximum 

tolerated dose. However, single intratracheal instillations of nickel powder in hamsters at doses near the 

LD50 have produced an increased incidence of fibrosarcomas, mesotheliomas and rhabdomyosarcomas. 

Inhalation of nickel powder at concentrations 15 times the PEL irritated the respiratory tract in rodents. 

Nickel is a known sensitizer and may produce allergic reactions. 

Silicon in dust form is considered a nuisance dust with no toxic effects when exposures are kept under 

control. However, like all dusts, high concentrations of silicon dust will cause some irritation to the nose and 

throat. Inhalation of crystalline silica (SiO2) over a long period of time can cause silicosis. In 1997, the 

International Agency for Research on Cancer (IARC) concluded that crystalline silica is a class I carcinogen. 

IARC states that a number of studies have shown that persons diagnosed as having silicosis have an 

increased risk of dying from lung cancer. 

No information was found on the hazards of ingestion of crystalline silica as the material seems to be 

relatively inert. Acute exposures to this material will irritate the respiratory tract. Chronic inhalation (after 10 - 

20 years) can produce silicosis pneumoconiosis of the lungs) with symptoms of dyspnea, cough, wheezing 

and repeated, non-specific chest illnesses. Impairment of pulmonary function may be progressive. In 1997, 

the International Agency for Research on Cancer (IARC) concluded that crystalline silica is a class 1 

carcinogen. IARC states that a number of studies have shown that persons diagnosed as having silicosis 

have an increased risk of dying from lung cancer. 

There is very little toxicity and health data on this material. Excessive overexposure to the dust may ulcerate 

mucous membranes in the nose and may cause sneezing and coughing. No data found on ingestion 

problems. 

Inhalation of titanium could cause mild irritation to the respiratory tract. Inhalation of titanium dioxide dust or 

fume could produce lung fibrosis and chronic bronchitis.

Ta Tantalum 7440-25-7 TLV: 5 mg/m 3 (Metal & oxide dusts) 

PEL: 5 mg/m 3 (Metal & oxide dusts) 


EH40 OES 5.0 mg/m 3 (8 hours TWA), 

10 mg/m 3 (15 minute reference period) 

TiO2 Titanium Dioxide 13463-67-7 TLV: 10 mg/m 3 (Dust); 

PEL: 5 mg/m 3 (Respirable) 


EH40: Total inhalable dust OES 10.0 mg/m 3 (8-hour TWA), total 

respirable OES 4 mg/m 3 

W Tungsten 231-143-9 7440-33-7 TLV: 5 mg/m 3 insoluble compounds, as W 

STEL: 10 mg/m 3 for soluble compounds, as W 


LD50: 2,000mg/kg, rat, unreported route 

EH40: Soluble compounds, OES 1.0 mg/m 3 (8-hour TWA) and 3 

mg/m 3 (15 minute reference period). 

In-soluble compounds, OES 5 mg/m 3 (8-hour TWA) and 

10.0 mg/m3 (15 minutes reference period) 

Zr02 Zirconium Dioxide 1314-23-4 TLV: 5 mg/m 3 (as Zr) 10 mg/m 3 (STEL) 

PEL: 5 mg/m 3 (as Zr) 10 mg/m 3 (STEL) 


EH40 Zirconium compounds (as Zr), OES 5mg/m 3 (8-hour TWA), 

10 mg/m 3 (15-minute reference period 





There are no reports of adverse health effects in industrially exposed workers. Massive doses of tantalum 

given by the intratracheal route to rats have produced respiratory tract lesions. In contact with tissue, 

metallic tantalum is inert. Tantalum pentoxide has an LD50 of >8 g/kg, orally in rats. 

Is considered a nuisance dust that is inert, practically non-toxic and chemically non-irritating. Skin contact 

has shown no problems other than possible drying and mechanical abrasion. 

Eye contact can produce particulate irritation. Does not seem to be absorbed by the body through ingestion. 

Excessive inhalation can produce mild pulmonary irritation and possible non-disabling slight fibrosis of 

the lungs. 

Inhalation of tungsten dust may cause irritation of the respiratory tract. Skin or eye contact could cause 

abrasion or irritation of the respective surfaces. No hazards have been identified for tungsten fume except 

that it may aggravate an existing chronic respiratory disease. 

Though this material has a low order of toxicity on inhalation some lung granulomas have been reported. 

Excessive inhalation may cause irritation of the nose and respiratory tract. Eye contact may cause irritation. 

Skin contact may cause irritation and sensitization dermatitis characterized by dusty red-brown papules. No 

information found on effects of ingestion. 

Notes: (1) TLV = Threshold Limit Values - American Conference of Governmental Industrial Hygienists 

PEL = Permissible Exposure Limit - OSHA 29 CFR 1910.1000 

C = Ceiling value 

STEL = Short Term Exposure Limit - a time-weighted 15-minute exposure limit, not to be exceeded at any time during a workday. 

(2) CAS No. = Chemical Abstracts Services Number 

Trace impurities and additional material names not listed above may also appear in Appendix 1 toward the end of the MSDS. These materials may be listed for local “Right-To-Know” 

compliance and for other reasons. 

Weight percentages for each grade of product are listed in Table 2.x


MSDS NO: 415889 

REVISED: April 30, 2009 

TW 3575 

For U.S. Manufactured or Distributed Welding Consumables and Related Products. May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200 and Superfund 

Amendments and Reauthorization Act (SARA) of 1986 Public Law 99-499. Standard must be consulted for specific requirements. 

SECTION 1 IDENTIFICATION 

Manufacturer/Supplier Name: HOBART BROTHERS COMPANY Telephone No: (937) 332-4000 

Address: 101 TRADE SQUARE EAST, TROY, OH 45373 Emergency No: (800) 424-9300 

Website: www.hobartbrothers.com 

Product Type: TUBULAR ARC WELDING ELECTRODES FOR FLUX CORED, METAL CORED AND COMPOSITE SUBMERGED ARC WELDING 

GROUP A: Product For: Gas Shielded Carbon and Low Alloy Steel 

Trade Name: EXCEL-ARC 71; FABCO 80D2, 82HD, 85, 90, 825, E70T-1C, E70T-9C H8, HORNET, RXR, RXR-XLS, TR70, XL-71; FABCOR 80XLS, 86R, 96, 702; FABDUAL T9M, T91M; FLUX- 

COR 2, 3, 7,9XT, 37, 80A1, 90D3; GALVACOR; GALVALLOY; METAL-COR 3, 3S, 6, 6L, 8, 80D2, EH14S, EL12KS, EM12KS, EN-VISION; METALLOY 70, 70R, 70X, 71,76, 80D2, 

A1S, A3S, CO2, EH14S, EL12KS, EM12KS, EM13KS, X-CEL; PIPEMASTER MC70; SPEED-ALLOY 70, 71, 71A, 71A1, 71-V, 719, 75, 95D2, 105D2; SPEED-COR 6; SUPER-COR; 

SUPER TUF-COR; TM-11, 22, 37, 55, 71 XTR, 72, 73, 75A1, 81A1, 91D3, 95D2, 105D2, 711M, 791, 811A1, RX7; TRIPLE-7, 8; TUF-COR 1, 5, 75A1, 95D2, 105D2; 

VERSATILE; VERTI-COR I, II, III, 71, 81A1 

GROUP B: Product For: Self-Shielded Carbon Steel 

Trade Name: FABSHIELD 4, 21B, 23, 31, 55, 120C, 7027, HSR; SELF-SHIELD 3, 4, 7, 11, 11GS; SPEED-SHIELD 11, GS; TM- 33R, 44, 77, 121, 123, 133 

GROUP C: Product For: Carbon and Low Alloy Steel 

Trade Name: DURASHIELD 8-11; EDGE; FABCO 81K2-C, 83, 91, 91K2-C, 107G, 110, 110K3-M, 115, 803, HICOR, XTREME 120, B2, B3; FABCOR 209, 1100; FABSHIELD 3Ni1, 71K6, 

81N1, 81N2, 811K6, 7018, OFFSHORE 71Ni, XLNT-6, XLR-8, X80; FLUX-COR 80B2, 80Ni1, 80Ni2, 80W, 90B3, 90K2, 90Ni2, 100K3, 110K3; FORMULA XL8Ni1, XL8Ni1-C, 

XL525, XL550, GD5; HOBART CBC-1; MATRIX; MEGAZORD; METAL-COR 80B2, 80Ni1, 80Ni2, 80Ni3, 90, 90B3, 100, 110, B2S, B3S, F2S, MAXIM, N1S, N2S, N3S, N4S, WS; 

METALLOY 80B2, 80N1, 80N2, 80N3, 80W, 90, 90B3, 100, 100G, 110, 120S, B2S, B3S, F2S, N1S, N2S, N3S, N4S, VANTAGE, VANTAGE CVN, VANTAGE D2, VANTAGE Ni1, 

WS; PREMIER 70; PW-201; PIPEMASTER F100-K2, F101-K2, F110-N1, F71, FS71-K6, FS71Ni1, FS 81-Ni2, MC90, MC100; SELF-SHIELD 8; SPEED-ALLOY 71-VC, 81B2L-V, 

81Ni1-V, 81Ni2-V, 81W, 81W-V, 85, 85C1, 85C2, 85C3, 91B3, 91B3L, 91B3L-V, 91B3-V, 91-V, 92S, 95, 100F3-S, 111-V, 112-S, 115, 125, 712, 712M, 790, 4130-V; TM- 

78K6, 81B2, 81N1, 81N2, 81W, 85B2L, 85N1, 85N2, 85N3, 91B3, 91B3L, 91K2, 91N2, 95K2, 95M-B3, 101K3, 105K3, 111K3, 115, 125K4, 770, 771, 71HYN, 772, 811B2, 

811N1, 811N2, 811N3, 811W, 880, 881K2, 910, 911B3, 911N2, 991K2, 101, 101K3-C, 1101K3-M, 4130; TUF-COR 85B2L, 85Ni1, 85Ni2, 85Ni3, 95B3, 95K2, 105K3, 115, 

125K4; VERTI-COR 70, 72, 81B2, 81Ni1, 81Ni2, 81W, 91B3, 91K2, 91Ni2, 110K3-M, 1101K3-C, IINi1 

GROUP D: Product For: Corrosion Resisting Steel 

Trade Name: ARC STAR 409; FABCOR 409; FABLOY 409, 409T, 439; FABTUF 250, 960; METAL-COR 409, 409Cb, 439; METALLOY 18CrCb, 409, 409Cb, MCW430NbL, 439; POWERCORE 

91; RSC-409; SPEED-ALLOY 5055; TM B6, B9 


IMPORTANT - This section covers the hazardous materials from which this product is manufactured. The fumes and gases produced during welding with normal use of this product are also addressed 

in Section 5. The term "hazardous" in this section should be interpreted as a term required and defined in OSHA Hazard Communication Standard (29 CFR Part 1910.1200). 

