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© P. Stroppa/<strong>CEA</strong> © Artechnique/<strong>CEA</strong><br />

8<br />

4<br />

AROUND<br />

THE WORLD<br />

/// Global Nuclear Energy Partnership<br />

/// ESARDA Conference<br />

/// President of the Chinese Academy<br />

of Sciences visits the <strong>CEA</strong><br />

/// Speech on Nuclear Power in<br />

European Parliament<br />

/// Start of construction work for JHR<br />

16<br />

24<br />

SCIENTIFIC<br />

HIGHLIGHTS<br />

ADVANCED<br />

PARTITIONING<br />

SOLUTIONS FOR<br />

RADIOACTIVE WASTE<br />

/// Review of 15 years of research<br />

/// Partitioning<br />

/// 2006: the new law<br />

NANOSCIENCES<br />

UNDERSTANDING THE<br />

NEW LAWS OF PHYSICS<br />

/// Nanostructured matter<br />

/// Quantum effects<br />

/// How are nano-objects designed?<br />

/// The toxicity of nano-objects<br />

/// MINATEC ®<br />

/// Dynamics of the Earth’s<br />

magnetic field reproduced<br />

in laboratory<br />

/// XEDIX : 100 TB of<br />

data screened<br />

© P. Stroppa/<strong>CEA</strong> © <strong>CEA</strong>/Lesénechal<br />

/// Atlas, accelerating<br />

detection<br />

/// First complete simulation<br />

of PET imaging scan<br />

/// Superdoped silicon:<br />

an excellent conductor<br />

<strong>CEA</strong> <strong>News</strong> is edited by the French Atomic Energy Commission – Communication<br />

Division – Headquarters – 91191 Gif-sur-Yvette cedex - France - www.cea.fr<br />

Publication Director: Xavier Clément<br />

Contributors to this edition: Claire Abou, Anne-Marie Birac, Patrick Cappe de Baillon,<br />

Olivier Caron, Xavier Clément, Elisabeth De Lavergne, Thierry Ethvignot,<br />

Didier Kechemair, Florence Klotz, Lucia Le Clech, Brigitte Raffray<br />

ceanews.contact@cea.fr<br />

Graphic design: MAYA press - www.mayapress.net<br />

Cover photo: Carbon nanotube models in front of a nanotube “mat” viewed<br />

under the microscope. © <strong>CEA</strong><br />

30<br />

BOOK REVIEW<br />

31 EXHIBITIONS<br />

<strong>CEA</strong> NEWS 2 September <strong>2007</strong>


FOREWORD<br />

Nuclear Energy’s Responsible,<br />

Sustainable Future<br />

© L.Godart/<strong>CEA</strong><br />

Welcome to this second issue of <strong>CEA</strong> NEWS, the international publication of the French<br />

Atomic Energy Commission. <strong>CEA</strong> is committed to providing in-depth but wide ranging<br />

coverage of its activities ands achievements. We hope that this issue conforms to this goal.<br />

Since our last issue, momentous events have taken place in our country including the<br />

election of a new administration and the establishment of a new government. One of the<br />

new government’s priorities is a determined undertaking to expand the research effort in<br />

our country and to reform the governance and operations of universities. We at <strong>CEA</strong><br />

welcome this development, which corresponds to our deeply held view that partnership<br />

with a strong and reactive academic sector can only be of benefit to an institution such as<br />

ours, that thrives on cross-fertilization with our domestic and international partners in<br />

both the academic and industrial sectors. We are all the more convinced that our mission<br />

is to contribute to the building of the knowledge-based, high-valued added economy that<br />

must rest on a deliberate as well as unrelenting effort in both fundamental and applied<br />

research. This, one might add, is also a key to nurturing the international partnerships that<br />

we at <strong>CEA</strong> value as a core component of our strategy.<br />

Mr. Olivier Caron<br />

Director of International Relations<br />

In the field of energy, which remains at the forefront<br />

of our priorities, <strong>CEA</strong> is committed to partaking in<br />

national and international efforts and undertakings<br />

that will foster the responsible and sustainable drive<br />

toward expanded recourse to nuclear energy. If we<br />

are to offer humanity reliable and cost-effective access<br />

to this energy source, it is of prime import that new<br />

nuclear programmes – as well as mature or<br />

expanding ones – adopt or continue to uphold the<br />

highest safety and spent fuel management standards.<br />

It is an economic requirement as well as a civic duty<br />

and moral responsibility to see to it that nuclear<br />

expansion does not result in the unwarranted<br />

accumulation and dissemination of spent fuels. A<br />

fundamental rethink of security and nonproliferation<br />

tenets are in order to address this<br />

challenge successfully. We in France pride ourselves<br />

on having pioneered an approach to the fuel cycle<br />

that is precisely geared toward rising up to the<br />

magnitude of the issue. And we are glad to see that<br />

our major international partners are now willing to<br />

reengage on the closed fuel cycle issue. This is a<br />

heartening testimony to the virtues of patient and<br />

steadfast policy development, based on confidence in<br />

science and an acute awareness of the need to engage<br />

public opinion and policy-makers. On this optimistic<br />

note, I invite you to enjoy agreeable and thoughtprovoking<br />

reading while awaiting our next issue. ■<br />

<strong>CEA</strong> NEWS 3 September <strong>2007</strong>


AroundTheWorld<br />

Global Nuclear Energy Partnership – Joint statement<br />

by France, China, Japan, USA and Russia<br />

Representatives of five nations (France, China,<br />

Japan, USA and Russia) and the International<br />

Atomic Energy Agency (IAEA) were invited<br />

by Samuel Bodman, US Secretary of Energy<br />

to a Ministerial Conference on the Global<br />

Nuclear Energy Partnership (GNEP) in<br />

Washington on May 21, <strong>2007</strong>. The French<br />

delegation was led by Alain Bugat, Chairman<br />

of the <strong>CEA</strong>. A joint statement was issued at<br />

the end of the conference.<br />

The GNEP is a US initiative to kick-start nuclear energy once<br />

again. On a domestic level, it aims to close off the fuel cycle and<br />

ensure large-scale reprocessing of spent fuel. Its international<br />

aims are to prevent the spread of technology that has proliferation<br />

potential, to seek partnerships with<br />

countries wishing to access nuclear<br />

energy and to increase its use. The<br />

goal is to offer spent fuel reprocessing<br />

and recycling solutions without<br />

requiring domestic facilities to be<br />

built. This will complement the<br />

IAEA's efforts to fine-tune its preproduction<br />

fuel service supply<br />

guarantee mechanisms.<br />

Research and development into advanced cycle technologies<br />

and fast reactors to burn actinides is also a subject of consultation<br />

and coordination as part of the Generation IV International<br />

Forum (GIF), currently chaired by France.<br />

© A. Gonin/<strong>CEA</strong><br />

SECURITY AND NON-PROFILERATION<br />

<strong>CEA</strong> and IRSN at the ESARDA conference<br />

The <strong>CEA</strong> and IRSN both took part in the 29 th conference of ESARDA, the European<br />

Safeguards Research & Development Association from May 22 to 24 in Aix-en-Provence.<br />

This association was established in 1969 and draws together research laboratories,<br />

industrial operators, inspection bodies and government ministers from the member<br />

states of the European Union. ESARDA's goal is to facilitate R&D cooperation between<br />

the various players involved in nuclear material security controls.<br />

Around three hundred experts in the field of nuclear security and non-proliferation met<br />

for three days to review the control of nuclear materials in the European Union and<br />

around the world.<br />

Representatives of organizations such as the IAEA 1 , ABACC 2 and INMM 3 are regular<br />

participants. Olli Heinonen, Deputy Director General of the IAEA, Roland Schenkel,<br />

Director General of the Joint Research Centre (JCR – European Commission) and<br />

Dominique Ristori, Deputy Director General of the Directorate-General for Energy<br />

and Transport (DGTREN – European Commission) all spoke at the conference.<br />

Olivier Caron, <strong>CEA</strong> Director of International Relations and France's governor on the<br />

IAEA board, spoke about French policies in the areas of nuclear security and compliance<br />

with international treaties. Emmanuel Sartorius, Senior Defence and Security Official<br />

in charge of domestic control of nuclear materials, spoke about control issues in France.<br />

Video tracking : A digital camera may be attached to the radiation monitor for video capture and identification.<br />

1. IAEA: International Atomic Energy Agency, responsible for the NPT inspection provisions.<br />

2. ABACC: Brazilian- Argentine Agency for Accounting and Control of nuclear materials (regional control agency).<br />

3. INMM : Institute of Nuclear Materials Management (USA).<br />

Two types of controls apply to nuclear<br />

materials in Europe: first, security<br />

controls as instituted by the Euratom<br />

Treaty (effective since 1958), and second,<br />

nuclear weapons non-proliferation<br />

controls (NPT, effective since 1970). The<br />

inspection provisions in both treaties<br />

cover the full range of controls in order<br />

to ensure that members comply with<br />

nuclear proliferation restraints. The<br />

association's work brings the field's<br />

many experts and practitioners together<br />

to discuss relevant general topics and<br />

detailed issues that relate to particular<br />

types of nuclear facilities. The<br />

association also promotes discussion<br />

with nuclear operators and researchers<br />

to facilitate cooperation in the area of<br />

international controls, thus ensuring that<br />

treaties are applied as comprehensively<br />

as possible and that new control<br />

technologies continue to be developed.<br />

<strong>CEA</strong> NEWS 4 September <strong>2007</strong>


AroundTheWorld<br />

A NEW FRANCO-CHINESE PARTICLE<br />

PHYSICS LABORATORY<br />

Alain Bugat, Chairman of the <strong>CEA</strong>,<br />

Catherine Bréchignac, President of the<br />

CNRS, Arnold Migus, Director General<br />

of the CNRS and Lu Yongxiang,<br />

President of the Chinese Academy<br />

of Sciences, have inked an agreement<br />

to set up a Franco-Chinese international<br />

associate particle physics laboratory,<br />

the France-China Particle Physics<br />

Laboratory (FCPPL). This agreement<br />

formalises a longstanding partnership<br />

between France and China in this field,<br />

officially recognising the joint work of<br />

more than 250 researchers, engineers<br />

and students from the two countries.<br />

The France-China Particle Physics<br />

Laboratory (FCPPL) has been set up<br />

as part of a key strategy of the CNRS<br />

IN2P3 organization (French national<br />

institute for nuclear and particle<br />

physics), consolidating its links with<br />

various Asian countries over the last<br />

two years. The institute works with<br />

Japan, South Korea, Vietnam, and<br />

particularly with China's rapidly<br />

expanding research sector. Several<br />

dozen scientists in France and China<br />

are already collaborating to study<br />

particle physics, astroparticles and<br />

cosmology.<br />

This agreement sets up a framework<br />

for establishing a genuine Franco-<br />

Chinese scientific community, with joint<br />

management, a joint steering committee<br />

and regular conferences. Many Chinese<br />

researchers have already been hosted<br />

by French laboratories, and the program<br />

will also allow French researchers to<br />

work in Chinese laboratories.<br />

Bilateral cooperation between <strong>CEA</strong> and Slovenia:<br />

Call for projects<br />

A second call for projects has been issued under the agreement executed on<br />

March 27, 2006 between the <strong>CEA</strong> and the Slovenian Minister for Higher Education,<br />

Science and Technology. The topics selected for <strong>2007</strong> are the following: life sciences,<br />

new energy technologies (fuel cells, biomass, etc.), new materials (catalytic materials,<br />

nanomaterials, etc.), nuclear energy (material ageing, etc.) and lasers.<br />

The goal of these one-year projects is to strengthen relations between the <strong>CEA</strong><br />

and Slovenian laboratories and to establish new joint ventures. This agreement<br />

provides an official framework for the work already in progress with the Republic<br />

of Slovenia. It shows the way to new areas for cooperation and strengthens<br />

current partnerships by contributing to the structures of European bilateral<br />

nuclear research in the context of the 7 th Framework Programme.<br />

The projects to receive backing were chosen on July 10, <strong>2007</strong> as part of the<br />

second Sterling Committee meeting that was held in Marcoule.<br />

© P. Stroppa/<strong>CEA</strong><br />

P hysics<br />

New scientific<br />

interest group –<br />

“Physics of the<br />

two infinities”<br />

Man has always sought to answer fundamental<br />

questions on the origins and evolution of<br />

the Universe. What is it made up of? What are<br />

the basic laws that govern it? What is its future?<br />

Pushing back the boundaries of knowledge<br />

and technology in these areas requires deeper<br />

investigation into phenomena occurring both<br />

on an infinitely small scale (elementary particles<br />

and quantum mechanics) and an infinitely<br />

large scale (cosmology and general relativity).<br />

These fascinating and closely related physics<br />

fields are the focus of the scientific interest<br />

group “Physics of the two infinities” (P2i) which<br />

was officially launched on 30 March <strong>2007</strong> and<br />

draws together 19 laboratories at the CNRS<br />

(National Centre for Scientific Research), <strong>CEA</strong><br />

(Atomic Energy Commission), the Paris<br />

Observatory and various higher education<br />

bodies (Pierre and Marie Curie University<br />

Paris 6), Paris Diderot University (Paris 7),<br />

Paris-Sud University (Paris 11) and the École<br />

Polytechnique.<br />

P2i has set itself the goals of achieving<br />

international recognition, increasing<br />

coordination in research and boosting the<br />

dynamism and resources of teams working in<br />

subatomic physics and cosmology in the Paris<br />

region. Particle physicists, nuclear physicists,<br />

theorists and astrophysicists will pool their<br />

equipment as part of the consortium. The aim<br />

is also to promote<br />

skill-sharing in order<br />

to tackle the major<br />

scientific challenges<br />

laid down by<br />

nature, such as the<br />

exploration of dark<br />

matter and dark<br />

energy, which are<br />

poorly understood,<br />

but together account<br />

for more than 95%<br />

of the Universe's<br />

energy density.<br />

© <strong>CEA</strong>/Dapnia<br />

<strong>CEA</strong> NEWS 5 September <strong>2007</strong>


AroundTheWorld<br />

© D.Marchand/<strong>CEA</strong><br />

Lu Yongxiang,<br />

President of the Chinese<br />

Academy of Sciences,<br />

visits the <strong>CEA</strong><br />

During his trip to France, Lu<br />

Yongxiang, President of the<br />

Chinese Academy of Sciences 1<br />

and Vice-Chairman of the People's<br />

National Congress visited <strong>Saclay</strong><br />

on April 11, <strong>2007</strong>. He was<br />

received by Yves Caristan, Director<br />

of Physical Sciences, André Syrota,<br />

Director of Life Sciences and<br />

Olivier Caron, Director of<br />

International Relations, and was<br />

shown the latest developments<br />

in the <strong>CEA</strong>'s work, witnessing at<br />

first hand the dynamic working<br />

environment at <strong>Saclay</strong>. Mr. Lu's<br />

visit included Soleil, the<br />

third generation synchrotron<br />

inaugurated last December, and<br />

NeuroSpin, the new intense-field<br />

nuclear magnetic resonance<br />

cerebral imaging (MRI) center.<br />

He then had a meeting with<br />

Bernard Bigot, High Commissioner<br />

for Atomic Energy.<br />

During the visit, <strong>CEA</strong> Chairman<br />

Alain Bugat signed two agreements<br />

on behalf of the <strong>CEA</strong> in the<br />

presence of Zhao Jinjun, Chinese<br />

Ambassador to France. The first<br />

was an agreement to set up an<br />

international associate laboratory<br />

involving the <strong>CEA</strong>, CNRS and the<br />

Chinese Academy of Sciences<br />

focusing on high-energy physics,<br />

and the second was an<br />

amendment to the agreement<br />

between the <strong>CEA</strong> and the Chinese<br />

Academy of Sciences on cosupervision<br />

of research projects.<br />

Mr. Lu emphasized the importance<br />

of the <strong>CEA</strong>'s collaboration to the<br />

Chinese Academy of Sciences, and<br />

described it as strategic. He<br />

suggested instituting a yearly forum<br />

to promote exchange between<br />

researchers from the two bodies.<br />

1. The Chinese Academy of Sciences is<br />

China's largest national research<br />

organization, with 58,000 staff.<br />

Start of<br />

construction work<br />

for Jules Horowitz<br />

research reactor<br />

Construction work on the Jules Horowitz research reactor<br />

(JHR) was launched by François Loos, Minster for Industry,<br />

on March 19, <strong>2007</strong>. Other figures who attended the ceremony,<br />

along with 500 other guests, included <strong>CEA</strong> Chairman Alain<br />

Bugat, Philippe Pradel, <strong>CEA</strong> Director of Nuclear Energy,<br />

Serge Durand, Director of the Cadarache research site and<br />

representatives of French industrial partners such as EDF<br />

and Areva.<br />

The goal of the Jules Horowitz Reactor is to develop and test<br />

new fuels and materials to be used in production reactors<br />

now and in the future, with a particular focus on Generation IV.<br />

In addition to the applications for power production, JHR<br />

will supply 25% of Europe's requirements for radioelements<br />

used in nuclear medicine and could contribute to the<br />

production of high-performance silicon<br />

for industrial and electronic<br />

components. The reactor is due<br />

for commissioning in 2014.<br />

©<strong>CEA</strong><br />

S ynergies<br />

New “Climate-Environment-Society” scientific interest group<br />

The newly established “Climate-Environment-<br />

Society” is a joint venture between the CNRS,<br />

<strong>CEA</strong>, the École Polytechnique, University<br />

of Versailles Saint-Quentin-en-Yvelines,<br />

University Pierre and Marie Curie and<br />

ADEME 1 . Its goal is to synergize experts’ skill<br />

sets to study climate change and its<br />

consequences for society and the environment.<br />

It will create solid links between researchers in complementary disciplines<br />

