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6148 Ethylene - Total Refining & Chemicals

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Material Safety Data SheetSection 1. Chemical Product and Company IdentificationProduct nameSupplierChemical Family OlefinicCAS RegistryNumberSynonym<strong>Ethylene</strong><strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.P O Box 674411Houston,TX 77267-441174-85-1<strong>Ethylene</strong>, EtheneIn Case ofEmergencyTechnicalInformationMSDS#ValidationDatePrint DateChemtrec:(800) 424-9300<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.:(800) 322-3462For non-emergency product information:email product.stewardship@total.comBC00041/1/20141/1/2014Section 2. Hazards IdentificationEmergency OverviewFLAMMABLE GAS. MAY CAUSE FLASH FIRE.CONTENTS UNDER PRESSURE.POTENTIAL SUFFOCATION GAS REDUCES OXYGEN AVAILABLE FOR BREATHING.MAY CAUSE EYE IRRITATION.Routes of EntryEye contact. Inhalation. Skin contact.Potential Acute Health EffectsEyes Liquid: freezing burns from direct contact with liquid. May cause eye irritation.Potential Chronic HealthEffectsMedical ConditionsAggravated byOverexposureOverexposure /Signs/SymptomsInhalationSkin Non-permeator by skin. Liquid: Frostbite, freezing burns from direct contact with liquid.Aspyxia from lack of oxygen. Moderate concentrations may cause headache, drowsiness,dizziness, and excitation. At high concentrations, loss of consciousness.Ingestion An unlikely route of exposure.See Toxicological Information (Section 11)CARCINOGENIC EFFECTS: Not listed as a carcinogen by OSHA, NTP or IARC.Pre-existing disorders involving any target organs mentioned in this MSDS as being at riskmay be aggravated by over-exposure to this product.Typical route of exposure is expected to be by inhalation. Inhalation of minor amounts is notexpected to cause symptoms. Significant inhalation may cause symptoms similar to oxygendeprivation.Section 3. Composition and Information on IngredientsOccupational exposure limits, if available, are listed in Section 8.Substance NameCAS #% by Weight<strong>Ethylene</strong> 74-85-1 ~100Section 4. First Aid MeasuresEye ContactSkin ContactInhalationIMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open.COLD water may be used.Remove affected clothing. In case of frostbite, flush with warm water. Get medical attention.Do not use hot water!If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention immediately.<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 2/7IngestionSection 5. Fire Fighting MeasuresFlammability of theProductAuto-ignitionTemperatureFlash Points_Since the product is a gas and that it is mostly probable that it will be inhaled morethan ingested, please consider first to look at the preventive measures in case ofinhalation.Flammable.450°C (842°F)CLOSED CUP: -136.11°C (-213°F). (Tagliabue.).Flammable LimitsProducts of CombustionFire Hazards in Presenceof Various SubstancesExplosion Hazards inPresence of VariousSubstancesFire Fighting Mediaand InstructionsProtective Clothing (Fire)Special Remarks onExplosion HazardsLower: 2.3%Upper: 36%These products are carbon oxides (CO, CO2).Extremely flammable in presence of open flames and sparks, heat, or static. Protectcontainers from physical damage and static discharge.Risks of explosion of the product in presence of static discharge: Expected.Risks of explosion of the product in presence of mechanical impact: Not expected.Flammable gas.SMALL FIRE: Use DRY chemicals, CO2, alcohol foam or water spray.LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Move containingvessels from fire area if without risk. Cool containing vessels with flooding quantities of wateruntil well after fire is out. Cool containing vessels with water jet in order to prevent pressurebuild-up, autoignition or explosion. DO NOT extinguish a leaking gas flame unless leak canbe stopped. Extinguish secondary fire. Handle damaged cylinders with extreme care.Wear MSHA/NIOSH approved self-contained breathing apparatus or equivalent and fullprotective gear.Forms explosive mixtures with air. Container may explode in fire. Flashback along vapor trailmay occur. May