GROUP - % WEIGHT EXPOSURE LIMIT (mg/m 3 ) 

HAZARDOUS INGREDIENTS A B C D CAS NO. OSHA PEL ACGIH TLV 

IRON+ 75-98 75-95 75-95 75-95 7439-89-6 5 R* 5 R* (Fe2O3) {A4} 

IRON OXIDE --- ---

71Ni, XLNT-6; SELF-SHIELD 8 (12) Present only in MATRIX; METAL-COR MAXIM; METALLOY VANTAGE, VANTAGE CVN, VANTAGE D2, VANTAGE Ni1 R* - Respirable Fraction I* - Inhalable Fraction 

** - Ceiling Limit *** - Short Term Exposure Limit + - As a nuisance particulate covered under "Particulates Not Otherwise Regulated" by OSHA or "Particulates Not Otherwise Classified" by ACGIH 

++ - Crystalline silica is bound within the product as it exists in the package. However, research indicates silica is present in welding fume in the amorphous (noncrystalline) form # - Reportable 

material under Section 313 of SARA ### - Reportable material under Section 313 of SARA as dust or fume {A1} - Confirmed Human Carcinogen per ACGIH {A2} - Suspected Human Carcinogen per 

ACGIH {A3} - Confirmed Animal Carcinogen with Unknown Relevance to Humans per ACGIH {A4} - Not Classifiable as a Human Carcinogen per ACGIH {A5} - Not Suspected as a Human Carcinogen 

per ACGIH (noncrystalline) form - Listed under ACGIH Notice of Intended Changes for Mn in 2009 - Limit of 0.02 mg/m 3 is proposed for Respirable Mn in 2010 by ACGIH - NIOSH 

Recommended Exposure Limit (REL) TWA and STEL 

The exposure limit for welding fume has been established at 5 mg/m 3 with OSHA's PEL. The individual complex compounds within the fume may have lower exposure limits than the general 

welding fume PEL. An Industrial Hygienist, the OSHA Permissible Exposure Limits for Air Contaminants (29 CFR 1910.1000), and the ACGIH Threshold Limit Values should be consulted to 

determine the specific fume constituents present and their respective exposure limits. 

SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS 

Welding consumables applicable to this sheet are solid and nonvolatile as shipped. 

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA 

Welding consumables applicable to this sheet as shipped are nonreactive, nonflammable, nonexplosive and essentially nonhazardous until welded. Welding arcs and sparks can ignite combustibles 

and flammable products. See American National Standard Z49.1 referenced in Section 7. 

SECTION 5 - REACTIVITY DATA - HAZARDOUS DECOMPOSITION/INDUSTRIAL HYGIENE INFORMATION 

Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process, procedures and electrodes used. Most fume 

ingredients are present as complex oxides and compounds and not as pure metals. 

Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating or 

galvanizing), the number of welders and the volume of the work area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence 

of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). When the electrode is consumed, the fume and gas decomposition products 

generated are different in percent and form from the ingredients listed in Section 2. Decomposition products of normal operation include those originating from the volatilization, reaction or 

oxidation of the materials shown in Section 2, plus those from the base metal and coating, etc., as noted above. Reasonably expected constituents of the fume would include: Complex oxides of iron, 

manganese, silicon and titanium. Groups A and B may also contain calcium oxides. Groups A, B and C may have fluorides present. Groups A, C, and D may also contain molybdenum. Groups A, B, 

and C may also contain aluminum. Groups B and C may also contain barium. Groups A and C may also contain copper. Groups C and D may also contain chromium and nickel. Group B may also 

contain magnesium, lithium and strontium. Group C may also contain cobalt. Group C may also contain antimony trioxide. 

Monitor for the materials identified in Section 2. Fumes from the use of this product may contain: manganese, fluorspar or fluorides, barium, chromium and nickel compounds, calcium oxide, 

copper, silica, amorphous silica fume, lithium, strontium, cobalt and antimony trioxide whose exposure limits are lower than the 5 mg/m 3 PEL for general welding fume. Gaseous reaction 

products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. One recommended way to determine the composition and 

quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder's helmet if worn or in the worker's breathing zone. [See ANSI/AWS F1.1, available from the 

"American Welding Society", P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3 "Evaluating Contaminants in the Welding Environment - A Sampling Strategy Guide", which gives additional 

advice on sampling.] 

SECTION 6 - HEALTH HAZARD DATA 


Electric arc welding may create one or more of the following health hazards: 

ARC RAYS can injure eyes and burn skin. 

ELECTRIC SHOCK can kill. See Section 7. 

FUMES AND GASES can be dangerous to your health. 

PRIMARY ROUTES OF ENTRY are the respiratory system, eyes and/or skin. 

SHORT-TERM (ACUTE) OVEREXPOSURE EFFECTS: 

Welding Fumes - May result in discomfort such as dizziness, nausea or dryness or irritation of nose, throat or eyes. Iron, Iron Oxide - None are known. Treat as nuisance dust or fume. Manganese - 

Metal fume fever characterized by chills, fever, upset stomach, vomiting, irritation of the throat and aching of body. Recovery is generally complete within 48 hours of the overexposure. Titanium 

Dioxide - Irritation of respiratory system. Silica (Amorphous) - Dust and fumes may cause irritation of the respiratory system, skin and eyes. Fluorides - Fluoride compounds evolved may cause skin 

and eye burns, pulmonary edema and bronchitis. Molybdenum, Cerium Oxide - Irritation of the eyes, nose and throat. Calcium Oxide - Dust or fumes may cause irritation of the respiratory system, 

skin and eyes. Aluminum Oxide - Irritation of the respiratory system. Magnesium, Magnesium Oxide - Overexposure to the oxide may cause metal fume fever characterized by metallic taste, 

tightness of chest and fever. Symptoms may last 24 to 48 hours following overexposure. Barium - Aching eyes, rhinitis, frontal headache, wheezing, laryngeal spasms, salivation or anorexia. Nickel, 

Nickel Compounds - Metallic taste, nausea, tightness in chest, metal fume fever, allergic reaction. Chromium - Inhalation of fume with chromium (VI) compounds can cause irritation of the 

respiratory tract, lung damage and asthma-like symptoms. Swallowing chromium (VI) salts can cause severe injury or death. Dust on skin can form ulcers. Eyes may be burned by chromium (VI) 

compounds. Allergic reactions may occur in some people. Copper - Metal fume fever characterized by metallic taste, tightness of chest and fever. Symptoms may last 24 to 48 hours following 

overexposure. Strontium Compounds - Strontium salts are generally non-toxic and are normally present in the human body. In large oral doses, they may cause gastrointestinal disorders, vomiting 

and diarrhea. Lithium Compounds - Overexposure may cause tremor and nausea. Cobalt - Pulmonary irritation, cough, dermatitis, weight loss. Antimony Compounds - Irritation of nose, throat, 

eyes and skin. 

LONG-TERM (CHRONIC) OVEREXPOSURE EFFECTS: 

Welding Fumes - Excess levels may cause bronchial asthma, lung fibrosis, pneumoconiosis or "siderosis." Iron, Iron Oxide Fumes - Can cause siderosis (deposits of iron in lungs) which some 

researchers believe may affect pulmonary function. Lungs will clear in time when exposure to iron and its compounds ceases. Iron and magnetite (Fe3O4) are not regarded as fibrogenic materials. 

Manganese - Long-term overexposure to manganese compounds may affect the central nervous system. Symptoms may be similar to Parkinson's disease and can include slowness, changes in 

handwriting, gait impairment, muscle spasms and cramps and less commonly, tremor and behavioral changes. Employees who are overexposed to manganese compounds should be seen by a 

physician for early detection of neurologic problems. Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central nervous 

system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and spastic gait. Titanium Dioxide - Pulmonary irritation 

and slight fibrosis. Silica (Amorphous) - Research indicates that silica is present in welding fume in the amorphous form. Long term overexposure may cause pneumoconiosis. Noncrystalline forms of 

silica (amorphous silica) are considered to have little fibrotic potential. Fluorides - Serious bone erosion (Osteoporosis) and mottling of teeth. Molybdenum, Cerium Oxide - Prolonged overexposure 

may result in loss of appetite, weight loss, loss of muscle coordination, difficulty in breathing and anemia. Calcium Oxide - Prolonged overexposure may cause ulceration of the skin and perforation of 

the nasal septum, dermatitis and pneumonia. Aluminum Oxide - Pulmonary fibrosis and emphysema. Magnesium, Magnesium Oxide - No adverse long term health effects have been reported in the 

literature. Barium - Long term overexposure to soluble barium compounds may cause nervous disorders and may have deleterious effects on the heart, circulatory system and musculature. Nickel, 

Nickel Compounds - Lung fibrosis or pneumoconiosis. Studies of nickel refinery workers indicated a higher incidence of lung and nasal cancers. Chromium - Ulceration and perforation of nasal 

septum. Respiratory irritation may occur with symptoms resembling asthma. Studies have shown that chromate production workers exposed to hexavalent chromium compounds have an excess of 

lung cancers. Chromium (VI) compounds are more readily absorbed through the skin than chromium (III) compounds. Good practice requires the reduction of employee exposure to chromium (III) 

and (VI) compounds. Copper - Copper poisoning has been reported in the literature from exposure to high levels of copper. Liver damage can occur due to copper accumulating in the liver 

characterized by cell destruction and cirrhosis. High levels of copper may cause anemia and jaundice. High levels of copper may cause central nervous system damage characterized by nerve fiber 

separation and cerebral degeneration. Strontium Compounds - Strontium at high doses is known to concentrate in bone. Major signs of chronic toxicity, which involve the skeleton, have been 

labeled as "strontium rickets". Lithium Compounds - May be considered as potentially teratogenic. Cobalt - Repeated overexposure to cobalt compounds can produce reduced pulmonary function, 

diffuse nodular fibrosis of lungs and respiratory hypersensitivity. Antimony Compounds - Metal fume fever, dermatitis, keratitis, conjunctivitis and ulceration and perforation of the nasal septum. 

Avoid conditions in which fresh hydrogen will react with antimony to form stibine which is extremely toxic. 

415889 April 30, 2009 Page 2 of 3

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing impaired lung functions (asthma-like conditions). Persons with a pacemaker should not go near welding and cutting 

operations until they have consulted their doctor and obtained information from the manufacturer of the device. Respirators are to be worn only after being medically cleared by your companydesignated 

physician. 

EMERGENCY AND FIRST AID PROCEDURES: Call for medical aid. Employ first aid techniques recommended by the American Red Cross. Eyes & Skin: If irritation or flash burns develop after 

exposure, consult a physician. 

CARCINOGENICITY: Chromium VI compounds, nickel compounds and silica (crystalline quartz) are classified as IARC Group 1 and NTP Group K carcinogens. Titanium dioxide compounds, antimony 

trioxide compounds and cobalt compounds are classified as IARC Group 2B carcinogens. Chromium VI compounds, cobalt compounds, nickel compounds, silica (crystalline quartz) and welding fumes 

must be considered as carcinogens under OSHA (29 CFR 1910.1200). 

CALIFORNIA PROPOSITION 65: For Group C and D products: WARNING: This product contains or produces a chemical known to the State of California to cause cancer and birth defects (or other 

reproductive harm). (California Health & Safety Code Section 25249.5 et seq.) For Group A and B products: WARNING: This product, when used for welding or cutting, produces fumes or gases 

which contain chemicals known to the State of California to cause birth defects and, in some cases, cancer. (California Health & Safety Code Section 25249.5 et seq.) 

SECTION 7 - PRECAUTIONS FOR SAFE HANDLING & USE/APPLICABLE CONTROL MEASURES 

Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1; Safety in Welding and Cutting published by the American 

Welding Society, P.O. Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29 CFR 1910), U.S. Government Printing Office, Washington, DC 20402 for more detail on any of the following. 

VENTILATION: Use enough ventilation, local exhaust at the arc or both to keep the fumes and gases below PEL/TLVs in the worker's breathing zone and the general area. Train the welder to keep his 

head out of the fumes. 

RESPIRATORY PROTECTION: Use NIOSH approved or equivalent fume respirator or air supplied respirator when welding in confined space or where local exhaust or ventilation does not keep 

exposure below PEL/TLVs. 