– climatology, ecology, medicine, economics and the social sciences –<br />

and promote the emergence of a more precise description of the<br />

interactions between climate change and future societal choices.<br />

The work will focus on the coordinated<br />

development of climate models, observation<br />

systems and tools for effecting change on<br />

the interfaces between climate and society.<br />

With the support of the Minister for Higher<br />

Education and Research and the Minister of<br />

Ecology and Sustainable Development, the<br />

research group will enjoy international stature,<br />

attracting foreign researchers and organizing conferences and<br />

communication campaigns.<br />

http://gisclimat.ipsl.jussieu.fr/<br />

1. The French Environment and Energy Management Agency<br />

© P. Bazoge/ <strong>CEA</strong><br />

<strong>CEA</strong> NEWS 6 September <strong>2007</strong>


AroundTheWorld<br />

© DR<br />

European Parliament:<br />

Speech by Oliver Caron<br />

on Nuclear Power<br />

Olivier Caron, <strong>CEA</strong> Director of<br />

International Relations and France's<br />

governor on the IAEA Board was<br />

invited to speak the European Energy<br />

Forum 1 , a discussion group led by<br />

British MEP Giles Chichester, former<br />

Chairman of the European Parliament<br />

ITRE Committee 2 .<br />

Mr. Caron's speech focused on the<br />

worldwide renewal of interest in<br />

nuclear energy. He described the<br />

world's current energy challenges<br />

(securing supply, combating climate<br />

change, remaining competitive) and<br />

demonstrated the vital place of this<br />

energy source. He highlighted the<br />

encouraging fact that discussions are<br />

underway within European<br />

institutions to develop a<br />

comprehensive energy policy across<br />

the European Union.<br />

After the speech, a discussion that<br />

included the fifteen or so MEPs in<br />

attendance (including representatives<br />

of the EU’s new member states)<br />

confirmed Parliament's interest in<br />

energy issues, including nuclear<br />

power in particular. There were<br />

discussions between the Committee<br />

and various MEPs on the question<br />

of nuclear safety and the requirement<br />

laid down during accession<br />

negotiations that some power stations,<br />

particularly in Bulgaria, be shut down.<br />

The issue of waste was brought up<br />

repeatedly. Mr. Caron took the<br />

opportunity to explain that technical<br />

solutions do exist and, referring to<br />

the French process, showed that waste<br />

processing is now an issue for political<br />

decision-making.<br />

1. More info:<br />

http://www.europeanenergyforum.eu/<br />

2. Industry, Telecoms, Research et Energy.<br />

FRANCO-JAPANESE DISCUSSIONS ON STORAGE<br />

The 5 th “information exchange” between EDF, <strong>CEA</strong> and CRIEPI (Japanese Central<br />

Research Institute of Electric Power Industry) was held in the Tokyo suburb of Abiko.<br />

Hervé Lagrave, high-level radwaste storage manager and Guillaume Ranc, expert in<br />

concrete structures, presented the most recent results from the Department of Fuel<br />

Cycle Technology on spent fuel storage, chiefly<br />

focusing on heat and air flows within storage<br />

facilities, the mechanical behavior of structures at<br />

temperature and the confinement of containers during<br />

accidents (earthquake or drop accident). These joint<br />

ventures should all be validated at the Management<br />

Committee meeting in September <strong>2007</strong>. The trip also<br />

provided an opportunity to visit the Abiko center’s laboratories, which are working on<br />

seal testing, dynamic characterization of concrete and chloride source terms; the<br />

Akagi site, looking at heating within concrete containers, metal container drop<br />

accidents and the transmission and use of electricity; the JAPC spent fuel dry<br />

