Chemwatch Australian MSDS 3826981 - FUJIFILM Australia

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Chemwatch Australian MSDS 3826981 - FUJIFILM Australia

FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 1 of 10Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME61336 FUJIFILM CP-49E P1 PART A SUCPROPER SHIPPING NAMECAUSTIC ALKALI LIQUID, N.O.S.(contains sodium hydroxide and potassium hydroxide)PRODUCT USEFor processing of photographic colour paper. Part 1 of a 2 part system.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISKRisk CodesR38R41R43R56SAFETYSafety CodesS23S24S25Risk Phrases• Irritating to skin.• Risk of serious damage to eyes.• May cause SENSITISATION by skin contact.• Toxic to soil organisms.Safety Phrases• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 3 of 10Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing mediawhich may be used. Choice of extinguishing media should take into account surrounding areas.Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may producefloating layers of combustible substances.In such an event consider:• foam.FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• Non combustible.• Not considered a significant fire risk, however containers may burn.Decomposition may produce toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), other pyrolysisproducts typical of burning organic material.May emit corrosive fumes.FIRE INCOMPATIBILITY■ None known.HAZCHEM2RSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS■ Environmental hazard - contain spillage.• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge ordisposal of material.• Check regularly for spills and leaks.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS■ Environmental hazard - contain spillage.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with moisture.SUITABLE CONTAINER• Lined metal can, lined metal pail/ can.• Plastic pail.• Polyliner drum.• Packing as recommended by manufacturer.continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 4 of 10Section 7 - HANDLING AND STORAGEFor low viscosity materials• Drums and jerricans must be of the non-removable head type.• Where a can is to be used as an inner package, the can must have a screwed enclosure.


