Chemwatch MSDS Print - FUJIFILM Australia

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Chemwatch MSDS Print - FUJIFILM Australia

FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 1 of 9Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510PROPER SHIPPING NAMEAEROSOLSPRODUCT USE■ Application is by spray atomisation from a hand held aerosol pack.Aerosol adhesive.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel:+61 1800 039 008Emergency Tel:+61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Extremely flammable.■ Irritating to eyes and skin.■ May cause CANCER.■ May cause heritable genetic damage.■ May cause long- term adverse effectsin the aquatic environment.■ Repeated exposure may cause skindryness and cracking.■ Vapours may cause drowsiness anddizziness.SAFETY• Keep locked up.• Keep away from sources of ignition. No smoking.• Do not breathe gas/fumes/vapour/spray.• In case of insufficient ventilation, wear suitablerespiratory equipment.• Avoid exposure - obtain special instructions beforeuse.• To clean the floor and all objects contaminated by thismaterial, use water and detergent.• This material and its container must be disposed of ina safe way.continued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 2 of 9Section 2 - HAZARDS IDENTIFICATION• Keep away from food, drink and animal feeding stuffs.• In case of contact with eyes, rinse with plenty ofwater and contact Doctor or Poisons Information Centre.• This material and its container must be disposed of ashazardous waste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %naphtha petroleum, light, hydrotreated 64742-49-0. 10-25acetone 67-64-1 10-25n- hexane 110-54-3 1-5hydrocarbon propellant 68476-85-7. 30-60Section 4 - FIRST AID MEASURESSWALLOWED• Not considered a normal route of entry.• If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.• Avoid giving milk or oils.• Avoid giving alcohol.EYE■ If aerosols come in contact with the eyes:• Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lowerlids.• Transport to hospital or doctor without delay.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.SKIN■ If solids or aerosol mists are deposited upon the skin:• Flush skin and hair with running water (and soap if available).• Remove any adhering solids with industrial skin cleansing cream.• DO NOT use solvents.• Seek medical attention in the event of irritation.INHALED■ If aerosols, fumes or combustion products are inhaled:• Remove to fresh air.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve maskdevice, or pocket mask as trained. Perform CPR if necessary.NOTES TO PHYSICIAN■ Treat symptomatically.For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:• Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.• Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and givenoxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.• Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported;intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so thathyperventilation improves clearance.• A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence ofpneumothorax.for simple ketones:--------------------------------------------------------------BASIC TREATMENT--------------------------------------------------------------• Establish a patent airway with suction where necessary.• Watch for signs of respiratory insufficiency and assist ventilation as necessary.• Administer oxygen by non-rebreather mask at 10 to 15 l/min.• Monitor and treat, where necessary, for pulmonary oedema .continued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 3 of 9Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ SMALL FIRE:• Water spray, dry chemical or CO2LARGE FIRE:• Water spray or fog.FIRE FIGHTING■ FOR FIRES INVOLVING MANY GAS CYLINDERS:• To stop the flow of gas, specifically trained personnel may inert the atmosphere to reduce oxygen levels thus allowing the capping of leakingcontainer(s).• Reduce the rate of flow and inject an inert gas, if possible, before completely stopping the flow to prevent flashback.• DO NOT extinguish the fire until the supply is shut off otherwise an explosive re-ignition may occur.• If the fire is extinguished and the flow of gas continues, used increased ventilation to prevent build-up, of explosive atmosphere.• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.When any large container (including road and rail tankers) is involved in a fire,consider evacuation by 100 metres in all directions.FIRE/EXPLOSION HAZARD• Liquid and vapour are highly flammable.