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Dangerous Goods Storage and Handling Guidelines - Staff

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DANGEROUS GOODS STORAGE AND HANDLING<br />

GUIDELINES<br />

Contents<br />

1 Introduction............................................................................................................................... 3<br />

2 Scope ....................................................................................................................................... 4<br />

3 Responsibilities ........................................................................................................................ 4<br />

3.1 Deans <strong>and</strong> Directors of Units .................................................................................... 4<br />

3.2 Department Heads <strong>and</strong> Managers ............................................................................ 4<br />

3.3 Employees................................................................................................................ 4<br />

4 Definitions ................................................................................................................................ 4<br />

5 Implementation ......................................................................................................................... 5<br />

6 Hazard Identification ................................................................................................................. 5<br />

6.1 Determination of <strong>Dangerous</strong> <strong>Goods</strong> ......................................................................... 5<br />

6.2 <strong>Dangerous</strong> <strong>Goods</strong> Classes ....................................................................................... 6<br />

6.3 Manifest Requirements ............................................................................................. 6<br />

7 Risk Assessment ...................................................................................................................... 6<br />

7.1 Review of Risk Assessments .................................................................................... 7<br />

7.2 Records of Risk Assessments .................................................................................. 7<br />

8 Risk Control Strategies ............................................................................................................. 7<br />

8.1 Stability <strong>and</strong> Interaction with <strong>Dangerous</strong> <strong>Goods</strong> ....................................................... 8<br />

8.2 Preventing Interaction with Other Substances .......................................................... 8<br />

8.3 Ignition Sources ........................................................................................................ 8<br />

8.4 Emissions ................................................................................................................. 8<br />

8.5 Contamination of Food <strong>and</strong> Personal Products ......................................................... 8<br />

8.6 Containers for <strong>Dangerous</strong> <strong>Goods</strong> in Bulk .................................................................. 8<br />

8.7 Containment of Spills ................................................................................................ 8<br />

8.8 Transfer of <strong>Dangerous</strong> <strong>Goods</strong> .................................................................................. 9<br />

8.9 Fire Protection, Spillage Controls <strong>and</strong> Ventilation ..................................................... 9<br />

8.10 Planning for Emergencies ......................................................................................... 9<br />

8.11 Safety Equipment <strong>and</strong> Safe Access .......................................................................... 9<br />

8.12 Cleaning or Decommissioning Plant, Equipment <strong>and</strong> Containers ............................. 9<br />

8.13 Placarding .............................................................................................................. 10<br />

8.14 Labelling ................................................................................................................. 10<br />

8.15 Records .................................................................................................................. 10<br />

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8.16 <strong>Storage</strong> ................................................................................................................... 11<br />

8.17 Incident Management ............................................................................................. 11<br />

8.18 Other Controls ........................................................................................................ 11<br />

8.19 Operations of <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling in Small Quantities ........................................ 11<br />

8.20 Monitoring <strong>and</strong> Review ........................................................................................... 12<br />

9 Transport of <strong>Dangerous</strong> <strong>Goods</strong> .............................................................................................. 12<br />

10 Security Sensitive <strong>Dangerous</strong> Substances ............................................................................. 12<br />

11 Program evaluation ................................................................................................................ 13<br />

12 Related documents ................................................................................................................. 13<br />

13 References ............................................................................................................................. 13<br />

14 Version Control Table ............................................................................................................. 14<br />

Appendix 1: Notification Quantities ............................................................................................... 15<br />

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<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

1 Introduction<br />

<strong>Dangerous</strong> goods are substances, mixtures or articles that, because of their physical, chemical<br />

(physicochemical) or acute toxicity properties, present an immediate hazard to people, property<br />

or the environment. Types of substances classified as dangerous goods include explosives,<br />

flammable liquids <strong>and</strong> gases, corrosives, chemically reactive or acutely (highly) toxic substances.<br />

The criteria used to determine whether substances are classified as dangerous goods are<br />

contained in the Australian Code for the Transport of <strong>Dangerous</strong> <strong>Goods</strong> by Road <strong>and</strong> Rail (ADG<br />

Code). The ADG Code contains a list of substances classified as dangerous goods.<br />

State <strong>and</strong> territory workplace dangerous goods storage <strong>and</strong> h<strong>and</strong>ling laws also capture<br />

combustible liquids. The criteria for classifying combustible liquids are contained in Australian<br />

St<strong>and</strong>ard AS1940 (The <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling of Flammable <strong>and</strong> Combustible Liquids).<br />

Many dangerous goods are also classed as hazardous substances.<br />

There are nine classes of dangerous goods:<br />

Class 1<br />

Class 2<br />

Class 3<br />

Class 4<br />

Class 5<br />

Class 6<br />

Class 7<br />

Class 8<br />

Class 9<br />

Explosives<br />

Gases (Flammable, Compressed/Non-Toxic, Poisonous)<br />

Flammable Liquids<br />

Flammable Solids<br />

Oxidisers <strong>and</strong> Organic Peroxides<br />

Toxic Substances<br />

Radioactive Substances<br />

Corrosive Substances<br />

Miscellaneous <strong>Dangerous</strong> <strong>Goods</strong><br />

It is possible for substances to display more than one characteristic, therefore these substances<br />

will display more than one class label. In those circumstances the substance will have a full<br />

primary class label <strong>and</strong> a subsidiary label which is less prominent that the primary.<br />

