ds chemport impulse ra-sf fountain solution - FUJIFILM Australia

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ds chemport impulse ra-sf fountain solution - FUJIFILM Australia

DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 1 of 7Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEDS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONSYNONYMS"Product Code: LT2708"PRODUCT USEDesigned for alcohol reduction or elimination on sheetfed presses.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Irritating to eyes and skin.■ May cause SENSITISATION by skin contact.■ Harmful to aquatic organisms, may causelong- term adverse effects in the aquaticenvironment.SAFETY• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable gloves.• Wear eye/face protection.• To clean the floor and all objects contaminatedby this material, use water.• In case of contact with eyes, rinse with plentyof water and contact Doctor or Poisons InformationCentre.continued...


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 2 of 7Section 2 - HAZARDS IDENTIFICATION• If swallowed, IMMEDIATELY contact Doctor orPoisons Information Centre. (show this containeror label).Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %propylene glycol monobutyl ether - alpha isomer 5131-66-8 10-302- ethyl hexanol 104-76-7


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 3 of 7Section 5 - FIRE FIGHTING MEASURESFIRE INCOMPATIBILITY■ - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignitionmay result.HAZCHEMNoneSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS■ - Remove all ignition sources.- Clean up all spills immediately.- Avoid breathing vapours and contact with skin and eyes.- Control personal contact by using protective equipment.MAJOR SPILLS■ Moderate hazard.- Clear area of personnel and move upwind.- Alert Fire Brigade and tell them location and nature of hazard.- Wear breathing apparatus plus protective gloves.- Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING■ - DO NOT allow clothing wet with material to stay in contact with skin.The tendency of many ethers to form explosive peroxides is well documented. Ethers lacking non-methyl hydrogen atoms adjacent tothe ether link are thought to be relatively safe- DO NOT concentrate by evaporation, or evaporate extracts to dryness, as residues may contain explosive peroxides withDETONATION potential.- Any static discharge is also a source of hazard.- Before any distillation process remove trace peroxides by shaking with excess 5% aqueous ferrous sulfate solution or bypercolation through a column of activated alumina.- Distillation results in uninhibited ether distillate with considerably increased hazard because of risk of peroxide formationon storage.The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treated toconcentrate the peroxides. The substance may concentrate around the container opening for example.Purchases of peroxidisable chemicals should be restricted to ensure that the chemical is used completely before it can becomeperoxidised.- A responsible person should maintain an inventory of peroxidisable chemicals or annotate the general chemical inventory toindicate which chemicals are subject to peroxidation. An expiration date should be determined. The chemical should either betreated to remove peroxides or disposed of before this date.- Avoid all personal contact, including inhalation.- Wear protective clothing when risk of exposure occurs.- Use in a well-ventilated area.- Prevent concentration in hollows and sumps.SUITABLE CONTAINER■ - Metal can or drum- Packaging as recommended by manufacturer.- Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY■ - Glycol ethers may form peroxides under certain conditions; the potential for peroxide formation is enhanced when thesesubstances are used in processes such as distillation where they are concentrated or even evaporated to near-dryness or dryness;storage under a nitrogen atmosphere is recommended to minimise the possible formation of highly reactive peroxides- Nitrogen blanketing is recommended if transported in containers at temperatures within 15 deg C of the flash-point and at orabove the flash-point - large containers may first need to be purged and inerted with nitrogen prior to loading- In the presence of strong bases or the salts of strong bases, at elevated temperatures, the potential exists for runawayreactions.- Contact with aluminium should be avoided; release of hydrogen gas may result- glycol ethers will corrode scratched aluminiumsurfaces.- Avoid reaction with oxidising agents.continued...


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 4 of 7Section 7 - HANDLING AND STORAGESTORAGE REQUIREMENTS■ - Store in original containers.- Keep containers securely sealed.- No smoking, naked lights or ignition sources.- Store in a cool, dry, well-ventilated area.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• propylene glycol monobutyl ether - alpha isomer: CAS:5131- 66- 8• 2- ethyl hexanol: CAS:104- 76- 7• isothiazolinones, mixed: CAS:55965- 84- 9PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE■ - Safety glasses with side shields.- Chemical goggles.- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a reviewof lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aidpersonnel should be trained in their removal and suitable equipment should be readily available. In the event of chemicalexposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the firstsigns of eye redness or irritation - lens should be removed in a clean environment only after workers have washed handsthoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET■ - Wear chemical protective gloves, eg. PVC.- Wear safety footwear or safety gumboots, eg. Rubber.NOTE:- The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.- Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:- frequency and duration of contact,- chemical resistance of glove material,- glove thickness and- dexterity.OTHER■ - Overalls.- P.V.C. apron.- Barrier cream.- Skin cleansing cream.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.continued...


