Process Systems MRA Crude Oil Solutions - Coqa-inc.org
Process Systems MRA Crude Oil Solutions - Coqa-inc.org
Process Systems MRA Crude Oil Solutions - Coqa-inc.org
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<strong>MRA</strong> <strong>Crude</strong> <strong>Oil</strong> <strong>Solutions</strong><br />
COQG General Meeting – New Orleans – 9 NOV 2006<br />
Eric Gildea – IPS Global <strong>Solutions</strong> Business Consultant<br />
<strong>Process</strong> <strong>Systems</strong><br />
Get More from One<br />
Avantis • Foxboro • SimSci-Esscor • Triconex
Invensys <strong>Process</strong> <strong>Systems</strong> /<br />
IPS Global <strong>Solutions</strong><br />
<strong>Process</strong> <strong>Systems</strong><br />
Invensys is a global automation, controls and solutions company.<br />
• $5B in sales with ~35,000 employees, listed on London Stock Exchange<br />
• Invensys <strong>Process</strong> <strong>Systems</strong>: $1.5B business; > $12B installed base in O&G & HPI<br />
• IPS Global <strong>Solutions</strong>: Advanced <strong>Process</strong> Control, Simulation, & Optimization<br />
• PRO/II<br />
Irvine<br />
Lake Forest<br />
Toronto<br />
Houston<br />
Mexico City<br />
Montreal<br />
Foxboro<br />
Philadelphia<br />
Crawley<br />
Paris<br />
Milan<br />
Baarn<br />
Düsseldorf<br />
Rome<br />
Abu Dhabi<br />
Hyderabad<br />
Shanghai<br />
Chennai<br />
Seoul<br />
Singapore<br />
Tokyo<br />
• ROMeo<br />
• DYNSIM<br />
• Connoisseur<br />
• ROMSS<br />
Sao Paulo<br />
Buenos Aires<br />
Sydney<br />
• <strong>MRA</strong><br />
Melbourne<br />
Invensys Confidential<br />
2
<strong>Process</strong> Magnetic Resonance<br />
Analyzer (<strong>MRA</strong>)<br />
<strong>Process</strong> <strong>Systems</strong><br />
• High-frequency analysis of key chemical<br />
and physical properties of refining &<br />
petrochemical process streams<br />
• Field-proven, with success stories on<br />
crude/conversion unit feeds & rundowns,<br />
and product blending applications<br />
• Simple, highly-reliable sampling handling<br />
& analytical system (98-99% availability)<br />
• Robust chemometric models<br />
• Significant value from:<br />
– feedstock selection & management<br />
(reduce plan vs. actual gap)<br />
– crude & product blend optimization<br />
– APC feedforward/feedback<br />
– RTO kinetic model feed characterization<br />
Invensys Confidential<br />
3
Magnetic Resonance<br />
Analysis (<strong>MRA</strong>)<br />
<strong>Process</strong> <strong>Systems</strong><br />
Theory<br />
Practice<br />
1 H<br />
Energy<br />
Transition<br />
Invensys Confidential<br />
4
<strong>MRA</strong> Hydrocarbon Spectra<br />
<strong>Process</strong> <strong>Systems</strong><br />
3 CH-C= and CH<br />
CH 2<br />
2.5<br />
H R<br />
2<br />
R H<br />
R R<br />
1.5<br />
H H<br />
CH 3<br />
CH 3<br />
CH 3<br />
1<br />
.5<br />
0<br />
R H<br />
R H<br />
8 7 6 5 4 3 2 1 0<br />
Aromatic Olefinic Water Oxygenate<br />
Methyl<br />
Aromatic<br />
Aliphatic<br />
All functional groups are orthogonal and linear<br />
Invensys Confidential<br />
5
<strong>MRA</strong> Sample Handling<br />
& Conditioning <strong>Systems</strong><br />
<strong>Process</strong> <strong>Systems</strong><br />
• Multi-stream switching system (SSS)<br />
• Optional lab cylinder sample injection<br />
(SIS) & capture (SGS) systems<br />
• Sample returned to process<br />