To further assist with the identification of dangerous goods <strong>and</strong> their particular hazards, those of<br />

class 3, 4, 5, 6 <strong>and</strong> 8 are assigned to a packing group which represents the "level of danger" to<br />

persons exposed.<br />

Packing groups:<br />

I = Great danger<br />

II = Medium danger<br />

III = Minor danger<br />

The United Nations have allocated a four digit UN Number to substances <strong>and</strong> articles to assist in<br />

their identification, e.g. UN 1075 = LP Gas. To assist emergency services around the world a<br />

HAZCHEM Code has been developed which is a first response instruction which provides advice<br />

on dealing with issues such as a fire or an environmental contamination situation involving<br />

dangerous goods. For further details on UN Numbers <strong>and</strong> HAZCHEM Coding, reference should<br />

be made to the current edition of the Australian <strong>Dangerous</strong> <strong>Goods</strong> (ADG) Code.<br />

These guidelines are based on specific legislative requirements as contained in the WHS<br />

Regulation 2011 <strong>and</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling of <strong>Dangerous</strong> <strong>Goods</strong>: Code of Practice.<br />

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2 Scope<br />

<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

This document provides guidelines on the storage <strong>and</strong> h<strong>and</strong>ling of dangerous goods including the<br />

requirement for notification to authorities when exceeding the threshold.<br />

3 Responsibilities<br />

3.1 Deans <strong>and</strong> Directors of Units<br />

Deans <strong>and</strong> Directors of units have the responsibility to ensure that legislation relating to storage<br />

<strong>and</strong> h<strong>and</strong>ling of dangerous goods is implemented <strong>and</strong> that appropriate support strategies <strong>and</strong><br />

management plans are adopted according to the University’s dangerous goods program <strong>and</strong><br />

practices.<br />

3.2 Department Heads <strong>and</strong> Managers<br />

Department heads <strong>and</strong> managers are responsible to implement legislation <strong>and</strong> dangerous goods<br />

guidelines within their area of responsibility.<br />

3.3 Employees<br />

All employees are required to cooperate with the University <strong>and</strong>, in relation to the tasks that effect<br />

them directly, contribute to the process of identification, assessment <strong>and</strong> control, <strong>and</strong> support<br />

implementation of the legislation by participation in:<br />

• risk assessment processes<br />

• consultation, <strong>and</strong><br />

• training.<br />

4 Definitions<br />

Bunding<br />

Cabinet<br />

Class<br />

Combustible<br />

<strong>Dangerous</strong> <strong>Goods</strong><br />

EPA<br />

Flammable<br />

HAZCHEM<br />

Keeping<br />

Label<br />

PG<br />

PPE<br />

Containment device for liquid storage<br />

Approved internal storage cabinet for a particular <strong>Dangerous</strong> <strong>Goods</strong> class<br />

Classification applied to <strong>Dangerous</strong> <strong>Goods</strong><br />

C1 - substance having a flashpoint of >60.5 o C <strong>and</strong> 150 o C<br />

Substances or articles defined under the Australian <strong>Dangerous</strong> <strong>Goods</strong><br />

(ADG) code as class 2, 3, 4, 5, 6.1, 8 or 9, goods too dangerous to be<br />

transported or C1 combustible liquids<br />

Environment Protection Authority<br />

substance having a flashpoint of


<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

SDS<br />

SSDS<br />

UN Number<br />

WorkCover<br />

A Safety Data Sheet (SDS) is a document which outlines specific health<br />

<strong>and</strong> safety information about the substance. Information includes:<br />

- Whether the substance is classified as hazardous<br />

- Chemical aspects of the substance<br />

- First aid advice<br />

- Risk controls to prevent injury<br />

Security sensitive dangerous substances (SSDS) are any goods prescribed<br />

by the regulation as security sensitive dangerous substances, also referred<br />

to as explosive precursors.<br />

The four digit number used to identify dangerous goods worldwide<br />

WorkCover Authority NSW<br />

5 Implementation<br />

These guidelines assist with the implementation of the requirements of the WHS Regulation <strong>and</strong><br />

<strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling of <strong>Dangerous</strong> <strong>Goods</strong>: Code of Practice. Further information regarding<br />

implementation should be referred to the Code of Practice <strong>and</strong> associated st<strong>and</strong>ards.<br />

6 Hazard Identification<br />

It is essential to identify foreseeable hazards associated with any substance that is classified as a<br />

dangerous good in order to enable an assessment of the risk <strong>and</strong> determine the required<br />

controls. The following details the process to identify dangerous goods within the University.<br />

6.1 Determination of <strong>Dangerous</strong> <strong>Goods</strong><br />

It is necessary to identify those dangerous goods at the workplace together with any foreseeable<br />

hazards arising from the use, storage <strong>and</strong> h<strong>and</strong>ling of the product. This can occur through risk<br />

management processes as per the Risk Management <strong>Guidelines</strong>.<br />

This identification may include a stocktake to establish:<br />

• what items are stored<br />

• the method of storage<br />

• transport<br />

• how it is h<strong>and</strong>led <strong>and</strong> used<br />

• who is in control<br />

• substance compatibility <strong>and</strong> separation<br />

• hazardous areas that is within, or arises from storage or h<strong>and</strong>ling.<br />

Information regarding a dangerous good will be available from the supplied Safety Data Sheet<br />

(SDS). SDS’s are available from the supplier <strong>and</strong> uploaded by each unit to Chem Alert.<br />

A review SDS will identify if there is a need to segregate substances according to dangerous<br />

goods class. Source an SDS from the supplier for the substance if there is not one available.<br />

