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Published by the<br />

<strong>National</strong> <strong>Water</strong> Research Institute<br />

NWRI-2006-02<br />

10500 Ellis Avenue • P.O. Box 20865<br />

Fountain Valley, California 92728-0865 USA<br />

(714) 378-3278 • Fax: (714) 378-3375<br />

www.NWRI-USA.org


Conference Planning Committee<br />

Chair:<br />

✦ SAMER S. ADHAM, Ph.D., MWH<br />

✦ SIMON J. JUDD, Ph.D., Cranfield University<br />

✦ GINA MELIN, <strong>National</strong> <strong>Water</strong> Research Institute<br />

✦ JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute<br />

✦ TAMMY RUSSO, <strong>National</strong> <strong>Water</strong> Research Institute<br />

Sponsors<br />

The Conference Planning Committee is indebted to the following organizations and<br />

corporations whose support has helped make this conference a success.<br />

✦ NATIONAL WATER RESEARCH INSTITUTE<br />

✦ MWH<br />

✦ CRANFIELD UNIVERSITY<br />

✦ USFILTER<br />

✦ ZENON ENVIRONMENTAL CORPORATION<br />

✦ ORANGE COUNTY WATER DISTRICT<br />

✦ CORONA DEPARTMENT OF WATER AND POWER<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

iii


Foreword<br />

ICROFILTRATION IV is the fourth in a series of conferences sponsored by the <strong>National</strong><br />

M<strong>Water</strong> Research Institute (NWRI) devoted to low-pressure membrane (microfiltration<br />

and ultrafiltration) applications to water and wastewater treatment.<br />

Since the first NWRI-sponsored Microfiltration Conference in 1994, the technology has<br />

advanced and become a popular alternative to conventional treatment. MICROFILTRATION IV<br />

provides an update on the status of the technology and a focus on critical issues faced by<br />

end-users, such as new applications, regulatory perspectives, operational experiences, and<br />

fouling control.<br />

A special feature of MICROFILTRATION IV is a one-day short course on membrane bioreactors<br />

(MBRs), a promising technology that uses microfiltration to enhance the wastewater and<br />

reclaimed water treatment processes. The short course provides information on the state-of-the-art<br />

in MBRs and focuses on topics such as MBR design, procurement issues, and costs.<br />

The extended abstracts presented in this document were the contributions of conference speakers.<br />

The opinions expressed within the abstracts are those of individual authors and do not<br />

necessarily reflect those of the sponsors.<br />

NWRI gratefully acknowledges the efforts of all those involved with the planning, organizing,<br />

and sponsoring the conference, including MWH, Cranfield University, USFilter, Zenon<br />

Environmental Corporation, the Corona Department of <strong>Water</strong> and Power, and Orange County<br />

<strong>Water</strong> District. NWRI also extends special thanks to the conference moderators and speakers,<br />

whose expertise provided invaluable insight into the status and needs of membrane technology.<br />

NWRI would also like to extend sincere thanks to Gina Melin, Editor, and Tim Hogan,<br />

Graphic Designer, for their efforts in bringing this document to press and ensuring that the<br />

quality of each and every abstract reached their fullest potential.<br />

Lastly, this conference would not have been possible without the vision of Ronald B. Linsky,<br />

Executive Director of NWRI until his passing in August 2005. Ron will be fondly<br />

remembered for his energy, enthusiasm, and dedication to NWRI and the water community.<br />

Jeffrey J. Mosher<br />

Acting Executive Director<br />

<strong>National</strong> <strong>Water</strong> Research Institute<br />

Fountain Valley, California<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

v


Program and Contents<br />

WEDNESDAY, MARCH 22, 2006<br />

7:00 am - 9:00 am Registration Foyer of California Ballroom<br />

Session 1: Introduction<br />

California Ballroom<br />

Moderated by JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />

8:30 am - 8:45 am Welcome<br />

JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />

8:45 am - 9:15 am <strong>Membrane</strong> <strong>Bioreactors</strong> and ............................. 1<br />

the Future of Wastewater Treatment<br />

R. RHODES TRUSSELL, Ph.D., P.E., DEE,<br />

Trussell Technologies, Inc., California<br />

9:15 am - 9:45 am Biological Process Principles ............................ 3<br />

GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />

University of California, Davis, California<br />

9:45 am - 10:00 am Break<br />

Session 2: Fundamentals and Applications<br />

Moderated by SAMER S. ADHAM, Ph.D., MWH, California<br />

10:00 am - 10:45 am <strong>Membrane</strong> Bioreactor Process Fundamentals .............. 5<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

10:45 am - 11:05 am Commercially Available <strong>Membrane</strong> Bioreactor Systems ...... 11<br />

JAMES F. DECAROLIS, MWH, California<br />

11:05 am - 11:25 am Evaluation of Conventional Activated Sludge .............. 19<br />

Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />

R. SHANE TRUSSELL, Ph.D., P.E.,<br />

Trussell Technologies, Inc., California<br />

11:25 am - 11:45 am <strong>Membrane</strong> Bioreactor Global Knowledgebase .............. 25<br />

GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE,<br />

CH2M HILL, Colorado<br />

11:45 am - 12:15 pm Panel Discussion<br />

12:15 pm - 1:30 pm Lunch The Atrium<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

vii


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Moderated by GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />

University of California, Davis, California<br />

1:30 pm - 2:00 pm Design, Procurement, and Costs of. ...................... 29<br />

<strong>Membrane</strong> Bioreactor Systems<br />

STEPHEN M. LACY, P.E., DEE, MWH, Nevada<br />

2:00 pm - 2:20 pm Retrofit of an Existing .................................. 33<br />

Conventional Wastewater Treatment Plant with<br />

Zenon <strong>Membrane</strong> Bioreactor Technology<br />

DAVE N. COMMONS,<br />

City of Redlands Municipal Utilities Department, California<br />

2:20 pm - 2:40 pm Retrofit of an Existing .................................. 37<br />

Conventional Wastewater Treatment Plant<br />

with USFilter <strong>Membrane</strong> Bioreactor Technology<br />

JOHN HATCHER, Oconee County Utility Department, Georgia<br />

2:40 pm - 3:20 pm <strong>Membrane</strong> Bioreactor Applications: A Global Perspective .... 39<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

3:20 pm - 3:45 pm Panel Discussion<br />

3:45 pm - 4:00 pm Break<br />

Session 4: Innovative Applications and Future Outlook of the Technology<br />

Moderated by R. RHODES TRUSSELL, Ph.D., P.E., DEE<br />

Trussell Technologies, Inc., California<br />

4:00 pm - 4:30 pm <strong>Membrane</strong> Aeration, Biofilms, ........................... 43<br />

and <strong>Membrane</strong> <strong>Bioreactors</strong><br />

MICHAEL J. SEMMENS, Ph.D., P.E.,<br />

University of Minnesota, Minnesota<br />

4:30 pm - 4:50 pm Future Outlook on <strong>Membrane</strong> Bioreactor Technology ....... 45<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

4:50 pm - 5:15 pm Panel Discussion<br />

5:15 pm <strong>Short</strong> <strong>Course</strong> on <strong>Membrane</strong> <strong>Bioreactors</strong> Adjourns<br />

viii


THURSDAY, MARCH 23, 2006 ~ FIELD TRIPS<br />

8:30 am - 11:30 am Field Trips<br />

Those who are attending field trips must turn in field trip passes prior to bus departure. Please check in<br />

at the Foyer of the California Ball Room at least 30 minutes prior to departure.<br />

Field Trip Option A:<br />

MICROFILTRATION AT THE ORANGE COUNTY WATER DISTRICT<br />

The Groundwater Replenishment System Phase One plant is a 5-million gallon per day (mgd)<br />

advanced water treatment facility that contains three major processes: microfiltration, reverse<br />

osmosis, and advanced oxidation. The microfiltration<br />

process consists of a 6-mgd USFilter<br />

CMF-S submersible system. This process is a<br />

smaller-scale version of the 86-mgd microfiltration<br />

facility currently under construction at<br />

the same site. Driving time from the hotel to<br />

the Orange County <strong>Water</strong> District in<br />

Fountain Valley, California, is approximately<br />

20 minutes.<br />

Field Trip Option B:<br />

MEMBRANE BIOREACTOR AT THE CORONA DEPARTMENT OF WATER AND POWER<br />

Wastewater Treatment Plant 3 at the Corona Department of <strong>Water</strong> and Power was<br />

commissioned in 2001 to treat 1.1-mgd raw wastewater to Title 22 standards for recycling<br />

purposes. Currently, about 0.4 mgd of recycled water is<br />

produced, which is used to irrigate a nearby golf course<br />

and will soon irrigate surrounding schools and parks.<br />

The foundation for Plant 3 is the ZenoGem Process, a<br />

technology designed by Zenon that consists of a<br />

suspended growth biological reactor integrated with a<br />

microfiltration membrane system. Driving time from<br />

the hotel to the Corona Department of <strong>Water</strong> and Power<br />

in Corona, California, is approximately 35 minutes.<br />

Photos courtesy of the Orange County <strong>Water</strong> District,<br />

and the Corona Department of <strong>Water</strong> and Power<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

ix


<strong>Abstracts</strong><br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

xi


xii


Session 1: Introduction<br />

<strong>Membrane</strong> <strong>Bioreactors</strong> and<br />

the Future of Wastewater Treatment<br />

R. RHODES TRUSSELL, PH.D., P.E., DEE<br />

Trussell Technologies, Inc.<br />

Pasadena, California<br />

Adecade ago, membrane bioreactors (MBRs) weren’t even on our radar screen. Today,<br />

MBRs are the process of choice for small-scale reuse projects with demands for high<br />

water quality. Projects are popping up everywhere. Soon, MBRs will change the way we think<br />

about treatment for reuse, opening a new era of decentralized treatment. In the very longterm,<br />

just as membrane filtration will replace granular media filtration, MBRs will replace<br />

conventional biological processes that depend on gravity sedimentation or granular media<br />

filtration for solids separation.<br />

What is the appeal of the MBR? What are some of the limits of the process? How is our<br />

thinking about MBRs changing, and how will it change in the future? What problems must<br />

we solve for MBRs to reach their full potential? What can MBRs do to help us meet future<br />

regulations?<br />

The most obvious appeal of the MBR is that it produces an excellent effluent quality. The<br />

compactness of the MBR is another important element in its appeal. Finally, the MBR has<br />

great potential for automation. Important to both the design engineer and operator, the MBR<br />

eliminates the need for good sludge settleability as a central requirement. Effluent quality is<br />

less sensitive to operations, and precise control of the sludge residence time (SRT)/mixed<br />

liquor suspended solids (MLSS)/food to microorganisms (F:M) ratio is not as important.<br />

Finally, the MBR puts much greater distance between reclamation and the risk of microbial<br />

disease. Pathogens are not just reduced by a highly selective chemical or photochemical<br />

reaction, they are rejected by size exclusion. The MBR also makes longer SRTs feasible in a<br />

compact space, resulting in less biomass to waste, the removal of a broader variety of resistant<br />

compounds, and a more biostable effluent with a lower oxidant demand. Finally, the MBR<br />

produces an effluent that is immediately suitable for reverse osmosis treatment, should that be<br />

a requirement.<br />

In today’s world, there are two kinds of issues that we face in making decision about the<br />

deployment of MBRs:<br />

Type I Issues — Issues that must be resolved to improve reliability, cost, and/or<br />

performance.<br />

Type II Issues — Issues that are inherent to the process and must be understood by<br />

designers and operators of successful MBR projects.<br />

Correspondence should be addressed to:<br />

R. Rhodes Trussell, Ph.D., P.E., DEE<br />

President<br />

Trussell Technologies, Inc.<br />

232 North Lake Avenue, Suite 300<br />

Pasadena, CA 91101-1862 USA<br />

Phone: (626) 486-0560 • Email: rhodes.trussell@trusselltech.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

1


Examples of Type I issues are: (a) understanding the upper limits of the MLSS that the<br />

process can handle and how the reactor configuration affects this, (b) understanding the lower<br />

limits of SRT and hydraulic residence time (HRT), (c) the optimization of air scouring and<br />

energy consumption, (d) membrane cleaning, (e) design and operational practices that will<br />

extend membrane life, and (f) designing and operating the MBR process to optimize sludge<br />

filterability.<br />

Examples of Type II issues are the design and operation requirements imposed by the impact<br />

that fouling can have on hydraulic performance, by MBR’s limited ability to handle peaking,<br />

and on MBRs by reduced oxygen transfer at high MLSS.<br />

To date, most MBR installations have been small enough that it has basically been possible to<br />

ignore the biology. This will not do in the future. The future belongs to those who take full<br />

advantage of all that we have learned about the behavior of this complex biological system and<br />

integrate it with the unique capabilities and limitations of MBRs. Some examples of problems<br />

that must be addressed include:<br />

• The management of organisms associated with foaming.<br />

• The management of the biological system to produce a sludge that is easily<br />

filtered and dewatered.<br />

• The full integration of what we know about nutrient removal with the MBR<br />

process.<br />

In the meantime, there are places where MBR is attractive today, even for the conservative<br />

engineer. MBR is most appealing when its small footprint, ease of automation, and excellent<br />

effluent quality are all requirements. It is also most appealing when flow peaking can be<br />

easily addressed. Reuse projects that scalp the flow from nearby sewers are one of the more<br />

obvious examples. Moreover, MBR has the potential to rearrange our thinking about reuse.<br />