EYE PROTECTION: Wear helmet or use face shield with filter lens. As a rule of thumb begin with Shade Number 14. Adjust if needed by selecting the next lighter and/or darker shade number. 

Provide protective screens and flash goggles, if necessary, to shield others. 

PROTECTIVE CLOTHING: Wear hand, head and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1. At a minimum this includes welder's gloves 

and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection as well as dark nonsynthetic clothing. Train the welder not to touch live electrical parts and to insulate 

himself from work and ground. 

PROCEDURE FOR CLEANUP OF SPILLS OR LEAKS: Not applicable 

WASTE DISPOSAL: Prevent waste from contaminating surrounding environment. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full 

compliance with Federal, State and Local regulations. 

SPECIAL PRECAUTIONS (IMPORTANT): Maintain exposure below the PEL/TLVs. Use industrial hygiene monitoring to ensure that your use of this material does not create exposures which exceed 

PEL/TLVs. Always use exhaust ventilation. Refer to the following sources for important additional information: ANSI Z49.1 from the American Welding Society, P.O. Box 351040, Miami, FL 33135 and 

OSHA (29 CFR 1910) from the U.S. Department of Labor, Washington, DC 20210. 

Hobart Brothers Company believes this data to be accurate and to reflect qualified expert opinion regarding current research. However, Hobart Brothers Company cannot make any expressed or 

implied warranty as to this information. 

415889 April 30, 2009 Page 3 of 3
















Item Name 

Part Number/Trade Name CARBON STEEL ELECTRODE 

PROSTAR/ ELECTRODE WELDING 

National Stock Number 3439011686208 

CAGE Code AB168 

Part Number Indicator A 

MSDS Number 194367 

HAZ Code B 


Manufacturer Name SIDERGAS 

Street VIALE RIMEMBRANZA #17 37010 S 

City AMBROGIO (VERNON) 

Country IT 

Emergency Phone 800-424-9300 (CHEMTREC) 

MSDS Preparer's Information 

Date MSDS Prepared/Revised 01JAN00 

Active Indicator Y 

Alternate Vendors 

Page 1 of 4 

No Changes as of April 2011 


4/21/2011



Appearance/Odor WELDING ELECTRODE ROLL 

Boiling Point N/A 

Melting Point N/A 

Vapor Pressure N/A 

Specific Gravity 1 

Chemical pH N/A 

Container Pressure Code 1 

Temperature Code 4 

Product State Code S 


Flash Point Method UNK 

Lower Explosion Limit UK 

Upper Explosion Limit UK 

Extinguishing Media NON-FLAMMABLE 

Special Fire Fighting Procedures WELDING ARC AND SPARKS CAN 

IGNITE COMBUSTIBLE AND 

FLAMMABLE PRODUCTS 

Unusual Fire/Explosion Hazards SEE ABOVE 


Stability N/K 

Stability Conditions to Avoid UNKNOWN 

Materials to Avoid NONE LISTED 

Hazardous Decomposition Products CARBON MONOXIDE AND CARBON 

DIOXIDE, OZONE AND NITROGEN 

OXIDES MAY BE FORMED BY THE 

RADIATION FROM THE ARC 

Hazardous Polymerization UK 

Polymerization Conditions to Avoid NONE LISTED 


Health Hazards - Acute and Chronic ELECTRIC ARC WELDING MAY 

CREATE ONE OR MORE OF THE 

FOLLOWING HEALTH HAZARDS: 

FUMES AND GASES CAN BE 

DANGEROUS TO YOUR HEALTH. 

COMMON ENTRY IS INHALATION. 

SHORT TERM OVER EXPOSURE TO 

WELDING FUMES MAY RESULT IN 

DISCOMFORT SUCH AS DIZZINESS, 

NAUSEA, OR DRYNESS OR 

IRRITATION OF NOSE, THROAT, OR 


Page 2 of 4 

4/21/2011


EYES. LONG TERM MAY FEAD TO 

SIDEROSIS, AND AFFECT 

PULMONARY FUNCTION. ARC RAYS 

CAN INJURE EYES AND BURN SKIN. 

ELECTRIC SHOCK CAN KILL 

Carcinogenity: NTP UK 

Carcinogenity: IARC UK 

Carcinogenity: OSHA UK 

Explanation of Carcinogenity NONE LISTED 

Symptoms of Overexposure SEE ABOVE 

Medical Cond. Aggrevated by Exposure NONE LISTED 

Emergency/First Aid Procedures NONE LISTED 


Steps if Material Released/Spilled WILL NOT SPILL 

Waste Disposal Method IN ACCORDANCE WITH STATE, 

LOCAL, AND FEDERAL 

REGULATIONS 

Handling and Storage Precautions NONE LISTED 

Other Precautions NONE LISTED 


Respiratory Protection USE RESPIRABLE FUME RESPIRATOR 

OR AIR SUPPLIED RESPIRATOR 

WHEN WELDING IN CONFINED 

SPACES. OR GENERAL WORK AREA 

WHEN LOCAL EXHAUST OR 

VENTILATION DOES NOT KEEP 

EXPOSURE BELOW TLV 

Ventilation LOCAL EXHAUST 

Protective Gloves WELDERS GLOVES 

Eye Protection PROTECTIVE FACE SHIELD 

Other Protective Equipment ARM PORTECTORS, APRON, HATS, 

SHOULDER PROTECTION. EYEWASH 

Work Hygenic Practices WASH HAND AFTER HANDLING 

MATERIAL 


Protect Eye NO 

Protect Skin NO 

Protect Respiratory NO 

Chronic Indicator UNKNOWN 

Contact Code UNKNOWN 

Fire Code UNKNOWN 


Page 3 of 4 

4/21/2011


Health Code UNKNOWN 

React Code UNKNOWN 



Volatile Organic Compounds (P/G) 0 

Volatile Organic Compounds (G/L) 0 



Ingredient Name CARBON STEEL WIRE 


Percent 100 




Ingredient Name (MNCPD) TOTAL MANGANESE 


Percent 2 




Ingredient Name (CUCPD) COPPER 


Percent 0.5 




Ingredient Name IRON 


Percent 0 




Page 4 of 4 

4/21/2011

No change as of April 2011


-1- 





Product Name: ESAB MILD STEEL COVERED ELECTRODES 

Application: Arc Welding 

Classification: AWS A5.4 


Telephone No.: 1-717-637-8911, 1-800-933-7070 




Emergency Overview: Coated metal rods in varying colors. These products are normally not considered hazardous as shipped. 

Gloves should be worn when handling to prevent contaminating hands with product dust. 

These products contain titanium dioxide which is possibly carcinogenic. These products contain quartz, but normally not in an 

inhalable fraction. Quartz can cause silicosis and may cause cancer. 

Avoid eye contact or inhalation of dust from these products. Skin contact is normally no hazard but should be avoided to prevent 

possible allergic reactions. 

Persons with a pacemaker should not go near welding or cutting operations until they have consulted their doctor and obtained 

information from the manufacturer of the device. 

When these products are used in a welding process, the most important hazards are heat, radiation, electric shock and welding 

fumes. 




Fumes: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or 

irritation of the nose, throat or eyes. Chronic overexposure to welding fumes may affect pulmonary function. 





These products are preparations of core wire with extruded coating. 


Hazard 


NTP 

OSHA 

List (4) 

Aluminum Oxide 1344-28-1 215-691-6 No -- -- -- 

Calcium Carbonate 1317-65-3 215-279-6 No -- -- -- 

Calcium Fluoride 7789-75-5 232-188-7 No -- -- -- 

Cellulose 9004-34-6 232-674-9 No -- -- -- 

Iron and Iron Oxides 7439-89-6 231-096-4 No -- -- -- 

Manganese 7439-96-5 231-105-1 No -- -- -- 

Mineral Silicates All considered to be quartz 

Bentonite Clays 1302-78-9 215-108-5 No -- -- -- 

Chlorite 14808-60-7 238-878-4 T; R45 1 K -- 

Feldspar 14808-60-7 238-878-4 T; R45 1 K -- 

Hectorite 14808-60-7 238-878-4 T; R45 1 K -- 

Pyrropholite 14808-60-7 238-878-4 T; R45 1 K -- 

Wollanstanite 14808-60-7 238-878-4 T; R45 1 K -- 

Zircon 14808-60-7 238-878-4 T; R45 1 K -- 

Potassium Titanate 12030-97-6 234-748-6 No -- -- -- 

Silicate Binder (Potassium Silicate) 1312-76-1 215-199-1 No -- -- -- 

Silicate Binder (Sodium Silicate) 1344-09-8 215-687-4 No -- -- -- 

Silicon 7440-21-3 231-130-8 No -- -- --


-2- 




Hazard 


NTP 

OSHA 

List (4) 

Silicon Dioxide 14808-60-7 238-878-4 T; R45 1 K -- 

Sodium Titanate 12034-34-3 234-802-9 No -- -- -- 

Titanium Oxide 13463-67-7 236-675-5 No ## -- -- 

Zirconium Compounds -- -- No -- -- -- 

(1) 


(2) 



(3) 



(4) 

Carcinogen listing according to OSHA, Occupational Safety & Health Administration (USA). 

## Presently designated to become 2B with publication of monograph. 

Product Trade Name Mn CaCO3 CaF2 Si SiO2 

APPROXIMATE COMPOSITION (Wt. %) 

Silicate 

Binder 

TiO2 

Mineral 

Silicates 

Cellulose FexOy Al2O3 

ESAB 

6010 1-2 -- -- --


-3- 




No specific recommendations for welding consumables. Welding arcs and sparks can ignite combustible and flammable 

materials. Use the extinguishing media recommended for the burning materials and fire situation. Wear self-contained breathing 

apparatus as fumes or vapors may be harmful. 


Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up and placed into a container. 

Wear proper protective equipment while handling these materials. Do not discard as refuse. 




Handling: 

Handle with care to avoid stings and cuts. Wear gloves when handling welding consumables. Avoid exposure to dust. Do not 

ingest. 


Storage: 

Keep separate from chemical substances like acids and strong bases, which could cause chemical reactions. 


Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust. 

Engineering measures: 

Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and general area. 

Keep working place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate 

conductive parts. Check condition of protective clothing and equipment on a regular basis. 

Personal protective equipment: 

Use respirator or air supplied respirator when welding or brazing in a confined space, or where local exhaust or ventilation is not 

sufficient to keep exposure values within safe limits. Use special care when welding painted or coated steels since hazardous 

substances from the coating may be emitted. Wear hand, head, eyes, ear and body protection like welders gloves, helmet or 

face shield with filter lens, safety boots, apron, arm and shoulder protection. Keep protective clothing clean and dry. 


following limits can be used as guidance. For information about welding fume analysis refer to Section 10. 



Aluminum Oxide (as Al) 1344-28-1 1** 15*, 5** 

Calcium Carbonate 1317-65-3 Withdrawn 15*, 5** 

Calcium Fluoride (as F) 7789-75-5 2.5 2.5 

Cellulose 9004-34-6 10 15*, 5** 

Iron and Iron Oxides 7439-89-6 5** 10 (fume) 

Manganese & 

Manganese compounds (as Mn) 

Mineral Silicates (no exposure anticipated) 

All substances with CAS of 14808-60-7 are quartz. 

