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April 2005<br />

Study and Estimate <strong>for</strong> CO 2<br />

Capture Facilities<br />

<strong>for</strong> <strong>the</strong> <strong>proposed</strong> <strong>800</strong> <strong>MW</strong> <strong>Combined</strong> <strong>Cycle</strong><br />

<strong>Power</strong> <strong>Plant</strong> - Tjeldbergodden, Norway<br />

Non-confidential


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

TABLE OF CONTENTS<br />

1.0 EXECUTIVE SUMMARY<br />

1.0 Executive Summary<br />

2.0 BASIS OF DESIGN<br />

2.1 <strong>Power</strong> <strong>Plant</strong><br />

2.2 CO 2 <strong>Plant</strong><br />

2.3 Process Design Basis<br />

2.4 Codes and Standards<br />

2.5 Units of Measurement<br />

2.6 Equipment Numbering<br />

2.7 <strong>Power</strong> <strong>Plant</strong> Design Assumptions<br />

3.0 PROCESS DESCRIPTION & DISCUSSIONS.<br />

3.1 CO 2 Capture<br />

3.2 Cooling Water Supplies<br />

3.3 Energy Integration<br />

3.4 Off Gas Plume Dispersion<br />

3.5 Emissions and Effluents<br />

3.6 Process Utility Interfaces<br />

3.7 <strong>Power</strong> <strong>Plant</strong> Pre-investment<br />

4.0 KEY DELIVERABLES –<br />

PFD’s, UFD’s, Mass Balances, Equipment List<br />

4.1 Block Flow Diagram<br />

4.2 PFD Economine FG Plus<br />

4.3 PFD Economine FG Plus – Compression<br />

4.4 Heat and Material Balances<br />

4.5 UFD Cooling Water<br />

4.6 Water Balance<br />

4.7 Equipment list<br />

5.0 FACILITIES LAYOUT<br />

5.1 Montage of <strong>Plant</strong><br />

5.2 3D Perspective of CO 2 <strong>Plant</strong><br />

5.3 Plot Plan CO 2 plant<br />

6.0 CAPEX ESTIMATE<br />

6.0 Total Installed Cost<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

1.0 EXECUTIVE SUMMARY<br />

1.1 Introduction<br />

Statoil ASA are proposing to build an <strong>800</strong> <strong>MW</strong> combined cycle power plant as part<br />

of <strong>the</strong> overall expansion of <strong>the</strong>ir methanol plant facilities at Tjeldbergodden. The<br />

plant will comprise two gas turbines, two HRSGs and a single steam turbine. As<br />

part of <strong>the</strong> <strong>Power</strong> <strong>Plant</strong> Statoil are considering using Fluor’s Economine FG +<br />

CO 2 capture licensed technology <strong>for</strong> emission control.<br />

1.2 Executive Summary<br />

Fluor have developed and licensed a CO 2 capture technology to be used <strong>for</strong><br />

capture of acid gases in an oxidising environment where normal amines are<br />

rapidly degraded, such as are found in <strong>the</strong> exhaust gases of a combined cycle<br />

power plant.<br />

Statoil ASA engaged Fluor to undertake selective studies leading to <strong>the</strong><br />

development of a capital cost estimate <strong>for</strong> <strong>the</strong> process facilities comprising <strong>the</strong><br />

CO 2 capture plant, to be incorporated on an adjacent plot to <strong>the</strong> <strong>proposed</strong> power<br />

plant facilities at Tjeldbergodden.<br />

This report, which presents <strong>the</strong> non-confidential aspects of this study, outlines <strong>the</strong><br />

studies undertaken to define <strong>the</strong> design basis <strong>for</strong> <strong>the</strong> CO 2 <strong>Plant</strong>, establishes <strong>the</strong><br />

interface considerations, and assess <strong>the</strong> issues that may influence <strong>the</strong> design<br />

requirements of <strong>the</strong> power plant. The study draws conclusions that support <strong>the</strong><br />

completion of <strong>the</strong> capital cost estimate <strong>for</strong> this plant.<br />

In summary, <strong>the</strong> report concludes that a CO 2 capture plant can be built as an<br />

integral addition to <strong>the</strong> power plant <strong>for</strong> an indicated total installed cost of $500.MM<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

2.0 BASIS OF DESIGN<br />

2.1 Introduction<br />

This section presents <strong>the</strong> general design criteria <strong>for</strong> <strong>the</strong> CO 2 Capture Study at<br />

Tjeldbergodden, Base Scope – <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong>.<br />

Statoil is planning to install a combined cycle (CC) power plant based on 2<br />

commercially available gas turbines (GT) in <strong>the</strong> 250 -300 <strong>MW</strong> class with dedicated<br />

waste heat boilers and one common steam turbine whose nominal power output<br />

would be <strong>800</strong> <strong>MW</strong>. The flue gas quantity and quality from <strong>the</strong> two GTs was<br />

estimated by Fluor using standard software.<br />

Statoil is assessing <strong>the</strong> feasibility of capturing carbon dioxide from <strong>the</strong>se two new<br />

plants <strong>for</strong> Enhanced Oil Recovery (EOR) using Fluor’s proprietary Econamine FG<br />

Plus SM (EFG+) technology. The carbon dioxide recovery is set at 85% resulting in<br />

an EFG+ plant with a 6,170 Te/day (100% CO 2 ) capacity.<br />

2.2 Site Data<br />

• The EFG+ plant is located at Statoil’s existing complex in Tjeldbergodden,<br />

Norway.<br />

2.3 Process Design Basis<br />

Design Philosophy<br />

The EFG+ plant consists of three absorption trains and one common stripper<br />

train. Three was chosen <strong>for</strong> <strong>the</strong> number of absorption trains based on <strong>the</strong><br />

maximum allowable diameter of 15 meters <strong>for</strong> each absorber column.<br />

<strong>Plant</strong> Life<br />

The plant is designed <strong>for</strong> an operating life of no less than thirty (30) years.<br />

On-Stream Factor<br />

All systems are designed to achieve a minimum on-stream availability of 330 days<br />

per year.<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

Feedstock Properties<br />

The properties of <strong>the</strong> flue gas from <strong>the</strong> gas turbines were estimated by Fluor using<br />

<strong>the</strong> GTPRO program and are provided in Table 2-1.<br />

Table 2-1 – EFG+ <strong>Plant</strong> Feedstock Properties<br />

Description<br />

Flue Gas<br />

Temperature, °C 80<br />

Pressure, kg/cm 2 (g) 0<br />

Flow, kg/s 1384.8<br />

Composition (vol%)<br />

Nitrogen 74.65<br />

Oxygen 12.70<br />

Carbon Dioxide 3.91<br />

Water 7.84<br />

Argon 0.90<br />

SO 2<br />

0 ppm<br />

NO<br />

22 ppm<br />

NO 2 Component of NOx<br />

3 ppm<br />

NOx Total<br />

25 ppm<br />

Product Specification<br />

The specification of <strong>the</strong> carbon dioxide product is shown in Table 2-2.<br />

Table 2-2 – Product Specification at Battery<br />

Limits<br />

Water<br />

Description<br />

Specification<br />

50 ppmw (max)<br />

Pressure, kg/cm 2 (g) 102<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

Utilities<br />

The conditions <strong>for</strong> <strong>the</strong> utilities are shown in Table 2-3.<br />