• Severe fire hazard when exposed to heat or flame.• Vapour forms an explosive mixture with air.• Severe explosion hazard, in the form of vapour, when exposed to flame or spark.Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of burning organic material.Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.FIRE INCOMPATIBILITY• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.HAZCHEM2YEPersonal Protective EquipmentBreathing apparatus.Gas tight chemical resistant suit.Limit exposure duration to 1 BA set 30 mins.Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Wear protective clothing, impervious gloves and safety glasses.• Shut off all possible sources of ignition and increase ventilation.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• May be violently or explosively reactive.• Wear breathing apparatus plus protective gloves.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.continued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 4 of 9Section 7 - HANDLING AND STORAGESUITABLE CONTAINER• Aerosol dispenser.• Check that containers are clearly labelled.STORAGE INCOMPATIBILITY■ For alkyl aromatics:The alkyl side chain of aromatic rings can undergo oxidation by several mechanisms. The most common and dominant one is the attack by oxidation atbenzylic carbon as the intermediate formed is stabilised by resonance structure of the ring.• Following reaction with oxygen and under the influence of sunlight, a hydroperoxide at the alpha-position to the aromatic ring, is the primaryoxidation product formed (provided a hydrogen atom is initially available at this position) - this product is often short-lived but may be stabledependent on the nature of the aromatic substitution; a secondary C-H bond is more easily attacked than a primary C-H bond whilst a tertiary C-Hbond is even more susceptible to attack by oxygen• Monoalkylbenzenes may subsequently form monocarboxylic acids; alkyl naphthalenes mainly produce the corresponding naphthalene carboxylic acids.• Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic rings and strong oxidising agents.• Aromatics can react exothermically with bases and with diazo compounds.Acetone:• may react violently with chloroform, activated charcoal, aliphatic amines, bromine, bromine trifluoride, chlorotriazine, chromic(IV) acid,chromic(VI) acid, chromium trioxide, chromyl chloride, hexachloromelamine, iodine heptafluoride, iodoform, liquid oxygen, nitrosyl chloride,nitrosyl perchlorate, nitryl perchlorate, perchloromelamine, peroxomonosulfuric acid, platinum, potassium tert-butoxide, strong acids, sulfurdichloride, trichloromelamine, xenon tetrafluoride• reacts violently with bromoform and chloroform in the presence of alkalies or in contact with alkaline surfaces.• may form unstable and explosive peroxides in contact with strong oxidisers, fluorine, hydrogen peroxide (90%), sodium perchlorate, 2-methyl-1,3-butadiene• can increase the explosive sensitivity of nitromethane on contact flow or agitation may generate electrostatic charges due to low conductivity.Benzene:• reacts violently with iodine pentafluoride.• hydrogenation to cyclohexane was effected in a fixed bed reactor at 210-230 deg C, but a fall in conversion was apparent; increasing the bed tempby 10 deg C and the hydrogen flow led to a large increase in reaction rate which the interbed cooling coils could not handle; an exotherm to 280deg C developed, with a hot spot around 600 deg C which bulged the reactor wall.• ignites in contact with iodine heptafluoride gas• ignition may occur following addition of a small particle of dioxygenyl tetrafluoroborate (a very powerful oxidant) to small samples at ambienttemp caused/ ignition.Ketones in this group:• are reactive with many acids and bases liberating heat and flammable gases (e.g., H2).• react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat.• are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides.• react violently with aldehydes, HNO3 (nitric acid), HNO3 + H2O2 (mixture of nitric acid and hydrogen peroxide), and HClO4 (perchloric acid).• Compressed gases may contain a large amount of kinetic energy over and above that potentially available from the energy of reaction produced by thegas in chemical reaction with other substances.STORAGE REQUIREMENTS• Store below 38 deg. C.• Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can.• Store in original containers in approved flammable liquid storage area.• DO NOT store in pits, depressions, basements or areas where vapours may be trapped.