Safety Data Sheet according to Regulation (EC) No. 1907/2006 MSA
Safety Data Sheet according to Regulation (EC) No. 1907/2006 MSA
Safety Data Sheet according to Regulation (EC) No. 1907/2006 MSA
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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 1 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
1. Identification of the Substance / Preparation and of the Company / Undertaking<br />
Identification of the substance or preparation<br />
<strong>MSA</strong> – ZM 112<br />
Use of the substance/preparation<br />
Formulation for industrial and trade use<br />
<strong>No</strong>n-water-miscible metalworking lubricant<br />
Company/undertaking identification<br />
WERUCON GmbH<br />
Fahrenheitstr. 9, D-28359 Bremen<br />
Telefon: +49 (0) 421 223085-0<br />
Fax: +49 (0) 421 223085-99<br />
Information on substance/formulation:<br />
Product <strong>Safety</strong> Department<br />
Telephone: +49 (0) 2722 9376-17<br />
Emergency telephone: +49 (0) 2722 9376-54<br />
2. Hazards Identification<br />
Classification<br />
Harmful: may cause lung damage if swallowed.<br />
Repeated exposure may cause skin dryness or cracking.<br />
May cause long-term adverse effects in the aquatic environment.<br />
Additional hazard notes for persons and environment<br />
<strong>No</strong> further risks known.<br />
3. Composition / Information on Ingredients<br />
General designation of constituents<br />
Formulation of isoparaffinic hydrocarbons<br />
-Dangerous constituents<br />
Designation CAS-<strong>No</strong>. Concentration Symbol Risk <strong>No</strong>tes* .<br />
Alkanes (C11 – C15), Iso- 90622-58-5 75 – 100 % Xn 53-65-66<br />
* The text of the Risk Fac<strong>to</strong>rs quoted can be found in Chapter 16.<br />
4. First Aid Measures<br />
After inhalation<br />
Take the person affected out in<strong>to</strong> the fresh air and allow him <strong>to</strong> lie down quietly.<br />
After skin contact<br />
Remove contaminated clothing immediately and wash affected parts of the body with soap and<br />
water.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 2 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
After eye contact<br />
If product comes in<strong>to</strong> contact with eyes, carry out thorough rinsing immediately with plenty of water<br />
and consult a doc<strong>to</strong>r.<br />
After swallowing<br />
Do not induce vomiting - Aspiration hazard! Rinse out the mouth with water and drink water. Get<br />
medical attention.<br />
5. Fire-Fighting Measures<br />
Suitable extinguants<br />
Foam, CO2, dry powder extinguant<br />
Unsuitable extinguant for safety reasons<br />
Jet of water<br />
Special hazards from the substance or the actual product, its combustion products or gases produced<br />
CO x<br />
Special protective equipment for fire-fighting<br />
In the event of fire, use breathing apparatus suitable for any ambient conditions.<br />
Additional notes<br />
The disposal of fire residues and contaminated fire-protection water must be carried out in<br />
compliance with official regulations.<br />
6. Accidental Release Measures<br />
Personal precautionary measures<br />
Remove sources of ignition. Avoid skin and eye contact. Use personal protective equipment.<br />
Caution - Slippery surface through leakage of product.<br />
Environmental protection measures<br />
Do not allow product <strong>to</strong> get in<strong>to</strong> surface waters, the sewage system or the soil. Inform competent<br />
authorities if product has drained in<strong>to</strong> surface waters, the sewage system or in<strong>to</strong> the soil.<br />
Cleaning/elimination procedure<br />
Absorb liquid with oil or universal binders and carry out disposal in compliance with official<br />
regulations.<br />
7. Handling and S<strong>to</strong>rage<br />
Handling<br />
<strong>No</strong>tes on safe handling<br />