There are limits to the idea of pumping treated wastewater up into and throughout a<br />

community in purple pipe. MBR creates the potential for decentralized reuse systems with<br />

treatment systems located closer to the point of application and smaller, less-intrusive purple<br />

infrastructure.<br />

R. RHODES TRUSSELL, Ph.D., P.E., DEE, is recognized worldwide as an authority<br />

in methods and criteria for water quality and in the development of advanced<br />

processes for treating water or wastewater to achieve the highest standards. A Civil<br />

and Corrosion Engineer with 35 years of experience, he has worked on the process<br />

design for dozens of treatment plants ranging in size from 1 to 900 million gallons per<br />

day in capacity. At present, he is President of Trussell Technologies, Inc., an<br />

environmental engineering firm that focuses on the quality and treatment of water<br />

and wastewater. He is also active on numerous boards and committees, such as<br />

serving as Chair of the <strong>Water</strong> Science and Technology Board for the <strong>National</strong> Academies. Just recently,<br />

he retired from the U.S. Environmental Protection Agency’s Science Advisory Board after 17 years of<br />

service. Trussell received a B.S. in Civil Engineering and both an M.S. and Ph.D. in Sanitary<br />

Engineering from the University of California, Berkeley.<br />

2


Session 1: Introduction<br />

Biological Process Principles<br />

GEORGE TCHOBANOGLOUS, PH.D., P.E.<br />

University of California, Davis<br />

Davis, California<br />

With proper analysis and environmental control, almost all wastewaters containing<br />

biodegradable constituents can be treated biologically. Therefore, it is essential that the<br />

environmental engineer understand the characteristics of each biological process to ensure<br />

that the proper environment is produced and controlled effectively. The overall objectives of<br />

the biological treatment of domestic wastewater are to:<br />

• Transform (i.e., oxidize) dissolved and particulate biodegradable constituents into<br />

acceptable end-products.<br />

• Capture and incorporate suspended and nonsettleable colloidal solids into a biological<br />

floc or biofilm.<br />

• Transform or remove nutrients, such as nitrogen and phosphorus.<br />

• More recently, to remove specific trace constituents and compounds.<br />

For industrial wastewater, the objective is to remove or reduce the concentration of organic<br />

and inorganic compounds. Because some of the constituents and compounds found in<br />

industrial wastewater are toxic to microorganisms, pretreatment may be required before<br />

industrial wastewater can be discharged to a municipal collection system. For agricultural<br />

irrigation runoff, the objective is to remove nutrients (specifically nitrogen and phosphorus),<br />

pesticides, and trace constituents that are capable of affecting the aquatic environment.<br />

The principal biological processes used for wastewater treatment can be divided into three<br />

main categories: suspended growth, attached growth (or biofilm), and combined suspended and<br />

attached growth processes. The successful design and operation of the biological processes<br />

requires an understanding of the:<br />

• Types of microorganisms involved.<br />

• Specific reactions that they perform.<br />

• Environmental factors that affect their performance.<br />

• Nutritional needs of microorganisms.<br />

• Microorganism reaction kinetics.<br />

These subjects are reviewed in light of process developments that have occurred over the past<br />

century.<br />

Correspondence should be addressed to:<br />

George Tchobanoglous, Ph.D., P.E.<br />

Professor Emeritus of Civil and Environmental Engineering<br />

University of California, Davis<br />

662 Diego Place<br />

Davis, CA 95616 USA<br />

Phone: (530) 756-5747 • Email: gtchobanoglous@ucdavis.edu<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

3


4<br />

For over 35 years, wastewater expert GEORGE TCHOBANOGLOUS, PH.D., P.E.,<br />

has taught courses on water and wastewater treatment and solid waste management<br />

at the University of California, Davis, where he is Professor Emeritus in the Department<br />

of Civil and Environmental Engineering. He has authored or coauthored over<br />

350 publications, including 13 textbooks and five engineering reference books.<br />

Tchobanoglous has been past President of the Association of Environmental<br />

Engineering and Science Professors and currently serves as a national and international<br />

consultant to both government agencies and private concerns. Among his<br />

honors, he received the Athalie Richardson Irvine Clarke Prize from the <strong>National</strong> <strong>Water</strong> Research<br />

Institute in 2003 and was inducted to the <strong>National</strong> Academy of Engineers in 2004. In 2005, he<br />

received an Honorary Doctor of Engineering degree from the Colorado School of Mines.<br />

Tchobanoglous received a B.S. in Civil Engineering from the University of the Pacific, an M.S. in<br />

Sanitary Engineering from the University of California, Berkeley, and a Ph.D. in Environmental<br />

Engineering from Stanford University.


Session 2: Fundamentals and Applications<br />

<strong>Membrane</strong> Bioreactor Process Fundamentals<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Introduction<br />

The use of microfiltration (MF) or ultrafiltration (UF) membranes in biological wastewater<br />

treatment has been well documented and extensively reviewed. <strong>Membrane</strong> filtration<br />

produces a high-quality, clarified, and disinfected permeate product. It also permits absolute<br />

control of solids retention time (SRT) and, thus, correspondingly, control of the mixed liquor<br />

suspended solids (MLSS) concentration. This both reduces the required reactor size and<br />

promotes the development of specific nitrifying bacteria, thereby enhancing ammonia removal,<br />

as well as producing less sludge.<br />

However, as with almost all other membrane processes, the production rate of membrane<br />

bioreactors (MBRs) is ultimately limited by membrane fouling. Fouling arises from the<br />

accumulation of solute, colloidal, and particulate species on or within the membrane, leading<br />

to a deterioration in membrane permeability. This phenomenon has led to the development<br />

of the low-fouling submerged configuration, first introduced 15 years ago, as opposed to<br />

sidestream systems, wherein the membrane is immersed in the bioreactor rather than fitted<br />

external to it (Figure 1). Submerged systems tend to allow greater hydraulic efficiencies,<br />

reflected in greater permeabilities, due to their operation at substantially lower fluxes than<br />

sidestream systems (Table 1), since fouling tends to increase with increasing flux.<br />

Out<br />

(membrane fouling)<br />

Feed<br />

(Screens)<br />

Bioreactor<br />

(Activity + Nature)<br />

Air<br />

(Energy)<br />

Sludge Waste<br />

(Quantity and Quality)<br />

Figure 1.<br />

Elements of a membrane bioreactor.<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

5


Table 1. Summary of <strong>Membrane</strong> Bioreactor Process Conditions for Sewage Treatment<br />

Mitsubushi<br />

Orelis or<br />

Parameter Kubota Rayon Zenon Wehrle<br />

<strong>Membrane</strong> Geometry FS HF HF MT<br />

Process Configuration Submerged Submerged Submerged Side-stream<br />

Mean Air Velocity (m/s) 0.05 0.03 0.1 –<br />

Mean Liquid Velocity (m/s) 0.5* – – 1-3<br />

TMP (bar) 0.05-0.15 0.1-0.5 0.1-0.5 2-5<br />

Flux (LMH) ~25 ~15 ~25 70-100<br />

FS = Flat sheet. HF = Hollow fiber. MT = Multitube. LMH = Liters per cubic meter per hour.<br />

TMP= Transmembrane pressure. m/s = Meters per second. *As quoted by supplier.<br />

Fouling<br />

Fouling is a particularly acute problem in the case of MBRs, since the membrane is challenged<br />

with highly contaminated liquors having total solids concentrations of 20 grams per liter (g/L) or<br />

more arising from concentrated biomass. A second limitation, clogging – which refers to the<br />

filling of the membrane interstices with solids – is generally of less significance, but must still<br />

be suppressed for successful operation. There are a number of elements of a submerged MBR<br />

system (see Figure 1), all contributing to varying degrees of fouling and clogging, and their<br />

interrelationship is complex (Figure 2).<br />

In considering fouling and its causes and implications, the various elements of the system<br />

(see Figure 1) can be discussed in turn. Firstly, there are the feed characteristics. Various<br />

biochemical transformations in the bioreactor convert the organic matter in the feed into largely<br />

EPS<br />

• Free<br />

• Bound<br />

Feed Characteristics<br />

Biomass Characteristics<br />

Floc Characteristics<br />

• Size<br />

• Structure<br />

Bulk Characteristics<br />

• Viscosity/Rheology<br />

• Hydrophobicity<br />

Operation<br />

Retention Time<br />

• Hydraulic<br />

• Solids<br />

Hydraulics<br />

• Flux<br />

• TMP<br />

Reversible<br />

Fouling<br />

Irreversible<br />

Clogging<br />

<strong>Membrane</strong><br />

Channels<br />

Aerator<br />

Ports<br />

Cleaning<br />

• Physical<br />

• Chemical<br />

<strong>Membrane</strong> Module Characteristics<br />

Pore<br />

• Size<br />

• Shape<br />

Surface Characteristics<br />

• Porosity<br />

• Charge/Hydrophobicity<br />

Configuration<br />

• Geometry<br />

• Dimensions<br />

Aeration<br />

• Design (Port Size)<br />

• Mean Flow Rate<br />

• Pulse Rate<br />

Figure 2. Inter-relationships between membrane bioreactor parameters and fouling.<br />

6


mineralized products, principally carbon dioxide and nitrate. In doing so, a variety of materials<br />

are released from the biomass in the reactor, which are collectively referred to as extracellular<br />

polymeric substances (EPS) and which contain a number of components that can foul the<br />

membrane to various extents. The relative and overall concentrations of the various components<br />

are determined both by feed characteristics and operational facets of the system and, in<br />

particular, by microbial speciation. Other foulants originate directly from unbiodegraded<br />

components of the feedwater, particularly for feeds of low biodegrability.<br />

Secondly, there is the actual process design and configuration of the MBR process, which in<br />

turn affects the key operator parameter values chosen. Submerged MBRs operate at lower<br />

fluxes and, as a result, lower transmembrane pressure (TMP) values (and so permeabilities)<br />

than the sidestream configuration. Therefore, they are inherently higher in energy efficiency,<br />

manifested as the specific energy demand in kilowatt-hour per cubic meter (kWh/m 3 )<br />

permeate product. The configuration of the membrane module — principally, the membrane<br />

element geometry (planar or cylindrical), material physical properties (pore size, tortuosity,<br />

hydrophobicity, and surface porosity), and chemistry (polymeric or ceramic) — can also<br />

influence fouling. Although there are now a number of proprietary MBR technologies in the<br />

marketplace, the majority of them are based either on a flat sheet (FS) membrane<br />

configuration or on hollow fibers (HF).<br />

Thirdly, the operation of the MBR can profoundly impact fouling. There are two components<br />

of MBR operation: the membrane and the bioreactor. The bioreactor component (as with a<br />

conventional activated sludge process) is controlled by the relative values of the retention of<br />

solids and liquid (i.e., the solids [SRT] and hydraulic [HRT] retention times). Increasing the<br />

SRT and decreasing the HRT leads to higher levels of suspended solids (usually referred to as<br />

mixed liquor suspended solids [MLSS]) in the bioreactor, which increases the risk of clogging<br />

in both the membrane interstices and aerator ports. However, the impact of retention times<br />

on fouling is normally not significant in sewage treatment provided the MLSS is kept within a<br />

range of values in which fouling and foaming are suppressed (which tends to prevail at low<br />

MLSS values of around 4 to 6 g/L) and clogging is avoided by operating below a threshold<br />

MLSS value (which depends largely upon the membrane configuration). The main<br />

determinants for fouling control, however, relate directly to the membrane itself.<br />

Fouling Control<br />

In submerged MBRs, generally only three strategies are available for limiting fouling with<br />

regards to operation: reducing the flux, increasing aeration, or employing physical or chemical<br />

cleaning. Coarse bubble aeration produces scouring action at the surface of the membrane,<br />

which limits the build-up of foulant material. Lowering the flux reduces the rate at which<br />

foulants arrive at the membrane. However, both these modifications have cost implications,<br />

since a reduced flux implies a greater membrane area requirement and energy demand<br />

increases roughly linearly with increasing air flow rate. Cleaning demands downtime, and<br />

more rigorous cleaning using chemicals exerts chemical demand and produces chemical waste.<br />

A good operation of submerged MBR systems is based on obtaining the appropriate balance<br />

between operational flux, aeration, and cleaning. It follows that good MBR design is associated<br />

with maximizing the impact of aeration (in terms of reducing fouling) and facilitating<br />

cleaning with minimal downtime and chemicals consumption, as well as providing a high<br />

membrane area at low cost so as to permit a low flux.<br />

The constraints imposed by the challenging environment in which the membranes operate<br />

have meant that the municipal wastewater treatment MBR market is dominated by just two<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

7


designs: the HF membrane-based product (Zenon) and the FS (Kubota). Much debate exists<br />

as to the relative merits offered by these two designs. The flat plate configuration tends to run<br />

at slightly higher permeabilities (flux per unit TMP) and is simpler in operation. On the other<br />

hand, unlike the HF, it cannot be backflushed. Both systems appear to maintain reasonable<br />

fluxes by applying relaxation – intermittent physical cleaning attained simply by closing the<br />

permeate valve and allowing air to scour the membrane surface. Both Kubota and Zenon have<br />

also recently developed design modifications for increasing efficiency. In the case of Kubota,<br />

this is achieved by stacking the membrane modules (already employed by Mitsubishi Rayon in<br />

its MBRs based on its Sterapore HF membrane). Zenon has introduced intermittent aeration,<br />

which effectively halves the specific energy demand associated with aeration, the main<br />

operating cost component.<br />

Technologies<br />

There are an increasing number of commercial MBR technologies, many of which are listed in<br />