• No smoking, naked lights, heat or ignition sources.• Keep containers securely sealed. Contents under pressure.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSSource Material TWA ppm TWA STEL STEL Peak Peak TWA Notesmg/m³ ppm mg/m³ ppm mg/m³ F/CC___________ ___________ _______ _______ _______ _______ _______ _______ _______ _______Australia naphtha 900 (seeExposure petroleum, light, ChapterStandards hydrotreated 16)(Petrol(gasoline))Australia acetone (Acetone) 500 1185 1000 2375ExposureStandardsAustralia n- hexane (Hexane 20 72Exposure(n- Hexane))Standardscontinued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 5 of 9Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONSource Material TWA ppm TWA STEL STEL Peak Peak TWA Notesmg/m³ ppm mg/m³ ppm mg/m³ F/CC___________ ___________ _______ _______ _______ _______ _______ _______ _______ _______Australia hydrocarbon 1000 1800Exposurepropellant (LPGStandards(liquifiedpetroleum gas))PERSONAL PROTECTIONRESPIRATORType AX Filter of sufficient capacityEYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing thewearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].HANDS/FEET• No special equipment needed when handling small quantities.• OTHERWISE:• For potentially moderate exposures:• Wear general protective gloves, eg. light weight rubber gloves.OTHER• Employees working with confirmed human carcinogens should be provided with, and be required to wear, clean, full body protective clothing (smocks,coveralls, or long-sleeved shirt and pants), shoe covers and gloves prior to entering the regulated area.• Employees engaged in handling operations involving carcinogens should be provided with, and required to wear and use half-face filter-typerespirators with filters for dusts, mists and fumes, or air purifying canisters or cartridges. A respirator affording higher levels of protectionmay be substituted.• Emergency deluge showers and eyewash fountains, supplied with potable water, should be located near, within sight of, and on the same level withlocations where direct exposure is likely.• Prior to each exit from an area containing confirmed human carcinogens, employees should be required to remove and leave protective clothing andequipment at the point of exit and at the last exit of the day, to place used clothing and equipment in impervious containers at the point of exitfor purposes of decontamination or disposal. The contents of such impervious containers must be identified with suitable labels. For maintenanceand decontamination activities, authorized employees entering the area should be provided with and required to wear clean, impervious garments,including gloves, boots and continuous-air supplied hood.• Prior to removing protective garments the employee should undergo decontamination and be required to shower upon removal of the garments and hoo• The clothing worn by process operators insulated from earth may develop static charges far higher (up to 100 times) than the minimum ignitionenergies for various flammable gas-air mixtures. This holds true for a wide range of clothing materials including cotton.• Avoid dangerous levels of charge by ensuring a low resistivity of the surface material worn outermost.BRETHERICK: Handbook of Reactive Chemical Hazards.ENGINEERING CONTROLS• Employees exposed to confirmed human carcinogens should be authorized to do so by the employer, and work in a regulated area.• Work should be undertaken in an isolated system such as a "glove-box" . Employees should wash their hands and arms upon completion of the assignedtask and before engaging in other activities not associated with the isolated system.• Within regulated areas, the carcinogen should be stored in sealed containers, or enclosed in a closed system, including piping systems, with anysample ports or openings closed while the carcinogens are contained within.• Open-vessel systems are prohibited.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE■ Supplied as an aerosol pack. Contents under PRESSURE.Coloured highly flammable liquid with a characteristic odour; does not mix with water.continued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 6 of 9Section 9 - PHYSICAL AND CHEMICAL PROPERTIESPHYSICAL PROPERTIESLiquid.Gas.Does not mix with water.Floats on water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) - 44 Solubility in water (g/L) ImmiscibleFlash Point (°C)