Avoid unprotected skin contact, use gloves if necessary (e.g., nitrile rubber). Avoid forming of<br />
vapors and aerosols as far as possible. Ensure adequate ventilation, if necessary use local fume<br />
extraction equipment.<br />
S<strong>to</strong>rage<br />
Requirements for s<strong>to</strong>rage rooms/conditions
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 3 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
Protect from frost and heat. S<strong>to</strong>re in closed containers. Take action <strong>to</strong> prevent from electrostatic<br />
charging.<br />
Containers and filling equipment is <strong>to</strong> be handled/s<strong>to</strong>red in such a manner that endangerment of<br />
water and soil from leakage of product can be excluded water.<br />
<strong>No</strong>tes on mixed s<strong>to</strong>rage<br />
S<strong>to</strong>rage Class 10, flammable liquids if not LGK 3A or 3B (LGK = S<strong>to</strong>rage Class) (VCI = German<br />
Chemical Industry Association)<br />
Specific use(s)<br />
Formulation for industrial and trade use<br />
<strong>No</strong>n-water-miscible metalworking lubricant<br />
BGR/GUV-R 143 “Activities involving coolant lubricants” is <strong>to</strong> be observed<br />
8. Exposure Controls / Personal Protection<br />
Exposure limit values<br />
Workplace limit-value<br />
Designation of substance Remarks .<br />
C9-C15-aliphaten (RCP-group) 600 mg/m³ Germany<br />
Exposure controls in the workplace<br />
Protection and Hygiene measures<br />
Keep away from food and drink. Do not put cleaning cloths saturated with product in your pockets.<br />
Wash your hands before breaks and meals. After work, use moisturizing skin cream. Observe<br />
workplace-related skin protection plan.<br />
Personal protection equipment<br />
Respira<strong>to</strong>ry protection<br />
<strong>No</strong>t necessary with adequate ventilation.<br />
Hand protection<br />
Use protective gloves of suitable material (e.g., nitrile rubber, penetration time > 480 min) tested<br />
<strong>according</strong> <strong>to</strong> EN 374.<br />
Use suitable skin protection cream that is not dissolved by oil if gloves cannot be worn.<br />
Observe skin-protection plan.<br />
Eye protection<br />
Wear protective goggles with side protection if there is a risk of splashing.<br />
Skin protection<br />
Wear industrial clothing.<br />
Environmental exposure controls<br />
See data in Point 6<br />
9. Physical and Chemical Properties
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 4 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
Appearance<br />
Form liquid<br />
Color colorless<br />
Odor mild<br />
Important data on health and environmental protection and safety<br />
Basic safety-relevant parameters<br />
pH-value ( g/l water, 20°C) not applicable<br />
Melting range not determined °C<br />
Boiling point/boiling range 182 / 200 °C<br />
Flammability 63 °C<br />
Ignition temperature > 200 °C<br />
Explosive limits lower 0.6 Vol%<br />
upper 7.0 Vol%<br />
Vapour pressure (20°C) 1.0 hPa<br />
Density (20°C) 765 kg/m³<br />
Water solubility (20°C) practically insoluble g/l<br />
Partition coefficient:<br />
n-octanol/water (log POW) not determined<br />
Viscosity, kinematic (20°C) 1.9 mm²/s<br />
10. Stability and Reactivity<br />
Conditions <strong>to</strong> avoid<br />
Substance is stable when handled for the intended purpose under the usual conditions of use.<br />
Observe notes on s<strong>to</strong>rage.<br />
Materials <strong>to</strong> avoid<br />
Powerful oxidizing agents<br />
Hazardous decomposition products<br />
In the event of fire: CO x<br />
11. Toxicological Information<br />
General remarks<br />
Acute <strong>to</strong>xicity, skin irritation, mucosal irritation, genotype change potential and skin-sensitization of<br />
the formulation were assessed on the basis of the data available for the individual components .<br />
To some extent, there are gaps in the data for individual components.