Table 2-3 – Utilities<br />

Temperature<br />

°C<br />

Pressure,<br />

kg/cm 2 (g)<br />

Low Pressure Steam 148 3.5<br />

Medium Pressure Steam 160 5.4<br />

Make-up Water 40 6.5-7.0<br />

Sea Water Cooling Water Supply 18 4.5<br />

O<strong>the</strong>r required utilities are:<br />

• Service water<br />

• Steam condensate return<br />

• <strong>Plant</strong> and instrument air<br />

• Nitrogen <strong>for</strong> blanketing<br />

2.4 Codes and Standards<br />

Return<br />

28 (max)<br />

Fluor standards are used <strong>for</strong> <strong>the</strong> equipment codes and standards (e.g. ASME,<br />

API, TEMA, ANSI).<br />

2.5 Units of Measurement<br />

All units of measurement are in <strong>the</strong> metric system and are shown in Table 5-1.<br />

Table 5-1<br />

Units of Measurement<br />

Temperature °C<br />

Pressure (gauge)<br />

(absolute)<br />

kg/cm 2 (g)<br />

kg/cm 2 (a)<br />

Vacuum<br />

mm H 2 O<br />

Liquid flow<br />

m 3 /hr, kg/hr<br />

Steam flow<br />

kg/hr<br />

Gas flow<br />

Nm 3 /hr<br />

(at 0°C & 760 mmHg)<br />

Heat flow<br />

kcal, Gcal<br />

<strong>Power</strong><br />

kW<br />

Viscosity<br />

cP<br />

Dimensions<br />

m, mm<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

2.6 Equipment Numbering<br />

Every piece of equipment is identified with an identification letter symbol indicating<br />

<strong>the</strong> equipment type and a three-digit item number with <strong>the</strong> notation A/B in <strong>the</strong><br />

presence of a spare. The following table shows <strong>the</strong> different identification letter<br />

symbols.<br />

Equipment Identification<br />

Letter Symbol<br />

BL<br />

C<br />

E<br />

F<br />

K<br />

P<br />

PK<br />

SU<br />

T<br />

V<br />

Equipment / Instrument<br />

Blowers<br />

Columns/Towers<br />

Heat Exchangers and Coolers<br />

Filters<br />

Compressors<br />

Pumps<br />

Vendor Packages<br />

Sumps<br />

Tanks<br />

Vessels<br />

An example of equipment numbering is BL-100 <strong>for</strong> <strong>the</strong> Blower.<br />

2.7 <strong>Power</strong> plant design assumptions.<br />

GT Master Simulations. ( For Simulation Reports See Section 4.8)<br />

The exhaust gas composition was obtained from <strong>the</strong> GT-Pro simulation. As an<br />

input, <strong>the</strong> following gas composition which had been provided by Statoil was<br />

applied under <strong>the</strong> title Statoil Gas.<br />

Component<br />

Percentage by<br />

volume<br />

Nitrogen 0.39<br />

Carbon Dioxide 2.03<br />

Methane 86.65<br />

Ethane 6.52<br />

Propane 2.29<br />

Butane 1.27<br />

Pentane 0.46<br />

Hexane 0.39<br />

TOTAL 100.00<br />

From this analysis GT-Pro calculated <strong>the</strong> Lower Calorific Value at 25°C as 46662<br />

kJ/kg, and a molecular weight of 19.28. The calorific value was applied to give<br />

<strong>the</strong> correct combustion conditions in <strong>the</strong> gas turbine which results in <strong>the</strong> fuel flow<br />

rate and hence <strong>the</strong> exhaust gas composition was derived.<br />

CB2005-0022_Final Report.Doc


3.0 PROCESS DESCRIPTION & DISCUSSIONS.<br />

CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

This section provides <strong>the</strong> process basis <strong>for</strong> <strong>the</strong> CO 2 capture facilities and<br />

discusses under separate headings <strong>the</strong> various <strong>Power</strong> plant interface<br />

considerations and design basis assumptions used to establish <strong>the</strong> CO 2 plant<br />

base case design.<br />

3.1 CO 2 Capture – Process Description<br />

The following is a process description <strong>for</strong> <strong>the</strong> <strong>proposed</strong> Econamine FG Plus SM<br />

(EFG+) plant that will be located at Statoil’s site in Tjeldbergodden, Norway.<br />

The plant is designed <strong>for</strong> a carbon dioxide production capacity of 6,170 Te/d. The<br />

product carbon dioxide is compressed and sent to <strong>the</strong> battery limits of <strong>the</strong> plant <strong>for</strong><br />

Enhanced Oil Recovery (EOR).<br />

The non-confidential process configuration <strong>for</strong> <strong>the</strong> EFG+ plant and carbon dioxide<br />

compression is shown in Process Flow Diagrams PFD-001 and PFD-002.<br />

The EFG+ plant battery limit <strong>for</strong> <strong>the</strong> flue gas feed is at <strong>the</strong> stacks of <strong>the</strong> Heat<br />

Recovery Steam Generators (HRSG). All of <strong>the</strong> flue gas from <strong>the</strong> two HRSGs is<br />

diverted from <strong>the</strong> stacks and is routed to <strong>the</strong> EFG+ plant thus resulting in a zero<br />

flow of gas through <strong>the</strong> stacks to <strong>the</strong> atmosphere.<br />

The tie-in points are at <strong>the</strong> two stacks where <strong>the</strong> flue gas is routed to a common<br />

header. The flue gas is <strong>the</strong>n divided equally and routed through three ducts to <strong>the</strong><br />

EFG+ plants in parallel. The following is a description of Train A <strong>for</strong> absorption,<br />

which is identical to Trains B and C. The stripper and CO 2 compression is one<br />

train common to <strong>the</strong> three absorption trains.<br />

The flue gas, at 80°C, enters <strong>the</strong> Direct Contact Cooler (DCC) (C-100) where <strong>the</strong><br />

gas is cooled to 30°C by a circulating water stream and any particulates present in<br />

<strong>the</strong> flue gas are removed by scrubbing. The flue gas and <strong>the</strong> circulating water are<br />

contacted over packing. By lowering <strong>the</strong> gas temperature, much of <strong>the</strong> water<br />

vapor contained in <strong>the</strong> flue gas is condensed and separated from <strong>the</strong> feed gas<br />

be<strong>for</strong>e entering <strong>the</strong> Absorber (C-101).<br />

The circulating water enters <strong>the</strong> DCC at 25°C and is heated to 42°C by <strong>the</strong> cooling<br />

and condensing of water vapor in <strong>the</strong> flue gas. The circulating water from <strong>the</strong><br />

DCC is routed through <strong>the</strong> DCC Water Cooler (E-100) by <strong>the</strong> DCC Circulating<br />

Water Pump (P-100A/B) and returned to <strong>the</strong> DCC. Cooling water at 18°C is used<br />

to cool <strong>the</strong> circulating water to 25°C. All cooling water used in <strong>the</strong> EFG+ plant is<br />

sea water from <strong>the</strong> cooling system in <strong>the</strong> power plant.<br />

A slip stream is diverted from <strong>the</strong> circulating water upstream of <strong>the</strong> pump and<br />

routed by <strong>the</strong> DCC Filter Pump (P-101A/B) through <strong>the</strong> DCC Circulating Water<br />

Filter (F-100) to continuously remove particulate matter. A portion of <strong>the</strong> filtered<br />

water is returned to <strong>the</strong> liquid surge volume in <strong>the</strong> bottom of <strong>the</strong> DCC. Excess<br />

water, produced in <strong>the</strong> DCC from <strong>the</strong> condensing of water vapor in <strong>the</strong> flue gas, is<br />

routed to <strong>the</strong> battery limits after filtration. The flow rate of this excess water is<br />

controlled by a flow controller with a reset by a level controller in <strong>the</strong> DCC.<br />