7439-96-5 0.2 5 Ceiling 

Bentonite Clays 1302-78-9 None None 

Chlorite Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Feldspar Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Hectorite Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Pyrropholite Silica-Crystalline- 

14808-60-7 0.025** 10 mg/m 

Quartz 

3 ** 

%SiO2+2 

Wollanstanite Silica-Crystalline- 

14808-60-7 0.025** 10 mg/m 

Quartz 

3 ** 

%SiO2+2 

Zircon Silica-Crystalline-Quartz 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Potassium Titanate (powder) 12030-97-6 None None


-4- 





Silicate Binder (Potassium Silicate 

& Sodium Silicate) 

1312-76-1 

1344-09-8 

None None 

Silicon (nuisance dust) 7440-21-3 Withdrawn 15*, 5** 

Silicon Dioxide (quartz) 14808-60-7 0.025** 10 mg/m 3 ** 

%SiO2+2 

Sodium Titanate (powder) 12034-34-3 None None 

Titanium Oxide 13463-67-7 10 15* 

Zirconium & Zirconium Compounds 7440-67-7 5 , 10 (STEL) 5 

(1) 


(2) 



* Total dust, ** Respirable fraction, *** Inhalable fraction. 

NOTE: Some of these products may not contain all of the materials listed. For details of composition, refer to the COMPOSITION 

TABLE in Section 3. 


Appearance: Solid, non-volatile with varying color 

Melting point: >1300°C / >2300ºF 


General: These products are only intended for normal welding purposes. 

Stability: These products are stable under normal conditions. 

Reactivity: Contact with chemical substances like acids or strong bases could cause generation of gas. 

When these products are used in a welding process, hazardous decomposition products would include those from the volatilization, 

reaction or oxidation of the materials listed in Section 3 and those from the base metal and coating. 

The amount of fumes generated from manual metal arc welding varies with welding parameters and dimensions but is generally no more 

than 5 to 15 g/kg consumable. Fumes from these products may contain compounds of the following chemical elements: Fe, O, Mn, Zr, 

F, Na, Si, K, Ca, Al, Mg and Ti. The rest is not analyzed, according to available standards. 

Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in Section 

8. Manganese has a low exposure limit, in some countries, that may be easily exceeded. 

Reasonably expected gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the welding 

area can be affected by the welding process and influence the composition and quantity of fumes and gases produced. 


Inhalation of welding fumes and gases can be dangerous to your health. Classification of welding fumes is difficult because of varying 



Acute toxicity: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or irritation 

of the nose, throat or eyes. 

Chronic toxicity: Overexposure to welding fumes may affect pulmonary function. Overexposure to manganese and manganese 



disturbances and spastic gait. Inhalable quartz is a respiratory carcinogen; however, the process of welding converts 

crystalline quartz to the amorphous form which is not considered to be a carcinogen. 


Welding consumables and materials could degrade/weather into components originating from the consumables or from the materials 

used in the welding process. Avoid exposure to conditions that could lead to accumulation in soils or groundwater. 


Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal and local 

regulations. Use recycling procedures if available. 

USA RCRA: These products are not considered hazardous waste if discarded. 

Residues from welding consumables and processes could degrade and accumulate in soils and groundwater. Welding slag from these 

products typically contain mainly the following components originating from the coating of the electrode: Fe, O, Mn, Zr, F, Na, Si, K, Ca, 

Al, Mg and Ti.


-5- 




No international regulations or restrictions are applicable. 



label. Observe any federal and local regulations. Take precautions when welding and protect yourself and others. 

WARNING: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate ventilation. 




Canada: WHMIS classification: Class D; Division 2, Subdivision A 

Canadian Environmental Protection Act (CEPA): All constituents of these products are on the Domestic Substance List (DSL). 

USA: Under the OSHA Hazard Communication Standard, these products are considered hazardous. 

These products contain or produce a chemical known to the state of California to cause cancer and birth defects (or other 


United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or are 





Product is a solid solution in the form of a solid article. -- -- 


Response Center and to your Local Emergency Planning Committee. 


As shipped: Immediate In use: Immediate delayed 





Manganese 1.0% de minimis concentration 


This Safety Data Sheet has been revised due to modifications to several paragraphs and/or new format. This SDS supersedes 7989-H. 

Refer to ESAB “Welding and Cutting - Risks and Measures”, F52-529 “Precautions and Safe Practices for Electric Welding and Cutting” 

and F2035 “Precautions and Safe Practices for Gas Welding, Cutting and Heating” available from ESAB, and to: 



Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by Welding 

and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North Le Jeune 

Road, Miami, Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org. 


371954, Pittsburgh, PA 15250-7954. 




Protection Association, 1 Batterymarch Park, Quincy, MA 02169.


-6- 



UK: WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of health and 

safety”. 



These products have been classified according to the hazard criteria of the CPR and the SDS contains all the information 


R-phrases: R45 – May cause cancer. 

ESAB requests the users of these products to study this Safety Data Sheet (SDS) and become aware of product hazards and safety 

information. To promote safe use of these products a user should: 

- notify its employees, agents and contractors of the information on this SDS and any product hazards/safety information. 

- furnish this same information to each of its customers for these products. 


The information herein is given in good faith and based on technical data that ESAB believes to be reliable. Since the conditions of use 

are outside our control, we assume no liability in connection with any use of this information and no warranty, expressed or implied is 

given. Contact ESAB for more information.

Boo ho 

Date: 7/19/2010 MSDS No.: CAN-W400-C 

Trade Name: Super Glaze Aluminum Wires/Rods 

Sizes: All 

Supersedes: 8/1/07 

M A T E R I A L S A F E T Y D A T A S H E E T 

For Welding Consumables and Related Products 

Conforms to Workplace Hazardous Materials Information System (WHMIS) Rev. November, 1988 

Section I & II - Preparation and Product Information 

Product Type: Aluminum Electrodes and Rods 

The Lincoln Electric Company of Canada LP 

179 Wicksteed Avenue 

Toronto, Ontario M4G 2B9 CANADA 

Phone: (416) 421-2600 

Products: Super Glaze 1100, 4043, 4047, 5087, 5183, 5356, 

5554, 5556, 5754 

Prepared by The Lincoln Electric Company, Cleveland, Ohio, USA 

(216) 481-8100, on the date shown above. 

Section III - Hazardous Ingredients (1) 

I M P O R T A N T ! 

This section covers the materials from which this product is manufactured. The fumes and gases produced during welding with the normal use of this 

product are covered by Section VII; see it for industrial hygiene information. 

CAS Number shown is representative for the ingredients listed. 

(1) The term “hazardous” in “Hazardous Ingredients” should be interpreted as a term required and defined in the Hazardous Products Act and does 

not necessarily imply the existence of any hazard. 

TLV 

Ingredients: CAS No. Wt. % mg/m 3 

LD50 LC50 mg/m 


3 


Aluminum wire 100 10* 

Nominal wire composition: 

Aluminum 7429-90-5 87 - 100 10** Not Available Not Available 

Silicon (4043 and 4047 only) 7440-21-3 5 - 13 10* Not Available Not Available 

Magnesium (5087, 5183, 5356, 5554, 5556, 5754 only) 7439-95-4 < 5 10* 

230 mg/kg LDLo 

(oral/dog) 

Not Available 

Manganese (5087, 5183, 5356, 5554, 5556, 5754 only) 7439-96-5 < 1 0.2 

9 g/kg 

(oral/rat) 

2.3 LCLo 

(inhalation/human) 

Copper (1100 only) 7440-50-8 < 0.5 0.2(a) 


(oral/human)gastrointestinal 

Not Available 

Chromium (5087, 5183, 5356, 5554, 5556 only) 7440-47-3 < 0.5 0.5(b) 


(intravenous/rat)tumorigenic Not Available 

Zirconium (5087 only) 7440-67-7 < 0.5 5 Not Available Not Available 

Notes: 

(*) Not listed. Nuisance value maximum is 10 milligrams per cubic meter. 

(**) TLV for aluminum welding fume is 5 mg/m 3 . 

(a) Values are for copper fume. 

(LDLo, LCLo) Lowest published toxic concentration. 

(b) The OSHA PEL for chromium (VI) is 5 micrograms (0.005 

milligrams) per cubic meter. The TLV for water soluble 

chromium (VI) is 0.05 milligrams per cubic meter and the 

TLV for insoluble chromium (VI) is 0.01 milligrams per 

cubic meter. 

Section IV - Physical Data 

Physical data such as odor, vapor pressure, density, evaporation rate and freezing or boiling points are not listed as they are not applicable to 

this product and its use. 

Section V - Hazard Data 

Non Flammable; Welding arc and sparks can ignite combustibles and flammable products. See CSA W117.2 Section 9.7 as referenced in 

Section VIII. Product is inert, no special handling or spill procedures required. 

Rev 9/07 (CONTINUED ON SIDE TWO)

Product: Super Glaze Aluminum Wires/Rods 

Date: 7/19/2010 

Section VI - Health Hazard Data and Toxicological Properties 

Acute Lethality Values: LC50 means the concentration of a substance in air that when administered by means of inhalation over a specified length of time 

in an animal assay, is expected to cause the death of 50% of a defined animal population. 

LD50 means the single dose of a substance that, when administered by a defined route in an animal assay, is expected to cause the death of 50% of 

a defined animal population. 

Threshold Limit Value: The ACGIH recommended general limit for Welding Fume NOS - (Not Otherwise Specified) is 5 mg/m 3 . 

The TLV-TWA is the time-weighted average concentration for a normal 8-hour workday and a 40 hour workweek, to which nearly all workers may be 

repeatedly exposed, day after day, without adverse effect. See Section VII for specific fume constituents which may modify this TLV. Threshold Limit 

Values are figures published by the American Conference of Government Industrial Hygienists. 

Effects of Overexposure: Electric arc welding may create one or more of the following health hazards: 

Fumes and Gases can be dangerous to your health. Common entry is by inhalation. Other possible routes are skin contact and ingestion. 

Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or irritation of 

nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema). 

Long-term (chronic) overexposure to welding fumes may affect pulmonary function. Bronchitis and some lung fibrosis have been 

reported. Chromates may cause ulceration and perforation of the nasal septum. Liver damage and allergic reactions, including skin 

rash, have been reported. Chromates contain the hexavalent form of chromium. Hexavalent chromium and its compounds are on the 

IARC (International Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a cancer risk to humans. 

Arc Rays can injure eyes and burn skin. Skin cancer has been reported. 

Electric Shock can kill. If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such as 

sitting, kneeling or lying, or if there is a high risk of unavoidable or accidental contact with workpiece, use the following equipment: Semiautomatic DC 

Welder, DC Manual (Stick) Welder, or AC Welder with Reduced Voltage Control. 

Section VII - Reactivity Data 

Hazardous Decomposition Products: Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon 

the metal being welded, the process, procedure and electrodes used. 

Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal 

being welded (such as paint, plating, or galvanizing), the number of welders and the volume of the worker area, the quality and amount of ventilation, the 

position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon 

vapors from cleaning and degreasing activities.) 

When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed in 

Section III. Decomposition products of normal operation include those originating from the volatilization, reaction, or oxidation of the materials shown in 

Section III, plus those from the base metal and coating, etc., as noted above. 

Reasonably expected fume constituents of this product would include: Primarily aluminum oxide; secondarily magnesium oxide (for 5356, 5087, 

5183, 5554, 5556, 5754) and complex oxides of silicon (for 4043 and 4047). 

Maximum fume exposure guideline and PEL for this product is 5.0 milligrams per cubic meter. 

Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. 

Determine the composition and quantity of fumes and gases to which workers are exposed by taking an air sample from inside the welder's helmet if worn or 

in the worker's breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1, F1.2, F1.3 and F1.5, available from the 

American Welding Society, 550 N.W. LeJeune Road, Miami, FL 33126. 

