Chemwatch MSDS Print - FUJIFILM Australia

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Chemwatch MSDS Print - FUJIFILM Australia

FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 1 of 8Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***PRODUCT USEScreen printing additive.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AUSTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4POISONS SCHEDULENoneRISKSAFETY¦ Harmful in contact with skin. ¦ Do not breathe gas/ fumes/ vapour/ spray.¦ Irritating to eyes respiratory system and ¦ Avoid contact with eyes.skin.¦ Limited evidence of a carcinogenic effect. ¦ Wear suitable protective clothing.¦ May cause SENSITISATION by skin contact. ¦ To clean the floor and all objects contaminatedby this material use water and detergent.¦ Toxic to aquatic organisms may cause long- ¦ This material and its container must be disposedterm adverse effects in the aquaticof in a safe way.environment.¦ Cumulative effects may result following ¦ Keep away from food drink and animal feedingexposure*.stuffs.¦ Possible respiratory sensitiser*. ¦ In case of contact with eyes rinse with plentyof water and contact Doctor or Poisons InformationCentre.continued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 2 of 8Section 2 - HAZARDS IDENTIFICATION* (limited evidence). ¦ If swallowed IMMEDIATELY contact Doctor orPoisons Information Centre (show this container orlabel).¦ Use appropriate container to avoid environmentcontamination.¦ Avoid release to the environment. Refer tospecial instructions/ safety data sheets.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %iso- decyl acrylate 1330-61-6 >60ethylene glycol phenyl ether acrylate 48145-04-6 10-30tripropylene glycol diacrylate 42978-66-5 1-10UV stabiliser


