CEA News sept. 2007 - CEA Saclay
CEA News sept. 2007 - CEA Saclay
CEA News sept. 2007 - CEA Saclay
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© P. Stroppa/<strong>CEA</strong> © Artechnique/<strong>CEA</strong><br />
8<br />
4<br />
AROUND<br />
THE WORLD<br />
/// Global Nuclear Energy Partnership<br />
/// ESARDA Conference<br />
/// President of the Chinese Academy<br />
of Sciences visits the <strong>CEA</strong><br />
/// Speech on Nuclear Power in<br />
European Parliament<br />
/// Start of construction work for JHR<br />
16<br />
24<br />
SCIENTIFIC<br />
HIGHLIGHTS<br />
ADVANCED<br />
PARTITIONING<br />
SOLUTIONS FOR<br />
RADIOACTIVE WASTE<br />
/// Review of 15 years of research<br />
/// Partitioning<br />
/// 2006: the new law<br />
NANOSCIENCES<br />
UNDERSTANDING THE<br />
NEW LAWS OF PHYSICS<br />
/// Nanostructured matter<br />
/// Quantum effects<br />
/// How are nano-objects designed?<br />
/// The toxicity of nano-objects<br />
/// MINATEC ®<br />
/// Dynamics of the Earth’s<br />
magnetic field reproduced<br />
in laboratory<br />
/// XEDIX : 100 TB of<br />
data screened<br />
© P. Stroppa/<strong>CEA</strong> © <strong>CEA</strong>/Lesénechal<br />
/// Atlas, accelerating<br />
detection<br />
/// First complete simulation<br />
of PET imaging scan<br />
/// Superdoped silicon:<br />
an excellent conductor<br />
<strong>CEA</strong> <strong>News</strong> is edited by the French Atomic Energy Commission – Communication<br />
Division – Headquarters – 91191 Gif-sur-Yvette cedex - France - www.cea.fr<br />
Publication Director: Xavier Clément<br />
Contributors to this edition: Claire Abou, Anne-Marie Birac, Patrick Cappe de Baillon,<br />
Olivier Caron, Xavier Clément, Elisabeth De Lavergne, Thierry Ethvignot,<br />
Didier Kechemair, Florence Klotz, Lucia Le Clech, Brigitte Raffray<br />
ceanews.contact@cea.fr<br />
Graphic design: MAYA press - www.mayapress.net<br />
Cover photo: Carbon nanotube models in front of a nanotube “mat” viewed<br />
under the microscope. © <strong>CEA</strong><br />
30<br />
BOOK REVIEW<br />
31 EXHIBITIONS<br />
<strong>CEA</strong> NEWS 2 September <strong>2007</strong>
FOREWORD<br />
Nuclear Energy’s Responsible,<br />
Sustainable Future<br />
© L.Godart/<strong>CEA</strong><br />
Welcome to this second issue of <strong>CEA</strong> NEWS, the international publication of the French<br />
Atomic Energy Commission. <strong>CEA</strong> is committed to providing in-depth but wide ranging<br />
coverage of its activities ands achievements. We hope that this issue conforms to this goal.<br />
Since our last issue, momentous events have taken place in our country including the<br />
election of a new administration and the establishment of a new government. One of the<br />
new government’s priorities is a determined undertaking to expand the research effort in<br />
our country and to reform the governance and operations of universities. We at <strong>CEA</strong><br />
welcome this development, which corresponds to our deeply held view that partnership<br />
with a strong and reactive academic sector can only be of benefit to an institution such as<br />
ours, that thrives on cross-fertilization with our domestic and international partners in<br />
both the academic and industrial sectors. We are all the more convinced that our mission<br />
is to contribute to the building of the knowledge-based, high-valued added economy that<br />
must rest on a deliberate as well as unrelenting effort in both fundamental and applied<br />
research. This, one might add, is also a key to nurturing the international partnerships that<br />
we at <strong>CEA</strong> value as a core component of our strategy.<br />
Mr. Olivier Caron<br />
Director of International Relations<br />
In the field of energy, which remains at the forefront<br />
of our priorities, <strong>CEA</strong> is committed to partaking in<br />
national and international efforts and undertakings<br />
that will foster the responsible and sustainable drive<br />
toward expanded recourse to nuclear energy. If we<br />
are to offer humanity reliable and cost-effective access<br />
to this energy source, it is of prime import that new<br />
nuclear programmes – as well as mature or<br />
expanding ones – adopt or continue to uphold the<br />
highest safety and spent fuel management standards.<br />
It is an economic requirement as well as a civic duty<br />
and moral responsibility to see to it that nuclear<br />
expansion does not result in the unwarranted<br />
accumulation and dissemination of spent fuels. A<br />
fundamental rethink of security and nonproliferation<br />
tenets are in order to address this<br />
challenge successfully. We in France pride ourselves<br />
on having pioneered an approach to the fuel cycle<br />
that is precisely geared toward rising up to the<br />
magnitude of the issue. And we are glad to see that<br />
our major international partners are now willing to<br />
reengage on the closed fuel cycle issue. This is a<br />
heartening testimony to the virtues of patient and<br />
steadfast policy development, based on confidence in<br />
science and an acute awareness of the need to engage<br />
public opinion and policy-makers. On this optimistic<br />
note, I invite you to enjoy agreeable and thoughtprovoking<br />
reading while awaiting our next issue. ■<br />
<strong>CEA</strong> NEWS 3 September <strong>2007</strong>
AroundTheWorld<br />
Global Nuclear Energy Partnership – Joint statement<br />
by France, China, Japan, USA and Russia<br />
Representatives of five nations (France, China,<br />
Japan, USA and Russia) and the International<br />
Atomic Energy Agency (IAEA) were invited<br />
by Samuel Bodman, US Secretary of Energy<br />
to a Ministerial Conference on the Global<br />
Nuclear Energy Partnership (GNEP) in<br />
Washington on May 21, <strong>2007</strong>. The French<br />
delegation was led by Alain Bugat, Chairman<br />
of the <strong>CEA</strong>. A joint statement was issued at<br />
the end of the conference.<br />
The GNEP is a US initiative to kick-start nuclear energy once<br />
again. On a domestic level, it aims to close off the fuel cycle and<br />
ensure large-scale reprocessing of spent fuel. Its international<br />
aims are to prevent the spread of technology that has proliferation<br />
potential, to seek partnerships with<br />
countries wishing to access nuclear<br />
energy and to increase its use. The<br />
goal is to offer spent fuel reprocessing<br />
and recycling solutions without<br />
requiring domestic facilities to be<br />
built. This will complement the<br />
IAEA's efforts to fine-tune its preproduction<br />
fuel service supply<br />
guarantee mechanisms.<br />
Research and development into advanced cycle technologies<br />
and fast reactors to burn actinides is also a subject of consultation<br />
and coordination as part of the Generation IV International<br />
Forum (GIF), currently chaired by France.<br />
© A. Gonin/<strong>CEA</strong><br />
SECURITY AND NON-PROFILERATION<br />
<strong>CEA</strong> and IRSN at the ESARDA conference<br />
The <strong>CEA</strong> and IRSN both took part in the 29 th conference of ESARDA, the European<br />
Safeguards Research & Development Association from May 22 to 24 in Aix-en-Provence.<br />
This association was established in 1969 and draws together research laboratories,<br />
industrial operators, inspection bodies and government ministers from the member<br />
states of the European Union. ESARDA's goal is to facilitate R&D cooperation between<br />
the various players involved in nuclear material security controls.<br />
Around three hundred experts in the field of nuclear security and non-proliferation met<br />
for three days to review the control of nuclear materials in the European Union and<br />
around the world.<br />
Representatives of organizations such as the IAEA 1 , ABACC 2 and INMM 3 are regular<br />
participants. Olli Heinonen, Deputy Director General of the IAEA, Roland Schenkel,<br />
Director General of the Joint Research Centre (JCR – European Commission) and<br />
Dominique Ristori, Deputy Director General of the Directorate-General for Energy<br />
and Transport (DGTREN – European Commission) all spoke at the conference.<br />
Olivier Caron, <strong>CEA</strong> Director of International Relations and France's governor on the<br />
IAEA board, spoke about French policies in the areas of nuclear security and compliance<br />
with international treaties. Emmanuel Sartorius, Senior Defence and Security Official<br />
in charge of domestic control of nuclear materials, spoke about control issues in France.<br />
Video tracking : A digital camera may be attached to the radiation monitor for video capture and identification.<br />
1. IAEA: International Atomic Energy Agency, responsible for the NPT inspection provisions.<br />
2. ABACC: Brazilian- Argentine Agency for Accounting and Control of nuclear materials (regional control agency).<br />
3. INMM : Institute of Nuclear Materials Management (USA).<br />
Two types of controls apply to nuclear<br />
materials in Europe: first, security<br />
controls as instituted by the Euratom<br />
Treaty (effective since 1958), and second,<br />
nuclear weapons non-proliferation<br />
controls (NPT, effective since 1970). The<br />
inspection provisions in both treaties<br />
cover the full range of controls in order<br />
to ensure that members comply with<br />
nuclear proliferation restraints. The<br />
association's work brings the field's<br />
many experts and practitioners together<br />
to discuss relevant general topics and<br />
detailed issues that relate to particular<br />
types of nuclear facilities. The<br />
association also promotes discussion<br />
with nuclear operators and researchers<br />
to facilitate cooperation in the area of<br />
international controls, thus ensuring that<br />
treaties are applied as comprehensively<br />
as possible and that new control<br />
technologies continue to be developed.<br />
<strong>CEA</strong> NEWS 4 September <strong>2007</strong>
AroundTheWorld<br />
A NEW FRANCO-CHINESE PARTICLE<br />
PHYSICS LABORATORY<br />
Alain Bugat, Chairman of the <strong>CEA</strong>,<br />
Catherine Bréchignac, President of the<br />
CNRS, Arnold Migus, Director General<br />
of the CNRS and Lu Yongxiang,<br />
President of the Chinese Academy<br />
of Sciences, have inked an agreement<br />
to set up a Franco-Chinese international<br />
associate particle physics laboratory,<br />
the France-China Particle Physics<br />
Laboratory (FCPPL). This agreement<br />
formalises a longstanding partnership<br />
between France and China in this field,<br />
officially recognising the joint work of<br />
more than 250 researchers, engineers<br />
and students from the two countries.<br />
The France-China Particle Physics<br />
Laboratory (FCPPL) has been set up<br />
as part of a key strategy of the CNRS<br />
IN2P3 organization (French national<br />
institute for nuclear and particle<br />
physics), consolidating its links with<br />
various Asian countries over the last<br />
two years. The institute works with<br />
Japan, South Korea, Vietnam, and<br />
particularly with China's rapidly<br />
expanding research sector. Several<br />
dozen scientists in France and China<br />
are already collaborating to study<br />
particle physics, astroparticles and<br />
cosmology.<br />
This agreement sets up a framework<br />
for establishing a genuine Franco-<br />
Chinese scientific community, with joint<br />
management, a joint steering committee<br />
and regular conferences. Many Chinese<br />
researchers have already been hosted<br />
by French laboratories, and the program<br />
will also allow French researchers to<br />
work in Chinese laboratories.<br />
Bilateral cooperation between <strong>CEA</strong> and Slovenia:<br />
Call for projects<br />
A second call for projects has been issued under the agreement executed on<br />
March 27, 2006 between the <strong>CEA</strong> and the Slovenian Minister for Higher Education,<br />
Science and Technology. The topics selected for <strong>2007</strong> are the following: life sciences,<br />
new energy technologies (fuel cells, biomass, etc.), new materials (catalytic materials,<br />
nanomaterials, etc.), nuclear energy (material ageing, etc.) and lasers.<br />
The goal of these one-year projects is to strengthen relations between the <strong>CEA</strong><br />
and Slovenian laboratories and to establish new joint ventures. This agreement<br />
provides an official framework for the work already in progress with the Republic<br />
of Slovenia. It shows the way to new areas for cooperation and strengthens<br />
current partnerships by contributing to the structures of European bilateral<br />
nuclear research in the context of the 7 th Framework Programme.<br />
The projects to receive backing were chosen on July 10, <strong>2007</strong> as part of the<br />
second Sterling Committee meeting that was held in Marcoule.<br />
© P. Stroppa/<strong>CEA</strong><br />
P hysics<br />
New scientific<br />
interest group –<br />
“Physics of the<br />
two infinities”<br />
Man has always sought to answer fundamental<br />
questions on the origins and evolution of<br />
the Universe. What is it made up of? What are<br />
the basic laws that govern it? What is its future?<br />
Pushing back the boundaries of knowledge<br />
and technology in these areas requires deeper<br />
investigation into phenomena occurring both<br />
on an infinitely small scale (elementary particles<br />
and quantum mechanics) and an infinitely<br />
large scale (cosmology and general relativity).<br />
These fascinating and closely related physics<br />
fields are the focus of the scientific interest<br />
group “Physics of the two infinities” (P2i) which<br />
was officially launched on 30 March <strong>2007</strong> and<br />
draws together 19 laboratories at the CNRS<br />
(National Centre for Scientific Research), <strong>CEA</strong><br />
(Atomic Energy Commission), the Paris<br />
Observatory and various higher education<br />
bodies (Pierre and Marie Curie University<br />
Paris 6), Paris Diderot University (Paris 7),<br />
Paris-Sud University (Paris 11) and the École<br />
Polytechnique.<br />
P2i has set itself the goals of achieving<br />
international recognition, increasing<br />
coordination in research and boosting the<br />
dynamism and resources of teams working in<br />
subatomic physics and cosmology in the Paris<br />
region. Particle physicists, nuclear physicists,<br />
theorists and astrophysicists will pool their<br />
equipment as part of the consortium. The aim<br />
is also to promote<br />
skill-sharing in order<br />
to tackle the major<br />
scientific challenges<br />
laid down by<br />
nature, such as the<br />
exploration of dark<br />
matter and dark<br />
energy, which are<br />
poorly understood,<br />
but together account<br />
for more than 95%<br />
of the Universe's<br />
energy density.<br />
© <strong>CEA</strong>/Dapnia<br />
<strong>CEA</strong> NEWS 5 September <strong>2007</strong>
AroundTheWorld<br />
© D.Marchand/<strong>CEA</strong><br />
Lu Yongxiang,<br />
President of the Chinese<br />
Academy of Sciences,<br />
visits the <strong>CEA</strong><br />
During his trip to France, Lu<br />
Yongxiang, President of the<br />
Chinese Academy of Sciences 1<br />
and Vice-Chairman of the People's<br />
National Congress visited <strong>Saclay</strong><br />
on April 11, <strong>2007</strong>. He was<br />
received by Yves Caristan, Director<br />
of Physical Sciences, André Syrota,<br />
Director of Life Sciences and<br />
Olivier Caron, Director of<br />
International Relations, and was<br />
shown the latest developments<br />
in the <strong>CEA</strong>'s work, witnessing at<br />
first hand the dynamic working<br />
environment at <strong>Saclay</strong>. Mr. Lu's<br />
visit included Soleil, the<br />
third generation synchrotron<br />
inaugurated last December, and<br />
NeuroSpin, the new intense-field<br />
nuclear magnetic resonance<br />
cerebral imaging (MRI) center.<br />
He then had a meeting with<br />
Bernard Bigot, High Commissioner<br />
for Atomic Energy.<br />
During the visit, <strong>CEA</strong> Chairman<br />
Alain Bugat signed two agreements<br />
on behalf of the <strong>CEA</strong> in the<br />
presence of Zhao Jinjun, Chinese<br />
Ambassador to France. The first<br />
was an agreement to set up an<br />
international associate laboratory<br />
involving the <strong>CEA</strong>, CNRS and the<br />
Chinese Academy of Sciences<br />