storage facility and the Tokai-Daini Electricity museum.<br />

© Champion/<strong>CEA</strong><br />

7 th European<br />

Framework<br />

Program for<br />

Research and<br />

Development<br />

The 7 th Framework Program was officially launched<br />

on December 22, 2006 and is the main research<br />

funding instrument for the period <strong>2007</strong>-2013. “Its<br />

goal is to consolidate the European Research Area,”<br />

points out Claude Ayache, Director for European<br />

Affairs (<strong>CEA</strong>'s International Relations Division),<br />

“and it follows directly in the footsteps of the previous<br />

framework program. There is a concerted focus on<br />

a limited number of priorities, with coordination at<br />

all levels, among researchers, institutions and State<br />

research policies.The aim is not just to provide funding,<br />

but to continue to structure research throughout<br />

Europe research.” Nevertheless, new ambitions<br />

are set out in the 7 th framework programme for<br />

research and development, both in financial and<br />

political terms. The budget is up by a yearly<br />

average of 60% compared with the 6 th framework<br />

program, with a total envelope of € 54.5 billion<br />

over the period <strong>2007</strong>-2013. There are new<br />

challenges on the research side too. “The biggest<br />

of the challenges,” says Mr. Ayache, “is setting up<br />

the European Research Council. The aim is to promote<br />

scientific excellence by funding very high-level research,<br />

pushing back the boundaries of knowledge. Establishing<br />

exploratory research as a major factor for future<br />

competitiveness is a first within the European<br />

Community. Other new aspects of the 7 th framework<br />

program include a boost for industrial collaborations,<br />

with new forms of public-private partnerships,<br />

European Technology Partnerships and Joint<br />

Technology Initiatives (JTIs). Finally, there are two<br />

new research priorities, security and space.”<br />

TWO NEW <strong>CEA</strong> COUNSELORS IN EUROPE:<br />

- Alain Régent in London<br />

- Claude Sainte-Catherine in Helsinki<br />

Pierre-Yves Cordier replaces Dominique Ochem<br />

after his four-year stint, in Tokyo<br />

Please refer to the back cover for contact information.<br />

<strong>CEA</strong> NEWS 7 September <strong>2007</strong>


NANOSCIENCES<br />

UNDERSTANDING<br />

Stimulated by the<br />

race towards<br />

miniaturization in<br />

the microelectronics<br />

industry, research<br />

in Nanosciences is<br />

conducted at two<br />

departments within<br />

the Physical<br />

Sciences Division:<br />

the Drecam 1 in<br />

<strong>Saclay</strong> and the<br />

DRFMC 2 in Grenoble.<br />

This involves<br />

disciplinary fields at<br />

the crossroads of<br />

Chemistry, Physics<br />

and Biology.<br />

Activities at <strong>Saclay</strong><br />

in the spotlight.<br />

© C. Fuseau/<strong>CEA</strong><br />

NEW LAWS<br />

OF PHYSICS<br />

Scanning<br />

Electron<br />

Microscopy<br />

(SEM) is<br />

among the<br />

tools<br />

frequently<br />

used in<br />

nanoscience.<br />

Trying to manipulate nano-objects,<br />

understanding the behavior of finely<br />

divided matter, exploring quantum<br />

effects: these are some of the<br />

challenges facing fundamental<br />

research in nanosciences.<br />

At the level of atoms and molecules,<br />

there is a whole world to explore:<br />

the nanoworld, christened thus in<br />

reference to the nanometer, a<br />

billionth of a meter. Observing<br />

atoms and molecules individually<br />

became possible at the start of the<br />

1980s thanks to two inventions:<br />

the scanning tunneling microscope<br />

for materials that conduct electricity<br />

and its derivative, the atomic force<br />

microscope for insulating materials.<br />

These instruments are used both<br />

to observe surfaces and to<br />

manipulate atoms or molecules.<br />

Pooling the talents of chemists,<br />

physicists and biologists has played<br />

a decisive role in the creation of<br />

electronic devices and innovative<br />

materials.<br />

<strong>CEA</strong> NEWS 8 September <strong>2007</strong>


© <strong>CEA</strong><br />

TOPICS TO EXPLORE<br />

/// Nanostructured matter<br />

/// Quantum effects<br />

/// How are nano-objects designed?<br />

/// Toxicity of nano-objects<br />

/// MINATEC ®<br />

THE ADVANTAGES OF<br />

NANOSTRUCTURED MATTER<br />

How do the properties of particles change when their dimensions<br />

go from the micrometric to the nanometric scale?<br />

Pilot<br />

installation<br />

of nanopowder<br />

synthesis<br />

using the inflow<br />

pyrolysis<br />

method.<br />

Understanding the effect of size on the<br />

physical or chemical properties of particles<br />

is essential in nanosciences. The particles<br />

can be separated out individually in a powder<br />

state or bonded to solid materials. At the<br />

frontier between science and technology,<br />

researchers are shuttling back and forth<br />

between synthesizing materials, conducting<br />

experiments and performing numerical<br />

simulations and interpretations.<br />

A more radiation-resistant<br />

ceramic<br />

A ceramic is a material obtained by heat<br />

treatment (sintering) from powders generally<br />

of micrometric size. A team specializing in<br />

laser pyrolysis has developed an original<br />

technique for producing chemical composites<br />

in powders of calibrated sizes. According to<br />

recent experiments, ceramics made from<br />

nanometric powders produced in a laboratory<br />

are more resistant to radiation than traditional<br />

ceramics. In both cases, it is possible to<br />

see the grains, separated by grain boundaries,<br />

at different scales. Under the effect of<br />

radiation, defects appear in the crystalline<br />

organization of the grains and tend to merge<br />

until they hit an obstacle: the boundary. It<br />

seems that, in nanostructured ceramics, the<br />

SIZE GUIDE<br />

0.1 nm atom<br />

1 nm molecule<br />

10 nm protein<br />

100 nm DNA<br />

appearance of radiation damage is delayed<br />

because the web of particles is a thousand<br />

times finer. From the “materials” point of<br />

view, these ceramic nanopowders could<br />

be used in the composition of composite<br />

materials for the nuclear reactors of the future.<br />

A larger active surface area<br />

Another example of a divided (or<br />

nanostructured) material is the platinum in<br />

fuel cells. The chemical reactions that produce<br />

the current in the fuel cell are accelerated<br />

(or catalyzed) by this metal when the reagents<br />

“meet”, coming into contact with it. The use<br />

of fine platinum particles makes it possible<br />

to reduce the quantity of metal required.<br />

The size of these particles varies from a<br />

few nanometers to tens of nanometers.<br />

Researchers are proposing to replace them<br />

with particles of a perfectly calibrated size.<br />

A “coating” of organic molecules prevents<br />

the particles from forming clusters and means<br />

that the distance between metal cores can<br />

be finely regulated by the choice of grafted<br />

molecules. From the perspective of<br />

application to fuel cells, the electrical<br />

conductivity of these objects can be optimized<br />

according to their size. The icing on the cake<br />

is that combining these particles with carbon<br />

nanotubes would make the catalysis sites<br />

more accessible to the reagents and improve<br />

efficiency even more.<br />

1. Department of Research on Condensed Matter, Atoms and Molecules<br />

2. Condensed Matter Fundamental Research Department.<br />

A choice of colors<br />

One particular property of semiconductors<br />

is photoluminescence, which provides a<br />

spectacular illustration of the size effect.<br />

When they are lit, these materials give out<br />

some of the energy they receive by emitting<br />

light. The color (or energy) of this light is<br />

determined by the chemical nature and size<br />

of the semiconductor. If the specimen size<br />

is reduced to a few nanometers, there is<br />

constant variation in this color: the energy<br />

of the emitted light increases as the size of<br />

the object decreases. The behavior of the<br />

nanocrystal, also known as a quantum dot,<br />

seems to gradually approach that of an<br />

isolated atom. In particular, silicon<br />

nanocrystals, still produced by laser pyrolysis,<br />

could act as in vivo tracers for the diagnosis<br />

and treatment of diseases.<br />

© A. Gonin/<strong>CEA</strong><br />

> PYROLYSIS: chemical decomposition<br />

through the action of heat alone.<br />

© <strong>CEA</strong><br />

<strong>CEA</strong> NEWS 9 September <strong>2007</strong><br />

© Artechnique/<strong>CEA</strong>


NANOSCIENCES<br />

OBSERVING AND USING<br />

QUANTUM EFFECTS<br />

On the scale of atoms, electrons and photons, interactions<br />

between these entities are governed by quantum physics.<br />

This opens up new perspectives for nano-objects.<br />

© F. Vigouroux/<strong>CEA</strong><br />

© <strong>CEA</strong><br />

As one of the dimensions of a device<br />

approaches the size of an atom, the quantum<br />

effects inherent in microscopic physics appear.<br />

They are apparent, most notably, through<br />

discontinuous energy transfers, in “packets”<br />

known as quanta. These phenomena, invisible<br />

on a large scale, open up potentially very<br />

interesting paths for exploration. This is why<br />

researchers are making an effort to observe<br />

and use quantum effects in reasonably “large”<br />

experimental devices.<br />

WHAT IS<br />

A QUANTUM STATE?<br />

Much more than a binary piece of<br />

information, a “quantum state” is defined<br />

as a set of several simultaneously possible<br />

situations, each with a very specific<br />

probability of occurrence. An experimental<br />

measurement fixes the quantum state in a<br />

single one of these situations. To evaluate<br />

the probability attached to the situation, the<br />

measurement has to be repeated a very<br />

large number of times.<br />

Playing with electron spin<br />

Giant magnetoresistance (GMR) manifests<br />

itself as an increase in electricity conduction<br />

in an electronic device when a magnetic field<br />

is applied to it. This effect is explained on<br />

a quantum scale by electron spin, the<br />

electron's intrinsic rotation.<br />

The device consists of an assembly of two<br />

layers of metal with different magnetisms,<br />

separated by a very thin insulating layer<br />

(of the order of a nanometer). In one of<br />

the magnetic layers, the spin of the electrons<br />

is fixed by the prior state of magnetization<br />

of the material and in the other, it is subject<br />

both to the coupling with the first layer and<br />

to an external magnetic field. The degree<br />

of resistance to the passage of current, which<br />

acts as a sensor, depends on the electron spin<br />

configuration in the layers it is crossing: there<br />

is less resistance when the magnetizations<br />

are aligned than when they are opposed.<br />

GMR can be used to read (and write)<br />

information in the first magnetic layer or<br />

to measure a magnetic field.<br />

Discovered in 1998, GMR is today used<br />

on an industrial scale in the hard disks of<br />

our computers. The property is also exploited<br />

in highly sensitive sensors, one of which<br />

should be able to detect magnetic fields as<br />

tiny as those resulting from neuron activity.<br />

Regulating the electron ballet<br />

How do you describe the passage of an electric<br />

current through a metal conductor? Imagine<br />

a set of relays in which an atom (for instance<br />

copper) “gives” one of its electrons to a<br />

neighboring atom and “receives” another in<br />

>>><br />

“<br />

Our collaboration<br />

with companies in<br />

many sectors, and<br />

these applications, are<br />

nurturing the most<br />

fundamental research<br />

into magnetism.<br />

”<br />

© Artechnique/<strong>CEA</strong><br />

Myriam Pannetier-Lecœur<br />

Physical Sciences<br />

Division/Drecam/<strong>Saclay</strong><br />

Measurement<br />

set devoted to<br />

studying spinpolarized<br />

currents in<br />

magnetic<br />

nanostructures.<br />

<strong>CEA</strong> NEWS 10 September <strong>2007</strong>


Fundamental research<br />

experiment on magnetism<br />

based on giant<br />

magnetoresistance<br />

ELECTRONS<br />

TO SEE THE NANOWORLD<br />

MICROSCOPES THAT<br />

CAN “SEE” ATOMS<br />

AND MOLECULES<br />

How do we “see” the atoms and molecules<br />

in a solid individually? The “eye” of these<br />

microscopes is a tip that scans the surface<br />

to be analyzed by gliding over it at a fixed<br />

height of the order of a few atom<br />

diameters (a few tenths of a nanometer).<br />

This distance is adjusted by very shortrange<br />

interactions between the last atom<br />

right on the tip and the surface.<br />

Microscope resolution is limited by the diffraction<br />

of light crossing the specimen. This becomes<br />

even more of a problem as the wavelength of the<br />

light increases. Hence the idea of replacing<br />

photons with electrons, which have a shorter<br />

wavelength. In transmission electron microscopy<br />

(TEM), a flow of electrons is passed through the<br />

specimen and detected to form the image.<br />

