CP-40 FA II P2-RS Bleach Fixer Replenisher Part A - FUJIFILM ...

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CP-40 FA II P2-RS Bleach Fixer Replenisher Part A - FUJIFILM ...

MATERIAL SAFETY DATA SHEETSMS 391037For FUJIFILM Product Code: 391037Description: CP-40 FA II P2-RS Bleach Fixer ReplenisherCarton Identification Code: Cat 850230Covers 2 part/s:Bottle Identification Code: Cat 750230, 750231Note: Material Safety Data Sheets must be kept on the premises where chemicals are stored and used.They must be made readily available to all persons concerned with this chemistry. These may includingtransport operators, store persons, workers, machine operators, retail / medical staff, store managers,building owners and managers, emergency services, and government or industry inspectors.AUSTRALIA:NEW ZEALAND:Emergency Information: (02) 9466 2721 (09)414 0400.FUJIFILM Australia Pty Ltd ABN 80 000 064 433114 Old Pittwater RoadBrookvale, NSW 2100Phone: (02) 9466 2600 Fax: (02) 9938 1975Visit our website: http://www.fujifilm.com.au for the latest version of this MSDS.Issue Date: August 2004


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part AThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 2 of 5SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTSIngredients CAS No Conc,% TWA (mg/m 3 ) STEL (mg/m 3 )Ammonium thiosulfate 7783-18-8


