Chemwatch Australian MSDS 28-0434 - FUJIFILM Australia

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Chemwatch Australian MSDS 28-0434 - FUJIFILM Australia

FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 1 of 9Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM UV LITHO O/P VARNISHSYNONYMS"Product Code: UV8085"PROPER SHIPPING NAMEENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains tripropylene glycol diacrylate)PRODUCT USETo provide a reasonable gloss finish for quality print work.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Irritating to eyes, respiratory system andskin.■ May cause SENSITISATION by skin contact.■ Toxic to aquatic organisms, may cause longtermadverse effects in the aquaticenvironment.SAFETY• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable gloves.continued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 3 of 9Section 4 - FIRST AID MEASURESSection 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ - Foam.- Dry chemical powder.- BCF (where regulations permit).- Carbon dioxide.FIRE FIGHTING■ - Alert Fire Brigade and tell them location and nature of hazard.- May be violently or explosively reactive.- Wear full body protective clothing with breathing apparatus.- Prevent, by any means available, spillage from entering drains or water course.When any large container (including road and rail tankers) is involved in a fire,consider evacuation by 100 metres in all directions.FIRE/EXPLOSION HAZARD■ - Combustible.- Slight fire hazard when exposed to heat or flame.- Heating may cause expansion or decomposition leading to violent rupture of containers.- On combustion, may emit toxic fumes of carbon monoxide (CO).Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.FIRE INCOMPATIBILITY■ - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignitionmay result.HAZCHEM•3ZPersonal Protective EquipmentBreathing apparatus.Gas tight chemical resistant suit.Limit exposure duration to 1 BA set 30 mins.Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS■ Environmental hazard - contain spillage.- Clean up all spills immediately.- Avoid breathing vapours and contact with skin and eyes.- Control personal contact by using protective equipment.- Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS■ Environmental hazard - contain spillage.Moderate hazard.- Clear area of personnel and move upwind.- Alert Fire Brigade and tell them location and nature of hazard.- Wear breathing apparatus plus protective gloves.- Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING■ - Most acrylic monomers have low viscosity therefore pouring, material transfer and processing of these materials do notnecessitate heating.- Viscous monomers may require heating to facilitate handling. To facilitate product transfer from original containers, productmust be heated to no more than 60 deg. C. (140 F.), for not more than 24 hours.- Do NOT use localised heat sources such as band heaters to heat/ melt product.continued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 4 of 9Section 7 - HANDLING AND STORAGE- Do NOT use steam .- DO NOT allow clothing wet with material to stay in contact with skin.- Avoid all personal contact, including inhalation.- Wear protective clothing when risk of exposure occurs.- Use in a well-ventilated area.- Prevent concentration in hollows and sumps.SUITABLE CONTAINER■ - Metal can or drum- Packaging as recommended by manufacturer.- Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY■ Benzophenone:- may ignite or explode in the presence of strong oxidisers- is incompatible with aliphatic amines, aldehydes, strong bases, hydrogen peroxide, nitric acid, perchloric acid- may form a variety of unstable peroxides following reaction with hydrogen peroxide.for multifunctional acrylates:- Avoid exposure to free radical initiators (peroxides, persulfates) , iron, rust, oxidisers, and strong acids and strong bases.- Avoid heat, flame, sunlight, X-rays or ultra-violet radiation.- Storage beyond expiration date, may initiate polymerisation. Polymerisation of large quantities may be violent (even explosive).STORAGE REQUIREMENTS■ - Storage requires stabilising inhibitor content and dissolved oxygen content to be monitored. Refer to manufacturer'srecommended levels.- DO NOT overfill containers so as to maintain free head space above product.- Blanketing or sparging with nitrogen or oxygen free gas will deactivate stabiliser.- Store in original containers.- Keep containers securely sealed.- Store in a cool, dry, well-ventilated area.- Store away from incompatible materials and foodstuff containers.