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 5 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
Practical experience<br />
Repeated or prolonged skin contact can lead <strong>to</strong> loss of fat and <strong>to</strong> dermatitis. As a result, the skin<br />
may react more sensitively <strong>to</strong> other irritant substances.<br />
Other information<br />
Aspiration can lead <strong>to</strong> irritation of the bronchia and lungs, in serious cases <strong>to</strong> pulmonary edema<br />
and inflammation of the lungs, and trigger disorders of the central nervous system.<br />
High vapour concentrations have an anaesthetic effect.<br />
Classification is carried out in accordance with directive 1999/45/EU.<br />
12. Ecological information<br />
Eco<strong>to</strong>xicity<br />
The product is a water-endangering liquid – do not allow product <strong>to</strong> get in<strong>to</strong> surface waters, the<br />
sewage system or the soil.<br />
Mobility<br />
<strong>No</strong> details available<br />
Persistence and degradability<br />
<strong>No</strong> details available<br />
Bioaccumulation potential<br />
<strong>No</strong> details available<br />
Other harmful effects<br />
The product does not contain any organically bound halogen. It does not contribute <strong>to</strong> the AOX<br />
value.<br />
13. Disposal Considerations<br />
Disposal / waste (product)<br />
Pass <strong>to</strong> approved waste-disposal company with due observance of official local regulations.<br />
Recommended EU waste code<br />
07 06 04 other organic solvents, washing liquors and mother liquors<br />
Packing<br />
Completely empty containers. Pass <strong>to</strong> approved waste-disposal company. Drums and containers<br />
can be reconditioned. Cleaning by recycling firm.<br />
14. Transport Information<br />
<strong>No</strong>t a hazardous substance <strong>according</strong> <strong>to</strong> ADR/RID, IMDG, IATA/ICAO<br />
15. Regula<strong>to</strong>ry Information<br />
Identification
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />
<strong>MSA</strong> – ZM 112 page 6 of 6<br />
Date printed: 30.09.2011<br />
Version 1.0 EN Revised on: 18.08.2010<br />
Hazard symbol(s) and hazard marking<br />
Xn Harmful<br />
Hazard-determining components<br />
Alkane, C11 – C15, Iso-<br />
Risk-<strong>No</strong>tes<br />
R 53 May cause long-term adverse effects in the aquatic environment.<br />
R 65 Harmful: may cause lung damage if swallowed.<br />
R 66 Repeated exposure may cause skin dryness or cracking.<br />
<strong>Safety</strong> <strong>No</strong>tes<br />
S 23 Do not breathe gas/fumes/vapour/spray (appropriate wording <strong>to</strong> be specified by the<br />
manufacturer).<br />
S 24 Avoid contact with skin.<br />
S 61 Avoid release <strong>to</strong> the environment. Refer <strong>to</strong> special instructions/safety data sheets.<br />
S 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this<br />
container or label.<br />
Other <strong>EC</strong> regulations<br />
Details concerning Directive 1999/13/<strong>EC</strong> on the limitation of emissions of volatile organic<br />
compounds (VOC-RL)<br />
The product contains “volatile organic compounds”.<br />
Content: 100%<br />
National regulations (Germany)<br />
31. BImSchV<br />
The product contains “volatile organic compounds”.<br />
Content: 100%<br />
Water endangerment class<br />
WGK 1 (slight water endangerment, VwVwS – Administrative Register – Substances hazardous <strong>to</strong><br />
water - Annex 4)<br />
16. Other Information<br />
Text of R-phrases in section 3<br />
R 53 May cause long-term adverse effects in the aquatic environment.<br />
R 65 Harmful: may cause lung damage if swallowed.<br />
R 66 Repeated exposure may cause skin dryness or cracking.<br />
Updating service<br />
Updated chapters are marked with an *.<br />
Details are based on our present knowledge. They describe our products with reference <strong>to</strong> safety requirements<br />
and are therefore not <strong>to</strong> be interpreted as promising certain properties.