Tables 2 and 3. It appears that almost all immersed MBRs are either rectangular FS or HF,<br />

and that most sidestream MBR technologies are multi-tubes (MT). The exceptions to these<br />

general observations appear to be:<br />

a. The Orelis Pleaide FS membrane used for sidestream treatment.<br />

b. The Polymem and Ultraflo sidestream HF systems.<br />

c. The hexagonal/octagonal rotating immersed Huber FS membrane.<br />

d) The Millenniumpore MT membrane, which has been used as an immersed module,<br />

as well as for air-lift sidestream.<br />

Table 2. Commercial Technologies<br />

Process Configuration<br />

Immersed<br />

Sidestream<br />

FS Colloide Novasep-Orelis<br />

Brightwater<br />

Huber*<br />

ITRI NWF<br />

Kubota<br />

Microdyn Nadir<br />

Toray<br />

<strong>Membrane</strong><br />

Configuration<br />

HF Asahi-kasie Polymem<br />

Han-S Environmental<br />

Ultraflo<br />

ITT<br />

Koch/Puron<br />

Kolon<br />

Mitsubishi Rayon<br />

Motimo<br />

Siemens/USF-Memcor<br />

Zenon<br />

MT Millenniumpore Berghof**<br />

Millenniumpore<br />

Norit-Xflow**<br />

*Rotating membrane.<br />

**MT membrane products used by process suppliers such as Aquabio, Dynatec, Triqua, and Wehrle.<br />

8


Table 3. Commercial <strong>Membrane</strong> Product Specifications<br />

<strong>Membrane</strong> Pore Specific Propietary Name,<br />

Supplier (Configuration, Size Surface <strong>Membrane</strong>,<br />

Material) (µm) Area (m -1 ) or Module<br />

Berghof MT, PES 0.08 110 HyPerm-AE<br />

or PVDF 0.12 Hyperflux<br />

Brightwater FS, PES 0.08 110 Membright<br />

Toray FS, PVDF 0.08 130 Toray<br />

Kubota FS, PE 0.4 150 Kubota<br />

Colloide FS, PES 0.04 160 Sub Snake<br />

Huber FS, PES 0.038 160 VRM<br />

Millenniumpore MT, PES 0.1 180 Millenniumpore<br />

Koch HF, PES 0.05 260 Puron<br />

Zenon HF, PVDF 0.04 300 ZW500C-D<br />

Norit-Stork MT, PVDF 0.038 320 F4385<br />

290 F5385<br />

Mitsubishi Rayon HF, PE 0.4 425 SUR<br />

HF, PVDF 0.4 333 SADF<br />

USF-Memcor HF, PVDF 0.04 600-700 B10R, B30R<br />

Asahi-kasie HF, PVDF 0.1 710 Microza<br />

Polymem HF, PS 0.08 800 WW120<br />

Motimo HF, PVDF 0.1-0.2 1100 Flat Plat<br />

Moreover, almost all HF MBR membrane products currently on the market are verticallymounted<br />

and polyvinylidene difluoride (PVDF)-based, the exceptions being the Koch-Puron<br />

membrane (which is polyethersulphone [PES]), the Polymem polysulfone (PS) membrane,<br />

and the Mitsubishi Rayon SUR module (which is polyethylene [PE] material and also<br />

horizontally oriented). All HF products are in the coarse UF/tight MF region of selectivity,<br />

having pore sizes predominantly between 0.03 and 0.4 micrometers (µm), and all such<br />

vertically-mounted systems are between 0.7 and 2.5 millimeters (mm) in external diameter.<br />

Distinctions in HF MBR systems can be found mainly in the use of membrane reinforcement<br />

(essential for those HF elements designed to provide significant lateral movement) and,<br />

perhaps most crucially, the air-to-membrane contact.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

9


10<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.


Session 2: Fundamentals and Applications<br />

Commercially Available<br />

<strong>Membrane</strong> Bioreactor Systems<br />

JAMES F. DECAROLIS<br />

MWH<br />

San Diego, California<br />

ZAKIR HIRANI<br />

MWH<br />

San Diego, California<br />

SAMER S. ADHAM, PH.D.<br />

MWH<br />

Pasadena, California<br />

NEIL TRAN, P.E.<br />

City of San Diego<br />

San Diego, California<br />

STEVE LAGOS<br />

City of San Diego<br />

San Diego, California<br />

Introduction<br />

The following paper provides a detailed description of four commercially available<br />

membrane bioreactor (MBR) systems currently established in the municipal wastewater<br />

treatment/water reclamation market in the United States. These systems are supplied by<br />

Zenon Environmental, Inc., USFilter, Ionics/Mitsubishi Rayon Corporation, and Enviroquip, Inc./<br />

Kubota Corporation. Each of these suppliers has full-scale MBRs currently operating in the<br />

United States, and their systems are approved by the California Department of Health<br />

Services (CDHS) to meet Title 22 water recycling criteria. Details of each system are based<br />

on knowledge gained during hands-on pilot testing performed by the project team along with<br />

information provided by the manufacturers. The paper will also describe four newly developed<br />

MBR systems currently entering the United States market. These suppliers include Koch<br />

<strong>Membrane</strong> Systems (KMS), Kruger, Parkson Corporation, and Huber, Inc. The project team<br />

is currently evaluating the ability of these new technologies to meet Title 22 recycling criteria<br />

under grant funding provided by the United States Department of Interior, Bureau of<br />

Correspondence should be addressed to:<br />

James F. DeCarolis<br />

MWH Americas, Inc.<br />

Aqua 2030 Research Center<br />

North City <strong>Water</strong> Reclamation Plant<br />

4949 Eastgate Mall<br />

San Diego, CA 92121 USA<br />

Phone: (858) 824-6067 • Email: jdecarolis@sandiego.gov<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

11


Reclamation. Lastly, the paper discusses MBR pilot-testing considerations based on nearly a<br />

decade of MBR research performed by the project team at the Aqua 2030 Research Center<br />

located in San Diego, California.<br />

Commercially Available <strong>Membrane</strong> Bioreactor Systems<br />

(Established in the United States)<br />

Zenon <strong>Membrane</strong> Bioreactor System<br />

The Zenon MBR system uses polyvinylidene fluoride (PVDF) ultrafiltration (UF) reinforced<br />

hollow fiber membranes (nominal pore size = 0.04 micron [µm]). Individual membrane<br />

elements are configured into membrane cassettes that are typically submerged directly into a<br />

designated membrane tank in direct contact with mixed liquor suspended solids (MLSS). The<br />

commercial designation of the membrane module currently used in the Zenon MBR system is<br />

ZW 500d, which has superseded previous generation modules offered by Zenon, including the<br />

ZW 500a and ZW 500c. Benefits of the<br />

ZW 500d configuration over its predecessors<br />

include a higher membrane packing density<br />

and lower air scouring requirements (Benedek<br />

and Cote, 2003). A photograph of a ZW 500d<br />

cassette is provided in Figure 1. Each cassette<br />

used in full-scale applications is typically<br />

designed to contain up to 48 individual<br />

membrane elements. Coarse bubble air is<br />

introduced from the bottom of the cassette to<br />

scour the surface of the membranes. This<br />

prevents solids from accumulating on the<br />

membrane surface, which could result in<br />

increased transmembrane pressure (TMP). A<br />

unique feature of the Zenon MBR system is<br />

the intermittent application of membrane air<br />

scour, which reduces energy consumption<br />

Figure 1. Photograph of Zenon 500d membrane<br />

cassette (Zenon, 2005).<br />

USFilter <strong>Membrane</strong> Bioreactor System<br />

The USFilter MBR system utilizes microfiltration (MF) hollow fiber PVDF membranes<br />

(nominal pore size of 0.08 µm) that are submerged in a separate membrane tank. The<br />

commercial designation of the original membranes used in USFilter’s MBR systems is B10R.<br />

Though still used in MBR package plants (


A unique feature of the USFilter MBR system is that it incorporates MemJet technology,<br />

which includes the injection of both air and mixed liquor at the bottom of the membrane<br />

modules. This operation causes the membranes to be scoured and fluidized and prevents<br />

particulate matter from accumulating on the membrane surface.<br />

Ionics/Mitsubishi Rayon <strong>Membrane</strong> Bioreactor System<br />

The Ionics/Mitsubishi Rayon MBR system uses<br />

polyethylene MF hollow fiber membranes (nominal<br />

pore size of 0.4 µm) that are submerged directly<br />

in an aeration basin. The commercial designation<br />

for the membranes is Sterapore HF. Though<br />

classified as MF, the membranes are characterized<br />

with a tight pore size distribution (absolute pore<br />

size= 0.5 µm). As shown in Figure 3, each<br />

membrane cassette contains individual hollow<br />

fibers membranes configured horizontally to make<br />

up an element. Each membrane cassette contains<br />

50 of the 1-square meter (m 2 ) Mitsubishi<br />

Sterapore HF MF membranes, for a total<br />

membrane area of 100 m 2 (1,076 ft 2 ). Air is<br />

supplied at the bottom of the tank for scour and Figure 3. Mitsubishi Sterapore HF membrane<br />

cassette.<br />

biological process. During filtration, vacuum<br />

pressure is applied, causing water to permeate through the membrane from the top and bottom.<br />

Kubota <strong>Membrane</strong> Bioreactor System<br />

The Kubota MBR system contains flat sheet, chlorinated polyethylene MF membranes (nominal<br />

pore = 0.4 µm) that are submerged directly in an aeration basin. The commercial designation<br />

of the flat sheet membrane cartridge is Type 510. Each cartridge is 1 m (H) x 0.49 m (W) x<br />

6 millimeters (mm) thick, and contains a membrane surface area of 0.8 m 2 . A photograph of<br />

the Type 510 membrane cartridge is provided in<br />

Figure 4. Each cartridge contains a support<br />

plate, spacer, permeate nozzle, and membrane<br />

layer on each side. Recently (2005), Kubota<br />

introduced a Type 515 membrane cartridge<br />

primarily for applications of 2 mgd or greater.<br />

The Type 515 cartridges are larger in dimension<br />

than Type 510 cartridges, resulting in increased<br />

membrane area per cassette. The Type 510<br />

cassette contains up to 150 individual cartridges<br />

(spaced 7 mm apart) and is equipped with a<br />

permeate manifold. During filtration, permeate<br />

water flows out of the cartridges through the<br />

permeate nozzle and into collection tubes that<br />

Figure 4. Kubota Type 510 membrane cassette.<br />

feed into the permeate manifold. A unique<br />

feature of the Kubota MBR system is that can be designed as a single or double deck (DD)<br />

configuration. The DD systems contain both upper and lower membrane cassettes. The<br />

lower cassettes are equipped with a coarse air bubble diffuser and provide structural support<br />

to the upper casts. This DD configuration offers several benefits (van der Roest et al, 2002),<br />

including the reduction of 1) the membrane footprint, 2) the biological volume consumed by<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

13


the membrane system, and 3) air consumption used for membrane cleaning. The DD also<br />

yields a more controllable biological process and reduces the possibility of short circuiting.<br />

Newly Developed <strong>Membrane</strong> Bioreactor Systems<br />

Koch <strong>Membrane</strong> Systems <strong>Membrane</strong> Bioreactor System<br />

The KMS membrane bioreactor uses PURON ® hollow fiber UF membranes (nominal pore<br />

size = 0.05 µm) that are made of polyethersulfone (PES) and casted onto a braided support.<br />

The hollow fiber membranes are configured in bundles to form membrane modules and are<br />

submerged in a designated membrane tank. A unique feature of the KMS MBR is that each<br />

membrane is sealed at the top and potted only at the lower end. This design allows the nonpotted<br />

ends to move freely in the MLSS, which eliminates the possibility of clogging. An air<br />

nozzle is located in the center of each bundle to provide membrane air scour. A standard<br />

module contains nine membrane bundles for a total membrane area of 30 m 2 . The PURON<br />

hollow fiber module is shown in Figure 5.<br />

Figure 5. PURON membrane module (Koch <strong>Membrane</strong> Systems, 2005).<br />

Huber <strong>Membrane</strong> Bioreactor System<br />

The Huber MBR system uses flat sheet UF membranes (nominal pore size= 0.038 µm)<br />

submerged in a designated membrane tank. A unique feature of the Huber MBR system is<br />

that the membranes are supported on a Vacuum Rotation <strong>Membrane</strong> (VRM ® ) unit, which<br />

consists of individual rotating VRM plate membranes installed around a stationary hollow<br />

shaft. Two centrally arranged air tubes<br />

introduce scouring air into the interspaces<br />

between the plates. Permeate<br />

is drawn from the each plate via<br />

permeate tubes that collect permeate<br />

to a common pipe. These horizontal<br />

pipes meet at a center manifold, from<br />

which the permeate exits the system.<br />

The constant rotation (1.8 revolutions<br />

per minute [RPM]) of the VRM unit<br />

allows the membrane plates to be air<br />

scoured alternatively by just two<br />

centrally placed air tubes, thereby Figure 6. Huber VRM unit (plan view).<br />

14


educing the scouring air requirements. Energy efficiency is maintained by using only a<br />

2−horsepower motor for the rotation of the VRM.<br />

The VRM membranes are configured in plates (3-m 2 filter surface area per plate) that contain<br />

permeate channels, spacers, and permeate discharge nozzles. A VRM module is comprised of<br />

four such plates; modules (when arranged circularly) form a membrane element. Huber MBR<br />

membrane elements are offered in two sizes: VRM 20 (containing six modules) and VRM 30<br />