Resolution can go below a nanometer.<br />

Meanwhile, the scanning electron microscope<br />

(SEM) uses secondary electrons emitted by the<br />

specimen when it is bombarded with electrons,<br />

on the same side as the source. This time the<br />

resolution is of the order of a nanometer.<br />

“<br />

With the benefit of experience,<br />

theoretical formalism has been pushed<br />

out in favor of intuition and inventiveness.<br />

© C. Dupont/<strong>CEA</strong><br />

Christian Glattli<br />

Physical Sciences Division/Drecam/<strong>Saclay</strong><br />

”<br />

© <strong>CEA</strong>-LEM<br />

In the scanning tunneling microscope (STM)<br />

this interaction, quantum in nature, is<br />

manifested by a weak electric current that<br />

flows between the atom on the tip and the<br />

surface. This current rapidly increases as the<br />

tip gets closer to the surface. In the atomic<br />

force microscope (AFM), similar forces to<br />

those that make atoms bond in a molecule<br />

are at work between the atom on the tip and<br />

the atoms on the surface. At even shorter<br />

distances, forces of repulsion predominate<br />

between the atomic nuclei. Subject to these<br />

antagonistic forces, the atom spontaneously<br />

tries to remain at a fixed distance.<br />

In both cases, a computer records either<br />

the current or the force, and keeps the tip<br />

at a constant distance from the surface. The<br />

relief “felt” by the tip can be reconstituted<br />

in this way with resolution of less than a<br />

nanometer, giving the user an atom-byatom<br />

picture of the material being studied.<br />

return. Under normal conditions, electrons<br />

barely move more than about thirty nanometers<br />

before experiencing a collision that “erases”<br />

their quantum effects. To observe the effects,<br />

it is necessary to reduce the number of<br />

collisions or to thin out the electron population<br />

and extend the free trajectory of the electrons.<br />

This is why some researchers have chosen<br />

to study the interface between two<br />

semiconducting layers 1 , working at very low<br />

temperatures to attenuate the thermal agitation<br />

of the atoms. The electrons can therefore<br />

spread out almost freely in a plane, typically<br />

over about ten thousand nanometers. The<br />

apparatus also has electrodes that control<br />

the opening of a passage for the electrons, a<br />

few hundred nanometers wide.<br />

What is observed? As the passage opens, the<br />

conductance of the system, i.e. its ability to<br />

conduct current, increases in steps! These<br />

steps correspond to the multiples of a<br />

fundamental constant known as a conductance<br />

quantum – another quantum effect! These<br />

effects can also be seen in metals when two<br />

electrodes are linked by just one or more<br />

atoms. What is even more extraordinary is<br />

that the phenomenon generates almost no<br />

spurious background noise! These “new”<br />

laws apply to nanocomponents such as carbon<br />

nanotubes, which transmit four conductance<br />

quanta – no more and no less…<br />

1. Made from gallium arsenide (AsGa) and gallium arsenide<br />

and aluminum (AsGaAl) respectively. The density of<br />

moving electrons is governed by the dopant concentration.<br />

<strong>CEA</strong> NEWS 11 September <strong>2007</strong>


NANOSCIENCES<br />

HOW ARE NANO-OBJECTS DESIGNED?<br />

The carbon nanotube, the material most emblematic of the nanosciences,<br />

is “coated” with molecules to massively increase its powers.<br />

The discovery of the carbon nanotube in<br />

1991 opened up a vast field of study in<br />

nanoelectronics. It is a long cylinder made<br />

from one or more rolled up sheets of carbon.<br />

The diameter of a carbon nanotube varies<br />

from a few nanometers for single-sheet tubes<br />

to about a hundred nanometers for those<br />

made from multiple sheets. What are their<br />

benefits? They are easily mass-produced<br />

to the point of becoming a commercial<br />

product. With a particular geometry, they<br />

can be semiconductors. Being much more<br />

stable than isolated molecules, they are easy<br />

to connect to electrodes. In 1998, the first<br />

transistor made with carbon nanotubes<br />

appeared.<br />

We will now look at some of the stages in<br />

the fabrication of nano-objects from carbon<br />

nanotubes.<br />

be highly practical for many types of<br />

manipulation. First it is necessary to “graft”<br />

organic molecules onto the nanotube that<br />

are capable of clinging to the nanotube's<br />

carbon atoms on the one hand, and giving<br />

it the required solubility properties on the<br />

other. One technique is to render soluble<br />

only the semiconductor nanotubes, so they<br />

can be sifted out. Once they are in a solution,<br />

the nanotubes can be diluted to obtain the<br />

desired rate of deposit on a surface.<br />

Molecular “coatings”:<br />

endless creativity<br />

It is now possible to “coat” the nanotubes,<br />

which simply means depositing molecules<br />

on their surface, attaching them solidly to<br />

the carbon atoms, or even inserting them<br />

inside the cylinders.<br />

The “coating” can make it possible for the<br />

nanotube to attach to a prepared surface, a<br />

bit like Velcro ® . More generally, combining<br />

nanotubes with molecules with specific<br />

electronic and optical properties is at the<br />

heart of research into molecular electronics.<br />

Nanotubes and DNA<br />

Some researchers are working on combining<br />

nano-objects such as DNA strands with<br />

carbon nanotubes to make T-shaped<br />

structures similar to those of a transistor.<br />

A kind of molecular Scotch ® tape needs to<br />

be devised to bind the nanotube and DNA<br />

together using real chemical bonds. In this<br />

case, nanotubes are being used because of<br />

their ability to be connected to electrodes.<br />

DNA could also be used as a “pattern” to<br />

guide the spontaneous assembly of carbon<br />

nanotube structures, along the same lines<br />

as biological processes.<br />

© <strong>CEA</strong><br />

Self-assembled carbon nanotubes on a surface of<br />

functionalized silica, connected electronically via gold wires.<br />

Preparing the bare nanotubes<br />

The first challenge is sorting the bare<br />

nanotubes, because they are a mixture of<br />

metallic objects and semiconductors. The<br />

second is that nanotubes are not soluble, so<br />

in their ordinary state they cannot be<br />

incorporated into a solvent, which would<br />

© Motorola/<strong>CEA</strong><br />

FROM NANOTUBES<br />

TO NANORINGS<br />

It sometimes happens that the<br />

unexpected texture of the<br />

chemical “coatings” of nanotubes<br />

inspires researchers, leading to<br />

the creation of some surprising<br />

nano-objects – nanorings, for<br />

example! Observation of ring<br />

structures under a transmission<br />

electron microscope led them to<br />

include reactive functions in the<br />

initial coating to stiffen the rings<br />

and detach them from the nanotube. These nanorings could carry anti-cancer molecules<br />

to diseased cells. This drug vectorization project is being carried out by a team from<br />

Divison of Life Sciences in partnership with Laboratoire Servier. Another application, with<br />

a more fundamental aim, is to use the nanorings as a substitute cell membrane for<br />

studying proteins in cells. These proteins degrade as soon as they are removed from<br />

their environment.<br />

© A. Gonin/<strong>CEA</strong><br />

<strong>CEA</strong> NEWS 12 September <strong>2007</strong>


Preparing<br />

impermeability tests<br />

for nanoparticles in<br />

protection equipment<br />

(masks and gloves), as<br />

part of the European<br />

Nanosafe2 project.<br />

© F. Vigouroux/<strong>CEA</strong><br />

EVALUATING THE TOXICITY<br />

OF NANO-OBJECTS<br />

Several <strong>CEA</strong> laboratories are participating in national and<br />

European programs to evaluate the risks from nanoparticles.<br />

How is their impact on health and the environment measured?<br />

© <strong>CEA</strong><br />

> TRANSISTOR:<br />

component that<br />

performs the functions<br />

of an amplifier,<br />

modulator or<br />

interrupter of<br />

electrical current.<br />

> DNA:<br />

deoxyribonucleic acid,<br />

an essential<br />

component of<br />

chromosomes, and the<br />

physical carrier of<br />

heredity.<br />

On a small scale, matter divided into<br />

nanoparticles has a larger surface area than<br />

ordinary matter. This could exacerbate its<br />

toxicity. Furthermore, nanoparticles have a<br />

natural tendency to form groups of<br />

micrometric size. Before a toxicological study<br />

is carried out, it is necessary to know the<br />

chemical nature of the particles, their structure<br />

and the physical and chemical state of their<br />

constituents. Finding out this information<br />

requires specialist skills and highly specialized<br />

analysis methods. When it comes to studying<br />

nanoparticles in suspension in the air, there<br />

is a particular problem: how can they be<br />

isolated or distinguished from ordinary<br />

atmospheric pollution?<br />

What effect do they have on<br />

animal cells and bacteria?<br />

Various teams are trying to assess the toxicity<br />

of nano-objects for humans using in vitro<br />

animal cell models. The aim is to study the<br />

biological effects on the organs they reach<br />

following inhalation or ingestion (lungs, liver)<br />

or following their passage through the body's<br />

natural barriers (kidneys).<br />

Two effects are being studied: the toxicity for<br />

the whole cell on the one hand and for the<br />

genes it contains on the other. Can<br />

nanoparticles pass through the cell<br />

membrane? Does the cell remain alive? Is its<br />

genetic material affected?<br />

Researchers are also interested in what<br />

happens in the environment to nanoparticles<br />

released by the decomposition of consumer<br />

products which have components containing<br />

them. The first targets to be looked at are<br />

bacteria in the ground and water. Are the<br />

nanoparticles trapped on the surface of the<br />

bacterium? Do they go inside it? If so, what<br />

happens to them? Do the bacteria put up<br />

any resistance?<br />

Toxicity and exposure<br />

These toxicological studies do not yet take<br />

account of the processes of exposure of cells<br />

in the body, which is a more complex<br />

environment than in vitro experiments<br />

provide. Until the results of the full toxicology<br />

study program are available, those working<br />

in laboratories are avoiding contact with<br />

nanoparticles by using containment methods<br />

(air locks, filters, packaging of powders, etc.).<br />

<strong>CEA</strong> NEWS 13 September <strong>2007</strong>


NANOSCIENCES<br />

Jean-Philippe<br />

Bourgoin<br />

of the Physical Sciences<br />

Division, director of<br />

<strong>CEA</strong>’s cross-disciplinary<br />

Nanosciences program<br />

INTERVIEW<br />

1. Minatec ® center was inaugurated in<br />

June 2006<br />

2. Scanning Electron Microscopy (SEM)<br />

performed on a nanocharacterisation<br />

platform<br />

3. Atomic force microscope used for nano<br />

and micro component imaging<br />

4. Automatic parametric tester<br />

to perform functional characterization on<br />

microsystems<br />

1<br />

5. Holographic and analytical Titan<br />

Transmission Electron Microscope (TEM)<br />

used to characterize materials<br />

6. Wafer to wafer assembly and<br />

lithography cluster<br />

7. Micro-traction station to study<br />

microsystems<br />

8. Programming the Endura 5500C<br />

machine to apply metal coating<br />

applications for Microsystems<br />

9. Lithography area for microsystems<br />

“ORGANIZING<br />

WORK AND<br />

SKILLS”<br />

© <strong>CEA</strong><br />

Why is such a program necessary?<br />

It’s a question of making early research in our<br />

fields – Information's Technologies, Health and<br />

Energy – more visible. It’s also a question of<br />

developing our partnerships most notably with<br />

CNRS and the universities, of strengthening<br />

the sectors in which we excel at fundamental<br />

research and of developing their application<br />

potential.<br />

What fields are covered?<br />

In addition to the work already in place on quantum<br />

electronics, chemistry for nanoelectronics,<br />

separation chemistry or spin electronics and<br />

nanomagnetism, new research subjects are<br />

emerging. We are interested in the behavior of<br />

fluids in fuel cells and biochips and in thermal<br />

exchanges in electronic components and<br />

refrigerant fluids. Simulation of nano-objects,<br />

materials and electronic<br />

components is also playing<br />

“<br />

an increasing role, as are<br />

particular aspects of nanocharacterization.<br />

Finally, in<br />

collaboration with crossdisciplinary<br />

programs on health<br />

technologies and materials, we<br />

have grouped and expanded the<br />

research launched by <strong>CEA</strong> since<br />

2001 on the potential risks from<br />

nanotechnologies.<br />

Simulation<br />

of nano-objects<br />

is also playing<br />

an increasing<br />

role in health<br />

technologies.<br />

”<br />

Sophie Astorg – Le journal de <strong>Saclay</strong> nr 36 – <strong>2007</strong>, April<br />