Section VIII - Preventive Measures and Precautions for Safe Handling and Use 

Read and understand the manufacturer's instruction and the precautionary label on the product. Request Lincoln Safety Publication E205. See Canadian 

Standards Association Standard CSA-W117.2 "Safety in Welding, Cutting, and Allied Processes" published by the Canadian Standards Association, 178 

Rexdale Blvd., Rexdale, Ontario M9W1R3 for more details on many of the following: 

Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases from the worker's breathing zone and the general area. 

Train the welder to keep his head out of the fumes. Keep exposure as low as possible. 

Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or general work area when local exhaust 

or ventilation does not keep exposure below TLV. 

Eye Protection: Wear helmet or use face shield with filter lens shade number 12 or darker. Shield others by providing screens and flash goggles. 

Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See W117.2. 

At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark 

substantial clothing. Train the welder not to permit electrically live parts or electrodes to contact skin or clothing or gloves if they are wet. Insulate from work 

and ground. 

Disposal Information: Discard any product, residue, disposable container, or liner as ordinary waste in an environmentally acceptable manner according to 

Federal, State and Local regulations unless otherwise noted. No applicable ecological information available. 

Section IX - Emergency and First Aid Procedures 

Call for medical aid. Employ first aid techniques recommended by the Canadian Red Cross. IF BREATHING IS DIFFICULT give oxygen. IF NOT 

BREATHING employ CPR (Cardiopulmonary Resuscitation) techniques. IN CASE OF ELECTRICAL SHOCK, turn off power and follow recommended 

treatment. In all cases call a physician.






by OSHA, NTP, or HARRIS PRODUCTS GROUP as being a potential carcinogen. Use of this product may expose you or others to fumes and 

gases at levels exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational 

Safety and Health Administration (OSHA) The information contained herein relates only to the specific product. If the product is combined with other 

materials, all component properties must be considered. ALWAYS CONSULT THE LATEST VERSION OF THE MSDS. MATERIAL SAFETY DATA 

SHEETS ARE AVAILABLE FROM HARRIS PRODUCTS GROUP. 513-754-2000 www.harrisproductsgroup.com 


To Harris Products Group knowledge, the information and recommendations contained in this publication are accurate as of the date prepared. However, 

accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by the Harris 

Products Group to the absolute correctness or sufficiency of any representation contained in this publications; Harris Products Group assumes no 

responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this publications, or that other 

additional measures may not be required under particular or exceptional conditions or circumstances . Data may be changed from time to time. 



TRADE NAME (AS LABELED): W1060 (R45) - W1200 (R60) Welding Rods 



PRODUCT USE: Metal Oxyfuel Gas Welding 






DATE OF PREPARATION: October 5, 2005 Revised 06/20/2007 

PRINT DATE: September 24, 2010 

2. COMPOSITION and INFORMATION ON INGREDIENTS 




Iron (exposure limits are 

for iron oxide dust and 

fume [Fe2O3], as Fe) 

Copper (exposure limits 

are for copper fume, as 

Copper) 

mg/m 3 

1309-37-1 Balance 5, A4 (Not 

Classifiable 

as a Human 

Carcinogen) 

mg/m 3 

mg/m 3 

® 

mg/m 3 

mg/m 3 

mg/m 3 


TWA = 5 

DFG MAK: 


Fraction) 


TLV-A4 

1317-38-0 0.30 0.2 NE 0.1 NE 100 NIOSH REL: 

TWA = 0.1 

DFG MAK: 


Fraction) 


average value 

NE = Not Established. See Section 16 for Definitions of Terms Used. NOTE (1): ACGIH has an established exposure limit for Welding Fumes, Not Otherwise 

Classified. The Threshold Limit Value is 5 mg/m 3 . NIOSH classifies welding fumes as carcinogens. Single values shown are maximum, unless otherwise 

noted. NOTE (2): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been 


W1060(R45) W1200(R60) PAGE 1 OF 8

2. COMPOSITION and INFORMATION ON INGREDIENTS (Continued) 


Manganese (exposure 

limits are for Manganese, 

elemental, inorganic 

compounds, and fume, 

as Mn) 

Low Hazard constituents each present 

in less than 1 percent 



mg/m 3 

mg/m 3 

mg/m 3 

7439-96-5 0.50 1.40 0.2 NE 1 (Vacated 

1989 PEL) 

mg/m 3 

5 Ceiling 

3 

(Vacated 

1989 

PEL) 

mg/m 3 

mg/m 3 


TWA: 1 

STEL: 3 

DFG MAK: 


Fraction) 


average value 




3 NE NE NE NE NE NE 







EMERGENCY OVERVIEW: This product consists of solid steel wire or rods (which may be copper coated), which are 

odorless. There are no immediate health hazards associated with the wire or rod form of this product. This product is not 

flammable nor reactive. If involved in a fire, this product may generate irritating iron fumes and a variety of iron 

compounds. Emergency responders must wear personal protective equipment suitable for the situation to which they are 

responding. 


During welding operations, the most significant route of overexposure 


INHALATION: Inhalation is not anticipated to be a significant route 

of over-exposure to the wire or rods. Inhalation of large amounts of 

particulates generated by this product during welding operations 

may result in pneumoconiosis (a disease of the lungs). Repeated 

over-exposures, via inhalation, to the dusts or fumes generated by 

this product may have adverse effects on the lungs with possible 

pulmonary edema and emphysema (life-threatening lung injuries). 


specific composition of welding fumes and gases. 

CONTACT WITH SKIN or EYES: Contact of the wire or rod form 

of this product with the skin is not anticipated to be irritating. 

Contact with the wire or rod form of this product can be physically 

damaging to the eye. Fumes generated during welding operations 

can be irritating to the skin and eyes. Symptoms of skin overexposure 

may include irritation and redness; prolonged or repeated 

skin over-exposures may lead to dermatitis. Contact with the 

molten core wire or rods will burn contaminated skin or eyes. 


significant route of over-exposure for any component of this 

product. 


HEALTH 

FLAMMABILITY 

REACTIVITY 



See 

Section 8 

(BLUE) 

(RED) 

(YELLOW) 

For routine industrial applications for the electrodes. 

0 

0 

0 

X 

See 

Section 8 


W1060(R45) W1200(R60) PAGE 2 OF 8

3. HAZARD IDENTIFICATION (Continued) 

INGESTION: Ingestion of the rods is not a likely route of exposure. If swallowed call physician immediately! Do not induce 

vomiting unless directed by medical personnel. Rinse mouth with water if person is conscious. Never give fluids or induce 

vomiting if person is unconscious, having convulsions, or not breathing. 




to this product and the fumes generated during welding operations are as follows: 


and eyes when exposed to fumes during welding operations. Inhalation of large amounts of particulates generated by this 

product during metal processing operations can result in pneumoconiosis (a disease of the lungs). Contact with the molten 

material will burn contaminated skin or eyes. 

CHRONIC: Chronic skin over-exposure to the fumes of this product during welding operations may produce dermatitis (red, 

inflamed skin). Repeated over-exposures to the fumes generated by this product via inhalation can have adverse effects on 

the lungs (e.g., pulmonary edema and emphysema). Repeated or prolonged ingestion exposures to > 50 100 mg of Iron per 

day can result in deposition of iron in the body tissues, which can cause disease. 

TARGET ORGANS: ACUTE: For fumes: Skin, eyes, respiratory system. CHRONIC: For fumes: Respiratory system, 

pancreas and liver. 





SKIN EXPOSURE: If fumes generated by welding operations involving this product contaminate the skin, begin 



EYE EXPOSURE: If fumes generated by welding operations involving this product enter the eyes, open victim's eyes while 



INHALATION: If fumes generated by welding operations involving this product are inhaled, remove victim to fresh air. If 


INGESTION: Ingestion of the rods is not a likely route of exposure. If swallowed call physician immediately! Do not induce 

vomiting unless directed by medical personnel. Rinse mouth with water if person is conscious. Never give fluids or induce 

vomiting if person is unconscious, having convulsions, or not breathing. 

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory, pancreas, and liver disorders may be 




FLASH POINT: Not flammable. NFPA RATING 









UNUSUAL FIRE AND EXPLOSION HAZARDS When involved in a fire, this 

material may decompose and produce irritating fumes containing iron 

compounds. The molten material can present a significant thermal hazard to 

firefighters. 



HEALTH 

0 

FLAMMABILITY 

0 

OTHER 

0 



REACTIVITY 

W1060(R45) W1200(R60) PAGE 3 OF 8

5. FIRE-FIGHTING MEASURES (Continued) 

SPECIAL FIRE-FIGHTING PROCEDURES: Not applicable. 


SPILL AND LEAK RESPONSE: Not applicable. 




Wash hands after handling this product. Do not eat or drink while handling this product. Use ventilation and other 

engineering controls to minimize potential exposure to this product. 


Use in a well-ventilated location. Avoid breathing fumes of this product during welding operations. Open containers on a 

stable surface. Packages of this product must be properly labeled. 

When this product is used during welding operations, follow the requirements of the Federal Occupational Safety and Health 

Welding and Cutting Standard (29 CFR 1910 Subpart Q) and the safety standards of the American National Standards 

Institute for welding and cutting (ANSI Z49.1). 

Store packages in a cool, dry location. Storage in an atmosphere that is wet, moist, or highly humid may lead to corrosion 

of this product. Store away from incompatible materials (see Section 10, Stability and Reactivity). 

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Not applicable 






(Composition and Information on Ingredients). If respiratory protection is needed (i.e., a Weld Fume Respirator, or Air-Line 

Respirator for welding in confined spaces), use only protection authorized in 29 CFR 1910.134 or applicable State 

regulations. Respiratory Protection is recommended to be worn during welding operations. Oxygen levels below 19.5% are 

considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, 

supplied air respirator with auxiliary self-contained air supply is required under OSHA’s Respiratory Protection Standard 

(1910.134-1998). 

EYE PROTECTION: Safety glasses. When this product is used in conjunction with welding, wear safety glasses, goggles, 

or face-shield with filter lens of appropriate shade number (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). 

HAND PROTECTION: Wear gloves for routine industrial use. When this product is used in conjunction with welding, wear 

gloves that protect from sparks and flame (per ANSI Z49.1-1988, “Safety in Welding and Cutting”). 

BODY PROTECTION: Wear body protection appropriate for task. 


The following information is for steel, a related compound: 


SPECIFIC GRAVITY (water = 1): 7.60 7.78 FREEZING/MELTING POINT: 1300 C (2372 F) 

SOLUBILITY IN WATER: Insoluble. pH: Not applicable. 

VAPOR PRESSURE, mm Hg @ 20 C: Not applicable. 

ODOR THRESHOLD: Not applicable. 

BOILING POINT: 3000 C (5432 F) 



APPEARANCE AND COLOR: This product consists of solid steel wire or rods (which may be copper coated), which are 

odorless. 

HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinctive characteristic of this product. 

W1060(R45) W1200(R60) PAGE 4 OF 8



DECOMPOSITION PRODUCTS: Iron oxides. 