explode if ignited in an enclosed area.Section 6. Accidental Release MeasuresSmall Spill and LeakLarge Spill and LeakSection 7. Handling and StorageHandlingStorageWarn personnel to move away. Try to stop the gaseous leak by taping the container with anappropriate material (tape, stretched plastic). Shut off all ignition sources: No flares, flamesor smoking in hazard area. Use water spray to reduce vapors. Isolate area until gas isdispersed.Flammable gas. Isolate area until gas has dispersed. Warn personnel to move away. Letevaporate. If possible, turn leaking container so that gas escapes rather than liquid. Do notdirect water at spill or source. Use water spray curtain to divert vapor drift. Prevent entry intosewers, basements or confined areas. Eliminate all ignition sources.Keep away from heat. Keep away from sources of ignition. In case of insufficient ventilation,wear suitable respiratory equipment. Keep container tightly closed and in a well-ventilatedplace. Keep away from incompatibles such as oxidizing agents, acids. Ground allequipment containing material. Take precautionary measures against electrostatic discharges.Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed untilready for use. Segregate from oxidizing materials. Avoid all possible sources of ignition(spark or flame). Take precautionary measures against static discharges. Ground allequipment containing material.Storage facilities for bulk quantities of light hydrocarbons, like ethylene, are highly specialized.Qualified engineering firms should be employed for the design and construction.<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 3/7Section 8. Exposure Controls/Personal Protection_Engineering ControlsUse process enclosures, local exhaust ventilation or other engineering controls to keepworker exposure to airborne contaminants below any recommended or statutory limits.Personal ProtectionProtective Clothing(Pictograms)Eyes Safety glasses with side shields. When handling liquid ethylene, a face shield isrecommended.Body Flame retardant clothing (FRC) required.Respiratory Use appropriate respiratory protection if there is a risk of exceeding any exposure limits.Hands If a liquid, then chemical resistant thermal insulating gloves are recommended.Feet Shoes.Personal Protection inCase of a Large SpillProduct NameSplash goggles. Full suit. Boots. Chemical resistant thermal insulating gloves. Suggestedprotective clothing might not be sufficient; consult a specialist BEFORE handling this product.Be sure to use a MSHA/NIOSH approved respirator or equivalent at high concentrations.Exposure Limits<strong>Ethylene</strong> ACGIH TLV (United States, 2011).TWA: 200 ppm 8 hour(s).Consult local authorities for acceptable exposure limits.Section 9. Physical and Chemical PropertiesPhysical State and AppearanceColorOdorOdor ThresholdMolecular WeightMolecular FormulaBoiling/Condensation PointMelting/Freezing PointCritical TemperatureVapor PressureVapor DensityVolatilityEvaporation RateVOCLogKowSolubility in WaterGas. (Liquid under pressure)Colorless gas with a slight sweet odorMild odor.270 ppm28.05 g/moleCH2=CH2-103.89°C (-155°F)-169°C (-272.2°F)9.6°C (49.3°F)30400 mm of Hg (@ 20°C)0.98 (Air = 1)100% (v/v).Very high.100 (%)The product is more soluble in oil; log(oil/water) = 1.8131 mg/L at 20°C<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 4/7Section 10. Stability and ReactivityStability and ReactivityConditions of InstabilityIncompatibility withVarious SubstancesHazardousDecomposition ProductsHazardousPolymerization_At elevated temperature (typically greater than 300° F) and pressure (typically greater than1000 psig) ethylene can decompose to carbon and methane. The reaction is exothermic,releasing heat which further fuels the decomposition. Unless steps are taken immediately tostop decomposition (depressuring, removing heat, lowering temperature), the elevatingtemperature can result in failure of the containment vessel with corresponding release ofunreacted ethylene. The higher the pressure, the lower the temperature needed to initiate thedecomposition reaction.No additional remark.Extremely reactive or incompatible