2<br />

3 4<br />

<strong>CEA</strong> NEWS 14 September <strong>2007</strong>


RESEARCH ON MICRO- AND<br />

NANOTECHNOLOGIES HOLDS<br />

PROMISE... WITH MINATEC ®<br />

6 7<br />

5<br />

8<br />

While Nanosciences are studied in both <strong>Saclay</strong> and Grenoble,<br />

research into Nanotechnology is mainly conducted at the<br />

Minatec ® labs in Grenoble.<br />

Initiated by <strong>CEA</strong>-LETI 1 and INP 2<br />

Grenoble, the Minatec ® center was<br />

inaugurated in early June 2006. It's an<br />

impressive site with 44,000 m 2 of new<br />

buildings spread over roughly 20 acres<br />

of land – becoming a major European<br />

innovation and consulting center for<br />

micro- and nanotechnologies demands<br />

significant investment. “Grenoble's<br />

nanoscience and nanotechnology center is<br />

an extension of all the programs recently<br />

implemented by public authorities for<br />

research and its application,” declared<br />

François Goulard, Minister Delegate for<br />

higher education and research, during<br />

his visit to the <strong>CEA</strong>'s Grenoble center<br />

on October 31 st , 2006.<br />

The Minatec ® concept is unique in both<br />

France and Europe. Why? Because it<br />

brings students and teachers as well as<br />

researchers and people from industry.<br />

Minatec ® gives them the chance to<br />

exchange ideas and work together at a<br />

single location. As a result, “upstream”<br />

research is undertaken by scientists in<br />

the Physical Sciences Division, whereas<br />

“downstream” projects tend to be handled<br />

by researchers in the Technological<br />

Research Division. Which is in keeping<br />

with the race to miniaturize and the era<br />

of the infinitely tiny, both well underway.<br />

It is imperative to harness the most<br />

fundamental properties of matter, push<br />

back the limits of current technologies,<br />

and map out new technologies within<br />

a multidisciplinary framework. Minatec ®<br />

will focus on major research themes such<br />

as microelectronics, nanoscience applied<br />

to biology or new materials, and software.<br />

No less than 3,500 engineers, researchers,<br />

and academics will strive to meet this<br />

objective, using the most advanced<br />

equipment and technological resources.<br />

Nanomaterials have inspired high hopes<br />

and should lead to all sorts of products<br />

that are both competitive and<br />

environmentally friendly. Being more<br />

and more efficient means producing on<br />

an ever smaller scale, with lower<br />

costs and higher performance. We<br />

immediately think of cell phones,<br />

computers, and so forth, but the realworld<br />

applications of this research are<br />

far more numerous: in the automotive<br />

industry, for healthcare, entertainment,<br />

safety, etc.<br />

1. Laboratoire d'électronique et de technologie<br />

de l'information (electronics and information<br />

technology laboratory).<br />

2.Institut National Polytechnique (engineering<br />

school).<br />

> For more information:<br />

http://www.minatec.com/minatec_uk/index.htm<br />

Photos 1-4 & 6-9: © P. Stroppa/<strong>CEA</strong><br />

Photo 5: © C. Morel/<strong>CEA</strong><br />

9<br />

<strong>CEA</strong> NEWS 15 September <strong>2007</strong>


WASTE – ADVANCED PARTITIONING<br />

SOLUTIONS FOR<br />

RADIOACTIVE WASTE<br />

How can<br />

radioactive waste<br />

be sustainably<br />

managed? The<br />

<strong>CEA</strong> (French<br />

Atomic Energy<br />

Commission) has<br />

been carrying out<br />

in-depth research<br />

under an Act dated<br />

December 30,<br />

1991 1 . Our report<br />

focuses on the<br />

three areas of<br />

investigation and<br />

their results.<br />

1. This act, also referred to as the “Bataille Act”, was transposed into the<br />

French Environment Code as Article L.542 in September 2000<br />

Storage hall in the <strong>Saclay</strong> center. Each of the<br />

100 shafts is ten meters deep, the highly irradiant<br />

drums are transferred to the shafts in a shipping<br />

cask and covered with a concrete plug.<br />

TOPICS TO EXPLORE<br />

/// Review of 15 years of research<br />

/// Partitioning<br />

/// 2006: the new law<br />

© P. Stroppa/<strong>CEA</strong><br />

<strong>CEA</strong> NEWS 16 September <strong>2007</strong>


Separating<br />

actinides:<br />

filtering operation<br />

in a glove box in<br />

the Atalante<br />

facility.<br />

© T. Foulon/<strong>CEA</strong><br />

In June 2005, ANDRA 2 and the<br />

<strong>CEA</strong> each submitted a report<br />

to the Ministry of Research<br />

reviewing their work on longlived,<br />

high level radioactive waste<br />

management, to enable the<br />

government to propose a bill that<br />

includes the solutions put<br />

forward for sustainable waste<br />

management. Nearly 80% of<br />

French electricity is currently<br />

produced by nuclear power<br />

plants, which ensures energy<br />

independence, standing France<br />

in good stead given oil<br />

price rises and limited fossil<br />

fuel supplies, and also<br />

ensures low greenhouse gas<br />

emissions. When France<br />

opted for nuclear power in<br />

the 1970s, it immediately<br />

started research into waste<br />

management. The 1991 Act<br />

gave the research a boost<br />

and focused on three<br />

areas: partitioning and<br />

transmutation, geological<br />

disposal and conditioning<br />

& storage. Research<br />

is still ongoing, but<br />

a large body of<br />

results has already<br />

been produced, showing the way<br />

to potential solutions.<br />

Let's take a look at three research<br />

areas that have focused French<br />

science on one major issue for<br />

a number of years: the sustainable<br />

management of radioactive material.<br />

2. French National Agency for Radioactive Waste Management.<br />

3. Spent fuel is processed in Cogema's La Hague plant.<br />

Research focus 1:<br />

Scientific demonstration<br />

of partitioning and<br />

transmutation (P&T)<br />

For the last twenty years or so,<br />

the French nuclear industry has<br />

been recycling 3 95% of its spent<br />

nuclear fuel, unburned uranium<br />

and plutonium, which is used<br />

for producing a new fuel cycle.<br />

The remaining 5%, which is<br />

waste, is immediately vitrified.<br />

Of this waste, the only items<br />

covered by the 1991 Act are longlived<br />

high-level radioactive<br />

elements (0.4% of the spent fuel).<br />

Research Focus 1 is looking<br />

into a way of separating the<br />

most radioactive elements for<br />

transmutation. The partitioning<br />

research undertaken at the Atalante<br />

facility at the <strong>CEA</strong> Valrhô center<br />

(at Marcoule, near Avignon) has<br />

demonstrated process feasibility<br />

in the laboratory. A high-yield<br />

transmutation process, where<br />

long-lived radioactive elements<br />

are bombarded with neutrons,<br />

can be performed in fast breeder<br />

reactors, as proven by the tests<br />

run in the <strong>CEA</strong>'s Phénix<br />

experimental reactor at Marcoule.<br />

However, partitioning and<br />

transmutation is not industrially<br />

feasible before 2040, and will<br />

only be used for waste produced<br />

after that time. The CNRS<br />

(French National Centre for<br />

>>><br />

Research<br />

reactor Phenix<br />

is dedicated to<br />

waste<br />

transmutation<br />

© A. Gonin/<strong>CEA</strong><br />

150<br />

The number of extracting molecules tested by<br />

researchers during studies into minor actinide<br />

partitioning.<br />

A TALANTE:<br />

T HE O NLY F ACILITY O F<br />

I TS T YPE IN T HE W ORLD<br />

The Atalante facility at Marcoule hosts highly specialized<br />

laboratories for work on improving spent fuel<br />

reprocessing procedures. It has been specially designed<br />

for studies into the management of long-lived high-level<br />

waste (HLW): design and testing of extraction molecules<br />

and studies into advanced partitioning processes,<br />

design and manufacturing of irradiation targets for<br />

transmutation and long term behavioral studies into<br />

waste in storage or repositories. The <strong>CEA</strong> is also<br />

developing methods for reprocessing and recycling fuel<br />

from the fast neutron energy production systems of the<br />

future. This unique facility is staffed by more than<br />

200 people. The commissioning of Atalante was<br />

announced by the ASN College (French Nuclear Safety<br />

Authority) on June 22, <strong>2007</strong>. ASN carried out a safety<br />

review at the same time.<br />

Special Issue – Les Défis du <strong>CEA</strong> – 2005, July<br />

© <strong>CEA</strong><br />

> TRANSMUTATION: The process of transforming a longlived<br />

radioactive element into an element with a shorter<br />

half-life or a stable element.<br />

<strong>CEA</strong> NEWS 17 September <strong>2007</strong><br />

© P. Stroppa/<strong>CEA</strong>


WASTE – ADVANCED PARTITIONING<br />

Scientific Research) is working<br />

on another transmutation method,<br />

using hybrid nuclear systems.<br />

Research focus 2:<br />

Towards reversible deep<br />

geological disposal<br />

ANDRA is working on the second<br />

research focus proposed in the<br />

1991 Act. It is looking at ultimate<br />

disposal of radioactive waste in<br />

deep geological repositories,<br />

capable of ensuring long-term<br />

containment several hundred<br />

meters below the ground. ANDRA<br />

(French National Agency for<br />

Radioactive Waste Management)<br />

is studying three rock types –<br />

granite, salt and clay. It has set up<br />

a field laboratory at Bure, in the<br />

Meuse region, that has been<br />

operational for several months. If<br />

the research is successful and<br />

political leaders make the relevant<br />

decisions, a geological disposal<br />

© P. Dumas/<strong>CEA</strong><br />

center should be built between<br />

2020 and 2025. According to the<br />

Parliamentary Office for the<br />

Evaluation of Scientific and<br />

Technological Choices, this is a<br />

vital option, but one that must be<br />

reversible. All nuclear-waste<br />

producing countries have selected<br />

this as an option. Likewise, experts<br />

from the International Atomic<br />

Energy Agency (IAEA), an UN<br />

authority recommend deep<br />

geological disposal, considering<br />

it the safest current option.<br />

Research focus 3:<br />

Increasingly<br />

high-quality storage<br />

Long-lived high level radioactive<br />

waste from spent fuel processing<br />

is currently vitrified and stored<br />

pending an ultimate solution, to<br />

be determined by the<br />

Government after a parliamentary<br />

debate. Current storage technologies<br />

and facilities have been much<br />

higher-performing over the last<br />

few years, improved through<br />

work by the <strong>CEA</strong> under Research<br />

Focus 3. New waste conditioning<br />

matrices developed at the <strong>CEA</strong><br />

Marcoule center have brought<br />

gains in terms of performance,<br />

reduced volumes and increaseddurability<br />

packages. The<br />

Parliamentary Office has judged<br />

France's currently operational<br />

storage facilities, at the Cogema<br />

plant at La Hague and the <strong>CEA</strong><br />

Cadarache center as highly<br />

efficient and fit to be safely used<br />

for another fifty years. The goal<br />

is to have storage facilities with<br />

a service life of 100 to 300 years.<br />

Amélie Kroell - Les Défis du <strong>CEA</strong> Nr 106<br />

2005, August<br />

Evolving Vitrification<br />

Prototype (AVP)<br />

1991-2006,<br />

a review of 15 years<br />

of research into<br />

advanced<br />

partitioning<br />

Under the “Bataille” Act, one of the<br />

major focuses in the drive to reduce<br />

the quantity and danger of long-lived<br />

high-level nuclear waste is to partition<br />

some long-lived radionuclides, either to<br />

transmute them or to carry out specific<br />

conditioning. After the 15 years of<br />

research prescribed by lawmakers,<br />

Christine Rostaing, “Advanced<br />

Partitioning” Project Manager, reviews<br />

the progress made in research in this<br />

field over the period.<br />

<strong>CEA</strong> NEWS 18 September <strong>2007</strong>


Most of the partitioning studies<br />

have focused on six radionuclides:<br />

• the minor actinides<br />

(americium Am, curium Cm<br />

and neptunium Np) which,<br />

after plutonium, are the main<br />

contributors to the long-term<br />

radio-toxic inventory of spent<br />

fuels,<br />

• three fission products<br />

(iodine I, cesium Cs and<br />

technetium Tc) which were<br />

selected due to their abundance<br />

in spent fuel, the existence of<br />

a long-lived isotope and their<br />

potential long-term mobility<br />

within a geological repository.<br />

The procedure used<br />

In order to perform minor actinide<br />

partitioning, extraction with a<br />

solvent was selected as the<br />

The entire processing and conditioning chain for highlevel<br />

radioactive waste was tested in Atalante: glove boxes<br />

comprised of a test loop for liquid-liquid extraction processes,<br />

a shielded process line on spent fuel and a selection of<br />

shielded compartments designed to host confinement<br />

matrices (glass, ceramic) and to study the long-term behavior<br />

of high-level waste packages; complemented by the shielded<br />

process line for experimentation, which confirmed the<br />

technical feasibility of advanced partitioning.<br />

reference procedure. This is a<br />

proven technique in the chemical<br />

industry and there is significant<br />

data available from operational<br />

use of the PUREX process at the<br />

La Hague plant over several<br />

decades. The strategy therefore<br />

consisted of:<br />

• firstly, adapting the PUREX<br />

process to recover neptunium,<br />

technetium and iodine.<br />

• secondly, developing complementary<br />

solvent-based extraction processes<br />

(hence the expression “advanced<br />

partitioning”) to separate out<br />

americium, curium and cesium<br />

from the high-level waste<br />

produced by the PUREX process<br />

currently vitrified.<br />

A target date of 2006 was set and<br />

the research was organized into<br />

two broad phases, aiming to<br />

demonstrate the scientific feasibility<br />

© P. Stroppa/<strong>CEA</strong><br />

(validating the basic concepts of<br />

partitioning) by the end of 2001<br />

and the technical feasibility (trials<br />

and overall validation of the<br />

processes) by 2005.<br />

The initial exploration phase<br />

was undertaken over a decade,<br />

involving wide-ranging cooperative<br />

ventures. It consisted of assessing<br />

the various extraction systems,<br />

chiefly targeting the trickiest stage<br />

– separating the actinides from<br />

the lanthanides. The second<br />

demonstration phase, between<br />

2002 and 2005, focused on the<br />

processes deemed the most<br />

promising.<br />

A three-stage approach<br />

It is not easy to recover and<br />

separate the minor actinides<br />

(americium and curium) within<br />

>>><br />

PARTITIONING<br />

BY LIQUID-<br />

LIQUID<br />

EXTRACTION<br />

Liquid-liquid extraction<br />

is a technique that<br />

uses two immiscible<br />

liquids, one aqueous<br />

phase and one organic<br />

phase. The elements to<br />

be separated are all<br />

dissolved in the<br />

aqueous phase and a<br />

special molecule,<br />

referred to as the<br />

“extracting” molecule,<br />

is dissolved in the<br />

organic phase. The role<br />

of this molecule is to<br />

capture the elements<br />

required for separation<br />

within the aqueous<br />

phase and to take them<br />

with it (extract them)<br />

into the organic phase.<br />

This molecule needs to<br />

be both effective<br />

(having a good affinity<br />

with the elements to be<br />

separated) and<br />

selective (affinity only<br />

with said elements).<br />

One of the major<br />

difficulties in designing<br />

a liquid-liquid<br />

extraction process is<br />

selecting this<br />

extracting molecule.<br />

Special Issue<br />

Les défis du <strong>CEA</strong> - 2005, July<br />

> PUREX:<br />

Purification by<br />

refining extraction.<br />

> LANTHANIDES:<br />

fission products<br />

from the lanthan<br />

family, with similar<br />

chemical properties<br />

to actinides.<br />

<strong>CEA</strong> NEWS 19 September <strong>2007</strong>


WASTE – ADVANCED PARTITIONING<br />

high-level waste (HLW). A number<br />

of factors make this a complex<br />

problem. The very similar chemical<br />

properties of the actinides (at<br />

oxidation degree III) and the<br />

lanthanides (at oxidation<br />

degree III), mean they are difficult<br />

to separate; in addition, there is a<br />

large variety of elements within<br />

the solution, which is moreover<br />

highly acidic. A three-stage<br />

approach is required:<br />

• Stage 1: the DIAMEX, which<br />

consists of simultaneously<br />

extracting the actinides and<br />

lanthanides using a molecule<br />

from the malonamide family;<br />

• Stage 2: the SANEX process,<br />

separating out the Am+Cm pair<br />

from the lanthanide group;<br />

• Stage 3: the Am/Cm partitioning<br />

process, using diamides.<br />

Review and outlook<br />

Since 1991, research into<br />

advanced partitioning has enabled<br />

procedures to be developed for<br />

selectively recovering americium<br />

and curium from fission product<br />

solutions derived from the PUREX<br />

process (99.9% recovery rate,<br />

which meets the stated goal). The<br />

selected concepts were validated<br />

before the end of the first phase<br />

of research (end of 2001). During<br />

the second phase (2002-2005),<br />

the processes were successfully<br />

tested. Firstly, the solvent<br />

endurance was tested in the<br />

irradiation loop. Subsequently<br />

the demonstration tests were<br />

successfully performed, in April<br />

and November 2005 respectively,<br />

in the Atalante shielded process<br />

cell, a 1/500 replica of the<br />

industrial technologies, using<br />

approximately 15 kg of EDF fuel.<br />

But over and above the scientific<br />

results expected within the strict<br />

framework of the law, it should<br />

also be emphasized that this<br />

period was useful for carrying<br />

out numerous basic studies, for<br />

instance into the extraction and<br />

complexation mechanisms of<br />

various extraction systems.<br />

Doctoral and Post-Doc research<br />

contributed greatly, along<br />

with national (GdR PRACTIS and<br />

PARIS), European (NEWPART,<br />

PARTNEW, CALIXPART,<br />

EUROPART, etc.) and<br />

international collaborations<br />

(Japan, Russia, USA, etc.). The<br />

<strong>CEA</strong> and the Valrho center have<br />

thus acquired new skills (e.g.<br />

molecular modeling) and new<br />

tools (see insert Future<br />

challenges).<br />

The program also provided an<br />

opportunity to run a project from<br />

start to finish, from designing the<br />

extraction molecules to testing a<br />

process on several kilograms of<br />

spent fuel. The work has boosted<br />

partitioning chemistry and<br />

actinide chemistry enhancing<br />

excellence within our teams ready<br />

to meet future challenges.<br />

Christine Rostaing,<br />

“Advanced Partitioning” Project Manager<br />

Rive droite Rive Gauche - 2006, May<br />

© A. Gonin/<strong>CEA</strong><br />

FUTURE CHALLENGES<br />

Given the decisions needed in 2006, our significant results opened up a range of possibilities<br />

for processing spent fuel in Generation IV reactor-fuel cycle systems that recycle their own<br />

waste. The choice was made to transmute actinides in FBRs 1 , these studies will need to be<br />

continued and adapted, depending on the nature of the actinide compounds selected for<br />

recycling. In Atalante, work is already under way in this area, with<br />

the parallel development of partitioning and multiple actinide<br />

conversion (integrated processing and re-manufacturing concept).<br />

The preparation for the demonstration experiment on key processes<br />

© A. Gonin/<strong>CEA</strong><br />

for this concept (access to the fissile compound; multiple actinide<br />

dissolving, extraction and conversion process; forming the fissile<br />

compound and re-manufacturing the fuel element), will use a fuel representative of a GFR 2 .<br />

The research teams will gradually focus their efforts on these new goals, which will also<br />

require developments in the Atalante facility.<br />

Christine Rostaing, “Advanced Partitioning” Project Manager<br />

1. FBR: Fast Breeder Reactor - 2. GFR: Gas-cooled Fast Reactor<br />

<strong>CEA</strong> NEWS 20 September <strong>2007</strong><br />

© P. Stroppa/<strong>CEA</strong>


© P. Dumas/<strong>CEA</strong><br />

Top: Managing waste drums during<br />

dismantling operations in the UP1 plant<br />

in Marcoule.<br />

Middle: Shielded compartments for<br />

dry processes used to manufacture<br />

(crushing, pressing, sintering and<br />

cladding) fuels for studies, transmutation<br />

targets and confinement matrices.<br />

Bottom: Mock-up for long-term<br />

storage in the ground below the CECER<br />

(Centre of expertise in conditioning and<br />

storage of radioactive material).<br />

99%<br />

This is the proportion of americium and curium<br />

that the selected molecules and the process<br />

developed in ATALANTE can partition out of the<br />

solution sourced from reprocessed spent fuel.<br />

NEW TEAMS FOR ICSM<br />

The Marcoule Institute of Separative<br />

Chemisty (ICSM), a mixed research unit<br />

jointly run by the CNRS (40%), University<br />

of Montpellier 2 (20%) and the <strong>CEA</strong><br />

(40%), is planning on an influx of around<br />

a hundred researchers in 2010. In the<br />

short term however, the first of these<br />

newcomers need to be identified – these<br />

will be the first teams to get into the<br />

Institute’s new premises at the entrance<br />

to the Marcoule site.<br />

Non-permanent staff Given staff<br />

turnover, 15 new researchers will be<br />

selected every year. Three tender<br />

processes were run, in September 2004,<br />

June and September 2005. In each<br />

tender, an innovative and realistic<br />

scientific collaboration was proposed,<br />

supervised either by the Montpellier<br />

Chemistry cluster – the Universities of<br />

Montpellier, the Montpellier-based<br />

Grande Ecole ENSCM and <strong>CEA</strong>-ICSM – or<br />

by another French university or CNRSrun<br />

laboratory.<br />

Permanent staff 50 applications were<br />

received by the close of the 2006<br />

recruitment campaign. 16 candidates<br />

have been interviewed by the<br />

Shortlisting Committee and 12 have been<br />

selected: 3 from the University of<br />

Montpellier 2, 3 from the CNRS and 6<br />

from the <strong>CEA</strong> (including 3 external<br />

recruits). After 4 campaigns, the staff<br />

team should be complete.<br />

In addition, European collaborations in<br />

the Physical Chemistry of Actinides (with<br />

the Institute for Transuranic Elements,<br />

Karlsruhe) and Sonochemistry (with<br />

Max Planck Institute) are being set up to<br />

enable researchers to work in mixed<br />

ICSM units hosted by foreign<br />

laboratories, from Spring <strong>2007</strong>.<br />

These initiatives should all help bring<br />

together the teams and enable them to<br />

be immediately operational when the<br />

ICSM laboratories open in March 2008.<br />

Gilles Richard - Rive droite Rive gauche – 2006, November<br />

The new<br />

law is here<br />

The final text 1 of the bill to succeed the “Bataille<br />

Act” (dating from December 30, 1991) was<br />

approved by the National Assembly on June 15,<br />

2006, following its examination by the Senate.<br />

This report focuses on “Program Law”<br />

no. 2006-739 dated June 28, which is much<br />

larger in scope than its predecessor, since it<br />

pertains “to the sustainable management of<br />

radioactive materials and waste.” In other words<br />

it covers all the <strong>CEA</strong>’s waste-related activities -<br />

research, management, decommissioning,<br />

facility operation and communication.<br />

The new law lays down the<br />

principle that “sustainable<br />

management of radioactive<br />

materials and waste of any<br />

description (…) is undertaken in<br />

compliance with the protection<br />

of human health, safety and the<br />

environment”, and in Article 3,<br />

stipulates that research and study<br />

related to long-lived high or<br />

intermediate level radioactive<br />

waste is to be performed “in three<br />

complementary areas”, resulting<br />

for the most part from work carried<br />

out at Marcoule over the last fifteen<br />

years or more.<br />

1. Research and study focusing on<br />

partitioning and transmutation<br />

of long-lived radioactive elements<br />

“are to be undertaken in relation<br />

to research carried out into new<br />

generations of nuclear reactors<br />

(…) and accelerator-driven<br />

systems dedicated to waste<br />

transmutation”. The stated goal<br />

is to be have an appraisal of the<br />

“industrial potential of these<br />

processes” by 2012 and to “put a<br />

prototype facility into operation<br />

by December 31, 2020”.<br />

2. With respect to deep geological<br />

disposal, a goal has been set for<br />

researchers and engineers, to<br />

design a reversible repository<br />

>>><br />

1. The Act was signed by the President of the Republic and 8 Government ministers: the Prime<br />

Ministers and Ministers of the Interior, Defense, Foreign Affairs, Health, Economy, Finance &<br />

Industry, Education & Research and Ecology.<br />

<strong>CEA</strong> NEWS 21 September <strong>2007</strong>


WASTE – ADVANCED PARTITIONING<br />

300years<br />

After this period, 90% of radioactive waste returns to a level of radioactivity<br />

comparable with background radiation. This waste is disposed of in existing final<br />