Document the findings such as compiling an inventory to establish what is stored, h<strong>and</strong>led <strong>and</strong><br />

used (Chem Alert). Identify which of those substances are classified as a dangerous good or a<br />

hazardous substance. Further information on SDS can be found in the Hazardous Substances<br />

<strong>Guidelines</strong>.<br />

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6.2 <strong>Dangerous</strong> <strong>Goods</strong> Classes<br />

<strong>Dangerous</strong> goods are divided into nine classes according to their dangerous properties. Classes<br />

1, 2, 4, 5 <strong>and</strong> 6 are further subdivided into sub-classes (e.g. 5.1, 5.2). In addition, goods in<br />

Classes 3, 4, 5, 6 <strong>and</strong> 8 are also organised into Packing Groups (PG) which indicate the degree<br />

of danger (PG I - great danger, PG II - medium danger, PG III - minor danger).<br />

<strong>Dangerous</strong> goods in any quantity must be stored safely <strong>and</strong> in compliance with the WHS Act <strong>and</strong><br />

associated regulations. <strong>Dangerous</strong> goods above certain quantities must be notified to<br />

WorkCover.<br />

6.3 Manifest Requirements<br />

Each area using, introducing or producing hazardous substances or dangerous goods is<br />

responsible to record these in the University manifest (Stock Holdings). Each of these products<br />

must also have relevant documentation including an SDS.<br />

The inventory should include:<br />

• product trade name <strong>and</strong> United Nations number<br />

• dangerous <strong>Goods</strong> Class <strong>and</strong> Packing Group<br />

• typical <strong>and</strong> maximum quantities held <strong>and</strong> the package sizes <strong>and</strong> supplier details, <strong>and</strong><br />

• location of storage <strong>and</strong> point of use.<br />

Quantities above the “Manifest quantities” outlined in Appendix 1 are to be in licensed stores,<br />

such as an approved storage cabinet, which is fitted with an internal bund to contain any spillage.<br />

Flammables are to be stored away from ignition sources, <strong>and</strong> wherever possible avoid the<br />

internal storage of flammable <strong>and</strong> poisonous gases.<br />

Externally relocate gas cylinders <strong>and</strong> pipe supplies to point of use, <strong>and</strong> always secure gas<br />

cylinders in an upright position.<br />

WorkCover NSW is required to be notified for quantities exceeding the ‘Manifest quantities’ as<br />

outlined in Appendix 1.<br />

7 Risk Assessment<br />

Once the hazards associated with the storage of dangerous goods are identified, a risk<br />

assessment should be undertaken to assess the level of risk of injury <strong>and</strong> then to implement risk<br />

controls in order to maintain legislative requirements <strong>and</strong> provide safe workplace.<br />

For the storage of dangerous goods below, the manifest threshold outlined in Appendix 1 <strong>and</strong> the<br />

requirements of the Code of Practice shall be implemented appropriately. Additionally the SDS<br />

for the dangerous good will act as the risk assessment for the storage, use <strong>and</strong> maintenance.<br />

Deviations from the requirements of the SDS will need to be recorded through the risk<br />

assessment form.<br />

Where the storage of dangerous goods is above the manifest quantity, a documented risk<br />

assessment needs to be undertaken. The risk assessment will take into consideration the<br />

following:<br />

• the quantity stored <strong>and</strong> in use<br />

• the extent of risk to people<br />

• the extent of risk to other substances, plant <strong>and</strong> buildings<br />

• factors contributing to the risk<br />

• types of controls required<br />

• priorities for implementing controls, <strong>and</strong><br />

• identification of type of records required.<br />

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<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

The risk assessment should reference the safety data sheet to identify risks associated with each<br />

dangerous good <strong>and</strong> use the Hazardous Substances Risk Assessment Form.<br />

The risk assessment process should also include a site map to indicate storage locations <strong>and</strong><br />

quantities for licensing with WorkCover.<br />

E.g.<br />

Underground tank = 45,000 l of diesel at Facilities Management Division compound<br />

Flammable liquids roofed package store = 8,000 kg at building 31<br />

Corrosives Cabinet = 250 l <strong>and</strong> Toxic Substances Cabinet = 100 l in Room 5:34<br />

Where a laboratory has a quantity of substances, but with no more than a few litres or kilos in any<br />

one class, it is not necessary to notify WorkCover NSW. However, it is recommended that the<br />

laboratory be marked on a map for internal use as being a facility that holds a quantity of<br />

substances. A hazard warning sign must be displayed upon the laboratory doors (order form<br />

available from WHS website, laboratory safety).<br />

Other issues to consider might include;<br />

• spill response kits on h<strong>and</strong>, <strong>and</strong> PPE<br />

• provision of appropriate fire protection <strong>and</strong> fighting equipment<br />

• establish that containers are suitable <strong>and</strong> fully labelled (further information on labelling<br />

can be found in the Hazardous Substances <strong>Guidelines</strong>)<br />

• establish location of the Safety Data Sheets<br />

• establish if <strong>and</strong> when personal monitoring or health surveillance takes place, <strong>and</strong><br />

• establish whether training has been provided to staff.<br />

7.1 Review of Risk Assessments<br />

Risk assessments regarding the storage <strong>and</strong> use of dangerous goods must be reviewed as<br />

detailed in the UOW WHS Risk Management <strong>Guidelines</strong>.<br />

7.2 Records of Risk Assessments<br />

Records must be kept of risk assessments developed in relation to the storage <strong>and</strong> h<strong>and</strong>ling of<br />

dangerous goods. These records should be kept in accordance with the UOW WHS Records<br />