NOTE: The composition and quality of welding fumes and gases are dependent upon the metal being welded, the process, 

the procedure, and the welding rods used. Other conditions that could also influence the composition and quantity of fumes 

and gases to which workers may be exposed include the following: any coatings on metal being welded (e.g., paint, plating, 

or galvanizing), the number of welders and the volume of the work area, the quality of ventilation, the position of the welder’s 

head with respect to the fume plume, and the presence of other contaminates in the atmosphere. When the welding rod is 

consumed, the fume and gas decomposition products generated are different in percent and form from the ingredients listed 

in Section 2 (Composition and Information on Ingredients). Fume and gas decomposition products, and not the ingredients 

in the welding rod, are important. Concentration of the given fume or gas component may decrease or increase by many 

times the original concentration. New compounds may form. Decomposition products of normal operations include not only 

those originating from volatilization, reaction, or oxidation of the product’s components but also those from base metals and 

any coating (as noted previously). The best method to determine the actual composition of generated fumes and gases is to 

take an air sample from inside the welder’s helmet if worn or in breathing zone. For additional information, refer to the 

American Welding Society Publication, “Fumes and Gases in the Welding Environment”. 

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids, strong oxidizers, mineral acids, some 

halogenated compounds. 


CONDITIONS TO AVOID: Avoid uncontrolled exposure to extreme temperatures and incompatible materials. 






IRON: 

TDLo (oral, child) = 77 mg/kg; BAH, gastrointestinal tract, blood effects 

MANGANESE: 

TCLo (inhalation, man) = 2300 g/m 3 ; BRN, central nervous system 

effects 


IRON OXIDE: : IARC Group 3 ( Not Classifiable as to Carcinogenicity to Humans), ACGIH-TLV-A4 (Not Classifiable as a Human Carcinogen) 

MANGANESE: EPA-D (Not Classifiable as to Human Carcinogenicity) 



IRRITANCY OF PRODUCT: Dusts or fumes of this product may be irritating to contaminated skin and eyes. Fumes may be 


SENSITIZATION TO THE PRODUCT: The components of this product are not known to be skin or respiratory sensitizers. 



Mutagenicity: This product is not reported to produce mutagenic effects in humans. 



exposed to relatively high doses of Copper (a component of this product) indicate teratogenic effects. 


animals exposed to relatively high doses of Copper (a component of this product) indicate adverse reproductive effects. 






BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) determined for the 


W1060(R45) W1200(R60) PAGE 5 OF 8



ENVIRONMENTAL STABILITY: The components of this product occur naturally in the environment and are expected to 

persist in the environment for an extended period of time. Iron will react with water and air to form a variety of stable iron 

oxides. 

EFFECT OF MATERIAL ON PLANTS or ANIMALS: The components of this product occur naturally in the environment 

and are essential for plant and animal life. This product is not expected to cause adverse effects on plant or animal life. 

Specific data on test animals are available but are not presented in this Material Safety Data Sheet. Other data are as 

follows: 

COPPER: 6 mg/day is harmful to rats. 1 g/day can be fatal to dogs. 18 g to sheep was fatal to all test subjects. 500 mg/kg to chicks is the maximum 

toxic level. Copper may concentrate to toxic levels in the food chain. 

EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not expected to cause adverse effects on aquatic life. The 

following information on components of this product. 

COPPER: Copper is concentrated by plankton by 1000 or more. Copper may concentrate to toxic levels in the food chain. 





EPA WASTE NUMBER: Not applicable to wastes consisting only of this product. 


THIS MATERIAL IS NOT HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION. 









TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is not considered 








SARA 304 

(40 CFR Table 302.4) 

SARA 313 

(40 CFR 372.65) 







U.S. CERCLA REPORTABLE QUANTITY (RQ): Copper = 5000 lbs (2270 kg) 


W1060(R45) W1200(R60) PAGE 6 OF 8







Manganese. 


Chemical Contaminants: Copper, 

Manganese. 


Mist, Manganese. 


Manganese. 


Manganese. 


Manganese. 

Michigan - Critical Materials Register: Copper. 


Copper Dust & Mists, Manganese. 


Substance List: Copper, Manganese. 


Substance List: Copper, Manganese. 


Reportable Quantities: Copper. 


Copper, Manganese. 


Copper Fume, Dust, & Mist, Manganese. 








product may contain chemicals, and when used for welding may produce fumes or gases containing chemicals, 

known 

to the State of California to cause cancer, and/or birth defects (or other reproductive harm.) 

LABELING (Precautionary Statements): 

WARNING! 

PROTECT yourself and others. Read and understand this information. 







general area. 







CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory. 


CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this 

product are not on the CEPA Priorities Substances Lists. 





858/565-0302 

DATE OF PRINTING: September 24, 2010 





guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by Harris Products Group as to the absolute correctness or 

sufficiency of any representation contained in this and other publications; Harris Products Group assumes no responsibility in connection therewith; nor 



W1060(R45) W1200(R60) PAGE 7 OF 8






professional association which establishes exposure limits. 

TLV - Threshold Limit Value - an airborne concentration of a 

substance, which represents conditions under which it is generally 

believed that nearly all workers, may be repeatedly exposed without 

adverse effect. The duration must be considered, including the 8-hour 

Time Weighted Average (TWA), the 15-minute Short Term Exposure 

Limit, and the instantaneous Ceiling Level. Skin absorption effects 

must also be considered. 


CPR - Canadian Product Regulations 

PEL - Permissible Exposure Limit - this exposure value means 

exactly the same as a TLV, except that it is enforceable by OSHA. The 

OSHA Permissible Exposure Limits are based in the 1989 PELs and 

the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338- 

35351 and 58: 40191). Both the current PELs and the vacated PELs 

are indicated. The phrase, “Vacated 1989 PEL,” is placed next to the 

PEL, which was vacated by Court Order. 

IDLH - Immediately Dangerous to Life and Health level represents a 

concentration from which one can escape within 30-minutes without 

suffering escape-preventing or permanent injury. The DFG - MAK is the 

Republic of Germany’s Maximum Exposure Level, similar to the U.S. 

PEL. NIOSH is the National Institute of Occupational Safety and 

Health, which is the research arm of the U.S. Occupational Safety and 

Health Administration (OSHA). NIOSH issues exposure guidelines 

called Recommended Exposure Levels (RELs). When no exposure 

guidelines are established, an entry of NE is made for reference. 

FLAMMABILITY LIMITS IN AIR: Much of the information related to fire 

and explosion is derived from the National Fire Protection Association 

(NFPA). LEL - the lowest percent of vapor in air, by volume, that will 

explode or ignite in the presence of an ignition source. UEL - the 

highest percent of vapor in air, by volume, that will explode or ignite in 

the presence of an ignition source. 

TOXICOLOGICAL INFORMATION 

Possible health hazards as derived from human data, animal studies, or 

from the results of studies with similar compounds is presented. 

Definitions of some terms used in this section are: LD50 - Lethal Dose 

(solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal 

Concentration (gases) which kills 50% of the exposed animals; ppm 

concentration expressed in parts of material per million parts of air or 

water; mg/m 3 concentration expressed in weight of substance per 

volume of air; mg/kg quantity of material, by weight, administered to a 

test subject, based on their body weight in kg. Data from several 

sources are used to evaluate the cancer-causing potential of the 

material. The sources are: IARC - the International Agency for 

Research on Cancer; NTP - the National Toxicology Program, RTECS - 

the Registry of Toxic Effects of Chemical Substances, OSHA and 

CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing 

potential to cause human cancer with rankings from 1 to 4. 

Subrankings (2A, 2B, etc.) are also used. Other measures of toxicity 

include TDLo, the lowest dose to cause a symptom and TCLo the 

lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, 

TCo, LCLo, and LCo, the lowest dose (or concentration) to cause 

death. BEI - Biological Exposure Indices, represent the levels of 

determinants which are most likely to be observed in specimens 



REGULATORY INFORMATION 


material. The acronyms used are: EPA is the U.S. Environmental 

Protection Agency. WHMIS is the Canadian Workplace Hazardous 

Materials Information System. DOT and TC are the U.S. Department of 

Transportation and Transport Canada, respectively. Superfund 

Amendments and Reauthorization Act (SARA); the Toxic 

Substance Control Act (TSCA); Marine Pollutant status according to 

the DOT; California's Safe Drinking Water Act (Proposition 65); the 

Comprehensive Environmental Response, Compensation, and 

Liability Act (CERCLA or Superfund); and various state regulations. 

This section also includes information on the precautionary warnings 

which appear on the materials package label. 

W1060(R45) W1200(R60) PAGE 8 OF 8

A Subsidiary of The ESAB Group, Inc. 


Revised: March 25, 2009 Supersedes: October 10, 2008 


Emergency Phone: 1-717-637-8911 or 1-800-424-9300 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

AlcoTec Wire Corporation 

2750 Aero Park Drive Traverse City, MI 49686-9263 USA Phone (231) 941-4111 

Sales and Marketing Fax (231) 941-9154 Administrative and Quality Control Fax (231) 941-1040 

alcotec@alcotec.com E-mail www.alcotec.com Web site 

SDS NO. 7994-G 

Chemical Formula: Mixture. 

Other Designations: AlcoTec ALMIGWELD (Aluminum spooled electrode) 

AlcoTec ALTIGWELD (Aluminum straight length welding rod) 

Aluminum Metallizing Wire (coils and spools) 

AlumaArc (Aluminum spooled electrode and straight length welding rod) 

Manufacturer: AlcoTec Wire Corporation, 2750 Aero Park Drive, Traverse City, MI 49686-9263 USA 

Product Use: Welding, Filler Metal, Metallizing, Brazing 

2. HAZARDS INFORMATION 


Solid, silvery, odorless. Non-flammable as supplied. Small chips, fine turnings, and dust from processing may 

ignite readily. 

Explosion/fire hazards may be present when (See Sections 5, 7 and 10 for additional information): 

Dust or fines are dispersed in the air. 

Fines or dust are in contact with other metal 

oxides (e.g., rust). 

Chips, fines, or dust are in contact with water. 

Molten aluminum is in contact with 

water/moisture or other metal oxides. 

Dust or fume from welding can cause eye, skin, or upper respiratory tract irritation; metal fume fever; lung 

diseases, neurological effects and other systemic effects. 

Potential Health Effects 

EYES: Fume can cause irritation. Ultraviolet radiation from welding can cause flash burns. 

SKIN: Can cause irritation. Ultraviolet radiation from welding can cause flash burns. 

INHALATION: Can cause respiratory tract irritation, metal fume fever, and other health effects listed below: 

Cancer hazard 

Aluminum is welded in a protective, inert atmosphere such as argon or helium using the MIG or TIG process. 

Welding processes generate welding fumes and an intense ultraviolet radiation that results in the formation of 

ozone, and oxides of nitrogen. Ultraviolet radiation from welding can also cause flash burns to the eyes and skin. 

The International Agency for Research on Cancer has classified welding fumes as possibly carcinogenic to 

humans (Group 2B). 

Exposure to low levels of ozone can cause irritation of the eyes, nose, and throat. Inhalation can cause chest 

tightness, headache, shortness of breath, cough, wheeze, nausea, and narrowing of airways. Symptoms 

disappear when removed from exposure. 

Exposure to high levels of ozone may cause acute respiratory distress with shortness of breath, pulmonary 

changes, hemorrhage, and pulmonary edema (fluid in the lungs). Symptoms of pulmonary edema may be 

delayed for one or more hours. Exposure of test animals and human tissue to high concentrations has shown 

chromosomal changes, reproductive effects, blood changes, and death from lung congestion. 

Oxides of nitrogen can cause irritation of the eyes, skin (when moist), and respiratory tract. Exposure to high 

levels of nitrogen oxides can cause delayed pulmonary edema (fluid in the lungs) which may be fatal. Nitric 

oxide can cause formation of methemoglobin, which decreases the blood’s ability to carry oxygen. Chronic 

overexposure can cause pulmonary fibrosis (scarring of the lungs). 