The cooled, overhead gas from <strong>the</strong> DCC is routed to Blower (BL-100) to<br />

overcome <strong>the</strong> pressure drop in <strong>the</strong> system. The flow rate of <strong>the</strong> feed gas to <strong>the</strong><br />

Blower is maintained by controlling <strong>the</strong> inlet guide vanes of <strong>the</strong> blower.<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

The treated flue gas is routed to <strong>the</strong> Absorber (C-101). The gas flows upwards<br />

counter current to <strong>the</strong> circulating MEA solvent. The MEA solvent reacts chemically<br />

with carbon dioxide, absorbing 80-90% of <strong>the</strong> carbon dioxide in <strong>the</strong> incoming flue<br />

gas. Residue gas, mainly nitrogen and oxygen , is vented after <strong>the</strong> wash section<br />

through <strong>the</strong> top of <strong>the</strong> absorber.<br />

The rich MEA solvent from all three trains is pumped from <strong>the</strong> bottom of <strong>the</strong><br />

Absorber to <strong>the</strong> top of <strong>the</strong> Stripper (C-102) by <strong>the</strong> Rich Solvent Pump (P-103A/B).<br />

It is preheated in Solvent Cross Exchanger (E-103A-L) be<strong>for</strong>e entering <strong>the</strong> top of<br />

<strong>the</strong> stripping tower. In <strong>the</strong> Stripper, <strong>the</strong> rich MEA solvent is fur<strong>the</strong>r heated in <strong>the</strong><br />

Reboiler (E-104A/B/C/D) by means of low pressure steam, releasing <strong>the</strong> carbon<br />

dioxide.<br />

From <strong>the</strong> reboiler, <strong>the</strong> lean MEA solvent is pumped by <strong>the</strong> Lean Solvent Pump (P-<br />

104A/B/C), cooled against rich solvent in <strong>the</strong> Solvent Cross Exchanger (E-103A-L)<br />

and fur<strong>the</strong>r cooled in <strong>the</strong> Lean Solvent Cooler (E-106A/B/C). A part of <strong>the</strong> lean<br />

MEA solvent is routed through <strong>the</strong> Lean Solvent Filter (F-102) in order to remove<br />

solution contaminants. The filtered solvent returns to <strong>the</strong> main lean solvent line.<br />

The combined solvent is <strong>the</strong>n divided equally and routed to <strong>the</strong> three absorption<br />

trains.<br />

Water in <strong>the</strong> overhead gas from <strong>the</strong> Stripper is condensed in Condenser (E-<br />

105A/B) and separated from <strong>the</strong> carbon dioxide product in <strong>the</strong> Overhead<br />

Accumulator (V-100). A portion of <strong>the</strong> condensed water is returned to <strong>the</strong> Stripper<br />

with <strong>the</strong> balance being equally distributed to each of <strong>the</strong> Absorbers. The carbon<br />

dioxide product is <strong>the</strong>n sent to <strong>the</strong> battery limit.<br />

To maintain <strong>the</strong> highest possible absorption capacity of <strong>the</strong> MEA solvent,<br />

contaminants, such as heat stable salts, are removed in <strong>the</strong> Reclaimer (E-107).<br />

The Reclaimer is operated as a semi-batch process. Heat stable salts are<br />

removed using a <strong>the</strong>rmal process utilizing both LP and MP steam.<br />

The carbon dioxide product from <strong>the</strong> Overhead Accumulator is compressed in <strong>the</strong><br />

Product CO 2 Compressor (K-100) to <strong>the</strong> required 103 kg/cm 2 (a) pressure. The<br />

compressor consists of five stages with intercooling provided. Each stage of<br />

compression is followed by an air cooler (E-108, 110, 112 and 114) and trim<br />

coolers (E-109, 111, 113 and 115) where <strong>the</strong> carbon dioxide product is cooled to<br />

25°C against cooling water. After each stage of cooling, <strong>the</strong> carbon dioxide is<br />

routed to knock-out drums (V-103, 104, 105 and 106) to remove condensate. At<br />

an interstage pressure of 39.5 kg/cm 2 (a), <strong>the</strong> compressed carbon dioxide is sent<br />

to a Dehydration Package (ME-100), which reduces <strong>the</strong> moisture level down to<br />

less than 50 ppm (weight basis).<br />

3.2 Cooling Water Supplies<br />

To achieve a temperature rise of 10°C, <strong>the</strong> basic power plant requires a cooling<br />

water flow of 41500 tons per hour. After <strong>the</strong> carbon capture plant is added <strong>the</strong><br />

steam flow to <strong>the</strong> power plant condenser is greatly diminished however <strong>the</strong> flow<br />

through <strong>the</strong> condenser is unchanged so that <strong>the</strong> temperature rise now becomes<br />

5.28°C.<br />

The Carbon Dioxide capture plant has been specified to use outlet sea water from<br />

<strong>the</strong> power plant condenser as it does not have to reach such a low temperature to<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

provide <strong>the</strong>rmal efficiency in <strong>the</strong> power cycle. Its consumption was based on a<br />

temperature rise of 10°C, which required a flow rate of 36750 tons per hour.<br />

It is <strong>proposed</strong> to install a booster pump to serve <strong>the</strong> carbon dioxide capture plant,<br />

which takes suction from <strong>the</strong> return sea water connection on <strong>the</strong> power plant<br />

condenser. It will boost <strong>the</strong> pressure so that <strong>the</strong>re is sufficient flow through <strong>the</strong><br />

carbon dioxide capture plant coolers and fill <strong>the</strong> system to its highest elevation,<br />

which is 6 meters above grade <strong>for</strong> <strong>the</strong> highest condenser.<br />

If <strong>the</strong>re is a weir box to control <strong>the</strong> pressure at <strong>the</strong> outlet of <strong>the</strong> power plant<br />

condenser, <strong>the</strong> suction to <strong>the</strong> booster pump and discharge from <strong>the</strong> carbon<br />

capture plant cooling system, may be made at this weir box without any<br />

connections to existing piping being required<br />

After passing through <strong>the</strong> heat exchangers <strong>the</strong> sea water is collected in <strong>the</strong> return<br />

main and is discharged to <strong>the</strong> outfall pit in <strong>the</strong> power plant. This prevents outlet<br />

sea water returning to <strong>the</strong> booster pump inlet.<br />

The system is depicted on <strong>the</strong> Cooling Water utility flow diagram, and <strong>the</strong> method<br />

of connection using <strong>the</strong> weir box in <strong>the</strong> outfall from <strong>the</strong> main power plant<br />

condenser is shown in <strong>the</strong> figure below<br />

Given a total flow of 41500 tons per hour <strong>the</strong> overall temperature rise is expected<br />

to be just above 14°C.<br />

To arrive at a specification <strong>for</strong> <strong>the</strong> booster pump an allowance of 0.7 Bar <strong>for</strong> <strong>the</strong><br />

pipework in addition to <strong>the</strong> 0.7 bar <strong>for</strong> <strong>the</strong> heat exchangers and 0.6 bar <strong>for</strong> <strong>the</strong><br />

control valves has been made. The static head difference between <strong>the</strong> level in<br />

<strong>the</strong> main weir box and <strong>the</strong> elevated weir box (see figure below) has been taken as<br />

7 metres. This give a total discharge pressure of 2.7 bar and <strong>for</strong> a flow of<br />

