Fujifilm Sericol Flushing and Cleaning Solution QU016

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Fujifilm Sericol Flushing and Cleaning Solution QU016

FUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 4988-35XC9317SCVersion No:3CD 2010/3 Page 1 of 6Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016SYNONYMS"digital printing head cleaner", "QU 016"PRODUCT USECleaning of digital printing heads.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel:+61 1800 039 008Emergency Tel:+61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Harmful by inhalation and incontact with skin.■ HARMFUL- May cause lung damage ifswallowed.■ Potentially explosive peroxidesmay form on standing.*.■ Ingestion may produce healthdamage*.■ Cumulative effects may resultfollowing exposure*.SAFETY■ Do not breathe gas/fumes/vapour/spray.■ Use only in well ventilated areas.■ Keep container in a well ventilated place.■ Avoid exposure - obtain special instructions before use.■ To clean the floor and all objects contaminated by thismaterial, use water.continued...


FUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 4988-35XC9317SCVersion No:3CD 2010/3 Page 3 of 6Section 5 - FIRE FIGHTING MEASURESFIRE/EXPLOSION HAZARD• Combustible.• Slight fire hazard when exposed to heat or flame.• Heating may cause expansion or decomposition leading to violent rupture of containers.• On combustion, may emit toxic fumes of carbon monoxide (CO).• Hot organic vapours or mist are capable of sudden spontaneous combustion when mixed with air even at temperatures below their publishedautoignition temperatures.• The temperature of ignition decreases with increasing vapour volume and vapour/air contact times and is influenced by pressure change.• Ignition may occur under elevated-temperature process conditions especially in processes performed under vacuum subjected to sudden ingress of airor in processes performed at elevated pressure, where sudden escape of vapours or mists to the atmosphere occurs.Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.May emit poisonous fumes.May emit corrosive fumes.FIRE INCOMPATIBILITY• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.HAZCHEMNonePersonal Protective EquipmentBreathing apparatus.Chemical splash suit.Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.MAJOR SPILLS■ Moderate hazard.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.• DO NOT allow clothing wet with material to stay in contact with skin.SUITABLE CONTAINER• Metal can or drum• Packaging as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY• Glycol ethers may form peroxides under certain conditions; the potential for peroxide formation is enhanced when these substances are used inprocesses such as distillation where they are concentrated or even evaporated to near-dryness or dryness; storage under a nitrogen atmosphere isrecommended to minimise the possible formation of highly reactive peroxides• Nitrogen blanketing is recommended if transported in containers at temperatures within 15 deg C of the flash-point and at or above the flash-point -large containers may first need to be purged and inerted with nitrogen prior to loading• In the presence of strong bases or the salts of strong bases, at elevated temperatures, the potential exists for runaway reactions.• Contact with aluminium should be avoided; release of hydrogen gas may result- glycol ethers will corrode scratched aluminium surfaces.• Avoid reaction with oxidising agents.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.continued...


FUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 4988-35XC9317SCVersion No:3CD 2010/3 Page 4 of 6Section 7 - HANDLING AND STORAGE• No smoking, naked lights or ignition sources.• Store in a cool, dry, well-ventilated area.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSSource Material TWA ppm TWA mg/m³ STEL ppm STEL mg/m³ Notes___________ ___________ _______ _______ _______ _______ _______Australia Exposure ethylene glycol 20 133 50 333 SkStandardsmonobutyl ether acetate(2- Butoxyethylacetate)PERSONAL PROTECTIONRESPIRATORType A Filter of sufficient capacityEYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing thewearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.OTHER• Overalls.• P.V.C. apron.• Barrier cream.• Skin cleansing cream.ENGINEERING CONTROLS■ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEColourless liquid with a pleasant ester-like odour; mixes with water and commonorganic solvents.PHYSICAL PROPERTIESLiquid.Mixes with water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) - 63 Viscosity Not AvailableBoiling Range (°C) 192 Solubility in water (g/L) MiscibleFlash Point (°C) 74 pH (1% solution) Not AvailableDecomposition Temp (°C) Not Available pH (as supplied) Not ApplicableAutoignition Temp (°C) 340 Vapour Pressure (kPa) Very LowUpper Explosive Limit (%) 8.5 (135C) Specific Gravity (water=1) 0.942Lower Explosive Limit (%) 0.5 (135C) Relative Vapour Density 5.5(air=1)continued...


FUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 4988-35XC9317SCVersion No:3CD 2010/3 Page 5 of 6Section 9 - PHYSICAL AND CHEMICAL PROPERTIESVolatile Component (%vol) 100 Evaporation Rate 0.3 BuAC = 1Section 10 - CHEMICAL STABILITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTS■ HARMFUL- May cause lung damage if swallowed.■ Harmful by inhalation and in contact withskin.■ Ingestion may produce health damage*.■ May produce discomfort of the eyes andskin*.■ * (limited evidence).CHRONIC HEALTH EFFECTS■ May possibly affect fertility*.■ Cumulative effects may result followingexposure*.■ * (limited evidence).TOXICITY AND IRRITATION■ Not available. Refer to individual constituents.Section 12 - ECOLOGICAL INFORMATIONNo dataEcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilethylene glycol monobutyl ether LOW LOW HIGHacetateSection 13 - DISPOSAL CONSIDERATIONS• Containers may still present a chemical hazard/ danger when empty.• Return to supplier for reuse/ recycling if possible.Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the sameproduct, then puncture containers, to prevent re-use, and bury at an authorised landfill.• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Section 14 - TRANSPORTATION INFORMATIONLabels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.HAZCHEM:None (ADG7)continued...


FUJIFILM SERICOL SOLVENT FLUSHING SOLUTION QU016Hazard Alert Code: MODERATEChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 4988-35XC9317SCVersion No:3CD 2010/3 Page 6 of 6Section 14 - TRANSPORTATION INFORMATIONNOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDGSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE S6REGULATIONSRegulations for ingredientsethylene glycol monobutyl ether acetate (CAS: 112-07-2) is found on the following regulatorylists;"Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","GESAMP/EHS Composite List -GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid SubstancesCarried in Bulk","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High ProductionVolume (HPV) Chemicals"No data for Fujifilm Sericol Solvent Flushing Solution QU016 (CW: 4988-35)Section 16 - OTHER INFORMATION■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review bythe Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 6-Aug-2010Print Date: 21-Oct-2010This is the end of the MSDS.

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