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Safety Data Sheet according to Regulation (EC) No. 1907/2006 MSA

Safety Data Sheet according to Regulation (EC) No. 1907/2006 MSA

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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 1 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

1. Identification of the Substance / Preparation and of the Company / Undertaking<br />

Identification of the substance or preparation<br />

<strong>MSA</strong> – ZM 112<br />

Use of the substance/preparation<br />

Formulation for industrial and trade use<br />

<strong>No</strong>n-water-miscible metalworking lubricant<br />

Company/undertaking identification<br />

WERUCON GmbH<br />

Fahrenheitstr. 9, D-28359 Bremen<br />

Telefon: +49 (0) 421 223085-0<br />

Fax: +49 (0) 421 223085-99<br />

Information on substance/formulation:<br />

Product <strong>Safety</strong> Department<br />

Telephone: +49 (0) 2722 9376-17<br />

Emergency telephone: +49 (0) 2722 9376-54<br />

2. Hazards Identification<br />

Classification<br />

Harmful: may cause lung damage if swallowed.<br />

Repeated exposure may cause skin dryness or cracking.<br />

May cause long-term adverse effects in the aquatic environment.<br />

Additional hazard notes for persons and environment<br />

<strong>No</strong> further risks known.<br />

3. Composition / Information on Ingredients<br />

General designation of constituents<br />

Formulation of isoparaffinic hydrocarbons<br />

-Dangerous constituents<br />

Designation CAS-<strong>No</strong>. Concentration Symbol Risk <strong>No</strong>tes* .<br />

Alkanes (C11 – C15), Iso- 90622-58-5 75 – 100 % Xn 53-65-66<br />

* The text of the Risk Fac<strong>to</strong>rs quoted can be found in Chapter 16.<br />

4. First Aid Measures<br />

After inhalation<br />

Take the person affected out in<strong>to</strong> the fresh air and allow him <strong>to</strong> lie down quietly.<br />

After skin contact<br />

Remove contaminated clothing immediately and wash affected parts of the body with soap and<br />

water.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 2 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

After eye contact<br />

If product comes in<strong>to</strong> contact with eyes, carry out thorough rinsing immediately with plenty of water<br />

and consult a doc<strong>to</strong>r.<br />

After swallowing<br />

Do not induce vomiting - Aspiration hazard! Rinse out the mouth with water and drink water. Get<br />

medical attention.<br />

5. Fire-Fighting Measures<br />

Suitable extinguants<br />

Foam, CO2, dry powder extinguant<br />

Unsuitable extinguant for safety reasons<br />

Jet of water<br />

Special hazards from the substance or the actual product, its combustion products or gases produced<br />

CO x<br />

Special protective equipment for fire-fighting<br />

In the event of fire, use breathing apparatus suitable for any ambient conditions.<br />

Additional notes<br />

The disposal of fire residues and contaminated fire-protection water must be carried out in<br />

compliance with official regulations.<br />

6. Accidental Release Measures<br />

Personal precautionary measures<br />

Remove sources of ignition. Avoid skin and eye contact. Use personal protective equipment.<br />

Caution - Slippery surface through leakage of product.<br />

Environmental protection measures<br />

Do not allow product <strong>to</strong> get in<strong>to</strong> surface waters, the sewage system or the soil. Inform competent<br />

authorities if product has drained in<strong>to</strong> surface waters, the sewage system or in<strong>to</strong> the soil.<br />

Cleaning/elimination procedure<br />

Absorb liquid with oil or universal binders and carry out disposal in compliance with official<br />

regulations.<br />

7. Handling and S<strong>to</strong>rage<br />

Handling<br />

<strong>No</strong>tes on safe handling<br />

Avoid unprotected skin contact, use gloves if necessary (e.g., nitrile rubber). Avoid forming of<br />

vapors and aerosols as far as possible. Ensure adequate ventilation, if necessary use local fume<br />

extraction equipment.<br />

S<strong>to</strong>rage<br />

Requirements for s<strong>to</strong>rage rooms/conditions


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 3 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