repositories managed by ANDRA.<br />

Studying the<br />

diffusion of<br />

hydrogen<br />

through concrete<br />

in the top of shell<br />

used for the<br />

storage/disposal<br />

of intermediatelevel,<br />

long-lived<br />

waste.<br />

Laser-welding glove-box for<br />

cladding containing pellets of study<br />

fuel, transmutation targets and<br />

confinement matrices.<br />

and to focus on selecting a site.<br />

The operating start date has<br />

been set for 2025, ten years after<br />

filing the permission application,<br />

which will be investigated and<br />

debated in depth.<br />

3. The same date of 2015 (at the<br />

latest) has been set for creating<br />

new storage facilities or adapting<br />

existing facilities, on the basis<br />

of research and study into the<br />

© A. Gonin/<strong>CEA</strong><br />

issues, in order to “meet the<br />

needs, particularly in terms<br />

of capacity and duration.”<br />

These three research focuses were<br />

already known, but a calendar has<br />

now been set, and additional<br />

details and provisions laid down:<br />

• the partitioning and transmutation<br />

process is clearly linked to<br />

Generation IV systems,<br />

• deep geological disposal must<br />

be reversible for a duration of<br />

“no less than one hundred years”,<br />

• the role of ANDRA is broadening,<br />

to include, for instance, cleaning<br />

up of radioactive contamination<br />

sites or coordinating research<br />

and study to be carried out (or<br />

commissioned) with respect to<br />

deep geological disposal and<br />

as well as storage,<br />

• three new taxes have been<br />

created, in addition to the<br />

existing tax on Basic Nuclear<br />

Installations: they will be used<br />

to fund economic development<br />

and the roll-out of technology<br />

in the areas surrounding the<br />

selected disposal site, and<br />

research and study into storage<br />

and deep geological disposal.<br />

The sums allocated to this research<br />

and the construction and operation<br />

of the corresponding facilities will<br />

be paid into funds accounted for<br />

separately within ANDRA.<br />

A broader scope<br />

The new law is much broader<br />

in scope than the previous Bataille<br />

Act. In particular, it sets in place<br />

a research and study program,<br />

aimed at commissioning a graphite<br />

and radium-bearing waste disposal<br />

center by 2013, and provide three<br />

“deliverables” by 2008: storage<br />

solutions for tritiated waste (until<br />

the radioactivity has decayed<br />

enough to allow for ground-level<br />

or shallow disposal), finalization<br />

of disposal solutions for used<br />

sealed sources (in existing or new<br />

centers) and a long-term impact<br />

assessment on uranium mine<br />

tailing disposal sites (with a<br />

reinforced radiological monitoring<br />

plan for these sites).<br />

Under the new law, the first ever<br />

national radioactive materials and<br />

waste management plan is to be<br />

put in place by December 31,<br />

2006. This type of plan is to be<br />

drawn up every three years by the<br />

Government, and assessed by the<br />

Parliamentary Office for the<br />

Evaluation of Scientific and<br />

Technological Choices. It will<br />

review the existing management<br />

methods for radioactive materials<br />

and waste, survey the foreseeable<br />

requirements for storage or<br />

disposal facilities, specify their<br />

capacity and duration (in the case<br />

of storage) and establish targets<br />

to be met (with a calendar), for<br />

radioactive waste items that<br />

still have no final management<br />

method. This plan must comply<br />

with three major objectives:<br />

1. reducing the quantity and<br />

danger of the radioactive waste,<br />

in particular by reprocessing<br />

spent fuel and processing and<br />

conditioning radioactive waste;<br />

in this respect, owners of long-<br />

>>><br />

<strong>CEA</strong> NEWS 22 September <strong>2007</strong>


Interview<br />

PHILIPPE PRADEL<br />

<strong>CEA</strong> Director of Nuclear Energy<br />

“<br />

Major breakthroughs have<br />

been achieved in nuclear<br />

waste management.<br />

lived Intermediate Level Waste<br />

(ILW) produced before 2015<br />

must have it conditioned by<br />

2030 at the latest,<br />

2. use specially designed facilities<br />

to store radioactive material<br />

awaiting reprocessing and<br />

ultimate radioactive waste<br />

awaiting disposal,<br />

3. use deep geological repositories<br />

to dispose of ultimate radioactive<br />

waste that cannot be disposed<br />

of in ground or shallow<br />

repositories, for nuclear safety<br />

or radiological protection<br />

reasons.<br />

Information,<br />

assessment and<br />

international cooperation<br />

Like the preceding law, the new<br />

one outlaws the disposal of<br />

foreign radioactive waste in<br />

France, but specifies the reason<br />

for this ban. The law provides for<br />

intergovernmental agreements to<br />

be published in the Journal Officiel<br />

(official gazette), specifying a<br />

framework under which foreign<br />

fuels may be reprocessed in<br />

France, and how long the related<br />

waste will remain stored on French<br />

soil. Operators running research<br />

and reprocessing operations<br />

involving foreign radioactive<br />

”<br />

substances will have to draw up<br />

an annual inventory on this issue,<br />

which will be made public, along<br />

with the annual report form the<br />

National Board for Research<br />

Assessment. The board must<br />

include “at least one international<br />

expert” and its report must “review<br />

research carried out abroad”. The<br />

same requirements apply to the<br />

national radioactive materials and<br />

waste management plan. It will<br />

have to summarize research and<br />

projects carried out outside France.<br />

The new law requires wider<br />

communication to the general<br />

public. One body that could be<br />

involved in communication<br />

is the High Commission for<br />

Transparency and Information on<br />

Nuclear Safety, established under<br />

a different law dated June 13,<br />

2006. This new body could<br />

organize “periodical consultations<br />

and debates on the sustainable<br />

management of radioactive<br />

materials and waste.” Likewise, a<br />

National Board, distinct from the<br />

aforementioned research board,<br />

will assess operators' funding of<br />

decommissioning and radioactive<br />

material management expenses.<br />

It will also issue a tri-annual report<br />

to the general public.<br />

Gilles Richard - Rive droite Rive gauche<br />

2006, September<br />

© A. Gonin/<strong>CEA</strong><br />

<strong>CEA</strong> NEWS 23 September <strong>2007</strong><br />

What is your appraisal of<br />

<strong>CEA</strong> research over these<br />

last fifteen years?<br />

The 1991 law brought<br />

research projects into the<br />

spotlight, some of which<br />

were already underway, and<br />

encouraged domestic and<br />

international cooperation.<br />

I would like to emphasize<br />

the lively exchanges<br />

stemming from the<br />

confrontation of scientific<br />

ideas among various players<br />

in research, industry and<br />

operations. The full range of<br />

possibilities has been<br />

explored with our partners<br />

[ed: in France, chiefly ANDRA<br />

and the CNRS] and major<br />

breakthroughs have been<br />

achieved. We now have a<br />

panel of solutions, which are<br />

actually complementary, and<br />

will feed a calm and<br />

informed public debate. To<br />

give you an example, we<br />

have reduced the volume of<br />

intermediate level<br />

radioactive waste by a factor<br />

of 10. Likewise, having<br />

demonstrated the scientific<br />

feasibility of actinide<br />

partitioning [ed: some of the<br />

most radioactive elements]<br />

and the existing methods for<br />

transmuting them in fast<br />

reactors, there is potential<br />

for further reductions in final<br />

waste in the future.<br />

What might be the<br />

international knock-on<br />

effect of the these<br />

results?<br />

There is now a massive<br />

renewal of interest in<br />

nuclear power, throughout<br />

the world, particularly in Asia<br />

[ed: China and India], linked<br />

to growing energy needs<br />

and the requirement of<br />

limiting CO2 emissions.<br />

France is one of the<br />

technological leaders with its<br />

spent fuel reprocessing &<br />

recycling processes, but also<br />

a leader in institutional<br />

terms, with a coherent<br />

system and multiple,<br />

rigorous, independent<br />

control mechanisms. We are<br />

being watched by the rest of<br />

the world and need to show<br />

that reasonable, sustainable<br />

solutions for nuclear waste<br />

management exist. Japan is<br />

building a plant similar to<br />

Cogema’s La Hague facility<br />

at Rokkasho Mura. The USA<br />

and China are now looking<br />

at our technological options<br />

with interest.<br />

Is there a synergy<br />

between research into<br />

waste management and<br />

research into future<br />

systems?<br />

Yes there is, because<br />

research into the nuclear<br />

systems of the future<br />

involves a goal of<br />

sustainable development,<br />

which implies reducing<br />

releases and waste as much<br />

as possible, and recycling to<br />

maximize resources. That is<br />

why people talk about<br />

“systems” these days, a<br />

term referring both to<br />

reactors and the associated<br />

fuel cycle. Within the<br />

framework of the<br />

Generation IV initiative,<br />

drawing together Euratom<br />

and 10 other countries, four<br />

of the six technological<br />

options selected for the<br />

nuclear systems to be<br />

deployed by 2030 are fast<br />

breeder reactors, which will<br />

enable these sustainable<br />

development goals to be<br />

met. France is heavily<br />

involved in research on this<br />

type of reactor, and<br />

already has wideranging<br />

expertise. ■<br />

Interview with Claire Abou<br />

Les défis du <strong>CEA</strong> – No. 106<br />

© L. Godart/<strong>CEA</strong>


SCIENTIFIC HIGHLIGHTS<br />

The dynamics of<br />

THE EARTH’S MAGNETIC FIELD<br />

reproduced in the laboratory<br />

© Collaboration VKS/<strong>CEA</strong><br />

Over the geological ages, the Earth has<br />

undergone several erratic reversals of its<br />

magnetic field. The sun’s magnetic field is<br />

reversed regularly every 22 years according to<br />

its cycle. These magnetic dynamics, which are<br />

still shrouded in mystery, play a role in our<br />

planet’s exposure to cosmic rays.<br />

The joint VKS experiment 1 (<strong>CEA</strong> 2 , CNRS, the Ecole<br />

Normale Supérieure in Lyon 3 and the Ecole Normale<br />

Supérieure in Paris 4 ) has, for the very first time,<br />

observed magnetic field reversals in laboratory<br />

conditions thanks to a highly turbulent flow of<br />

liquid sodium. The experiments should help scientists<br />

to understand more about cosmic magnetic field<br />

reversals. The results are published in Europhysics<br />

Letters, Volume 77, March <strong>2007</strong>.<br />

The Earth’s magnetic field is created by highly<br />

disordered movements that churn up the liquid<br />

iron core at the center of the Earth. This is known<br />

as the “dynamo” effect. One of its most astonishing<br />

characteristics, revealed by paleomagnetic research,<br />

is that reversal of the magnetic poles is totally random.<br />

They remain close to the Earth’s geographic poles<br />

and flip between north and south about once every<br />

100,000 years or so, although longer periods have<br />

been found between reversals. On average, these<br />

reversals last a few thousand years.<br />

The cause and timescale of such reversals, together<br />

with the geometry of the magnetic field during a<br />

reversal, remain the subject of much debate.<br />

The consequences may be considerable: during a<br />

reversal, the magnetosphere that protects the Earth<br />

from solar and cosmic radiation is significantly<br />

weakened. Life on Earth, and human life in<br />

particular, has survived this kind of situation in<br />

the past (the last reversal occurred 700,000 years<br />

ago), but a repeat would severely interfere with<br />

our modern communications systems (satellites<br />

and networks, etc.).<br />

The researchers involved in the VKS experiment<br />

have shown that the dynamo effect could be<br />

reproduced in a laboratory experiment, using a<br />

turbulent flow of liquid sodium produced by the<br />

counter-rotation of two impellers inside a cylinder 5 :<br />

with the two impellers rotating at the same speed,<br />

a stationary magnetic field is spontaneously generated<br />

once a certain threshold is exceeded. They have<br />

now observed that when the impellers rotate at<br />

different speeds, thus adding global rotation similar<br />

to that of the planets and stars, the dynamo field<br />

may vary over the course of time. Certain regimes<br />

have uncannily similar characteristics to the behavior<br />

of the Earth’s magnetic field.<br />

The field flips from one state of polarity to its opposite<br />

for irregular time periods, with the transition from<br />

one polarity to the other lasting a very short duration.<br />

- The periods during which the field is stable vary<br />

in length, but always last longer than reversal time.<br />

- Field excursions, periods during which the field<br />

decays and then grows again with no polarity<br />

change, can also be observed.<br />

At other rotation speeds, the magnetic field may<br />

periodically be reversed, rotating in space without<br />

polarities canceling each other out, as is observed<br />

in the case of the sun.<br />

These experiments imply that it will now be possible<br />

to conduct laboratory studies of phenomena that<br />

have intrigued geophysicists and astrophysicists for<br />

centuries.<br />

Magnetic field (in gauss) measured in the experiment<br />

in relation to time (in seconds). The sodium flow<br />

is driven by two turbines with counter-rotating<br />

impellers rotating at different speeds.<br />

Delphine Kaczmarek – <strong>2007</strong>, April<br />

1. Von Karman (the physicist after whom the flow was<br />

named). Sodium (the fluid used in these experiments).<br />

2. <strong>CEA</strong>’s Condensed State Physics Department, Physical<br />

Sciences Division, team headed by François Daviaud.<br />

3. Physics Laboratory at the Ecole Normale Supérieure de<br />

Lyon, (CNRS, ENS Lyon), team headed by Jean-<br />

François Pinton.<br />

4. Statistical Physics Laboratory (ENS Paris, CNRS,<br />

University of Paris VI and Paris VII), team headed by<br />

Stephan Fauve.<br />

5. The VKS experiment took place at <strong>CEA</strong>/Cadarache, at<br />

the Department of Nuclear Technology in the Nuclear<br />

Energy Division. The results are presented in an article in<br />

Physical Review Letter 98, 044502 (<strong>2007</strong>).<br />

SOITEC-LETI COMPETENCY CENTER<br />

© P. Stroppa/<strong>CEA</strong><br />

Soitec, the world leader in silicon-on-insulator technology, is pooling its skills with<br />

those of <strong>CEA</strong>/LETI* to set up the Nanosmart Center, a world-class center of excellence<br />

in advanced materials for the microelectronics industry. Funded by A21, the French<br />

agency for industrial innovation, the Nanosmart Center will develop new generations<br />

of semiconductor materials for innovative applications, such as high-frequency telecom<br />

components and power components for the automotive and audiovisual industries.<br />

* LETI: Electronics and Information Technology Laboratory.<br />

<strong>CEA</strong> Technologies No. 83 – November-December 2006<br />

<strong>CEA</strong> NEWS 24 September <strong>2007</strong>


XEDIX: 100 TB OF DATA SCREENED<br />

IN JUST A FEW SECONDS<br />

Using Xedix, the native XML database developed by the <strong>CEA</strong>, it takes less than<br />

a second to find a document in a 100 Tbyte base. A start-up called Xedix Tera<br />

Solutions is being set up to market this unique product that has potential<br />

applications in a wide range of areas, including multimedia, research,<br />

telecommunications and avionics.<br />

The <strong>CEA</strong> is producing for its own<br />

requirements an ultra high-performance<br />

information management system called<br />

Xedix, which it is currently testing on a<br />

100 TB database.<br />

A world first. “The archives of the Institut<br />

National de l'Audiovisuel (French National<br />

Audiovisual Institute) only represent 85 to<br />

90 TB of data,” comments Didier Courtaud.<br />

“If we were to store all the events of a person's<br />

life on a single electronic storage medium,<br />

it would take up about 100 GB, in other words,<br />

a thousand times less than the total storage<br />

capacity of Xedix.” The tests are performed<br />

using standard test cases made up of several<br />

types of realistic data. They are expected<br />

to confirm the good results from earlier<br />

tests carried out in 2003 on one TB and<br />

in 2005 on ten TB. “We think we'll be able<br />

to obtain response times of less than a second<br />

for most queries.”<br />

An outstanding information storage and<br />

indexing system is the key to this<br />

performance. The system stores and<br />

indexes all data in XML (Extended Markup<br />

Language), a descriptive language that<br />

is totally independent of desktop software<br />

programs and their constant stream of<br />

upgrades. Image or video files are stored<br />

in the base and listed in XML as metadata<br />

describing the subject, shooting date,<br />

characters or any other information selected<br />

by the database administrator.<br />

What's more, the data indexing system is<br />

smart. “Unlike conventional search engines,<br />

Xedix identifies the tag in which the required<br />

character string(s) is(are) located. This means<br />

that the query can be made clearer by adding<br />

as many criteria as necessary.” Queries can<br />

be carried out using a conventional browser<br />

or a customized interface developed in<br />

the language of the user's choice (Java,<br />

PHP, etc.). The tool has already been<br />

validated on other applications during<br />

collaborative work carried out in the<br />

System@tic competitiveness cluster. A<br />

start-up called Xedix Tera Solutions is<br />

being set up to market it.<br />

With a product like this, the future looks<br />

bright for the budding firm. There are<br />

clear signs of interest from many<br />

sectors including archiving services and<br />

multimedia libraries, the research<br />

community (European projects, joint<br />

research-industry projects) and the world<br />

of scientific and technical information.<br />

Xedix Tera Solutions also hopes to arouse<br />

the interest of other sectors such as largescale<br />

scientific instrument companies (that<br />

generate vast amounts of data),<br />

telecommunications, and industries that<br />

produce great quantities of documentation,<br />

like the automotive and pharmaceutical<br />

industries.<br />

<strong>CEA</strong> Technologies No. 85 – April <strong>2007</strong><br />

© F. Rhodes/<strong>CEA</strong><br />

© Artechnique/<strong>CEA</strong><br />

REMOTE<br />

RECHARGE<br />

FOR YOUR<br />

BATTERIES<br />

The mini-battery developed by <strong>CEA</strong>-LITEN 1<br />

research teams could make a great difference<br />

in the lives of people with certain disabilities.<br />

The remotely rechargeable battery, which<br />

can be fitted inside the human body with<br />

a number of other stand-alone devices, opens<br />

the door to a new generation of medical<br />

appliances, including muscle stimulators<br />

for paralyzed hands or for hearing implants.<br />

The long-familiar lithium battery used in<br />

pacemakers is capable of supplying electrical<br />

power over a period of many years.<br />

However, as it cannot be recharged and its<br />

lifetime is limited by its size, it can only be<br />

used to power devices with very low energy<br />

consumption. “Which brings us to the<br />

rechargeable, lithium-ion mini-battery we have<br />

developed as part of the European Healthy Aims<br />

project, in association with our industrial partner,<br />

Saft. The battery meets the specifications of<br />

implant manufacturers like Cochlear Ltd. and<br />

Finetech Medical,” explains Séverine<br />

Jouanneau, a researcher at <strong>CEA</strong>-LITEN.<br />

“Lightweight (2 g) and compact (1 cm 3 ), the<br />

battery is only 5 mm thick, yet provides<br />

maximum energy (50 mAh) and can be<br />

recharged daily.” Recharging can be carried<br />

out by induction through the skin during<br />

the night using a device placed at the patient's<br />

bedside. Another advantage is service life –<br />

the battery can work for more than ten years<br />

at a temperature of 37°C.<br />

Vahé Ter Minassian - Les Défis du <strong>CEA</strong> No. 122 – March <strong>2007</strong><br />

1. LITEN: Laboratory for Innovation in New Energy<br />

Technologies and Nanomaterials<br />

<strong>CEA</strong> NEWS 25 September <strong>2007</strong>


SCIENTIFIC HIGHLIGHTS<br />

The HESS observatory team awarded the European<br />

Descartes prize for its progress in<br />

VERY HIGH-ENERGY GAMMA ASTRONOMY<br />

© ESO/ANTO/UT1<br />

On March 7, <strong>2007</strong>, the French-German very<br />

high-energy gamma ray observatory received<br />

the 2006 Descartes prize. Since the year 2000,<br />

this prize has been awarded annually to scientific<br />

teams for their transnational research results.<br />

It was awarded to the HESS team in recognition<br />

of the quality of results concerning the “nonthermal<br />

universe” or “violent universe” that<br />

opened up a new field of astronomy. The HESS<br />

observatory's results have been hailed as a world<br />

first in gamma astronomy.<br />

The observatory was mainly built by French<br />

and German laboratories, later joined by teams<br />

from other European and southern African<br />

countries. In France, it brings together CNRS<br />

(IN2P3 and INSU) 1 and <strong>CEA</strong> (DAPNIA 2 )<br />

laboratories.<br />

HESS (High Energy Stereoscopic System) is<br />

the name given to four telescopes installed<br />

on the Gamsberg plateau in Namibia. HESS is<br />

primarily dedicated to observing the southern<br />

skies that give access to most of the Milky Way.<br />

HESS provides precious information about<br />

some of the Universe’s most violent phenomena<br />

by detecting very high-energy gamma rays,<br />

using the light flashes they produce as they<br />

interact with the Earth's<br />

atmosphere (“Cherenkov<br />

effect”). The HESS<br />

experiment will soon be<br />

enhanced by the installation<br />

of a very large telescope - 28<br />

meters in diameter - at the<br />

center of the existing array<br />

of four instruments. This new<br />

phase of the experiment will<br />

not only enhance sensitivity<br />

but also overlap with the<br />

energy range covered by<br />

NASA's gamma astronomy<br />

satellite, GLAST, which should<br />

be launched in <strong>2007</strong>. The<br />

project, called Cherenkov<br />

> GAMMA RAYS: Like visible light<br />

or X-rays, gamma radiation is<br />

made up of photons, but at much<br />

higher energy levels. Visible light<br />

has an energy of around one<br />

electron volt (1 eV). X-rays are in<br />

the range of one thousand to one<br />

million eV. HESS detects very<br />

high-energy gamma rays that can<br />

reach a million million eV (or<br />

1 tera-electron volt (1 TeV)).<br />

There are few of these very highenergy<br />

gamma rays. Even for a<br />

relatively intense astrophysics<br />

source, the flow of gamma<br />

photons entering the atmosphere<br />

is around one per month per<br />

square meter.<br />

Telescope Array or CTA, will increase sensitivity<br />

tenfold and considerably add to available<br />

information sources.<br />

Delphine Kaczmarek – <strong>2007</strong>, March<br />

1. LLR École polytechnique (IN2P3/CNRS), LPNHE of the<br />

Universités Paris VI and VII (IN2P3/CNRS), APC<br />

(IN2P3/CNRS/Université Paris 7/<strong>CEA</strong>), LPTA Université<br />

de Montpellier 2 (IN2P3/CNRS), LAPP Annecy le Vieux<br />

(IN2P3/CNRS), CESR Toulouse (INSU/CNRS), LAOG<br />

Grenoble (INSU/CNRS), LUTH Observatoire de Paris-<br />

Meudon (INSU/CNRS).<br />

2. DAPNIA, Research laboratory dedicated to the<br />

fundamental laws of the Universe in the Physical Sciences<br />

Division.<br />

ATLAS, ACCELERATING DETECTION<br />

The superconducting toroidal magnet of the Atlas experiment<br />

has just been started up at the LHC facility 1 .<br />

A 21,000 A current was injected into the eight coils of the<br />

magnet to produce its magnetic field 2 . <strong>CEA</strong>-DAPNIA scientists,<br />

who have been closely involved in the design and construction<br />

of Atlas, took this opportunity to check all the magnet operating<br />

parameters and performed a successful test on its muon<br />

spectrometer. This instrument has already detected cosmic<br />

muon tracks bent under the influence of the magnetic field.<br />

These results are very encouraging for the research teams, who<br />

are now waiting for the LHC – the world's largest proton collider<br />

– to be commissioned at the end of the year, when they will<br />

be able to record and analyze the first collision data, and answer<br />

a number of basic questions in particle physics – such as “does<br />

the Higgs boson exist?”.<br />

1. Large Hadron Collider,<br />

installed in a tunnel with a<br />

circumference of 27 km,<br />

built 100 m below the<br />

ground at the CERN in<br />

Geneva.<br />

2. The Atlas magnet stores<br />

1.1 GJ of magnetic energy,<br />

enough to lift the Eiffel<br />

Tower about ten meters off<br />

the ground.<br />

Aude Ganier – Les Défis du <strong>CEA</strong> n° 121 – February <strong>2007</strong><br />

