fujfilm sericol multipurpose gold powder - FUJIFILM Australia

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fujfilm sericol multipurpose gold powder - FUJIFILM Australia

Fujfilm Sericol Multipurpose Gold Powder 851045FujiFilm Chemwatch Hazard Alert Code: 3Chemwatch: 6516-10Version No: 7.1.1.1Material Safety Data Sheet according to NOHSC and ADG requirementsIssue Date: 01/01/2013Print Date: 16/03/2015Initial Date: Not AvailableS.Local.AUS.ENSECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKINGProduct IdentifierProduct name Fujfilm Sericol Multipurpose Gold Powder 851045SynonymsProper shipping nameOther means ofidentificationNot AvailableMETAL POWDER, FLAMMABLE, N.O.S. (contains copper and zinc)Not AvailableRelevant identified uses of the substance or mixture and uses advised againstRelevant identified usesMetallic pigment for paints, printing inks and plastics.Details of the manufacturer/importerRegistered company name FujiFilmAddress 114 Old Pittwater Road Brookvale NSW AustraliaTelephone +61 2 9466 2600Fax +61 2 9938 1975Website http://www.fujifilm.coEmail Not AvailableEmergency telephone numberAssociation / OrganisationEmergency telephonenumbersOther emergency telephonenumbersNot AvailableNot AvailableNot AvailableSECTION 2 HAZARDS IDENTIFICATIONClassification of the substance or mixtureDANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to NOHSC Criteria, and ADG Code.CHEMWATCH HAZARD RATINGSFlammability 3Toxicity 2Body Contact 0Reactivity 2Chronic 2MinMax0 = Minimum1 = Low2 = Moderate3 = High4 = ExtremePoisons ScheduleS6Risk Phrases [1] R11 Highly flammable.Legend:1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VIRelevant risk statements are found in section 2Indication(s) of dangerFSAFETY ADVICES07Keep container tightly closed.Continued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 2 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015S08S09S16S29S33S41S43S51S56Keep container dry.Keep container in a well ventilated place.Keep away from sources of ignition. No smoking.Do not empty into drains.Take precautionary measures against static discharges.In case of fire and/or explosion, DO NOT BREATHE FUMES.In case of fire use...Use only in well ventilated areas.Dispose of this material and its container at hazardous or special waste collection point.Other hazardsInhalation may produce health damage*.Cumulative effects may result following exposure*.SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTSSubstancesSee section below for composition of MixturesMixturesCAS No %[weight] NameNot Available 100 flake gold bronze powder, as7440-50-87440-66-6copperzincSECTION 4 FIRST AID MEASURESDescription of first aid measuresEye ContactSkin ContactInhalationIngestionIf this product comes in contact with the eyes:Wash out immediately with fresh running water.Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.Seek medical attention without delay; if pain persists or recurs seek medical attention.Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.If skin or hair contact occurs:Flush skin and hair with running water (and soap if available).Seek medical attention in event of irritation.If fumes or combustion products are inhaled remove from contaminated area.Lay patient down. Keep warm and rested.Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR ifnecessary.Transport to hospital, or doctor.Immediately give a glass of water.First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.Indication of any immediate medical attention and special treatment neededTreat symptomatically.SECTION 5 FIREFIGHTING MEASURESExtinguishing mediaMetal dust fires need to be smothered with sand, inert dry powders.DO NOT USE WATER, CO2 or FOAM.Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met L-X to smother fire.Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas.Special hazards arising from the substrate or mixtureFire IncompatibilityReacts with acids producing flammable / explosive hydrogen (H2) gasNone known.Advice for firefightersFire FightingFire/Explosion HazardAlert Fire Brigade and tell them location and nature of hazard.Wear breathing apparatus plus protective gloves.Prevent, by any means available, spillage from entering drains or water course.Fight fire from a safe distance, with adequate cover.Decomposition may produce toxic fumes of:, metal oxidesDO NOT disturb burning dust. Explosion may result if dust is stirred into a cloud, by providing oxygen to a large surface of hot metal.DO NOT use water or foam as generation of explosive hydrogen may result.With the exception of the metals that burn in contact with air or water (for example, sodium), masses of combustible metals do not represent unusual fire risksContinued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 3 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015because they have the ability to conduct heat away from hot spots so efficiently that the heat of combustion cannot be maintained - this means that it will require alot of heat to ignite a mass of combustible metal.SECTION 6 ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresMinor SpillsMajor SpillsRemove all ignition sources.DO NOT touch or walk through spilled material.Clean up all spills immediately.Avoid contact with skin and eyes.Clear area of personnel and move upwind.Alert Fire Brigade and tell them location and nature of hazard.DO NOT touch or walk through spilled material.Control personal contact with the substance, by using protective equipment.Personal Protective Equipment advice is contained in Section 8 of the MSDS.SECTION 7 HANDLING AND STORAGEPrecautions for safe handlingSafe handlingOther informationAvoid all personal contact, including inhalation.Wear protective clothing when risk of overexposure occurs.Use in a well-ventilated area.Prevent concentration in hollows and sumps.FOR MINOR QUANTITIES:Store in an indoor fireproof cabinet or in a room of noncombustible construction.Provide adequate portable fire-extinguishers in or near the storage area.FOR PACKAGE STORAGE:Store in original containers in approved flame-proof area.No smoking, naked lights, heat or ignition sources.Conditions for safe storage, including any incompatibilitiesSuitable containerStorage incompatibilityCARE: Packing of high density product in light weight metal or plastic packages may result in container collapse with product releaseHeavy gauge metal packages / Heavy gauge metal drumsFor low viscosity materials and solids:Drums and jerricans must be of the non-removable head type.Where a can is to be used as an inner package, the can must have a screwed enclosure.For materials with a viscosity of at least 2680 cSt. (23 deg. C):Removable head packaging andcans with friction closures may be used.Many metals may incandesce, react violently, ignite or react explosively upon addition of concentrated nitric acid.Metals exhibit varying degrees of activity. Reaction is reduced in the massive form (sheet, rod, or drop), compared with finely divided forms. The less activemetals will not burn in air but:can react exothermically with oxidising acids to form noxious gases.PACKAGE MATERIAL INCOMPATIBILITIESNot AvailableSECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTIONControl parametersOCCUPATIONAL EXPOSURE LIMITS (OEL)INGREDIENT DATASource Ingredient Material name TWA STEL Peak NotesAustralia Exposure Standards copper Copper (fume) / Copper, dusts & mists (as Cu) 0.2 mg/m3 / 1 mg/m3 Not Available Not Available Not AvailableAustralia Exposure Standards zinc Fume (thermally generated) (respirable dust)(g) 2 mg/m3 Not Available Not Available Not AvailableEMERGENCY LIMITSIngredient Material name TEEL-1 TEEL-2 TEEL-3copper Copper 1 mg/m3 1 mg/m3 45 mg/m3zinc Zinc 1.9 mg/m3 21 mg/m3 120 mg/m3Ingredient Original IDLH Revised IDLHflake gold bronze powder, as Not Available Not Availablecopper N.E. mg/m3 / N.E. ppm 100 mg/m3zinc Not Available Not AvailableExposure controlsAppropriate engineeringcontrolsFor large scale or continuous use:Spark-free, earthed ventilation system, venting directly to the outside and separate from usual ventilation systemsProvide dust collectors with explosion ventsContinued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 4 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015Metal dusts must be collected at the source of generation as they are potentially explosive.Avoid ignition sources.Good housekeeping practices must be maintained.Dust accumulation on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary explosions.Personal protectionEye and face protectionSkin protectionHands/feet protectionBody protectionOther protectionThermal hazardsSafety glasses with side shieldsChemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing oflenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience.See