Chemwatch MSDS Print - FUJIFILM Australia

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Chemwatch MSDS Print - FUJIFILM Australia

Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 1 of 7

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

Fujifilm Sericol Dirasol 916

PRODUCT USE

Photostencil emulsion.

SUPPLIER

Company: FUJIFILM Australia Pty Ltd

Address:

114 Old Pittwater Road

Brookvale

NSW, 2100

Australia

Telephone: +61 2 9466 2600

Emergency Tel:+61 1800 039 008

Emergency Tel:+61 3 9573 3112

Fax: +61 2 9938 1975

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability

Toxicity

Body Contact

Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

RISK

■ May cause SENSITISATION by skin contact.

■ Harmful to aquatic organisms, may cause

long- term adverse effects in the aquatic

environment.

SAFETY

• Do not breathe gas/fumes/vapour/spray.

• Avoid contact with skin.

• To clean the floor and all objects contaminated

by this material, use water.

• If swallowed, IMMEDIATELY contact Doctor or

Poisons Information Centre. (show this container

or label).

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 2 of 7

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %

tripropylene glycol diacrylate 42978-66-5 1-5

dipropylene glycol dibenzoate 27138-31-4 1-5

other non hazardous ingredients >60

Section 4 - FIRST AID MEASURES

SWALLOWED

• Immediately give a glass of water.

• First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

EYE

■ If this product comes in contact with eyes:

• Wash out immediately with water.

• If irritation continues, seek medical attention.

• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin contact occurs:

• Immediately remove all contaminated clothing, including footwear.

• Flush skin and hair with running water (and soap if available).

• Seek medical attention in event of irritation.

INHALED

• If fumes, aerosols or combustion products are inhaled remove from contaminated area.

• Other measures are usually unnecessary.

NOTES TO PHYSICIAN

Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

• There is no restriction on the type of extinguisher which may be used.

• Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

• Alert Fire Brigade and tell them location and nature of hazard.

• May be violently or explosively reactive.

• Wear full body protective clothing with breathing apparatus.

• Prevent, by any means available, spillage from entering drains or water course.

FIRE/EXPLOSION HAZARD

• Non combustible.

• Not considered a significant fire risk, however containers may burn.

Decomposition may produce toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of

burning organic material.

May emit poisonous fumes.

May emit corrosive fumes.

FIRE INCOMPATIBILITY

• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may

result.

HAZCHEM

None

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 3 of 7

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

• Clean up all spills immediately.

• Avoid breathing vapours and contact with skin and eyes.

• Control personal contact with the substance, by using protective equipment.

• Contain and absorb spill with sand, earth, inert material or vermiculite.

MAJOR SPILLS

Moderate hazard.

• Clear area of personnel and move upwind.

• Alert Fire Brigade and tell them location and nature of hazard.

• Wear breathing apparatus plus protective gloves.

• Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

• Most acrylic monomers have low viscosity therefore pouring, material transfer and processing of these materials do not

necessitate heating.

• Viscous monomers may require heating to facilitate handling. To facilitate product transfer from original containers, product

must be heated to no more than 60 deg. C. (140 F.), for not more than 24 hours.

• Do NOT use localised heat sources such as band heaters to heat/ melt product.

• Do NOT use steam .

• DO NOT allow clothing wet with material to stay in contact with skin.

• Avoid all personal contact, including inhalation.

• Wear protective clothing when risk of exposure occurs.

• Use in a well-ventilated area.

• Avoid contact with moisture.

SUITABLE CONTAINER

• Polyethylene or polypropylene container.

• Packing as recommended by manufacturer.

• Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

for multifunctional acrylates:

• Avoid exposure to free radical initiators (peroxides, persulfates) , iron, rust, oxidisers, and strong acids and strong bases.

• Avoid heat, flame, sunlight, X-rays or ultra-violet radiation.

• Storage beyond expiration date, may initiate polymerisation. Polymerisation of large quantities may be violent (even explosive).

STORAGE REQUIREMENTS

• Store in original containers.

• Keep containers securely sealed.

• Store in a cool, dry, well-ventilated area.

• Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

The following materials had no OELs on our records

• tripropylene glycol diacrylate: CAS:42978- 66- 5 CAS:68901- 05- 3

• dipropylene glycol dibenzoate: CAS:27138- 31- 4 CAS:20109- 39- 1

MATERIAL DATA

FUJIFILM SERICOL DIRASOL 916:

Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically

occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne

concentrations.

None assigned. Refer to individual constituents.

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 4 of 7

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

TRIPROPYLENE GLYCOL DIACRYLATE:

For 4-methoxyphenol (MEHQ)

MEHQ has caused ocular toxicity in animals and skin depigmentation in rodents and workers. The recommendation for the TLV-TWA

arises from documented eye and skin toxicities and by analogy with hydroquinone.

CEL TWA: 1 mg/m3 [compare WEEL-TWA* for multifunctional acrylates (MFAs)]

Exposure to MFAs has been reported to cause contact dermatitis in humans and serious eye injury in laboratory animals.

Exposure to some MFA-resin containing aerosols has also been reported to cause dermatitis.

DIPROPYLENE GLYCOL DIBENZOATE:

No exposure limits set by NOHSC or ACGIH.

PERSONAL PROTECTION

RESPIRATOR

•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

EYE

• Safety glasses with side shields.

• Chemical goggles.

• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of

chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].

HANDS/FEET

• Wear chemical protective gloves, eg. PVC.

• Wear safety footwear or safety gumboots, eg. Rubber.

NOTE:

• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other

protective equipment, to avoid all possible skin contact.

• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:

• frequency and duration of contact,

• chemical resistance of glove material,

• glove thickness and

• dexterity.

OTHER

• Overalls.

• P.V.C. apron.

• Barrier cream.

• Skin cleansing cream.

ENGINEERING CONTROLS

■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to

provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation

that strategically "adds" and "removes" air in the work environment.

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 5 of 7

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Coloured liquid with a characteristic odour; mixes with water.

PHYSICAL PROPERTIES

Liquid.

Mixes with water.

State Liquid Molecular Weight Not Applicable

Melting Range (°C) Not Available Viscosity Not Available

Boiling Range (°C) 100 Solubility in water (g/L) Miscible

Flash Point (°C) Not Applicable pH (1% solution) Not Available

Decomposition Temp (°C) Not Available pH (as supplied) 4.2

Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) 2.3 @ 20C

Upper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.07

Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available

(air=1)

Volatile Component (%vol) Not Available Evaporation Rate Not Available

Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY

• Presence of incompatible materials.

• Product is considered stable.

• Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

■ The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is

because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual,

following ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident. Present definitions of harmful or

toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health).

Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant

quantities is not thought to be cause for concern.

EYE

■ Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce

transient discomfort characterised by tearing or conjunctival redness (as with windburn).

SKIN

■ All multifunctional acrylates (MFA) produce skin disorders and sensitise the skin and inflammation. Vapours generated by the

heat of milling may occur in sufficient concentration to produce inflammation. Because exposure to industrial aerosols of MFA

includes exposure to resin systems, photo-initiators, solvents, hydrogen-transfer agents, stabilisers, surfactants, fillers and

polymerisation inhibitors, poisoning may arise due to a range of chemical actions.

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.

Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

INHALED

■ No report of respiratory illness in humans as a result of exposure to multifunctional acrylates has been found.

CHRONIC HEALTH EFFECTS

■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general

population.

Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational

exposure.

There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 6 of 7

Section 11 - TOXICOLOGICAL INFORMATION

the general population.

Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised persons should not be

allowed to work in situations where exposure may occur.

TOXICITY AND IRRITATION

■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis

of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,

e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simply

determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are

equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with

stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are

noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.

Section 12 - ECOLOGICAL INFORMATION

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Ecotoxicity

Ingredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soil

tripropylene glycol diacrylate HIGH No Data LOW HIGH

Available

dipropylene glycol dibenzoate HIGH No Data LOW MED

Available

Section 13 - DISPOSAL CONSIDERATIONS

• Containers may still present a chemical hazard/ danger when empty.

• Return to supplier for reuse/ recycling if possible.

Otherwise:

• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to

store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.

• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws

operating in their area.

A Hierarchy of Controls seems to be common - the user should investigate:

• Reduction.

