MSDS 3-7-90 Type S-2 Developer-Replenisher - Merry X-Ray
MSDS 3-7-90 Type S-2 Developer-Replenisher - Merry X-Ray
MSDS 3-7-90 Type S-2 Developer-Replenisher - Merry X-Ray
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
MATERIAL SAFETY DATA SHEET Issue Date January 2009<br />
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION<br />
Product Name: 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong>-<strong>Replenisher</strong><br />
Catalog Number: 262889-2 - To Make 10 U.S. gallons (38 L) - (Parts 1&2)<br />
Supplied By: SourceOne Healthcare Technologies, 8020 Tyler Blvd., Mentor, OH 44060, Phone (440) 701-1200<br />
Supplied in Canada by: CAN-med Surgical Supplies, 160 Matheson Blvd. East, Unit 4, Mississauga, Ontario L4Z 1V4,<br />
Phone (866) 277-3577 or (<strong>90</strong>5) 502-1166 and Optimum Medical Imaging, #5 7355 72 nd Street, Delta, BC V4G 1L5,<br />
Phone (604) 512-3728<br />
For Emergency Assistance call: USA - CHEMTREC (800) 424-9300 Canada - CANUTEC (610) 996-6666<br />
Synonym(s): 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong> <strong>Replenisher</strong> Parts 1, 2, & Working Solution (10-gallon size).<br />
Product Use: Photographic processing solution.<br />
2. COMPOSITION/INFORMATION ON INGREDIENTS<br />
Ingredient %Weight/ CAS Reg. # LD 50* LC 50**<br />
Volume mg/kg mg/l<br />
Part 1<br />
Water 60 - 70 7732-18-5 -- --<br />
Potassium Sulfite 10 - 15 10117-38-1 -- --<br />
Sodium Sulfite 10 - 15 7757-83-7 rabbit 2,825 --<br />
Hydroquinone 5 - 10 123-31-9 400 0.004 - 0.18<br />
Potassium Hydroxide 2 - 6 1310-58-3 365 179<br />
Sodium Metaborate 2 - 6 12179-04-3 -- --<br />
Part 2<br />
Water 60 - 75 7732-18-5 -- --<br />
Glutaraldehyde-Bis-<br />
Potassium Bisulfite 20 - 40 7420-89-5 -- --<br />
Working Solution<br />
Water 85 - <strong>90</strong> 7732-18-5 -- --<br />
Potassium Sulfite 1 - 5 10117-38-1 -- --<br />
Sodium Sulfite 1 - 5 7757-83-7 rabbit 2,825 --<br />
Hydroquinone 1 - 5 123-31-9 400 0.004 - 0.18<br />
Potassium Hydroxide 1 - 5 1310-58-3 365 179<br />
Sodium Metaborate 1 - 5 12179-04-3 -- --<br />
Glutaraldehyde-Bis -<br />
Potassium Bisulfite 1 - 5 7420-89-5 -- --<br />
*LD50 = oral rat unless other mentioned<br />
**LC50 = 96 hr fathead minnow unless other mentioned<br />
Page 1 of 5
3. HAZARDS IDENTIFICATION<br />
Part 1: Colorless to Brown liquid that contains Hydroquinone and Potassium Hydroxide.<br />
HARMFUL IF SWALLOWED, CAUSES SKIN AND EYE IRRITATION AND MAY CAUSE<br />
ALLERGIC SKIN REACTION.<br />
HMIS Hazard Rating: Flammability - 0, Reactivity - 0, Health - 1, Protection - B<br />
Part 2: Off-white to pale yellow liquid.<br />
HARMFUL IF SWALLOWED, VAPOR IRRITATING TO THE EYES AND RESPIRATORY<br />
TRACT AND MAY CAUSE ALLERGIC SKIN REACTION.<br />
HMIS Hazard Rating: Flammability - 0, Reactivity - 0, Health - 1, Protection - B<br />
Working Solution: Pale Yellow to Brown liquid with no appreciable smell that contains Hydroquinone and<br />
Potassium Hydroxide.<br />
CAUSES SKIN AND EYE IRRITATION AND MAY CAUSE ALLERGIC SKIN REACTION.<br />
HMIS Hazard Rating: Flammability - 0, Reactivity - 0, Health - 1, Protection - B<br />
4. FIRST AID MEASURES<br />
Inhalation: Move to fresh air, obtain medical attention if required.<br />
Eye Contact: Hold eyelids apart and immediately flush eyes with plenty of water for 15 minutes. Get medical<br />
attention.<br />
Skin Contact: Immediately flush with plenty of water while removing contaminated clothing and shoes. Launder<br />
contaminated clothes prior to reuse. Discard contaminated shoes.<br />
Part 1: Wash with a non-alkaline (acid) skin cleaner, if skin irritation or an allergic skin reaction develops<br />
get medical attention.<br />
Part 2: If skin irritation or an allergic skin reaction develops get medical attention.<br />
Working Solution: If skin irritation or an allergic skin reaction develops get medical attention.<br />
Ingestion:<br />
Part 1: Induce vomiting as directed by medical personnel. Never give anything by mouth to an<br />
unconscious person. Obtain medical care and hospital treatment immediately.<br />
Part 2: Induce vomiting as directed by medical personnel. Never give anything by mouth to an<br />
unconscious person. Obtain medical care and hospital treatment immediately.<br />
Working Solution: Drink 1 - 2 glasses of water, get medical attention.<br />
5. FIRE FIGHTING MEASURES<br />
Extinguishing Media: Water spray, dry chemical, and carbon dioxide (CO 2 ) or alcohol foam.<br />
Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.<br />
Hazardous Combustion Products: Excessive heat may produce hazardous decomposition products.<br />
Part 1: Carbon dioxide, carbon monoxide, and oxides of sulfur.<br />
Part 2: Carbon dioxide, carbon monoxide, and oxides of sulfur.<br />
Working Solution: Oxides of sulfur.<br />
Unusual Fire and Explosion Hazards: None Flash Points: See section 9<br />