Hand protection belowThe selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Wherethe chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked priorto the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a finalchoice.Suitability and durability of glove type is dependent on usage.See Other protection belowOveralls.Eyewash unit.Barrier cream.Skin cleansing cream.Not AvailableRecommended material(s)GLOVE SELECTION INDEXGlove selection is based on a modified presentation of the:"Forsberg Clothing Performance Index".The effect(s) of the following substance(s) are taken into account in the computergeneratedselection:Fujfilm Sericol Multipurpose Gold Powder 851045 Not AvailableRespiratory protectionNot ApplicableMaterialCPI* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors such as"feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwisebe unsuitable following long-term or frequent use. A qualified practitioner should be consulted.SECTION 9 PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesAppearanceGold flammable powder; insoluble in water.Physical state Liquid Relative density (Water = 1) 8.96OdourOdour thresholdpH (as supplied)Melting point / freezingpoint (°C)Initial boiling point andboiling range (°C)Not AvailableNot AvailableNot ApplicablePartition coefficientn-octanol / waterAuto-ignition temperature(°C)DecompositiontemperatureNot AvailableNot AvailableNot AvailableNot Available Viscosity (cSt) Not Applicable999 Molecular weight (g/mol) Not ApplicableFlash point (°C) Not Available Taste Not AvailableEvaporation rate Not Applicable Explosive properties Not AvailableUpper Explosive Limit (%)Flammability Not Available Oxidising properties Not AvailableNot AvailableSurface Tension (dyn/cm ormN/m)Not AvailableLower Explosive Limit (%) Not Available Volatile Component (%vol) Not ApplicableVapour pressure (kPa) Not Applicable Gas group Not AvailableSolubility in water (g/L) Immiscible pH as a solution Not ApplicableContinued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 5 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015Vapour density (Air = 1) Not Applicable VOC g/L Not AvailableSECTION 10 STABILITY AND REACTIVITYReactivity See section 7Chemical stabilityPossibility of hazardousreactionsUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.See section 7Conditions to avoid See section 7Incompatible materials See section 7Hazardous decompositionproductsSee section 5SECTION 11 TOXICOLOGICAL INFORMATIONInformation on toxicological effectsInhaledIngestionInhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual.The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroboratinganimal or human evidence.Skin ContactEyeChronicThe liquid may be miscible with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic contact dermatitis. The material isunlikely to produce an irritant dermatitis as described in EC Directives .Open cuts, abraded or irritated skin should not be exposed to this materialAlthough the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort characterisedby tearing or conjunctival redness (as with windburn).Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis; caused by particles less than 0.5 micron penetratingand remaining in the lung.Metallic dusts generated by the industrial process give rise to a number of potential health problems. The larger particles, above 5 micron, are nose and throatirritants.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.Fujfilm SericolMultipurpose Gold Powder851045TOXICITYNot AvailableIRRITATIONNot AvailablecopperTOXICITYdermal (rat) LD50: >2000 mg/kg [1]Inhalation (rat) LC50: 0.733 mg/l4 h [1]Inhalation (rat) LC50: 1.03 mg/l4 h [1]Inhalation (rat) LC50: 1.67 mg/l4 h [1]Oral (rat) LD50: 300500 mg/kg [1]IRRITATIONNil ReportedzincTOXICITYDermal (rabbit) LD50: 1130 mg/kg [2]Oral (rat) LD50: >2000 mg/kg [1]IRRITATIONNot AvailableLegend:1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds Unless otherwise specified dataextracted from RTECS - Register of Toxic Effect of chemical SubstancesCOPPERfor copper and its compounds (typically copper chloride):Acute toxicity: There are no reliable acute oral toxicity results available. In an acute dermal toxicity study (OECD TG 402), one group of 5 male rats and 5groups of 5 female rats received doses of 1000, 1500 and 2000 mg/kg bw via dermal application for 24 hours. The LD50 values of copper monochloridewere 