(containing eight modules). Standard VRM 20 systems are designed with a minimum of 10<br />

and maximum of 50 elements, while standard VRM 30 systems are designed with a minimum<br />

of 20 and maximum of 60 elements. A photograph of a VRM 20 unit mounted on the VRM<br />

drive is provided in Figure 6.<br />

Kruger <strong>Membrane</strong> Bioreactor System<br />

Kruger MBR system uses flat-sheet PVDF UF<br />

membranes (nominal pore size of 0.08 µm)<br />

submerged in a designated membrane tank.<br />

<strong>Membrane</strong>s are supported on a polyolefin nonwoven<br />

material and Acrylonitrile Butadiene<br />

Styrene (ABS) plate. Each module contains<br />

100 flat-sheet membrane elements, with a total<br />

membrane area of 1,500 ft 2 . A photograph of the<br />

flat sheet module is provided in Figure 7. A<br />

unique feature of the Kruger MBR system is that<br />

the membrane is characterized with a tight pore<br />

size distribution (0.03 µm), allowing the fluid to<br />

Figure 7. Flat sheet module (Kruger, 2005).<br />

be equally distributed along the membrane surface<br />

during filtration (Kruger, 2005). It also allows the cleaning chemicals to be evenly distributed<br />

during maintenance cleaning, making cleaning more effective.<br />

Parkson Dynalift <strong>Membrane</strong> Bioreactor System<br />

The Parkson Dynalift MBR contains X-Flow ® PVDF tubular<br />

UF membranes with a nominal pore size of 0.03 µm. A unique<br />

feature of the Parkson MBR system is that the membranes are<br />

configured in modules and are external to the biological process.<br />

These tubular membranes provide a wide-channel, non-clogging<br />

design and, according to the manufacturer, can be operated at<br />

high MLSS levels of up to 15,000 milligrams per liter (mg/L).<br />

To eliminate high pumping energies, membranes are placed in a<br />

vertical orientation and MLSS is kept suspended inside the<br />

module using air-lift assisted cross-flow pumping. A photograph<br />

of the X-Flow membranes is provided in Figure 8.<br />

Aqua 2030 <strong>Membrane</strong> Bioreactor Research Program<br />

Figure 8. Parkson Corporation’s<br />

X-Flow membrane<br />

(Parkson, 2005)<br />

For nearly a decade, MWH and the City of San Diego in California have been researching<br />

MBR technology and its application for water reuse at the Aqua 2030 Research Center.<br />

The majority of this research was made possible under funding provided by the United States<br />

Department of Interior, Bureau of Reclamation, and was conducted in multiple phases from<br />

1997 to the present. Phase I (Adham and Gagliardo, 1998) included an extensive literature<br />

search on MBR technology and identified major MBR suppliers in the field. In addition, the<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

15


project team implemented a worldwide survey of full-scale MBR applications for domestic<br />

wastewater treatment and developed rough cost estimates for the technology. Information<br />

gathered during the survey included operational characteristics such as capacity, MLSS<br />

concentrations, food-to-microorganism ratio, permeate flux, solids retention time (SRT), and<br />

hydraulic retention time (HRT), along with performance in terms of particulate, organic,<br />

nutrient, and microbial contaminant removal.<br />

Phase II testing (Adham et al., 2000) included the operation and evaluation of two pilot-scale<br />

MBRs (Zenon and Mitsubishi) over a 1-year period. The purpose of testing was to evaluate<br />

the performance of these systems during the treatment of municipal wastewater and to<br />

establish baseline operating conditions. Towards the end of the pilot-testing period, the<br />

project team worked with CDHS to establish criteria for MBR systems to gain Title 22<br />

approval. Based on these criteria, further testing of the Zenon and Mitsubishi systems was<br />

done in 2001 under funding provided by the <strong>National</strong> <strong>Water</strong> Research Institute (Adham et al.,<br />

2001a and 2001b). Results from this testing, along with those acquired during the<br />

1-year operating period, were submitted to CDHS in September 2001. <strong>Short</strong>ly after, the two<br />

systems were granted conditional approval to meet Title 22 water recycling criteria.<br />

In June 2002, the project team embarked on Phase III (Adham and DeCarolis, 2004), which<br />

included the evaluation of four MBR pilot units (USFilter Corporation/Jet Tech Products Group;<br />

Zenon Environmental, Inc.; Ionics/Mitsubishi Rayon Corporation; and Enviroquip Inc./<br />

Kubota Corporation). Pilot testing of these systems was conducted over a 16-month period on<br />

raw and advanced primary effluent to evaluate MBR performance and to determine the<br />

suitability of MBR effluent as a feed to reverse osmosis units. Data generated during this<br />

study demonstrated the ability of the Kubota and USFilter MBR systems to meet Title 22<br />

<strong>Water</strong> Recycling Criteria, and both were granted approval in 2002/2003 (California<br />

Department of Health Services, 2005). In addition, it was shown that MBR systems could<br />

successfully operate on advanced primary treated wastewater containing coagulant and<br />

polymer residual.<br />

Recently, the project team has begun Phase IV (U.S. Department of Interior, Bureau of<br />

Reclamation, 2005) of the MBR program. The purpose of this ongoing project is to evaluate<br />

four newly developed MBR systems entering the municipal wastewater market in the United<br />

States. These include systems from Koch <strong>Membrane</strong> Systems (Wilmington, Massachusetts),<br />

Parkson Corporation (Fort Lauderdale, Florida), Huber Technology, Inc. (Huntersville, North<br />

Carolina), and Kruger (Cary, North Carolina). Each of these systems has been designed with<br />

innovative features aimed to optimize operational performance and efficiency. As part of<br />

testing, each system will be evaluated to meet Title 22 requirements, which (upon approval)<br />

would double the number of approved systems available to the water reclamation industry.<br />

Based on the research program described above, the project team has identified several<br />

important factors to consider when pilot testing MBR systems for water reuse applications.<br />

These include:<br />

• <strong>Water</strong> Quality Goals (total nitrogen, phosphorus, establish a water quality sampling plan).<br />

• Selecting a Supplier(s) (system configuration, customer support, suppliers experience,<br />

capacity of full-scale potential plant, pilot rental fee).<br />

• Pilot Site (access to raw wastewater [20- to 40 gallons per minute]), access to sewer to<br />

dispose of waste, potable water supply for cleaning, adequate power supply available).<br />

16


• MBR Operating Conditions (flux, HRT, SRT, membrane cleaning frequency [maintenance<br />

and recovery cleans], backwash/relax frequency, recirculation rate for denitrification).<br />

• Special Considerations (pretreatment, operator requirements, duration of testing, post<br />

treatment requirements, operation and maintenance requirements, biological tank mixing<br />

requirements, redundancy and location of feed pumps, wasting, foaming control).<br />

Additional information regarding these considerations will be provided during the conference<br />

presentation.<br />

References<br />

Adham, S., and P. Gagliardo (1998). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Repurification – Phase I. Desalination<br />

Research and Development Program Report No. 34, Project No. 1425-97-FC-81-30006J, United States<br />

Department of Interior, Bureau of Reclamation.<br />

Adham, S., R. Mirlo R. and P. Gagliardo (2000). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Reclamation – Phase II.<br />

Desalination Research and Development Program Report No. 60; Project No. 98-FC-81-0031, United<br />

States Department of Interior, Bureau of Reclamation.<br />

Adham, S., D. Askenaizer, R. Trussell, and P. Gagliardo (2001a). Assessing the Ability of the Zenon Zenogem<br />

<strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong> Research<br />

Institute.<br />

Adham, S., D. Askenaizer, R. Trussell, P. and Gagliardo (2001b). Assessing the Ability of the Zenon Mitsubishi<br />

Sterapore <strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong><br />

Research Institute.<br />

Adham, S., and J. DeCarolis (2004). Optimization of Various MBR Systems for <strong>Water</strong> Reclamation – Phase III.<br />

Final Report Project No. 01-FC-81-0736, Bureau of Reclamation.<br />

Benedek, A., and P. Cote (2003). “Long-Term Experience with Hollow Fiber <strong>Membrane</strong> <strong>Bioreactors</strong>.”<br />

Proceedings, International Desalination Association Conference.<br />

California Department of Health Services (2005). Treatment Technology Report for Recycled <strong>Water</strong>. Department<br />

of Health Services, State of California Division of Drinking <strong>Water</strong> and Environmental Management.<br />

Koch <strong>Membrane</strong> Systems (2005). Technical literature on the KMS <strong>Membrane</strong> Bioreactor.<br />

Kruger (2005). Technical literature on the BIOSEP FS MBR Process.<br />

Parkson Corporation (2005). Website: http://www.parkson.com/Content.aspx?ntopicid=196.<br />

U.S. Department of Interior, Bureau of Reclamation (2005). Project agreement number 05 FC 81157,<br />

October.<br />

USFilter-Memcor (2005). Technical information and correspondence provided by Wenjun Liu, Director of<br />

Bioprocess Technology.<br />

van der Roest, H.F., D.P. Lawrence, and A.G.N. van Bentem, (2002) <strong>Membrane</strong> <strong>Bioreactors</strong> for Municipal<br />

Wastewater Treatment. IWA Publishing. STOWA.<br />

Zenon (2005). Website: http://www.zenon.com/mbr/design_considerations.shtml.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

17


18<br />

JAMES F. DECAROLIS is a Senior Engineer with the Applied Research Department<br />

of the consulting firm, MWH, where he has been involved with several low-pressure<br />

membrane pilot studies conducted at the Aqua 2030 Research Center located in San<br />

Diego, California. In 2002/2003, he served as an on-site Project Engineer for a United<br />

States Department of Interior, Bureau of Reclamation (USBR) study evaluating the<br />

feasibility of using membrane bioreactor technology for water reclamation. In tandem<br />

with this project, he served as Project Engineer for a Desalination Research Innovation<br />

Partnership project to assess the ability of membrane bioreactors to serve as<br />

pretreatment to reverse osmosis during the treatment of municipal wastewater. Recently, he served as an<br />

on-site Engineer for an advanced water treatment pilot study conducted at North City <strong>Water</strong> Reclamation<br />

Plant, which evaluated ultrafiltration followed by reverse osmosis followed by ultraviolet plus peroxide for<br />

indirect potable reuse. He is currently serving as Project Manager for a USBR project evaluating newly<br />

developed membrane bioreactor systems for water reuse. DeCarolis received both a B.S. and M.S. in<br />

Environmental Engineering from the University of Central Florida.


Session 2: Fundamentals and Applications<br />

Evaluation of Conventional Activated Sludge<br />

Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />

R. SHANE TRUSSELL, PH.D., P.E.<br />

Trussell Technologies, Inc.<br />

Pasadena, California<br />

Introduction<br />

Amembrane bioreactor (MBR) is a biological wastewater treatment process that<br />

implements a low-pressure membrane — microfiltration (MF) or ultrafiltration (UF) — to<br />

provide solid-liquid separation. Due to its compact footprint and consistent high-quality<br />

effluent, MBRs have captured the attention of the international wastewater treatment<br />

community. Although MBRs are ideal for water reclamation projects, the high-quality effluent<br />

and additional pathogen removal make MBRs a promising technology for discharging highquality,<br />

partially disinfected wastewater into streams and water bodies while using little or no<br />

chemical addition for disinfection. The purpose of this presentation is to compare and<br />

evaluate the principle differences, advantages, and disadvantages of the MBR process<br />

compared to a conventional, gravity-settled activated sludge.<br />

Brief Perspective on <strong>Membrane</strong> Bioreactor Development<br />

Biological processes have become the preferred process for municipal wastewater treatment.<br />

The activated sludge process (ASP) was pioneered by Arden and Lockett, who reused the<br />

flocculent solids from the previous aeration cycle to accelerate treatment rates (Ardern and<br />

Lockett, 1914). They called the accumulation of these flocculent solids activated sludge and<br />

found that treatment efficiency increased with higher proportions of activated sludge. The<br />

ASP has continued to develop over the past nine decades, and wastewater treatment plants<br />

are being designed today with an excellent understanding of how to optimize plant<br />

performance for organic, solids, and (more frequently) nutrient removal. However, regardless<br />

of how sophisticated and automated the plant design is, the solid-liquid separation is still<br />

performed by gravity sedimentation, and this means that operations staff must understand<br />

what influences sludge settleability to maintain good effluent quality.<br />

Relatively new to biological wastewater treatment is the MBR process. The development of<br />

the MBR process began in the United States with the direct filtration of activated sludge<br />

through a cloth filter along with the concept of coupling a membrane with activated sludge by<br />

Dorr-Oliver in Stamford, Connecticut (Stiefel and Washington, 1966). Thetford Systems in<br />

Ann Arbor, Michigan, commercialized the MBR process in the early 1970s. This new MBR<br />

process combined the three separate unit operations required in a conventional activated<br />

Correspondence should be addressed to:<br />

R. Shane Trussell, Ph.D., P.E.<br />

Principal<br />

Trussell Technologies, Inc.<br />

232 North Lake Avenue, Suite 300<br />

Pasadena, CA 91101 USA<br />

Phone: (626) 486-0560 • Email: shane.trussell@trusselltech.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

19


sludge treatment train into one compact process (Figure 1). The original MBR was an external<br />

MBR (EMBR) where mixed liquor was pumped from an aeration basin to the membrane<br />

module for solid-liquid separation. Yamamoto et al. (1989) developed the submerged MBR<br />

(SMBR) configuration where the membrane module was immersed directly in the mixed<br />

liquor and operated under suction pressure. It is the SMBR configuration that is currently<br />

dominating the municipal wastewater market and is the focus of this presentation, while the<br />

EMBR configuration is principally implemented on high-strength industrial wastewaters.<br />

