Chemwatch MSDS Print - FUJIFILM Australia

products.fujifilm.com.au

Chemwatch MSDS Print - FUJIFILM Australia

FUJIFILM SERICOL THINNER #10 857110Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 6516-31XC9317SCVersion No:3CD 2010/3 Page 2 of 7Section 2 - HAZARDS IDENTIFICATION■ Cumulative effects may resultfollowing exposure*.■ May produce discomfort of therespiratory system and skin*.■ Limited evidence of a carcinogeniceffect*.■ Repeated exposure potentially causesskin dryness and cracking*.■ Vapours potentially cause drowsinessand dizziness*.■ Avoid exposure - obtain special instructions beforeuse.■ To clean the floor and all objects contaminated by thismaterial, use water and detergent.■ Keep container tightly closed.■ This material and its container must be disposed of ina safe way.■ Keep away from food, drink and animal feeding stuffs.* (limited evidence). ■ In case of contact with eyes, rinse with plenty ofwater and contact Doctor or Poisons Information Centre.■ This material and its container must be disposed of ashazardous waste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %propylene glycol monomethyl ether acetate, alpha- isomer 108-65-6 30-60cyclohexanone 108-94-1 30-60NOTE: Manufacturer has supplied full ingredientinformation to allow CHEMWATCH assessment.Section 4 - FIRST AID MEASURESSWALLOWED• For advice, contact a Poisons Information Centre or a doctor.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.EYE■ If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lowerlids.• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.• Transport to hospital or doctor without delay.SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear.• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.Perform CPR if necessary.NOTES TO PHYSICIAN■ Treat symptomatically.Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA• Water spray or fog.• Alcohol stable foam.• Dry chemical powder.• BCF (where regulations permit).FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.continued...


FUJIFILM SERICOL THINNER #10 857110Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 6516-31XC9317SCVersion No:3CD 2010/3 Page 3 of 7Section 5 - FIRE FIGHTING MEASURES• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.FIRE/EXPLOSION HAZARD• Liquid and vapour are flammable.• Moderate fire hazard when exposed to heat or flame.• Vapour may travel a considerable distance to source of ignition.• Heating may cause expansion or decomposition leading to violent rupture of containers.Other combustion products include: carbon dioxide (CO2).FIRE INCOMPATIBILITY■ Avoid contamination with strong oxidising agents as ignition may result.Attacks, softens and may dissolve rubber, many plastics, paints and coatings.HAZCHEM•3YPersonal Protective EquipmentBreathing apparatus.Chemical splash suit.Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.• Wear breathing apparatus plus protective gloves.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING■ Avoid generating and breathing mist.• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of overexposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.SUITABLE CONTAINER• Glass container is suitable for laboratory quantities.• Packing as supplied by manufacturer.• Plastic containers may only be used if approved for flammable liquid.• Check that containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY■ Avoid storage with oxidisers.STORAGE REQUIREMENTS• Store in original containers in approved flammable liquid storage area.• Store away from incompatible materials in a cool, dry, well-ventilated area.• DO NOT store in pits, depressions, basements or areas where vapours may be trapped.• No smoking, naked lights, heat or ignition sources.continued...


FUJIFILM SERICOL THINNER #10 857110Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 6516-31XC9317SCVersion No:3CD 2010/3 Page 4 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSSource Material TWA ppm TWA mg/m³ STEL ppm STEL mg/m³ Notes___________ ___________ _______ _______ _______ _______ _______Australia Exposure propylene glycol 50 274 100 548 SkStandardsmonomethyl etheracetate, alpha- isomer(1- Methoxy- 2-propanol acetate)Australia Exposure cyclohexanone 25 100 SkStandards(Cyclohexanone)PERSONAL PROTECTIONRESPIRATORType A Filter of sufficient capacityEYE• Safety glasses with side shields; or as required,• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing thewearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].HANDS/FEET• Barrier cream and • Butyl rubber gloves or • Rubber gloves.• Rubber boots.• DO NOT use this product to clean the skin.OTHER• Overalls.• Eyewash unit.Ensure there is ready access to an emergency shower.ENGINEERING CONTROLS■ CARE: Use of a quantity of this material in confined space or poorly ventilated area, where rapid build up of concentrated atmosphere may occur,could require increased ventilation and/or protective gear.Use in a well-ventilated area.General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator.In confined spaces where there is inadequate ventilation, wear full-face air supplied breathing apparatus.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear, colourless flammable liquid with a characteristic solvent odour;does not mix with water.PHYSICAL PROPERTIESLiquid.Does not mix with water.Floats on water.State Liquid Molecular Weight Not applicableMelting Range (°C) Not available Viscosity Not availableBoiling Range (°C) 145- 156 Solubility in water (g/L) ImmiscibleFlash Point (°C) 48 pH (1% solution) Not available.Decomposition Temp (°C) Not available pH (as supplied) Not applicablecontinued...