Protect from frost and heat. S<strong>to</strong>re in closed containers. Take action <strong>to</strong> prevent from electrostatic<br />

charging.<br />

Containers and filling equipment is <strong>to</strong> be handled/s<strong>to</strong>red in such a manner that endangerment of<br />

water and soil from leakage of product can be excluded water.<br />

<strong>No</strong>tes on mixed s<strong>to</strong>rage<br />

S<strong>to</strong>rage Class 10, flammable liquids if not LGK 3A or 3B (LGK = S<strong>to</strong>rage Class) (VCI = German<br />

Chemical Industry Association)<br />

Specific use(s)<br />

Formulation for industrial and trade use<br />

<strong>No</strong>n-water-miscible metalworking lubricant<br />

BGR/GUV-R 143 “Activities involving coolant lubricants” is <strong>to</strong> be observed<br />

8. Exposure Controls / Personal Protection<br />

Exposure limit values<br />

Workplace limit-value<br />

Designation of substance Remarks .<br />

C9-C15-aliphaten (RCP-group) 600 mg/m³ Germany<br />

Exposure controls in the workplace<br />

Protection and Hygiene measures<br />

Keep away from food and drink. Do not put cleaning cloths saturated with product in your pockets.<br />

Wash your hands before breaks and meals. After work, use moisturizing skin cream. Observe<br />

workplace-related skin protection plan.<br />

Personal protection equipment<br />

Respira<strong>to</strong>ry protection<br />

<strong>No</strong>t necessary with adequate ventilation.<br />

Hand protection<br />

Use protective gloves of suitable material (e.g., nitrile rubber, penetration time > 480 min) tested<br />

<strong>according</strong> <strong>to</strong> EN 374.<br />

Use suitable skin protection cream that is not dissolved by oil if gloves cannot be worn.<br />

Observe skin-protection plan.<br />

Eye protection<br />

Wear protective goggles with side protection if there is a risk of splashing.<br />

Skin protection<br />

Wear industrial clothing.<br />

Environmental exposure controls<br />

See data in Point 6<br />

9. Physical and Chemical Properties


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 4 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

Appearance<br />

Form liquid<br />

Color colorless<br />

Odor mild<br />

Important data on health and environmental protection and safety<br />

Basic safety-relevant parameters<br />

pH-value ( g/l water, 20°C) not applicable<br />

Melting range not determined °C<br />

Boiling point/boiling range 182 / 200 °C<br />

Flammability 63 °C<br />

Ignition temperature > 200 °C<br />

Explosive limits lower 0.6 Vol%<br />

upper 7.0 Vol%<br />

Vapour pressure (20°C) 1.0 hPa<br />

Density (20°C) 765 kg/m³<br />

Water solubility (20°C) practically insoluble g/l<br />

Partition coefficient:<br />

n-octanol/water (log POW) not determined<br />

Viscosity, kinematic (20°C) 1.9 mm²/s<br />

10. Stability and Reactivity<br />

Conditions <strong>to</strong> avoid<br />

Substance is stable when handled for the intended purpose under the usual conditions of use.<br />

Observe notes on s<strong>to</strong>rage.<br />

Materials <strong>to</strong> avoid<br />

Powerful oxidizing agents<br />

Hazardous decomposition products<br />

In the event of fire: CO x<br />

11. Toxicological Information<br />

General remarks<br />

Acute <strong>to</strong>xicity, skin irritation, mucosal irritation, genotype change potential and skin-sensitization of<br />

the formulation were assessed on the basis of the data available for the individual components .<br />

To some extent, there are gaps in the data for individual components.