Activated Sludge Process<br />

Aeration Basin<br />

Secondary Clarifier<br />

Microfiltration<br />

or Ultrafiltration<br />

Tertiary Treated<br />

Wastewater<br />

Primary Treated<br />

Wastewater<br />

(Equivalent to a<br />

1–3 mm screen)<br />

SMBR Process<br />

Aeration Basin<br />

Backwash <strong>Water</strong><br />

WASTE<br />

Tertiary Treated<br />

Wastewater<br />

WASTE<br />

Figure 1. Flow schemes for activated sludge and SMBR processes.<br />

Submerged <strong>Membrane</strong> <strong>Bioreactors</strong> Versus the Activated Sludge Process<br />

Process Design: The SMBR process uses activated sludge technology, combining it with membrane<br />

filtration, to expand the normal operating region. The SMBR process is not affected by the<br />

limitations associated with gravity sedimentation for solid-liquid separation, and this allows<br />

operation at much higher mixed liquor suspended solids (MLSS) concentrations. The peak<br />

MLSS concentration at which the SMBR process is not sustainable due to rapid membrane<br />

fouling is complex and is an area of ongoing research. However, today’s SMBR plants are<br />

optimally designed for MLSS concentrations between 8 and 12 grams per liter (g/L)<br />

(Trussell et al., 2005a; Trussell et al., 2005b).<br />

Higher MLSS concentrations translate into a longer solids retention time (SRT) for a given<br />

hydraulic retention time (HRT). This means that for the same aeration basin volume needed<br />

for the ASP, the SMBR process could double the design SRT. Longer SRTs provide a more<br />

stable biological process that results in wastewater effluent with low oxygen demand.<br />

Traditionally, SMBRs have been designed to operate at SRTs greater than 20 days (d), and<br />

some small facilities only waste once or twice per year. These longer SRTs ensure that<br />

adequate organics removal and complete nitrification can occur even in cold climates. Longer<br />

SRTs also bring about the possibility that specialized microorganisms could propagate and<br />

remove organics that are difficult and slow to degrade. Most importantly, longer SRTs reduce<br />

biological sludge production, reducing the mass of solids that needs to be disposed.<br />

20


Alternatively, higher MLSS concentrations can translate into reduced aeration basin volume.<br />

This means that for the same SRT as the ASP, the SMBR process could reduce aeration basin<br />

volume significantly, reducing HRT by close to one-half. However, this concept brings to light<br />

one of the principle disadvantages of the SMBR process compared to ASP: the SMBR process<br />

has a minimum SRT, where organics present in the mixed liquor have not been adequately<br />

stabilized, and these organics result in rapid membrane fouling (Trussell et al., 2005a;<br />

Trussell et al., 2004). Some manufacturers have set a minimum SRT at 12 d, while others are<br />

willing to work with design engineers to design at reduced SRTs (as low as 8 d). A common<br />

design for the minimum SRT is to determine where nitrification fails at the wastewater<br />

temperature and then apply a safety factor to ensure nitrification does not fail. The ASP is not<br />

restricted by the interaction of the membrane with the mixed liquor, and many wastewater<br />

treatment plants with ASP operate with low SRTs to inhibit nitrification. Operation at these<br />

low SRTs in SMBRs results in rapid membrane fouling, and SMBR manufacturers do not<br />

recommend plant designs at these low SRTs.<br />

Effluent <strong>Water</strong> Quality: The principle difference in effluent water quality between an SMBR<br />

and an ASP is the solid-liquid separation mechanism. Both SMBR and ASP depend principally<br />

on the biological process to oxidize influent organics and nitrogen. However, SMBR uses a<br />

membrane for solid-liquid separation to obtain a higher quality effluent. A well-operated ASP<br />

will contain suspended solids ≤ 10 milligrams per liter (mg/L), turbidity ≤ 10 nephelometric<br />

turbidity units (NTU), and 5-day biological oxygen demand (BOD 5 ) ≤ 10 mg/L, while the SMBR<br />

process typically contains suspended solids ≤ 2 mg/L (non-detect), turbidity ≤ 0.2 NTU, and<br />

BOD 5 ≤ 2 mg/L (non-detect) (Trussell et al., 2000). The SMBR is retaining all suspended<br />

solids in the reactor and, even though the degree of biological soluble organics removal is solely<br />

a function of the SRT, the SMBR process is removing additional soluble organics because of<br />

the direct filtration of activated sludge. Any organics larger than the membrane pores are<br />

being retained in the reactor, and organics even smaller than the membrane pores are being<br />

retained due to additional filtration provided by the cake layer that develops in these high<br />

solids environments. The SMBR process uses membrane separations to improve the biological<br />

process and produce an effluent that exceeds the effluent quality produced in ASP.<br />

Peak Flows: The principle advantage of the SMBR process — the membrane — is also its<br />

principle weakness when it comes to addressing peak flows. Although highly dependent on<br />

the specifics of the design (i.e., temperature, design flux, etc.), the SMBR process is typically<br />

limited to a peaking factor of 1.5 Q (flow rate), while the ASP is capable of sustaining much<br />

larger peak flows (>2.5 Q) for a longer period of time. This is because all of the peak flow<br />

must be filtered through the membranes to exit the facility in the SMBR, but the peak flow<br />

passes effortlessly over a weir in the ASP. The SMBR process is most economical when<br />

designed to operate at a constant flow rate, and large peak flows are best addressed with flow<br />

equalization in most facilities. As future membrane costs continue to decrease, the issue of<br />

peak flows in SMBRs will become less important because design engineers will be able to<br />

ensure that adequate membrane area is installed to sustain membrane performance during<br />

peak flow events.<br />

Mixed Liquor Properties: The mixed liquor properties are important because they affect how<br />

easily sludge can be filtered through membranes, settled, or dewatered. There is a significant<br />

difference in selective pressures between the ASP and SMBR, and one would expect<br />

significant differences in mixed liquor properties as well. While the ASP requires biology that<br />

flocculates and settles well to remain in the system, the SMBR process retains all biomass,<br />

even single cells, in the mixed liquor.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

21


Although research is still needed to completely understand the differences and what<br />

influences these mixed liquor properties between the ASP and SMBR, Merlo et al. (2004) has<br />

revealed some key findings that highlight the differences in mixed liquor properties:<br />

1. SMBR sludge has a higher colloidal material content than ASP sludge.<br />

2. SMBR sludge has higher filament concentrations than ASP sludge.<br />

3. SMBR sludge particle size distribution (excluding colloidal) was controlled<br />

exclusively by the mixing intensity, G, and the same particle size distribution for an<br />

ASP was obtained for the SMBR.<br />

Merlo et al. (2004) provides explanations for these observed differences between SMBR and<br />

ASP mixed liquor properties:<br />

1. The SMBR mixed liquor has higher colloidal content because the membrane is<br />

retaining materials that would normally exit the ASP over the effluent weir.<br />

2. The SMBR mixed liquor has higher filament concentrations because the SMBR<br />

process is the perfect “trapping” environment. Unless designed with a surface<br />

wasting system, the SMBR process will retain all floating material, including<br />

filamentous microorganisms that float and may cause foam.<br />

3. A similar particle size distribution was obtained for an activated sludge reactor at high<br />

shear conditions (ASP) as that obtained for the SMBR (Figure 2).<br />

0.6<br />

0.5<br />

ASP<br />

Frequency<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

0.6<br />

0.5<br />

2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />

SMBR<br />

Frequency<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />

Characteristic Length, micron<br />

Figure 2. Particle size distribution for ASP and SMBR at 5-d mean cell residence time<br />

(Adapted from Merlo et al., 2004).<br />

22


Still Need to Flocculate: A key conclusion of the SMBR process is that despite all of its<br />

differences from the ASP and the membrane providing an absolute barrier, the mixed liquor<br />

properties still play a significant role in the successful application of the process. A mixed<br />

liquor that is well flocculated and contains a lower concentration of colloidal material is<br />

inherently easier to filter and has a lower fouling potential than a dispersed sludge with high<br />

concentrations of colloidal material (Fan et al., 2006). Recently, this topic has become the<br />

focus of the two leading SMBR manufacturers in the United States market. One gave a<br />

recent workshop in 2005 on “Biohydraulics” while another presented a plot of colloidal<br />

material versus time to filter and indicated the preferred region for good sludge filterability.<br />

As SMBR technology advances, engineers will need to understand mixed liquor properties and<br />

biological characteristics to design an optimized SMBR for a specific application.<br />

Conclusions<br />

Relatively new to the wastewater treatment industry, SMBRs offer significant advantages<br />

compared to conventional ASP: a more compact reactor, higher effluent quality, and higher<br />

MLSS concentrations. However, there are currently significant disadvantages of the SMBR<br />

process that design engineers need to be informed about: high MLSS limit, low SRT limit,<br />

and peak flow issues. Finally, although the SMBR process retains everything larger than the<br />

membrane pores, the mixed liquor properties are still important to minimize fouling and<br />

ensure successful plant operation. We need to change from the concept of sludge settleability<br />

to sludge filterability.<br />

References<br />

Ardern, E., and W.T. Lockett (1914). “Experiments on the oxidation of sewage without the aid of filters.”<br />

J. Soc. Chem. Indtr., (33): 523.<br />

Fan, F., Z. Hongde, and H. Husain (2006). “Identification of wastewater sludge characteristics to predict<br />

critical flux for membrane bioreactor processes.” <strong>Water</strong> Res., (40): 205.<br />

Merlo, R., R.S. Trussell, S.H. Hermanowicz, and D. Jenkins (2004). “Physical, chemical and biological<br />

properties of submerged membrane bioreactor and conventional activated sludges.” WEFTEC,<br />

New Orleans, LA.<br />

Stiefel, R.C., and D.R. Washington (1966). “Aeration of concentrated activated sludge.” Biotechnol. Bioeng.,<br />

(8): 379.<br />

Trussell, R.S., S. Adham, P. Gagliardo, R. Merlo, and R.R. Trussell (2000). “WERF: Application of membrane<br />

bioreactor (MBR) technology for wastewater treatment.” WEFTEC, Anaheim, CA.<br />

Trussell, R.S., S. Adham, and R.R. Trussell (2005a). “Process limits of municipal wastewater treatment with<br />

the submerged membrane bioreactor.” J. Environ. Eng.-ASCE, 131: 410.<br />

Trussell, R.S., R. Merlo, S.H. Hermanowicz, and D. Jenkins (2005b). “The effect of high mixed liquor<br />

suspended solids concentration, mixed liquor properties, and coarse bubble aeration flow rate on membrane<br />

permeability.” WEFTEC, Washington D.C.<br />

Trussell, R.S., R.P. Merlo, S. Hermanowicz, and D. Jenkins (2004). “The effect of organic loading on<br />

membrane fouling in a submerged membrane bioreactor treating municipal wastewater.” WEFTEC,<br />

New Orleans, LA.<br />

Yamamoto, K., M. Hiasa, T. Mahmood, and T. Matsuo (1989). “Direct solid-liquid separation using hollow fiber<br />

membrane in an activated-sludge aeration tank.” <strong>Water</strong> Sci. Technol., 21: 43.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

23


24<br />

R. SHANE TRUSSELL, Ph.D., P.E., is a Principal at Trussell Technologies, Inc., an<br />

environmental engineering firm that focuses on the quality and treatment of water<br />

and wastewater. He has 8 years of hands-on experience with processes for advanced<br />

wastewater treatment, particularly membrane filtration of secondary and tertiary<br />

effluents, membrane bioreactors, reverse osmosis, electrodialysis, ion exchange,<br />

granular activated carbon adsorption, and disinfection with ozone, chlorine, and<br />

chloramines. Where membrane bioreactors are concerned, he is a recognized<br />

authority, and he was the first to demonstrate that membrane fouling due to high<br />

solids concentrations and high food-to-microorganism ratios (low mean cell residence times) are fundamentally<br />

different in their nature. Trussel received a B.S. in Chemical Engineering from the University<br />

of California, Riverside, an M.S. in Environmental Engineering from the University of California, Los<br />

Angeles, and a Ph.D. in Environmental Engineering from the University of California, Berkeley.


