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Medicinal Chemistry Course

Medicinal Chemistry Course

Isomers of omeprazole-

Isomers of omeprazole- after 1990• Efforts to identify microbial or enzymatic preparationof single enantiomers• Separation of diastereomeric derivatives ofomeprazole using preparative reversed phasechromatographyLindberg / von Unge

Resolution via a diastereomeric derivative ofomeprazole (spin-off from prodrug project)OCH 3H 3C CH 3NOCH 3H 3C CH 3O NN SNHomeprazoleOCH 31) CH 2O2) SOCl 23) (S)-mandelic acidNOSONOOHOCH 31) RP chromatographyOCH 3H 3C CH 3NOCH 3H 3C CH 3O NOCH 3NaOHNOS..NOCH 3NS..NHOOOHesomeprazoleLindberg / von Unge

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