focusing on high-energy physics,<br />
and the second was an<br />
amendment to the agreement<br />
between the <strong>CEA</strong> and the Chinese<br />
Academy of Sciences on cosupervision<br />
of research projects.<br />
Mr. Lu emphasized the importance<br />
of the <strong>CEA</strong>'s collaboration to the<br />
Chinese Academy of Sciences, and<br />
described it as strategic. He<br />
suggested instituting a yearly forum<br />
to promote exchange between<br />
researchers from the two bodies.<br />
1. The Chinese Academy of Sciences is<br />
China's largest national research<br />
organization, with 58,000 staff.<br />
Start of<br />
construction work<br />
for Jules Horowitz<br />
research reactor<br />
Construction work on the Jules Horowitz research reactor<br />
(JHR) was launched by François Loos, Minster for Industry,<br />
on March 19, <strong>2007</strong>. Other figures who attended the ceremony,<br />
along with 500 other guests, included <strong>CEA</strong> Chairman Alain<br />
Bugat, Philippe Pradel, <strong>CEA</strong> Director of Nuclear Energy,<br />
Serge Durand, Director of the Cadarache research site and<br />
representatives of French industrial partners such as EDF<br />
and Areva.<br />
The goal of the Jules Horowitz Reactor is to develop and test<br />
new fuels and materials to be used in production reactors<br />
now and in the future, with a particular focus on Generation IV.<br />
In addition to the applications for power production, JHR<br />
will supply 25% of Europe's requirements for radioelements<br />
used in nuclear medicine and could contribute to the<br />
production of high-performance silicon<br />
for industrial and electronic<br />
components. The reactor is due<br />
for commissioning in 2014.<br />
©<strong>CEA</strong><br />
S ynergies<br />
New “Climate-Environment-Society” scientific interest group<br />
The newly established “Climate-Environment-<br />
Society” is a joint venture between the CNRS,<br />
<strong>CEA</strong>, the École Polytechnique, University<br />
of Versailles Saint-Quentin-en-Yvelines,<br />
University Pierre and Marie Curie and<br />
ADEME 1 . Its goal is to synergize experts’ skill<br />
sets to study climate change and its<br />
consequences for society and the environment.<br />
It will create solid links between researchers in complementary disciplines<br />
– climatology, ecology, medicine, economics and the social sciences –<br />
and promote the emergence of a more precise description of the<br />
interactions between climate change and future societal choices.<br />
The work will focus on the coordinated<br />
development of climate models, observation<br />
systems and tools for effecting change on<br />
the interfaces between climate and society.<br />
With the support of the Minister for Higher<br />
Education and Research and the Minister of<br />
Ecology and Sustainable Development, the<br />
research group will enjoy international stature,<br />
attracting foreign researchers and organizing conferences and<br />
communication campaigns.<br />
http://gisclimat.ipsl.jussieu.fr/<br />
1. The French Environment and Energy Management Agency<br />
© P. Bazoge/ <strong>CEA</strong><br />
<strong>CEA</strong> NEWS 6 September <strong>2007</strong>
AroundTheWorld<br />
© DR<br />
European Parliament:<br />
Speech by Oliver Caron<br />
on Nuclear Power<br />
Olivier Caron, <strong>CEA</strong> Director of<br />
International Relations and France's<br />
governor on the IAEA Board was<br />
invited to speak the European Energy<br />
Forum 1 , a discussion group led by<br />
British MEP Giles Chichester, former<br />
Chairman of the European Parliament<br />
ITRE Committee 2 .<br />
Mr. Caron's speech focused on the<br />
worldwide renewal of interest in<br />
nuclear energy. He described the<br />
world's current energy challenges<br />
(securing supply, combating climate<br />
change, remaining competitive) and<br />
demonstrated the vital place of this<br />
energy source. He highlighted the<br />
encouraging fact that discussions are<br />
underway within European<br />
institutions to develop a<br />
comprehensive energy policy across<br />
the European Union.<br />
After the speech, a discussion that<br />
included the fifteen or so MEPs in<br />
attendance (including representatives<br />
of the EU’s new member states)<br />
confirmed Parliament's interest in<br />
energy issues, including nuclear<br />
power in particular. There were<br />
discussions between the Committee<br />
and various MEPs on the question<br />
of nuclear safety and the requirement<br />
laid down during accession<br />
negotiations that some power stations,<br />
particularly in Bulgaria, be shut down.<br />
The issue of waste was brought up<br />
repeatedly. Mr. Caron took the<br />
opportunity to explain that technical<br />
solutions do exist and, referring to<br />
the French process, showed that waste<br />
processing is now an issue for political<br />
decision-making.<br />
1. More info:<br />
http://www.europeanenergyforum.eu/<br />
2. Industry, Telecoms, Research et Energy.<br />
FRANCO-JAPANESE DISCUSSIONS ON STORAGE<br />
The 5 th “information exchange” between EDF, <strong>CEA</strong> and CRIEPI (Japanese Central<br />
Research Institute of Electric Power Industry) was held in the Tokyo suburb of Abiko.<br />
Hervé Lagrave, high-level radwaste storage manager and Guillaume Ranc, expert in<br />
concrete structures, presented the most recent results from the Department of Fuel<br />
Cycle Technology on spent fuel storage, chiefly<br />
focusing on heat and air flows within storage<br />
facilities, the mechanical behavior of structures at<br />
temperature and the confinement of containers during<br />
accidents (earthquake or drop accident). These joint<br />
ventures should all be validated at the Management<br />
Committee meeting in September <strong>2007</strong>. The trip also<br />
provided an opportunity to visit the Abiko center’s laboratories, which are working on<br />
seal testing, dynamic characterization of concrete and chloride source terms; the<br />
Akagi site, looking at heating within concrete containers, metal container drop<br />
accidents and the transmission and use of electricity; the JAPC spent fuel dry<br />
storage facility and the Tokai-Daini Electricity museum.<br />
© Champion/<strong>CEA</strong><br />
7 th European<br />
Framework<br />
Program for<br />
Research and<br />
Development<br />
The 7 th Framework Program was officially launched<br />
on December 22, 2006 and is the main research<br />
funding instrument for the period <strong>2007</strong>-2013. “Its<br />
goal is to consolidate the European Research Area,”<br />
points out Claude Ayache, Director for European<br />
Affairs (<strong>CEA</strong>'s International Relations Division),<br />
“and it follows directly in the footsteps of the previous<br />
framework program. There is a concerted focus on<br />
a limited number of priorities, with coordination at<br />
all levels, among researchers, institutions and State<br />
research policies.The aim is not just to provide funding,<br />
but to continue to structure research throughout<br />
Europe research.” Nevertheless, new ambitions<br />
are set out in the 7 th framework programme for<br />
research and development, both in financial and<br />
political terms. The budget is up by a yearly<br />
average of 60% compared with the 6 th framework<br />
program, with a total envelope of € 54.5 billion<br />
over the period <strong>2007</strong>-2013. There are new<br />
challenges on the research side too. “The biggest<br />
of the challenges,” says Mr. Ayache, “is setting up<br />
the European Research Council. The aim is to promote<br />
scientific excellence by funding very high-level research,<br />
pushing back the boundaries of knowledge. Establishing<br />
exploratory research as a major factor for future<br />
competitiveness is a first within the European<br />
Community. Other new aspects of the 7 th framework<br />
program include a boost for industrial collaborations,<br />
with new forms of public-private partnerships,<br />
European Technology Partnerships and Joint<br />
Technology Initiatives (JTIs). Finally, there are two<br />
new research priorities, security and space.”<br />
TWO NEW <strong>CEA</strong> COUNSELORS IN EUROPE:<br />
- Alain Régent in London<br />
- Claude Sainte-Catherine in Helsinki<br />
Pierre-Yves Cordier replaces Dominique Ochem<br />
after his four-year stint, in Tokyo<br />
Please refer to the back cover for contact information.<br />
<strong>CEA</strong> NEWS 7 September <strong>2007</strong>
NANOSCIENCES<br />
UNDERSTANDING<br />
Stimulated by the<br />
race towards<br />
miniaturization in<br />
the microelectronics<br />
industry, research<br />
in Nanosciences is<br />
conducted at two<br />
departments within<br />
the Physical<br />
Sciences Division:<br />
the Drecam 1 in<br />
<strong>Saclay</strong> and the<br />
DRFMC 2 in Grenoble.<br />
This involves<br />
disciplinary fields at<br />
the crossroads of<br />
Chemistry, Physics<br />
and Biology.<br />
Activities at <strong>Saclay</strong><br />
in the spotlight.<br />
© C. Fuseau/<strong>CEA</strong><br />
NEW LAWS<br />
OF PHYSICS<br />
Scanning<br />
Electron<br />
Microscopy<br />
(SEM) is<br />
among the<br />
tools<br />
frequently<br />
used in<br />
nanoscience.<br />
Trying to manipulate nano-objects,<br />
understanding the behavior of finely<br />
divided matter, exploring quantum<br />
effects: these are some of the<br />
challenges facing fundamental<br />
research in nanosciences.<br />
At the level of atoms and molecules,<br />
there is a whole world to explore:<br />
the nanoworld, christened thus in<br />
reference to the nanometer, a<br />
billionth of a meter. Observing<br />
atoms and molecules individually<br />
became possible at the start of the<br />
1980s thanks to two inventions:<br />
the scanning tunneling microscope<br />
for materials that conduct electricity<br />
and its derivative, the atomic force<br />
microscope for insulating materials.<br />
These instruments are used both<br />
to observe surfaces and to<br />
manipulate atoms or molecules.<br />
Pooling the talents of chemists,<br />
physicists and biologists has played<br />
a decisive role in the creation of<br />
electronic devices and innovative<br />
materials.<br />
<strong>CEA</strong> NEWS 8 September <strong>2007</strong>
© <strong>CEA</strong><br />
TOPICS TO EXPLORE<br />
/// Nanostructured matter<br />
/// Quantum effects<br />
/// How are nano-objects designed?<br />
/// Toxicity of nano-objects<br />
/// MINATEC ®<br />
THE ADVANTAGES OF<br />
NANOSTRUCTURED MATTER<br />
How do the properties of particles change when their dimensions<br />
go from the micrometric to the nanometric scale?<br />
Pilot<br />
installation<br />
of nanopowder<br />
synthesis<br />
using the inflow<br />
pyrolysis<br />
method.<br />
Understanding the effect of size on the<br />
physical or chemical properties of particles<br />
is essential in nanosciences. The particles<br />
can be separated out individually in a powder<br />
state or bonded to solid materials. At the<br />
frontier between science and technology,<br />
researchers are shuttling back and forth<br />
between synthesizing materials, conducting<br />
experiments and performing numerical<br />
simulations and interpretations.<br />
A more radiation-resistant<br />
ceramic<br />
A ceramic is a material obtained by heat<br />
treatment (sintering) from powders generally<br />
of micrometric size. A team specializing in<br />
laser pyrolysis has developed an original<br />
technique for producing chemical composites<br />
in powders of calibrated sizes. According to<br />
recent experiments, ceramics made from<br />
nanometric powders produced in a laboratory<br />
are more resistant to radiation than traditional<br />
ceramics. In both cases, it is possible to<br />
see the grains, separated by grain boundaries,<br />
at different scales. Under the effect of<br />
radiation, defects appear in the crystalline<br />
organization of the grains and tend to merge<br />
until they hit an obstacle: the boundary. It<br />
seems that, in nanostructured ceramics, the<br />
SIZE GUIDE<br />
0.1 nm atom<br />
1 nm molecule<br />
10 nm protein<br />
100 nm DNA<br />
appearance of radiation damage is delayed<br />
because the web of particles is a thousand<br />
times finer. From the “materials” point of<br />
view, these ceramic nanopowders could<br />
be used in the composition of composite<br />
materials for the nuclear reactors of the future.<br />
A larger active surface area<br />
Another example of a divided (or<br />
nanostructured) material is the platinum in<br />
fuel cells. The chemical reactions that produce<br />
the current in the fuel cell are accelerated<br />
(or catalyzed) by this metal when the reagents<br />
“meet”, coming into contact with it. The use<br />
of fine platinum particles makes it possible<br />
to reduce the quantity of metal required.<br />
The size of these particles varies from a<br />
few nanometers to tens of nanometers.<br />
Researchers are proposing to replace them<br />
with particles of a perfectly calibrated size.<br />
A “coating” of organic molecules prevents<br />
the particles from forming clusters and means<br />
that the distance between metal cores can<br />
be finely regulated by the choice of grafted<br />
molecules. From the perspective of<br />
application to fuel cells, the electrical<br />
conductivity of these objects can be optimized<br />
according to their size. The icing on the cake<br />
is that combining these particles with carbon<br />
nanotubes would make the catalysis sites<br />
more accessible to the reagents and improve<br />
efficiency even more.<br />
1. Department of Research on Condensed Matter, Atoms and Molecules<br />
2. Condensed Matter Fundamental Research Department.<br />
A choice of colors<br />
One particular property of semiconductors<br />
is photoluminescence, which provides a<br />
spectacular illustration of the size effect.<br />
When they are lit, these materials give out<br />
some of the energy they receive by emitting<br />
light. The color (or energy) of this light is<br />
determined by the chemical nature and size<br />
of the semiconductor. If the specimen size<br />
is reduced to a few nanometers, there is<br />
constant variation in this color: the energy<br />
of the emitted light increases as the size of<br />
the object decreases. The behavior of the<br />
nanocrystal, also known as a quantum dot,<br />
seems to gradually approach that of an<br />
isolated atom. In particular, silicon<br />
nanocrystals, still produced by laser pyrolysis,<br />
could act as in vivo tracers for the diagnosis<br />
and treatment of diseases.<br />
© A. Gonin/<strong>CEA</strong><br />
> PYROLYSIS: chemical decomposition<br />
through the action of heat alone.<br />
© <strong>CEA</strong><br />
<strong>CEA</strong> NEWS 9 September <strong>2007</strong><br />
© Artechnique/<strong>CEA</strong>
NANOSCIENCES<br />
OBSERVING AND USING<br />
QUANTUM EFFECTS<br />
On the scale of atoms, electrons and photons, interactions<br />
between these entities are governed by quantum physics.<br />
This opens up new perspectives for nano-objects.<br />
© F. Vigouroux/<strong>CEA</strong><br />
© <strong>CEA</strong><br />
As one of the dimensions of a device<br />
approaches the size of an atom, the quantum<br />
effects inherent in microscopic physics appear.<br />
They are apparent, most notably, through<br />
discontinuous energy transfers, in “packets”<br />
known as quanta. These phenomena, invisible<br />
on a large scale, open up potentially very<br />
interesting paths for exploration. This is why<br />
researchers are making an effort to observe<br />
and use quantum effects in reasonably “large”<br />
experimental devices.<br />
WHAT IS<br />
A QUANTUM STATE?<br />
Much more than a binary piece of<br />
information, a “quantum state” is defined<br />
as a set of several simultaneously possible<br />
situations, each with a very specific<br />
probability of occurrence. An experimental<br />
measurement fixes the quantum state in a<br />
single one of these situations. To evaluate<br />
the probability attached to the situation, the<br />
measurement has to be repeated a very<br />
large number of times.<br />
Playing with electron spin<br />
Giant magnetoresistance (GMR) manifests<br />
itself as an increase in electricity conduction<br />
in an electronic device when a magnetic field<br />
is applied to it. This effect is explained on<br />