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 5 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

Practical experience<br />

Repeated or prolonged skin contact can lead <strong>to</strong> loss of fat and <strong>to</strong> dermatitis. As a result, the skin<br />

may react more sensitively <strong>to</strong> other irritant substances.<br />

Other information<br />

Aspiration can lead <strong>to</strong> irritation of the bronchia and lungs, in serious cases <strong>to</strong> pulmonary edema<br />

and inflammation of the lungs, and trigger disorders of the central nervous system.<br />

High vapour concentrations have an anaesthetic effect.<br />

Classification is carried out in accordance with directive 1999/45/EU.<br />

12. Ecological information<br />

Eco<strong>to</strong>xicity<br />

The product is a water-endangering liquid – do not allow product <strong>to</strong> get in<strong>to</strong> surface waters, the<br />

sewage system or the soil.<br />

Mobility<br />

<strong>No</strong> details available<br />

Persistence and degradability<br />

<strong>No</strong> details available<br />

Bioaccumulation potential<br />

<strong>No</strong> details available<br />

Other harmful effects<br />

The product does not contain any organically bound halogen. It does not contribute <strong>to</strong> the AOX<br />

value.<br />

13. Disposal Considerations<br />

Disposal / waste (product)<br />

Pass <strong>to</strong> approved waste-disposal company with due observance of official local regulations.<br />

Recommended EU waste code<br />

07 06 04 other organic solvents, washing liquors and mother liquors<br />

Packing<br />

Completely empty containers. Pass <strong>to</strong> approved waste-disposal company. Drums and containers<br />

can be reconditioned. Cleaning by recycling firm.<br />

14. Transport Information<br />

<strong>No</strong>t a hazardous substance <strong>according</strong> <strong>to</strong> ADR/RID, IMDG, IATA/ICAO<br />

15. Regula<strong>to</strong>ry Information<br />

Identification


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

<strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong>. <strong>1907</strong>/<strong>2006</strong><br />

<strong>MSA</strong> – ZM 112 page 6 of 6<br />

Date printed: 30.09.2011<br />

Version 1.0 EN Revised on: 18.08.2010<br />

Hazard symbol(s) and hazard marking<br />

Xn Harmful<br />

Hazard-determining components<br />

Alkane, C11 – C15, Iso-<br />

Risk-<strong>No</strong>tes<br />

R 53 May cause long-term adverse effects in the aquatic environment.<br />

R 65 Harmful: may cause lung damage if swallowed.<br />

R 66 Repeated exposure may cause skin dryness or cracking.<br />

<strong>Safety</strong> <strong>No</strong>tes<br />

S 23 Do not breathe gas/fumes/vapour/spray (appropriate wording <strong>to</strong> be specified by the<br />

manufacturer).<br />

S 24 Avoid contact with skin.<br />

S 61 Avoid release <strong>to</strong> the environment. Refer <strong>to</strong> special instructions/safety data sheets.<br />

S 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this<br />

container or label.<br />

Other <strong>EC</strong> regulations<br />

Details concerning Directive 1999/13/<strong>EC</strong> on the limitation of emissions of volatile organic<br />

compounds (VOC-RL)<br />

The product contains “volatile organic compounds”.<br />

Content: 100%<br />

National regulations (Germany)<br />

31. BImSchV<br />

The product contains “volatile organic compounds”.<br />

Content: 100%<br />

Water endangerment class<br />

WGK 1 (slight water endangerment, VwVwS – Administrative Register – Substances hazardous <strong>to</strong><br />

water - Annex 4)<br />

16. Other Information<br />

Text of R-phrases in section 3<br />

R 53 May cause long-term adverse effects in the aquatic environment.<br />

R 65 Harmful: may cause lung damage if swallowed.<br />

R 66 Repeated exposure may cause skin dryness or cracking.<br />

Updating service<br />

Updated chapters are marked with an *.<br />

Details are based on our present knowledge. They describe our products with reference <strong>to</strong> safety requirements<br />

and are therefore not <strong>to</strong> be interpreted as promising certain properties.

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