H<strong>and</strong>ling <strong>Guidelines</strong>.<br />

Records of results of risk assessments regarding the storage <strong>and</strong> h<strong>and</strong>ling of substances should<br />

be recorded by:<br />

• noting in the local manifest inventory if no specific control options are required to manage<br />

the risks associated with the storage or h<strong>and</strong>ling of the dangerous good, or;<br />

• preparing a report on the risk assessment if specific control options are required to<br />

manage the risks associated with the storage or h<strong>and</strong>ling of the dangerous good.<br />

8 Risk Control Strategies<br />

The documented risk assessment should identify control measures to be implemented to<br />

minimise the risk to the lowest level as reasonably practical. Risk control must be achieved<br />

following the hierarchy of controls. Elimination should be considered as a means to control the<br />

risk, the best way of achieving this is to remove the hazard. If this is not possible the risk must be<br />

minimised using one or more of the other control options from the hierarchy. Risk control is to be<br />

conducted in accordance with the UOW WHS Risk Management <strong>Guidelines</strong>.<br />

Consideration should be provided for the following subsections.<br />

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8.1 Stability <strong>and</strong> Interaction with <strong>Dangerous</strong> <strong>Goods</strong><br />

8.1.1 Stability of <strong>Dangerous</strong> <strong>Goods</strong><br />

<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

Controls must be put in place to ensure dangerous goods do not inadvertently become unstable,<br />

decompose or change. Controls should ensure hazards are not created that are different from<br />

the hazard originally created by the dangerous goods, or increase the risk associated with the<br />

dangerous goods.<br />

If the stability of dangerous goods is dependent on the maintenance of levels of stabilisers, those<br />

levels must be maintained as specified by the manufacturer of the dangerous goods. Additionally<br />

if the dangerous goods are required to be stored or h<strong>and</strong>led with a particular temperature range<br />

specified by the manufacturer, they must be stored or h<strong>and</strong>led within that temperature range.<br />

8.2 Preventing Interaction with Other Substances<br />

Provisions should be made to ensure dangerous goods that are not compatible with other<br />

substances (including other dangerous goods) are stored <strong>and</strong> h<strong>and</strong>led separately from the other<br />

substances so that a loss of containment or any other interaction cannot cause a serious incident.<br />

8.3 Ignition Sources<br />

Provisions should be made to ensure any ignition sources in hazardous areas (as defined by the<br />

Permit to Work <strong>Guidelines</strong>) are eliminated <strong>and</strong> where this is not possible the risk should be<br />

controlled as per the UOW Risk Management <strong>Guidelines</strong>. Ignition sources include but are not<br />

limited to naked flames, static electricity, heat, sparks, internal combustion engines, heated<br />

surfaces electrical equipment, radio transmitters, mobile phones <strong>and</strong> oily material.<br />

8.4 Emissions<br />

Any atmospheric emissions (toxic, corrosive, flammable, explosive or asphyxiant) that poses a<br />

risk must be eliminated <strong>and</strong> where this is not possible the risk should be controlled as per the<br />

UOW WHS Risk Management <strong>Guidelines</strong>.<br />

8.5 Contamination of Food <strong>and</strong> Personal Products<br />

Provisions should be made to ensure that dangerous goods cannot contaminate food, food<br />

packaging or personal use products.<br />

8.6 Containers for <strong>Dangerous</strong> <strong>Goods</strong> in Bulk<br />

Areas where dangerous goods stored in bulk must ensure that:<br />

• the container <strong>and</strong> any associated pipe work are provided with stable foundations <strong>and</strong><br />

supports, <strong>and</strong><br />

• any pipe work or equipment connected to the container is installed so as to prevent<br />

excessive stress on the container, pipe work or equipment, <strong>and</strong><br />

• the container <strong>and</strong> any associated pipe work are protected from deterioration.<br />

8.7 Containment of Spills<br />

Controls should be put in place to ensure any risk associated with spills <strong>and</strong> leaks from<br />

dangerous goods are eliminated or controlled as per the UOW WHS Risk Management<br />

<strong>Guidelines</strong>. Additionally provisions should be put in place to ensure any spills or leaks are<br />

contained safely within the premises it has taken place as well as any effluent arising from an<br />

incident.<br />

Any area or receptacle intended to contain spills or leaks must not be shared with any other<br />

substances, including other dangerous goods that are not compatible with the dangerous goods<br />

to be contained. Bunding <strong>and</strong> draining into an underground sump or tank are examples of<br />

containment controls.<br />

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<strong>Dangerous</strong> <strong>Goods</strong> <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling <strong>Guidelines</strong><br />

8.8 Transfer of <strong>Dangerous</strong> <strong>Goods</strong><br />

Any risks associated with the transfer of <strong>Dangerous</strong> <strong>Goods</strong> must be eliminated <strong>and</strong> where this is<br />

not possible the risk should be controlled as per the UOW WHS Risk Management <strong>Guidelines</strong>. In<br />

particular provisions should be made to:<br />

• control spills <strong>and</strong> leaks, <strong>and</strong><br />

• minimise static electricity, <strong>and</strong><br />

• control vapour generation, <strong>and</strong><br />

• Ensure the suitability of pipe work, attachments <strong>and</strong> associated safety systems in areas<br />

where the risk elimination or control measures have been proposed.<br />

8.9 Fire Protection, Spillage Controls <strong>and</strong> Ventilation<br />

The need for fire protection <strong>and</strong> the appropriate fire protection system should be determined by a<br />

risk assessment. The “fire protection system” includes fire detection, fire suppression <strong>and</strong> fire<br />

fighting equipment, which may be fixed or portable. The risk assessment should take into<br />

account the types <strong>and</strong> quantities of dangerous goods <strong>and</strong> other material <strong>and</strong> substances <strong>and</strong> how<br />

they are stored <strong>and</strong> h<strong>and</strong>led. Additionally, the risk assessment should consider the types <strong>and</strong><br />

quantities of dangerous goods <strong>and</strong> other materials <strong>and</strong> substances in the area <strong>and</strong> the types of<br />

incidents these could potentially cause. The fire protection system should be installed, tested<br />