a quantum scale by electron spin, the<br />
electron's intrinsic rotation.<br />
The device consists of an assembly of two<br />
layers of metal with different magnetisms,<br />
separated by a very thin insulating layer<br />
(of the order of a nanometer). In one of<br />
the magnetic layers, the spin of the electrons<br />
is fixed by the prior state of magnetization<br />
of the material and in the other, it is subject<br />
both to the coupling with the first layer and<br />
to an external magnetic field. The degree<br />
of resistance to the passage of current, which<br />
acts as a sensor, depends on the electron spin<br />
configuration in the layers it is crossing: there<br />
is less resistance when the magnetizations<br />
are aligned than when they are opposed.<br />
GMR can be used to read (and write)<br />
information in the first magnetic layer or<br />
to measure a magnetic field.<br />
Discovered in 1998, GMR is today used<br />
on an industrial scale in the hard disks of<br />
our computers. The property is also exploited<br />
in highly sensitive sensors, one of which<br />
should be able to detect magnetic fields as<br />
tiny as those resulting from neuron activity.<br />
Regulating the electron ballet<br />
How do you describe the passage of an electric<br />
current through a metal conductor? Imagine<br />
a set of relays in which an atom (for instance<br />
copper) “gives” one of its electrons to a<br />
neighboring atom and “receives” another in<br />
>>><br />
“<br />
Our collaboration<br />
with companies in<br />
many sectors, and<br />
these applications, are<br />
nurturing the most<br />
fundamental research<br />
into magnetism.<br />
”<br />
© Artechnique/<strong>CEA</strong><br />
Myriam Pannetier-Lecœur<br />
Physical Sciences<br />
Division/Drecam/<strong>Saclay</strong><br />
Measurement<br />
set devoted to<br />
studying spinpolarized<br />
currents in<br />
magnetic<br />
nanostructures.<br />
<strong>CEA</strong> NEWS 10 September <strong>2007</strong>
Fundamental research<br />
experiment on magnetism<br />
based on giant<br />
magnetoresistance<br />
ELECTRONS<br />
TO SEE THE NANOWORLD<br />
MICROSCOPES THAT<br />
CAN “SEE” ATOMS<br />
AND MOLECULES<br />
How do we “see” the atoms and molecules<br />
in a solid individually? The “eye” of these<br />
microscopes is a tip that scans the surface<br />
to be analyzed by gliding over it at a fixed<br />
height of the order of a few atom<br />
diameters (a few tenths of a nanometer).<br />
This distance is adjusted by very shortrange<br />
interactions between the last atom<br />
right on the tip and the surface.<br />
Microscope resolution is limited by the diffraction<br />
of light crossing the specimen. This becomes<br />
even more of a problem as the wavelength of the<br />
light increases. Hence the idea of replacing<br />
photons with electrons, which have a shorter<br />
wavelength. In transmission electron microscopy<br />
(TEM), a flow of electrons is passed through the<br />
specimen and detected to form the image.<br />
Resolution can go below a nanometer.<br />
Meanwhile, the scanning electron microscope<br />
(SEM) uses secondary electrons emitted by the<br />
specimen when it is bombarded with electrons,<br />
on the same side as the source. This time the<br />
resolution is of the order of a nanometer.<br />
“<br />
With the benefit of experience,<br />
theoretical formalism has been pushed<br />
out in favor of intuition and inventiveness.<br />
© C. Dupont/<strong>CEA</strong><br />
Christian Glattli<br />
Physical Sciences Division/Drecam/<strong>Saclay</strong><br />
”<br />
© <strong>CEA</strong>-LEM<br />
In the scanning tunneling microscope (STM)<br />
this interaction, quantum in nature, is<br />
manifested by a weak electric current that<br />
flows between the atom on the tip and the<br />
surface. This current rapidly increases as the<br />
tip gets closer to the surface. In the atomic<br />
force microscope (AFM), similar forces to<br />
those that make atoms bond in a molecule<br />
are at work between the atom on the tip and<br />
the atoms on the surface. At even shorter<br />
distances, forces of repulsion predominate<br />
between the atomic nuclei. Subject to these<br />
antagonistic forces, the atom spontaneously<br />
tries to remain at a fixed distance.<br />
In both cases, a computer records either<br />
the current or the force, and keeps the tip<br />
at a constant distance from the surface. The<br />
relief “felt” by the tip can be reconstituted<br />
in this way with resolution of less than a<br />
nanometer, giving the user an atom-byatom<br />
picture of the material being studied.<br />
return. Under normal conditions, electrons<br />
barely move more than about thirty nanometers<br />
before experiencing a collision that “erases”<br />
their quantum effects. To observe the effects,<br />
it is necessary to reduce the number of<br />
collisions or to thin out the electron population<br />
and extend the free trajectory of the electrons.<br />
This is why some researchers have chosen<br />
to study the interface between two<br />
semiconducting layers 1 , working at very low<br />
temperatures to attenuate the thermal agitation<br />
of the atoms. The electrons can therefore<br />
spread out almost freely in a plane, typically<br />
over about ten thousand nanometers. The<br />
apparatus also has electrodes that control<br />
the opening of a passage for the electrons, a<br />
few hundred nanometers wide.<br />
What is observed? As the passage opens, the<br />
conductance of the system, i.e. its ability to<br />
conduct current, increases in steps! These<br />
steps correspond to the multiples of a<br />
fundamental constant known as a conductance<br />
quantum – another quantum effect! These<br />
effects can also be seen in metals when two<br />
electrodes are linked by just one or more<br />
atoms. What is even more extraordinary is<br />
that the phenomenon generates almost no<br />
spurious background noise! These “new”<br />
laws apply to nanocomponents such as carbon<br />
nanotubes, which transmit four conductance<br />
quanta – no more and no less…<br />
1. Made from gallium arsenide (AsGa) and gallium arsenide<br />
and aluminum (AsGaAl) respectively. The density of<br />
moving electrons is governed by the dopant concentration.<br />
<strong>CEA</strong> NEWS 11 September <strong>2007</strong>
NANOSCIENCES<br />
HOW ARE NANO-OBJECTS DESIGNED?<br />
The carbon nanotube, the material most emblematic of the nanosciences,<br />
is “coated” with molecules to massively increase its powers.<br />
The discovery of the carbon nanotube in<br />
1991 opened up a vast field of study in<br />
nanoelectronics. It is a long cylinder made<br />
from one or more rolled up sheets of carbon.<br />
The diameter of a carbon nanotube varies<br />
from a few nanometers for single-sheet tubes<br />
to about a hundred nanometers for those<br />
made from multiple sheets. What are their<br />
benefits? They are easily mass-produced<br />
to the point of becoming a commercial<br />
product. With a particular geometry, they<br />
can be semiconductors. Being much more<br />
stable than isolated molecules, they are easy<br />
to connect to electrodes. In 1998, the first<br />
transistor made with carbon nanotubes<br />
appeared.<br />
We will now look at some of the stages in<br />
the fabrication of nano-objects from carbon<br />
nanotubes.<br />
be highly practical for many types of<br />
manipulation. First it is necessary to “graft”<br />
organic molecules onto the nanotube that<br />
are capable of clinging to the nanotube's<br />
carbon atoms on the one hand, and giving<br />
it the required solubility properties on the<br />
other. One technique is to render soluble<br />
only the semiconductor nanotubes, so they<br />
can be sifted out. Once they are in a solution,<br />
the nanotubes can be diluted to obtain the<br />
desired rate of deposit on a surface.<br />
Molecular “coatings”:<br />
endless creativity<br />
It is now possible to “coat” the nanotubes,<br />
which simply means depositing molecules<br />
on their surface, attaching them solidly to<br />
the carbon atoms, or even inserting them<br />
inside the cylinders.<br />
The “coating” can make it possible for the<br />
nanotube to attach to a prepared surface, a<br />
bit like Velcro ® . More generally, combining<br />
nanotubes with molecules with specific<br />
electronic and optical properties is at the<br />
heart of research into molecular electronics.<br />
Nanotubes and DNA<br />
Some researchers are working on combining<br />
nano-objects such as DNA strands with<br />
carbon nanotubes to make T-shaped<br />
structures similar to those of a transistor.<br />
A kind of molecular Scotch ® tape needs to<br />
be devised to bind the nanotube and DNA<br />
together using real chemical bonds. In this<br />
case, nanotubes are being used because of<br />
their ability to be connected to electrodes.<br />
DNA could also be used as a “pattern” to<br />
guide the spontaneous assembly of carbon<br />
nanotube structures, along the same lines<br />
as biological processes.<br />
© <strong>CEA</strong><br />
Self-assembled carbon nanotubes on a surface of<br />
functionalized silica, connected electronically via gold wires.<br />
Preparing the bare nanotubes<br />
The first challenge is sorting the bare<br />
nanotubes, because they are a mixture of<br />
metallic objects and semiconductors. The<br />
second is that nanotubes are not soluble, so<br />
in their ordinary state they cannot be<br />
incorporated into a solvent, which would<br />
© Motorola/<strong>CEA</strong><br />
FROM NANOTUBES<br />
TO NANORINGS<br />
It sometimes happens that the<br />
unexpected texture of the<br />
chemical “coatings” of nanotubes<br />
inspires researchers, leading to<br />
the creation of some surprising<br />
nano-objects – nanorings, for<br />
example! Observation of ring<br />
structures under a transmission<br />
electron microscope led them to<br />
include reactive functions in the<br />
initial coating to stiffen the rings<br />
and detach them from the nanotube. These nanorings could carry anti-cancer molecules<br />
to diseased cells. This drug vectorization project is being carried out by a team from<br />
Divison of Life Sciences in partnership with Laboratoire Servier. Another application, with<br />
a more fundamental aim, is to use the nanorings as a substitute cell membrane for<br />
studying proteins in cells. These proteins degrade as soon as they are removed from<br />
their environment.<br />
© A. Gonin/<strong>CEA</strong><br />
<strong>CEA</strong> NEWS 12 September <strong>2007</strong>
Preparing<br />
impermeability tests<br />
for nanoparticles in<br />
protection equipment<br />
(masks and gloves), as<br />
part of the European<br />
Nanosafe2 project.<br />
© F. Vigouroux/<strong>CEA</strong><br />
EVALUATING THE TOXICITY<br />
OF NANO-OBJECTS<br />
Several <strong>CEA</strong> laboratories are participating in national and<br />
European programs to evaluate the risks from nanoparticles.<br />
How is their impact on health and the environment measured?<br />
© <strong>CEA</strong><br />
> TRANSISTOR:<br />
component that<br />
performs the functions<br />
of an amplifier,<br />
modulator or<br />
interrupter of<br />
electrical current.<br />
> DNA:<br />
deoxyribonucleic acid,<br />
an essential<br />
component of<br />
chromosomes, and the<br />
physical carrier of<br />
heredity.<br />
On a small scale, matter divided into<br />
nanoparticles has a larger surface area than<br />
ordinary matter. This could exacerbate its<br />
toxicity. Furthermore, nanoparticles have a<br />
natural tendency to form groups of<br />
micrometric size. Before a toxicological study<br />
is carried out, it is necessary to know the<br />
chemical nature of the particles, their structure<br />
and the physical and chemical state of their<br />
constituents. Finding out this information<br />
requires specialist skills and highly specialized<br />
analysis methods. When it comes to studying<br />
nanoparticles in suspension in the air, there<br />
is a particular problem: how can they be<br />
isolated or distinguished from ordinary<br />
atmospheric pollution?<br />
What effect do they have on<br />
animal cells and bacteria?<br />
Various teams are trying to assess the toxicity<br />
of nano-objects for humans using in vitro<br />
animal cell models. The aim is to study the<br />
biological effects on the organs they reach<br />
following inhalation or ingestion (lungs, liver)<br />
or following their passage through the body's<br />
natural barriers (kidneys).<br />
Two effects are being studied: the toxicity for<br />
the whole cell on the one hand and for the<br />
genes it contains on the other. Can<br />
nanoparticles pass through the cell<br />
membrane? Does the cell remain alive? Is its<br />
genetic material affected?<br />
Researchers are also interested in what<br />
happens in the environment to nanoparticles<br />
released by the decomposition of consumer<br />
products which have components containing<br />
them. The first targets to be looked at are<br />
bacteria in the ground and water. Are the<br />
nanoparticles trapped on the surface of the<br />
bacterium? Do they go inside it? If so, what<br />
happens to them? Do the bacteria put up<br />
any resistance?<br />
Toxicity and exposure<br />
These toxicological studies do not yet take<br />
account of the processes of exposure of cells<br />
in the body, which is a more complex<br />
environment than in vitro experiments<br />
provide. Until the results of the full toxicology<br />
study program are available, those working<br />
in laboratories are avoiding contact with<br />
nanoparticles by using containment methods<br />
(air locks, filters, packaging of powders, etc.).<br />
<strong>CEA</strong> NEWS 13 September <strong>2007</strong>
NANOSCIENCES<br />
Jean-Philippe<br />
Bourgoin<br />
of the Physical Sciences<br />
Division, director of<br />
<strong>CEA</strong>’s cross-disciplinary<br />
Nanosciences program<br />
INTERVIEW<br />
1. Minatec ® center was inaugurated in<br />
June 2006<br />
2. Scanning Electron Microscopy (SEM)<br />
performed on a nanocharacterisation<br />
platform<br />
3. Atomic force microscope used for nano<br />
and micro component imaging<br />
4. Automatic parametric tester<br />
to perform functional characterization on<br />
microsystems<br />
1<br />
5. Holographic and analytical Titan<br />
Transmission Electron Microscope (TEM)<br />
used to characterize materials<br />
6. Wafer to wafer assembly and<br />
lithography cluster<br />
7. Micro-traction station to study<br />
microsystems<br />
8. Programming the Endura 5500C<br />
machine to apply metal coating<br />
applications for Microsystems<br />
9. Lithography area for microsystems<br />
“ORGANIZING<br />
WORK AND<br />
SKILLS”<br />
© <strong>CEA</strong><br />
Why is such a program necessary?<br />
It’s a question of making early research in our<br />
fields – Information's Technologies, Health and<br />
Energy – more visible. It’s also a question of<br />
developing our partnerships most notably with<br />
CNRS and the universities, of strengthening<br />
the sectors in which we excel at fundamental<br />
research and of developing their application<br />
potential.<br />
What fields are covered?<br />
In addition to the work already in place on quantum<br />
electronics, chemistry for nanoelectronics,<br />
separation chemistry or spin electronics and<br />
nanomagnetism, new research subjects are<br />
emerging. We are interested in the behavior of<br />
fluids in fuel cells and biochips and in thermal<br />
exchanges in electronic components and<br />
refrigerant fluids. Simulation of nano-objects,<br />
materials and electronic<br />
components is also playing<br />
“<br />
an increasing role, as are<br />
particular aspects of nanocharacterization.<br />
Finally, in<br />
collaboration with crossdisciplinary<br />
programs on health<br />
technologies and materials, we<br />
have grouped and expanded the<br />
research launched by <strong>CEA</strong> since<br />
2001 on the potential risks from<br />
nanotechnologies.<br />
Simulation<br />
of nano-objects<br />
is also playing<br />
an increasing<br />
role in health<br />
technologies.<br />
”<br />
Sophie Astorg – Le journal de <strong>Saclay</strong> nr 36 – <strong>2007</strong>, April<br />
2<br />
3 4<br />
<strong>CEA</strong> NEWS 14 September <strong>2007</strong>
RESEARCH ON MICRO- AND<br />
NANOTECHNOLOGIES HOLDS<br />