40000m3/h a hydraulic power of 3000kW is calculated. These are default values<br />

pending a full layout study and <strong>the</strong> investigation of operating some condensers<br />

under vacuum on <strong>the</strong> cooling water side. It is recognized <strong>the</strong>re<strong>for</strong>e that power<br />

consumptions could be optimized during plant design.<br />

CB2005-0022_Final Report.Doc


C.W. Users at Carbon Capture <strong>Plant</strong><br />

Elevated Weir Box <strong>for</strong><br />

Carbon Capture <strong>Plant</strong><br />

Return from<br />

Main<br />

Condenser<br />

Booster Pump<br />

Outfall Weir Box<br />

Outfall to Sea<br />

Flow Schematic showing Cooling Water Supply and Return connected at Outfall Weir Box


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

3.3 Energy Integration<br />

In a conventional <strong>Combined</strong> <strong>Cycle</strong> Gas Turbine power plant <strong>the</strong> steam circuit<br />

is arranged to follow <strong>the</strong> decay in temperature of <strong>the</strong> exhaust gas as heat is<br />

abstracted to give <strong>the</strong> most efficient <strong>the</strong>rmal cycle as shown below:<br />

HP Steam<br />

Source<br />

Reheat<br />

Coils<br />

IP Steam<br />

Source<br />

LP Steam<br />

Source<br />

Condenser<br />

Conventional Steam Circuit <strong>for</strong> CCGT <strong>Power</strong> <strong>Plant</strong><br />

Where a plant is to be fitted with Carbon Dioxide capture, a considerable<br />

amount of heat is required <strong>for</strong> <strong>the</strong> regeneration of <strong>the</strong> scrubbing liquor. We<br />

have <strong>for</strong>mulated a number of rules, which will give <strong>the</strong> best <strong>the</strong>rmal efficiency<br />

of <strong>the</strong> total unit and are:<br />

1. Add “source heat at as high a temperature as possible so as to achieve<br />

<strong>the</strong> highest possible Carnot efficiency (set by source and sink<br />

temperatures). Add this heat to <strong>the</strong> highest efficiency combustion system<br />

and do nt add auxiliary low efficiency combustion devices.<br />

2. Reject heat to <strong>the</strong> “sink” at as low a temperature as possible<br />

3. Extract as much work from <strong>the</strong> working fluids in <strong>the</strong> expansion turbines of<br />

<strong>the</strong> power train and only extract LP steam <strong>for</strong> amine reboilers at <strong>the</strong><br />

lowest possible pressure and temperature.<br />

4. Reject as little heat as possible to <strong>the</strong> “sink” and utilise as much waste<br />

heat as possible without violating any pinch rules<br />

5. Use <strong>the</strong> lowest possible energy in <strong>the</strong> amine stripper. This requires <strong>the</strong><br />

use of <strong>the</strong> best solvents plus intensive integration within <strong>the</strong> amine<br />

capture plant.<br />

In designing a plant where <strong>the</strong> CO 2 capture plant is commissioned with <strong>the</strong><br />

power plant, <strong>the</strong> steam turbine is sized so that it is working under optimum<br />

conditions when steam is being extracted <strong>for</strong> <strong>the</strong> CO 2 capture plant.<br />

If <strong>the</strong> CO 2 capture plant is to be commissioned some time after <strong>the</strong> power<br />

plant, <strong>the</strong>n one can ei<strong>the</strong>r:<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

1. The alternative of using an auxiliary boiler to provide <strong>the</strong> steam <strong>for</strong> <strong>the</strong><br />

CO2 capture plant has been demonstrated to be of lesser <strong>the</strong>rmal<br />

efficiency<br />

If <strong>the</strong> rules of integration are to be followed <strong>the</strong>n <strong>the</strong> alternatives are:<br />

2. Install <strong>the</strong> optimum steam turbine <strong>for</strong> <strong>the</strong> capture case and accept <strong>the</strong><br />

inefficiency resulting while <strong>the</strong> capture plant is not present.<br />

3. Install <strong>the</strong> optimum steam turbine <strong>for</strong> <strong>the</strong> capture case and add a small<br />

steam turbine to accept <strong>the</strong> steam which will be used by <strong>the</strong> capture plant<br />

when it is eventually commissioned<br />

4. Install <strong>the</strong> optimum steam turbine <strong>for</strong> <strong>the</strong> non-capture case and accept <strong>the</strong><br />

inefficiency resulting after <strong>the</strong> capture plant is commissioned and <strong>the</strong><br />

plant will be configured as shown below<br />

HP Steam<br />

Source<br />

Reheat<br />

Coils<br />

IP Steam<br />

Source<br />

LP Steam<br />

Source<br />

Condenser<br />

Steam to CO 2<br />

capture plant<br />

Steam Circuit <strong>for</strong> CCGT <strong>Power</strong> <strong>Plant</strong> with steam extraction <strong>for</strong> CO 2<br />

capture plant<br />

GT-Master versions of <strong>the</strong> abated and non-abated cases were made and<br />

used to demonstrate each case in <strong>the</strong> off design <strong>for</strong>m. The net <strong>the</strong>rmal<br />

efficiencies obtained are:<br />

With Extract Without Extract<br />

Small LP Turbine (Abated case) 51.71% 55.31%<br />

Large LP Turbine (Non-abated case) 51.50% 56.63%<br />

In reality <strong>the</strong>se results show so little difference between ei<strong>the</strong>r configuration of<br />

turbine that <strong>the</strong>re is no point in considering <strong>the</strong> addition of a small temporary<br />

turbine (alternative 3 above). Alternative 4 will give a marginally greater<br />

output until <strong>the</strong> Carbon dioxide capture plant is commissioned but <strong>the</strong> capital<br />

cost of <strong>the</strong> turbine is likely to be higher. It is suggested that options 2 & 4<br />

should be developed during detailed design with a turbine supplier when <strong>the</strong><br />

costs can be developed in greater detail and when <strong>the</strong> minor per<strong>for</strong>mance<br />

differences can be quantified with assurance.<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

3.4 Off Gas Plume Dispersion<br />

Stack Gas from Absorber Towers<br />

The stack gas has been passed through <strong>the</strong> absorber towers, <strong>the</strong>re<strong>for</strong>e it will<br />

have been saturated with water as well as having had <strong>the</strong> majority of its acidic<br />

components removed.<br />

These acidic components include oxides of nitrogen as well as carbon<br />

dioxide. Thus <strong>the</strong> final effluent gas will be air from which a portion of <strong>the</strong><br />

oxygen has been removed and which is saturated with water vapour at 37°C.<br />

The gas is not hazardous to life, however upon contact with cooler air, a<br />

visible plume of water vapour will <strong>for</strong>m. Under freezing conditions this could<br />

<strong>for</strong>m ice on exposed cold surfaces.<br />

The need <strong>for</strong> plume dispersal by heating or dilution with ambient air, will<br />

depend on <strong>the</strong> location of <strong>the</strong> plume in relation to access roads and work<br />

areas, where it could reduce visibility; and structures, where icing could lead<br />

to overloading of such structures. It is recommended that this be studied in a<br />

later phase.<br />

3.5 Emissions and Effluents Introduction<br />

The Econamine FG Plus SM (EFG+) process produces three main<br />

emissions/effluents:<br />

• Absorber Stack Emissions: MEA and Ammonia<br />

• Reclaimer Waste<br />

• DCC Excess Water containing dissolved carbon dioxide<br />

3.5.1 Absorber Stack Emissions<br />

The expected concentrations of MEA and ammonia in <strong>the</strong> absorber stack gas<br />

are as follows.<br />

Expected Emissions<br />

Expected<br />

Emissions<br />

MEA<br />

Ammonia<br />

ppmv 0.2 23<br />

3.5.2 Reclaimer Waste<br />

Heat stable salts (HSS) are <strong>for</strong>med in <strong>the</strong> EFG+ process due to acid-base<br />

reaction between MEA and different acid products present in <strong>the</strong> flue gas or in<br />