<strong>and</strong> maintained in accordance with legislative requirements.<br />

Any spill or leak associated with <strong>Dangerous</strong> <strong>Goods</strong> in bulk or those that are packaged that poses<br />

a risk must be eliminated <strong>and</strong> where this is not possible the risk controls as per the UOW WHS<br />

Risk Management <strong>Guidelines</strong>. Ensure spillage controls are in place to prevent or limit<br />

environmental contamination, <strong>and</strong> that ventilation is adequate for storage, h<strong>and</strong>ling <strong>and</strong> use. This<br />

may require a ventilation survey.<br />

Any atmospheric emissions from dangerous goods that are toxic, corrosive, flammable, explosive<br />

or asphyxiate must be eliminated or, if that is not reasonably practicable, reduced so far as is<br />

reasonably practicable in accordance with the UOW WHS Risk Management <strong>Guidelines</strong>.<br />

8.10 Planning for Emergencies<br />

The University has a procedure for dealing with hazardous material spills or leaks in the<br />

Emergency Management Procedures.<br />

8.11 Safety Equipment <strong>and</strong> Safe Access<br />

Safety equipment must be provided, maintained <strong>and</strong> accessible if it has been determined to be<br />

required to control an identified risk in relation to the storage or h<strong>and</strong>ling of dangerous goods<br />

(including personal protective equipment <strong>and</strong> clean up equipment such as neutralisers,<br />

decontaminants <strong>and</strong> associated equipment). Additionally, a safe means of access to <strong>and</strong> from<br />

<strong>and</strong> within any locations where dangerous goods are stored or h<strong>and</strong>led must be provided <strong>and</strong><br />

maintained.<br />

8.12 Cleaning or Decommissioning Plant, Equipment <strong>and</strong> Containers<br />

Plant, equipment or containers that are to be disposed of must be made free from dangerous<br />

goods or otherwise made safe. If dangerous goods have not been placed in or taken from the<br />

plant, equipment or container for a continuous period of 12 months they should be made free of<br />

dangerous goods or otherwise made safe.<br />

Provisions should be made if the dangerous goods container has been made free from<br />

dangerous goods to ensure any references, signs symbols or warnings in regards to dangerous<br />

foods it previously contained have been removed or obliterated.<br />

If dangerous goods have not been put in or taken out of an underground, or partially underground<br />

or fully mounded tank (other than an LPG tank) any remaining dangerous goods must be<br />

removed from the tank <strong>and</strong> ab<strong>and</strong>on them in accordance with AS 1940. WorkCover must be<br />

notified within 7 days of the ab<strong>and</strong>onment.<br />

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A regular cleaning program should be in place for those areas storing or h<strong>and</strong>ling dangerous<br />

goods. This process should include the removing of dust deposits from exposed surfaces. Risks<br />

associated with cleaning should be eliminated or controlled in accordance with the UOW WHS<br />

Risk Management <strong>Guidelines</strong>.<br />

8.13 Placarding<br />

All dangerous goods in quantities exceeding the “Placarding quantities’ are placarded with the<br />

appropriate warning signage as outlined in appropriate to the class of goods being stored. A<br />

placarding report is available for each storage location in Chem Alert. The WHS Unit will review<br />

the manifest requirements according to Chem Alert to ensure placarding of buildings <strong>and</strong><br />

manifests are obtained appropriately on an annual basis.<br />

8.13.1 Outer Warning Placards<br />

HAZCHEM outer warning placarding as specified in the Code of Practice must be displayed at<br />

the entrance of a premises that emergency services would use in the event of an emergency if<br />

the quantities of dangerous goods stored <strong>and</strong> h<strong>and</strong>led at that premises exceeds the relevant<br />

quantities specified in the column headed “Placarding quantity” in the table in Appendix 1.<br />

8.13.2 Other Placarding Requirements<br />

The following should be placarded in accordance with the NSW WHS Regulation:<br />

• containers or other forms of storage of dangerous goods in bulk<br />

• locations of dangerous goods in bulk, <strong>and</strong><br />

• locations where packages are stored <strong>and</strong> h<strong>and</strong>led.<br />

8.14 Labelling<br />

Each container that holds products is required to be labelled. This includes dangerous goods<br />

which are supplied to or produced by the University. The label must not be removed, defaced or<br />

altered <strong>and</strong> should be replaced if damaged or hard to read.<br />

Packaged dangerous goods should be labelled in accordance with the ADG Code. If labelling<br />

does not meet requirements of the ADG code provisions should be made to ensure the<br />

appropriate labelling is sought <strong>and</strong> assigned to the package.<br />

Labelling is also required for containers or transfer systems storing dangerous goods.<br />

8.14.1 Decanting<br />

Hazardous substances that have been decanted are required to be labelled in accordance with<br />

the UOW WHS Hazardous Substance <strong>Guidelines</strong>.<br />

8.15 Records<br />

8.15.1 Induction <strong>and</strong> Training<br />

Adequate training should be provided to persons who h<strong>and</strong>le dangerous goods. The Work<br />

