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1 - Memorial University of Newfoundland

1 - Memorial University of Newfoundland

1 - Memorial University of

  • Page 5 and 6: INVERSE ELECTRON DEMAND DIELS-ALDER
  • Page 7 and 8: Abstract The Dicls-Alder reaction i
  • Page 9 and 10: Acknowledgements I am thankful 10 m
  • Page 12 and 13: 1.4.2.1 Representative Procedure A:
  • Page 14 and 15: 3.2.3 Scope of Inrramolecular Povar
  • Page 16 and 17: List of Tables TABLE 1.1 Optimizati
  • Page 18 and 19: list of Figures FIGURE 1.1 3tural A
  • Page 20 and 21: SCHEME 3.4 Talal Synthesis of rac-y
  • Page 22 and 23: List or Abbreviations Ab, APeI calc
  • Page 28: 1.2.3 Synlhesis of Various 3-Aminoc
  • Page 40: 1.4.2.4 Representative Procedure D:
  • Page 51 and 52: (7-Hydroxy-2.oxo.2JJ-chromen.3-yl)c
  • Page 53:

    According 10 representalive procedu

  • Page 58:

    128.5, 126.5, 125.8, 122.2, 119.0,

  • Page 61 and 62:

    ----------------------------- 3-«2

  • Page 63 and 64:

    According to representative procedu

  • Page 65:

    3. (a) Nine!, L.; Benazel, F.; Char

  • Page 76 and 77:

    m "" NHAc "" "" I A 0 0 51 53

  • Page 79:

    Me'CC::(NHBoc a a 50 56

  • Page 94 and 95:

    1\ 71

  • Page 96:

    1 73

  • Page 106:

    aldehyde. was investigated. Indeed.

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    the ground state to the transition

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    perfonned in the presence of a pote

  • Page 120 and 121:

    any further beneficial effect on th

  • Page 125:

    (F;g.2.2). 51 FIGURE 2.2 A possible

  • Page 129 and 130:

    2.4.2 General EXI)Crimental Procedu

  • Page 134 and 135:

    1.57-1.51 (m. 1H). 1.47-1.42 (m. 2H

  • Page 136:

    acetatelhexanes) to afford 26a as a

  • Page 141 and 142:

    (m. IH. H-2). 3.40-3.35 (m, IH. H-3

  • Page 144 and 145:

    2.46 (s. 3H. COCH,), 2.38-2.33 (m.

  • Page 146 and 147:

    ------------, 2.31 (s. 3H, OCOCHJ)

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    1.80-1.76 (m, IH, H-3) ppm; liC

  • Page 150 and 151:

    COOCH,), 3.97-3.92 (m, IH, H-2). 3.

  • Page 152 and 153:

    Hz, IH, H-8), 5.40 (d, j =6.1 Hz, I

  • Page 155:

    (m). 1020 (w) em']; MS (APCI) m/: (

  • Page 161 and 162:

    (4aS·, 5R·, 12cS·)-4-(7-Oxo·2,3

  • Page 163:

    (30-100% ethyl acet'l.Ielhexanes) t

  • Page 166 and 167:

    Acetic acid-4-[3-(2-hydroxyethyl)-1

  • Page 169 and 170:

    3 min. After the addition, the reac

  • Page 171:

    2.5 References I. For review articl

  • Page 175 and 176:

    62. 3977-3984. 12. Povarov, L. S. C

  • Page 177 and 178:

    see: Anderson, H. J.; Loader. C E.;

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    2.6 Appendix 2.6.1 I H and IJC NMR

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    160

  • Page 187:

    164

  • Page 190 and 191:

    "0 167

  • Page 193 and 194:

    170

  • Page 195:

    "0 I I III II I I I I I I 150 100 5

  • Page 199:

    COOCI"J 176

  • Page 204 and 205:

    181

  • Page 211:

    ." 188

  • Page 216 and 217:

    The data were collected at a temper

  • Page 218 and 219:

    The standard deviation of an observ

  • Page 221 and 222:

    Detector Goniometer Radiation Detec

  • Page 223 and 224:

    C. Structure Solution and Refinemen

  • Page 225 and 226:

    C(24) C(25) 1.370(3) C(26) C(27) 1.

  • Page 227 and 228:

    C(8) C(7) C(IO) 119.5(2) N(I) C(8)

  • Page 229 and 230:

    C(30) C(31) C(32) 123.9(2) C(31) C(

  • Page 231:

    Chapter 3. Intramolecular Inverse E

  • Page 242:

    (48) in the intramolecular Povarov

  • Page 254 and 255:

    SCHEME 3.18 Povarov Reaction betwee

  • Page 256 and 257:

    3.4 Experimental 3.4.1 General Meth

  • Page 260:

    1432 (m), 1339 (s), 1177 (w), 1026

  • Page 268 and 269:

    (C-6), 128.6 (C-n. 127.3 (C-6'), 12

  • Page 272 and 273:

    (w), 1426 (w), 1343 (m), 1319 (w),

  • Page 280:

    CH) ppm: Oc(CD,CI,) = 159.5 (C-6).

  • Page 287 and 288:

    3.5 References I. (a) Nicolaou. K.

  • Page 289 and 290:

    S. E.: Socnen, D. R.; Miller, M. M.

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    3.6 Appendix 3.6.1 I H and lJC NMR

  • Page 294 and 295:

    , I 271

  • Page 300 and 301:

    277

  • Page 302 and 303:

    279

  • Page 306:

    "0 283

  • Page 311:

    1'0 288

  • Page 314:

    "0 oJ:' .J,) 291

  • Page 317:

    I II 1,1111111 II o 294

  • Page 321 and 322:

    Creagh and Hubbeli lO. All calculat

  • Page 324 and 325:

    Detector Goniometer Radiation Detec

  • Page 326 and 327:

    TABLE 3.4 Bond lengths ( ) atom ato

  • Page 328 and 329:

    C(4) C(5) C(6) 121.5(2) C(7) C(6) C

  • Page 330:

    4.1 Inlroduction Chapter 4. Toward

  • Page 343 and 344:

    4.4 Experimental 4.4.1 General Meth

  • Page 348 and 349:

    3.94 (s, 3H) 3.57 (s. 3H), 3.39 (br

  • Page 350 and 351:

    4.5 References 1. (a) Anthony, J. E

  • Page 352 and 353:

    14. The synthesis of tetramethoxyet

  • Page 357 and 358:

    334

  • Page 359:

    naming such molecules, a simpler sy

  • Page 365:

    which was accomplished previously b

  • Page 371:

    Entry TABLE 5.1 Attempted Synthesis

  • Page 375 and 376:

    SCHEME 5.14 Attempted Synthesis of

  • Page 377 and 378:

    5.5 Experimental 5.5.1 General Meth

  • Page 383:

    was stirred at-78 "C for another 2

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    7-tert-Butyl-I-(mcthoxyrnethoxy)p)'

  • Page 388 and 389:

    diethyl ether (2 x 5 mL). The combi

  • Page 391 and 392:

    solution of 34 (0.54 g, 0.92 mmol)

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    (d. C-4). 125.4 (d. C-IO), 124.2 (d

  • Page 397 and 398:

    1·(1-«2·(Bu t-3·ynyl)naphthalen

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    5. (a) Misek. J.; Teply, F.; Stara,

  • Page 403:

    5.7. Appendix NMR Spectra for Selec

  • Page 407:

    384

  • Page 411:

    388

  • Page 426:

    403

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