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R eview of A ir Q u ality - Isle of Man Government

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Carbon<br />

monoxide<br />

10ppm<br />

Running 8<br />

hour mean<br />

0 0<br />

Nitrogen<br />

dioxide<br />

105ppb 1 hour mean 18 0<br />

PM 10 50µg/m 3 24 hour<br />

mean<br />

35 3 3 exceedances during March 2007<br />

132ppb 1 hour mean 24 0<br />

Sulphur<br />

dioxide<br />

47ppb<br />

24 hour<br />

mean<br />

3 0<br />

100ppb<br />

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mean<br />

35 0<br />

Ozone<br />

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PM 2.5<br />

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105ppb 1 hour mean 18 0<br />

PM 10 50µg/m 3 24 hour mean 35 2 2 exceedances during March 2007<br />

132ppb 1 hour mean 24 0<br />

Sulphur<br />

dioxide<br />

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mean<br />

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50ppb<br />

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hour mean<br />

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1 <br />

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NO 2 99.9% 97.3% 100% 77.6%<br />

CO 46.6% 44.9% 100% 99.7%<br />

PM 10 100% 100% 100% 100%<br />

SO 2 17.2% 14.5% 88.2% 22.8%<br />

O 3 46.6% 45.8% 100% 99.7%<br />

PM 2.5 48.1% 3.2% - -<br />

For both stations, percentage data capture statistics have been generated<br />

for both raw data captured and valid post calibration data. The data<br />

capture statistics are intended to reflect the comparison between total raw<br />

data capture and valid calibrated data.<br />

The raw data capture percentage represents the total possible hourly<br />

intervals (15 minute intervals for SO 2 ) during the month for which raw data<br />

has been collected. This is an indication <strong>of</strong> how well the analysers have<br />

been working during the month.<br />

The valid post calibration data capture percentage represents the relevant<br />

assessment periods (e.g. running 8-hour mean for O 3 ). This is all data that<br />

is valid once the relevant calibration factors have been applied.<br />

The Richmond Hill Monitoring Station has a high proportion <strong>of</strong> captured raw<br />

data for March 2007, in excess <strong>of</strong> 88% in all cases. There are lower<br />

percentages <strong>of</strong> valid data at Richmond Hill during March 2007 compared to<br />

captured data. Some <strong>of</strong> the data loss is due to the span test undertaken on<br />

the 5 th March.<br />

At Richmond Hill, there is a much lower percentage <strong>of</strong> valid post calibration<br />

data for SO 2 than captured raw data. This loss is due to negative<br />

measurements <strong>of</strong> SO 2 after the calibration factor has been applied. It is<br />

considered that this may be due to low levels <strong>of</strong> ambient concentrations <strong>of</strong><br />

SO 2 in the vicinity <strong>of</strong> Richmond Hill during March 2007.<br />

Similarly, the percentage <strong>of</strong> valid post calibration NO 2 data is lower in<br />

comparison to other pollutant concentrations at Richmond Hill. Again, it is<br />

considered that this may be due to low levels <strong>of</strong> ambient NO 2<br />

concentrations during March 2007.<br />

At the Quarterbridge Monitoring Station, there were a series <strong>of</strong> power cuts,<br />

commencing on the 14 th February. Env<strong>ir</strong>o Technology visited the<br />

R<strong>eview</strong> <strong>of</strong> A<strong>ir</strong> Qu<strong>ality</strong> Monitoring Data<br />

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Quarterbridge site on the 26 th February. During the visit, it was concluded<br />

that the a<strong>ir</strong> conditioning unit was causing the power failures. On the 1 st<br />

March, an engineer from Stewart Clague Services investigated the a<strong>ir</strong><br />

conditioning unit for a fault and determined that the cause <strong>of</strong> the fault was<br />

the failure <strong>of</strong> the compressor. To reduce heat generation whilst the a<strong>ir</strong><br />

conditioning unit was not operational, it was decided to keep just the PM 10<br />

and NO x analysers running until the a<strong>ir</strong> conditioning unit was replaced,<br />

resulting in low percentages <strong>of</strong> captured raw data for all other pollutants for<br />

March 2007. Whilst the a<strong>ir</strong> conditioning unit was out <strong>of</strong> action, regular<br />

temperature checks were made to ensure the analysers were not<br />

overheating. On the 17 th March, a replacement a<strong>ir</strong> conditioning unit was<br />

fitted and the CO, O 3 and PM 2.5 were put back into service. However, the<br />

SO 2 analyser requ<strong>ir</strong>ed a permeation tube to be refitted and remained<br />

switched <strong>of</strong>f, therefore the percentage <strong>of</strong> captured raw data for SO 2 is lower<br />

than the percentages <strong>of</strong> captured raw data for all the other pollutants. The<br />

permeation tube was then refitted on the 26 th March 2007 and the SO 2<br />

analyser was put back into service.<br />

At the end <strong>of</strong> March 2007, there are two episodes <strong>of</strong> elevated PM 10<br />

concentrations at both Richmond Hill and Quarterbridge Monitoring<br />

Stations. It is possible that the elevated PM 10 concentrations are due to<br />

foggy conditions at the end <strong>of</strong> March 2007.<br />

At the Quarterbridge Monitoring Station, there were 3 exceedances <strong>of</strong> the<br />

PM 10 24 hour mean objective and 1 exceedance <strong>of</strong> the O 3 8-hour running<br />

mean objective during March 2007. At Richmond Hill, there were 2<br />

exceedances <strong>of</strong> the PM 10 24 hour mean objective and 3 exceedances <strong>of</strong><br />

the O 3 8-hour running mean objective during March 2007.<br />

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01/03/07 SCS engineer investigates AC unit for fault –<br />

Compressor has failed and a new unit is requ<strong>ir</strong>ed.<br />

Quote requested from SCS for a replacement unit.<br />

Marcus Spry<br />

NOx and PM 10 kept switched on – all other units <strong>of</strong>f<br />

to reduce heat generation. Regular temperature<br />

checks requ<strong>ir</strong>ed.<br />

02/03/07 Temperature check at QB Marcus Spry<br />

05/03/07 Span/Zero Check. Filters changed and BAM<br />

Tapes checked (due end <strong>of</strong> April).<br />

Temperature check at QB<br />

Marcus Spry<br />

06/03/07 Temperature check at QB Marcus Spry<br />

07/03/07 Temperature checks at QB. Span/Zero check for<br />

NO x analyser.<br />

17/03/07 Replacement a<strong>ir</strong>-conditioning unit fitted. CO, O 3<br />

and PM 2.5 analysers back in service. SO 2 analyser<br />

requ<strong>ir</strong>es permeation tube to be refitted.<br />

26/03/07 Permeation tube refitted with assistance from<br />

Env<strong>ir</strong>otech Tech Support. SO 2 analyser back in<br />

service. Span checks for CO and O 3 carried out.<br />

Marcus Spry<br />

Marcus Spry<br />

Marcus Spry<br />

27/03/07 SO 2 analyser span/zero check Marcus Spry<br />

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