Session 2: Fundamentals and Applications<br />

<strong>Membrane</strong> Bioreactor Global Knowledgebase<br />

GLEN T. DAIGGER, PH.D., P.E., BCEE, NAE<br />

CH2M HILL<br />

Englewood, Colorado<br />

Introduction<br />

In 2001, the <strong>Water</strong> Environment Research Foundation (WERF) authorized a project to<br />

assemble a global knowledgebase summarizing the applications and performance of membrane<br />

bioreactors (MBRs) (Daigger et al., 2001). Available on the WERF website to WERF<br />

subscribers or for purchase as a CD-ROM, the knowledgebase contains eight elements,<br />

including:<br />

1. Tutorials (PowerPoint-based) to provide an introduction and overview to parties<br />

potentially interested in MBRs for a particular application.<br />

2. Published Literature Database Search Tool, which is an extensive searchable database<br />

consisting of abstracts from relevant technical papers.<br />

3. Gray Literature Database Search Tool, which is an extensive searchable database<br />

providing listing and source information for relevant gray literature (pilot-plant reports,<br />

manufacturer’s information, etc).<br />

4. Installation Database Search Tool, which is a searchable database providing summary<br />

information for a wide range of MBR installations and more detailed information for<br />

selected examples of various types of installations.<br />

5. Decision Tool, which provides a set of questions and answers to help the website user<br />

determine whether MBRs are potentially applicable for a specific application (should<br />

they be interested in learning more!).<br />

6. Preliminary Sizing Tool, which is used to develop preliminary sizes for a particular<br />

application (used in conjunction with the Decision Tool).<br />

7. Installations Survey Tool, which allows owners of MBR installations to input data on their<br />

application to share with others.<br />

8. Links to Related Websites, which allow access to information on MBRs contained in<br />

other websites.<br />

The searchable database format was selected due to the rapid development of this technology<br />

and allows updates to be completed easily as needed.<br />

Correspondence should be addressed to:<br />

Glen T. Daigger, Ph.D., P.E., BCEE, NAE<br />

Senior Vice President and Chief Technology Officer<br />

CH2M HILL<br />

9191 South Jamaica Street<br />

Englewood, CO 80112 USA<br />

Phone: (720) 286-2542 • Email: gdaigger@ch2m.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

25


The website was initially completed and made available in 2002, then updated in 2004 due to<br />

the rapid development of the technology (Schwartz et al., 2006). Key observations associated<br />

with this knowledgebase are summarized below.<br />

Key Observations<br />

1. Several thousand MBR installations exist on a worldwide basis, with significant<br />

installations located on virtually every continent. A wide range of wastewaters are<br />

treated in MBRs, including municipal and a diverse range of industrial wastewaters,<br />

along with other applications such as landfill leachate.<br />

2. The vast majority of existing MBR applications are small, reflecting historical approaches<br />

to the application of MBR technology (Crawford et al., 2000). However, MBRs are<br />

increasingly being applied to larger plants (Crawford et al., 2005; Daigger et al., 2002).<br />

3. Technical analysis indicates that MBR technology is ready for a wide range of<br />

applications in both developed and developing countries (Daigger et al., 2005), including<br />

advanced wastewater treatment, water reclamation and reuse, pretreatment prior to<br />

reverse osmosis for water reclamation, grey water recycling, and the treatment of highly<br />

polluted environmental waters (Fleischer et al., 2005).<br />

4. MBR design and application has progressed through “three generations,” beginning with<br />

small installations intended to reliably produce high-quality effluent with minimal<br />

attention, to modest sized facilities capable of not only removing biodegradable organic<br />

matter, but also removing nutrients (Crawford et al., 2000). Fourth generation plants<br />

are now being implemented that resemble larger, conventional wastewater treatment<br />

facilities, but are using MBRs rather than conventional biological processes (Daigger and<br />

Crawford, 2005; Daigger et al., 2002).<br />

5. As the size and complexity of MBR facilities have increased, the method of procuring<br />

MBR equipment for these facilities has evolved from one similar to that used to procure<br />

“package” wastewater treatment plants to that used to procure conventional wastewater<br />

treatment equipment (Crawford et al., 2002). As a consequence, owners (and their<br />

engineers) are taking increased responsibility for the overall design of the wastewater<br />

treatment plant and are more carefully defining the responsibilities and scope of supply<br />

of the membrane suppliers.<br />

6. The performance characteristics of MBRs are increasingly well understood (Schwartz et<br />

al., 2006), resulting in increased consensus on the design of these facilities (Daigger and<br />

Crawford, 2005; Daigger et al., 2002).<br />

A result of these trends is that MBRs are becoming an accepted approach to wastewater<br />

treatment that can be successfully applied to a wide range of applications and facility sizes.<br />

The features of MBRs lead some to conclude that they can play an important role in delivering<br />

needed water to even the most disadvantaged worldwide, thereby playing an important role in<br />

meeting Millennium Development goals (DiGiano et al., 2004).<br />

26


References<br />

Crawford, G., G. Daigger, J. Fisher, S. Blair, and R. Lewis (2005). “Parallel Operation of Large <strong>Membrane</strong><br />

<strong>Bioreactors</strong> at Traverse City.” Proceedings of the <strong>Water</strong> Environment Federation 78 th Annual Conference &<br />

Exposition, Washington DC, CD-ROM.<br />

Crawford, G., A. Fernandez, A. Shawwa, and G. Daigger (2002). “Competitive Bidding and Evaluation of<br />

<strong>Membrane</strong> Bioreactor Equipment – Three Large Plant Case Studies.” Proceedings of the <strong>Water</strong> Environment<br />

Federation 75 th Annual Conference & Exposition, Chicago, IL, CD-ROM.<br />

Crawford, G., D. Thompson, J. Lozier, G. Daigger, and E. Fleischer (2000). “<strong>Membrane</strong> <strong>Bioreactors</strong> – A<br />

Designer’s Perspective.” Proceedings of the <strong>Water</strong> Environment Federation 73 rd Annual Conference &<br />

Exposition on <strong>Water</strong> Quality and Wastewater Treatment, Anaheim, CA, CD-ROM.<br />

Daigger, G.T., B.E. Rittmann, S. Adham, and G. Andreottola (2005). “Are <strong>Membrane</strong> <strong>Bioreactors</strong> Ready for<br />

Widespread Application?” Environmental Science and Technology, 399A-406A.<br />

Daigger, G.T. and G.V. Crawford (2005). “Incorporation of Biological Nutrient Removal (BNR) Into <strong>Membrane</strong><br />

<strong>Bioreactors</strong> (MBRs).” Proceedings of the IWA Specialized Conference, Nutrient Management in Wastewater<br />

Treatment Processes and Recycle Streams, Krakow, Poland, 235.<br />

Daigger, G.T., G.V. Crawford, and J.C. Lozier 2002). “<strong>Membrane</strong> Bioreactor Practices and Applications in<br />

North America.” Proceedings of the First Leading Edge Drinking <strong>Water</strong> and Wastewater Treatment Technology<br />

Conference, International <strong>Water</strong> Association.<br />

Daigger, G.T., G. Crawford, A. Fernandez, J.C. Lozier, and E. Fleischer (2001). “WERF Project: Feasibility of<br />

<strong>Membrane</strong> Technology for Biological Wastewater Treatment – Identification of Issues and MBR Technology<br />

Assessment Tool.” Proceedings of the <strong>Water</strong> Environment Federation 74 th Annual Conference & Exposition,<br />

Atlanta, GA, CD-ROM.<br />

DiGiano, F.A., G. Andreottola, S. Adham, C. Buckley, P. Cornel, G.T. Daigger, A.G. Fane, N. Galil, J.G. Jacangelo,<br />

A. Pollice, B.E. Rittmann, A. Rozzi, T. Stephenson, and Z. Ujani (2004). “Safe <strong>Water</strong> for Everyone.”<br />

<strong>Water</strong> Environment and Technology, 31-35.<br />

Fleischer, E.J., T.A. Broderick, G.T. Daigger, A.D. Fonseca, R.D. Holbrook, and S.N. Murthy (2005).<br />

“Evaluation of <strong>Membrane</strong> Bioreactor Process Capabilities to Meet Stringent Effluent Nutrient Discharge<br />

Requirements.” <strong>Water</strong> Environment Research, (77): 162-178.<br />

Schwartz, A.E., B.E. Rittmann, G.V. Crawford, A.M. Klein, and G.T. Daigger (2006). “Critical Review on the<br />

Effects of Mixed Liquor Suspended Solids on <strong>Membrane</strong> Bioreactor Operation.” Separation Science and<br />

Technology, In Press.<br />

GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE, is a recognized expert in wastewater<br />

treatment, especially the use of biological processes. At present, he is a Senior Vice<br />

President and Chief Technology Officer for the international consulting engineering<br />

firm CH2M HILL, where he has been employed for over 23 years. Among his<br />

responsibilities, he oversees wastewater process engineering on both municipal and<br />

industrial wastewater treatment projects on a firmwide basis. He is also the first<br />

Technical Fellow for the firm, an honor recognizing the leadership that he provides<br />

for CH2M HILL and for the profession in the development and implementation of<br />

new wastewater treatment technology. From 1994 to 1996, Daigger also served as Professor and Chair<br />

of the Environmental Systems Engineering Department at Clemson University. In addition, he formerly<br />

served as Chair of the Board of Editorial Review of <strong>Water</strong> Environment Research and as Chair of the<br />

<strong>Water</strong> Environmental Federation Technical Practice Committee. He is currently Chair of the<br />

Committee Leadership Council. Daigger received a B.S. and M.S. in Civil Engineering and a Ph.D. in<br />

Environmental Engineering from Purdue University.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

27


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Design, Procurement, and Costs<br />

of <strong>Membrane</strong> Bioreactor Systems<br />

STEPHEN M. LACY, P.E., DEE<br />

MWH Americas, Inc.<br />

Las Vegas, Nevada<br />

The membrane bioreactor (MBR) has integrated microfiltration with activated sludge to<br />

create a space-efficient facility capable of producing high-quality water. Like any process,<br />

there are advantages and disadvantages to using MBRs. Because of rapid growth in the<br />

application of plant configurations, it is important to understand the design principles<br />

necessary to result in a successful installation. Since MBRs are used in both large and<br />

“end-of-pipe” facilities, understanding the limitations of the process and the proper sizing<br />

of components becomes critical to success.<br />

The MBR process can have the same features and performance of any advanced secondary or<br />

Biological Nutrient Removal (BNR) facility, combined with the flexibility and performance of<br />

membrane filtration. In general, the membrane portion functions as a solid-liquid separation<br />

process. The effluent from an MBR can be expected to outperform any traditional or<br />

conventional treatment system.<br />

Initially, MBRs were installed in small facilities to handle a wastewater flow from a small area,<br />

or as a scalping plant to supply reuse-quality water to an individual user. Today, MBRs are<br />

seeing an expanded use as “end-of-pipe” facilities and to supply clusters of reuse water users<br />

as remote reclamation facilities.<br />

In this presentation, we will discuss several important design concepts and suggest design<br />

parameters that will provide flexibility in the operation of facilities, including the ability to<br />

properly maintain components. We will also discuss a procurement process for the membrane<br />

system. Finally, we will look at some of the costing developed for scalping-type facilities.<br />

Design Considerations<br />

It is important to note that with an MBR, there is no other option for producing an effluent<br />

other than through the membranes. The configuration of an MBR is greatly impacted by<br />

whether the facility will be used as a scalping plant or “end-of-pipe” treatment plant.<br />

Understanding both 1) how the MBR is being applied and 2) the required components needed<br />

for reliable operation are critical to proper design. Several MBR design considerations that<br />

will be discussed during the presentation include:<br />

• Screening (which is critical).<br />

• Handling peak flows.<br />

Correspondence should be addressed to:<br />

Stephen M. Lacy, P.E., DEE<br />

MWH Americas, Inc.<br />

3014 West Charleston Boulevard<br />

Las Vegas, NV 89102 USA<br />

Phone: (702)878-8010 • Email: stephen.lacy@mwhglobal.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

29


• <strong>Membrane</strong> flux rate (which should be selected to allow flexibility).<br />

• Foam control.<br />

• Waste sludge handling.<br />

• Low demand at scalping plants.<br />

A typical layout of an MBR facility configured for full BNR treatment is shown in Figure 1.<br />

This presentation will discuss the configuration of return streams and how to gain some<br />

advantage from the air used to agitate the membranes and avoid negatively impacting the<br />

biological process.<br />

Solids Recirculating System<br />

Anoxic<br />

Zones<br />

Screened<br />

& Degritted<br />

Wastewater<br />

Anaerobic<br />

Zones<br />

OxicZones<br />

<strong>Membrane</strong><br />

Bays<br />

MLSS Recycle System<br />

Selectors Nitrification <strong>Membrane</strong>s<br />

Figure 1. MBR flow schematic.<br />

Procurement of <strong>Membrane</strong> Systems<br />

MBR systems that are commercially available today do not lend themselves to a common<br />

design arrangement, thereby requiring custom application of each manufacturer’s system.<br />

There are three general ways to proceed with the selection and procurement of an MBR system:<br />

• Sufficiently isolate the membrane system from the remainder of the process units so<br />

that the system is independent with minimal impact on the plant layout, allowing the<br />

design to proceed without specific details required of the membrane system.<br />

• Implement the project on an alternative delivery basis, allowing the design-builder to<br />

select and work with a membrane system supplier.<br />

• Procure the membrane system early in the project design so that the facility is<br />

configured around specific equipment.<br />

In this presentation, we will focus on the latter of the options.<br />

The early procurement of the membrane systems can shorten the project schedule by allowing<br />

both the designers to customize the design around the specific equipment being installed and<br />

the equipment supplier to commence manufacturing while design is underway. Commonly,<br />

this procurement is accomplished in a two-step process. The first is a qualification-based<br />

selection to create a short-list of manufacturers. These manufacturers are invited to furnish<br />

proposals for their equipment as part of the second step. Because the equipment is varied in<br />

configuration and operation, an evaluated bid process is used to review the proposals and the<br />

final selection of the supplier.<br />

30


Cost Analysis of <strong>Membrane</strong> Bioreactor Systems for <strong>Water</strong> Reclamation<br />

Cost estimates were developed for full-scale MBR reclamation (scalping) systems ranging from<br />

0.2 to 10 million gallons per day (mgd). These estimates included both capital and operational<br />

costs related to the MBR process and subsequent disinfection. The costs associated with the<br />

membrane portion of the MBR systems were developed from cost quotes from four leading<br />

MBR suppliers. All other costs, including headworks, biological process, and disinfection<br />

costs, were estimated from preliminary conceptual design. Results of the analysis indicate<br />

that the total costs ($/1000 gallons) for 1-mdg MBR water reclamation systems, designed<br />

to operate on raw wastewater, ranged from $1.81 to $2.24.<br />

STEPHEN M. LACY, P.E., DEE, has more than 30-years experience in all facets of<br />

water and wastewater projects, from development through construction. He is a<br />

Project Manager for MWH Americas, Inc., working with the wastewater technical<br />

group. Over the past several years, Lacy has been involved in the testing, evaluation,<br />

and conceptual design for clients who are considering membrane treatment of their<br />

wastewater. He has also looked at wastewater membranes in the membrane<br />

bioreactor process and ultrafiltration of secondary effluent using submerged and<br />

pressure membrane configurations. A member of the Nevada <strong>Water</strong> Environment<br />