PROMISE... WITH MINATEC ®<br />
6 7<br />
5<br />
8<br />
While Nanosciences are studied in both <strong>Saclay</strong> and Grenoble,<br />
research into Nanotechnology is mainly conducted at the<br />
Minatec ® labs in Grenoble.<br />
Initiated by <strong>CEA</strong>-LETI 1 and INP 2<br />
Grenoble, the Minatec ® center was<br />
inaugurated in early June 2006. It's an<br />
impressive site with 44,000 m 2 of new<br />
buildings spread over roughly 20 acres<br />
of land – becoming a major European<br />
innovation and consulting center for<br />
micro- and nanotechnologies demands<br />
significant investment. “Grenoble's<br />
nanoscience and nanotechnology center is<br />
an extension of all the programs recently<br />
implemented by public authorities for<br />
research and its application,” declared<br />
François Goulard, Minister Delegate for<br />
higher education and research, during<br />
his visit to the <strong>CEA</strong>'s Grenoble center<br />
on October 31 st , 2006.<br />
The Minatec ® concept is unique in both<br />
France and Europe. Why? Because it<br />
brings students and teachers as well as<br />
researchers and people from industry.<br />
Minatec ® gives them the chance to<br />
exchange ideas and work together at a<br />
single location. As a result, “upstream”<br />
research is undertaken by scientists in<br />
the Physical Sciences Division, whereas<br />
“downstream” projects tend to be handled<br />
by researchers in the Technological<br />
Research Division. Which is in keeping<br />
with the race to miniaturize and the era<br />
of the infinitely tiny, both well underway.<br />
It is imperative to harness the most<br />
fundamental properties of matter, push<br />
back the limits of current technologies,<br />
and map out new technologies within<br />
a multidisciplinary framework. Minatec ®<br />
will focus on major research themes such<br />
as microelectronics, nanoscience applied<br />
to biology or new materials, and software.<br />
No less than 3,500 engineers, researchers,<br />
and academics will strive to meet this<br />
objective, using the most advanced<br />
equipment and technological resources.<br />
Nanomaterials have inspired high hopes<br />
and should lead to all sorts of products<br />
that are both competitive and<br />
environmentally friendly. Being more<br />
and more efficient means producing on<br />
an ever smaller scale, with lower<br />
costs and higher performance. We<br />
immediately think of cell phones,<br />
computers, and so forth, but the realworld<br />
applications of this research are<br />
far more numerous: in the automotive<br />
industry, for healthcare, entertainment,<br />
safety, etc.<br />
1. Laboratoire d'électronique et de technologie<br />
de l'information (electronics and information<br />
technology laboratory).<br />
2.Institut National Polytechnique (engineering<br />
school).<br />
> For more information:<br />
http://www.minatec.com/minatec_uk/index.htm<br />
Photos 1-4 & 6-9: © P. Stroppa/<strong>CEA</strong><br />
Photo 5: © C. Morel/<strong>CEA</strong><br />
9<br />
<strong>CEA</strong> NEWS 15 September <strong>2007</strong>
WASTE – ADVANCED PARTITIONING<br />
SOLUTIONS FOR<br />
RADIOACTIVE WASTE<br />
How can<br />
radioactive waste<br />
be sustainably<br />
managed? The<br />
<strong>CEA</strong> (French<br />
Atomic Energy<br />
Commission) has<br />
been carrying out<br />
in-depth research<br />
under an Act dated<br />
December 30,<br />
1991 1 . Our report<br />
focuses on the<br />
three areas of<br />
investigation and<br />
their results.<br />
1. This act, also referred to as the “Bataille Act”, was transposed into the<br />
French Environment Code as Article L.542 in September 2000<br />
Storage hall in the <strong>Saclay</strong> center. Each of the<br />
100 shafts is ten meters deep, the highly irradiant<br />
drums are transferred to the shafts in a shipping<br />
cask and covered with a concrete plug.<br />
TOPICS TO EXPLORE<br />
/// Review of 15 years of research<br />
/// Partitioning<br />
/// 2006: the new law<br />
© P. Stroppa/<strong>CEA</strong><br />
<strong>CEA</strong> NEWS 16 September <strong>2007</strong>
Separating<br />
actinides:<br />
filtering operation<br />
in a glove box in<br />
the Atalante<br />
facility.<br />
© T. Foulon/<strong>CEA</strong><br />
In June 2005, ANDRA 2 and the<br />
<strong>CEA</strong> each submitted a report<br />
to the Ministry of Research<br />
reviewing their work on longlived,<br />
high level radioactive waste<br />
management, to enable the<br />
government to propose a bill that<br />
includes the solutions put<br />
forward for sustainable waste<br />
management. Nearly 80% of<br />
French electricity is currently<br />
produced by nuclear power<br />
plants, which ensures energy<br />
independence, standing France<br />
in good stead given oil<br />
price rises and limited fossil<br />
fuel supplies, and also<br />
ensures low greenhouse gas<br />
emissions. When France<br />
opted for nuclear power in<br />
the 1970s, it immediately<br />
started research into waste<br />
management. The 1991 Act<br />
gave the research a boost<br />
and focused on three<br />
areas: partitioning and<br />
transmutation, geological<br />
disposal and conditioning<br />
& storage. Research<br />
is still ongoing, but<br />
a large body of<br />
results has already<br />
been produced, showing the way<br />
to potential solutions.<br />
Let's take a look at three research<br />
areas that have focused French<br />
science on one major issue for<br />
a number of years: the sustainable<br />
management of radioactive material.<br />
2. French National Agency for Radioactive Waste Management.<br />
3. Spent fuel is processed in Cogema's La Hague plant.<br />
Research focus 1:<br />
Scientific demonstration<br />
of partitioning and<br />
transmutation (P&T)<br />
For the last twenty years or so,<br />
the French nuclear industry has<br />
been recycling 3 95% of its spent<br />
nuclear fuel, unburned uranium<br />
and plutonium, which is used<br />
for producing a new fuel cycle.<br />
The remaining 5%, which is<br />
waste, is immediately vitrified.<br />
Of this waste, the only items<br />
covered by the 1991 Act are longlived<br />
high-level radioactive<br />
elements (0.4% of the spent fuel).<br />
Research Focus 1 is looking<br />
into a way of separating the<br />
most radioactive elements for<br />
transmutation. The partitioning<br />
research undertaken at the Atalante<br />
facility at the <strong>CEA</strong> Valrhô center<br />
(at Marcoule, near Avignon) has<br />
demonstrated process feasibility<br />
in the laboratory. A high-yield<br />
transmutation process, where<br />
long-lived radioactive elements<br />
are bombarded with neutrons,<br />
can be performed in fast breeder<br />
reactors, as proven by the tests<br />
run in the <strong>CEA</strong>'s Phénix<br />
experimental reactor at Marcoule.<br />
However, partitioning and<br />
transmutation is not industrially<br />
feasible before 2040, and will<br />
only be used for waste produced<br />
after that time. The CNRS<br />
(French National Centre for<br />
>>><br />
Research<br />
reactor Phenix<br />
is dedicated to<br />
waste<br />
transmutation<br />
© A. Gonin/<strong>CEA</strong><br />
150<br />
The number of extracting molecules tested by<br />
researchers during studies into minor actinide<br />
partitioning.<br />
A TALANTE:<br />
T HE O NLY F ACILITY O F<br />
I TS T YPE IN T HE W ORLD<br />
The Atalante facility at Marcoule hosts highly specialized<br />
laboratories for work on improving spent fuel<br />
reprocessing procedures. It has been specially designed<br />
for studies into the management of long-lived high-level<br />
waste (HLW): design and testing of extraction molecules<br />
and studies into advanced partitioning processes,<br />
design and manufacturing of irradiation targets for<br />
transmutation and long term behavioral studies into<br />
waste in storage or repositories. The <strong>CEA</strong> is also<br />
developing methods for reprocessing and recycling fuel<br />
from the fast neutron energy production systems of the<br />
future. This unique facility is staffed by more than<br />
200 people. The commissioning of Atalante was<br />
announced by the ASN College (French Nuclear Safety<br />
Authority) on June 22, <strong>2007</strong>. ASN carried out a safety<br />
review at the same time.<br />
Special Issue – Les Défis du <strong>CEA</strong> – 2005, July<br />
© <strong>CEA</strong><br />
> TRANSMUTATION: The process of transforming a longlived<br />
radioactive element into an element with a shorter<br />
half-life or a stable element.<br />
<strong>CEA</strong> NEWS 17 September <strong>2007</strong><br />
© P. Stroppa/<strong>CEA</strong>
WASTE – ADVANCED PARTITIONING<br />
Scientific Research) is working<br />
on another transmutation method,<br />
using hybrid nuclear systems.<br />
Research focus 2:<br />
Towards reversible deep<br />
geological disposal<br />
ANDRA is working on the second<br />
research focus proposed in the<br />
1991 Act. It is looking at ultimate<br />
disposal of radioactive waste in<br />
deep geological repositories,<br />
capable of ensuring long-term<br />
containment several hundred<br />
meters below the ground. ANDRA<br />
(French National Agency for<br />
Radioactive Waste Management)<br />
is studying three rock types –<br />
granite, salt and clay. It has set up<br />
a field laboratory at Bure, in the<br />
Meuse region, that has been<br />
operational for several months. If<br />
the research is successful and<br />
political leaders make the relevant<br />
decisions, a geological disposal<br />
© P. Dumas/<strong>CEA</strong><br />
center should be built between<br />
2020 and 2025. According to the<br />
Parliamentary Office for the<br />
Evaluation of Scientific and<br />
Technological Choices, this is a<br />
vital option, but one that must be<br />
reversible. All nuclear-waste<br />
producing countries have selected<br />
this as an option. Likewise, experts<br />
from the International Atomic<br />
Energy Agency (IAEA), an UN<br />
authority recommend deep<br />
geological disposal, considering<br />
it the safest current option.<br />
Research focus 3:<br />
Increasingly<br />
high-quality storage<br />
Long-lived high level radioactive<br />
waste from spent fuel processing<br />
is currently vitrified and stored<br />
pending an ultimate solution, to<br />
be determined by the<br />
Government after a parliamentary<br />
debate. Current storage technologies<br />
and facilities have been much<br />
higher-performing over the last<br />
few years, improved through<br />
work by the <strong>CEA</strong> under Research<br />
Focus 3. New waste conditioning<br />
matrices developed at the <strong>CEA</strong><br />
Marcoule center have brought<br />
gains in terms of performance,<br />
reduced volumes and increaseddurability<br />
packages. The<br />
Parliamentary Office has judged<br />
France's currently operational<br />
storage facilities, at the Cogema<br />
plant at La Hague and the <strong>CEA</strong><br />
Cadarache center as highly<br />
efficient and fit to be safely used<br />
for another fifty years. The goal<br />
is to have storage facilities with<br />
a service life of 100 to 300 years.<br />
Amélie Kroell - Les Défis du <strong>CEA</strong> Nr 106<br />
2005, August<br />
Evolving Vitrification<br />
Prototype (AVP)<br />
1991-2006,<br />
a review of 15 years<br />
of research into<br />
advanced<br />
partitioning<br />
Under the “Bataille” Act, one of the<br />
major focuses in the drive to reduce<br />
the quantity and danger of long-lived<br />
high-level nuclear waste is to partition<br />
some long-lived radionuclides, either to<br />
transmute them or to carry out specific<br />
conditioning. After the 15 years of<br />
research prescribed by lawmakers,<br />
Christine Rostaing, “Advanced<br />
Partitioning” Project Manager, reviews<br />
the progress made in research in this<br />
field over the period.<br />
<strong>CEA</strong> NEWS 18 September <strong>2007</strong>
Most of the partitioning studies<br />
have focused on six radionuclides:<br />
• the minor actinides<br />
(americium Am, curium Cm<br />
and neptunium Np) which,<br />
after plutonium, are the main<br />
contributors to the long-term<br />
radio-toxic inventory of spent<br />
fuels,<br />
• three fission products<br />
(iodine I, cesium Cs and<br />
technetium Tc) which were<br />
selected due to their abundance<br />
in spent fuel, the existence of<br />
a long-lived isotope and their<br />
potential long-term mobility<br />
within a geological repository.<br />
The procedure used<br />
In order to perform minor actinide<br />
partitioning, extraction with a<br />
solvent was selected as the<br />
The entire processing and conditioning chain for highlevel<br />
radioactive waste was tested in Atalante: glove boxes<br />
comprised of a test loop for liquid-liquid extraction processes,<br />
a shielded process line on spent fuel and a selection of<br />
shielded compartments designed to host confinement<br />
matrices (glass, ceramic) and to study the long-term behavior<br />
of high-level waste packages; complemented by the shielded<br />
process line for experimentation, which confirmed the<br />
technical feasibility of advanced partitioning.<br />
reference procedure. This is a<br />
proven technique in the chemical<br />
industry and there is significant<br />
data available from operational<br />
use of the PUREX process at the<br />
La Hague plant over several<br />
decades. The strategy therefore<br />
consisted of:<br />
• firstly, adapting the PUREX<br />
process to recover neptunium,<br />
technetium and iodine.<br />
• secondly, developing complementary<br />
solvent-based extraction processes<br />
(hence the expression “advanced<br />
partitioning”) to separate out<br />
americium, curium and cesium<br />
from the high-level waste<br />
produced by the PUREX process<br />
currently vitrified.<br />
A target date of 2006 was set and<br />
the research was organized into<br />
two broad phases, aiming to<br />
demonstrate the scientific feasibility<br />
© P. Stroppa/<strong>CEA</strong><br />
(validating the basic concepts of<br />
partitioning) by the end of 2001<br />
and the technical feasibility (trials<br />
and overall validation of the<br />
processes) by 2005.<br />
The initial exploration phase<br />
was undertaken over a decade,<br />
involving wide-ranging cooperative<br />
ventures. It consisted of assessing<br />
the various extraction systems,<br />
chiefly targeting the trickiest stage<br />
– separating the actinides from<br />
the lanthanides. The second<br />
demonstration phase, between<br />
2002 and 2005, focused on the<br />
processes deemed the most<br />
promising.<br />
A three-stage approach<br />
It is not easy to recover and<br />
separate the minor actinides<br />
(americium and curium) within<br />
>>><br />
PARTITIONING<br />
BY LIQUID-<br />
LIQUID<br />
EXTRACTION<br />
Liquid-liquid extraction<br />
is a technique that<br />
uses two immiscible<br />
liquids, one aqueous<br />
phase and one organic<br />
phase. The elements to<br />
be separated are all<br />
dissolved in the<br />
aqueous phase and a<br />
special molecule,<br />
referred to as the<br />
“extracting” molecule,<br />
is dissolved in the<br />
organic phase. The role<br />
of this molecule is to<br />
capture the elements<br />
required for separation<br />
within the aqueous<br />
phase and to take them<br />
with it (extract them)<br />
into the organic phase.<br />
This molecule needs to<br />
be both effective<br />
(having a good affinity<br />
with the elements to be<br />
separated) and<br />
selective (affinity only<br />
with said elements).<br />
One of the major<br />
difficulties in designing<br />
a liquid-liquid<br />
extraction process is<br />
selecting this<br />
extracting molecule.<br />
Special Issue<br />
Les défis du <strong>CEA</strong> - 2005, July<br />
> PUREX:<br />
Purification by<br />
refining extraction.<br />
> LANTHANIDES:<br />
fission products<br />
from the lanthan<br />
family, with similar<br />
chemical properties<br />
to actinides.<br />
<strong>CEA</strong> NEWS 19 September <strong>2007</strong>
WASTE – ADVANCED PARTITIONING<br />
high-level waste (HLW). A number<br />
of factors make this a complex<br />
problem. The very similar chemical<br />
properties of the actinides (at<br />
oxidation degree III) and the<br />
lanthanides (at oxidation<br />
degree III), mean they are difficult<br />
