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Botkin Environmental Science Earth as Living Planet 8th txtbk

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120 CHAPTER 6 The Biogeochemical Cycles<br />

oxygen will incre<strong>as</strong>e. Conversely, if more organic carbon<br />

escapes burial and is oxidized to produce CO 2 , then the<br />

CO 2 concentration in the atmosphere will incre<strong>as</strong>e. 13<br />

The Nitrogen Cycle<br />

Nitrogen is essential to life in proteins and DNA. As we<br />

discussed at the beginning of this chapter, free or diatonic<br />

nitrogen (N 2 uncombined with any other element) makes<br />

up approximately 78% of <strong>Earth</strong>’s atmosphere. However,<br />

no organism can use molecular nitrogen directly. Some<br />

organisms, such <strong>as</strong> animals, require nitrogen in an organic<br />

compound. Others, including plants, algae, and bacteria,<br />

can take up nitrogen either <strong>as</strong> the nitrate ion (NO 3 ) or the<br />

ammonium ion (NH 4 ). Because nitrogen is a relatively<br />

unreactive element, few processes convert molecular nitrogen<br />

to one of these compounds. Lightning oxidizes<br />

nitrogen, producing nitric oxide. In nature, essentially all<br />

other conversions of molecular nitrogen to biologically<br />

useful forms are conducted by bacteria.<br />

The nitrogen cycle is one of the most important<br />

and most complex of the global cycles (Figure 6.18). The<br />

process of converting inorganic, molecular nitrogen in the<br />

atmosphere to ammonia or nitrate is called nitrogen fixation.<br />

Once in these forms, nitrogen can be used on land<br />

by plants and in the oceans by algae. Bacteria, plants, and<br />

algae then convert these inorganic nitrogen compounds<br />

into organic ones through chemical reactions, and the nitrogen<br />

becomes available in ecological food chains. When<br />

organisms die, bacteria convert the organic compounds<br />

containing nitrogen back to ammonia, nitrate, or molecular<br />

nitrogen, which enters the atmosphere. The process<br />

of rele<strong>as</strong>ing fixed nitrogen back to molecular nitrogen is<br />

called denitrification.<br />

Land plants<br />

3500<br />

Atmosphere<br />

4,000,000,000<br />

Nitrogen fixation<br />

(by bacteria)<br />

Industrial<br />

fixation<br />

80<br />

20<br />

Fixation in<br />

lightning<br />

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