© Cern<br />

<strong>CEA</strong> NEWS 26 September <strong>2007</strong>


FIRST COMPLETE SIMULATION OF<br />

PET IMAGING SCAN<br />

OF THE WHOLE HUMAN BODY<br />

Interpreting data from positron emission tomography (PET) - medical<br />

imaging scanning increasingly used in hospitals - is still a complex<br />

task. With a view to optimizing its analysis and extracting the most<br />

relevant physiological information, researchers are working on computer<br />

simulation programs to enhance PET techniques. The programs are<br />

currently held back by computing time limitations.<br />

This problem spurred <strong>CEA</strong>-SHFJ 1 (Service<br />

hospitalier Frédéric Joliot in Orsay near Paris) to<br />

set up the GATE 2 simulation platform, which<br />

models PET scans using the Tera 10 supercomputer<br />

located at the <strong>CEA</strong>'s DAM-Ile-de-France 3 centre<br />

in Bruyères-le-Châtel near Paris. The ensuing<br />

simulation made it possible to reproduce - in an<br />

entirely realistic manner and in a very short time<br />

- the distribution of a tracer used in PET for<br />

diagnosing cancer. This first simulation result<br />

means that, in the medium term, a more precise<br />

use of data provided by the images can be envisaged<br />

as well as personalized scans for patients.<br />

These simulations are carried out using the<br />

Monte-Carlo method, based on probability<br />

theories. The analysis is hindered, however, by<br />

the limitations of digital processing: for a standard<br />

PET scan of the whole human body, a Monte-<br />

Carlo simulation must process the emission of<br />

several billion positrons and gamma photons,<br />

which is the equivalent of 10,000 computing<br />

hours, or 400 days of analysis on a standard PC.<br />

To reduce this computing time, researchers<br />

conducted a simulation on<br />

the Tera 10 supercomputer.<br />

After modeling the<br />

patient's body, using data<br />

from an actual scan,<br />

researchers simulated the<br />

injection of a tracer by<br />

selecting a realistic activity of 264 megabecquerels<br />

(MBq) and an acquisition time similar to that<br />

required for a standard PET scan. This initial<br />

simulation required less than three hours'<br />

computing time using 7,000 processors. The<br />

subsequent comparison of the actual scan and<br />

its simulation showed almost identical tracer<br />

distribution. From a quantitative point of view,<br />

comparisons of the volume of a tumor located<br />

under the patient’s left axilla indicated a difference<br />

of 6%, which is considered very low for an initial<br />

simulation. This result represents a first decisive<br />

step towards the development of methods that<br />

could be used to correct actual data from PET<br />

scans and, in the long term, target the creation<br />

of a patient specification for PET acquisition<br />

© <strong>CEA</strong><br />

See the comparison of images<br />

obtained below:<br />

• Left: PET image of an actual<br />

‘whole body’ scan<br />

• Right: the result obtained through<br />

simulation on Tera 10<br />

protocols and analysis. It also shows the benefits<br />

of intensive computing in the life science field.<br />

Stéphane Laveissière – <strong>2007</strong>, April<br />

1. The SHFJ is one of the 4 research platforms of the<br />

French Institute for BioMedical Imaging (<strong>CEA</strong>-I 2 BM).<br />

The others are NeuroSpin (<strong>Saclay</strong>), MIRCen<br />

(Fontenay-aux-Roses) and C-INAPS (Caen).<br />

2. GATE: Geant4 Application for Tomographic Emission<br />

– Geant4 is an international simulation program<br />

developed at CERN (Switzerland).<br />

3. DAM: Military Applications Division.<br />

© P. Stroppa/<strong>CEA</strong><br />

THE PIANIST'S FLOWING TOUCH<br />

Music lovers everywhere expect a digital piano to<br />

provide a perfect reproduction of the touch offered<br />

by a grand piano. But high-fidelity reproduction calls<br />

for perfect control of parameters such as the mechanism's<br />

resolution and bandwidth. <strong>CEA</strong>/LIST* took up this<br />

challenge by joining forces with the Ecole Polytechnique's<br />

Solid Mechanics Laboratory to develop a new sensory<br />

interface technology based on the use of magnetorheological<br />

or MR fluids. These fluids, made up of<br />

microscopic metal particles suspended in a liquid<br />

solvent, change viscosity under the influence of a<br />

magnetic field.<br />

The degree of change is proportional to the intensity<br />

of the applied field, making it possible to simulate<br />

the “perfect” touch, using a real-time control system<br />

and a dynamic model of traditional keys. The<br />

demonstrator developed by <strong>CEA</strong>/LIST has not only<br />

lived up to expectations. It also offers something extra<br />

– low cost! This makes it compatible with industrial<br />

production of keyboards integrating the new keys.<br />

Other potential applications include sensory interfaces<br />

and the design of new types of brakes and active dampers<br />

for motor vehicles.<br />

Sylvie Guigon – Atouts Bio Nr 4 – <strong>2007</strong>, March<br />

* LIST : Laboratory for Integration of Systems and Technologies.<br />

> RHEOLOGY: Branch of mechanics<br />

concerned with the study of flows<br />

in liquids and related deformation<br />

phenomena.<br />

<strong>CEA</strong> NEWS 27 September <strong>2007</strong>


SCIENTIFIC HIGHLIGHTS<br />

© <strong>CEA</strong>/Inserm-GBF<br />

ANTICANCER DRUGS TACKLE<br />

SCHIZOPHRENIA<br />

Since they created the first “model” schizophrenic<br />

mouse in 2002, pharmacologists from the<br />

<strong>CEA</strong> and INSERM have been making one<br />

discovery after another, the reward! The<br />

reward being an alternative to existing<br />

schizophrenia therapies. They observed an<br />

improvement in the animal's behavior after<br />

administering the epithilone D molecule,<br />

an anticancer drug. In their efforts to find a<br />

remedy, they focused on neurons rather than<br />

the neurotransmitters involved in the disease<br />

and currently treated by antipsychotic drugs.<br />

In 2002, researchers found a link between<br />

schizophrenia and cell microtubules for<br />

the first time ever. They observed behavior<br />

disorders in the animal if they deactivated<br />

Compared with those of the expression of a protein<br />

a normal mouse (A), the<br />

microtubules (shown in involved in microtubule<br />

green) of the neurons of a function. These disorders<br />

schizophrenic mouse are were reflected in a lack of<br />

not stable (B) at 4 °C,<br />

social interaction or maternal<br />

except when epothilone D<br />

is present (C).<br />

feeling, hyperlocomotion or<br />

spatial memory problems.<br />

In order to treat this schizophrenia, they turned<br />

to molecules used in cancer treatment that<br />

are capable of stabilizing microtubules. They<br />

opted for epothilone D, one of the few<br />

molecules that can penetrate the brain.<br />

Administered at very low doses to prevent its<br />

blocking action on cells (a trait common to<br />

all anticancer drugs), it proved highly effective<br />

in restoring synaptic functions with no adverse<br />

side effects. This molecule has now been<br />

patented and will soon be studied in humans.<br />

Aude Ganier - Les Défis du <strong>CEA</strong> No. 122 – March <strong>2007</strong><br />

> NEUROTRANSMITTERS:<br />

Molecules that transmit information<br />

from one neuron to another during<br />

connections known as synapses.<br />

> MICROTUBULES: Fibers along which<br />

various components are routed from<br />

one point of the neuron to another.<br />

A CLIMATIC UPHEAVAL<br />

BROUGHT TO LIGHT<br />

Between ten and three million years ago,<br />

the tropical rain forests of East Africa<br />

gradually gave way to savannah. What<br />

brought about such a radical change<br />

in the environment? Until recently,<br />

paleoclimatologists thought the cause was<br />

twofold: a drop in the CO2 level in the air<br />

and cooler surface water in the Indian<br />

Ocean. Today, a French team 1 , including<br />

researchers from LSCE (Laboratory of<br />

Climate and Environmental Sciences), a<br />

joint <strong>CEA</strong>/CNRS/UVSQ laboratory 2 , has<br />

discovered a third factor explaining this<br />

change 3 : the upthrust of the East African<br />

Rift System.<br />

This extraordinary geological structure<br />

saw a renewal in its activity 12 million<br />

years ago. In response to tectonic activity,<br />

the Earth's crust was raised before<br />

collapsing in the center to create a<br />

6,000 km long valley, bordered by hills,<br />

plateaus and mountains ranging from<br />

2,000 m to 5,000 m in height. A<br />

phenomenon on such a scale as this must<br />

have had an impact on the climate but<br />

this impact on the climate, but had never<br />

been quantified.<br />

Turning the problem round<br />

LSCE climatologists therefore teamed up<br />

with paleontologists and geologists 4 to<br />

simulate the possible impact of the<br />

emergence of the East African Rift. “In fact,<br />

we turned the problem round,” says Pierre<br />

Sepulchre, a member of the LSCE climate<br />

modeling team. “We asked ourselves what<br />

would happen if the Rift didn't exist? We used<br />

the climate model developed by the Dynamic<br />

Meteorology Laboratory to perform two digital<br />

simulations. The first considered geological<br />

structures only 2,000 m high and the second<br />

at areas with no relief.”<br />

The result left no room for doubt: the<br />

flatter the region, the higher the<br />

precipitation. Compared with today's<br />

figures, the average annual rainfall rose<br />

by 15%for the first simulation and by 40%<br />

for the second, “The lack of relief allows the<br />

Indian monsoon to progress farther into the<br />

continent in winter and causes a moistureladen<br />

zonal flow between southern Sudan<br />

and Ethiopia in summer,” explains Pierre<br />

“<br />

Transport of<br />

moisture from east<br />

to west or vice<br />

versa depending<br />

on the latitude<br />

and season.<br />

”<br />

The emergency of the Rift contributed significantly<br />

to the desiccation of East Africa, as can be seen in<br />

these simulations of changes in moisture transport.<br />

Sepulchre. This humidity results in heavy<br />

rainfall that favors the development of<br />

forests, as illustrated by vegetation models<br />

based on climatic simulation. This goes<br />

to show that the emergence of the East<br />

African Rift really is a key factor in the<br />

desiccation observed in East Africa during<br />

this period.<br />

Fabrice Demarthon<br />

Les Défis du <strong>CEA</strong> No. 121 – February <strong>2007</strong><br />

1. Paris Earth Physics Institute, European Institute<br />

of the Sea in Brest, Human Paleontology<br />

Laboratory of the University of Poitiers, LSCE.<br />

2. University of Versailles-Saint-Quentin.<br />

3. Science, vol. 313, 08.11.06, P. Sepulchre et al.;<br />

research funded by the CNRS Eclipse<br />

multidisciplinary program.<br />

4. From the University of Poitiers, the Paris Earth<br />

Physics Institute and the European Institute of<br />

the Sea.<br />

© <strong>CEA</strong><br />

<strong>CEA</strong> NEWS 28 September <strong>2007</strong>


SUPERDOPED SILICON:<br />

AN EXCELLENT CONDUCTOR<br />

Superconducting silicon capable of conducting<br />

electricity without the slightest resistance?<br />

Microelectronics specialists would think it quite<br />

a paradox!<br />

Because that's exactly the material they use for its intrinsic<br />

semiconducting powers to control the intensity and<br />

direction of electric current. Yet a CNRS 1 /<strong>CEA</strong> 2 /University 3<br />

collaboration has come up with these results using silicon<br />

that has undergone chemical treatment at ambient pressure.<br />

As its superconductivity is only apparent at very low<br />

temperatures (- 272.8 °C) 4 , its use should be restricted<br />

to fundamental research laboratories, for testing theories<br />

on nanostructure superconductivity, for example.<br />

This result is still quite a performance!<br />

“In the 1980s, researchers managed to make silicon a<br />

superconducting material by subjecting it to tremendous<br />

compression, but its crystalline structure was changed in<br />

the process,” recalls <strong>CEA</strong> researcher Christophe Marcenat.<br />

So he and his colleagues opted for a chemical process in<br />

which silicon was “doped” through the gradual addition<br />

of boron, gradually increasing its conducting power.<br />

Until then, this process had always come up against the<br />

inability of silicon to absorb large amounts of boron. “To<br />

get round this problem, we used laser pulses to heat a silicon<br />

film in an atmosphere of gas containing boron,” explains<br />

Etienne Busterrret, a CNRS researcher. “These pulses also<br />

force boron atoms inside the molten material where they<br />

bind during recrystallization.” So superconductive doped<br />

silicon isn't such a paradox after all!<br />

Claire Abou - Les Défis du <strong>CEA</strong> No. 121 – February <strong>2007</strong><br />

