MSDS - DuBois Chemicals Online Store

1.Product nameSupplier/ManufacturerRecommended useMSDS #Material Safety Data SheetRUST PREVENT 500Product and company identification: RUST PREVENT 500: DuBois Chemicals, Inc.3630 E. Kemper Rd.Cincinnati, OH 45241Phone: 1-800-438-2647::DuBois Chemicals Canada, Inc.3450 Ridgeway Drive, Unit 2Mississauga, Ontario, L5L OA2Phone: 1-866-861-3603Industrial applications: Rust/Corrosion InhibitorMS0127177Product code : 00167010, 00167480Validation date: 5/6/2011.Version : 2In case of emergency : 1-866-923-4919 (US and Canada)01-651-523-0314 (Int'l and Mexico)Hazardous MaterialInformation System (U.S.A.):HealthFlammabilityPhysical hazards*1102.Physical stateHazards identificationOSHA/HCS statusEmergency overviewRoutes of entryPotential acute health effectsInhalationSee toxicological information (section 11)::::Liquid. [Viscous liquid.]CAUTION!MAY CAUSE EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED.CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT MAYCAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.Aspiration hazard if swallowed. Do not ingest. Avoid breathing vapor or mist. Avoidcontact with eyes, skin and clothing. Wash thoroughly after handling.No known significant effects or critical hazards.IngestionSkin::Aspiration hazard if swallowed. Can enter lungs and cause damage.Slightly irritating to the skin.Eyes: Moderately irritating to eyes.Potential chronic health effectsChronic effects: Contains material that may cause target organ damage, based on animal data.CarcinogenicityTarget organsMedical conditionsaggravated by overexposure: This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).: No known significant effects or critical hazards.:Dermal contact. Eye contact. Inhalation.: Contains material which may cause damage to the following organs: upper respiratorytract.Pre-existing disorders involving any target organs mentioned in this MSDS as being at riskmay be aggravated by over-exposure to this product.Validated on 5/6/2011.RUST PREVENT 5001/6

3.Composition/information on ingredientsName CAS number % by weightDistillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 10 - 20There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.4.First aid measuresEye contactSkin contactInhalationIngestionProtection of first-aidersNotes to physician5.Fire-fighting measuresFlammability of the product :Extinguishing mediaSuitable :Not suitable :Special exposure hazards :Hazardous thermaldecomposition productsSpecial protectiveequipment for fire-fighters:::::Check for and remove any contact lenses. Immediately flush eyes with plenty of water forat least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attentionimmediately.In case of contact, immediately flush skin with plenty of water for at least 15 minutes whileremoving contaminated clothing and shoes. Wash clothing before reuse. Clean shoesthoroughly before reuse. Get medical attention immediately.Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratoryarrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tightclothing such as a collar, tie, belt or waistband. Get medical attention immediately.Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.: No action shall be taken involving any personal risk or without suitable training. It may bedangerous to the person providing aid to give mouth-to-mouth resuscitation.:No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.In a fire or if heated, a pressure increase will occur and the container may burst.Use an extinguishing agent suitable for the surrounding fire.None known.Promptly isolate the scene by removing all persons from the vicinity of the incident if thereis a fire. No action shall be taken involving any personal risk or without suitable training.: No specific data.Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.6.Accidental release measuresPersonal precautions :Environmental precautionsMethods for cleaning upNo action shall be taken involving any personal risk or without suitable training. Evacuatesurrounding areas. Keep unnecessary and unprotected personnel from entering. Do nottouch or walk through spilled material. Avoid breathing vapor or mist. Provide adequateventilation. Wear appropriate respirator when ventilation is inadequate. Put onappropriate personal protective equipment (see section 8).: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air).Small spill :Stop leak if without risk. Move containers from spill area. Dilute with water and mop up ifwater-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material andplace in an appropriate waste disposal container. Dispose of via a licensed wastedisposal contractor.Validated on 5/6/2011.RUST PREVENT 5002/6

