Chemwatch MSDS Print - FUJIFILM Australia

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Chemwatch MSDS Print - FUJIFILM Australia

Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 1 of 7Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFujifilm Sericol Diazo Sensitiser SZM02PROPER SHIPPING NAMEDYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)PRODUCT USEPhotostencil emulsion sensitiser.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel:+61 1800 039 008Emergency Tel:+61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Harmful if swallowed.■ Causes burns.■ Risk of serious damage to eyes.■ Toxic to aquatic organisms, may causelong- term adverse effects in the aquaticenvironment.SAFETY• Keep locked up.• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable protective clothing.• Wear suitable gloves.• Wear eye/face protection.• Do not empty into drains.continued...


Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 2 of 7Section 2 - HAZARDS IDENTIFICATION• To clean the floor and all objects contaminated bythis material, use water.• This material and its container must be disposed ofin a safe way.• Take off immediately all contaminated clothing.• In case of contact with eyes, rinse with plenty ofwater and contact Doctor or Poisons InformationCentre.• In case of accident or if you feel unwellIMMEDIATELY contact Doctor or Poisons InformationCentre (show label if possible).• Use appropriate container to avoid environmentalcontamination.• Avoid release to the environment. Refer to specialinstructions/Safety data sheets.• This material and its container must be disposed ofas hazardous waste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %phosphoric acid 7664-38-2 25-50dye unregulated >50additives unregulatedSection 4 - FIRST AID MEASURESSWALLOWED■ If poisoning occurs, contact a doctor or Poisons Information Centre.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.EYE■ If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally liftingthe upper and lower lids.• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.• Transport to hospital or doctor without delay.SKIN■ If skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safety shower if available.• Quickly remove all contaminated clothing, including footwear.• Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.• Transport to hospital, or doctor.INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary.NOTES TO PHYSICIANFor acute or short term repeated exposures to strong acids:• Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.• Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling• Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.• Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicatingaction of the acid on proteins in specific tissues.continued...


Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 3 of 7Section 4 - FIRST AID MEASURESSection 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA• Water spray or fog.• Foam.• Dry chemical powder.• BCF (where regulations permit).FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• Non combustible.• Not considered to be a significant fire risk.• Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.• Heating may cause expansion or decomposition leading to violent rupture of containers.Other decomposition products include: phosphorus oxides (POx).HAZCHEM2XSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLSClean up all spills immediately.Avoid contact with skin and eyes.Wear protective neoprene gloves and chemical goggles.Use soda ash or slaked lime to neutralise.Wipe up and absorb small quantities with vermiculite or other absorbent material.Place in suitable containers for disposal.Wash spill area with large quantities of water.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.SUITABLE CONTAINERPlastic carboy.Polyethylene or polypropylene container.Polylined drum.• Check that containers are clearly labelled.• Packaging as recommended by manufacturer.STORAGE INCOMPATIBILITYAvoid storage with strong alkalis, common metals andcontinued...


Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 4 of 7Section 7 - HANDLING AND STORAGEtheir alloys, oxidising and reducing agents, cyanides, sulphides andcombustible materials and other chemicals decomposed by strong acids.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSSource Material TWA TWA STEL STEL Peak Peak TWA Notesppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC__________ __________ ______ ______ ______ ______ ______ ______ ______ ______Australia (Phosphoric 1 3Exposureacid)StandardsMATERIAL DATAFUJIFILM SERICOL DIAZO SENSITISER SZM02:None assigned. Refer to individual constituents.PHOSPHORIC ACID:The saturated vapour concentration of phosphoric acid exceeds the TLV. The TLV-TWA is based by analogy from comparableexperience and data for sulfuric acid.Fumes of phosphorus pentoxide at concentrations between 0.8 and 5.4 mg/m3 were reported to be noticeable but not uncomfortablewhilst concentrations between 3.6 and 11.3 mg/m3 produced coughing in unacclimatised workers but were tolerable.PERSONAL PROTECTIONRESPIRATOR•Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE• Safety glasses with side shields.• Chemical goggles.• Full face shield may be required for supplementary but never for primary protection of eyes• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Butyl rubber gloves.• Rubber gloves.• PVC gloves.• Impervious gloves.• Safety footwear.• Rubber boots.OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.continued...


Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 5 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEColoured acidic liquid with a characteristic odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Corrosive.Acid.State Liquid Molecular Weight Not applicableMelting Range (°C) Not available Viscosity Not availableBoiling Range (°C) Not available Solubility in water (g/L) MiscibleFlash Point (°C) Not applicable pH (1% solution) Not availableDecomposition Temp (°C) Not available pH (as supplied)


Fujifilm Sericol Diazo Sensitiser SZM02Chemwatch Material Safety Data SheetIssue Date: 9-Dec-2009 CHEMWATCH 4600-359317SPVersion No:4Page 7 of 7Section 14 - TRANSPORTATION INFORMATIONPacking Instructions: 856 Maximum Qty/Pack: 60 LPassenger and CargoPassenger and CargoPacking Instructions: 852 Maximum Qty/Pack: 5 LPassenger and Cargo Limited QuantityPassenger and Cargo Limited QuantityPacking Instructions: Y841 Maximum Qty/Pack: 1 LShipping name:DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)Maritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: NoneUN Number: 2801 Packing Group: IIIEMS Number: F-A,S-B Special provisions: 223 274Limited Quantities: 5 L Marine Pollutant: YesShipping name:DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S.(contains phosphoric acid)Section 15 - REGULATORY INFORMATIONPOISONS SCHEDULES6REGULATIONSRegulations for ingredientsphosphoric acid (CAS: 7664-38-2, 16271-20-8) is found on the following regulatory lists;"Australia Exposure Standards", "Australia Hazardous Substances", "Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling ofMedicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Schedule 5", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6", "GESAMP/EHSComposite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimum requirements", "IMO MARPOL 73/78 (AnnexII) - List of Noxious Liquid Substances Carried in Bulk", "International Agency for Research on Cancer (IARC) - Agents Reviewedby the IARC Monographs", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List ofHigh Production Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – United Kingdom"No data for Fujifilm Sericol Diazo Sensitiser SZM02 (CW: 4600-35)Section 16 - OTHER INFORMATIONINGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient Name CASphosphoric acid 7664-38-2, 16271-20-8■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 9-Dec-2009Print Date: 25-Jun-2012This is the end of the MSDS.

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