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 5 of 10Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.NOTE:• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity.OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear amber alkaline liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Corrosive.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) >100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not Availab leDecomposition Temp (°C) Not Available pH (as supplied) 13.4Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa ) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.20Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not Availablecontinued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 6 of 10Section 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Accidental ingestion of the material may be damaging to the health of the individual.Sulfonamides and their derivatives can cause extensive kidney damage, and destroy red blood cells. Overdose may cause anaccumulation of acid in the blood or a diminished blood sugar level with confusion and coma resulting. Predisposed persons candevelop hypersensitivity reactions, including for topical application. Deaths have occurred due to hypersensitivity, anaemia,imbalances in blood cell distribution and kidney and liver damage. 2-5 grams can be fatal. Sulfonamides cross the placentalbarrier, are excreted in the breast milk and may produce adverse effects in the foetus/embryo and newborn, including loss ofcertain white blood cells causing immune function deficiency, anaemia, jaundice and kernicterus.EYE■ If applied to the eyes, this material causes severe eye damage.Eye drops with sulfonamides can cause local irritation, sensations of burning and stinging, blurred vision and loss of depthperception. The conjunctiva and cornea may become inflamed, and the cornea and lens may become clouded.SKIN■ This material can cause inflammation of the skin oncontact in some persons.The material may accentuate any pre-existing dermatitis condition.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.INHALED■ The material is not thought to produce either adverse health effects or irritation of the respiratory tract followinginhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been producedfollowing exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimumand that suitable control measures be used in an occupational setting.Not normally a hazard due to non-volatile nature of product.CHRONIC HEALTH EFFECTS■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared tothe general population.Prolonged oral treatment with sulfonamides has caused nausea, vomiting, diarrhoea, abdominal pain, loss of appetite, inflammationof the mouth cavity, impaired folic acid absorption, exacerbation of porphyria, acidosis, liver damage with impaired bloodclotting, jaundice and inflammation of the pancreas. Effects on the kidney include blood and crystals in the urine, painful andfrequent urination or lack of urine with nitrogen retention. Nervous system symptoms include headache, drowsiness, troublesleeping, dizziness, ringing in the ears, hearing loss, depression, hallucinations, inco-ordination, paralysis of muscles,numbness in the extremities, spinal cord damage and inflammation, convulsions and unconsciousness. Effects on the blood include achange in blood cell distribution with loss of white blood cells and platelets, and anaemia, which Africans seem to be more proneto developing than Europeans. Cyanosis can occur owing to complexes being formed by haemoglobin. Eye effects include inflamedcornea and conjunctiva with eyelid swelling and in severe cases, fear of the light. Allergies and cross-sensitivity is common,and can cause itches, wheals and sometimes a severe red rash with blisters that is often fatal. This class of drugs can scar thecornea and conjunctiva, cause swelling around the eyes, painful and inflamed joints, reduced sperm counts, pneumonia, fever,chills, hair loss, inflammation of vessels, lupus, reduced lung function, infertility, hypothyroidism and goitre, and increasedurinary output. More seriously, the lungs may become permanently scarred and there may be irreversible damage to the nervoussystem and muscles. Inflammation of the skin has occurred after the drug is ingested and has travelled through the bloodstream.Skin effects often occur when there has been exposure in conjunction with UV light. Clothed areas are initially less likely to beaffected but may be in later stages. Rarely there may be persistence of inflammation on light contact even after the drug hasbeen removed.Repeated exposure to hydroxylamine and derivatives may result in respiratory sensitisation with asthma-like symptoms.continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 7 of 10Section 11 - TOXICOLOGICAL INFORMATIONTOXICITY AND IRRITATION■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesisof contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simplydetermined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it areequally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one withstronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances arenoteworthy if they produce an allergic test reaction in more than 1% of the persons tested.No significant acute toxicological data identified in literature search.Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels ofhighly irritating compound.Section 12 - ECOLOGICAL INFORMATIONToxic to soil organisms.This material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilpotassium carbonate No Data No DataAvailableAvailableEDTA tetrapotassium salt No Data No DataAvailableAvailabledisodium N, N- No Data No Databis(sulfonatoethyl)hydroxylamine Available AvailableN- [2- (4- amino- N- ethyl- m- HIGH No Data LOW MEDtoluidino)ethyl]methanesulfonamiAvailabledepotassium sulfate No Data No DataAvailableAvailablesodium hydroxide LOW No Data LOW HIGHAvailablepotassium hydroxide No Data No Data LOWAvailableAvailableSection 13 - DISPOSAL CONSIDERATIONS• Containers may still present a chemical hazard/ danger when empty.• Return to supplier for reuse/ recycling if possible.Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to lawsoperating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.• Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation followed by: burial in a landfillspecifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (afteradmixture with suitable combustible material)• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 8 of 10Section 14 - TRANSPORTATION INFORMATIONLabels Required: CORROSIVEHAZCHEM:2R (ADG7)ADG7:Class or Division: 8 Subsidiary Risk: NoneUN No.: 1719 Packing Group: IIISpecial Provision: 223 274 Limited Quantity: 5 LPortable Tanks & Bulk T7 Portable Tanks & Bulk TP1 TP28Containers -Containers - SpecialInstruction:Provision:Packagings & IBCs - None Packagings & IBCs - P001 IBC03Packing Instruction:Special PackingProvision:Name and Description: CAUSTIC ALKALI LIQUID, N.O.S. (contains sodiumhydroxide and potassium hydroxide)Land Transport UNDG:Class or division: 8 Subsidiary risk: NoneUN No.: 1719 UN packing group: IIIShipping Name:CAUSTIC ALKALI LIQUID, N.O.S. (contains sodium hydroxideand potassium hydroxide)Air Transport IATA:ICAO/IATA Class: 8 ICAO/IATA Subrisk: NoneUN/ID Number: 1719 Packing Group: IIISpecial provisions:A3Shipping name:CAUSTIC ALKALI LIQUID, N.O.S.(contains sodium hydroxide and potassium hydroxide)Maritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: NoneUN Number: 1719 Packing Group: IIIEMS Number: F- A, S- B Special provisions: 223 274Limited Quantities:5 LShipping name:CAUSTIC ALKALI LIQUID, N.O.S.(contains sodium hydroxide and potassium hydroxide)POISONS SCHEDULE S5REGULATIONSRegulations for ingredientsSection 15 - REGULATORY INFORMATIONpotassium carbonate (CAS: 584-08-7,6381-79-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD List of High Production Volume(HPV) Chemicals"EDTA tetrapotassium salt (CAS: 5964-35-2) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Schedule 4","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution –United Kingdom"disodium N,N-bis(sulfonatoethyl)hydroxylamine (CAS: 133986-51-3) is found on the followingregulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory"continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 9 of 10Section 15 - REGULATORY INFORMATIONN-[2-(4-amino-N-ethyl-m-toluidino)ethyl]methanesulfonamide (CAS: 92-09-1) is found on thefollowing regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Schedule 4"potassium sulfate (CAS: 7778-80-5) is found on the following regulatory lists;"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic watersupply - inorganic chemicals)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambientenvironmental standards (STOCK - inorganic chemicals)","Australia - Australian Capital Territory - Environment ProtectionRegulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)","Australia -Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm(STOCK)","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines andPoisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - AppendixF (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard forthe Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) -Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD List of High ProductionVolume (HPV) Chemicals","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not beenestablished"sodium hydroxide (CAS: 1310-73-2,12200-64-5) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Illicit Drug Reagents/Essential Chemicals - Category III","Australia Inventory ofChemical Substances (AICS)","Australia Quarantine and Inspection Service List of chemical compounds that are accepted solely foruse at establishments registered to prepare meat and meat products for the purpose of the Export Control Act 1982","AustraliaStandard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Schedulingof Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for FoodAdditives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","International Fragrance Association (IFRA) Survey: Transparency List","OECD List of High Production Volume (HPV) Chemicals","United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted orNot Approved by Governments"potassium hydroxide (CAS: 1310-58-3) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD List of High Production Volume(HPV) Chemicals"water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECDList of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"No data for Fujifilm CP-49E P1 Part A SUC (CW: 3826981)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesN- [2- (4- amino- N- ethyl- m- 92- 09- 1 Xn; R22 R43 N;toluidino)ethyl]methanesulfonamide R50/53INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCASpotassium carbonate 584- 08- 7, 6381- 79- 9sodium hydroxide 1310- 73- 2, 12200- 64- 5■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.continued...