6.Accidental release measuresLarge spill :Stop leak if without risk. Move containers from spill area. Approach release from upwind.Prevent entry into sewers, water courses, basements or confined areas. Wash spillagesinto an effluent treatment plant or proceed as follows. Contain and collect spillage withnon-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earthand place in container for disposal according to local regulations (see section 13).Dispose of via a licensed waste disposal contractor. Contaminated absorbent materialmay pose the same hazard as the spilled product. Note: see section 1 for emergencycontact information and section 13 for waste disposal.7.Handling and storageHandlingStorage::Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.Keep in the original container or an approved alternative made from a compatiblematerial, kept tightly closed when not in use. Empty containers retain product residue andcan be hazardous. Do not reuse container.Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.8.Exposure controls/personal protectionOccupational exposure limitsIngredientDistillates (petroleum), hydrotreated heavynaphthenicExposure limitsACGIH TLV (United States, 2/2010).TWA: 5 mg/m³ 8 hour(s). Form: Inhalable fraction. See Appendix C,paragraph A. Inhalable Particulate Mass TLVs (IPM–TLVs) for thosematerials that are hazardous when deposited anywhere in the respiratorytract.OSHA PEL (United States, 6/2010).TWA: 5 mg/m³ 8 hour(s).Consult local authorities for acceptable exposure limits.Recommended monitoringproceduresEngineering measuresHygiene measuresPersonal protectionRespiratoryHands :: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.: No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure below any recommended or statutorylimits.: Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.:Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.Validated on 5/6/2011.RUST PREVENT 5003/6

8.EyesSkinExposure controls/personal protectionEnvironmental exposurecontrols9.Physical stateFlash pointColorOdorpHDilution pHBoiling/condensation pointMelting/freezing point::Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.Physical and chemical propertiesSpecific gravityDensityVapor pressureVapor densityOdor thresholdEvaporation rateSolubility::::Liquid. [Viscous liquid.]: Closed cup: >100°C (>212°F) [Tagliabue.]Amber.Hydrocarbon.Not applicable.: Not available.: Not available.: Not available.: 0.82: 6.8429 lbs/gal: Not available.::::Not available.Not available.Not available.Elemental Phosphorus : 0 %Octanol/water partition : Not available.coefficient10.Stability and reactivityChemical stabilityConditions to avoidMaterials to avoidHazardous decompositionproductsPossibility of hazardousreactions11.::::Insoluble in the following materials: cold water and hot water.The product is stable.Do not swallow.No specific data.Toxicological informationAcute toxicityDistillates (petroleum),hydrotreated heavynaphthenicUnder normal conditions of storage and use, hazardous decomposition products shouldnot be produced.: Under normal conditions of storage and use, hazardous reactions will not occur.Product/ingredient name Result Species Dose ExposureCarcinogenicityClassificationDistillates (petroleum),hydrotreated heavynaphthenicLD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat >5000 mg/kg -Product/ingredient name ACGIH IARC EPA NIOSH NTPValidated on 5/6/2011.A4 - - - - -RUST PREVENT 500OSHA4/6

11.Toxicological informationNumerical measures of toxicityAcute toxicity estimatesRouteDermalATE value2410.8 mg/kg12.EcotoxicityEcological informationAquatic ecotoxicityNone known.13.Disposal considerationsWaste disposal: No known significant effects or critical hazards.:The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products via alicensed waste disposal contractor. Disposal of this product, solutions and any byproductsshould at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.Disposal should be in accordance with applicable regional, national and local laws and regulations.Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION foradditional handling information and protection of employees.14.Transport informationIATA/IMDG/DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information.15.United StatesRegulatory informationU.S. Federal regulationsUnited States inventory(TSCA 8b)SARA 313None identified.State regulationsMassachusettsRhode IslandNew JerseyPennsylvania: None of the components are listed.: None of the components are listed.: None of the components are listed.: None of the components are listed.California Prop. 65None of the components are listed.CanadaWHMIS (Canada): Not controlled under WHMIS (Canada).Canadian listsCanadian NPRI :Validated on 5/6/2011.: TSCA 12(b) one-time export: No products were found.TSCA 12(b) annual export notification: No products were found.: All components are listed or exempted.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: RUSTPREVENT 500: Immediate (acute) health hazardSARA 302/304/311/312 extremely hazardous substances: No products were found.CERCLA: Hazardous substances.: No products were found.The following components are listed: Hydrotreated light distillateRUST PREVENT 5005/6

15.Regulatory informationCanada inventory: At least one component is not listed in DSL but all such components are listed in NDSL.This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations andthe MSDS contains all the information required by the Controlled Products Regulations.International regulationsInternational lists : Australia inventory (AICS): Not determined.China inventory (IECSC): All components are listed or exempted.Japan inventory: Not determined.Korea inventory: Not determined.New Zealand Inventory of Chemicals (NZIoC): Not determined.Philippines inventory (PICCS): Not determined.Europe inventory: Not determined.16.Other informationHazardous MaterialInformation System (U.S.A.):Health*1Flammability1Physical hazards0Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may bepurchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.Indicates information that has changed from previously issued version.Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.Validated on 5/6/2011.RUST PREVENT 5006/6