Health <strong>and</strong> Safety Act also require the provision of induction <strong>and</strong> training. Training should meet<br />

the requirements set out in the UOW Training <strong>Guidelines</strong>.<br />

8.15.2 Maintenance, Inspections <strong>and</strong> Repairs<br />

Records should be kept to confirm that maintenance, inspections <strong>and</strong> repairs of storage areas<br />

<strong>and</strong> h<strong>and</strong>ling processes are regularly carried out.<br />

8.15.3 Documentation<br />

Any documents generated as part of this guideline must meet the requirements as set out in the<br />

WHS Document Control <strong>Guidelines</strong>.<br />

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8.16 <strong>Storage</strong><br />

<strong>Dangerous</strong> goods in bulk must be stored appropriately so that the container, associated pipe<br />

work <strong>and</strong> transfer systems are in good condition. Where the need is identified this may include<br />

inspection <strong>and</strong> maintenance to occur on items that may include but not limited to:<br />

• stable foundations <strong>and</strong> supports<br />

• installation is free from excessive stress <strong>and</strong> forces<br />

• protected from deterioration.<br />

Containers, pipe work <strong>and</strong> attachments holding DG are to be protected from physical damage<br />

which may include impacts, imposed loads <strong>and</strong> mechanical stress.<br />

8.16.1 Temporary <strong>Storage</strong> Areas<br />

Control measures should ensure risks associated with temporarily storing dangerous goods in a<br />

temporary storage location is eliminated or controlled in accordance with the UOW WHS Risk<br />

Management <strong>Guidelines</strong>.<br />

8.17 Incident Management<br />

Incidents including dangerous goods should be managed according to the UOW Incident<br />

Management <strong>Guidelines</strong>.<br />

8.18 Other Controls<br />

Consideration should be given to minimising quantities of dangerous goods that are kept on site<br />

where possible e.g. purchase 2.5L Winchester instead of 20L drum to minimise h<strong>and</strong>ling of<br />

dangerous goods. Any materials h<strong>and</strong>ling must be conducted in accordance with the Materials<br />

H<strong>and</strong>ling <strong>Guidelines</strong>.<br />

8.19 Operations of <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling in Small Quantities<br />

8.19.1 Packages<br />

<strong>Dangerous</strong> goods stored in packages must be:<br />

• closed when not in use<br />

• stored on surfaces which will not deteriorate if the package is damaged resulting in a spill<br />

• stored in such a way to minimise the risk of falling, <strong>and</strong><br />

• positioned in such a way so that leakage will not affect other dangerous goods.<br />

8.19.2 Transfer<br />

When transferring dangerous goods:<br />

• an appropriate area should be set aside for the purposes of transfer or decanting of<br />

dangerous goods products<br />

• spill containment should be provided to hold the spill of the largest package i.e. bunding;<br />

• vapour or dust generation during transfer should be minimised, <strong>and</strong><br />

• where static electricity is generated, appropriate controls measures should be adopted to<br />

minimise the charge build up. This might be in the form of earthing, bonding or relaxation.<br />

• Consideration should be given to minimising the generation of static electricity <strong>and</strong> for<br />

sources of heat or ignition.<br />

8.19.3 Segregation<br />

<strong>Dangerous</strong> goods incompatible with other substances should be segregated from other<br />

dangerous goods to eliminate or reduce risk associated with contact such as:<br />

• solids/liquids - 1.5m<br />

• gases - 3m.<br />

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8.19.4 Separation<br />

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<strong>Dangerous</strong> <strong>Goods</strong> should be separated from people or property. Where barriers are used these<br />

should be impervious.<br />

8.19.5 Ventilation<br />

The generation of flammable or harmful atmospheric levels should be kept to a minimum using<br />

adequate ventilation. The minimum ventilated area should be 1m 2 for every 50m 2 of floor area.<br />

8.19.6 Fuel dispensing<br />

The following controls must be in place for fuel dispensing:<br />

• any self-service fuel dispensing machine shall not be operated by a person under the age<br />

of 16 years<br />

• the driver of a vehicle being refuelled shall ensure that the vehicle is switched off before<br />

the fuel tank is opened<br />

• the driver of a vehicle being refuelled shall ensure the vehicle remains switched off while<br />

the fuel is being dispensed into the vehicle<br />

• no smoking or any other ignition sources are allowed within 3 metres of any point where<br />

fuel might be exposed, particularly when receiving or dispensing.<br />

8.20 Monitoring <strong>and</strong> Review<br />

Implemented controls should be reviewed to ensure that they are effective <strong>and</strong> minimising injury.<br />

This can be completed by inspecting the area or process <strong>and</strong> identifying if the controls are<br />

maintained <strong>and</strong> working properly. The effectiveness of controls can also be reviewed by<br />

analysing injuries <strong>and</strong> incidents which may have occurred.<br />

Risk assessments must be reviewed as per the WHS Risk Management <strong>Guidelines</strong> <strong>and</strong> in<br />

addition, a minimum of at least once every 5 years.<br />

9 Transport of <strong>Dangerous</strong> <strong>Goods</strong><br />

<strong>Dangerous</strong> goods during transport are subject to the regulations for road, rail, sea <strong>and</strong> air<br />

transport. <strong>Dangerous</strong> goods transported by air must be packaged by a licences dangerous<br />

goods h<strong>and</strong>ler.<br />

Minor transport of <strong>Dangerous</strong> goods for purposes such as fieldwork, must comply with the<br />

relevant guidelines <strong>and</strong> SDS including segregation from food stuffs, <strong>and</strong> as appropriate labelling<br />