<strong>the</strong> solution, including:<br />

• SO 2 and SO 3 in <strong>the</strong> flue gas<br />

• The NO 2 portion of NO x in <strong>the</strong> flue gas<br />

• Small quantities of acids generated by oxidation MEA<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

HSS are removed from <strong>the</strong> system using <strong>the</strong>rmal reclaiming. The expected<br />

amount of reclaimer waste and a typical waste composition as follows.<br />

Table 2<br />

Reclaimer Waste<br />

Expected Amount Tonnes/yr 2,300<br />

Composition<br />

MEA %wt 15<br />

Water %wt 7<br />

MEA Degradation Products %wt 75<br />

Inorganic Residue %wt 3<br />

3.5.3 DCC Excess Water<br />

The hot flue gas from <strong>the</strong> Heat Recovery Steam Generators must first be<br />

cooled to <strong>the</strong> operating conditions of <strong>the</strong> EFG+ plant to minimize amine<br />

degradation. The gas is cooled in <strong>the</strong> Direct Contact Cooler (DCC) by a<br />

circulating water stream. By lowering <strong>the</strong> gas temperature, much of <strong>the</strong> water<br />

vapor contained in <strong>the</strong> flue gas is condensed and separated from <strong>the</strong> feed<br />

upstream of <strong>the</strong> absorber. The condensed water from <strong>the</strong> flue gas is taken<br />

out of <strong>the</strong> DCC with <strong>the</strong> hot circulating water. A slip stream of excess water is<br />

taken from <strong>the</strong> circulating water stream to maintain <strong>the</strong> water balance around<br />

<strong>the</strong> DCC. This DCC excess water contains some dissolved carbon dioxide<br />

and is combined with <strong>the</strong> cooling water return. The expected amount of DCC<br />

excess water is shown in table 3.<br />

Table 3<br />

DCC Excess Water<br />

Expected Amount m 3 /hr 116.4<br />

pH pH 5.0 – 5.5<br />

It is <strong>proposed</strong> that this water be used as demineralized plant make-up after<br />

degassing <strong>the</strong> carbon dioxide.<br />

3.6 Process Utility Interfaces<br />

The following table provides a listing of <strong>Power</strong> plant utility interfaces with<br />

relevant stream in<strong>for</strong>mation.<br />

ECONAMINE FG PLUS SM INTERFACE TABLE<br />

Commodity Unit In/Out Flow Temp.<br />

(°C)<br />

Pressure<br />

BAR(G)<br />

PROCESS<br />

Flue Gas<br />

Vent Gas<br />

CO 2 Product<br />

DCC Excess<br />

Water<br />

1000 m 3 /hr<br />

(actual)<br />

1000 m 3 /hr<br />

(actual)<br />

m 3 /hr<br />

(actual)<br />

Te/hr<br />

In 5,090 80 0.0<br />

Out 4,231 37 0.0<br />

Out 90,361 25 0.6<br />

Out 115.5 42 2.5<br />

UTILITIES<br />

Demin Water Te/hr In 55.2 40 7.0<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

Seawater<br />

Coolant Te/hr In 36,750 18<br />

2.7 @ Booster<br />

Pump Discharge<br />

Seawater<br />

Coolant<br />

Te/hr Out 36,750 28<br />

Low Pressure<br />

Steam Te/hr In 424.4 148 3.5<br />

Medium<br />

Pressure Steam<br />

Condensate<br />

Nitrogen<br />

Instrument Air<br />

CB2005-0022_Final Report.Doc<br />

ATM @ 7m<br />

elevation<br />

Te/hr In 24.1 (Note 1) 161 5.4<br />

Te/hr Out 424.4 147 7.2<br />

Nm 3 /hr In 4,839 30 7.0<br />

Nm 3 /hr In 122 30 7.0<br />

Notes:<br />

1) Medium Pressure Steam is required intermittently towards <strong>the</strong> end of <strong>the</strong> reclaiming cycle<br />

(8-12 hours per month).<br />

2) Pressure drop across water cooled exchangers = 0.7 BAR. Add additional 0.6 BAR <strong>for</strong><br />

variable loss. Pressure loss in inlet lines allowance = 0.7 BAR. Elevation of outlet weir<br />

box taken as 7 meters.<br />

3.7 <strong>Power</strong> <strong>Plant</strong> Pre-investment<br />

It is anticipated that limited pre investment would be required in <strong>the</strong> <strong>Power</strong><br />

plant to accommodate <strong>the</strong> carbon capture plant. Main pre investment would<br />

be in <strong>the</strong> specification of <strong>the</strong> HRSG and <strong>the</strong> steam turbine where a change to<br />

<strong>the</strong> specification of <strong>the</strong> equipment is best accommodated prior to purchase.<br />

Recommended changes to <strong>the</strong> specification are as follows.<br />

Qualifications to HRSG Specification to facilitate addition of Carbon Capture<br />

`<strong>Plant</strong><br />

1. Steam Extracted <strong>for</strong>m <strong>the</strong> crossover <strong>for</strong>m <strong>the</strong> IP to LP sections of <strong>the</strong><br />

turbine should be arranged to be at 4.6 Bar (a) at <strong>the</strong> turbine, so as to suit<br />

<strong>the</strong> temperature requirement of <strong>the</strong> carbon capture plant.<br />

2. Low pressure steam supply to <strong>the</strong> Carbon Capture <strong>Plant</strong> is to be supplied<br />

from <strong>the</strong> boiler drum plus extraction <strong>for</strong> <strong>the</strong> IP/LP crossover of <strong>the</strong> steam<br />

turbine. It will be desuperheated to near saturation conditions using an<br />

enthalpy controlled desuperheater. (See attached sketch at <strong>the</strong> end of this<br />

section.)<br />

3. No provision <strong>for</strong> a LP superheater is needed<br />

4. Preferred configuration of <strong>the</strong> HRSG is horizontal to enable <strong>the</strong> ductwork<br />

to <strong>the</strong> Carbon Capture plant to be arranged <strong>for</strong> minimum pressure loss<br />

5. Space provision should be made so that <strong>the</strong> structure of <strong>the</strong> HRSG can<br />

have a diverter damper installed at a later date, which will divert flue gas<br />

from <strong>the</strong> stack to <strong>the</strong> future Carbon Capture <strong>Plant</strong><br />

Qualifications to Steam Turbine Specification to facilitate addition of Carbon<br />

Capture <strong>Plant</strong><br />

1. Pressure at <strong>the</strong> IP/LP crossover to be 4.6 bar(a)<br />

2. The turbine is to be constructed to enable <strong>the</strong> later addition of controlled<br />

steam extraction from <strong>the</strong> IP/LP crossover.<br />

3. The actual LP steam pressure supplied should be controlled at <strong>the</strong> turbine<br />

to meet <strong>the</strong> load on <strong>the</strong> carbon capture plant


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

Sea Water Off Take.<br />

Sea water <strong>for</strong> cooling of <strong>the</strong> carbon capture plant is taken from <strong>the</strong> main<br />

<strong>Power</strong> plant cooling water supply. It is <strong>the</strong>re<strong>for</strong>e recommended that <strong>the</strong> Wier<br />

