Electro Optical Characterisation of Short Wavelength Semiconductor ...
Basic Concepts many problems appear during the processing phase of the devices  (see also chapter 2). The thermodynamically stable crystall structure of ZnSe is the zincblende structure. The wurtzite structure occurs at temperatures above 1425 ◦ C . ZnSe can be cleaved along the  direction which allows a simple fabrication of mirror facets. ZnSe single crystals with a crystalline quality suitable for device fabrication are rare and usually only available in small sizes . Band gap and lattice Having a direct band gap is a prerequisite for an efficient radiative recombination. Due to the direct band gap there are no phonons necessary for momentum conservation. This leads to a much higher recombination rate compared to indirect semiconductors. The III-nitrides and II-VI compounds are such direct band gap semiconductors as can be Figure 1.4: Electronic band structure along the symmetry directions of the first Brillouin zone of (a) wurtzite GaN  and (b) ZnSe . (c) and (d)  are band crossing and band mixing points within the energy bands of the wurtzite phase of GaN respectively. seen in Fig. 1.4. The band gap energy at 300 K amounts 3.42 eV for GaN and 2.69 eV for ZnSe. 6
Physics of Semiconductor Lasers Besides the mentioned binary alloys, ternary and quaternary alloys are of enormous meaning for the production of laser diodes, as they allow a free design of the band structure. The band structure parameter can be adjusted depending on the composition of the alloy. In case of III-nitrides only the ternaries InGaN and AlGaN beside GaN are being used in the devices although studies on quaternary III-nitrides as AlInGaN are in progress [32, 33]. On the contrary, not only the ternary but also the quaternary alloys play a big role in the II-VI laser diode systems. ZnSSe, MgZnSSe, CdSSe and CdZnSSe are of the examples. Fig. 1.5 shows the the band gap energy versus the lattice constant for II-VI and III-V material systems. All the points shown on the Fig. 1.5 are binary materials. The composition change, i.e. making ternary or quaternary materials out of the binary ones, influences the lattice constant and the band gap energy. Modification of the lattice constants a of Figure 1.5: Band gap energy vs. lattice constant  AxB1−xC and AxB1−xCyD1−y obeys the Vegard’s law : a(x) = xaAC + (1 − x)aBC (1.1) a(x, y) = xyaAC + (1 − x)yaBC + x(1 − y)aAD + (1 − x)(1 − y)aBD. (1.2) For calculation of the band gap energy Eg(x) the simple linear interpolation is not valid. A so called bowing parameter b is introduced, Eg(x) = xEg,AC + (1 − x)Eg,BC − x(1 − x)b (1.3) Eg(x, y) = xyEg,AC + (1 − x)yEg,BC + x(1 − y)Eg,AD + (1 − x)(1 − y)Eg,BD −x(1 − x)[ybABC + (1 − y)bABD] −y(1 − y)[xbACD − (1 − x)bBCD]. (1.4) It is of importance to mention that not all theoretical compositions are possible to form a ternary or quaternary alloy as certain ranges are not stable and phase separation occurs. 7
ZnSe threshold current density valu
Bibliography  N. G. Basov, O. N.
BIBLIOGRAPHY  G. Snider, 1D Poi