Overexposure to Aluminum dust/fines and fumes can cause reduced lung function and may be associated with 

neurological effects.




Overexposure to magnesium oxide fumes can cause respiratory tract irritation and fever, chills, shortness of 

breath, and malaise (metal fume fever). Temporary symptoms can include fever, chills, nausea, vomiting, and 

muscular pain. 

Chronic exposure to inert dusts of silicon can cause increased airway resistance and contributes to chronic 

bronchitis. Intratracheal administration of silicon in rabbits produced significant pulmonary lesions. 

Exposure to zinc oxide fumes subsequent to burning, welding, and molten metal work can result in fever, 

chills, shortness of breath, and malaise (metal fume fever), and upper respiratory tract irritation. Temporary 

symptoms can include fever, chills, nausea, vomiting, and muscular pain. Exposure to dust or fines presents a 

low health risk by inhalation. 




Hexavalent chromium (Chrome VI) can cause asthma, kidney damage, primary irritant dermatitis, sensitization 

dermatitis, skin ulceration, and pulmonary edema (fluid in the lungs). Chronic inhalation or overexposure has 

been associated with lung, nasal, and gastrointestinal cancer. Hexavalent chromium is listed as carcinogenic 

to humans by IARC (Group 1)*. Chromium and some of its compounds are listed as carcinogenic by the NTP. 

Hexavalent chromium compounds may be generated during welding operations, with alloys containing 

chromium. A SIGNIFICANT AMOUNT OF THE CHROMIUM IN THE FUMES CAN BE HEXAVALENT 

CHROMIUM, WHICH HAS A VERY LOW EXPOSURE LIMIT, 0.005 mg/m 3 (5µg/m 3 ). 

The potential for overexposure to copper fume may exist when welding, flame cutting, etc. Overexposure to 

copper dust/mists can cause irritation of the eyes, skin, and upper respiratory tract. Chronic overexposure may 

result in blood disorders (anemia), and skin and hair discolorations. Overexposure to copper fume can result in 

respiratory tract irritation, nausea, and fever, chills, shortness of breath and malaise (metal fume fever). 

Nickel dust and fume can cause skin sensitization, allergic contact dermatitis, and conjunctivitis. Chronic 

inhalation of high levels of nickel can cause irritation of airways and lungs, lung fibrosis (scarring of the lungs), 

nasal septum perforation, nasal sinusitis, respiratory sensitization and asthma. Nickel compounds have been 

associated with cancer of lungs, larynx, and paranasal sinuses in humans. Nickel compounds are listed on the 

NTP and are listed as carcinogenic to humans by IARC (Group 1)*. Nickel metal is possibly carcinogenic to 

humans as defined by IARC (Group 2B)*. 

Beryllium can cause irritant dermatitis, allergic contact dermatitis, and skin granulomas. Inhalation of excessive 

levels of beryllium can result in acute pneumonitis (inflammation of the lung tissues). 

Beryllium can cause lung sensitization in susceptible individuals. Chronic inhalation of dust and fumes by 

these sensitized individuals can result in a serious, progressive disease called Chronic Beryllium Disease 

(CBD). This disease, often misdiagnosed as sarcoidosis, is an allergic condition in which the lung tissues 

become inflamed. This inflammation, sometimes accompanied with fibrosis (lung scarring), restricts the uptake 

of oxygen into the blood stream. CBD can, over time, be fatal. 

Inhalation of beryllium has produced lung tumors in animals. Beryllium is listed on the NTP and is known to be 

carcinogenic to humans by IARC (Group 1)*. (See Section 8) 

Lead inorganic dust and fume is listed as a possibly carcinogenic to humans by IARC Group 2B*. 

Overexposure to lead dust or fume can cause weakness of extremities (peripheral neuropathy), stomach 

disturbances, harm to the kidneys, liver, central nervous system, blood and blood forming tissues, and 

reproductive organs. Overexposure to lead has been associated with human reproductive effects (e.g. 

reduced fertility and damage to the fetus of exposed pregnant women). Lead is a cumulative toxic metal by 

inhalation or ingestion. 

Warning: This product contains or produces a chemical known to the State of California to cause cancer and 

birth defects (or other reproductive harm). (California Health & safety Code 25249.5 et seq.) 

Medical conditions aggravated by exposure to the product: 

Chronic lung disease, skin rashes, and asthma. 

*IARC CLASSIFICATIONS: 

Group 1: The agent is carcinogenic to humans. 

There is sufficient evidence that a casual relationship existed between exposure to the agent and 

human cancer.




Group 2B: The agent is possibly carcinogenic to humans. 

Generally includes agents for which there is limited evidence in humans in the absence of 

sufficient evidence in experimental animals. 

3. COMPOSITION INFORMATION ON INGREDIENTS 

Alloy Ingredients: (% by weight shown as a maximum or a range, except for Aluminum, which is a minimum % by weight) 

Alloy Si Fe Cu Mn Mg Cr Ni Zn Ti 

Others 

Each 1 

Others 

Total 

Al 

1100 0.95 = Si + Fe 0.05-0.20 0.05 ---- ---- ---- 0.10 ---- 0.05 0.15 99.00 

1350 0.10 0.40 0.05 0.01 ---- 0.01 ---- 0.05 ---- 0.03 3 0.10 99.50 

1188 0.06 0.06 0.005 0.01 0.01 ---- ---- 0.03 0.01 0.01 4 ---- 99.88 

1199 0.006 0.006 0.006 0.002 0.006 ---- ---- 0.006 0.002 0.002 7 ---- 99.99 

2319 0.20 0.30 5.8-6.8 0.20-0.40 0.02 ---- ---- 0.10 0.10-0.20 0.05 5 0.15 Rmnd 2 

4043 4.5-6.0 0.8 0.30 0.05 0.05 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

4047 (718) 11.0-13.0 0.8 0.30 0.15 0.10 ---- ---- 0.20 ---- 0.05 0.15 Rmnd 2 

4145 (716) 9.3-10.7 0.8 3.3-4.7 0.15 0.15 0.15 ---- 0.20 ---- 0.05 0.15 Rmnd 2 

4643 3.6-4.6 0.8 0.10 0.05 0.10-0.30 ---- ---- 0.10 0.15 0.05 0.15 Rmnd 2 

5183 0.40 0.40 0.10 0.50-1.0 4.3-5.2 0.05-0.25 ---- 0.25 0.15 0.05 0.15 Rmnd 2 

5356 0.25 0.40 0.10 0.05-0.20 4.5-5.5 0.05-0.20 ---- 0.10 0.06-0.20 0.05 0.15 Rmnd 2 

5554 0.25 0.40 0.10 0.50-1.0 2.4-3.0 0.05-0.20 ---- 0.25 0.05-0.20 0.05 0.15 Rmnd 2 

5556 0.25 0.40 0.10 0.50-1.0 4.7-5.5 0.05-0.20 ---- 0.25 0.05-0.20 0.05 0.15 Rmnd 2 

5654 0.45 = Si + Fe 0.05 0.01 3.1-3.9 0.15-0.35 ---- 0.20 0.05-0.15 0.05 0.15 Rmnd 2 

206.0 0.10 0.15 4.2-5.0 0.20-0.50 0.15-0.35 ---- 0.05 0.10 0.15-0.30 0.05 6 0.15 Rmnd 2 

C355.0 (4009) 4.5-5.5 0.20 1.0-1.5 0.10 0.40-0.6 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

A356.0 (4008, 4010) 6.5-7.5 0.20 0.20 0.10 0.25-0.45 ---- ---- 0.10 0.20 0.05 0.15 Rmnd 2 

357.0 6.5-7.5 0.15 0.05 0.03 0.45-0.6 ---- ---- 0.05 0.20 0.05 0.15 Rmnd 2 

Notes: 

1 

Beryllium shall not exceed 0.0003 percent. 

2 

Rmnd = remainder. 

3 

1350 may contain Gallium, 0.03% (max.), Boron 0.05% (max.), and Vanadium plus Titanium, 0.02% (max.). 

4 

1188 may contain Gallium, 0.03% (max.), and Vanadium, 0.05% (max.). 

5 

2319 contains Vanadium, 0.05-0.15% and Zirconium, 0.10-0.25%. 

6 

206.0 may contain Tin, 0.05% (max.). 

7 

1199 may contain 0.005% each (max.) of Gallium and Vanadium. 


EYES: Flush eyes with plenty of water or saline for at least 15 minutes. Consult a physician. 

SKIN: Wash thoroughly with soap and water. Consult a physician if irritation persists. 

INHALATION: Remove to fresh air. Check for clear airway, breathing, and presence of pulse. Provide CPR for 

persons without pulse or respirations. Consult a physician immediately.





FLAMMABLE PROPERTIES: Non-flammable as shipped. Small chips and dust from processing may ignite 

readily. 

FIRE/EXPLOSION: May be a potential hazard under the following conditions: 

Dusts or fines dispersed in the air can be explosive. 

Chips, fines and dust in contact with water can generate flammable/explosive hydrogen gas. These gases 

could present an explosion hazard in confined or poorly ventilated spaces. 

Fines and dust in contact with certain metal oxides (e.g., rust). A thermite reaction, with considerable heat 

generation, can be initiated by a weak ignition source. 

Molten aluminum in contact with water/moisture or other metal oxides (e.g., rust). Moisture entrapped by 

molten aluminum can be explosive. Contact of molten aluminum with other metal oxides can initiate a 

thermite reaction. 

EXTINGUISHING MEDIA: Use fire fighting methods and materials that are appropriate for surrounding fire. Use 

coarse water spray on chips or turnings. For fines, dust or molten aluminum, use 

Class D extinguishing agents. 

DO NOT USE: Halogenated extinguishing agents on small chips/fines. Do not use water in fighting fires around 

molten aluminum. 

FIRE FIGHTING INSTRUCTIONS: Fire fighters should wear NIOSH approved, positive pressure, self-contained 

breathing apparatus and full protective clothing when appropriate. 


SMALL/LARGE SPILL: If molten: Contain the flow using dry sand or salt flux as a dam. Do not use shovels or 

hand tools to halt the flow of molten aluminum. Allow the spill to cool before remelting as scrap. 


Product should be kept dry. Avoid generating dust. Avoid contact with sharp edges or heated metal. Hot and cold 

aluminum are not visually different. 

REQUIREMENTS FOR PROCESSES WHICH GENERATE DUSTS OR FINES 

If processing of these products includes operations where dust or extremely fine particulate is generated, 

obtain and follow the safety procedures and equipment guides contained in Aluminum Association Bulletin F1 

and National Fire Protection Association (NFPA) brochures listed in Section 16. Use non-sparking handling 

equipment. Cover and reseal partially empty containers. Provide grounding and bonding where necessary to 

prevent accumulation of static charges during aluminum dust handling and transfer operations. (See 

Section15). 

Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuums and 

electrostatic precipitators must not be used. Dust collection systems must be dedicated to aluminum dust only 

and should be clearly labeled as such. Do not co-mingle fines of aluminum with fines of iron, iron oxide (rust) 

or other metal oxides. 

Do not allow chips, fines or dust to contact water, particularly in enclosed areas. 

Avoid all ignition sources. Good housekeeping practices must be maintained. 

REQUIREMENTS FOR REMELTING OF ALUMINUM SCRAP MATERIAL AND/OR INGOT 

Molten aluminum and water can be an explosive combination. The risk is greatest when there is sufficient 

molten aluminum to entrap or seal off the water. Water and other forms of contamination on or contained in 

aluminum scrap or remelt ingot are known to have caused explosions in melting operations. While the 

products may have minimal surface roughness and internal voids, there remains the possibility of moisture 

contamination or entrapment. If confined, even a few drops of water can lead to violent explosions.