Box associated with <strong>the</strong> SW return from <strong>the</strong> main condenser is sized sufficient<br />

to accommodate <strong>the</strong> suction and discharge piping to and from <strong>the</strong> carbon<br />

capture plant.<br />

As shown in <strong>the</strong> attached accompanying diagram.<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

FW<br />

13.14p<br />

26T<br />

109.8h<br />

785.3M<br />

5.274p<br />

26T<br />

109.8h<br />

785.3M<br />

LPE<br />

103560 Q<br />

5.12p<br />

139T<br />

584.5h<br />

785.3M<br />

LPB<br />

65766 Q<br />

5.12p<br />

153T<br />

2748.6h<br />

90.23M<br />

ST extraction<br />

5.12p<br />

304T<br />

3073h<br />

289.2M<br />

695.1 M<br />

HP/IP<br />

5.12 p<br />

153 T<br />

2748.6 h<br />

90.23 M<br />

4.592p<br />

149T<br />

2739.3h<br />

424.4M<br />

45 M<br />

CB2005-0022_Final Report.Doc


4.0 KEY DELIVERABLES –<br />

PFD’S, UFD’S, Mass Balances, Equipment List<br />

CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.1 Block Flow Diagram<br />

CB2005-0022_Final Report.Doc


Battery Limits<br />

Flue Gas to<br />

Atmosphere<br />

Gas<br />

Turbine 1<br />

HRSG<br />

1<br />

Stack<br />

Gas<br />

NNF<br />

Excess<br />

Water<br />

DCC<br />

Train A<br />

Cooling<br />

Water<br />

Return<br />

Blower<br />

Train A<br />

Cooling<br />

Water<br />

Supply<br />

Absorber<br />

Train A<br />

Flue Gas to<br />

Atmosphere<br />

Steam<br />

Reclaimer<br />

Condensate<br />

Dehydration<br />

Package<br />

CO 2<br />

Compressor<br />

Carbon Dioxide<br />

Product<br />

6,170 MTPD<br />

Gas<br />

Turbine 2<br />

HRSG<br />

2<br />

Stack<br />

Gas<br />

NNF<br />

Excess<br />

Water<br />

DCC<br />

Train B<br />

Cooling<br />

Water<br />

Return<br />

Cooling<br />

Water<br />

Supply<br />

Blower<br />

Train B<br />

Absorber<br />

Train B<br />

Flue Gas to<br />

Atmosphere<br />

Steam<br />

Stripper<br />

Reboiler<br />

Condensate<br />

Cooling<br />

Water<br />

Return<br />

Cooling<br />

Water<br />

Supply<br />

DCC<br />

Train C<br />

Blower<br />

Train C<br />

Absorber<br />

Train C<br />

Excess<br />

Water<br />

Abbreviations:<br />

DCC - Direct Contact Cooler<br />

HRSG - Heat Recovery Steam Generator<br />

MTPD - Metric Tons per Day<br />

NNF - Normally No Flow<br />

Cooling<br />

Water<br />

Return<br />

Cooling<br />

Water<br />

Supply<br />

Flue Gas<br />

Solvent<br />

CO2 Product<br />

Steam/Condensate<br />

Cooling Water<br />

Rev. Date Revision Description By<br />

A 2/15/05 Issued to Client. VJF<br />

Chk<br />

JG<br />

Appv<br />

SR<br />

Statoil<br />

Block Flow Diagram<br />

®<br />

Drawing Number: BFD-001


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.2 PFD Economine FG Plus<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.3 PFD Economine FG Plus – Compression<br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.4 Heat and Material Balances<br />

CB2005-0022_Final Report.Doc


Statoil<br />

Revision A<br />

Econamine FG Plus SM<br />

Contract: A0NL<br />

Overall Heat and Material Balance March 31, 2005<br />

Stream Description<br />

Flue Gas to Direct<br />

Contact Cooler<br />

Absorber Overhead to<br />

Atmosphere<br />

Make-Up Wash Water<br />

to Absorber<br />

Excess Water from<br />

DCC<br />

Carbon Dioxide<br />

Product<br />

Compressed CO2<br />

Product<br />

Stream Numbers<br />

Temperature, °C<br />

Pressure, kg/cm² (a)<br />

1 (Note 2)<br />

80.0<br />

1.03<br />

2 (Note 2)<br />

36.9<br />

1.03<br />

3 (Note 2)<br />

40.0<br />

1.03<br />

4 (Note 2)<br />

41.7<br />

3.53<br />

5<br />

25.0<br />

1.65<br />

6<br />

124.0<br />

103.43<br />

Component Flows <strong>MW</strong> kgmol/hr mol% kgmol/hr mol% kgmol/hr mol% kgmol/hr mol% kgmol/hr mol% kgmol/hr mol%<br />

H 2 O 18.02 13,782 7.8% 10,332 6.2% 3,072 100.0% 6,402 100.0% 120 2.0% 0 0.0%<br />

CO 2 44.01 6,873 3.9% 1,032 0.6% 0 0.0% 0 0.0% 5,841 98.0% 5,841 100.0%<br />

MEA 61.08 0 0.0% Trace 0.0% 0 0.0% 0 0.0% Trace 0.0% 0 0.0%<br />

N 2 + Ar 28.02 132,801 75.5% 132,801 79.8% 0 0.0% 0 0.0% 0 0.0% 0 0.0%<br />

O 2 32.00 22,323 12.7% 22,323 13.4% 0 0.0% 0 0.0% 0 0.0% 0 0.0%<br />

HSS - 0 0.0% 0 0.0% 0 0.0% 0 0.0% 0 0.0% 0 0.0%<br />

Total kgmol/hr<br />

Total kg/hr<br />

Molecular Weight<br />

Density, kg/m³<br />

Liquid Flow, m³/hr<br />

Vapor Flow, m³/hr<br />

175,779<br />

4,985,400<br />

28.4<br />

0.980<br />

1,696,580<br />

166,488<br />

4,665,900<br />

28.0<br />

1.103<br />

1,410,319<br />

3,072<br />

55,200<br />

18.0<br />

992<br />

18.5<br />

6,402<br />

115,500<br />

18.0<br />

992<br />

38.8<br />

5,961<br />

259,200<br />

43.5<br />

2.869<br />

90,361<br />

5,841<br />

257,000<br />

44.0<br />

720<br />

356.9<br />

NOTES:<br />

1) Stream in<strong>for</strong>mation corresponds to Process Flow Diagram PFD-001.<br />

2) Stream flow rate listed is <strong>the</strong> total flow to/from all three absorption trains of <strong>the</strong> Econamine FG Plus plant. Flow to/from each absorption train is<br />

one-third of <strong>the</strong> indicated flow.