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 3 of 8Section 5 - FIRE FIGHTING MEASURES• Heating may cause expansion or decomposition leading to violent rupture of containers.• On combustion, may emit toxic fumes of carbon monoxide (CO).• May emit acrid smoke.• Mists containing combustible materials may be explosive.May emit clouds of acrid smoke.May emit poisonous fumes.FIRE INCOMPATIBILITY¦ Avoid contamination with strong oxidising agents as ignition may result.HAZCHEMNonePERSONAL PROTECTIONGlasses: Gloves: Respirator:Chemical goggles. PVC chemical resistant type. Type A- P Filter of sufficient capacitySection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.• Wipe up.• Place in a suitable, labelled container for waste disposal.MAJOR SPILLS¦ Moderate hazard.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.• No smoking, naked lights or ignition sources.• Increase ventilation.• Stop leak if safe to do so.• Contain spill with sand, earth or vermiculite.• Collect recoverable product into labelled containers for recycling.• Absorb remaining product with sand, earth or vermiculite.• Collect solid residues and seal in labelled drums for disposal.• Wash area and prevent runoff into drains.• If contamination of drains or waterways occurs, advise emergency services.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• Handle and open container with care.• Limit all unnecessary personal contact.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with incompatible materials.• When handling, DO NOT eat, drink or smoke.• Keep containers securely sealed when not in use.• Avoid physical damage to containers.• Always wash hands with soap and water after handling.• Work clothes should be laundered separately.• Use good occupational work practice.• Observe manufacturer's storing and handling recommendations.• Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.SUITABLE CONTAINER• Metal can or drum• Packaging as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY¦ Segregate from strong acids, peroxides, strong alkalis, ammonia, amines, oxidisers and strong oxidisers.continued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 4 of 8Section 7 - HANDLING AND STORAGESTORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• No smoking, naked lights or ignition sources.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.• Protect containers against physical damage and check regularly for leaks.• Observe manufacturer's storing and handling recommendations.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• iso- decyl acrylate: CAS:1330- 61- 6• ethylene glycol phenyl ether acrylate: CAS:48145- 04- 6• tripropylene glycol diacrylate: CAS:42978- 66- 5 CAS:68901- 05- 3PERSONAL PROTECTIONRESPIRATORType A-P Filter of sufficient capacityEYE• Safety glasses with side shields; or as required,• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing thewearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption andadsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in theirremoval and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contactlens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environmentonly after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].HANDS/FEET• Barrier cream and • Polyethylene gloves.Wear chemical protective gloves, eg. PVC.Wear safety footwear.OTHER• Overalls.• Eyewash unit.Ensure there is ready access to an emergency shower.ENGINEERING CONTROLS¦ Use in a well-ventilated area.General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk ofoverexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse orclosed storage areas. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capturevelocities" of fresh circulating air required to effectively remove the contaminant.Type of Contaminant:solvent, vapours, degreasing etc., evaporatingfrom tank (in still air).aerosols, fumes from pouring operations,intermittent container filling, low speedconveyer transfers, welding, spray drift,plating acid fumes, pickling (released at lowvelocity into zone of active generation)direct spray, spray painting in shallow booths,drum filling, conveyer loading, crusher dusts,gas discharge (active generation into zone ofrapid air motion)grinding, abrasive blasting, tumbling, highspeed wheel generated dusts (released at highinitial velocity into zone of very high rapidair motion).Air Speed:0.25- 0.5 m/s (50- 100 f/min)0.5- 1 m/s (100- 200 f/min.)1- 2.5 m/s (200- 500 f/min.)2.5- 10 m/s (500- 2000 f/min.)continued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 5 of 8Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONWithin each range the appropriate value depends on:Lower end of the rangeUpper end of the range1: Room air currents minimal or favourable to 1: Disturbing room air currentscapture2: Contaminants of low toxicity or of nuisance 2: Contaminants of high toxicityvalue only.3: Intermittent, low production. 3: High production, heavy use4: Large hood or large air mass in motion 4: Small hood- local control onlySimple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreaseswith the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations,producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 ormore when extraction systems are installed or used.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEColoured liquid with a characteristic odour; does not mix with water.PHYSICAL PROPERTIESLiquid.Does not mix with water.State Liquid Molecular Weight Not applicableMelting Range (°C) Not available Viscosity Not availableBoiling Range (°C) Not available Solubility in water (g/L) ImmiscibleFlash Point (°C) Not available pH (1% solution) Not applicableDecomposition Temp (°C) Not available pH (as supplied) Not applicableAutoignition Temp (°C) Not available Vapour Pressure (kPa) Not availableUpper Explosive Limit (%) Not available Specific Gravity (water=1) Not availableLower Explosive Limit (%) Not available Relative Vapour Density Not available(air=1)Volatile Component (%vol) Not available Evaporation Rate Not availableSection 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATIONCONDITIONS CONTRIBUTING TO INSTABILITY• Polymerisation may occur at elevated temperatures and in the presence of ignition sources.• Stable under controlled storage conditions provided material contains adequate stabiliser / polymerisation inhibitor.• Bulk storages may have special storage requirements• WARNING: Gradual decomposition in strong, sealed containers may lead to a large pressure build-up and subsequent explosion. Rapid and violentpolymerisation possible at temperatures above 32 deg c.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSCHRONIC HEALTH EFFECTS¦ Harmful in contact with skin. ¦ May cause SENSITISATION by skin contact.¦ Irritating to eyes, respiratory system and ¦ Limited evidence of a carcinogenic effect.skin.