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• tripropylene glycol diacrylate: CAS:42978- 66- 5 CAS:68901- 05- 3• benzophenone: CAS:119- 61- 9PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE■ - Safety glasses with side shields.- Chemical goggles.- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a reviewof lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aidpersonnel should be trained in their removal and suitable equipment should be readily available. In the event of chemicalexposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the firstsigns of eye redness or irritation - lens should be removed in a clean environment only after workers have washed handsthoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET■ NOTE:- The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.- Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:- frequency and duration of contact,continued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 5 of 9Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION- chemical resistance of glove material,- glove thickness and- dexterity.General warning: Do NOT use latex gloves! Use only recommended gloves - using the wrong gloves may increase the risk:Exposure condition Short time use; (few minutesless than 0.5 hour) Little physical stressExposure condition Medium time use; less than 4hours Physical stress (opening drums, usingtools, etc.)Exposure condition Long time CleaningoperationsUse of thin nitrile rubber gloves: Nitrilerubber (0.1 mm) Excellent tactibility (" feel"), powder- free Disposable Inexpensive Giveadequate protection to low molecular weighacrylic monomersUse of medium thick nitrile rubber glovesNitrile rubber, NRL (latex) free; 0.56 mm lowtactibility (" feel" ), powder free High priceGives adequate protection for most acrylates incombination with commonly used solvents up to 8hours Do NOT give adequate protection to lowmolecular weight monomers at exposures longerthan 1 hour Avoid use of ketones and acetatesin wash- up solutions..OTHER■ - Overalls.- P.V.C. apron.- Barrier cream.- Skin cleansing cream.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear viscous liquid with an acrylate odour; does not mix with water.PHYSICAL PROPERTIESLiquid.Does not mix with water.Sinks in water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) >100 Solubility in water (g/L) Immiscibl eFlash Point (°C) >100 pH (1% solution) Not ApplicableDecomposition Temp (°C) Not Available pH (as supplied) Not A pplicableAutoignition Temp (°C) Not Available Vapour Pressure (kPa) Not AvailableUpper Explosive Limit (%) Not Available Specific Gravity (water=1) 1.05- 1.10Lower Explosive Limit (%) Not Available Relative Vapour Density Not Available(air=1)Volatile Component (%vol) 0 Evaporation Rate Not Availablecontinued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 6 of 9Section 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY■ - Presence of incompatible materials.- Product is considered stable.- Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTS■ Irritating to eyes, respiratory system and skin.CHRONIC HEALTH EFFECTS■ May cause SENSITISATION by skin contact.TOXICITY AND IRRITATION■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.■ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels ofhighly irritating compound.■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesisof contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.TRIPROPYLENE GLYCOL DIACRYLATE:FUJIFILM UV LITHO O/P VARNISH:■ Where no "official" classification for acrylates and methacrylates exists, there has been cautious attempts to createclassifications in the absence of contrary evidence. For exampleMonalkyl or monoarylesters of acrylic acids should be classified as R36/37/38 and R51/53Monoalkyl or monoaryl esters of methacrylic acid should be classified as R36/37/38.■ UV (ultraviolet)/ EB (electron beam) acrylates are generally of low toxicityUV/EB acrylates are divided into two groups; "stenomeric" and "eurymeric" acrylates.The first group consists of well-defined acrylates which can be described by a simple idealised chemical;they are low molecularweight species with a very narrow weight distribution profile.The eurymeric acrylates cannot be described by an idealised structure and may differ fundamentally between various suppliers;they are of relatively high molecular weigh and possess a wide weight distribution.Stenomeric acrylates are usually more hazardous than the eurymeric substances.TRIPROPYLENE GLYCOL DIACRYLATE:TOXICITYIRRITATIONOral (rat) LD50: 6200 mg/kgSkin (rabbit): 500 