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.5 UFD Cooling Water<br />

CB2005-0022_Final Report.Doc


12,984 Te/hr<br />

28°C<br />

Seawater<br />

Return<br />

129.8<br />

Gcal/hr<br />

229.5 Gcal/hr<br />

2.24<br />

Gcal/hr<br />

1.95<br />

Gcal/hr<br />

1.85<br />

Gcal/hr<br />

2.08<br />

Gcal/hr<br />

E-100/200/300<br />

DCC Water<br />

Coolers<br />

Econamine FG<br />

Plus SM Absorption<br />

and Stripping<br />

E-109<br />

Compressor<br />

Trim Cooler #1<br />

E-111<br />

Compressor<br />

Trim Cooler #2<br />

E-113<br />

Compressor<br />

Trim Cooler #3<br />

E-115<br />

Compressor<br />

Trim Cooler #4<br />

22,955 Te/hr<br />

223 Te/hr<br />

194 Te/hr<br />

185 Te/hr<br />

208 Te/hr<br />

Seawater from<br />

<strong>Power</strong> <strong>Plant</strong><br />

18°C<br />

36,749 Te/hr<br />

Rev. Date Revision Description By<br />

A 4/4/05 Issued to Client JPG<br />

Chk<br />

VJF<br />

Appv<br />

SR<br />

Statoil<br />

Cooling Water Utility Flow Diagram<br />

Non-Confidential Version<br />

Drawing Number: UFD-001<br />

®


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.6 Water Balance<br />

CB2005-0022_Final Report.Doc


186.0 Te/hr<br />

H 2<br />

O in Absorber<br />

Vent to Atmosphere<br />

H 2<br />

O in Flue Gas from<br />

<strong>Power</strong> <strong>Plant</strong><br />

Demin H 2<br />

O from<br />

<strong>Power</strong> <strong>Plant</strong><br />

248.4 Te/hr<br />

55.2 Te/hr<br />

CARBON DIOXIDE<br />

RECOVERY UNIT<br />

2.1 Te/hr H 2<br />

O in CO 2<br />

to<br />

Compression<br />

115.5 Te/hr DCC Excess H 2<br />

O to<br />

<strong>Power</strong> <strong>Plant</strong><br />

Rev. Date Revision Description By<br />

A 2/14/05 Issued to Client JPG<br />

Chk<br />

VJF<br />

Appv<br />

SR<br />

Statoil<br />

Water Balance<br />

®<br />

Drawing Number: BFD-002


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

4.7 Equipment list<br />

CB2005-0022_Final Report.Doc


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Compressors / Blowers<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Actual Inlet<br />

Flow<br />

Inlet Flow<br />

Suction<br />

Pressure<br />

Normal Pres.<br />

Rise<br />

<strong>Power</strong><br />

m 3 /hr kg/hr kg/cm 2 (g) kg/cm 2 kW<br />

Materials<br />

Comments<br />

BL-100 Blower Data is Fluor Confidential<br />

BL-100M Blower Motor Data is Fluor Confidential<br />

BL-200 Blower Data is Fluor Confidential<br />

BL-200M Blower Motor Data is Fluor Confidential<br />

BL-300 Blower Data is Fluor Confidential<br />

BL-300M Blower Motor Data is Fluor Confidential<br />

K-100<br />

CO 2 Product<br />

Compressor<br />

90,361 259,200<br />

0.620<br />

102 22,281 316L SS<br />

Major Ticket Item: Cost = $3,922,695<br />

5-stage - 3 body centrifugal compressor.<br />

Cost does not include interstage coolers or interstage<br />

knockout pots.<br />

Cost basis: Factored from ano<strong>the</strong>r vendor budgetary quote.


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Exchangers<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

E-100, E-200,<br />

E-300<br />

Description<br />

Pres Temp Pres Temp<br />

Gcal/hr m 2 kg/cm 2 (g) °C bar (g) °C<br />

DCC Water Cooler Plate 43.3 1,548 6.0 125 6.0 125 CS Titanium<br />

E-101, E-201, E-<br />

Wash Water Cooler<br />

301<br />

TEMA<br />

Type or<br />

Plate<br />

Exch.<br />

Operating<br />

Duty<br />

Surface Area<br />

Shell/Hot (<strong>for</strong> Plate or<br />

AC)<br />

Design Conditions<br />

Tube/Cold<br />

(<strong>for</strong> Plate or AC)<br />

Shell/<br />

Frame/ Fin<br />

Cost = $490,000 (per train)<br />

Cost basis: Vendor budgetary quote.<br />

Data is Fluor Confidential<br />

E-103 Solvent Cross Exhanger Data is Fluor Confidential<br />

Material<br />

Tube/ Plate<br />

Comments<br />

E-104 Reboiler Data is Fluor Confidential<br />

E-105 Condenser Data is Fluor Confidential<br />

E-106 Lean Solvent Cooler Data is Fluor Confidential<br />

E-107 Reclaimer Data is Fluor Confidential<br />

E-108<br />

CO 2 Compressor Air<br />

Cooler #1<br />

Air Cooler 2.33 - 4.5 125 - - Aluminum 304L SS<br />

Cost = $349,000<br />

Cost basis: In-house sizing and pricing<br />

E-109<br />

CO 2 Compressor Trim<br />

Cooler #1<br />

AEU 2.24 739.5 4.5 125 6.0 125 304 SS Titanium<br />

Cost = $425,000<br />

Cost basis: In-house sizing and pricing<br />

E-110<br />

CO 2 Compressor Air<br />

Cooler #2<br />

Air Cooler 2.42 - 8.3 125 - - Aluminum 304L SS<br />

Cost = $315,000<br />

Cost basis: In-house sizing and pricing<br />

E-111<br />

CO 2 Compressor Trim<br />

Cooler #2<br />

AEU 1.95 715.2 8.3 125 6.4 125 304 SS Titanium<br />

Cost = $416,000<br />

Cost basis: In-house sizing and pricing<br />

E-112<br />

CO 2 Compressor Air<br />

Cooler #3<br />

Air Cooler 2.61 - 17.4 125 - - Aluminum 304L SS<br />

Cost = $286,000<br />

Cost basis: In-house sizing and pricing<br />

E-113<br />

CO 2 Compressor Trim<br />

Cooler #3<br />

AEU 1.85 694.6 17.4 125 13.4 125 304 SS Titanium<br />

Cost = $414,000<br />

Cost basis: In-house sizing and pricing<br />

E-114<br />

CO 2 Compressor Air<br />

Cooler #4<br />

Air Cooler 3.27 - 42.0 125 - - Aluminum 304L SS<br />

Cost = $321,000<br />

Cost basis: In-house sizing and pricing<br />

E-115<br />

CO 2 Compressor Trim<br />

Cooler #4<br />

AEU 2.08 743.8 42.0 125 32.3 125 304 SS Titanium<br />

Cost = $486,000<br />

Cost basis: In-house sizing and pricing


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Filters<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Operating<br />

Vol. Flow<br />

Part. Size<br />

Op.<br />

Temp<br />

Pressure<br />

Design<br />

Temp<br />

m 3 /hr micron °C kg/cm 2 (g) °C<br />

Material<br />

Comments<br />

F-100, F-200, F-<br />

300<br />

DCC Circulating Water Filter 105.1 5 42 6.6 125<br />

Shell: 304LSS<br />

Internals: 304 SS<br />

Cost = $7,500 (per train)<br />

Cost basis: Vendor budgetary quote.<br />

F-101, F-201, F-<br />

301<br />

Wash Water Filter<br />

Data is Fluor Confidential<br />

F-102 Lean Solvent Filter Data is Fluor Confidential<br />

F-103 Solvent Sump Filter Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Columns and Vessels<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Vertical /<br />

Horizontal<br />

Dimensions<br />

Diameter T/T<br />

meter<br />

meter<br />

Design<br />

Press Temp<br />

kg/cm 2 (g) °C<br />

C-100/200/300 Direct Contact Cooler Vertical 13.8 15.9 0.7 125<br />

Material<br />

CS with 0.10"<br />

min 304L<br />

cladding<br />

Comments<br />

Major Ticket Item: Cost = $1,942,605 (per train)<br />

Cost basis: Factored from ano<strong>the</strong>r project.<br />

Internals<br />

304 SS<br />

Major Ticket Item: Cost = $1,948,500 (per train)<br />

Cost basis: Vendor budgetary quote.<br />

C-101/201/301 Absorber Data is Fluor Confidential<br />

Internals<br />

Data is Fluor Confidential<br />

C-102 Stripper Data is Fluor Confidential<br />

Internals<br />

Data is Fluor Confidential<br />

V-100 Overhead Accumulator Data is Fluor Confidential<br />

V-101 A/B<br />

Reboiler Condensate<br />

Drums<br />

Data is Fluor Confidential<br />

V-102<br />

Reclaimer Condensate<br />

Drum<br />

Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Columns and Vessels (continued)<br />