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 5 of 7Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear pale yellow liquid with a mild alcohol odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) 100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not Availab leDecomposition Temp (°C) Not Available pH (as supplied) 4.2- 4.6Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa ) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.03- 1.04Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) 63 Evaporation Rate Not AvailableSection 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY■ - Presence of incompatible materials.- Product is considered stable.- Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Although ingestion is not thought to produce harmful effects (as classified under EC Directives), the material may still bedamaging to the health of the individual, following ingestion, especially where pre-existing organ (e.g liver, kidney) damage isevident. Present definitions of harmful or toxic substances are generally based on doses producing mortality rather than thoseproducing morbidity (disease, ill-health).EYE■ This material can cause eye irritation and damage in some persons.■ The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis.Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated.SKIN■ Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still producehealth damage following entry through wounds, lesions or abrasions.INHALED■ The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by ECDirectives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and thatsuitable control measures be used in an occupational setting.CHRONIC HEALTH EFFECTS■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.Prolonged or repeated skin contact to 2-ethyl hexanol may result in irritation, reddening and sensitisation. Repeated oral anddermal exposures to animals has resulted in adverse liver and kidney effects.Male and female rats receiving 1.25% 2-ethyl hexanol in the diet for 90 days showed evidence of kidney and liver effects.The material produces teratogenic effects in laboratory rats when administered orally to pregnant Wistar rats on day 12 ofgestation (1 and 2 ml/kg).Some glycol esters and their ethers cause wasting of the testicles, reproductive changes, infertility and changes to kidneycontinued...


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 6 of 7Section 11 - TOXICOLOGICAL INFORMATIONfunction. Shorter chain compounds are more dangerous. Higher concentrations and prolonged exposure can cause blood in the urine.TOXICITY AND IRRITATION■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesisof contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simplydetermined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it areequally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one withstronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances arenoteworthy if they produce an allergic test reaction in more than 1% of the persons tested.for propylene glycol ethers (PGEs):Typical propylene glycol ethers include propylene glycol n-butyl ether (PnB); dipropylene glycol n-butyl ether (DPnB);dipropylene glycol methyl ether acetate (DPMA); tripropylene glycol methyl ether (TPM).Testing of a wide variety of propylene glycol ethers Testing of a wide variety of propylene glycol ethers has shown thatpropylene glycol-based ethers are less toxic than some ethers of the ethylene series.SENSITISERisothiazolinones, mixed Australia Final Report Recommended for Hazard Currently listed inon Hazard Classification (R43) Annex 1, DirectiveClassification of67/548/EECCommon Skin SensitisersSection 12 - ECOLOGICAL INFORMATIONHarmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/SoilDS Chemport Impulse RA- SF No Data No DataFountain Solution Available Availablepropylene glycol monobutyl ether LOW No Data LOW HIGH- alpha isomer Available2- ethyl hexanol LOW No Data LOW HIGHAvailableisothiazolinones, mixed No Data No DataAvailableAvailableSection 13 - DISPOSAL CONSIDERATIONS■ - Containers may still present a chemical hazard/ danger when empty.- Return to supplier for reuse/ recycling if possible.Otherwise:- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to lawsoperating in their area.A Hierarchy of Controls seems to be common - the user should investigate:- Reduction.- DO NOT allow wash water from cleaning or process equipment to enter drains.- It may be necessary to collect all wash water for treatment before disposal.- In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.- Where in doubt contact the responsible authority.- Recycle wherever possible or consult manufacturer for recycling options.- Consult State Land Waste Authority for disposal.- Bury or incinerate residue at an approved site.- Recycle containers if possible, or dispose of in an authorised landfill.continued...


DS CHEMPORT IMPULSE RA-SF FOUNTAIN SOLUTIONChemwatch Independent Material Safety Data SheetIssue Date: 12-Oct-2011 CHEMWATCH 28-44319317SP(cs)Version No:2.0CD 2011/3 Page 7 of 7Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:None (ADG7)NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDGSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientspropylene glycol monobutyl ether - alpha isomer (CAS: 5131-66-8) is found on the followingregulatory lists;"Australia Inventory of Chemical Substances (AICS)"2-ethyl hexanol (CAS: 104-76-7) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","WHO Food Additives Series - Flavouring agents considered for specificationsonly"No data for DS Chemport Impulse RA-SF Fountain Solution (CW: 28-4431)Section 16 - OTHER INFORMATION■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 12-Oct-2011Print Date: 12-Oct-2011This is the end of the MSDS.

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