to separate; in addition, there is a<br />
large variety of elements within<br />
the solution, which is moreover<br />
highly acidic. A three-stage<br />
approach is required:<br />
• Stage 1: the DIAMEX, which<br />
consists of simultaneously<br />
extracting the actinides and<br />
lanthanides using a molecule<br />
from the malonamide family;<br />
• Stage 2: the SANEX process,<br />
separating out the Am+Cm pair<br />
from the lanthanide group;<br />
• Stage 3: the Am/Cm partitioning<br />
process, using diamides.<br />
Review and outlook<br />
Since 1991, research into<br />
advanced partitioning has enabled<br />
procedures to be developed for<br />
selectively recovering americium<br />
and curium from fission product<br />
solutions derived from the PUREX<br />
process (99.9% recovery rate,<br />
which meets the stated goal). The<br />
selected concepts were validated<br />
before the end of the first phase<br />
of research (end of 2001). During<br />
the second phase (2002-2005),<br />
the processes were successfully<br />
tested. Firstly, the solvent<br />
endurance was tested in the<br />
irradiation loop. Subsequently<br />
the demonstration tests were<br />
successfully performed, in April<br />
and November 2005 respectively,<br />
in the Atalante shielded process<br />
cell, a 1/500 replica of the<br />
industrial technologies, using<br />
approximately 15 kg of EDF fuel.<br />
But over and above the scientific<br />
results expected within the strict<br />
framework of the law, it should<br />
also be emphasized that this<br />
period was useful for carrying<br />
out numerous basic studies, for<br />
instance into the extraction and<br />
complexation mechanisms of<br />
various extraction systems.<br />
Doctoral and Post-Doc research<br />
contributed greatly, along<br />
with national (GdR PRACTIS and<br />
PARIS), European (NEWPART,<br />
PARTNEW, CALIXPART,<br />
EUROPART, etc.) and<br />
international collaborations<br />
(Japan, Russia, USA, etc.). The<br />
<strong>CEA</strong> and the Valrho center have<br />
thus acquired new skills (e.g.<br />
molecular modeling) and new<br />
tools (see insert Future<br />
challenges).<br />
The program also provided an<br />
opportunity to run a project from<br />
start to finish, from designing the<br />
extraction molecules to testing a<br />
process on several kilograms of<br />
spent fuel. The work has boosted<br />
partitioning chemistry and<br />
actinide chemistry enhancing<br />
excellence within our teams ready<br />
to meet future challenges.<br />
Christine Rostaing,<br />
“Advanced Partitioning” Project Manager<br />
Rive droite Rive Gauche - 2006, May<br />
© A. Gonin/<strong>CEA</strong><br />
FUTURE CHALLENGES<br />
Given the decisions needed in 2006, our significant results opened up a range of possibilities<br />
for processing spent fuel in Generation IV reactor-fuel cycle systems that recycle their own<br />
waste. The choice was made to transmute actinides in FBRs 1 , these studies will need to be<br />
continued and adapted, depending on the nature of the actinide compounds selected for<br />
recycling. In Atalante, work is already under way in this area, with<br />
the parallel development of partitioning and multiple actinide<br />
conversion (integrated processing and re-manufacturing concept).<br />
The preparation for the demonstration experiment on key processes<br />
© A. Gonin/<strong>CEA</strong><br />
for this concept (access to the fissile compound; multiple actinide<br />
dissolving, extraction and conversion process; forming the fissile<br />
compound and re-manufacturing the fuel element), will use a fuel representative of a GFR 2 .<br />
The research teams will gradually focus their efforts on these new goals, which will also<br />
require developments in the Atalante facility.<br />
Christine Rostaing, “Advanced Partitioning” Project Manager<br />
1. FBR: Fast Breeder Reactor - 2. GFR: Gas-cooled Fast Reactor<br />
<strong>CEA</strong> NEWS 20 September <strong>2007</strong><br />
© P. Stroppa/<strong>CEA</strong>
© P. Dumas/<strong>CEA</strong><br />
Top: Managing waste drums during<br />
dismantling operations in the UP1 plant<br />
in Marcoule.<br />
Middle: Shielded compartments for<br />
dry processes used to manufacture<br />
(crushing, pressing, sintering and<br />
cladding) fuels for studies, transmutation<br />
targets and confinement matrices.<br />
Bottom: Mock-up for long-term<br />
storage in the ground below the CECER<br />
(Centre of expertise in conditioning and<br />
storage of radioactive material).<br />
99%<br />
This is the proportion of americium and curium<br />
that the selected molecules and the process<br />
developed in ATALANTE can partition out of the<br />
solution sourced from reprocessed spent fuel.<br />
NEW TEAMS FOR ICSM<br />
The Marcoule Institute of Separative<br />
Chemisty (ICSM), a mixed research unit<br />
jointly run by the CNRS (40%), University<br />
of Montpellier 2 (20%) and the <strong>CEA</strong><br />
(40%), is planning on an influx of around<br />
a hundred researchers in 2010. In the<br />
short term however, the first of these<br />
newcomers need to be identified – these<br />
will be the first teams to get into the<br />
Institute’s new premises at the entrance<br />
to the Marcoule site.<br />
Non-permanent staff Given staff<br />
turnover, 15 new researchers will be<br />
selected every year. Three tender<br />
processes were run, in September 2004,<br />
June and September 2005. In each<br />
tender, an innovative and realistic<br />
scientific collaboration was proposed,<br />
supervised either by the Montpellier<br />
Chemistry cluster – the Universities of<br />
Montpellier, the Montpellier-based<br />
Grande Ecole ENSCM and <strong>CEA</strong>-ICSM – or<br />
by another French university or CNRSrun<br />
laboratory.<br />
Permanent staff 50 applications were<br />
received by the close of the 2006<br />
recruitment campaign. 16 candidates<br />
have been interviewed by the<br />
Shortlisting Committee and 12 have been<br />
selected: 3 from the University of<br />
Montpellier 2, 3 from the CNRS and 6<br />
from the <strong>CEA</strong> (including 3 external<br />
recruits). After 4 campaigns, the staff<br />
team should be complete.<br />
In addition, European collaborations in<br />
the Physical Chemistry of Actinides (with<br />
the Institute for Transuranic Elements,<br />
Karlsruhe) and Sonochemistry (with<br />
Max Planck Institute) are being set up to<br />
enable researchers to work in mixed<br />
ICSM units hosted by foreign<br />
laboratories, from Spring <strong>2007</strong>.<br />
These initiatives should all help bring<br />
together the teams and enable them to<br />
be immediately operational when the<br />
ICSM laboratories open in March 2008.<br />
Gilles Richard - Rive droite Rive gauche – 2006, November<br />
The new<br />
law is here<br />
The final text 1 of the bill to succeed the “Bataille<br />
Act” (dating from December 30, 1991) was<br />
approved by the National Assembly on June 15,<br />
2006, following its examination by the Senate.<br />
This report focuses on “Program Law”<br />
no. 2006-739 dated June 28, which is much<br />
larger in scope than its predecessor, since it<br />
pertains “to the sustainable management of<br />
radioactive materials and waste.” In other words<br />
it covers all the <strong>CEA</strong>’s waste-related activities -<br />
research, management, decommissioning,<br />
facility operation and communication.<br />
The new law lays down the<br />
principle that “sustainable<br />
management of radioactive<br />
materials and waste of any<br />
description (…) is undertaken in<br />
compliance with the protection<br />
of human health, safety and the<br />
environment”, and in Article 3,<br />
stipulates that research and study<br />
related to long-lived high or<br />
intermediate level radioactive<br />
waste is to be performed “in three<br />
complementary areas”, resulting<br />
for the most part from work carried<br />
out at Marcoule over the last fifteen<br />
years or more.<br />
1. Research and study focusing on<br />
partitioning and transmutation<br />
of long-lived radioactive elements<br />
“are to be undertaken in relation<br />
to research carried out into new<br />
generations of nuclear reactors<br />
(…) and accelerator-driven<br />
systems dedicated to waste<br />
transmutation”. The stated goal<br />
is to be have an appraisal of the<br />
“industrial potential of these<br />
processes” by 2012 and to “put a<br />
prototype facility into operation<br />
by December 31, 2020”.<br />
2. With respect to deep geological<br />
disposal, a goal has been set for<br />
researchers and engineers, to<br />
design a reversible repository<br />
>>><br />
1. The Act was signed by the President of the Republic and 8 Government ministers: the Prime<br />
Ministers and Ministers of the Interior, Defense, Foreign Affairs, Health, Economy, Finance &<br />
Industry, Education & Research and Ecology.<br />
<strong>CEA</strong> NEWS 21 September <strong>2007</strong>
WASTE – ADVANCED PARTITIONING<br />
300years<br />
After this period, 90% of radioactive waste returns to a level of radioactivity<br />
comparable with background radiation. This waste is disposed of in existing final<br />
repositories managed by ANDRA.<br />
Studying the<br />
diffusion of<br />
hydrogen<br />
through concrete<br />
in the top of shell<br />
used for the<br />
storage/disposal<br />
of intermediatelevel,<br />
long-lived<br />
waste.<br />
Laser-welding glove-box for<br />
cladding containing pellets of study<br />
fuel, transmutation targets and<br />
confinement matrices.<br />
and to focus on selecting a site.<br />
The operating start date has<br />
been set for 2025, ten years after<br />
filing the permission application,<br />
which will be investigated and<br />
debated in depth.<br />
3. The same date of 2015 (at the<br />
latest) has been set for creating<br />
new storage facilities or adapting<br />
existing facilities, on the basis<br />
of research and study into the<br />
© A. Gonin/<strong>CEA</strong><br />
issues, in order to “meet the<br />
needs, particularly in terms<br />
of capacity and duration.”<br />
These three research focuses were<br />
already known, but a calendar has<br />
now been set, and additional<br />
details and provisions laid down:<br />
• the partitioning and transmutation<br />
process is clearly linked to<br />
Generation IV systems,<br />
• deep geological disposal must<br />
be reversible for a duration of<br />
“no less than one hundred years”,<br />
• the role of ANDRA is broadening,<br />
to include, for instance, cleaning<br />
up of radioactive contamination<br />
sites or coordinating research<br />
and study to be carried out (or<br />
commissioned) with respect to<br />
deep geological disposal and<br />
as well as storage,<br />
• three new taxes have been<br />
created, in addition to the<br />
existing tax on Basic Nuclear<br />
Installations: they will be used<br />
to fund economic development<br />
and the roll-out of technology<br />
in the areas surrounding the<br />
selected disposal site, and<br />
research and study into storage<br />
and deep geological disposal.<br />
The sums allocated to this research<br />
and the construction and operation<br />
of the corresponding facilities will<br />
be paid into funds accounted for<br />
separately within ANDRA.<br />
A broader scope<br />
The new law is much broader<br />
in scope than the previous Bataille<br />
Act. In particular, it sets in place<br />
a research and study program,<br />
aimed at commissioning a graphite<br />
and radium-bearing waste disposal<br />
center by 2013, and provide three<br />
“deliverables” by 2008: storage<br />
solutions for tritiated waste (until<br />
the radioactivity has decayed<br />
enough to allow for ground-level<br />
or shallow disposal), finalization<br />
of disposal solutions for used<br />
sealed sources (in existing or new<br />
centers) and a long-term impact<br />
assessment on uranium mine<br />
tailing disposal sites (with a<br />
reinforced radiological monitoring<br />
plan for these sites).<br />
Under the new law, the first ever<br />
national radioactive materials and<br />
waste management plan is to be<br />
put in place by December 31,<br />
2006. This type of plan is to be<br />
drawn up every three years by the<br />
Government, and assessed by the<br />
Parliamentary Office for the<br />
Evaluation of Scientific and<br />
Technological Choices. It will<br />
review the existing management<br />
methods for radioactive materials<br />
and waste, survey the foreseeable<br />
requirements for storage or<br />
disposal facilities, specify their<br />
capacity and duration (in the case<br />
of storage) and establish targets<br />
to be met (with a calendar), for<br />
radioactive waste items that<br />
still have no final management<br />
method. This plan must comply<br />
with three major objectives:<br />
1. reducing the quantity and<br />
danger of the radioactive waste,<br />
in particular by reprocessing<br />
spent fuel and processing and<br />
conditioning radioactive waste;<br />
in this respect, owners of long-<br />
>>><br />
<strong>CEA</strong> NEWS 22 September <strong>2007</strong>
Interview<br />
PHILIPPE PRADEL<br />
<strong>CEA</strong> Director of Nuclear Energy<br />
“<br />
Major breakthroughs have<br />
been achieved in nuclear<br />
waste management.<br />
lived Intermediate Level Waste<br />
(ILW) produced before 2015<br />
must have it conditioned by<br />
2030 at the latest,<br />
2. use specially designed facilities<br />
to store radioactive material<br />
awaiting reprocessing and<br />
ultimate radioactive waste<br />
awaiting disposal,<br />
3. use deep geological repositories<br />
to dispose of ultimate radioactive<br />
waste that cannot be disposed<br />
of in ground or shallow<br />
repositories, for nuclear safety<br />
or radiological protection<br />
reasons.<br />
Information,<br />
assessment and<br />
international cooperation<br />
Like the preceding law, the new<br />
one outlaws the disposal of<br />
foreign radioactive waste in<br />
France, but specifies the reason<br />
for this ban. The law provides for<br />
intergovernmental agreements to<br />
be published in the Journal Officiel<br />
(official gazette), specifying a<br />
framework under which foreign<br />
fuels may be reprocessed in<br />
France, and how long the related<br />
waste will remain stored on French<br />
soil. Operators running research<br />
and reprocessing operations<br />
involving foreign radioactive<br />
”<br />
substances will have to draw up<br />
an annual inventory on this issue,<br />
which will be made public, along<br />
with the annual report form the<br />
National Board for Research<br />
Assessment. The board must<br />
include “at least one international<br />
expert” and its report must “review<br />
research carried out abroad”. The<br />
same requirements apply to the<br />
national radioactive materials and<br />
waste management plan. It will<br />
have to summarize research and<br />
projects carried out outside France.<br />
The new law requires wider<br />
communication to the general<br />
public. One body that could be<br />
involved in communication<br />
is the High Commission for<br />
Transparency and Information on<br />
Nuclear Safety, established under<br />
a different law dated June 13,<br />
2006. This new body could<br />
organize “periodical consultations<br />
and debates on the sustainable<br />
management of radioactive<br />
materials and waste.” Likewise, a<br />
National Board, distinct from the<br />
aforementioned research board,<br />
will assess operators' funding of<br />
decommissioning and radioactive<br />
material management expenses.<br />
It will also issue a tri-annual report<br />
to the general public.<br />
Gilles Richard - Rive droite Rive gauche<br />
2006, September<br />
© A. Gonin/<strong>CEA</strong><br />
<strong>CEA</strong> NEWS 23 September <strong>2007</strong><br />
What is your appraisal of<br />
<strong>CEA</strong> research over these<br />
last fifteen years?<br />
The 1991 law brought<br />
research projects into the<br />
spotlight, some of which<br />
were already underway, and<br />
encouraged domestic and<br />
international cooperation.<br />
I would like to emphasize<br />
the lively exchanges<br />
stemming from the<br />
confrontation of scientific<br />
ideas among various players<br />
in research, industry and<br />
operations. The full range of<br />
possibilities has been<br />