Association, he is currently Co-Chairman of both the Professional Development and Government Affair<br />

Committees. Lacy received a B.S. in Civil Engineering and an M.E. in Sanitary Engineering from the<br />

University of Idaho.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

31


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Retrofit of an Existing Conventional Wastewater<br />

Treatment Plant with Zenon <strong>Membrane</strong><br />

Bioreactor Technology<br />

DAVE N. COMMONS<br />

City of Redlands Municipal Utilities Department<br />

Redlands, California<br />

On May 31, 2001, the State of California Waste Discharge Requirement (WDR) permit<br />

for the wastewater treatment facility of the Wastewater Division of the City of Redlands<br />

Municipal Utilities Department was modified from requiring a Total Inorganic Nitrogen (TIN)<br />

12-month average effluent limitation of 15 milligrams per liter (mg/L) to a new permit effluent<br />

compliance level of 10 mg/L. The wastewater treatment plant, as configured at that time,<br />

could not meet this new compliance limitation because of insufficient aeration basin capacity.<br />

Because California was experiencing energy shortages in 2001, the City of Redlands<br />

Wastewater Division was also asked to provide to the Mountain View Power Company (a<br />

division of the Southern California Edison Company) a reliable source of high-quality cooling<br />

water that was not only low in total suspended solids (TSS) and biochemical oxygen demands<br />

(BOD), but also had less than 5 mg/L of total phosphates.<br />

The Wastewater Division evaluated the capability of a step feed, multi-anoxic zone nitrification/<br />

denitrification treatment process modification with both pre-anoxic and post-anoxic zone<br />

configurations to the current treatment process to meet these nutrient requirements. It was<br />

determined that even thought both of these process modifications met the required effluent<br />

TIN limitation of 10 mg/L, neither would be able to meet the effluent TIN limitation on a<br />

sustained basis. It was also determined that the Division would not meet the total phosphates<br />

requirement of the power plant with the current plant configuration and treatment processes.<br />

After an extensive evaluation of the capabilities of conventional granular filtration technology<br />

versus membrane bioreactor (MBR) technology in different configurations, the City decided to<br />

upgrade 22.7 megaliters per day (ML/d) (6.0 million gallons per day [mgd]) of the Wastewater<br />

Division’s 35.96 ML/d (9.5 mgd) secondary-level activated sludge facility to a full tertiary-level<br />

treatment by using a dual-stage MBR facility. The dual-stage MBR configuration places the<br />

membrane cassettes in separate bioreactor tanks rather than within aeration basins. It was<br />

also decided that because the plant used anaerobic digestion for biosolids stabilization and<br />

because space was limited in the aeration basins for separate anaerobic zones, chemical<br />

precipitation using iron salts would be used for phosphate removal instead of using biological<br />

phosphorus removal. The iron salts were chosen over aluminum salts because ferrous chloride<br />

was already being used in the facility for hydrogen sulfide control in the anaerobic digesters.<br />

Correspondence should be addressed to:<br />

Dave N. Commons<br />

<strong>Water</strong> Operations Manager<br />

City of Redlands Municipal Utilities Department<br />

P.O. Box 3005<br />

35 Cajon Street, Suite 15A<br />

Redlands, CA 92373 USA<br />

Phone: (909) 798-7588 • Email: dcommons@cityofredlands.org<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

33


This presentation will give a description of the treatment technology evaluation that led to the<br />

decision to construct an MBR facility instead of using conventional granular filtration<br />

technology to meet California’s Title 22 requirements for reclaimed water usage. A detailed<br />

evaluation of the start-up problems will then follow. This will include dealing with such issues<br />

as a lower-than-expected aeration influent soluble BOD, which required evaluating long-term<br />

methanol addition to resolve the low soluble BOD issue. An extensive explanation of start-up<br />

procedures will then follow, which will include testing protocol, treatment methodology<br />

experimentation, and treatment evaluation results that were necessary for the Wastewater<br />

Division to bring this dual-stage MBR facility into compliance with the both the State of<br />

California WDR permit requirements and the needs of the electrical power generating facility.<br />

The final section of the presentation will deal with a discussion of long-term process problems,<br />

challenges, and recommendations that resulted from the start-up and operations of a full<br />

tertiary treatment level, dual-stage MBR wastewater reclamation facility.<br />

As more wastewater treatment facilities use MBR facilities to meet high-quality wastewater<br />

effluent criteria needed for water reclamation because of the technology’s ability to meet<br />

high-level criteria on a consistent, low-cost basis, it is importance to evaluate the operational<br />

problems and challenges that these plants present. This presentation will provide insights into<br />

both start-up and long-term operating process issues. Since this conference is being held in<br />

California, a discussion of the operational issues and problems of the largest membrane<br />

bioreactor facility in the State of California (at the time of this submission), where water<br />

reclamation issues are paramount, should be relevant to conference attendees.<br />

Further Reading<br />

Commons, D. (2002). Twenty Week Evaluation of the Multi-Anoxic Zones Nitrification/ Denitrification<br />

Treatment Process for Removing Low Level Total Inorganic Nitrogen at the City of Redlands, California<br />

Wastewater Treatment Facility, WEFTEC 2002, Chicago, IL.<br />

Commons, D., G. Beliew, S.S. Nedic, and J. Cumin (2005). “MBR Reduces Potable <strong>Water</strong> Use, Increases<br />

Revenue,” <strong>Water</strong>world, September, Volume 21, No. 9.<br />

Pearson, D. (2005). “New Dual-Stage MBR Technology Yields Higher Quality Effluent at Reduced Operating<br />

Costs,” Industrial <strong>Water</strong>world, March/ April, Volume 6, No. 2.<br />

U.S. Environmental Protection Agency (1987). Phosphorus Removal, EPA/625/1-87/001, Washington, D.C.<br />

U.S. Environmental Protection Agency (1993). Nitrogen Control, EPA/625/R-93/010, Washington, D.C.<br />

<strong>Water</strong> Environment Federation (1996). Operation of Municipal Wastewater Treatment Plants, Volume III, 5 th<br />

Edition, Alexandria, VA.<br />

<strong>Water</strong> Environment Federation (1998). Biological and Chemical Systems for Nutrient Removal, Special<br />

Publication, Alexandria, VA.<br />

34


DAVE N. COMMONS has over 25 years of experience with wastewater treatment<br />

and collection and over 18 years of experience in the water treatment and distribution<br />

field. At present, he is the <strong>Water</strong> Operations Manager for the City of Redlands<br />

Municipal Utilities Department, where he oversees all City water supply sources,<br />

water and wastewater treatment facilities, and potable water distribution and<br />

wastewater collection systems, among others. Prior to joining the City of Redlands,<br />

he was the <strong>Water</strong> Utilities Operations Manager for the City of Corona <strong>Water</strong> Utilities<br />

Department in California and Field Operations Division Manager for the Sarasota<br />

County Utilities Department in Florida. Commons received a B.A. in Divinity and Education from<br />

Antioch Baptist Bible College and a Masters degree in Divinity and Religious Education from<br />

Southwestern Baptist Theological Seminary. He also holds Grade V Wastewater Operator, Grade T5<br />

<strong>Water</strong> Operator, and D5 Distribution Operator certificates in the State of California, with equivalent<br />

wastewater certificates in both the States of Georgia and Florida.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

35


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Retrofit of an Existing Conventional Wastewater<br />

Treatment Plant with USFilter <strong>Membrane</strong><br />

Bioreactor Technology<br />

JOHN HATCHER<br />

Oconee County Utility Department<br />

Watkinsville, Georgia<br />

In 2002, the Oconee County Utility Department (OCUD) sought to increase plant capacity<br />

at Calls Creek Wastewater Treatment Plant in Georgia. Different traditional treatment<br />

processes were looked at and weighed against the quality of the effluent that each produced.<br />

For the cost and quality of the system, membrane microfiltration emerged as the leading<br />

candidate. Traditional equipment would provide the quality of water needed to meet the<br />

present discharge permit, but may not have met it in the future. The quality of the water<br />

produced by membranes surpassed any other available technology for the price, and the<br />

decision was made to proceed in that direction.<br />

After deciding on the manufacturer, a pilot plant was provided by USFilter for evaluation and<br />

testing. The pilot plant passed all testing and met the effluent quality parameters that were<br />

needed. After completion of the pilot, OCUD moved forward with awarding the bid to<br />

USFilter to complete a design/build upgrade at Calls Creek.<br />

The construction process worked alongside the existing Orbal aeration basin and was<br />

integrated into it. Submersible pumps were installed in the center channel of the aeration<br />

tank, which pumped the mixed liquor into ultrafine wedge wire rotary screens. The screens<br />

removed all types of trash before the mixed liquor entered the membrane bioreactor (MBR)<br />

building for filtration. After filtration, the effluent was discharged to the existing ultraviolet<br />

system for disinfection before final discharge. The return activated sludge leaving the MBR<br />

was sent back to the aeration tank to begin the process all over again.<br />

The MBR system went online in April 2004 and has been in service since then. The system<br />

has provided high quality effluent and has allowed OCUD to look into the possibility of<br />

providing the treated effluent back to our customers as reuse water for irrigation.<br />

Correspondence should be addressed to:<br />

John Hatcher<br />

Wastewater Supervisor<br />

Oconee County Utility Department<br />

P..O Box 88<br />

Watkinsville, GA 30677 USA<br />

Phone: (706) 769-3963 • Email: callscreek@msn.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

37


38<br />

JOHN HATCHER is the Wastewater Supervisor for Oconee County Utility Department,<br />

which provides drinking water and sanitary sewer service to its customers within the<br />

service areas inside Oconee County, Georgia. As Wastewater Supervisor, he is<br />

responsible for the daily operation and compliance of a conventional wastewater<br />

treatment plant and a land-application wastewater plant. Recently, he won two<br />

awards from the Georgia <strong>Water</strong> and Pollution Control Association, one of which was<br />

for the Calls Creek Wastewater Treatment Plant, which discharges into the Calls<br />

Creek watershed. Hatcher received a B.S. in Environmental Health Science from<br />

the University of Georgia. He is also a licensed water and wastewater treatment plant operator in the<br />

State of Georgia.


Session 3: Case Studies - Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

<strong>Membrane</strong> Bioreactor Applications:<br />

A Global Perspective<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Pilot-Plant Studies<br />

Since membrane bioreactor (MBR) performance is highly dependent upon feedwater<br />

quality, a true comparison of the performance of different MBR technologies can only be<br />

achieved when they are tested against the same feedwater matrix. A number of comparative<br />

pilot trials have been conducted over the past 5 years, which permit a useful technology<br />

comparison (Table 1), albeit with certain caveats. The studies identified in Table 1 have all<br />

been conducted this millennium, and all employ at least one full-scale membrane module and<br />

at least three different technologies. Not all of these studies have been published, however.<br />

Table 1.<br />

Comparative Pilot-Plant Trials<br />

Reference<br />

Technology Adham Van der Tao Honolulu Lawrence Trento EAWAG<br />

Tested et al. Roest et al. et al.<br />

(2005) et al. (2005) (2005)<br />

(2002)<br />

Zenon X X X X X X<br />

Kubota X X X X X X<br />

Mitsubishi Rayon X X X X X<br />

Norit – X –<br />

Huber (X) X<br />

Memcor X X X<br />

Toray<br />

X<br />

Comparative Parameters<br />

To allow a comparison of disparate sets of data from various full-scale plants, normalization of<br />

the data is required. The most convenient parameters to use are flux (J, liters per cubic meter<br />

per hour [LMH]), permeability (K, LMH/bar), and specific aeration demand with respect to<br />

membrane area (SAD m , Nm 3 hr -1 m -2 or m hr -1 ) and permeate volume (SAD p , Nm 3 air per m 3<br />

permeate [i.e., unitless]). A comparison of such data for full- and pilot-scale plants is provided<br />

in Table 2.<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

39


Table 2. Summary of Key Parameters<br />

Cap 1 Flux K SAD m<br />

2 SAD p<br />

2 MLSS Filt. cycle3 (min) Cleaning Cycle 4<br />

(MLD) (LMH) (LMH/bar) (Nm/h) (–) (g/L) on r or b Interval Type<br />

Zenon<br />

p 20 225 0.54 27 10-11<br />

p 35 225 0.54 15 10-11<br />

p 37.2 270 0.52 14 8-10 9.5 0.5b<br />

p 16 120 0.33 22 9 1b<br />

p 10 200 0.54 28 7 5 0.5b<br />

p 12.4 124 5 0.31 25 4-13 12 0.5b<br />

2* 18 95 1 56 15 10 0.75b 1w/6m mCIP/R<br />

48 18 144 0.29 16 8-10 10.5 1.5r 1w/15m mCIP/R<br />

0.15,i 12 71 0.65 54 10-15 10 0.5b 0.5w mCIP<br />

48 25 175 0.4 17 12 7 1 0.5m mCIA<br />

Mitsubishi Rayon<br />

p 7.5 200 0.33 52 9-12 1200 240r<br />

p 4.8 90 0.37 38 8 8 0.5b/1.5r<br />

0.38 10 30 0.65 65 12<br />

p 23 140 1 45 8-14 12 2r<br />

p 20 66 5 0.48 20 6-14 13 2r<br />

USF Memcor<br />

p 21.7 150 0.39 18 6-8<br />

p 21 182 0.2 17<br />

0.61 16 150 5 0.18 11<br />

Asahi-kasei<br />

0.9,i 16 80 0.24 15 Ind<br />

Koch Puron<br />

0.63 25 160 0.25 10 Mun 5 3w mCIP<br />

Kubota<br />

p 10.4 650 0.75 75 10-12 8 2r<br />

p 25 250 0.6 24 9-12 9 1r<br />

p 15 261 0.98 79 9 1r<br />

p 9.5 200 1.5 88 8 8 2r<br />

p 26 650 4 0.94 39 6-12 9 1r<br />

1.9 20 350 0.75 32 12-18 1380 60r 8-9m CIP<br />

13 33 330 1.06 32 8-12 1380 60r 6m CIP<br />

4.3 25 680 0.56 23 10-20 1-2 6m CIP<br />

Brightwater<br />

1.2 27 150 1.28 47 12-15 55 5r >18m CIP<br />

Toray<br />

0.53 25 208 0.54 22 6<br />

Huber<br />

0.11 24 250 0.35 22 Mun 9 1 none<br />

Colloide<br />

0.29 25 62.5 0.5 20 Mun 6 2 na<br />

1 Plant capacity or plant type (p = pilot plant); MLD = Megaliters per day.<br />

2 Specific aeration demand; Nm/h = Cubic namometers per hour air per cubic meters membrane.<br />

3 Filtration cycle (r = relaxation; b = backflush); on = Filtration period.<br />

4 Cleaning intervals (w = weeks; m = months).<br />

5 Maximum permeability.<br />

Intermittent aeration used for all Zenon plants other than *.<br />

CIP = Cleaning in place. mCIP = Maintenance cleaning in place.<br />

mCIP/R = Maintenance cleaning in place with relaxation. mCIA = Maintenance cleaning in air.<br />