• Double block & bleed valves<br />
• <strong>Process</strong> stream (e.g., kero) flushing,<br />
if required at all<br />
• No water removal required<br />
(can be measured!)<br />
• Coarse filtering (100 μm) of fast loops<br />
only to protect valve seats<br />
• Rough temperature control: +/- 5 deg C)<br />
Invensys Confidential<br />
6
<strong>MRA</strong> Refinery Applications<br />
<strong>Process</strong> <strong>Systems</strong><br />
Gas Plant<br />
Olefins<br />
Poly. Plant<br />
LPG<br />
<strong>Crude</strong> <strong>Oil</strong><br />
Atmospheric<br />
Tower<br />
Gas<br />
iC 4<br />
Alky. Plant<br />
Alkylate<br />
Lt. Naphtha<br />
Cat. Reformer<br />
Hy. Naphtha<br />
Naphtha<br />
Aromatic Extraction<br />
Reformate<br />
Gasoline Blending<br />
Gasoline<br />
Aromates<br />
<strong>Crude</strong> <strong>Oil</strong>-Preparation<br />
Kero.<br />
Kerosene / Diesel<br />
AGO<br />
Fuel <strong>Oil</strong><br />
Hydrocracker<br />
Residue<br />
VGO<br />
FCC Gasoline<br />
Distillate Blending<br />
<strong>Crude</strong> <strong>Oil</strong> Blending<br />
Coker<br />
FCC<br />
Lubricant <strong>Oil</strong>s<br />
Vacuum<br />
Tower<br />
Bitumen<br />
Invensys Confidential<br />
7
<strong>MRA</strong> <strong>Systems</strong><br />
in <strong>Crude</strong> <strong>Oil</strong> Applications<br />
<strong>Process</strong> <strong>Systems</strong><br />
• Property Analyses:<br />
– API, H2O, S, TBP curve, viscosity<br />
validated to date<br />
– P,N,A, concarbon, asphaltenes,<br />
TAN are feasible/in-progress*<br />
• Projects & Applications:<br />
– ERG ISAB – lab unit for crude<br />
– Isla Curacao<br />
CDU feed/rundowns with ROMeo<br />
– Reliance Jamnagar<br />
crude tank farm blending w/ BOSS<br />
– CITGO Lake Charles*<br />
CDU feed/rundowns with ROMeo<br />
– Conoco-Phillips Bayway*<br />
CDU feed/rundowns for APC<br />
– Pemex E&P*<br />
offshore production & terminal blending<br />
Invensys Confidential<br />
8
<strong>MRA</strong> <strong>Crude</strong> Assays<br />
<strong>Process</strong> <strong>Systems</strong><br />
<strong>MRA</strong> has been successfully<br />
applied to crudes ranging<br />
from 9 to 52 deg API<br />
Invensys Confidential<br />
9
<strong>MRA</strong> Feed Blend and CDU<br />
Optimization System<br />
<strong>Process</strong> <strong>Systems</strong><br />
FFC<br />
BOSS/BPO/OMM<br />
FFC<br />
FFC<br />
<strong>MRA</strong><br />
<strong>Crude</strong><br />
Receipts<br />
CDU APC &<br />
ROMeo<br />
Invensys Confidential<br />
10
<strong>Crude</strong> Supply Chain<br />
Quality Measurement Value?<br />
<strong>Process</strong> <strong>Systems</strong><br />
• Potential Sample Points:<br />
– production field/platform blending<br />
– syncrude upgrader units<br />
– crude terminal receipts, blends,<br />
& shipments<br />
– refinery pipeline/jetty receipts &<br />
tank farm transfers<br />
– refinery CDU feed blending<br />
• Potential Application Value:<br />
– production facility giveaway minimization<br />
– flash assay updates for crude trading valuation<br />
– refinery inventory valuation, planning & scheduling accuracy<br />
– refinery plan vs. actual gap reduction<br />
– stabilized, optimal CDU & downstream unit operation<br />
<br />
Ideas? Questions? Eric Gildea – 281-217-0001 – eric.gildea@ips.invensys.com<br />
Invensys Confidential<br />
11
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