<strong>and</strong> signage.<br />

<strong>Dangerous</strong> goods should not be transported within the cabin of the vehicle.<br />

10 Security Sensitive <strong>Dangerous</strong> Substances<br />

As per the NSW legislation, a licence is required to possess <strong>and</strong> store explosives <strong>and</strong>/or security<br />

sensitive dangerous goods (SSDG). Under the new legislation, fertilizers <strong>and</strong> other ammonium<br />

nitrate products that contain more than 45 per cent ammonium nitrate are designated SSDS, <strong>and</strong><br />

their access <strong>and</strong> use is restricted. Those wishing to obtain a licence must satisfy a police <strong>and</strong><br />

commonwealth agencies national probity assessment.<br />

It is now illegal to possess Security Sensitive Ammonium Nitrate (SSAN, includes any emulsion,<br />

gel, suspension or mixture with greater than 45% ammonium nitrate) without a licence.<br />

Exemptions are made for quantities less than 3kg which are being used for educational or<br />

research purposes at a school, university or research institution.<br />

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There are a number of controls to be implemented for these types of substances. Further detail<br />

can be found in the ‘Security plan for storage <strong>and</strong> h<strong>and</strong>ling of explosives’ from WorkCover NSW.<br />

11 Program evaluation<br />

In order to ensure that these guidelines continue to be effective <strong>and</strong> applicable to the University,<br />

the program will be reviewed regularly by the WHS Unit <strong>and</strong> relevant stakeholders. Conditions<br />

which might warrant a review of the guidelines on a more frequent basis would include:<br />

• an injury or near miss resulting from storage <strong>and</strong> h<strong>and</strong>ling of dangerous goods<br />

• incidents related to storage <strong>and</strong> h<strong>and</strong>ling of dangerous goods<br />

• changes to legislation <strong>and</strong> associated st<strong>and</strong>ards<br />

• employee or Employer concern.<br />

Following completion of any review, the program will be revised <strong>and</strong>, if necessary, updated in<br />

order to correct any deficiencies.<br />

12 Related documents<br />

• WHS Legislative Compliance <strong>Guidelines</strong><br />

• WHS Risk Management <strong>Guidelines</strong><br />

• Hazardous Substances <strong>Guidelines</strong><br />

• Purchasing Materials <strong>and</strong> Substances<br />

• Consultation<br />

13 References<br />

• WHS Act 2011<br />

• WHS Regulation 2011<br />

• <strong>Storage</strong> <strong>and</strong> H<strong>and</strong>ling of <strong>Dangerous</strong> <strong>Goods</strong>, Code of Practice;<br />

• Gas Supply (Consumer Safety) Regulation 2004<br />

• <strong>Dangerous</strong> <strong>Goods</strong> (Road <strong>and</strong> Rail Transport) Regulation 2009<br />

• Explosives Act 2003, NSW<br />

• Explosives Regulation 2005;<br />

• <strong>Storage</strong> <strong>and</strong> h<strong>and</strong>ling of explosives (including explosives precursors): Security plan<br />

• AS1596:2008 The storage <strong>and</strong> h<strong>and</strong>ling of LP Gas<br />

• AS1894:1997 The storage <strong>and</strong> h<strong>and</strong>ling of non-flammable cryogenic <strong>and</strong> refrigerated<br />

liquids<br />

• AS1940:2004 The storage <strong>and</strong> h<strong>and</strong>ling of flammable <strong>and</strong> combustible liquids<br />

• AS2022:2003 Anhydrous ammonia - <strong>Storage</strong> <strong>and</strong> h<strong>and</strong>ling<br />

• AS 2030.1-2009 Gas cylinders – General requirements<br />

• AS2030.2-1996 The verification, filling, inspection, testing <strong>and</strong> maintenance of cylinders<br />

for the storage <strong>and</strong> transport of compressed gases - Cylinders for dissolved acetylene<br />

• AS2187.1-1998 Explosives –<strong>Storage</strong>, transport <strong>and</strong> use – <strong>Storage</strong><br />

• AS2187.2 2006 Explosives – <strong>Storage</strong> <strong>and</strong> Use – Use of explosives<br />

• AS/NZS 2243.1:2005 Safety in Laboratories - Planning <strong>and</strong> Operational Aspects<br />

• AS/NZS 2243.2:2006 Safety in Laboratories – Chemical Aspects<br />

• AS/NZS 2243.3:2010 Safety in Laboratories – Microbiological Aspects <strong>and</strong> Containment<br />

• AS 2243.4-1998 Safety in Laboratories – Ionizing Radiation<br />

• AS/NZS 2243.5:2004 Safety in Laboratories – Non-ionizing Radiations – Electromagnetic,<br />

Sound <strong>and</strong> Ultrasound<br />

• AS 2243.6-2010 Safety in Laboratories – Plant <strong>and</strong> Equipment Aspects<br />

• AS2243.7-1991 Safety in Laboratories – Electrical Aspects<br />

• AS/NZS 2243.8:2006 Safety in Laboratories – Fume Cupboards<br />

• AS/NZS 2243.9:2009 Safety in Laboratories – Recirculating Fume Cabinets<br />

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• AS/NZS 2243.10:2004 Safety in Laboratories – <strong>Storage</strong> of Chemicals<br />