All tooling and containers which come in contact with molten aluminum must be preheated or specially coated 

and rust free. Molds and ladles must be preheated or oiled before casting. Any surfaces that may contact 

molten aluminum (i.e., concrete) should be specially coated. 

Drops of molten aluminum in water (e.g. from plasma arc cutting), while not normally an explosion hazard, can 

generate enough flammable hydrogen gas to present an explosion hazard. Circulation of the water and 

removal of the aluminum particles minimize the hazards. 

During melting operations, the following minimum guidelines should be observed: 

Inspect all aluminum materials before furnace charging and completely remove surface contamination such as 

water, ice, snow, deposits of grease and oil or other surface contamination resulting from weather exposure, 

shipment, or storage. 

Store materials in dry, heated areas with any cracks or cavities pointed downwards. 

Preheat and dry large or heavy items such as ingot adequately before charging into a furnace containing 

molten aluminum. This is typically done by use of a drying oven or homogenizing furnace. The drying cycle 

should bring the internal metal temperature of the coldest item of the batch to 400 0 F and then hold at that 

temperature for 6 hours. 


ENGINEERING CONTROLS: Use with adequate explosion-proof ventilation to meet the limits listed in Section 2. 

RESPIRATORY PROTECTION: Use NIOSH-approved respiratory protection [dust, fume, high efficiency dust/fume 

mask for lead, or other (organic vapor)] as specified by an Industrial Hygienist or other qualified professional if 

concentrations exceed the limits listed in Section 2. 

EYE PROTECTION: Welders should use appropriate equipment (e.g. welder's helmet, face shield, filter lens) to 

prevent eye irritation or flash burns. 

SKIN PROTECTION: Wear impervious gloves to avoid any skin injury. 

The presence of airborne beryllium has been detected during the welding of aluminum alloys with beryllium 

content at only 0.002% by weight. In accordance with OSHA 29 CFR 1910.252: Welding or cutting operations 

involving beryllium-containing base or filler metals shall be done using local exhaust ventilation and airline 

respirators unless atmospheric tests under the most adverse conditions have established that the workers' 

exposures is within the acceptable concentrations defined by 29 CFR 1910.1000. In all cases, workers in the 

immediate vicinity of the welding or cutting operations shall be protected as necessary by local exhaust 

ventilation or airline respirators. 

Good industrial hygiene practices, including reducing occupational exposures to as low as reasonably 

achievable, are recommended. Where employees are exposed to beryllium above the PEL or where excessive 

contamination of clothing with beryllium is possible, adequate protective clothing should be provided to prevent 

contamination of personal clothing. Personnel assigned to launder such clothing should be advised of 

beryllium's presence and potential health effects. 

Sampling to establish lead level exposure is advised where exposure to airborne particulate or fumes is 

possible. Consult OSHA Lead Standard 29 CFR 1910.1025 for specific health/industrial hygiene precautions 

and requirements to follow when handling lead compounds.





EXPOSURE LIMITS 

(TWA in mg/m 3 unless noted) 

Component CAS No. Form ACGIH TLV OSHA PEL 

Aluminum 7429-90-5 

Beryllium and 

Beryllium 

Compounds 

Total dust, fume 

Respirable 1 

7440-41-7 All compounds as Be 0.00005 0.002, 0.005 Ceiling, 

0.025 for 30 minutes 

Chromium 7440-47-3 Metals 

Cr II compounds 

Cr IIl compounds, inorganic 

Cr VI compounds, water soluble 

Cr VI compounds, water insoluble 

Copper 7440-50-8 Fume 

Dust/mist 

0.5 

---- 

0.5 as Cr 

0.05 as Cr 

0.01 as Cr 

0.2 

1 

15 

5 

1 

0.5 as Cr 

0.5 as Cr 



Gallium 7440-55-3 None None 

Iron 7439-89-6 Oxide dust & fume (as Fe) 5 (respirable) 10 

Lead (nonvolatile) 7439-92-1 Elemental and inorganic 

compounds 

0.05 as Pb 0.05 as Pb 

Magnesium 7439-95-4 Oxide fume 10 (inhalable) 15 Total particulate 

Manganese 7439-96-5 Dust fume 0.2 5 (ceiling) 

Nickel 7440-02-0 Metal & insoluble compounds 

Soluble inorganic compounds 

Insoluble inorganic compounds 

Silicon 7440-21-3 Total dust 

Respirable 

1.5 as Ni 



TLV withdrawn 

---- 

0.1 

1 

1 as Ni 

1 as Ni 

1 as Ni 

Titanium 7440-32-6 Oxide dust 10 15 (total particulate) 

Vanadium 7440-62-2 Respirable dust 

Respirable fume 

Zinc 7440-66-6 Oxide fume 

Total Oxide dust 

Respirable oxide dust 

0.05 as V2O5 

---- 

---- 

2, 10 (STEL) 

15 

5 



Zirconium 7440-67-7 5, 10 (STEL) 5 (compounds only) 

5 

15 

5




Possible hazards during processing by welding, or arc spray metallizing 

ACGIH TLV OSHA PEL 

Ozone (light, heavy work) 0.1, 0.05 ppm 0.1 ppm 

Nitric oxide 25 ppm 25 ppm 

Nitrogen dioxide 3, 5ppm (STEL) 5 ppm (ceiling) 


APPEARANCE: Solid 

BOILING POINT: Not applicable 

FREEZE-MELT POINT: 970 ° -1215 ° F (521 ° -657 ° C) 

VAPOR PRESSURE (mm): Not applicable 

VAPOR DENSITY (air = 1): Not applicable 

SOLUBILITY IN WATER: None 

SPECIFIC GRAVITY: Not determined 

DENSITY: Approximately .1 lb/in 

pH: Not applicable 

ODOR: None 

ODOR THRESHOLD (ppm): Not applicable 

COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable 


Stable under normal conditions of use, storage, and transportation as shipped. Chips, fines, dust and molten 

aluminum are considerable more reactive with the following: 

Water: Slowly generates flammable/explosive hydrogen gas and heat. Generation rate is greatly increased 

with smaller particles (e.g., fines and dusts). 

Molten aluminum can react violently/explosively with water or moisture, particularly when the water is 

entrapped. 

Heat: Oxidizes at a rate dependent upon temperature and particle size. 

Strong oxidizers: Violent reaction with considerable heat generation. 

Can react explosively with nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) when heated or 

molten. 

Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is greatly 

increased with smaller particles (e.g., fines and dusts). 

Halogenated compounds: Many halogenated hydrocarbons, including halogenated fire extinguishing agents, 

can react violently with finely divided aluminum. 

Iron oxide (rust) and other metal oxides (e.g., copper and lead oxides): A violent thermite reaction 

generating considerable heat can occur. Reaction with aluminum fines and dusts requires only very weak 

ignition sources for initiation. 

Molten aluminum can react violently without external ignition source. 

Iron powder: An explosive reaction forming hydrogen gas occurs when heated above 1470 ° F (600 ° C). 


LD50 or LCLO found for oral, dermal or inhalation routes of administration: 

Nickel: oral rat LD50: 9000 mg/kg body weight 

Silicon: oral rat LD50: 3160 mg/kg body weight 

Manganese: oral rat LD50: 9000 mg/kg body weight 

Iron: intraperitoneal rabbit LDLO: 20 mg/kg - no toxic effect noted 


ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: Not available.




13. DISPOSAL CONSIDERATION 

Collect scrap for remelting and recycling. To maintain metal purity, it may be desirable to segregate this scrap from 

other alloys. 

RCRA Status: Characterize in accordance with 40 CFR 261 or state equivalent. 


USA DOT: Not Regulated - Enter the proper freight classification, "SDS Number," and "Product Name" on the 

shipping paperwork. 

Canadian TDG Hazard Class & PIN: Not regulated. 


All electrical equipment must be suitable for use in hazardous atmospheres involving aluminum powder in 

accordance with 29 CFR 1910.307. The National Electrical Code, NFPA 70, contains guidelines for determining 

the type and design of equipment and installation, which will meet this requirement. 


TSCA STATUS: All components of this product are listed on the TSCA inventory. 

CERCLA HAZARDOUS SUBSTANCES: Beryllium, Chromium, Chromium compounds, Copper, Lead, 

Manganese, Nickel, Zinc. 


Section 311/312 Physical and Health Hazard Categories: Immediate (acute), delayed (chronic) if 

particulates/fumes are generated during processing. 

Section 313 Toxic Chemicals: Aluminum (fume/dust), Beryllium, Chromium, Copper, Lead, Manganese, Nickel, 

Vanadium (fume/dust), and Zinc (fume/dust). 

State Regulations 

PENNSYLVANIA "Special Hazardous Substance": Beryllium; Nickel; Chromium compounds, hexavalent. 

International Regulations 

CANADIAN DOMESTIC SUBSTANCES LIST: All components of this product are listed on the Canadian DSL. 

EUROPEAN COMMUNITY: All components of this product are listed on ECOIN, the European Core Inventory. 


STATUS: Changes in Section 3. 

PREPARED BY: Hazardous Materials Control Committee 

OSHA Standard 29 CFR 1910.1025 (Lead) 

OSHA Standard 29 CFR 1910.252 

ANSI 249.1, Safety in Welding and Cutting 

Aluminum Association's Bulletin F-1,"Guidelines for Handling Aluminum Fines Generated during Various 

Aluminum Fabricating Operations.” The Aluminum Association, 900 19th Street, NW, Washington, DC 20006. 

NFPA 65, Standard for Processing and Finishing of Aluminum (NFPA phone: 800-344-3555) 

NFPA 70, Standard for National Electrical Code 

NFPA 77, Standard for Static Electricity 

Guide to Occupational Exposure Values-I 997, Compiled by the American Conference of Governmental 

Industrial Hygienists (ACGIH). 

Dept. of Health and Human Services, NIOSH: Registry of Toxic Effects of Chemical Substances, 1985-86 

Edition 

Sax, N. Irving: Dangerous Properties of Industrial Materials, Van Nostrand Reinhold Co., Inc., 1984




INFORMATION HEREIN IS GIVEN IN GOOD FAITH AS AUTHORITATIVE AND VALID; 

HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, CAN BE MADE. 

LEGEND: 

ACGIH American Conference of Governmental Industrial Hygienists atm atmosphere 

AICS Australian Inventory of Chemical Substances cm centimeter 

CAS Chemical Abstract Services g gram 

CERCLA Comprehensive Environmental Response, Compensation, & Liability Act in inch 

CFR Code of Federal Regulations kg kilogram 

DOT Department of Transportation lb. pound 

DSL Domestic Substances List (Canada) m meter 

ECOIN European Core Inventory mg milligram 

EPA Environmental Protection Agency mm millimeter 

IARC International Agency for Research on Cancer n.o.s. not otherwise specified 

LC50 Lethal Concentration (50 percent kill) ppb parts per billion 

LCLo Lowest published lethal concentration ppm parts per million 

LD50 Lethal dose (50 percent kill) psia pounds/square inch absolute 

LDLo Lowest published lethal dose ug microgram 

MIG Metal Inert Gas 



NTP National Toxology Program 



PIN Product Identification Number 

RCA Resource Conservation and Recovery Act 


STEL Short Term Exposure Limit 

TCLP Toxic Chemicals Leachate Program 

TDG Transportation of Dangerous Goods 

TIG Tungsten Inert Gas 



TWA Time weighted Average

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