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 7 of 9Section 11 - TOXICOLOGICAL INFORMATIONcommonalities from both manufacturing process and compositional perspectives. intermediates.ACETONE:TOXICITYIRRITATIONOral (man) TDLo: 2857 mg/kgEye (human): 500 ppm - IrritantOral (rat) LD50: 5800 mg/kgEye (rabbit): 3.95 mg - SEVEREInhalation (human) TCLo: 500 ppmEye (rabbit): 20mg/24hr - ModerateInhalation (man) TCLo: 12000 ppm/4 hrSkin (rabbit):395mg (open) - MildInhalation (man) TCLo: 10 mg/m³/6 hrSkin (rabbit): 500 mg/24hr - MildInhalation (rat) LC50: 50100 mg/m³/8 hrDermal (rabbit) LD50: 20000 mg/kg■ The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling epidermis.N-HEXANE:TOXICITYIRRITATIONOral (rat) LD50: 28710 mg/kgEye(rabbit): 10 mg - MildInhalation (human) TCLo: 190 ppm/8WInhalation (rat) LD50: 48000 ppm/4h■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.Section 12 - ECOLOGICAL INFORMATIONMay cause long-term adverse effects in the aquatic environment.This material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilacetone LOW HIGH LOW HIGHn- hexane LOW MED MEDSection 13 - DISPOSAL CONSIDERATIONS• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Consult State Land Waste Management Authority for disposal.• Discharge contents of damaged aerosol cans at an approved site.• Allow small quantities to evaporate.• DO NOT incinerate or puncture aerosol cans.Section 14 - TRANSPORTATION INFORMATIONLabels Required: FLAMMABLE GASHAZCHEM:2YE (ADG7)Land Transport UNDG:Class or division 2.1 Subsidiary risk: NoneUN No.: 1950 UN packing group: NoneShipping Name:AEROSOLScontinued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 8 of 9Section 14 - TRANSPORTATION INFORMATIONAir Transport IATA:ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: NoneUN/ID Number: 1950 Packing Group: -Special provisions:A145Cargo OnlyPacking Instructions: 203 Maximum Qty/Pack: 150 kgPassenger and CargoPassenger and CargoPacking Instructions: 203 Maximum Qty/Pack: 75 kgPassenger and Cargo Limited QuantityPassenger and Cargo Limited QuantityPacking Instructions: Y203 Maximum Qty/Pack: 30 kg GShipping Name: AEROSOLS, FLAMMABLEMaritime Transport IMDG:IMDG Class: 2 IMDG Subrisk: SP63UN Number: 1950 Packing Group: NoneEMS Number: F-D , S-U Special provisions: 63 190 277 327 959Limited Quantities: See SP277Shipping Name: AEROSOLSSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientsnaphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following regulatorylists;"Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD Representative List of High Production Volume (HPV)Chemicals"acetone (CAS: 67-64-1) is found on the following regulatory lists;"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Illicit DrugReagents/Essential Chemicals - Category III","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","AustraliaStandard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling ofMedicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5""GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 18: List of products to which the Code does not apply","IMO MARPOL(Annex II) - List of Other Liquid Substances","International Fragrance Association (IFRA) Survey: Transparency List","OECD Representative List ofHigh Production Volume (HPV) Chemicals","United Nations List of Precursors and Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugsand Psychotropic Substances Under International Control - Table II"n-hexane (CAS: 110-54-3) is found on the following regulatory lists;"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia NationalPollutant Inventory","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","OECD Representative List of High Production Volume (HPV)Chemicals"hydrocarbon propellant (CAS: 68476-85-7,68476-86-8) is found on the following regulatory lists;"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory ofChemical Substances (AICS)","OECD Representative List of High Production Volume (HPV) Chemicals"No data for Fujifilm Sericol T-Fix Extra Aerosol Adhesive IA510 (CW: 4606-24)Section 16 - OTHER INFORMATIONINGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCAShydrocarbon propellant 68476-85-7, 68476-86-8■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review bythe Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings.continued...


FUJIFILM SERICOL T-FIX EXTRA AEROSOL ADHESIVE IA510Chemwatch Material Safety Data SheetIssue Date: 24-Dec-2009 CHEMWATCH 4606-24C9317ECVersion No:4CD 2011/1 Page 9 of 9Section 16 - OTHER INFORMATIONThis document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 24-Dec-2009Print Date: 27-Jan-2011This is the end of the MSDS.

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