FUJIFILM SERICOL THINNER #10 857110Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 6516-31XC9317SCVersion No:3CD 2010/3 Page 5 of 7Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAutoignition Temp (°C) Not available Vapour Pressure (kPa) Not availableUpper Explosive Limit (%) 7.0 PGMA Specific Gravity (water=1) 0.95Lower Explosive Limit (%) 1.5 PGMA Relative Vapour Density >1(air=1)Volatile Component (%vol) Not available Evaporation Rate Not availablecyclohexanone■ log Kow (Sangster 1997): 0.81Section 10 - CHEMICAL STABILITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTS■ Irritating to eyes.■ HARMFUL- May cause lung damage if swallowed.■ Harmful by inhalation, in contact with skinand if swallowed.■ Can be absorbed through skin.■ Vapours may cause dizziness or suffocation.■ May produce discomfort of the respiratorysystem and skin*.■ Vapours potentially cause drowsiness anddizziness*.■ * (limited evidence).CHRONIC HEALTH EFFECTS■ May cause harm to the unborn child.■ Limited evidence of a carcinogenic effect*.■ Cumulative effects may result followingexposure*.■ Repeated exposure potentially causes skindryness and cracking*.■ * (limited evidence).TOXICITY AND IRRITATION■ Not available. Refer to individual constituents.Section 12 - ECOLOGICAL INFORMATIONThis material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilpropylene glycol monomethyl HIGH LOW HIGHether acetate, alpha- isomercyclohexanone LOW LOW HIGHSection 13 - DISPOSAL CONSIDERATIONS• Consult manufacturer for recycling options and recycle where possible .• Consult State Land Waste Management Authority for disposal.• Incinerate residue at an approved site.• Recycle containers if possible, or dispose of in an authorised landfill.continued...


FUJIFILM SERICOL THINNER #10 857110Hazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 6-Aug-2010 CHEMWATCH 6516-31XC9317SCVersion No:3CD 2010/3 Page 6 of 7Section 14 - TRANSPORTATION INFORMATIONLabels Required: FLAMMABLE LIQUIDHAZCHEM:●3Y (ADG7)Land Transport UNDG:Class or division: 3 Subsidiary risk: NoneUN No.: 1993 UN packing group: IIIShipping Name:FLAMMABLE LIQUID, N.O.S. (contains propylene glycolmonomethyl ether acetate, alpha-isomer cyclohexanone)Air Transport IATA:ICAO/IATA Class: 3 ICAO/IATA Subrisk: NoneUN/ID Number: 1993 Packing Group: IIISpecial provisions:Cargo OnlyA3Packing Instructions: 310 Maximum Qty/Pack: 220 LPassenger and CargoPassenger and CargoPacking Instructions: 309 Maximum Qty/Pack: 60 LPassenger and Cargo Limited QuantityPassenger and Cargo Limited QuantityPacking Instructions: Y309 Maximum Qty/Pack: 10 LShipping Name: FLAMMABLE LIQUID, N.O.S. *(CONTAINSPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE, ALPHA-ISOMERCYCLOHEXANONE)Maritime Transport IMDG:IMDG Class: 3 IMDG Subrisk: NoneUN Number: 1993 Packing Group: IIIEMS Number: F-E , S-E Special provisions: 223 274 955Limited Quantities: 5 LShipping Name: FLAMMABLE LIQUID, N.O.S.(contains propylene glycol monomethyl ether acetate, alpha-isomer cyclohexanone)Section 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientspropylene glycol monomethyl ether acetate, alpha-isomer (CAS: 108-65-6,84540-57-8,142300-82-1)is found on the following regulatory lists;"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory ofChemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV)Chemicals"cyclohexanone (CAS: 108-94-1) is found on the following regulatory lists;"Australia Exposure Standards","Australia Hazardous Substances","Australia Illicit Drug Reagents/Essential Chemicals - Category III","AustraliaInventory of Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimumrequirements","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Agency for Research on Cancer (IARC) -Agents Reviewed by the IARC Monographs","International Fragrance Association (IFRA) Survey: Transparency List","OECD Representative List of HighProduction Volume (HPV) Chemicals"No data for Fujifilm Sericol Thinner #10 857110 (CW: 6516-31)Section 16 - OTHER INFORMATIONNDSubstance CAS Suggested codespropylene glycol monomethyl ether 84540- 57- 8continued...

More magazines by this user
Similar magazines