¦ Can be absorbed through skin. ¦ Possible respiratory sensitiser*.¦ Cumulative effects may result followingexposure*.¦ * (limited evidence).TOXICITY AND IRRITATIONETHYLENE GLYCOL PHENYL ETHER ACRYLATE:TRIPROPYLENE GLYCOL DIACRYLATE:ISO-DECYL ACRYLATE:¦ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.¦ Based on the available oncogenicity data and without a better understanding of the carcinogenic mechanism the Health and Environmental ReviewDivision (HERD), Office of Toxic Substances (OTS), of the US EPA previously concluded that all chemicals that contain the acrylate or methacrylatemoiety (CH2=CHCOO or CH2=C(CH3)COO) should be considered to be a carcinogenic hazard unless shown otherwise by adequate testing.continued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 6 of 8Section 11 - TOXICOLOGICAL INFORMATIONThis position has now been revised and acrylates and methacrylates are no longer de facto carcinogens.¦ Where no "official" classification for acrylates and methacrylates exists, there has been cautious attempts to create classifications in theabsence of contrary evidence. For exampleMonalkyl or monoarylesters of acrylic acids should be classified as R36/37/38 and R51/53Monoalkyl or monoaryl esters of methacrylic acid should be classified as R36/37/38.¦ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic conditionknown as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteriafor the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthmalikesymptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence ofmoderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder withrates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorderthat occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible afterexposure ceases. The disorder is characterised by dyspnea, cough and mucus production.ETHYLENE GLYCOL PHENYL ETHER ACRYLATE:ISO-DECYL ACRYLATE:¦ The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin.¦ Not available. Refer to individual constituents.ISO-DECYL ACRYLATE:TOXICITYOral (rat) LD50: 12000 mg/kgDermal (rat) LD50: 3540 mg/kgIRRITATIONSkin (rabbit): 500 mg(open)- MildETHYLENE GLYCOL PHENYL ETHER ACRYLATE:TOXICITYOral (rat) LD50: 5190 mg/kgDermal (rabbit) LD50: 1800 mg/kgIRRITATIONSkin (rabbit):500 mg (open) MildTRIPROPYLENE GLYCOL DIACRYLATE:TOXICITYIRRITATIONOral (rat) LD50: 6200 mg/kgSkin (rabbit): 500 mg/24h ModerateDermal (rabbit) LD50: >2000 mg/kg Draize =2.5/8.0 *Intraperitoneal (Rat) LD50: 345 mg/kgEye (rabbit): 100 uL/24h SEVEREIntraperitoneal (Rabbit) LD: 275 mg/kg *[Manufacturer H]¦ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczemainvolves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibodymediatedimmune reactions. The significance of the contact allergen is not simply determined by its sensitisation potential: the distribution of thesubstance and the opportunities for contact with it are equally important. A weakly sensitising substance which is widely distributed can be a moreimportant allergen than one with stronger sensitising potential with which few individuals come into contact. From a clinical point of view,substances are noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.UV (ultraviolet)/ EB (electron beam) acrylates are generally of low toxicityUV/EB acrylates are divided into two groups; "stenomeric" and "eurymeric" acrylates.The first group consists of well-defined acrylates which can be described by a simple idealised chemical;they are low molecular weight species with avery narrow weight distribution profile.The eurymeric acrylates cannot be described by an idealised structure and may differ fundamentally between various suppliers; they are of relativelyhigh molecular weigh and possess a wide weight distribution.Stenomeric acrylates are usually more hazardous than the eurymeric substances. Stenomeric acrylates are also well defined which allows comparison andexchange of toxicity data - this allows more accurate classification.The stenomerics cannot be classified as a group; they exhibit substantial variation.The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production ofvesicles, scaling and thickening of the skin.Section 12 - ECOLOGICAL INFORMATIONToxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Avoid release to the environment.Refer to special instructions/ safety data sheets.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilcontinued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 7 of 8Section 12 - ECOLOGICAL INFORMATIONiso- decyl acrylate LOW LOW MEDethylene glycol phenyl ether LOW LOW MEDacrylatetripropylene glycol diacrylate HIGH LOW HIGHSection 13 - DISPOSAL CONSIDERATIONS• Consult manufacturer for recycling options and recycle where possible .• Consult State Land Waste Management Authority for disposal.• Incinerate residue at an approved site.• Recycle containers if possible, or dispose of in an authorised landfill.Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:None (ADG7)NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDGSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULENoneREGULATIONSRegulations for ingredientsiso-decyl acrylate (CAS: 1330-61-6) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","OECDRepresentative List of High Production Volume (HPV) Chemicals"ethylene glycol phenyl ether acrylate (CAS: 48145-04-6) is found on the following regulatorylists;"Australia Inventory of Chemical Substances (AICS)","OECD Representative List of High Production Volume (HPV) Chemicals"tripropylene glycol diacrylate (CAS: 42978-66-5,68901-05-3) is found on the followingregulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - HighProduction Volume List","OECD Representative List of High Production Volume (HPV) Chemicals"No data for Fujifilm Sericol Hiflex EY Thinner ZE-829***OBSOLETE*** (CW: 4603-95)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesethylene glycol phenyl ether acrylate 48145- 04- 6 Xn Carc3; R40 NR50tripropylene glycol diacrylate 68901- 05- 3 Xn Carc3; R40 NR50INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCAStripropylene glycol diacrylate 42978-66-5, 68901-05-3¦ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review bythe Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.¦ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazardsare Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and currentcontinued...


FUJIFILM SERICOL HIFLEX EY THINNER ZE-829***OBSOLETE***Chemwatch Independent Material Safety Data SheetIssue Date: 11-Dec-2009 CHEMWATCH 4603-95XCC317TCPVersion No:4CD 2010/1 Page 8 of 8Section 16 - OTHER INFORMATIONor available engineering controls must be considered.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 11-Dec-2009Print Date: 23-May-2010This is the end of the MSDS.

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