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The Effects of Road Transport on Freshwater and Marine Ecosystems

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104<br />

that “c<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> Zn in 20-50 years will exceed the sediment quality guidelines at which biological<br />

effects are expected to widely occur”.<br />

<str<strong>on</strong>g>The</str<strong>on</strong>g> predicti<strong>on</strong>s, presented in Williams<strong>on</strong> et al. (1999) <strong>and</strong> detailed in Vant et al. (1993), Snelder (1995)<br />

<strong>and</strong> Snelder & Trueman (1995) are based up<strong>on</strong> a series <str<strong>on</strong>g>of</str<strong>on</strong>g> scenarios. <str<strong>on</strong>g>The</str<strong>on</strong>g> detailed calculati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> which<br />

can be found in Appendix 3 <str<strong>on</strong>g>of</str<strong>on</strong>g> Vant et al. (1993).<br />

<str<strong>on</strong>g>The</str<strong>on</strong>g> predicted increases in total metal c<strong>on</strong>centrati<strong>on</strong>s identified by Williams<strong>on</strong> et al. (1999) <strong>and</strong> earlier<br />

reports are based up<strong>on</strong> ‘urban’ stormwater run<str<strong>on</strong>g>of</str<strong>on</strong>g>f, a proporti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> which is c<strong>on</strong>tributed by road transport.<br />

<str<strong>on</strong>g>The</str<strong>on</strong>g> available data has already indicated that c<strong>on</strong>taminant c<strong>on</strong>centrati<strong>on</strong>s in urbanised estuaries are at<br />

levels with the potential to create adverse effects <strong>on</strong> biota. However, the direct comparis<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

c<strong>on</strong>centrati<strong>on</strong>s with guidelines such as the ER-L <str<strong>on</strong>g>of</str<strong>on</strong>g> L<strong>on</strong>g et al. (1995) <strong>and</strong> the ANZECC sediment quality<br />

triggers (refer Secti<strong>on</strong> 5), does not c<strong>on</strong>firm that adverse effects have <strong>and</strong> are occurring as a c<strong>on</strong>sequence<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> the elevated c<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> the c<strong>on</strong>taminants. In additi<strong>on</strong>, any comparis<strong>on</strong> does not take into<br />

account changes in the geochemistry <str<strong>on</strong>g>of</str<strong>on</strong>g> the c<strong>on</strong>taminant over time (i.e., the potential toxicity may<br />

decrease). <str<strong>on</strong>g>The</str<strong>on</strong>g>se factors all add to the difficulty in making such predicti<strong>on</strong>s.<br />

Examinati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> sediment quality adjacent to North Shore City <str<strong>on</strong>g>of</str<strong>on</strong>g>f the East Coast Bays has shown that<br />

sediments c<strong>on</strong>tain elevated c<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> elements such as Pb. C<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> Pb are about<br />

100% higher than would be expected as a result <str<strong>on</strong>g>of</str<strong>on</strong>g> historical c<strong>on</strong>tributi<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> Pb from motor vehicle<br />

emissi<strong>on</strong>s <strong>and</strong> other sources (Kingett Mitchell 2003c). <str<strong>on</strong>g>The</str<strong>on</strong>g> c<strong>on</strong>centrati<strong>on</strong>s in muddy sediments (about 22<br />

mg/kg) are lower than the ANZECC ISQG-low trigger <str<strong>on</strong>g>of</str<strong>on</strong>g> 50 mg/kg however.<br />

In New Zeal<strong>and</strong> <strong>and</strong> internati<strong>on</strong>ally there appears to be little data <strong>on</strong> the distributi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> other elements in<br />

the marine envir<strong>on</strong>ment that have been identified as being emitted from motor vehicles (e.g., Mo, Sb<br />

etc.,). In relati<strong>on</strong> to the PGEs, Tuit et al. (2000) reported <strong>on</strong> Pt <strong>and</strong> Pd in Bost<strong>on</strong> Harbour sediments. <str<strong>on</strong>g>The</str<strong>on</strong>g><br />

study reported that c<strong>on</strong>centrati<strong>on</strong>s had increased about five times above background. Both Pt <strong>and</strong> PD<br />

are released to the envir<strong>on</strong>ment from a number <str<strong>on</strong>g>of</str<strong>on</strong>g> sources. Tuit et al. (2000) described the<br />