• DO NOT allow wash water from cleaning or process equipment to enter drains.

• It may be necessary to collect all wash water for treatment before disposal.

• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.

• Where in doubt contact the responsible authority.

• Recycle wherever possible.

• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable

treatment or disposal facility can be identified.

• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in

a licenced apparatus (after admixture with suitable combustible material).

• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None (ADG7)

NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG

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Fujifilm Sericol Dirasol 916

Chemwatch Material Safety Data Sheet

Issue Date: 10-Dec-2009 CHEMWATCH 4600-33

9317SP

Version No:5

Page 7 of 7

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

None

REGULATIONS

Regulations for ingredients

tripropylene glycol diacrylate (CAS: 42978-66-5, 68901-05-3) is found on the following

regulatory lists;

"Australia Hazardous Substances", "Australia Inventory of Chemical Substances (AICS)", "International Council of Chemical

Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals"

dipropylene glycol dibenzoate (CAS: 27138-31-4, 20109-39-1) is found on the following

regulatory lists;

"Australia Inventory of Chemical Substances (AICS)", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "OECD List of High

Production Volume (HPV) Chemicals"

No data for Fujifilm Sericol Dirasol 916 (CW: 4600-33)

Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substances

Substance CAS Suggested codes

tripropylene glycol diacrylate 68901- 05- 3 Carc3; R40 R43

Xi; R38 N; R50

dipropylene glycol dibenzoate 27138- 31- 4 N; R51/53

dipropylene glycol dibenzoate 20109- 39- 1 R43 N; R51/53

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name

CAS

tripropylene glycol diacrylate 42978-66-5, 68901-05-3

dipropylene glycol dibenzoate 27138-31-4, 20109-39-1

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as

independent review by the Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether

the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written

permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 10-Dec-2009

Print Date: 25-Jun-2012

This is the end of the MSDS.


Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 1 of 7

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

Fujifilm Sericol Diazo Sensitiser SZM02

PROPER SHIPPING NAME

DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)

PRODUCT USE

Photostencil emulsion sensitiser.

SUPPLIER

Company: FUJIFILM Australia Pty Ltd

Address:

114 Old Pittwater Road

Brookvale

NSW, 2100

Australia

Telephone: +61 2 9466 2600

Emergency Tel:+61 1800 039 008

Emergency Tel:+61 3 9573 3112

Fax: +61 2 9938 1975

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability

Toxicity

Body Contact

Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

RISK

■ Harmful if swallowed.

■ Causes burns.

■ Risk of serious damage to eyes.

■ Toxic to aquatic organisms, may cause

long- term adverse effects in the aquatic

environment.

SAFETY

• Keep locked up.

• Do not breathe gas/fumes/vapour/spray.

• Avoid contact with skin.

• Avoid contact with eyes.

• Wear suitable protective clothing.

• Wear suitable gloves.

• Wear eye/face protection.

• Do not empty into drains.

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Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 2 of 7

Section 2 - HAZARDS IDENTIFICATION

• To clean the floor and all objects contaminated by

this material, use water.

• This material and its container must be disposed of

in a safe way.

• Take off immediately all contaminated clothing.

• In case of contact with eyes, rinse with plenty of

water and contact Doctor or Poisons Information

Centre.

• In case of accident or if you feel unwell

IMMEDIATELY contact Doctor or Poisons Information

Centre (show label if possible).

• Use appropriate container to avoid environmental

contamination.

• Avoid release to the environment. Refer to special

instructions/Safety data sheets.

• This material and its container must be disposed of

as hazardous waste.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %

phosphoric acid 7664-38-2 25-50

dye unregulated >50

additives unregulated

Section 4 - FIRST AID MEASURES

SWALLOWED

■ If poisoning occurs, contact a doctor or Poisons Information Centre.

• If swallowed do NOT induce vomiting.

• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and

prevent aspiration.

• Observe the patient carefully.

• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

EYE

■ If this product comes in contact with the eyes:

• Immediately hold eyelids apart and flush the eye continuously with running water.

• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting

the upper and lower lids.

• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.

• Transport to hospital or doctor without delay.