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part AThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 3 of 5disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contaminationwhen sending contaminated clothing to laundry.SECTION 7 - HANDLING AND STORAGEHandling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. CheckSection 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.The measures detailed below under "Storage" should be followed during handling in order to minimise risks topersons using the product in the workplace. Also, avoid contact or contamination of product with incompatiblematerials listed in Section 10.Storage: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make surethat the product does not come into contact with substances listed under "Materials to avoid" in Section 10. Someliquid preparations settle or separate on standing and may require stirring before use. Check packaging - there maybe further storage instructions on the label.SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIONThe following Australian Standards will provide general advice regarding safety clothing and equipment:Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial EyeProtection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 )Acetic acid 25 37No special equipment is usually needed when occasionally handling small quantities. The following instructions arefor bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.Ventilation: No special ventilation requirements are normally necessary for this product. However make sure thatthe work environment remains clean and that vapours and mists are minimised.Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is beingused.Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skinprotection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that youwear suitable gloves (preferably elbow-length) when skin contact is likely.Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,PVC.Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consultthe Australian Standard mentioned above.SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:Physical Description & colour: Clear colourless liquid.Odour:No odour.Boiling Point:Approximately 100°C at 100kPa.Freezing/Melting Point: Approximately 0°C.Volatiles:Water component.Vapour Pressure:2.37 kPa at 20°C (water vapour pressure).Vapour Density:No data.Specific Gravity: 1.261Water Solubility:Completely soluble in water.pH:No data.Volatility:No data.Odour Threshold:No data.Evaporation Rate:No data.Coeff Oil/water distribution: No dataAutoignition temp:Does not burn.SECTION 10 - STABILITY AND REACTIVITYReactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you haveany doubts, contact the supplier for advice on shelf life properties.Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part AThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 4 of 5Incompatibilities: No particular Incompatibilities.Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strongheating. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogencyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foulodour.Polymerisation: This product will not undergo polymerisation reactions.SECTION 11 - TOXICOLOGICAL INFORMATIONLocal Effects:Target Organs:There is no data to hand indicating any particular target organs.Classification of Hazardous IngredientsIngredientRisk PhrasesNo ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardousconcentrations.Insufficient data to be sure of status.SECTION 12 - ECOLOGICAL INFORMATIONSECTION 13 - DISPOSAL CONSIDERATIONSDisposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containerseither in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Thisproduct should be suitable for landfill. However, check with local Waste Disposal Authority before sending there. Notethat product properties may have been changed in use, significantly altering it's suitability for landfill. Please do NOTdispose into sewers or waterways. The use of a commercial waste disposal service is recommended for photographicwastes as they may contain reclaimable silver or other ingredients which are not desirable in waste water streams.SECTION 14 - TRANSPORT INFORMATIONADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessaryunless required by other regulations.SECTION 15 - REGULATORY INFORMATIONAICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.The following ingredients: Acetic acid, are mentioned in the SUSDP.Acronyms:ADG CodeAICSCAS numberHazchem NumberIARCNOHSCNOSNTPR-PhraseSUSDPUN NumberSECTION 16 - OTHER INFORMATIONThis MSDS contains only safety-related information. For other data see product literature.A more recent version of this MSDS might be found at http://www.fujifilm.com.au/Australian Code for the Transport of Dangerous Goods by Road and RailAustralian Inventory of Chemical SubstancesChemical Abstracts Service Registry NumberEmergency action code of numbers and letters that provide information toemergency services especially firefightersInternational Agency for Research on CancerNational Occupational Health and Safety CommissionNot otherwise specifiedNational Toxicology Program (USA)Risk PhraseStandard for the Uniform Scheduling of Drugs & PoisonsUnited Nations NumberTHIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT ANDHOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OFHOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part AThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 5 of 5IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERSOUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENTTO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.Please read all labels carefully before using product.This MSDS is prepared in accord with the NOHSC document “National Code of Practice for thePreparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]Copyright © Kilford & Kilford Pty Ltd, August, 2004.http://www.kilford.com.au/ Phone (02)9251 4532MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part BThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 1 of 5SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANYFUJIFILM Australia Pty Ltd ABN 80 000 064 433FUJIFILM (NZ) Limited114 Old Pittwater Rd Cnr William Pickering Dr & Bush RdBrookvale NSW 2100Albany, AucklandPhone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ)http://www.fujifilm.com.au/Substance:Water solution of ingredients.Trade Name:CP-40 FA II P2-RS Bleach Fixer Replenisher Part BProduct Use:Bleach-fix replenisher. Part B of a two part system.Creation Date: August, 2004Revision Date: August, 2004SECTION 2 - HAZARDS IDENTIFICATIONStatement of Hazardous NatureThis product is classified as: Hazardous according to the criteria of NOHSC Australia.Dangerous according to the Australian Dangerous Goods (ADG) Code.Risk Phrases: R36/38. Irritating to eyes and skin.Safety Phrases: S45, S24/25, S36/37. In case of accident or if you feel unwell, contact a doctor or PoisonsInformation Centre immediately (show the label where possible). Avoid contact with skin and eyes. Wear suitableprotective clothing and gloves.SUSDP Classification: S5ADG Classification: Class 8 (CORROSIVE LIQUID, N.O.S.)UN Number: 1760Physical Description & colour: Brown solution.Odour: No odour.Major Health Hazards: irritating to eyes and skin.Emergency OverviewPotential Health EffectsInhalationShort term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that thisproduct is not harmful. In addition product is unlikely to cause any discomfort or irritation.Long Term exposure: No data for health effects associated with long term inhalation.Skin Contact:Short term exposure: Available data indicates that this product is not harmful. However product is a skin irritant.Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but allshould disappear once exposure has ceased.Long Term exposure: No data for health effects associated with long term skin exposure.Eye Contact:Short term exposure: Exposure via eyes is considered to be unlikely. This product is an eye irritant. Symptomsmay include stinging and reddening of eyes and watering which may become copious. Other symptoms may alsobecome evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthyexposure or delayed treatment may cause permanent damage.Long Term exposure: No data for health effects associated with long term eye exposure.Ingestion:Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is likely to bean oral irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptomsmay also become evident.Long Term exposure: No data for health effects associated with long term ingestion.MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part BThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 2 of 5Carcinogen Status:NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.NTP: No significant ingredient is classified as carcinogenic by NTP.IARC: No significant ingredient is classified as carcinogenic by IARC.SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTSIngredients CAS No Conc,% TWA (mg/m 3 ) STEL (mg/m 3 )Ferric ammonium ethylenediamine tetraacetate 21265-50-9