Statoil<br />

Contract: A0NL<br />

Date: 18-Feb-2005<br />

Tag No. Description V/H<br />

Dimensions<br />

Diameter T/T<br />

meter meter<br />

Design<br />

Press Temp<br />

kg/cm 2 (g) °C<br />

Material<br />

Comments<br />

V-103<br />

CO 2 Compressor KO<br />

Drum #1<br />

Vertical 3.4 4.5 3.5 125 316 SS<br />

Cost = $108,700<br />

Cost basis: K-base<br />

V-104<br />

CO 2 Compressor KO<br />

Drum #2<br />

Vertical 2.9 3.9 7.4 125 316 SS<br />

Cost = $86,<strong>800</strong><br />

Cost basis: K-base<br />

V-105<br />

CO 2 Compressor KO<br />

Drum #3<br />

Vertical 2.4 3.4 17.0 125 316 SS<br />

Cost = $90,700<br />

Cost basis: K-base<br />

V-106<br />

CO 2 Compressor KO<br />

Drum #4<br />

Vertical 2.0 3.1 41.6 125 316 SS<br />

Cost = $116,100<br />

Cost basis: K-base<br />

V-107<br />

Reclaimer Waste<br />

Vessel<br />

Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Pumps<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Pump Type<br />

Operating Diff. Hyd. Spec.<br />

Material<br />

Flow Head <strong>Power</strong> Grav.<br />

m 3 /hr m kW @ PT Impeller Casing<br />

Comments<br />

P-100/200/300 A/B DCC Circulating Water Pump Centrifugal 2,652 35.6 280.1 0.99 316L SS 316L SS<br />

P-101/201/301 A/B DCC Filter Pumps Centrifugal 105 53.7 15.5 0.99 CS CS<br />

Cost = $353,010 (per train)<br />

Cost basis: Factored from ano<strong>the</strong>r project.<br />

Cost = $36,330 (per train)<br />

Cost basis: Factored from ano<strong>the</strong>r project.<br />

Class S-4, if CS construction<br />

P-103/203/303 A/B Rich Solvent Pump Data is Fluor Confidential<br />

P-104 A/B/C Lean Solvent Pump Data is Fluor Confidential<br />

P-105 A/B Reflux Pump Data is Fluor Confidential<br />

P-106/206/306 A/B Wash Water Cooler Pump Data is Fluor Confidential<br />

P-107 Solvent Make-up Pump Data is Fluor Confidential<br />

P-108 Solvent Charge Pump Data is Fluor Confidential<br />

P-109 A/B<br />

Reboiler A/B Condensate<br />

Pump<br />

Data is Fluor Confidential


Tag No. Description Pump Type<br />

Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Pumps (continued)<br />

Operating Diff. Hyd. Spec.<br />

Material<br />

Flow Head <strong>Power</strong> Grav.<br />

m 3 /hr m kW @ PT Impeller Casing<br />

Statoil<br />

Contract: A0NL<br />

Date: 18-Feb-2005<br />

Comments<br />

P-110 A/B<br />

Reboiler C/D Condensate<br />

Pump<br />

Data is Fluor Confidential<br />

P-111 A/B Solvent Sump Pump Data is Fluor Confidential<br />

P-112 A/B/C Seawater Booster Pump Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Sumps<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Dimensions<br />

Length Width Depth<br />

meter meter meter<br />

Comments<br />

SU-100 Solvent Sump Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Tanks<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Dimensions<br />

Design<br />

Tag No.<br />

Description<br />

Diameter<br />

T/T<br />

Pres<br />

Temp<br />

Material<br />

Comments<br />

meter<br />

meter<br />

mm H 2 O (g) °C<br />

TK-100<br />

Solvent Storage Tank<br />

(with Solvent Pump Suction Heater H-<br />

100)<br />

Data is Fluor Confidential


Econamine FG Plus SM<br />

Preliminary Equipment List<br />

Miscellaneous<br />

Statoil<br />

Contract: A0NL<br />

Date: 04-Apr-2005<br />

Tag No.<br />

Description<br />

Material<br />

Comments<br />

PK-101 Soda Ash Injection Package Data is Fluor Confidential<br />

ME-100<br />

Dehydration Package<br />

Major Ticket Item: Cost = $1,914,885<br />

Cost basis: Factored from ano<strong>the</strong>r project.<br />

Glycerol Dryer dehydrating product CO2 to 50 pp (wt ) of water (-46°C water dew point): All equipment skid mounted.<br />

CR-01<br />

Cranes, Hoists, etc, CO2<br />

Compressor Building Service<br />

Crane<br />

Cost = $276,400


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

5.0 FACILITIES LAYOUT<br />

5.1 Montage of <strong>Plant</strong><br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

5.2 3D Perspective of CO 2 <strong>Plant</strong><br />

CB2005-0022_Final Report.Doc


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

5.3 Plot Plan CO 2 plant<br />

CB2005-0022_Final Report.Doc


THE INFORMATION ON THIS DRAWING DEPICTS THE IMPLEMENTATION OF FLUOR'S<br />

SM<br />

ECONAMINE FG PLUS TECHNOLOGY, WHICH IS CONFIDENTIAL AND THE SOLE PROPERTY<br />

OF AND PROPRIETARY TO THE FLUOR CORPORATION.<br />

CONFIDENTIAL


SECTION AA<br />

SECTION BB<br />

THE INFORMATION ON THIS DRAWING DEPICTS THE IMPLEMENTATION OF FLUOR'S<br />

SM<br />

ECONAMINE FG PLUS TECHNOLOGY, WHICH IS CONFIDENTIAL AND THE SOLE PROPERTY<br />

OF AND PROPRIETARY TO THE FLUOR CORPORATION.<br />

CONFIDENTIAL


THE INFORMATION ON THIS DRAWING DEPICTS THE IMPLEMENTATION OF FLUOR'S<br />

SM<br />

ECONAMINE FG PLUS TECHNOLOGY, WHICH IS CONFIDENTIAL AND THE SOLE PROPERTY<br />

OF AND PROPRIETARY TO THE FLUOR CORPORATION.<br />

CONFIDENTIAL


THE INFORMATION ON THIS DRAWING DEPICTS THE IMPLEMENTATION OF FLUOR'S<br />

SM<br />

ECONAMINE FG PLUS TECHNOLOGY, WHICH IS CONFIDENTIAL AND THE SOLE PROPERTY<br />

OF AND PROPRIETARY TO THE FLUOR CORPORATION.<br />

CONFIDENTIAL


CO 2 Capture Study<br />

For <strong>800</strong> <strong>MW</strong> <strong>Power</strong> <strong>Plant</strong> – Tjeldbergodden<br />

6.0 CAPEX ESTIMATE<br />

6.0 Total Installed Cost<br />

CB2005-0022_Final Report.Doc


SECTION 6<br />

TOTAL INSTALLED COST<br />

Direct Field Costs<br />

O<strong>the</strong>r Costs<br />

$325 MM<br />

$175 MM<br />

Total Installed Cost<br />

$500 MM

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