explored with our partners<br />
[ed: in France, chiefly ANDRA<br />
and the CNRS] and major<br />
breakthroughs have been<br />
achieved. We now have a<br />
panel of solutions, which are<br />
actually complementary, and<br />
will feed a calm and<br />
informed public debate. To<br />
give you an example, we<br />
have reduced the volume of<br />
intermediate level<br />
radioactive waste by a factor<br />
of 10. Likewise, having<br />
demonstrated the scientific<br />
feasibility of actinide<br />
partitioning [ed: some of the<br />
most radioactive elements]<br />
and the existing methods for<br />
transmuting them in fast<br />
reactors, there is potential<br />
for further reductions in final<br />
waste in the future.<br />
What might be the<br />
international knock-on<br />
effect of the these<br />
results?<br />
There is now a massive<br />
renewal of interest in<br />
nuclear power, throughout<br />
the world, particularly in Asia<br />
[ed: China and India], linked<br />
to growing energy needs<br />
and the requirement of<br />
limiting CO2 emissions.<br />
France is one of the<br />
technological leaders with its<br />
spent fuel reprocessing &<br />
recycling processes, but also<br />
a leader in institutional<br />
terms, with a coherent<br />
system and multiple,<br />
rigorous, independent<br />
control mechanisms. We are<br />
being watched by the rest of<br />
the world and need to show<br />
that reasonable, sustainable<br />
solutions for nuclear waste<br />
management exist. Japan is<br />
building a plant similar to<br />
Cogema’s La Hague facility<br />
at Rokkasho Mura. The USA<br />
and China are now looking<br />
at our technological options<br />
with interest.<br />
Is there a synergy<br />
between research into<br />
waste management and<br />
research into future<br />
systems?<br />
Yes there is, because<br />
research into the nuclear<br />
systems of the future<br />
involves a goal of<br />
sustainable development,<br />
which implies reducing<br />
releases and waste as much<br />
as possible, and recycling to<br />
maximize resources. That is<br />
why people talk about<br />
“systems” these days, a<br />
term referring both to<br />
reactors and the associated<br />
fuel cycle. Within the<br />
framework of the<br />
Generation IV initiative,<br />
drawing together Euratom<br />
and 10 other countries, four<br />
of the six technological<br />
options selected for the<br />
nuclear systems to be<br />
deployed by 2030 are fast<br />
breeder reactors, which will<br />
enable these sustainable<br />
development goals to be<br />
met. France is heavily<br />
involved in research on this<br />
type of reactor, and<br />
already has wideranging<br />
expertise. ■<br />
Interview with Claire Abou<br />
Les défis du <strong>CEA</strong> – No. 106<br />
© L. Godart/<strong>CEA</strong>
SCIENTIFIC HIGHLIGHTS<br />
The dynamics of<br />
THE EARTH’S MAGNETIC FIELD<br />
reproduced in the laboratory<br />
© Collaboration VKS/<strong>CEA</strong><br />
Over the geological ages, the Earth has<br />
undergone several erratic reversals of its<br />
magnetic field. The sun’s magnetic field is<br />
reversed regularly every 22 years according to<br />
its cycle. These magnetic dynamics, which are<br />
still shrouded in mystery, play a role in our<br />
planet’s exposure to cosmic rays.<br />
The joint VKS experiment 1 (<strong>CEA</strong> 2 , CNRS, the Ecole<br />
Normale Supérieure in Lyon 3 and the Ecole Normale<br />
Supérieure in Paris 4 ) has, for the very first time,<br />
observed magnetic field reversals in laboratory<br />
conditions thanks to a highly turbulent flow of<br />
liquid sodium. The experiments should help scientists<br />
to understand more about cosmic magnetic field<br />
reversals. The results are published in Europhysics<br />
Letters, Volume 77, March <strong>2007</strong>.<br />
The Earth’s magnetic field is created by highly<br />
disordered movements that churn up the liquid<br />
iron core at the center of the Earth. This is known<br />
as the “dynamo” effect. One of its most astonishing<br />
characteristics, revealed by paleomagnetic research,<br />
is that reversal of the magnetic poles is totally random.<br />
They remain close to the Earth’s geographic poles<br />
and flip between north and south about once every<br />
100,000 years or so, although longer periods have<br />
been found between reversals. On average, these<br />
reversals last a few thousand years.<br />
The cause and timescale of such reversals, together<br />
with the geometry of the magnetic field during a<br />
reversal, remain the subject of much debate.<br />
The consequences may be considerable: during a<br />
reversal, the magnetosphere that protects the Earth<br />
from solar and cosmic radiation is significantly<br />
weakened. Life on Earth, and human life in<br />
particular, has survived this kind of situation in<br />
the past (the last reversal occurred 700,000 years<br />
ago), but a repeat would severely interfere with<br />
our modern communications systems (satellites<br />
and networks, etc.).<br />
The researchers involved in the VKS experiment<br />
have shown that the dynamo effect could be<br />
reproduced in a laboratory experiment, using a<br />
turbulent flow of liquid sodium produced by the<br />
counter-rotation of two impellers inside a cylinder 5 :<br />
with the two impellers rotating at the same speed,<br />
a stationary magnetic field is spontaneously generated<br />
once a certain threshold is exceeded. They have<br />
now observed that when the impellers rotate at<br />
different speeds, thus adding global rotation similar<br />
to that of the planets and stars, the dynamo field<br />
may vary over the course of time. Certain regimes<br />
have uncannily similar characteristics to the behavior<br />
of the Earth’s magnetic field.<br />
The field flips from one state of polarity to its opposite<br />
for irregular time periods, with the transition from<br />
one polarity to the other lasting a very short duration.<br />
- The periods during which the field is stable vary<br />
in length, but always last longer than reversal time.<br />
- Field excursions, periods during which the field<br />
decays and then grows again with no polarity<br />
change, can also be observed.<br />
At other rotation speeds, the magnetic field may<br />
periodically be reversed, rotating in space without<br />
polarities canceling each other out, as is observed<br />
in the case of the sun.<br />
These experiments imply that it will now be possible<br />
to conduct laboratory studies of phenomena that<br />
have intrigued geophysicists and astrophysicists for<br />
centuries.<br />
Magnetic field (in gauss) measured in the experiment<br />
in relation to time (in seconds). The sodium flow<br />
is driven by two turbines with counter-rotating<br />
impellers rotating at different speeds.<br />
Delphine Kaczmarek – <strong>2007</strong>, April<br />
1. Von Karman (the physicist after whom the flow was<br />
named). Sodium (the fluid used in these experiments).<br />
2. <strong>CEA</strong>’s Condensed State Physics Department, Physical<br />
Sciences Division, team headed by François Daviaud.<br />
3. Physics Laboratory at the Ecole Normale Supérieure de<br />
Lyon, (CNRS, ENS Lyon), team headed by Jean-<br />
François Pinton.<br />
4. Statistical Physics Laboratory (ENS Paris, CNRS,<br />
University of Paris VI and Paris VII), team headed by<br />
Stephan Fauve.<br />
5. The VKS experiment took place at <strong>CEA</strong>/Cadarache, at<br />
the Department of Nuclear Technology in the Nuclear<br />
Energy Division. The results are presented in an article in<br />
Physical Review Letter 98, 044502 (<strong>2007</strong>).<br />
SOITEC-LETI COMPETENCY CENTER<br />
© P. Stroppa/<strong>CEA</strong><br />
Soitec, the world leader in silicon-on-insulator technology, is pooling its skills with<br />
those of <strong>CEA</strong>/LETI* to set up the Nanosmart Center, a world-class center of excellence<br />
in advanced materials for the microelectronics industry. Funded by A21, the French<br />
agency for industrial innovation, the Nanosmart Center will develop new generations<br />
of semiconductor materials for innovative applications, such as high-frequency telecom<br />
components and power components for the automotive and audiovisual industries.<br />
* LETI: Electronics and Information Technology Laboratory.<br />
<strong>CEA</strong> Technologies No. 83 – November-December 2006<br />
<strong>CEA</strong> NEWS 24 September <strong>2007</strong>
XEDIX: 100 TB OF DATA SCREENED<br />
IN JUST A FEW SECONDS<br />
Using Xedix, the native XML database developed by the <strong>CEA</strong>, it takes less than<br />
a second to find a document in a 100 Tbyte base. A start-up called Xedix Tera<br />
Solutions is being set up to market this unique product that has potential<br />
applications in a wide range of areas, including multimedia, research,<br />
telecommunications and avionics.<br />
The <strong>CEA</strong> is producing for its own<br />
requirements an ultra high-performance<br />
information management system called<br />
Xedix, which it is currently testing on a<br />
100 TB database.<br />
A world first. “The archives of the Institut<br />
National de l'Audiovisuel (French National<br />
Audiovisual Institute) only represent 85 to<br />
90 TB of data,” comments Didier Courtaud.<br />
“If we were to store all the events of a person's<br />
life on a single electronic storage medium,<br />
it would take up about 100 GB, in other words,<br />
a thousand times less than the total storage<br />
capacity of Xedix.” The tests are performed<br />
using standard test cases made up of several<br />
types of realistic data. They are expected<br />
to confirm the good results from earlier<br />
tests carried out in 2003 on one TB and<br />
in 2005 on ten TB. “We think we'll be able<br />
to obtain response times of less than a second<br />
for most queries.”<br />
An outstanding information storage and<br />
indexing system is the key to this<br />
performance. The system stores and<br />
indexes all data in XML (Extended Markup<br />
Language), a descriptive language that<br />
is totally independent of desktop software<br />
programs and their constant stream of<br />
upgrades. Image or video files are stored<br />
in the base and listed in XML as metadata<br />
describing the subject, shooting date,<br />
characters or any other information selected<br />
by the database administrator.<br />
What's more, the data indexing system is<br />
smart. “Unlike conventional search engines,<br />
Xedix identifies the tag in which the required<br />
character string(s) is(are) located. This means<br />
that the query can be made clearer by adding<br />
as many criteria as necessary.” Queries can<br />
be carried out using a conventional browser<br />
or a customized interface developed in<br />
the language of the user's choice (Java,<br />
PHP, etc.). The tool has already been<br />
validated on other applications during<br />
collaborative work carried out in the<br />
System@tic competitiveness cluster. A<br />
start-up called Xedix Tera Solutions is<br />
being set up to market it.<br />
With a product like this, the future looks<br />
bright for the budding firm. There are<br />
clear signs of interest from many<br />
sectors including archiving services and<br />
multimedia libraries, the research<br />
community (European projects, joint<br />
research-industry projects) and the world<br />
of scientific and technical information.<br />
Xedix Tera Solutions also hopes to arouse<br />
the interest of other sectors such as largescale<br />
scientific instrument companies (that<br />
generate vast amounts of data),<br />
telecommunications, and industries that<br />
produce great quantities of documentation,<br />
like the automotive and pharmaceutical<br />
industries.<br />
<strong>CEA</strong> Technologies No. 85 – April <strong>2007</strong><br />
© F. Rhodes/<strong>CEA</strong><br />
© Artechnique/<strong>CEA</strong><br />
REMOTE<br />
RECHARGE<br />
FOR YOUR<br />
BATTERIES<br />
The mini-battery developed by <strong>CEA</strong>-LITEN 1<br />
research teams could make a great difference<br />
in the lives of people with certain disabilities.<br />
The remotely rechargeable battery, which<br />
can be fitted inside the human body with<br />
a number of other stand-alone devices, opens<br />
the door to a new generation of medical<br />
appliances, including muscle stimulators<br />
for paralyzed hands or for hearing implants.<br />
The long-familiar lithium battery used in<br />
pacemakers is capable of supplying electrical<br />
power over a period of many years.<br />
However, as it cannot be recharged and its<br />
lifetime is limited by its size, it can only be<br />
used to power devices with very low energy<br />
consumption. “Which brings us to the<br />
rechargeable, lithium-ion mini-battery we have<br />
developed as part of the European Healthy Aims<br />
project, in association with our industrial partner,<br />
Saft. The battery meets the specifications of<br />
implant manufacturers like Cochlear Ltd. and<br />
Finetech Medical,” explains Séverine<br />
Jouanneau, a researcher at <strong>CEA</strong>-LITEN.<br />
“Lightweight (2 g) and compact (1 cm 3 ), the<br />
battery is only 5 mm thick, yet provides<br />
maximum energy (50 mAh) and can be<br />
recharged daily.” Recharging can be carried<br />
out by induction through the skin during<br />
the night using a device placed at the patient's<br />
bedside. Another advantage is service life –<br />
the battery can work for more than ten years<br />
at a temperature of 37°C.<br />
Vahé Ter Minassian - Les Défis du <strong>CEA</strong> No. 122 – March <strong>2007</strong><br />
1. LITEN: Laboratory for Innovation in New Energy<br />
Technologies and Nanomaterials<br />
<strong>CEA</strong> NEWS 25 September <strong>2007</strong>
SCIENTIFIC HIGHLIGHTS<br />
The HESS observatory team awarded the European<br />
Descartes prize for its progress in<br />
VERY HIGH-ENERGY GAMMA ASTRONOMY<br />
© ESO/ANTO/UT1<br />
On March 7, <strong>2007</strong>, the French-German very<br />
high-energy gamma ray observatory received<br />
the 2006 Descartes prize. Since the year 2000,<br />
this prize has been awarded annually to scientific<br />
teams for their transnational research results.<br />
It was awarded to the HESS team in recognition<br />
of the quality of results concerning the “nonthermal<br />
universe” or “violent universe” that<br />
opened up a new field of astronomy. The HESS<br />
observatory's results have been hailed as a world<br />
first in gamma astronomy.<br />
The observatory was mainly built by French<br />
and German laboratories, later joined by teams<br />
from other European and southern African<br />
countries. In France, it brings together CNRS<br />
(IN2P3 and INSU) 1 and <strong>CEA</strong> (DAPNIA 2 )<br />
laboratories.<br />
HESS (High Energy Stereoscopic System) is<br />
the name given to four telescopes installed<br />
on the Gamsberg plateau in Namibia. HESS is<br />
primarily dedicated to observing the southern<br />
skies that give access to most of the Milky Way.<br />
HESS provides precious information about<br />
some of the Universe’s most violent phenomena<br />
by detecting very high-energy gamma rays,<br />
using the light flashes they produce as they<br />
interact with the Earth's<br />
atmosphere (“Cherenkov<br />
effect”). The HESS<br />
experiment will soon be<br />
enhanced by the installation<br />
of a very large telescope - 28<br />
meters in diameter - at the<br />
center of the existing array<br />
of four instruments. This new<br />
phase of the experiment will<br />
not only enhance sensitivity<br />
but also overlap with the<br />
energy range covered by<br />
NASA's gamma astronomy<br />
satellite, GLAST, which should<br />
be launched in <strong>2007</strong>. The<br />
project, called Cherenkov<br />
> GAMMA RAYS: Like visible light<br />
or X-rays, gamma radiation is<br />
made up of photons, but at much<br />
higher energy levels. Visible light<br />
has an energy of around one<br />
electron volt (1 eV). X-rays are in<br />
the range of one thousand to one<br />
million eV. HESS detects very<br />
high-energy gamma rays that can<br />
reach a million million eV (or<br />
1 tera-electron volt (1 TeV)).<br />
There are few of these very highenergy<br />
gamma rays. Even for a<br />
relatively intense astrophysics<br />
source, the flow of gamma<br />
photons entering the atmosphere<br />