mg/24h ModerateDermal (rabbit) LD50: >2000 mg/kg Draize = 2.5/8.0 *Intraperitoneal (Rat) LD50: 345 mg/kgEye (rabbit): 100 uL/24h SEVEREIntraperitoneal (Rabbit) LD: 275 mg/kg * [Manufacturer H]■ The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.Based on the available oncogenicity data and without a better understanding of the carcinogenic mechanism the Health andEnvironmental Review Division (HERD), Office of Toxic Substances (OTS), of the US EPA previously concluded that all chemicalsthat contain the acrylate or methacrylate moiety (CH2=CHCOO or CH2=C(CH3)COO) should be considered to be a carcinogenic hazardunless shown otherwise by adequate testing.This position has now been revised and acrylates and methacrylates are no longer de facto carcinogens.BENZOPHENONE:TOXICITYOral (rat) LD50: >10, 000 mg/kgOral (mouse) LD50: 2895 mg/kgDermal (rabbit) LD50: 3535 mg/kgIRRITATIONNil Reportedcontinued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 7 of 9Section 12 - ECOLOGICAL INFORMATIONToxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.This material and its container must be disposed of as hazardous waste.Avoid release to the environment.Refer to special instructions/ safety data sheets.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/SoilFujifilm UV Litho O/P Varnish No Data No DataAvailableAvailabletripropylene glycol diacrylate HIGH No Data LOW HIGHAvailablebenzophenone HIGH No Data LOW MEDAvailableSection 13 - DISPOSAL CONSIDERATIONS■ - Containers may still present a chemical hazard/ danger when empty.- Return to supplier for reuse/ recycling if possible.Otherwise:- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to lawsoperating in their area.A Hierarchy of Controls seems to be common - the user should investigate:- Reduction.- DO NOT allow wash water from cleaning or process equipment to enter drains.- It may be necessary to collect all wash water for treatment before disposal.- In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.- Where in doubt contact the responsible authority.- Recycle wherever possible or consult manufacturer for recycling options.- Consult State Land Waste Authority for disposal.- Bury or incinerate residue at an approved site.- Recycle containers if possible, or dispose of in an authorised landfill.Section 14 - TRANSPORTATION INFORMATION■ Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082are not subject to this Code when transported by road or rail in;(a) packagings;(b) IBCs; or(c) any other receptacle not exceeding 500 kg(L).- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.Labels Required: MISCELLANEOUSHAZCHEM:●3Z (ADG7)ADG7:Class or Division: 9 Subsidiary Risk: NoneUN No.: 3082 Packing Group: IIISpecial Provision: 179, 274, 331, 335, Limited Quantity: 5 LAU01Portable Tanks & Bulk T4 Portable Tanks & Bulk TP1, TP29Containers -Containers - SpecialInstruction:Provision:continued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 8 of 9Section 14 - TRANSPORTATION INFORMATIONPackagings & IBCs - PP1 Packagings & IBCs - P001, IBC03, LP01Packing Instruction:Special PackingProvision:Name and Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S. (contains tripropylene glycol diacrylate)Land Transport UNDG:Class or division: 9 Subsidiary risk: NoneUN No.: 3082 UN packing group: IIIShipping Name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains tripropylene glycol diacrylate)Air Transport IATA:UN/ID Number: 3082 Packing Group: IIISpecial provisions:A97Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S. *(CONTAINS TRIPROPYLENE GLYCOL DIACRYLATE)Maritime Transport IMDG:IMDG Class: 9 IMDG Subrisk: NoneUN Number: 3082 Packing Group: IIIEMS Number: F- A, S- F Special provisions: 274 335Limited Quantities: 5 L Marine Pollutant: YesShipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(contains tripropylene glycol diacrylate)Section 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientsNo data for Fujifilm UV Litho O/P Varnish (CW: 28-0434)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codestripropylene glycol diacrylate 68901- 05- 3 Carc3; R40 R43Xi; R38 N; R50INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCAStripropylene glycol diacrylate 42978- 66- 5, 68901- 05- 3■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 15-Aug-2011Print Date: 15-Aug-2011continued...


FUJIFILM UV LITHO O/P VARNISHChemwatch Independent Material Safety Data SheetIssue Date: 15-Aug-2011 CHEMWATCH 28-0434C9317EC(cs)Version No:2.0CD 2011/2 Page 9 of 9Section 16 - OTHER INFORMATIONThis is the end of the MSDS.

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