anthropogenic sources <str<strong>on</strong>g>of</str<strong>on</strong>g> both elements as being derived from sewage, sewage sludge, medical <strong>and</strong><br />

dental, chemical <strong>and</strong> the jewellery industry. <str<strong>on</strong>g>The</str<strong>on</strong>g> use <str<strong>on</strong>g>of</str<strong>on</strong>g> Pt in catalytic c<strong>on</strong>verters has been the major<br />

c<strong>on</strong>sumer <str<strong>on</strong>g>of</str<strong>on</strong>g> Pt (>60%) since 1973. Until 1993 when Pb was phased out <str<strong>on</strong>g>of</str<strong>on</strong>g> petrol in the US, catalytic<br />

c<strong>on</strong>verters <strong>on</strong>ly accounted for 10% <str<strong>on</strong>g>of</str<strong>on</strong>g> Pd use. Subsequently Pd use in catalytic c<strong>on</strong>verters has increased<br />

to about 40% <str<strong>on</strong>g>of</str<strong>on</strong>g> the dem<strong>and</strong>. <str<strong>on</strong>g>The</str<strong>on</strong>g> Bost<strong>on</strong> study didn’t specifically identify the proporti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> Pd <strong>and</strong> Pt in<br />

sediments attributable to vehicle emissi<strong>on</strong>s however. It is likely that it will be at least equal to or greater<br />

than the amount <str<strong>on</strong>g>of</str<strong>on</strong>g> those elements used in catalytic c<strong>on</strong>verters as the other c<strong>on</strong>sumers practise some<br />

element recovery.<br />

Examinati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> c<strong>on</strong>taminant c<strong>on</strong>centrati<strong>on</strong>s immediately around the discharge points for stormwater<br />

run<str<strong>on</strong>g>of</str<strong>on</strong>g>f from roads <strong>and</strong> urban areas shows that c<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> c<strong>on</strong>taminants in sediments are elevated.<br />

C<strong>on</strong>centrati<strong>on</strong>s in both intertidal <strong>and</strong> subtidal sediments can rise above sediment quality guidelines <strong>and</strong><br />

triggers. For most smaller discharge points haloes <str<strong>on</strong>g>of</str<strong>on</strong>g> metal c<strong>on</strong>centrati<strong>on</strong>s are generally restricted to 10-<br />

20 m. In the wider urban <strong>and</strong> estuary <strong>and</strong> harbour c<strong>on</strong>text it is evident that sediments <str<strong>on</strong>g>of</str<strong>on</strong>g>ten c<strong>on</strong>tain<br />

elevated c<strong>on</strong>centrati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g> metals <strong>and</strong> organic c<strong>on</strong>taminants. In locati<strong>on</strong>s such as the Waitemata<br />

Harbour it is evident that all <str<strong>on</strong>g>of</str<strong>on</strong>g> the surface sediments in the Harbour are c<strong>on</strong>taminated to some degree.<br />

In depositi<strong>on</strong>al envir<strong>on</strong>ments the c<strong>on</strong>centrati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> elements such as Cu can exceed sediment quality<br />

guidelines. Within New Zeal<strong>and</strong> such effects are likely to be restricted principally to depositi<strong>on</strong>al<br />

envir<strong>on</strong>ments adjacent to urban areas. However, stormwater discharges from roads <strong>and</strong> smaller urban<br />

centres to smaller estuarine will have comparable effects but <strong>on</strong> a smaller scale.<br />

Overall, the c<strong>on</strong>tributi<strong>on</strong> that motor vehicles have to sediment c<strong>on</strong>taminati<strong>on</strong> is identifiable where the<br />

discharge is derived from an isolated road. In urban areas, the c<strong>on</strong>tributi<strong>on</strong> from vehicles to sediment<br />

c<strong>on</strong>taminati<strong>on</strong> adjacent to outfalls <strong>and</strong> within estuaries <strong>and</strong> harbours will be dependent up<strong>on</strong> the ratio <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

the loads c<strong>on</strong>tributed by vehicle sources <strong>and</strong> other urban sources <strong>and</strong> activities. This ratio has not been<br />

clearly quantified to-date.<br />

Kingett Mitchell Ltd<br />

Resource & Envir<strong>on</strong>mental C<strong>on</strong>sultants

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