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Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

Molecular beam epitaxial growth of III-V semiconductor ... - KOBRA

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Summary<br />

The main focus and concerns <strong>of</strong> this PhD thesis is the <strong>growth</strong> <strong>of</strong> <strong>III</strong>-<br />

V <strong>semiconductor</strong> nanostructures (Quantum dots (QDs) and quantum<br />

dashes) on silicon substrates using molecular <strong>beam</strong> epitaxy (MBE)<br />

technique. The investigation <strong>of</strong> inuence <strong>of</strong> the major <strong>growth</strong> parameters<br />

on their basic properties (density, geometry, composition, size<br />

etc.) and the systematic characterization <strong>of</strong> their structural and optical<br />

properties are the core <strong>of</strong> the research work. The monolithic integration<br />

<strong>of</strong> <strong>III</strong>-V optoelectronic devices with silicon electronic circuits<br />

could bring enormous prospect for the existing <strong>semiconductor</strong> technology.<br />

Our challenging approach is to combine the superior passive<br />

optical properties <strong>of</strong> silicon with the superior optical emission properties<br />

<strong>of</strong> <strong>III</strong>-V material by reducing the amount <strong>of</strong> <strong>III</strong>-V materials to<br />

the very limit <strong>of</strong> the active region.<br />

Dierent hetero<strong>epitaxial</strong> integration approaches have been investigated<br />

to overcome the materials issues between <strong>III</strong>-V and Si. However,<br />

this include the self-assembled <strong>growth</strong> <strong>of</strong> InAs and InGaAs QDs<br />

in silicon and GaAx matrices directly on at silicon substrate, sitecontrolled<br />

<strong>growth</strong> <strong>of</strong> (GaAs/In 0.15 Ga 0.85 As/GaAs) QDs on pre-patterned<br />

Si substrate and the direct <strong>growth</strong> <strong>of</strong> GaP on Si using migration enhanced<br />

epitaxy (MEE) and MBE <strong>growth</strong> modes. An ecient ex-situ<br />

buered HF (BHF) and in-situ surface cleaning sequence based on<br />

atomic hydrogen (AH) cleaning at 500 ◦ C combined with thermal oxide<br />

desorption within a temperature range <strong>of</strong> 700-900 ◦ C has been<br />

established. The removal <strong>of</strong> oxide desorption was conrmed by semicircular<br />

streaky reection high energy electron diraction (RHEED)

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