SKIN

■ If skin or hair contact occurs:

• Immediately flush body and clothes with large amounts of water, using safety shower if available.

• Quickly remove all contaminated clothing, including footwear.

• Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.

• Transport to hospital, or doctor.

INHALED

• If fumes or combustion products are inhaled remove from contaminated area.

• Lay patient down. Keep warm and rested.

• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid

procedures.

• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket

mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIAN

For acute or short term repeated exposures to strong acids:

• Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.

• Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling

• Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.

• Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating

action of the acid on proteins in specific tissues.

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Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 3 of 7

Section 4 - FIRST AID MEASURES

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

• Water spray or fog.

• Foam.

• Dry chemical powder.

• BCF (where regulations permit).

FIRE FIGHTING

• Alert Fire Brigade and tell them location and nature of hazard.

• Wear full body protective clothing with breathing apparatus.

• Prevent, by any means available, spillage from entering drains or water course.

• Use fire fighting procedures suitable for surrounding area.

FIRE/EXPLOSION HAZARD

• Non combustible.

• Not considered to be a significant fire risk.

• Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.

• Heating may cause expansion or decomposition leading to violent rupture of containers.

Other decomposition products include: phosphorus oxides (POx).

HAZCHEM

2X

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

Clean up all spills immediately.

Avoid contact with skin and eyes.

Wear protective neoprene gloves and chemical goggles.

Use soda ash or slaked lime to neutralise.

Wipe up and absorb small quantities with vermiculite or other absorbent material.

Place in suitable containers for disposal.

Wash spill area with large quantities of water.

MAJOR SPILLS

• Clear area of personnel and move upwind.

• Alert Fire Brigade and tell them location and nature of hazard.

• Wear full body protective clothing with breathing apparatus.

• Prevent, by any means available, spillage from entering drains or water course.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

• Avoid all personal contact, including inhalation.

• Wear protective clothing when risk of exposure occurs.

• Use in a well-ventilated area.

• WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.

SUITABLE CONTAINER

Plastic carboy.

Polyethylene or polypropylene container.

Polylined drum.

• Check that containers are clearly labelled.

• Packaging as recommended by manufacturer.

STORAGE INCOMPATIBILITY

Avoid storage with strong alkalis, common metals and

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Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 4 of 7

Section 7 - HANDLING AND STORAGE

their alloys, oxidising and reducing agents, cyanides, sulphides and

combustible materials and other chemicals decomposed by strong acids.

STORAGE REQUIREMENTS

• Store in original containers.

• Keep containers securely sealed.

• Store in a cool, dry, well-ventilated area.

• Store away from incompatible materials and foodstuff containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

Source Material TWA TWA STEL STEL Peak Peak TWA Notes

ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC

__________ __________ ______ ______ ______ ______ ______ ______ ______ ______

Australia (Phosphoric 1 3

Exposure

acid)

Standards

MATERIAL DATA

FUJIFILM SERICOL DIAZO SENSITISER SZM02:

None assigned. Refer to individual constituents.

PHOSPHORIC ACID:

The saturated vapour concentration of phosphoric acid exceeds the TLV. The TLV-TWA is based by analogy from comparable

experience and data for sulfuric acid.

Fumes of phosphorus pentoxide at concentrations between 0.8 and 5.4 mg/m3 were reported to be noticeable but not uncomfortable

whilst concentrations between 3.6 and 11.3 mg/m3 produced coughing in unacclimatised workers but were tolerable.

PERSONAL PROTECTION

RESPIRATOR

•Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

EYE

• Safety glasses with side shields.

• Chemical goggles.

• Full face shield may be required for supplementary but never for primary protection of eyes

• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,

describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a

review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and

first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of

chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at

the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed

hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].

HANDS/FEET

• Butyl rubber gloves.

• Rubber gloves.

• PVC gloves.

• Impervious gloves.

• Safety footwear.

• Rubber boots.

OTHER

• Overalls.

• PVC Apron.

• PVC protective suit may be required if exposure severe.

• Eyewash unit.

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Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 5 of 7

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS

■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed

engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to

provide this high level of protection.

The basic types of engineering controls are:

Process controls which involve changing the way a job activity or process is done to reduce the risk.