Product Name: 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong> - Catalog Number: 262889-2 Page 2 of 5
6. ACCIDENTAL RELEASE MEASURES<br />
Flush to sewer with large amount of water - May require neutralization if pH below 3 or above 12.<br />
Part 1: pH below 12<br />
Part 2: pH 3<br />
Working Solution: pH 10.0 - 10.5.<br />
Otherwise, absorb spill with vermiculite or other suitable absorbent and place in impervious container for disposal in<br />
an approved and permitted landfill.<br />
Clean area thoroughly to remove residual contamination.<br />
7. HANDLING AND STORAGE<br />
Avoid contact with eyes, skin and clothing. Store between 10 - 25 o C (50 - 80 o F).<br />
Protect shipments from freezing (Keep above 4.4 o C (40 o F))<br />
8. EXPOSURE CONTROLS/PERSONAL PROTECTION<br />
Exposure Limits:<br />
ACGIH Threshold Limit Value (TLV)<br />
Hydroquinone: 2 mg/m 3 Ceiling<br />
OSHA Permissible Exposure Limits (PEL)<br />
Hydroquinone: 2 mg/m 3 Ceiling<br />
Potassium Hydroxide: 2 mg/m 3 Ceiling<br />
Engineering Controls: Good general ventilation (10 room volumes per hour) should be sufficient to control<br />
airborne levels below recommended exposure limits when product is used as intended.<br />
If product is used in any other manner local exhaust ventilation may be necessary to control any air contaminants, to within<br />
their TLV's during the use of this product.<br />
Eye Protection: Chemical splash goggles or face shield.<br />
Skin Protection: Nitrile rubber gloves suitable for Parts 1, 2 & Working Strengths Solutions.<br />
9. PHYSICAL AND CHEMICAL PROPERTIES<br />
Part 1 Part 2 Working Solution<br />
Physical State liquid liquid liquid<br />
Color colorless to brown yellow yellow/brown<br />
Odor none slight slight<br />
Specific Gravity 1.3 1.1 1.1<br />
pH 10.6 3 10 - 10.5<br />
Solubility in<br />
Water complete complete complete<br />
Flash Point none none none<br />
Vapor density, vapor pressure, evaporation rate, boiling point and odor threshold levels not known.<br />
10. STABILITY AND REACTIVITY<br />
Stability: All solutions stable under normal ambient and anticipated storage and handling conditions of temperature and<br />
pressure.<br />
Product Name: 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong> - Catalog Number: 262889-2 Page 3 of 5
Incompatibility:<br />
Part 1: Strong oxidizing agents and acids.<br />
Part 2: Strong reducing agents and strong bases.<br />
Working Solutions: Strong acids<br />
Hazardous Decomposition Products:<br />
Part 1: Sulfur dioxide<br />
Part 2: Carbon dioxide, carbon monoxide and oxides of sulfur.<br />
Working Solution: Oxides of sulfur.<br />
Hazardous Polymerization: Will not occur with any solution.<br />
11. TOXICOLOGICAL INFORMATION<br />
Eye effects:<br />
Part 1: Causes irritation.<br />
Part 2: Causes irritation.<br />
Working Solution: Causes irritation<br />
Skin effects:<br />
Part 1: Causes irritation - May cause allergic skin reaction.<br />
Part 2: Causes irritation - May cause allergic skin reaction.<br />
Working Solution: Causes irritation - May cause allergic skin reaction.<br />
Oral effects:<br />
Part 1: Harmful if swallowed. May cause irritation of the gastrointestinal tract.<br />
Part 2: Harmful if swallowed. May cause burns of the gastrointestinal tract.<br />
Working Solution: May cause irritation of the gastrointestinal tract.<br />
Inhalation effects:<br />
Part 1: May causes irritation.<br />
Part 2: May Causes irritation.<br />
Working Solution: None known<br />
None of the components of these solutions are listed by IARC, NTP or OSHA as a carcinogen.<br />
Other Teratogenicity, mutagenicity effects or toxicologically synergistic products: not known.<br />
12. ECOLOGICAL INFORMATION<br />
Summary: These solutions have pH's (see Section 9) that may cause adverse environmental effects.<br />
Once neutralized and diluted these effects will be lessened substantially.<br />
Aquatic Toxicity:<br />
Part 1: Hydroquinone - 96 hr LC-50 (fathead minnow) 0.044 - 0.18 mg/l<br />
Potassium Hydroxide - 96 hr TLm 10 - 100 mg/l<br />
Part 2: None listed<br />
13. DISPOSAL CONSIDERATIONS<br />
Discharge, treatment, or disposal may be subject to certain government regulations. See<br />
Section 6 - Accidental Release Measures<br />
14. TRANSPORTATION INFORMATION<br />
DOT: Not Regulated<br />
Product Name: 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong> - Catalog Number: 262889-2 Page 4 of 5
15. REGULATORY INFORMATION<br />
Chemicals subject to the reporting requirements of Section 313 of Title lll of the Superfund Amendments and<br />
Reauthorization Act (SARA) of 1986 and 40 CFR Part 372:<br />
Hydroquinone<br />
16. OTHER INFORMATION<br />
Prepared by: SourceOne Healthcare Technologies, Mentor, OH 44060 Phone Number: (440) 701-1200<br />
Product Name: 3-7-<strong>90</strong> <strong>Type</strong> S-2 <strong>Developer</strong> - Catalog Number: 262889-2 Page 5 of 5
Change language