is around one per month per<br />
square meter.<br />
Telescope Array or CTA, will increase sensitivity<br />
tenfold and considerably add to available<br />
information sources.<br />
Delphine Kaczmarek – <strong>2007</strong>, March<br />
1. LLR École polytechnique (IN2P3/CNRS), LPNHE of the<br />
Universités Paris VI and VII (IN2P3/CNRS), APC<br />
(IN2P3/CNRS/Université Paris 7/<strong>CEA</strong>), LPTA Université<br />
de Montpellier 2 (IN2P3/CNRS), LAPP Annecy le Vieux<br />
(IN2P3/CNRS), CESR Toulouse (INSU/CNRS), LAOG<br />
Grenoble (INSU/CNRS), LUTH Observatoire de Paris-<br />
Meudon (INSU/CNRS).<br />
2. DAPNIA, Research laboratory dedicated to the<br />
fundamental laws of the Universe in the Physical Sciences<br />
Division.<br />
ATLAS, ACCELERATING DETECTION<br />
The superconducting toroidal magnet of the Atlas experiment<br />
has just been started up at the LHC facility 1 .<br />
A 21,000 A current was injected into the eight coils of the<br />
magnet to produce its magnetic field 2 . <strong>CEA</strong>-DAPNIA scientists,<br />
who have been closely involved in the design and construction<br />
of Atlas, took this opportunity to check all the magnet operating<br />
parameters and performed a successful test on its muon<br />
spectrometer. This instrument has already detected cosmic<br />
muon tracks bent under the influence of the magnetic field.<br />
These results are very encouraging for the research teams, who<br />
are now waiting for the LHC – the world's largest proton collider<br />
– to be commissioned at the end of the year, when they will<br />
be able to record and analyze the first collision data, and answer<br />
a number of basic questions in particle physics – such as “does<br />
the Higgs boson exist?”.<br />
1. Large Hadron Collider,<br />
installed in a tunnel with a<br />
circumference of 27 km,<br />
built 100 m below the<br />
ground at the CERN in<br />
Geneva.<br />
2. The Atlas magnet stores<br />
1.1 GJ of magnetic energy,<br />
enough to lift the Eiffel<br />
Tower about ten meters off<br />
the ground.<br />
Aude Ganier – Les Défis du <strong>CEA</strong> n° 121 – February <strong>2007</strong><br />
© Cern<br />
<strong>CEA</strong> NEWS 26 September <strong>2007</strong>
FIRST COMPLETE SIMULATION OF<br />
PET IMAGING SCAN<br />
OF THE WHOLE HUMAN BODY<br />
Interpreting data from positron emission tomography (PET) - medical<br />
imaging scanning increasingly used in hospitals - is still a complex<br />
task. With a view to optimizing its analysis and extracting the most<br />
relevant physiological information, researchers are working on computer<br />
simulation programs to enhance PET techniques. The programs are<br />
currently held back by computing time limitations.<br />
This problem spurred <strong>CEA</strong>-SHFJ 1 (Service<br />
hospitalier Frédéric Joliot in Orsay near Paris) to<br />
set up the GATE 2 simulation platform, which<br />
models PET scans using the Tera 10 supercomputer<br />
located at the <strong>CEA</strong>'s DAM-Ile-de-France 3 centre<br />
in Bruyères-le-Châtel near Paris. The ensuing<br />
simulation made it possible to reproduce - in an<br />
entirely realistic manner and in a very short time<br />
- the distribution of a tracer used in PET for<br />
diagnosing cancer. This first simulation result<br />
means that, in the medium term, a more precise<br />
use of data provided by the images can be envisaged<br />
as well as personalized scans for patients.<br />
These simulations are carried out using the<br />
Monte-Carlo method, based on probability<br />
theories. The analysis is hindered, however, by<br />
the limitations of digital processing: for a standard<br />
PET scan of the whole human body, a Monte-<br />
Carlo simulation must process the emission of<br />
several billion positrons and gamma photons,<br />
which is the equivalent of 10,000 computing<br />
hours, or 400 days of analysis on a standard PC.<br />
To reduce this computing time, researchers<br />
conducted a simulation on<br />
the Tera 10 supercomputer.<br />
After modeling the<br />
patient's body, using data<br />
from an actual scan,<br />
researchers simulated the<br />
injection of a tracer by<br />
selecting a realistic activity of 264 megabecquerels<br />
(MBq) and an acquisition time similar to that<br />
required for a standard PET scan. This initial<br />
simulation required less than three hours'<br />
computing time using 7,000 processors. The<br />
subsequent comparison of the actual scan and<br />
its simulation showed almost identical tracer<br />
distribution. From a quantitative point of view,<br />
comparisons of the volume of a tumor located<br />
under the patient’s left axilla indicated a difference<br />
of 6%, which is considered very low for an initial<br />
simulation. This result represents a first decisive<br />
step towards the development of methods that<br />
could be used to correct actual data from PET<br />
scans and, in the long term, target the creation<br />
of a patient specification for PET acquisition<br />
© <strong>CEA</strong><br />
See the comparison of images<br />
obtained below:<br />
• Left: PET image of an actual<br />
‘whole body’ scan<br />
• Right: the result obtained through<br />
simulation on Tera 10<br />
protocols and analysis. It also shows the benefits<br />
of intensive computing in the life science field.<br />
Stéphane Laveissière – <strong>2007</strong>, April<br />
1. The SHFJ is one of the 4 research platforms of the<br />
French Institute for BioMedical Imaging (<strong>CEA</strong>-I 2 BM).<br />
The others are NeuroSpin (<strong>Saclay</strong>), MIRCen<br />
(Fontenay-aux-Roses) and C-INAPS (Caen).<br />
2. GATE: Geant4 Application for Tomographic Emission<br />
– Geant4 is an international simulation program<br />
developed at CERN (Switzerland).<br />
3. DAM: Military Applications Division.<br />
© P. Stroppa/<strong>CEA</strong><br />
THE PIANIST'S FLOWING TOUCH<br />
Music lovers everywhere expect a digital piano to<br />
provide a perfect reproduction of the touch offered<br />
by a grand piano. But high-fidelity reproduction calls<br />
for perfect control of parameters such as the mechanism's<br />
resolution and bandwidth. <strong>CEA</strong>/LIST* took up this<br />
challenge by joining forces with the Ecole Polytechnique's<br />
Solid Mechanics Laboratory to develop a new sensory<br />
interface technology based on the use of magnetorheological<br />
or MR fluids. These fluids, made up of<br />
microscopic metal particles suspended in a liquid<br />
solvent, change viscosity under the influence of a<br />
magnetic field.<br />
The degree of change is proportional to the intensity<br />
of the applied field, making it possible to simulate<br />
the “perfect” touch, using a real-time control system<br />
and a dynamic model of traditional keys. The<br />
demonstrator developed by <strong>CEA</strong>/LIST has not only<br />
lived up to expectations. It also offers something extra<br />
– low cost! This makes it compatible with industrial<br />
production of keyboards integrating the new keys.<br />
Other potential applications include sensory interfaces<br />
and the design of new types of brakes and active dampers<br />
for motor vehicles.<br />
Sylvie Guigon – Atouts Bio Nr 4 – <strong>2007</strong>, March<br />
* LIST : Laboratory for Integration of Systems and Technologies.<br />
> RHEOLOGY: Branch of mechanics<br />
concerned with the study of flows<br />
in liquids and related deformation<br />
phenomena.<br />
<strong>CEA</strong> NEWS 27 September <strong>2007</strong>
SCIENTIFIC HIGHLIGHTS<br />
© <strong>CEA</strong>/Inserm-GBF<br />
ANTICANCER DRUGS TACKLE<br />
SCHIZOPHRENIA<br />
Since they created the first “model” schizophrenic<br />
mouse in 2002, pharmacologists from the<br />
<strong>CEA</strong> and INSERM have been making one<br />
discovery after another, the reward! The<br />
reward being an alternative to existing<br />
schizophrenia therapies. They observed an<br />
improvement in the animal's behavior after<br />
administering the epithilone D molecule,<br />
an anticancer drug. In their efforts to find a<br />
remedy, they focused on neurons rather than<br />
the neurotransmitters involved in the disease<br />
and currently treated by antipsychotic drugs.<br />
In 2002, researchers found a link between<br />
schizophrenia and cell microtubules for<br />
the first time ever. They observed behavior<br />
disorders in the animal if they deactivated<br />
Compared with those of the expression of a protein<br />
a normal mouse (A), the<br />
microtubules (shown in involved in microtubule<br />
green) of the neurons of a function. These disorders<br />
schizophrenic mouse are were reflected in a lack of<br />
not stable (B) at 4 °C,<br />
social interaction or maternal<br />
except when epothilone D<br />
is present (C).<br />
feeling, hyperlocomotion or<br />
spatial memory problems.<br />
In order to treat this schizophrenia, they turned<br />
to molecules used in cancer treatment that<br />
are capable of stabilizing microtubules. They<br />
opted for epothilone D, one of the few<br />
molecules that can penetrate the brain.<br />
Administered at very low doses to prevent its<br />
blocking action on cells (a trait common to<br />
all anticancer drugs), it proved highly effective<br />
in restoring synaptic functions with no adverse<br />
side effects. This molecule has now been<br />
patented and will soon be studied in humans.<br />
Aude Ganier - Les Défis du <strong>CEA</strong> No. 122 – March <strong>2007</strong><br />
> NEUROTRANSMITTERS:<br />
Molecules that transmit information<br />
from one neuron to another during<br />
connections known as synapses.<br />
> MICROTUBULES: Fibers along which<br />
various components are routed from<br />
one point of the neuron to another.<br />
A CLIMATIC UPHEAVAL<br />
BROUGHT TO LIGHT<br />
Between ten and three million years ago,<br />
the tropical rain forests of East Africa<br />
gradually gave way to savannah. What<br />
brought about such a radical change<br />
in the environment? Until recently,<br />
paleoclimatologists thought the cause was<br />
twofold: a drop in the CO2 level in the air<br />
and cooler surface water in the Indian<br />
Ocean. Today, a French team 1 , including<br />
researchers from LSCE (Laboratory of<br />
Climate and Environmental Sciences), a<br />
joint <strong>CEA</strong>/CNRS/UVSQ laboratory 2 , has<br />
discovered a third factor explaining this<br />
change 3 : the upthrust of the East African<br />
Rift System.<br />
This extraordinary geological structure<br />
saw a renewal in its activity 12 million<br />
years ago. In response to tectonic activity,<br />
the Earth's crust was raised before<br />
collapsing in the center to create a<br />
6,000 km long valley, bordered by hills,<br />
plateaus and mountains ranging from<br />
2,000 m to 5,000 m in height. A<br />
phenomenon on such a scale as this must<br />
have had an impact on the climate but<br />
this impact on the climate, but had never<br />
been quantified.<br />
Turning the problem round<br />
LSCE climatologists therefore teamed up<br />
with paleontologists and geologists 4 to<br />
simulate the possible impact of the<br />
emergence of the East African Rift. “In fact,<br />
we turned the problem round,” says Pierre<br />
Sepulchre, a member of the LSCE climate<br />
modeling team. “We asked ourselves what<br />
would happen if the Rift didn't exist? We used<br />
the climate model developed by the Dynamic<br />
Meteorology Laboratory to perform two digital<br />
simulations. The first considered geological<br />
structures only 2,000 m high and the second<br />
at areas with no relief.”<br />
The result left no room for doubt: the<br />
flatter the region, the higher the<br />
precipitation. Compared with today's<br />
figures, the average annual rainfall rose<br />
by 15%for the first simulation and by 40%<br />
for the second, “The lack of relief allows the<br />
Indian monsoon to progress farther into the<br />
continent in winter and causes a moistureladen<br />
zonal flow between southern Sudan<br />
and Ethiopia in summer,” explains Pierre<br />
“<br />
Transport of<br />
moisture from east<br />
to west or vice<br />
versa depending<br />
on the latitude<br />
and season.<br />
”<br />
The emergency of the Rift contributed significantly<br />
to the desiccation of East Africa, as can be seen in<br />
these simulations of changes in moisture transport.<br />
Sepulchre. This humidity results in heavy<br />
rainfall that favors the development of<br />
forests, as illustrated by vegetation models<br />
based on climatic simulation. This goes<br />
to show that the emergence of the East<br />
African Rift really is a key factor in the<br />
desiccation observed in East Africa during<br />
this period.<br />
Fabrice Demarthon<br />
Les Défis du <strong>CEA</strong> No. 121 – February <strong>2007</strong><br />
1. Paris Earth Physics Institute, European Institute<br />
of the Sea in Brest, Human Paleontology<br />
Laboratory of the University of Poitiers, LSCE.<br />
2. University of Versailles-Saint-Quentin.<br />
3. Science, vol. 313, 08.11.06, P. Sepulchre et al.;<br />
research funded by the CNRS Eclipse<br />
multidisciplinary program.<br />
4. From the University of Poitiers, the Paris Earth<br />
Physics Institute and the European Institute of<br />
the Sea.<br />
© <strong>CEA</strong><br />
<strong>CEA</strong> NEWS 28 September <strong>2007</strong>
SUPERDOPED SILICON:<br />
AN EXCELLENT CONDUCTOR<br />
Superconducting silicon capable of conducting<br />
electricity without the slightest resistance?<br />
Microelectronics specialists would think it quite<br />
a paradox!<br />
Because that's exactly the material they use for its intrinsic<br />
semiconducting powers to control the intensity and<br />
direction of electric current. Yet a CNRS 1 /<strong>CEA</strong> 2 /University 3<br />
collaboration has come up with these results using silicon<br />
that has undergone chemical treatment at ambient pressure.<br />
As its superconductivity is only apparent at very low<br />
temperatures (- 272.8 °C) 4 , its use should be restricted<br />
to fundamental research laboratories, for testing theories<br />
on nanostructure superconductivity, for example.<br />
This result is still quite a performance!<br />
“In the 1980s, researchers managed to make silicon a<br />
superconducting material by subjecting it to tremendous<br />
compression, but its crystalline structure was changed in<br />
the process,” recalls <strong>CEA</strong> researcher Christophe Marcenat.<br />
So he and his colleagues opted for a chemical process in<br />
which silicon was “doped” through the gradual addition<br />
of boron, gradually increasing its conducting power.<br />
Until then, this process had always come up against the<br />
inability of silicon to absorb large amounts of boron. “To<br />
get round this problem, we used laser pulses to heat a silicon<br />
film in an atmosphere of gas containing boron,” explains<br />
Etienne Busterrret, a CNRS researcher. “These pulses also<br />
force boron atoms inside the molten material where they<br />
bind during recrystallization.” So superconductive doped<br />
silicon isn't such a paradox after all!<br />
Claire Abou - Les Défis du <strong>CEA</strong> No. 121 – February <strong>2007</strong><br />
Adjusting the laser beam used to obtain silicon samples with more boron doping than that obtained through the<br />
usual silicon microelectronics methods.<br />
> SEMICONDUCTIVITY:<br />
Intermediate electrical<br />
conductivity between<br />
that of metals and<br />
insulators.<br />
1. Laboratory for the Study of the Electronic Properties of Solids,<br />
Grenoble.<br />
2. Condensed Matter Fundamental Research Department, Grenoble.<br />
3. Condensed Matter and Nanostructure Physics Laboratory, University<br />
of Lyon 1 and CNRS; Basic Electronics Institute, University of Paris-<br />
Sud and CNRS.<br />
4. Today's superconducting materials operate within the –273 °C to<br />
–140°C temperature range.<br />
© J. Boulmer/CNRS<br />
200 MM MICROSYSTEMS LINE SEEKS DEVELOPMENT PROJECTS<br />
<strong>CEA</strong>/LETI has invested in a 200 mm R&D line<br />
dedicated to industrial partnerships in the microsystems<br />
field for development, prototyping and preproduction.<br />
It’s the ideal solution for creating new products faster<br />
and at lower cost without investing too soon.<br />
1,000 square meters of clean rooms, specific equipment<br />
worth €20 million available 24/7, teams of researchers<br />