with oxidizing agents, acids, halogens, chlorine, & AlCl 3.Explosive reactions may occur with carbon tetrachloride, bromotrichloromethane,chlorotrifluoroethylene, & copper. Incompatible with carbon tetrachloride + benzyl peroxide,ozone, carbon tetrachloride, bromotrichloromethane + benzyl peroxide, ozone, carbontetrachloride, bromotrichloromethane + aluminum trichloride, oxides of nitrogen, &tetrafluoroethylene.carbon monoxide & carbon dioxideMay occur.Section 11. Toxicological InformationToxicity to AnimalsProduct/ingredient name Result Species Dose Exposure<strong>Ethylene</strong> LC50 Inhalation Vapor Mouse 95 ppm 2 hChronic Effects onHumansOther Toxic Effects onHumansSpecial Remarks onToxicity to AnimalsCARCINOGENIC EFFECTS: Not listed as a carcinogen by OSHA, NTP or IARC.Acts as a simple asphyxiant. Vapors may cause drowsiness and dizziness.Based on animal studies, inhalation may cause nasal effects even at low concentrations.Section 12. Ecological InformationEcotoxicityBiodegradable/OECDMobilityNot available.Section 13. Disposal ConsiderationsWaste InformationWaste StreamConsult your local or regional authorities.Biodegradation, hydrolysis, bioconcentration, and adsorption are not major processes forethylene. Pure culture studies suggest that ethylene could be susceptible to microbialdegradation.<strong>Ethylene</strong> (gas) is degraded by ozone (half-life of 6.5 days), nitrate radicals (half-life of 190days), or photochemically produced hydroxyl radicals (est. half-life of 1.9 days). <strong>Ethylene</strong> mayoxidize to ethylene oxide in soil and water. Gas may permeate through soil and sediment dueto its high vapor pressure. Volatilization is the major environmental process in soil and water.Volatilization half-lives from a model river and a model environmental lake have beenestimated to be 1.6 and 50 hr respectivley.Fugitive emissions of ethylene are the most common form industrial release. Equipmentshould be regularly monitored for these emissions and corrective actions taken if found.Dispose of according to all federal, state and local applicable regulations.The classification of the product may meet the criteria for a hazardous waste.<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 5/7_Section 14. Transport Information(for domestic bulk shipments, non-bulk shipments may differ)DOT Classification forBulk Shipments (non bulkshipments may differ)Proper Shipping Name/DescriptionUN NumberDOT CLASS 2.1: Flammable gas.If shipped as a compressed gas: UN1962, <strong>Ethylene</strong>, 2.1If shipped as a refrigerated liquid: UN1038, <strong>Ethylene</strong> Refrigerated Liquid, 2.1UN1962orPacking GroupMarine PollutantUN1038Not applicable (gas).Not listed in Appendix B to 49CFR172.101Hazardous SubstancesReportable QuantitySpecial Provisions forTransportTDG ClassificationIMO/IMDG ClassificationNot listed in Appendix A to 49CFR172.101See codes as shown in 49 CFR 172.101 column 7.TDG CLASS 2.1: Flammable gas.IMDG CLASS 2.1: Flammable gas.ICAO/IATA ClassificationUSCG Proper ShippingNameIATA CLASS 2.1: Flammable gas.NOTE: Transportation is prohibited on passenger aircraft.Transportation of ethylene as a refrigerated liquid is prohibited on passenger or cargo aircraft.<strong>Ethylene</strong>Section 15. Regulatory InformationHCS ClassificationU.S. Federal RegulationsFlammable gasCompressed gasTarget organ effectsUnited States inventory (TSCA 8b): This material is listed or exempted.International RegulationsSARA 302/304/311/312 extremely hazardous substances: To the best of our knowledge,there are no substances that would be at reportable levels for this regulation in this product.SARA 302/304 emergency planning and notification: To the best of our knowledge, thereare no substances that would be at reportable levels for this regulation in this product.SARA 302/304/311/312 hazardous chemicals: <strong>Ethylene</strong>SARA 311/312 MSDS distribution - chemical inventory - hazard identification: <strong>Ethylene</strong>:Fire hazard, reactive, Sudden release of pressure, Immediate (acute) health hazardSARA 313 Supplier NotificationThis product contains the following EPCRA section 313 chemicals subject to the reportingrequirements of section 313 of the Emergency Planning and Community Right-to-Know Actof 1986 (40 CFR 372 -Table 372.65).Product name CAS number Concentration (%)<strong>Ethylene</strong> 74-85-1 ~100Clean Air Act (CAA) 112 accidental release prevention: <strong>Ethylene</strong>Clean Air Act (CAA) 112 regulated flammable substances: <strong>Ethylene</strong>WHMIS (Canada) Class A: Compressed gas.Class B-1: Flammable gas.Class D-2B: Material causing other toxic effects (Toxic).