FUJIFILM CP-49E P1 PART A SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 38269819317SP(cs)Version No:2.0CD 2012/1 Page 10 of 10Section 16 - OTHER INFORMATIONIssue Date: 15-Mar-2012Print Date: 15-Mar-2012This is the end of the MSDS.


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 1 of 7Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM CP-49E P1 PART B SUCSYNONYMS"Product Code: 61336 850106 / 750107"PRODUCT USEFor processing photographic colour paper. Part 2 of a 2 part system.SUPPLIERCompany: FujiFilm Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW,AustraliaTelephone: +61 2 9466 2600Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISKRisk CodesRisk PhrasesR36/38 • Irritating to eyes and skin.R66• Repeated exposure may cause skin dryness and cracking.SAFETYSafety CodesS23S24S25S37S39S40S26Safety Phrases• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable gloves.• Wear eye/face protection.• To clean the floor and all objects contaminated by this material, use water.• In case of contact with eyes, rinse with plenty of water and contact Doctor orcontinued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 2 of 7Section 2 - HAZARDS IDENTIFICATIONS46S63Poisons Information Centre.• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label).• In case of accident by inhalation: remove casualty to fresh air and keep atrest.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %potassium chloride 7447-40-7 7-15potassium carbonate 584-08-7 5-10sodium bicarbonate 144-55-8 1-5disodium N, N- bis(sulfonatoethyl)hydroxylamine 133986-51-3 1-5diethylenetriaminepentaacetic acid 67-43-6 1-5water 7732-18-5 60-80Section 4 - FIRST AID MEASURESSWALLOWED• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally liftingthe upper and lower lids.• Seek medical attention without delay; if pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear.• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.INHALED• If fumes, aerosols or combustion products are inhaled remove from contaminated area.• Other measures are usually unnecessary.NOTES TO PHYSICIAN■ Treat symptomatically.Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing mediawhich may be used. Choice of extinguishing media should take into account surrounding areas.Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may producefloating layers of combustible substances.In such an event consider:• foam.FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves for fire only.• Prevent, by any means available, spillage from entering drains or water courses.• Use fire fighting procedures suitable for surrounding area.continued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 3 of 7Section 5 - FIRE FIGHTING MEASURESFIRE/EXPLOSION HAZARD• Non combustible.• Not considered a significant fire risk, however containers may burn.Decomposition may produce toxic fumes of: carbon dioxide (CO2), hydrogen chloride, phosgene, nitrogen oxides (NOx), otherpyrolysis products typical of burning organic material.May emit poisonous fumes.May emit corrosive fumes.FIRE INCOMPATIBILITY■ None known.HAZCHEMNoneSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS■ Moderate hazard.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.SUITABLE CONTAINER• Polyethylene or polypropylene container.• Packing as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY■ None known.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• potassium chloride: CAS:7447- 40- 7• potassium carbonate: CAS:584- 08- 7 CAS:6381- 79- 9• sodium bicarbonate: CAS:144- 55- 8• disodium N, N- bis(sulfonatoethyl)hydroxylamine: CAS:133986- 51- 3• diethylenetriaminepentaacetic acid: CAS:67- 43- 6continued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 4 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION• water: CAS:7732- 18- 5MATERIAL DATADIETHYLENETRIAMINEPENTAACETIC ACID:DISODIUM N,N-BIS(SULFONATOETHYL)HYDROXYLAMINE:POTASSIUM CARBONATE:POTASSIUM CHLORIDE:SODIUM BICARBONATE:■ It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which thereis evidence of health effects at airborne concentrations encountered in the workplace.At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animalexperiments or clinical experience).NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.DIETHYLENETRIAMINEPENTAACETIC ACID:FUJIFILM CP-49E P1 PART B SUC:POTASSIUM CARBONATE:SODIUM BICARBONATE:■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat.Historically occupational exposure standards for these irritants have been based on observation of workers' responses to variousairborne concentrations.WATER:■ No exposure limits set by NOHSC or ACGIH.PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity.OTHER• Overalls.• P.V.C. apron.• Barrier cream.• Skin cleansing cream.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.continued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 5 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONSection 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear colourless liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) >100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not Availab leDecomposition Temp (°C) Not Available pH (as supplied) 9.4Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa ) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.19Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Applicable(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not AvailableSection 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Accidental ingestion of the material may be damaging to the health of the individual.EYE■ This material can cause eye irritation and damage in some persons.SKIN■ This material can cause inflammation of the skin oncontact in some persons.The material may accentuate any pre-existing dermatitis condition.Repeated exposure may cause skin cracking, flaking or drying following normal handling and use.Irritation and skin reactions are possible with sensitive skin.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.INHALED■ The material is not thought to produce either adverse health effects or irritation of the respiratory tract followinginhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been producedfollowing exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimumand that suitable control measures be used in an occupational setting.Not normally a hazard due to non-volatile nature of product.CHRONIC HEALTH EFFECTS■ Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitis following.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared tothe general population.There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment.Repeated exposure to hydroxylamine and derivatives may result in respiratory sensitisation with asthma-like symptoms.continued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 6 of 7Section 11 - TOXICOLOGICAL INFORMATIONTOXICITY AND IRRITATION■ No significant acute toxicological data identified in literature search.No dataSection 12 - ECOLOGICAL INFORMATIONEcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilpotassium chloride HIGH No Data LOW HIGHAvailablepotassium carbonate No Data No DataAvailableAvailablesodium bicarbonate LOW No Data LOW HIGHAvailabledisodium N, N- No Data No Databis(sulfonatoethyl)hydroxylamine Available Availablediethylenetriaminepentaacetic LOW No Data LOW LOWacidAvailableSection 13 - DISPOSAL CONSIDERATIONS■ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer tolaws operating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration ina licenced apparatus (after admixture with suitable combustible material).• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:None (ADG7)NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDGSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientspotassium chloride (CAS: 7447-40-7) is found on the following regulatory lists;"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic watersupply - inorganic chemicals)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambientenvironmental standards (STOCK - inorganic chemicals)","Australia - Australian Capital Territory - Environment ProtectionRegulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)","Australia -continued...