40


It has generally been observed from lab-scale studies that attainable flux increases with increasing<br />

aeration rates due to increased scouring. This is manifested either as an increase in the<br />

critical or sustainable flux. In a full-scale plant, this would be expected to be manifested as an<br />

increase in sustainable net permeability with an increasing aeration rate. This, indeed, appears<br />

to be the case, with a general tendency for increasing permeability with increasing SAD m ,<br />

though the data is highly scattered (Figure 1). Some of this data scatter can be attributed to<br />

obvious outliers, namely either a plant operating under sub-optimal conditions and/or a very<br />

small unstaffed plant, where blowers are more likely to be oversized to maintain permeability<br />

and, therefore, limit maintenance. Sustainable permeability also changes according to<br />

clearning protocols and the nature of aeration (i.e., the specifications of the aerator itself and<br />

the mode of application [continuous or intermittent]). Although physical cleaning is, to some<br />

extent, accounted for by using net rather than gross flux in calculating permeability,<br />

maintenance cleaning with hypochlorite permits higher permeabilities to be sustained.<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

✶<br />

▲<br />

❖<br />

♦<br />

✦<br />

✦ ❖<br />

❖ ✦<br />

✣ ▲<br />

▲●<br />

■<br />

✦<br />

✦<br />

✦ ❊<br />

■<br />

✦▲<br />

■<br />

■<br />

■<br />

■<br />

▲<br />

✦<br />

■<br />

✦ Zenon<br />

■ Kubota<br />

▲ M Rayon<br />

❖ USF<br />

✶ Huber<br />

● Colloide<br />

✣ Asahi-k<br />

♦ Puron<br />

✧ Brightwater<br />

❊ Toray<br />

✧<br />

■<br />

0<br />

0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6<br />

SADm, NM^3/hr per m^2<br />

Figure 1. Operating permeability versus specific aeration demand for data in Table 2.<br />

If the more obvious outliers are ignored, then some general trends can be identified from<br />

the data:<br />

a) Flat sheet (FS) systems tend to operate at high permeabilities (generally >200 LMH/bar)<br />

and are associated with high aeration demands, both as SAD m and SAD p . No trend<br />

is evident in this data subset, though all but the highest (and probably non-optimal)<br />

SAD p values lie within the range 20 to 39.<br />

b) Hollow fiber (HF) systems tend to operate at lower permeabilities (generally<br />


Physical cleaning appears to be predominantly by relaxation rather than by backflushing.<br />

Pilot−plant data indicate that the downtime for physical cleaning accounts for between 4 and<br />

20 percent of the operating time, with no profound difference between the two configurations.<br />

On the other hand, maintenance cleaning every 3 to 4 days using relatively low concentrations<br />

of hypochlorite (250 to 500 milligrams per liter [mg/L]) is routinely employed for the Zenon<br />

technology, whereas chemical cleaning is limited to infrequent recovery cleans alone for<br />

FS systems. For both FS and HF systems, such cleans are generally applied at intervals of<br />

6 to 18 months (depending on the flux) and generally employ hypochlorite concentrations<br />

between 1,000 and 5,000 mg/L sodium hypochlorite (NaOCl). Both maintenance and<br />

recovery cleaning are either brief or infrequent enough to add little to the percentage<br />

downtime. For example, an overnight soak of 16 hours every 6 months amounts to less than<br />

0.25 percent in such cases. For Zenon plants, the maintenance cleaning cycle is complete<br />

within 10 minutes and is employed no more than three times a week, again amounting to less<br />

than 0.4-percent downtime. Thus, for the majority of the most recent plants, the ratio of the<br />

net-to gross flux is determined by a period of relaxation alone, and the most onerous impact of<br />

chemical cleaning is chemical usage and chemical waste discharge.<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.<br />

42


Session 4: Innovative Applications and Future Outlook of the Technology<br />

<strong>Membrane</strong> Aeration, Biofilms,<br />

and <strong>Membrane</strong> <strong>Bioreactors</strong><br />

MICHAEL J. SEMMENS, PH.D., P.E.<br />

University of Minnesota<br />

Minneapolis, Minnesota<br />

The theory of membrane gas transfer has been studied and characterized in detail over the<br />

past 30 years. It is possible to accurately predict the gas transfer performance of<br />

membranes using numerous dimensionless correlations if the membrane area and operating<br />

conditions are known. <strong>Membrane</strong>s are now widely used for gas transfer in a variety of<br />

applications, including blood oxygenation, vacuum degassing, and pervaporation.<br />

Environmental applications of membrane gas transfer have been slower to develop because of<br />

problems with biofilm fouling of the membrane surface. If we are to design effective<br />

membrane gas transfer processes for water/wastewater treatment, we need to understand how<br />

these biofilms impact gas transfer. How do these biofilms behave? Is biofilm formation<br />

always a bad thing or are there advantages? This presentation will examine the influence of<br />

biofilms on the gas transfer performance of membranes and explore opportunities for novel<br />

applications in membrane bioreactors.<br />

PROFESSOR MICHAEL J. SEMMENS, P.E., is Professor in the Department of<br />

Civil and Mineral Engineering at the University of Minnesota, where he has taught<br />

since 1977. His research interests include the development of physical and chemical<br />

processes for water, wastewater, and waste treatment; processes to identify factors<br />

that limit mass transfer and the kinetics of separation; membrane bioreactors, module<br />

design, and membrane applications in water and wastewater treatment; and the use<br />

of membranes for controlled gas delivery in biologically active environments, such as<br />

groundwater and sediment remediation projects, and wastewater treatment.<br />

Semmens received a B.S. in Chemical Engineering from the Imperial College of Science and Technology<br />

in London, England, an M.S. in Environmental Engineering from Harvard University, and Ph.D. in<br />

Environmental Engineering from University College in London, England.<br />

Correspondence should be addressed to:<br />

Michael J. Semmens, Ph.D., P.E.<br />

Professor, Department of Civil Engineering<br />

University of Minnesota<br />

500 Pillsbury Drive SE<br />

Minneapolis, MN 55455 USA<br />

Phone: (612) 625-9857 • Email: semme001@umn.edu<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

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Session 4: Innovative Applications and Future Outlook of the Technology<br />

Future Outlook on<br />

<strong>Membrane</strong> Bioreactor Technology<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Challenges<br />

Two areas having a direct bearing on the effective and efficient operation of membrane<br />

bioreactors (MBRs) are 1) cleaning and 2) dynamic effects. The cleaning of surfaces, as<br />

a subject for scientific investigation, pre-dates membrane process development since the<br />

fouling of heat exchangers, and the consequent loss of thermal efficiency has been an issue for<br />

many years. The fouling and cleaning of membranes relating to industrial process separations<br />

have also been the subject of research and development for over 20 years. Compared to this,<br />

the science of membrane cleaning in the context of MBRs is a young one — there have been a<br />

great number of investigations of MBR fouling, but much less on the appropriate chemicals<br />

and protocol for recovering permeability for irreversibly fouled membranes. Given the large<br />

number of parameters that determine the degree of permanent fouling and the candidate<br />

variable parameters that could determine cleaning efficacy, the scope of a rigorous study of<br />

cleaning is potentially extremely broad. Thus, it is not surprising that cleaning protocols have<br />

been developed in an ad hoc way through heuristic investigation.<br />

Dynamic effects exert the greatest influence on consistency in MBR performance, ultimately<br />

leading to equipment and/or consent failures, but have also been largely overlooked by the<br />

academic research community. Specifications for full-scale MBR installations are generally<br />

based on conservative estimates of hydraulic and organic (and or ammoniacal) loading.<br />

However, in reality, these parameters fluctuate significantly. Moreover, even more significant<br />

and potentially catastrophic deterioration in performance can arise through equipment<br />

malfunction and operator error. Such events can be expected to produce over short periods of<br />

time (Table 1):<br />

• Decreases in mixed liquor suspended solids (MLSS) concentration (either through<br />

the loss of solids by foaming or by dilution with feedwater).<br />

• Foaming problems, usually associated with the above.<br />

• Loss of aeration (through control equipment malfunction or aerator port clogging).<br />

• Loss of permeability (through the misapplication of backflush and cleaning<br />

protocols, hydraulic shocks, or contamination of the feed with some unexpected<br />

component).<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

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Table 1. Key Dynamic Determinants and Their Impacts<br />

Determinants<br />

MLSS dilution<br />

Aeration loss<br />

Backflush/cleaning loss<br />

Hydraulic shock<br />

Saline intrusion<br />

Variables<br />

Dilution factor and rate of concentration increase<br />

Percentage and period of reduction<br />

Period of loss<br />

Rate and level of flow increase<br />

Ultimate concentration factor and rate of<br />

concentration decrease<br />

An example of feedwater constituent fluctuation is seawater intrusion. It has been recognized<br />

for some time that rapid changes in salinity can impact microbial physiology, increasing levels<br />

of organic matter (as chemical oxygen demand [COD] or biochemical oxygen demand [BOD])<br />

arising in activated sludge process (ASP) effluent and decreasing microbial activity. However,<br />

the phenomenon has not been investigated for MBRs, where such physiological changes might<br />

be expected to impact fouling. Further examples include fats, oils, and grease (FOGs) and<br />

bacteriological inhibitory substances, since the latter can then alter the system microbiology<br />

and, therefore, generate fouling.<br />

Outlook<br />

Despite the limitation imposed by fouling, the future of membrane bioreactors in municipal<br />

and industrial wastewater treatment seems assured. Valued at an estimated $216.6 million in<br />

2005, the global MBR market is rising at an average annual growth rate of 10.9 percent,<br />

significantly faster than the larger market for advanced wastewater treatment equipment and<br />

more rapidly than the markets for other types of membrane systems. It is expected to<br />

approach $363 million in 2010 (Hanft, 2006). The number of installations for both of the<br />

leading suppliers has undergone exponential growth since the first pilot trials of the submerged<br />

process in 1989 (Figure 1), driven by opportunities presented by increasingly stringent<br />

environmental legislation and by ever-decreasing process costs (Figure 2). Further<br />

incremental improvements can be expected as more is understood about the interrelationship<br />

between biomass characteristics, permanent fouling, and cleaning, and as membrane costs<br />

continue to be driven downwards. More significant “quantum leap” improvements are less<br />

easily envisioned, however, and it remains to be seen whether any profoundly original MBR<br />

products will arise from current research and development activity.<br />

References<br />

Hanft, S. (2006). <strong>Membrane</strong> <strong>Bioreactors</strong> in the Changing World <strong>Water</strong> Market. Business Communications<br />

Company, Report C-240.<br />

Kennedy, S., and C. Churchouse (2005). Progress in <strong>Membrane</strong> <strong>Bioreactors</strong>: New Advances, Experiences, and<br />

Applications of <strong>Membrane</strong> <strong>Bioreactors</strong> in the Treatment of Domestic and Industrial Wastewaters. Wakefield,<br />

United Kingdom.<br />

46


Kubota<br />

Zenon<br />

1500000<br />

1250000<br />

1000000<br />

750000<br />

500000<br />

250000<br />

0<br />

1995<br />

1996<br />

1997<br />

1998<br />

1999<br />

2000<br />

2001<br />

2002<br />

2003<br />

2004<br />

Figure 1. Cumulative installed capacity in cubic meters per day (m3/d) for Kubota and Zenon.<br />

Relative cost / m 3 at 100 l/s<br />

160<br />

140<br />

120<br />

100<br />

80<br />

60<br />

40<br />

@ 8640 m 3 /d<br />

Costs Projected in<br />

1999<br />

Rent and rates<br />

Sludge disposal<br />

Screenings<br />

<strong>Membrane</strong> replacement<br />

Chemicals<br />

Maintenance<br />

Power<br />

Amortised capital<br />

Actual Costs<br />

20<br />

0<br />

1992 1994 1995 1996 1998 2000 2002 2004 2005<br />

Year<br />

Figure 2. MBR process costs (Kubota) versus time (Kennedy and Churchouse, 2005).<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

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48<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.

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