Adjusting the laser beam used to obtain silicon samples with more boron doping than that obtained through the<br />

usual silicon microelectronics methods.<br />

> SEMICONDUCTIVITY:<br />

Intermediate electrical<br />

conductivity between<br />

that of metals and<br />

insulators.<br />

1. Laboratory for the Study of the Electronic Properties of Solids,<br />

Grenoble.<br />

2. Condensed Matter Fundamental Research Department, Grenoble.<br />

3. Condensed Matter and Nanostructure Physics Laboratory, University<br />

of Lyon 1 and CNRS; Basic Electronics Institute, University of Paris-<br />

Sud and CNRS.<br />

4. Today's superconducting materials operate within the –273 °C to<br />

–140°C temperature range.<br />

© J. Boulmer/CNRS<br />

200 MM MICROSYSTEMS LINE SEEKS DEVELOPMENT PROJECTS<br />

<strong>CEA</strong>/LETI has invested in a 200 mm R&D line<br />

dedicated to industrial partnerships in the microsystems<br />

field for development, prototyping and preproduction.<br />

It’s the ideal solution for creating new products faster<br />

and at lower cost without investing too soon.<br />

1,000 square meters of clean rooms, specific equipment<br />

worth €20 million available 24/7, teams of researchers<br />

and technicians boasting 20 years of experience in<br />

microsystems. That, in a nutshell, is what LETI is offering<br />

industrial firms in Grenoble wishing to develop<br />

components on 200 mm silicon wafers. “The microsystems<br />

industry is still very customized,” observes Bruno Mourey,<br />

in charge of the project at LETI. Everyone creates their own line (above-<br />

IC or stand-alone) for niche markets at the cost of heavy investment<br />

and long development times.“The aim, therefore, is to use LETI resources<br />

and expertise to work faster and at a lower cost.”<br />

The solution is based on the 200 mm format, which is not only tomorrow's<br />

microsystems standard, but also and above all, the current standard on<br />

a vast number of microelectronic production lines.<br />

Collaboration projects lasting two to four years will be proposed to<br />

© P. Stroppa/<strong>CEA</strong><br />

people in industry. This is the time it takes to develop<br />

lines (or set of processes), build prototypes, carry out<br />

preproduction runs and, if the partners wish, transfer<br />

the technology to their own production site. The platform<br />

is intended for two types of partners. First, silicon<br />

founders seeking new markets for their 200 mm facilities.<br />

Second, manufacturers or end users, who see the<br />

microsystem as an opportunity for differentiation and<br />

innovation and who need development work to be<br />

treated confidentially.<br />

In all, LETI plans on working with six to ten companies<br />

keen to invest in mass markets in various sectors, such<br />

as mobile telephony, consumer products, motor vehicles<br />

or industrial electronics. It will operate the equipment alone to ensure<br />

that there are no “leaks” between projects and will allow each partner<br />

access to its line. It is the only line dedicated to 200 mm microsystems<br />

in Europe. Platform users will also have access to LETI's microelectronics<br />

R&D resources as well as its other areas of expertise – characterization,<br />

design, testing and materials – grouped together at the Minatec cluster.<br />

<strong>CEA</strong> Technologies No. 83 – December 2006<br />

<strong>CEA</strong> NEWS 29 September <strong>2007</strong>


SCIENTIFIC HIGHLIGHTS<br />

Annual Report<br />

<strong>CEA</strong> 2006<br />

(french or english<br />

version)<br />

ARC-NUCLEART IN THE<br />

LAND OF THE MAYAS<br />

For the first time since the Atelier de Restauration (Restoration Workshop)<br />

was created in 1970, the Nucleart Method – resin impregnation and gamma<br />

irradiation – has been used abroad.<br />

“This Maya sculpture, discovered on the site<br />

of Becan in Yucatan, is a unique<br />

archeological object. It has also been<br />

declared a national treasure,<br />

so there was no question of it<br />

leaving the country,”<br />

explains Alejandra Alonso,<br />

a restoration specialist at<br />

the INAH, the Mexican<br />

National Institute of<br />

Anthropology and<br />

History. The Nucleart<br />

Method, developed at<br />

the <strong>CEA</strong> center in<br />

Grenoble, was chosen<br />

for the renovation work.<br />

“It seemed the most effective<br />

way of halting any further<br />

damage to this statuette, a dwarf only 20 cm<br />

tall, whose body had suffered considerable<br />

deterioration, with the wood flaking away<br />

at the slightest touch.” It was therefore decided<br />

that the first week of the mission 1 would<br />

be given over to treatment, with the second<br />

week set aside for three conferences on<br />

preservation and restoration processes for<br />

dry and waterlogged wooden objects.<br />

The Mayan statuette was first impregnated<br />

with liquid styrene-polyester resin. It was<br />

then packed in a special container and<br />

taken under police escort to the industrial<br />

irradiator located at the heart of the National<br />

Institute for Nuclear Investigation, 40 km<br />

outside Mexico City. This gamma irradiator<br />

induces radioactive polymerization which<br />

hardens the resin in the wood. Khôi Tran,<br />

an ARC-Nucleart chemical engineer, is<br />

working on something of a special agent's<br />

mission. “Alejandra Alonso Olvera called me<br />

at the beginning of 2006, asking me to come<br />

to Mexico City to restore a dry, wooden sculpture<br />

from the Maya period. This had first been<br />

Restoration at work<br />

mentioned back in 2002.” Although<br />

the INAH is a major preservation<br />

and restoration center employing<br />

some one hundred people,<br />

including forty restorers, it has quite<br />

modest technical resources.<br />

The next thing to do was to prepare the<br />

mission. Using Khôi Tran's diagrams and<br />

photos, Alejandra was able to have<br />

alterations made to a 40 l<br />

pressure cooker made<br />

in America. Other<br />

adjustments had to be<br />

made to the vacuum<br />

pump, pressure gauges,<br />

nitrogen cylinder, tubes<br />

and fittings, irradiation<br />

parameters, resin formulation – even the<br />

power supply voltage (110 V in Mexico).<br />

“But even after six months of preparation,<br />

there were always surprises in store, like<br />

the purple color of the impregnating resin.”<br />

The irradiation treatment lasted 48 hours.<br />

The consolidation of the sculpture was<br />

satisfactory and the polychrome resisted<br />

well, thereby minimizing the risk<br />

of damage during exhibitions. “We<br />

demonstrated that Nucleart technology can<br />

be transferred, especially to emerging<br />

countries,” stresses Khôi Tran. The process<br />

is of particular interest in tropical<br />

countries, where objects densified by<br />

Nucleart will put up better resistance to<br />

extreme variations in climate. For the<br />

past year, Vietnamese archeologists have<br />

called on ARC-Nucleart to preserve<br />

waterlogged, wooden, archeological<br />

objects on site.<br />

Marc Jary – Le mensuel de Grenoble – October 2006<br />

1. The mission is fully funded by the Mexican<br />

authorities.<br />

Organized every year by the <strong>CEA</strong> and the Association of French Mayors, the “Save the<br />

Heritage” competition offers the five award-winning towns the chance to have their<br />

works of art treated and restored by the ARC-Nucleart Laboratory at the <strong>CEA</strong> center<br />

in Grenoble.<br />

Les Défis du <strong>CEA</strong> No. 122 - March <strong>2007</strong><br />

© DR<br />

France-China Symposium<br />

on Nuclear Energy<br />

Regulations, Codes,<br />

Standards and Qualification<br />

Rostrum during the Vice-Minister's speech. From left to<br />

right: the Vice-Minister, Cyril Pinel of the ASN, the French<br />

Ambassador to China, the Chief Executive Officer of the Chinese<br />

nuclear safety authority.<br />

The <strong>CEA</strong> and the Chinese Safety Authority held<br />

the first “France-China Symposium on Nuclear<br />

Energy Regulations, Codes, Standards and<br />

Qualification” in Beijing on June 4-6, <strong>2007</strong>.<br />

China has recently decided to speed up the<br />

development of its nuclear program (10 reactors<br />

in service and 17 at various stages of testing,<br />

construction and licensing); a number of players<br />

will be involved: government authorities and<br />

regulators, utilities, design institutes and industry.<br />

France has completed a highly successful program.<br />

One of the keys to success is the implementation<br />

of a comprehensive set of regulations, codes and<br />

standards addressing such subjects as supplier<br />

qualification, equipment certification, on-site<br />

inspection, etc.<br />

The symposium provided an opportunity to<br />

compare current French and Chinese regulations<br />

and allowed government agencies, utilities, design<br />

institutes and people from industry to share their<br />

experience.<br />

Some 300 people took part (including more than<br />

200 Chinese). There were contributions from various<br />

representatives of French industry and the IRSN<br />

and some Chinese institutes. The Symposium was<br />

chaired by Mr. LI Ganjie – Vice-Minister of SEPA,<br />

Administrator of NNSA and Mr. André-Claude<br />

Lacoste – President of the ASN.<br />

Using hydrogen to produce<br />

energy – a traveling exhibition<br />

The depletion of petroleum resources is forcing us<br />

to consider other options, especially renewable<br />

energy sources. Among the possibilities, hydrogen<br />

offers numerous advantages. It can be easily<br />

© <strong>CEA</strong><br />

<strong>CEA</strong> NEWS 30 September <strong>2007</strong>


G8 Global Partnership<br />

Activity report<br />

2004-2005-2006<br />

(french and english version.<br />

Russian version available on<br />

line http://www-pmg8.cea.fr)<br />

> These brochures are<br />

available upon<br />

request in paper<br />

format or on line :<br />

www.cea.fr<br />

EXHIBITIONS<br />

© <strong>CEA</strong><br />

produced from any primary energy source (solar,<br />

wind, nuclear, etc.) and used in a “fuel cell” to<br />

generate high yields of electricity and heat, with<br />

water as its only waste product!<br />

To raise awareness about this important technology,<br />

the Palais de la Découverte, a science museum in<br />

Paris, has created a traveling exhibition (first stop<br />

in Berlin at the Technikmuseum, from May 24 th<br />

to July 24 th , <strong>2007</strong>, then on to the Visiatome before<br />

the end of the year). The exhibition covers all the<br />

steps studied at the <strong>CEA</strong>: production of electricity<br />

using photovoltaic panels, production of hydrogen<br />

by electrolysis, storage and retrieval of electrical<br />

energy using fuel cells. To illustrate how the<br />

research works, the exhibition uses prototypes<br />

and laboratory equipment, including the Genepac<br />

fuel cell, metal plates, graphite plates and<br />

membranes, along with an educational pack about<br />

fuel cells.<br />

As part of its renovation project, the Palais de la<br />

Découverte will present a stationary version of<br />

this exhibition in Paris.<br />

ICAPP <strong>2007</strong><br />

International Congress on Advances in Nuclear Power<br />

Plants - “Nuclear Renaissance at Work.” - May 13-<br />

18, <strong>2007</strong> • Nice Acropolis, France<br />

The <strong>CEA</strong> participated in the <strong>2007</strong> ICAPP<br />

international conference on progress in nuclear<br />

power plants, covering design, construction,<br />

operation, and maintenance. This professional<br />

gathering brought together the most important<br />

international stakeholders in the electronuclear<br />

industry around the theme of “nuclear renaissance”.<br />

It was an occasion for the Nuclear Energy Division<br />

of the <strong>CEA</strong> to present its research and development<br />

milestones in several areas and to co-chair the<br />

plenary session dedicated to nuclear systems of<br />

the future. The papers presented by the <strong>CEA</strong><br />

addressed the following areas:<br />

• Research to optimize existing industrial nuclear<br />

facilities and development of third-generation<br />

systems (optimization of fuels and plant life<br />

spans, better procedures for spent fuel processing,<br />

advanced methods of computer simulation, etc.)<br />

• The <strong>CEA</strong>'s commitment to the nuclear systems<br />

of the future (strategy and planning for sodiumcooled<br />

fast reactors, materials and fuel<br />

innovations, and new options for the back end<br />

of the fuel cycle and waste management)<br />

Finally, this conference allowed several major<br />

nuclear actors abroad (USA, Japan, Russia, China,<br />

South Korea, etc.) to share their vision of the<br />

nuclear renaissance.<br />

Following the conference, the participants toured the<br />

<strong>CEA</strong>'s Marcoule and Cadarache centers.They visited<br />

certain advanced facilities for nuclear research, such<br />

as Atalante, a large laboratory dedicated to actinide<br />

chemistry, and Tore Supra, a tokamak for fusion<br />

energy studies.<br />

The 20 th World Energy<br />

Congress & Exhibition<br />

is promoted by the World<br />

Energy Council (WEC*)<br />

This is the most authoritative international energy<br />

meeting, to be held in Rome in the new “Nuova<br />

Fiera” venue, November 11-15, <strong>2007</strong>. Excellent<br />

speakers and thousands of participants will come<br />

from all over the world. Besides the World Energy<br />

Council Members, the Congress will welcome<br />

exhibitors from both energy producing and<br />

consuming countries, institutions, international<br />

organizations and energy industry representatives,<br />

researchers and experts from all over the world,<br />

and all those who are interested in energy and<br />

development issues. During the four-day meeting,<br />

participants will have the chance to visit an<br />

interesting and important exhibition covering<br />

20,000 m 2 at the “Nuova Fiera”. Companies<br />

will have a great opportunity to present their<br />

products and technological innovations for the<br />

energy industry to an international and<br />

distinguished audience.<br />

*With several Member Committees in over 90 countries, WEC<br />

aims to monitor the status of the energy industry and find<br />

solutions fostering the economic development of both industrialized<br />

and developing countries. It also promotes the sustainable supply<br />

and usage of energy for the greatest benefit of all people.<br />

© <strong>CEA</strong><br />

Transducers 07<br />

TRANSDUCERS has grown into the largest<br />

multidisciplinary conference on microsensors,<br />

microactuators, and microsystems, with typically<br />

900 attendees from government and industry who<br />

gather every two years to share information on<br />

the latest advances in the field. This year, the<br />

technical program consisted of parallel oral sessions<br />

and poster presentations. Invited speakers<br />

(including researchers from LETI, the <strong>CEA</strong><br />

laboratory of electronics and information<br />

technology) gave insightful<br />

overviews on key topics<br />

during the plenary session<br />

and throughout the<br />

conference, which also<br />

included short courses and<br />

exhibitions.<br />

TRANSDUCERS 07 was<br />

held in Lyon, France,<br />

<strong>2007</strong>, June 10-14<br />

Visiatome<br />

The Visiatome is located in Southern France in<br />

Marcoule, not far from Nîmes. This scientific<br />

cultural center was created to inform the public<br />

and answer questions related to radioactivity and<br />

its applications, the various sources of energy,<br />

radioactive waste management, and the nuclear<br />

industry in general.<br />

The 600-m 2 site offers fun, interactive exhibitions<br />

addressing all these questions. Educational sessions<br />

are available to school groups, and scientific<br />

activities are offered Wednesday afternoons,<br />

Sundays, and during school vacations.<br />

> Practical info<br />

Visiatome - <strong>CEA</strong> Marcoule - BP 64172<br />

30207 Bagnols-sur-Cèze cedex<br />

www.visiatome.fr<br />

To learn more: Tel: +33 (0)4 66 39 78 78<br />

contact.info@visiatome.com<br />

Reservations: Tel: +33 (0)4 66 39 78 78<br />

Fax: +33 (0)4 66 39 78 30<br />

reservation@visiatome.com<br />

© C. Dupont/<strong>CEA</strong> © P. Stroppa/<strong>CEA</strong><br />

<strong>CEA</strong> NEWS 31 September <strong>2007</strong>


<strong>CEA</strong> EMBASSY<br />

COUNSELOR NETWORK<br />

WASHINGTON<br />

Jacques FIGUET<br />

nuclear.counselor@ambafrance-us.org<br />

BERLIN<br />

Jean-Marc CAPDEVILA<br />

jean-marc.capdevila@diplomatie.gouv.fr<br />

LONDRES<br />

Alain REGENT<br />

alain.regent@cea.fr<br />

HELSINKI<br />

Claude SAINTE-CATHERINE<br />

claude.sainte-catherine@cea.fr<br />

BUDAPEST<br />

Gérard COGNET<br />

gerard.cognet@cea.fr<br />

MOSCOU<br />

Denis FLORY<br />

nucleaire.moscou@diplomatie.gouv.fr<br />

NEW-DELHI<br />

Hugues de LONGEVIALLE<br />

hugues.de-longevialle@cea.fr<br />

SEOUL<br />

Jean-Yves DOYEN<br />

energykorea@kornet.net<br />

BRUSSELS - EU<br />

Guillaume GILLET<br />

guillaume.gillet@diplomatie.gouv.fr<br />

TOKYO<br />

Pierre-Yves Cordier<br />

pierre-yves.cordier@cea.fr<br />

PARIS<br />

<strong>CEA</strong> Headquarters<br />

ceanews.contact@cea.fr<br />

VIENNA - AIEA<br />

Marc-Gérard ALBERT<br />

marc-gerard.albert@diplomatie.gouv.fr<br />

BEIJING<br />

Alain TOURNYOL du CLOS<br />

servnucpekin@yahoo.com<br />

www.cea.fr<br />

More information: ceanews.contact@cea.fr

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