2,000 mg/kg bw or greater for male (no deaths observed) and 1,224 mg/kg bw for female. Four females died at both 1500 and 2000 mg/kg bw, and oneat 1,000 mg/kg bw.WARNING: Inhalation of high concentrations of copper fume may cause "metal fume fever", an acute industrial disease of short duration. Symptoms aretiredness, influenza like respiratory tract irritation with fever.ZINCThe material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,scaling and thickening of the skin.Acute ToxicitySkin Irritation/CorrosionSerious EyeDamage/IrritationRespiratory or SkinsensitisationMutagenicityCarcinogenicityReproductivitySTOT - Single ExposureSTOT - Repeated ExposureAspiration HazardContinued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 6 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015CMR STATUSNot ApplicableLegend: – Data required to make classification available– Data available but does not fill the criteria for classification– Data Not Available to make classificationSECTION 12 ECOLOGICAL INFORMATIONToxicityDO NOT discharge into sewer or waterways.Persistence and degradabilityIngredient Persistence: Water/Soil Persistence: AirNo Data available for all ingredientsNo Data available for all ingredientsBioaccumulative potentialIngredientBioaccumulationNo Data available for all ingredientsMobility in soilIngredientMobilityNo Data available for all ingredientsSECTION 13 DISPOSAL CONSIDERATIONSWaste treatment methodsProduct / PackagingdisposalLegislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In someareas, certain wastes must be tracked.A Hierarchy of Controls seems to be common - the user should investigate:ReductionReuseRecyclingDisposal (if all else fails)This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.SECTION 14 TRANSPORT INFORMATIONLabels RequiredMarine PollutantHAZCHEMNO4YLand transport (ADG)UN number 3089Packing groupUN proper shipping nameEnvironmental hazardTransport hazard class(es)IIMETAL POWDER, FLAMMABLE, N.O.S. (contains copper and zinc)No relevant dataClass 4.1Subrisk Not ApplicableSpecial precautions for userSpecial provisionsLimited quantityNot Applicable1 kgAir transport (ICAO-IATA / DGR)UN number 3089Packing groupUN proper shipping nameEnvironmental hazardIIMetal powder, flammable, n.o.s. (contains copper and zinc)No relevant dataICAO/IATA Class 4.1Transport hazard class(es)ICAO / IATA SubriskERG CodeNot Applicable3LContinued...


Chemwatch: 6516-10Version No: 7.1.1.1Page 7 of 7Fujfilm Sericol Multipurpose Gold Powder 851045Issue Date: 01/01/2013Print Date: 16/03/2015Special precautions for userSpecial provisionsA3Cargo Only Packing Instructions 448Cargo Only Maximum Qty / Pack50 kgPassenger and Cargo Packing Instructions 445Passenger and Cargo Maximum Qty / Pack15 kgPassenger and Cargo Limited Quantity Packing Instructions Y441Passenger and Cargo Limited Maximum Qty / Pack5 kgSea transport (IMDG-Code / GGVSee)UN number 3089Packing groupUN proper shipping nameEnvironmental hazardTransport hazard class(es)IIMETAL POWDER, FLAMMABLE, N.O.S. (contains copper and zinc)Not ApplicableIMDG Class 4.1IMDG Subrisk Not ApplicableSpecial precautions for userEMS NumberSpecial provisionsLimited QuantitiesF-G , S-GNot Applicable1 kgSECTION 15 REGULATORY INFORMATIONSafety, health and environmental regulations / legislation specific for the substance or mixturecopper(7440-50-8) is foundon the following regulatorylistszinc(7440-66-6) is found onthe following regulatorylists"Australia Exposure Standards","Australia Inventory of Chemical Substances (AICS)","International Agency for Research on Cancer (IARC) - AgentsClassified by the IARC Monographs","Australia Hazardous Substances Information System - Consolidated Lists""Australia Exposure Standards","Australia Inventory of Chemical Substances (AICS)","International Agency for Research on Cancer (IARC) - AgentsClassified by the IARC Monographs","Australia Hazardous Substances Information System - Consolidated Lists"SECTION 16 OTHER INFORMATIONOther informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee usingavailable literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/referencesThe (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or othersettings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by anyprocess without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.end of SDS

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