<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 6/7_CEPA Toxic substances: To the best of our knowledge, this product does not contain listedsubstances at reportable levels.Canadian ARET: To the best of our knowledge, this product does not contain listedsubstances at reportable levels.Canadian NPRI: This material is listed.Alberta Designated Substances: To the best of our knowledge, this product does not containlisted substances at reportable levels.Ontario Designated Substances: To the best of our knowledge, this product does notcontain listed substances at reportable levels.Quebec Designated Substances: To the best of our knowledge, this product does notcontain listed substances at reportable levels.EINECS200-815-3DSCL (EEC)CEPA DSL/NDSLInternational ListsState RegulationsSection 16. Other InformationLabel requirementsR12- Extremely flammable.R67- Vapors may cause drowsiness and dizziness.This material is listed or exempted.Australia inventory (AICS): This material is listed or exempted.China inventory (IECSC): This material is listed or exempted.Japan inventory (ENCS): This material is listed or exempted.Japan inventory (ISHL): Not determined.Korea inventory (KECI): This material is listed or exempted.New Zealand Inventory of <strong>Chemicals</strong> (NZIoC): This material is listed or exempted.Philippines inventory (PICCS): This material is listed or exempted.Massachusetts Substances: This material is listed.New Jersey Hazardous Substances: This material is listed.Pennsylvania RTK Hazardous Substances: This material is listed.California Proposition 65: To the best of our knowledge, there are no Proposition 65 chemicalspresent in this product at levels that would require warning under the California Safe DrinkingWater and Toxic Enforcement Act.FLAMMABLE GAS. MAY CAUSE FLASH FIRE.CONTENTS UNDER PRESSURE.POTENTIAL SUFFOCATION GAS REDUCES OXYGEN AVAILABLE FOR BREATHING.MAY CAUSE EYE IRRITATION.Hazardous MaterialInformation System(U.S.A.)HealthFire HazardReactivityPersonal Protection242jNational FireProtectionAssociation(U.S.A.)Health242Fire HazardReactivitySpecific HazardReferencesHazardous Substance Database Chemtox DatabaseValidated on 1/1/2014.Printed 1/1/2014.Chemtrec:(800) 424-9300<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.:(800) 322-3462Notice to Reader<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.


<strong>Ethylene</strong> Page: 7/7_The information contained in this Material Safety Data Sheet (MSDS) / Safety Data Sheet (SDS) is believed by <strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.(TPRI) to be accurate on the date issued. However, materials may present unknown hazards and should be used with caution. Final determination ofsuitability and use of any material is the sole responsibility of the user. Neither TPRI nor any of its subsidiaries or affiliated companies assumes any liabilitywhatsoever for the accuracy or completeness of the information contained herein or reliance thereto. If the material is repackaged, the user is responsible andmust ensure that proper health, safety and other necessary information is included with the material and/or on the container. NO WARRANTIES OF ANYKIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,ARE MADE REGARDING THE MATERIALS OR THE INFORMATION CONTAINED IN THIS SDS. ALTERATION OF THIS DOCUMENT ISSTRICTLY PROHIBITED.MSDS Name <strong>Ethylene</strong> MSDS Code ETHYLENE_PG24To obtain an electronic copy of this MSDS, please email: product.stewardship@total.com.<strong>Total</strong> Petrochemicals & <strong>Refining</strong> USA, Inc.

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