FUJIFILM CP-49E P1 PART B SUCChemwatch Independent Material Safety Data SheetIssue Date: 15-Mar-2012 CHEMWATCH 6621-019317SP(cs)Version No:2.0CD 2012/1 Page 7 of 7Section 15 - REGULATORY INFORMATIONAustralian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm(IRRIG)","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken tocause environmental harm (STOCK)","Australia - Victoria Drugs, Poisons and Controlled Substances (Precursor Chemicals) Regs 2007 -Schedule 1 - Precursor Chemicals and Quantities","Australia Inventory of Chemical Substances (AICS)","Australia NationalPollutant Inventory","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","CODEX General Standard for FoodAdditives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD Listof High Production Volume (HPV) Chemicals","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values havenot been established"potassium carbonate (CAS: 584-08-7,6381-79-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD List of High Production Volume(HPV) Chemicals"sodium bicarbonate (CAS: 144-55-8) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","International Fragrance Association(IFRA) Survey: Transparency List","OECD List of High Production Volume (HPV) Chemicals"disodium N,N-bis(sulfonatoethyl)hydroxylamine (CAS: 133986-51-3) is found on the followingregulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory"diethylenetriaminepentaacetic acid (CAS: 67-43-6) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","OSPAR National List of Candidatesfor Substitution – United Kingdom"water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECDList of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"No data for Fujifilm CP-49E P1 Part B SUC (CW: 6621-01)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesdiethylenetriaminepentaacetic acid 67- 43- 6 Xn; R22 Xi; R38INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCASpotassium carbonate 584- 08- 7, 6381- 79- 9■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 15-Mar-2012Print Date: 15-Mar-2012This is the end of the MSDS.

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