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation

that strategically "adds" and "removes" air in the work environment.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Coloured acidic liquid with a characteristic odour; mixes with water.

PHYSICAL PROPERTIES

Liquid.

Mixes with water.

Corrosive.

Acid.

State Liquid Molecular Weight Not applicable

Melting Range (°C) Not available Viscosity Not available

Boiling Range (°C) Not available Solubility in water (g/L) Miscible

Flash Point (°C) Not applicable pH (1% solution) Not available

Decomposition Temp (°C) Not available pH (as supplied)


Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 6 of 7

Section 11 - TOXICOLOGICAL INFORMATION

INHALED

■ Not normally a hazard due to non-volatile nature of product.

The vapour/mist is highly discomforting to the upper respiratory tract and may cause breathing difficulty.

Inhalation of vapour is more likely at higher than normal temperatures.

The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.

CHRONIC HEALTH EFFECTS

■ Principal routes of exposure are usually by skin contact/eye contact.

TOXICITY AND IRRITATION

■ Not available. Refer to individual constituents.

CARCINOGEN

Acid mists, strong International Agency for Group 1

inorganic Research on Cancer (IARC) -

Agents Reviewed by the IARC

Monographs

Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

This material and its container must be disposed of as hazardous waste.

Avoid release to the environment.

Refer to special instructions/ safety data sheets.

Ecotoxicity

Ingredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soil

phosphoric acid HIGH No Data LOW HIGH

Available

Section 13 - DISPOSAL CONSIDERATIONS

• Recycle wherever possible or consult manufacturer for recycling options.

• Consult State Land Waste Management Authority for disposal.

• Treat and neutralise with slaked lime at an effluent treatment plant.

• Recycle containers, otherwise dispose of in an authorised landfill.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: CORROSIVE

HAZCHEM:

2X (ADG7)

Land Transport UNDG:

Class or division: 8 Subsidiary risk: None

UN No.: 2801 UN packing group: III

Shipping Name:DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE,

LIQUID, CORROSIVE, N.O.S. (contains phosphoric acid)

Air Transport IATA:

ICAO/IATA Class: 8 ICAO/IATA Subrisk: None

UN/ID Number: 2801 Packing Group: III

Special provisions:

A3A803

Cargo Only

continued...


Fujifilm Sericol Diazo Sensitiser SZM02

Chemwatch Material Safety Data Sheet

Issue Date: 9-Dec-2009 CHEMWATCH 4600-35

9317SP

Version No:4

Page 7 of 7

Section 14 - TRANSPORTATION INFORMATION

Packing Instructions: 856 Maximum Qty/Pack: 60 L

Passenger and Cargo

Passenger and Cargo

Packing Instructions: 852 Maximum Qty/Pack: 5 L

Passenger and Cargo Limited Quantity

Passenger and Cargo Limited Quantity

Packing Instructions: Y841 Maximum Qty/Pack: 1 L

Shipping name:DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)

Maritime Transport IMDG:

IMDG Class: 8 IMDG Subrisk: None

UN Number: 2801 Packing Group: III

EMS Number: F-A,S-B Special provisions: 223 274

Limited Quantities: 5 L Marine Pollutant: Yes

Shipping name:DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE

S6

REGULATIONS

Regulations for ingredients

phosphoric acid (CAS: 7664-38-2, 16271-20-8) is found on the following regulatory lists;

"Australia Exposure Standards", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)",

"Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for the

Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling of

Medicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons

(SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "GESAMP/EHS

Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (Annex

II) - List of Noxious Liquid Substances Carried in Bulk", "International Agency for Research on Cancer (IARC) - Agents Reviewed

by the IARC Monographs", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of

High Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – United Kingdom"

No data for Fujifilm Sericol Diazo Sensitiser SZM02 (CW: 4600-35)

Section 16 - OTHER INFORMATION

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name CAS

phosphoric acid 7664-38-2, 16271-20-8

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as

independent review by the Chemwatch Classification committee using available literature references.

A list of reference resources used to assist the committee may be found at:

www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether

the reported Hazards are Risks in the workplace or other settings.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or

criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written

permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 9-Dec-2009

Print Date: 25-Jun-2012

This is the end of the MSDS.

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