• AS2381.1:2005 Electrical equipment for explosive gas atmospheres - Selection,<br />

installation <strong>and</strong> maintenance - General requirements<br />

• AS2507-1998 The storage <strong>and</strong> h<strong>and</strong>ling of agricultural <strong>and</strong> veterinary chemicals<br />

• AS2714-2008 The storage <strong>and</strong> h<strong>and</strong>ling of organic peroxides<br />

• AS2927:2001 <strong>Storage</strong> & h<strong>and</strong>ling of liquefied chlorine gas<br />

• AS3000:2007 Electrical installations(known as the Australian/New Zeal<strong>and</strong> Wiring Rules)<br />

• AS3780-2008 The storage & h<strong>and</strong>ling of Corrosive Substances<br />

• AS3961-2005 The storage <strong>and</strong> h<strong>and</strong>ling of liquefied natural gas<br />

• AS4081:2001 The storage <strong>and</strong> h<strong>and</strong>ling of liquid <strong>and</strong> liquefied polyfunctional isocyanates;<br />

• AS4289-1995 Oxygen & acetylene gas reticulation systems<br />

• AS4326-2008 The storage <strong>and</strong> h<strong>and</strong>ling of oxidising agents<br />

• AS4452:1997 The storage <strong>and</strong> h<strong>and</strong>ling of toxic substances<br />

• Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004)]<br />

• Australian Code for the Transport of <strong>Dangerous</strong> <strong>Goods</strong> by Road <strong>and</strong> Rail (7 th Edition).<br />

14 Version Control Table<br />

Version Date<br />

Approved By Amendment<br />

Control Released<br />

1 February 1999 Manager WHS Document updated<br />

2 January 2003 Manager WHS Scheduled review minor changes only.<br />

3 January 2005 Manager WHS Scheduled review minor changes only.<br />

4 May 2007 Manager WHS Document updated to reflect legislative requirements (Code<br />

of Practice) <strong>and</strong> incorporate <strong>Dangerous</strong> <strong>Goods</strong> Notification<br />

<strong>Guidelines</strong> 063.<br />

5 April 2010 Manager WHS Scheduled review. Minor changes with alignment to<br />

National Audit Tool requirements <strong>and</strong> Code of Practice.<br />

6 August 2010 Manager WHS Document updated to incorporate the Personnel name<br />

change to Human Resources Division.<br />

7 March 2012 Manager WHS Rebr<strong>and</strong><br />

8 March 2013 Manager WHS Legislative review <strong>and</strong> update<br />

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Appendix 1: Notification Quantities<br />

WorkCover must be notified where quantities of dangerous goods exceed those listed in the<br />

following table as listed in the Code of Practice.<br />

Item Description of dangerous Packing group Placard quantity Manifest<br />

goods<br />

quantity<br />

1 Class 2<br />

Class 2.1 NA 5,00 L 5,000 L<br />

Class 2.2, Subsidiary risk 5.1 NA 2,000 L 10,000 L<br />

Class 2.3 NA 50 L 500 L<br />

Aerosols NA 5,000 L 10,000 L<br />

Cryogenic fluids NA 1,000 L 10,000 L<br />

2 Class, 3, 4.1, 4.2, 4.3, 5.1, 5.2,<br />

6.1 or 8<br />

I 50 kg or L 500 kg or L<br />

II 2,50 kg or L 2,500 kg or L<br />

III 1,000 kg or L 10,000 kg or L<br />

Mixed packing groups in a single class with<br />

the quantity of each packing group below the<br />

specified quantity for the packing group<br />

1,000 kg or L 10,000 kg or L<br />

3 Class 9 II 1,000 kg or L 10,000 kg or L<br />

III 5,000 kg or L 10,000 kg or L<br />

Mixed packing groups in class 9 with the<br />

quantity of each packing group below the<br />

specified quantity for the packing group.<br />

5,000 kg or L 10,000 kg or L<br />

4 Mixed classes of dangerous<br />

goods where none of the classes,<br />

types of Packing Groups present<br />

exceeds the quantities specified<br />

for the relevant quantity in item, 1,<br />

2, 3 of this table<br />

5 C1 combustible liquids stored or<br />

h<strong>and</strong>led with fire risk dangerous<br />

goods where none of the classes,<br />

types or Packing Groups present<br />

exceeds the quantities in items 1,<br />

2, or 3 of this table.<br />

6 <strong>Goods</strong> too dangerous to be<br />

transported that are not kept in a<br />

laboratory<br />

7 C1 combustible liquids in bulk<br />

stored <strong>and</strong> h<strong>and</strong>led separately<br />

from other dangerous goods<br />

NA 5,000 kg or L<br />

(applies if the<br />

placard quantity of<br />

individual class is<br />

5,000 kg/L)<br />

2,000 kg or l<br />

(applies if placrd<br />

quantity for all<br />

classes is 2,000 kg<br />

or L<br />

10,000 kg or L<br />

NA 1,000 kg or L 10,000 kg or L<br />

NA Any quantity Any quantity<br />

NA<br />

10,000 L<br />

100,000 L<br />

C1 combustible liquids stored <strong>and</strong><br />

h<strong>and</strong>led in packages separately<br />

from other dangerous goods.<br />

C1 combustible liquids in bulk<br />

<strong>and</strong> in packages stored <strong>and</strong><br />

h<strong>and</strong>led separately from other<br />

dangerous goods provided the<br />

quantity in bulk is 10,000 L or<br />

less.<br />

50,000 L<br />

50,000 L<br />

100,000 L<br />

100,000 L<br />

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