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Canada - Memorial University of Newfoundland

Canada - Memorial University of Newfoundland

Canada - Memorial University of

  • Page 4: 1"'1 National Library of Canada Bib
  • Page 8: y thcnnally dc
  • Page 11 and 12: Gregory for his kindness and making
  • Page 15: LIST OF TABLES Table 1.1 Corrosion
  • Page 21 and 22: single crystals ofquartz (Nacken, 1
  • Page 23 and 24: phosphate control in the 19&Os was
  • Page 25: the standard Gibbs energies and ent
  • Page 36: consist ofortnophospllatcs. The bou
  • Page 41 and 42: 2 FcIlFc[[J204(S) + 26 Na+(aq) + 12
  • Page 44 and 45: solubility and phase relations ofpr
  • Page 46: where 11 equals the ionic state ofh
  • Page 49: '", g :£ 30
  • Page 55:

    1.10 Project Objectives The objecti

  • Page 61 and 62:

    II - "7 /'7"7L 41 J n

  • Page 65 and 66:

    2.3.2 Single Crystal X-Ray Dif'frac

  • Page 67 and 68:

    2.4 Synthesis and Characterization

  • Page 69 and 70:

    Several solid starting materials we

  • Page 75 and 76:

    FeUlNTA(aq) + HPOl(aq) + NH/(aq) __

  • Page 77 and 78:

    All runs lasted up to to days at a

  • Page 79 and 80:

    0.0 l--l_-L_l-....J.._-L_l-....J..-

  • Page 81 and 82:

    dissolution orSNHP and allowed the

  • Page 83 and 84:

    (a) (b) Figure 3.1a and b: Scanning

  • Page 87 and 88:

    and the equilibrium constant for ma

  • Page 89 and 90:

    groups. Oxidizing agents were previ

  • Page 91 and 92:

    and reacted with aqueous sodium pho

  • Page 94 and 95:

    (al (b) Figure 3.5a and b: Scanning

  • Page 97 and 98:

    Figure 3.7: Scanning electron micro

  • Page 99:

    Table 3.1: Positional parameters fo

  • Page 104:

    Figure 3.10: Scanning electron micr

  • Page 107 and 108:

    pattern is listed in Table A.LI3. E

  • Page 109:

    4.0 SOLUBILITY AND REACTION KINETIC

  • Page 117 and 118:

    Table 4.1 Experimental C

  • Page 119:

    Table 4.3 Standard slale properties

  • Page 126 and 127:

    Table 4.6 HKF equation ofstate coef

  • Page 128 and 129:

    Equilibrium constants are listed in

  • Page 130:

    Table 4.9 Equilbrium constants for

  • Page 136:

    Table 4.10 Standard state propertie

  • Page 142 and 143:

    lower NalP04 mole ratio than the re

  • Page 144:

    Broadbent D., Lewis G.G., and Wetto

  • Page 147 and 148:

    Marshall W.L. (1982) Two-liquid-pha

  • Page 150 and 151:

    Welton E.A.M. (1981) Phase equilibr

  • Page 152 and 153:

    APPENDIX I: Powder X-ray Diffractio

  • Page 154 and 155:

    TABLE A.l.l: X-Ray Diffraction Resu

  • Page 157 and 158:

    TABLE A,I.3 (continued) Quinlan JCP

  • Page 159 and 160:

    TABLE A.1.4 (continued) Quinlan (19

  • Page 162 and 163:

    TABLE A.l.S (continued) JCPDS Quinl

  • Page 164 and 165:

    TABLE A.1.6 (continued) Quinlan (19

  • Page 168 and 169:

    TABLE A.L8 (continued) Boudin JCPDS

  • Page 170 and 171:

    TABLE A.I.9 (continued) Product RGH

  • Page 172 and 173:

    TABLE A.I.IO (continued) Ziemniak a

  • Page 174:

    TABLE AJ.11 (continued) Zicmniak an

  • Page 177 and 178:

    TABLE A.T.I2 (continued) Zicmniak a

  • Page 180:

    TABLE A.I.13 (continued) Ziemniak a

  • Page 183:

    Experimental A colorless irrcg.plal

  • Page 188 and 189:

    Slfuc!ure Solution Refinemenl Funct

  • Page 190 and 191:

    111

  • Page 192 and 193:

    TABLE A.1II.1: Summary of ICP ES Re

  • Page 194 and 195:

    TABLE A.lll.2: KinclicData Time m(N

  • Page 196 and 197:

    TABLE A.III.2 (continued) Time m(Na

  • Page 198 and 199:

    TABLE A.lll.2 (continued) Time m(Na

  • Page 200 and 201:

    TABLE A.lIl.l (continued) Time m(Na

  • Page 202:

    TABLE A.III.3 (continued) t "C m(p0

Canada - Memorial University of Newfoundland DAI
Canada - Memorial University of Newfoundland DAI
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