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part BThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 3 of 5Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance thatvapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, norespirator is necessary when using this product. However, if you have any doubts consult the Australian Standardmentioned below (section 8).Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spillis too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drainsor waterways. Because of the corrosiveness of this product, special personal care should be taken in any cleanupoperation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, anddispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventingrunoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This materialmay be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal.Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination whensending contaminated clothing to laundry.SECTION 7 - HANDLING AND STORAGEHandling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. CheckSection 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.The measures detailed below under "Storage" should be followed during handling in order to minimise risks topersons using the product in the workplace. Also, avoid contact or contamination of product with incompatiblematerials listed in Section 10.Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storageof this class of poison. Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks.Containers should be kept closed in order to minimise contamination. Make sure that the product does not come intocontact with substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L ofCorrosive Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggestyou contact your licensing authority in order to clarify your obligations. Check packaging - there may be furtherstorage instructions on the label.SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIONThe following Australian Standards will provide general advice regarding safety clothing and equipment:Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial EyeProtection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 )nitric acid 5.2 10No special equipment is usually needed when occasionally handling small quantities. The following instructions arefor bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.Ventilation: No special ventilation requirements are normally necessary for this product. However make sure thatthe work environment remains clean and that vapours and mists are minimised.Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protectyour eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to wherethis product is being used.Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure thatall skin areas are covered. See below for suitable material types.Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,PVC.Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consultthe Australian Standard mentioned above.Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is beingused.Physical Description & colour:Odour:Boiling Point:Freezing/Melting Point:Volatiles:Vapour Pressure:SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:Brown solution.No odour.Approximately 100°C at 100kPa.Approximately 0°C.Water component.2.37 kPa at 20°C (water vapour pressure).MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400


Product Name: CP-40 FA II P2-RS Bleach Fixer Replenisher Part BThis revision issued: August, 2004Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)Page: 4 of 5Vapour Density:No data.Specific Gravity: 1.211Water Solubility:Completely soluble in water.pH:Corrosive to many metals including copper and even some stainless steelgrades. pH 6 approxVolatility:No data.Odour Threshold:No data.Evaporation Rate:No data.Coeff Oil/water distribution: No dataAutoignition temp:Does not burn.SECTION 10 - STABILITY AND REACTIVITYReactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you haveany doubts, contact the supplier for advice on shelf life properties.Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.Incompatibilities: zinc, tin, aluminium and their alloys, Corrosive to many metals including copper and even somestainless steel grades.Fire Decomposition: Only small quantities of decomposition products are expected from this products attemperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and ifcombustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under somecircumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Water, iron compounds, bromine compounds.Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,disturbance of judgment, and unconsciousness followed by coma and death.Polymerisation: This product will not undergo polymerisation reactions.SECTION 11 - TOXICOLOGICAL INFORMATIONLocal Effects:Target Organs: There is no data to hand indicating any particular target organs.Classification of Hazardous IngredientsIngredientRisk PhrasesNo ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardousconcentrations.Insufficient data to be sure of status.SECTION 12 - ECOLOGICAL INFORMATIONSECTION 13 - DISPOSAL CONSIDERATIONSDisposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containerseither in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Pleasedo NOT dispose into sewers or waterways. The use of a commercial waste disposal service is recommended forphotographic wastes as they may contain reclaimable silver or other ingredients which are not desirable in wastewater streams.SECTION 14 - TRANSPORT INFORMATIONADG Code: 1760, CORROSIVE LIQUID, N.O.S.Hazchem Code: 2XSpecial Provisions: SP109, SP130, SP275Dangerous Goods Class: Class 8, Corrosive Substances.Packaging Group: IIIPackaging Method: 3.8.8Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container withClasses 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6MATERIAL SAFETY DATA SHEETIssued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600FUJIFILM (NZ) Limited Phone (09)414 0400

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