and technicians boasting 20 years of experience in<br />
microsystems. That, in a nutshell, is what LETI is offering<br />
industrial firms in Grenoble wishing to develop<br />
components on 200 mm silicon wafers. “The microsystems<br />
industry is still very customized,” observes Bruno Mourey,<br />
in charge of the project at LETI. Everyone creates their own line (above-<br />
IC or stand-alone) for niche markets at the cost of heavy investment<br />
and long development times.“The aim, therefore, is to use LETI resources<br />
and expertise to work faster and at a lower cost.”<br />
The solution is based on the 200 mm format, which is not only tomorrow's<br />
microsystems standard, but also and above all, the current standard on<br />
a vast number of microelectronic production lines.<br />
Collaboration projects lasting two to four years will be proposed to<br />
© P. Stroppa/<strong>CEA</strong><br />
people in industry. This is the time it takes to develop<br />
lines (or set of processes), build prototypes, carry out<br />
preproduction runs and, if the partners wish, transfer<br />
the technology to their own production site. The platform<br />
is intended for two types of partners. First, silicon<br />
founders seeking new markets for their 200 mm facilities.<br />
Second, manufacturers or end users, who see the<br />
microsystem as an opportunity for differentiation and<br />
innovation and who need development work to be<br />
treated confidentially.<br />
In all, LETI plans on working with six to ten companies<br />
keen to invest in mass markets in various sectors, such<br />
as mobile telephony, consumer products, motor vehicles<br />
or industrial electronics. It will operate the equipment alone to ensure<br />
that there are no “leaks” between projects and will allow each partner<br />
access to its line. It is the only line dedicated to 200 mm microsystems<br />
in Europe. Platform users will also have access to LETI's microelectronics<br />
R&D resources as well as its other areas of expertise – characterization,<br />
design, testing and materials – grouped together at the Minatec cluster.<br />
<strong>CEA</strong> Technologies No. 83 – December 2006<br />
<strong>CEA</strong> NEWS 29 September <strong>2007</strong>
SCIENTIFIC HIGHLIGHTS<br />
Annual Report<br />
<strong>CEA</strong> 2006<br />
(french or english<br />
version)<br />
ARC-NUCLEART IN THE<br />
LAND OF THE MAYAS<br />
For the first time since the Atelier de Restauration (Restoration Workshop)<br />
was created in 1970, the Nucleart Method – resin impregnation and gamma<br />
irradiation – has been used abroad.<br />
“This Maya sculpture, discovered on the site<br />
of Becan in Yucatan, is a unique<br />
archeological object. It has also been<br />
declared a national treasure,<br />
so there was no question of it<br />
leaving the country,”<br />
explains Alejandra Alonso,<br />
a restoration specialist at<br />
the INAH, the Mexican<br />
National Institute of<br />
Anthropology and<br />
History. The Nucleart<br />
Method, developed at<br />
the <strong>CEA</strong> center in<br />
Grenoble, was chosen<br />
for the renovation work.<br />
“It seemed the most effective<br />
way of halting any further<br />
damage to this statuette, a dwarf only 20 cm<br />
tall, whose body had suffered considerable<br />
deterioration, with the wood flaking away<br />
at the slightest touch.” It was therefore decided<br />
that the first week of the mission 1 would<br />
be given over to treatment, with the second<br />
week set aside for three conferences on<br />
preservation and restoration processes for<br />
dry and waterlogged wooden objects.<br />
The Mayan statuette was first impregnated<br />
with liquid styrene-polyester resin. It was<br />
then packed in a special container and<br />
taken under police escort to the industrial<br />
irradiator located at the heart of the National<br />
Institute for Nuclear Investigation, 40 km<br />
outside Mexico City. This gamma irradiator<br />
induces radioactive polymerization which<br />
hardens the resin in the wood. Khôi Tran,<br />
an ARC-Nucleart chemical engineer, is<br />
working on something of a special agent's<br />
mission. “Alejandra Alonso Olvera called me<br />
at the beginning of 2006, asking me to come<br />
to Mexico City to restore a dry, wooden sculpture<br />
from the Maya period. This had first been<br />
Restoration at work<br />
mentioned back in 2002.” Although<br />
the INAH is a major preservation<br />
and restoration center employing<br />
some one hundred people,<br />
including forty restorers, it has quite<br />
modest technical resources.<br />
The next thing to do was to prepare the<br />
mission. Using Khôi Tran's diagrams and<br />
photos, Alejandra was able to have<br />
alterations made to a 40 l<br />
pressure cooker made<br />
in America. Other<br />
adjustments had to be<br />
made to the vacuum<br />
pump, pressure gauges,<br />
nitrogen cylinder, tubes<br />
and fittings, irradiation<br />
parameters, resin formulation – even the<br />
power supply voltage (110 V in Mexico).<br />
“But even after six months of preparation,<br />
there were always surprises in store, like<br />
the purple color of the impregnating resin.”<br />
The irradiation treatment lasted 48 hours.<br />
The consolidation of the sculpture was<br />
satisfactory and the polychrome resisted<br />
well, thereby minimizing the risk<br />
of damage during exhibitions. “We<br />
demonstrated that Nucleart technology can<br />
be transferred, especially to emerging<br />
countries,” stresses Khôi Tran. The process<br />
is of particular interest in tropical<br />
countries, where objects densified by<br />
Nucleart will put up better resistance to<br />
extreme variations in climate. For the<br />
past year, Vietnamese archeologists have<br />
called on ARC-Nucleart to preserve<br />
waterlogged, wooden, archeological<br />
objects on site.<br />
Marc Jary – Le mensuel de Grenoble – October 2006<br />
1. The mission is fully funded by the Mexican<br />
authorities.<br />
Organized every year by the <strong>CEA</strong> and the Association of French Mayors, the “Save the<br />
Heritage” competition offers the five award-winning towns the chance to have their<br />
works of art treated and restored by the ARC-Nucleart Laboratory at the <strong>CEA</strong> center<br />
in Grenoble.<br />
Les Défis du <strong>CEA</strong> No. 122 - March <strong>2007</strong><br />
© DR<br />
France-China Symposium<br />
on Nuclear Energy<br />
Regulations, Codes,<br />
Standards and Qualification<br />
Rostrum during the Vice-Minister's speech. From left to<br />
right: the Vice-Minister, Cyril Pinel of the ASN, the French<br />
Ambassador to China, the Chief Executive Officer of the Chinese<br />
nuclear safety authority.<br />
The <strong>CEA</strong> and the Chinese Safety Authority held<br />
the first “France-China Symposium on Nuclear<br />
Energy Regulations, Codes, Standards and<br />
Qualification” in Beijing on June 4-6, <strong>2007</strong>.<br />
China has recently decided to speed up the<br />
development of its nuclear program (10 reactors<br />
in service and 17 at various stages of testing,<br />
construction and licensing); a number of players<br />
will be involved: government authorities and<br />
regulators, utilities, design institutes and industry.<br />
France has completed a highly successful program.<br />
One of the keys to success is the implementation<br />
of a comprehensive set of regulations, codes and<br />
standards addressing such subjects as supplier<br />
qualification, equipment certification, on-site<br />
inspection, etc.<br />
The symposium provided an opportunity to<br />
compare current French and Chinese regulations<br />
and allowed government agencies, utilities, design<br />
institutes and people from industry to share their<br />
experience.<br />
Some 300 people took part (including more than<br />
200 Chinese). There were contributions from various<br />
representatives of French industry and the IRSN<br />
and some Chinese institutes. The Symposium was<br />
chaired by Mr. LI Ganjie – Vice-Minister of SEPA,<br />
Administrator of NNSA and Mr. André-Claude<br />
Lacoste – President of the ASN.<br />
Using hydrogen to produce<br />
energy – a traveling exhibition<br />
The depletion of petroleum resources is forcing us<br />
to consider other options, especially renewable<br />
energy sources. Among the possibilities, hydrogen<br />
offers numerous advantages. It can be easily<br />
© <strong>CEA</strong><br />
<strong>CEA</strong> NEWS 30 September <strong>2007</strong>
G8 Global Partnership<br />
Activity report<br />
2004-2005-2006<br />
(french and english version.<br />
Russian version available on<br />
line http://www-pmg8.cea.fr)<br />
> These brochures are<br />
available upon<br />
request in paper<br />
format or on line :<br />
www.cea.fr<br />
EXHIBITIONS<br />
© <strong>CEA</strong><br />
produced from any primary energy source (solar,<br />
wind, nuclear, etc.) and used in a “fuel cell” to<br />
generate high yields of electricity and heat, with<br />
water as its only waste product!<br />
To raise awareness about this important technology,<br />
the Palais de la Découverte, a science museum in<br />
Paris, has created a traveling exhibition (first stop<br />
in Berlin at the Technikmuseum, from May 24 th<br />
to July 24 th , <strong>2007</strong>, then on to the Visiatome before<br />
the end of the year). The exhibition covers all the<br />
steps studied at the <strong>CEA</strong>: production of electricity<br />
using photovoltaic panels, production of hydrogen<br />
by electrolysis, storage and retrieval of electrical<br />
energy using fuel cells. To illustrate how the<br />
research works, the exhibition uses prototypes<br />
and laboratory equipment, including the Genepac<br />
fuel cell, metal plates, graphite plates and<br />
membranes, along with an educational pack about<br />
fuel cells.<br />
As part of its renovation project, the Palais de la<br />
Découverte will present a stationary version of<br />
this exhibition in Paris.<br />
ICAPP <strong>2007</strong><br />
International Congress on Advances in Nuclear Power<br />
Plants - “Nuclear Renaissance at Work.” - May 13-<br />
18, <strong>2007</strong> • Nice Acropolis, France<br />
The <strong>CEA</strong> participated in the <strong>2007</strong> ICAPP<br />
international conference on progress in nuclear<br />
power plants, covering design, construction,<br />
operation, and maintenance. This professional<br />
gathering brought together the most important<br />
international stakeholders in the electronuclear<br />
industry around the theme of “nuclear renaissance”.<br />
It was an occasion for the Nuclear Energy Division<br />
of the <strong>CEA</strong> to present its research and development<br />
milestones in several areas and to co-chair the<br />
plenary session dedicated to nuclear systems of<br />
the future. The papers presented by the <strong>CEA</strong><br />
addressed the following areas:<br />
• Research to optimize existing industrial nuclear<br />
facilities and development of third-generation<br />
systems (optimization of fuels and plant life<br />
spans, better procedures for spent fuel processing,<br />
advanced methods of computer simulation, etc.)<br />
• The <strong>CEA</strong>'s commitment to the nuclear systems<br />
of the future (strategy and planning for sodiumcooled<br />
fast reactors, materials and fuel<br />
innovations, and new options for the back end<br />
of the fuel cycle and waste management)<br />
Finally, this conference allowed several major<br />
nuclear actors abroad (USA, Japan, Russia, China,<br />
South Korea, etc.) to share their vision of the<br />
nuclear renaissance.<br />
Following the conference, the participants toured the<br />
<strong>CEA</strong>'s Marcoule and Cadarache centers.They visited<br />
certain advanced facilities for nuclear research, such<br />
as Atalante, a large laboratory dedicated to actinide<br />
chemistry, and Tore Supra, a tokamak for fusion<br />
energy studies.<br />
The 20 th World Energy<br />
Congress & Exhibition<br />
is promoted by the World<br />
Energy Council (WEC*)<br />
This is the most authoritative international energy<br />
meeting, to be held in Rome in the new “Nuova<br />
Fiera” venue, November 11-15, <strong>2007</strong>. Excellent<br />
speakers and thousands of participants will come<br />
from all over the world. Besides the World Energy<br />
Council Members, the Congress will welcome<br />
exhibitors from both energy producing and<br />
consuming countries, institutions, international<br />
organizations and energy industry representatives,<br />
researchers and experts from all over the world,<br />
and all those who are interested in energy and<br />
development issues. During the four-day meeting,<br />
participants will have the chance to visit an<br />
interesting and important exhibition covering<br />
20,000 m 2 at the “Nuova Fiera”. Companies<br />
will have a great opportunity to present their<br />
products and technological innovations for the<br />
energy industry to an international and<br />
distinguished audience.<br />
*With several Member Committees in over 90 countries, WEC<br />
aims to monitor the status of the energy industry and find<br />
solutions fostering the economic development of both industrialized<br />
and developing countries. It also promotes the sustainable supply<br />
and usage of energy for the greatest benefit of all people.<br />
© <strong>CEA</strong><br />
Transducers 07<br />
TRANSDUCERS has grown into the largest<br />
multidisciplinary conference on microsensors,<br />
microactuators, and microsystems, with typically<br />
900 attendees from government and industry who<br />
gather every two years to share information on<br />
the latest advances in the field. This year, the<br />
technical program consisted of parallel oral sessions<br />
and poster presentations. Invited speakers<br />
(including researchers from LETI, the <strong>CEA</strong><br />
laboratory of electronics and information<br />
technology) gave insightful<br />
overviews on key topics<br />
during the plenary session<br />
and throughout the<br />
conference, which also<br />
included short courses and<br />
exhibitions.<br />
TRANSDUCERS 07 was<br />
held in Lyon, France,<br />
<strong>2007</strong>, June 10-14<br />
Visiatome<br />
The Visiatome is located in Southern France in<br />
Marcoule, not far from Nîmes. This scientific<br />
cultural center was created to inform the public<br />
and answer questions related to radioactivity and<br />
its applications, the various sources of energy,<br />
radioactive waste management, and the nuclear<br />
industry in general.<br />
The 600-m 2 site offers fun, interactive exhibitions<br />
addressing all these questions. Educational sessions<br />
are available to school groups, and scientific<br />
activities are offered Wednesday afternoons,<br />
Sundays, and during school vacations.<br />
> Practical info<br />
Visiatome - <strong>CEA</strong> Marcoule - BP 64172<br />
30207 Bagnols-sur-Cèze cedex<br />
www.visiatome.fr<br />
To learn more: Tel: +33 (0)4 66 39 78 78<br />
contact.info@visiatome.com<br />
Reservations: Tel: +33 (0)4 66 39 78 78<br />
Fax: +33 (0)4 66 39 78 30<br />
reservation@visiatome.com<br />
© C. Dupont/<strong>CEA</strong> © P. Stroppa/<strong>CEA</strong><br />
<strong>CEA</strong> NEWS 31 September <strong>2007</strong>
<strong>CEA</strong> EMBASSY<br />
COUNSELOR NETWORK<br />
WASHINGTON<br />
Jacques FIGUET<br />
nuclear.counselor@ambafrance-us.org<br />
BERLIN<br />
Jean-Marc CAPDEVILA<br />
jean-marc.capdevila@diplomatie.gouv.fr<br />
LONDRES<br />
Alain REGENT<br />
alain.regent@cea.fr<br />
HELSINKI<br />
Claude SAINTE-CATHERINE<br />
claude.sainte-catherine@cea.fr<br />
BUDAPEST<br />
Gérard COGNET<br />
gerard.cognet@cea.fr<br />
MOSCOU<br />
Denis FLORY<br />
nucleaire.moscou@diplomatie.gouv.fr<br />
NEW-DELHI<br />
Hugues de LONGEVIALLE<br />
hugues.de-longevialle@cea.fr<br />
SEOUL<br />
Jean-Yves DOYEN<br />
energykorea@kornet.net<br />
BRUSSELS - EU<br />
Guillaume GILLET<br />
guillaume.gillet@diplomatie.gouv.fr<br />
TOKYO<br />
Pierre-Yves Cordier<br />
pierre-yves.cordier@cea.fr<br />
PARIS<br />
<strong>CEA</strong> Headquarters<br />
ceanews.contact@cea.fr<br />
VIENNA - AIEA<br />
Marc-Gérard ALBERT<br />
marc-gerard.albert@diplomatie.gouv.fr<br />
BEIJING<br />
Alain TOURNYOL du CLOS<br />
servnucpekin@yahoo.com<br />
www.cea.fr<br />
More information: ceanews.contact@cea.fr