CPS Stencil Remover Concentrate - FUJIFILM Australia

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CPS Stencil Remover Concentrate - FUJIFILM Australia

CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 1 of 9Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMECPS Stencil Remover Concentrate 1:20/30, 1:50PROPER SHIPPING NAMECORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(contains periodic acid and sulfuric acid)PRODUCT USEStencil remover for removal of direct stencilling.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel:+61 1800 039 008Emergency Tel:+61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISK■ Harmful by inhalation.■ Causes burns.■ Risk of serious damageto eyes.SAFETY• Keep locked up.• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable protective clothing.• Wear suitable gloves.• Wear eye/face protection.• Use only in well ventilated areas.• Keep container in a well ventilated place.continued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 2 of 9Section 2 - HAZARDS IDENTIFICATION• To clean the floor and all objects contaminated by this material, usewater.• Keep container tightly closed.• Take off immediately all contaminated clothing.• In case of contact with eyes, rinse with plenty of water and contactDoctor or Poisons Information Centre.• In case of accident or if you feel unwell IMMEDIATELY contact Doctoror Poisons Information Centre (show label if possible).• This material and its container must be disposed of as hazardouswaste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %periodic acid 10450-60-9 10-30sulfuric acid 7664-93-9 1-5Section 4 - FIRST AID MEASURESSWALLOWED• For advice, contact a Poisons Information Centre or a doctor at once.• Urgent hospital treatment is likely to be needed.• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.EYE■ If this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally liftingthe upper and lower lids.• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.• Transport to hospital or doctor without delay.SKIN■ If skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safety shower if available.• Quickly remove all contaminated clothing, including footwear.• Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.• Transport to hospital, or doctor.INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary.NOTES TO PHYSICIANFor acute or short term repeated exposures to strong acids:• Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.• Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling• Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.• Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicatingaction of the acid on proteins in specific tissues.continued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 3 of 9Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA• Water spray or fog.• Foam.• Dry chemical powder.• BCF (where regulations permit).FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• Non combustible.• Not considered to be a significant fire risk.• Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.• Heating may cause expansion or decomposition leading to violent rupture of containers.Decomposition may produce toxic fumes of: sulfur oxides (SOx).FIRE INCOMPATIBILITY■ None known.HAZCHEM2XSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with moisture.SUITABLE CONTAINER• DO NOT use aluminium or galvanised containers.• Check regularly for spills and leaks.• Lined metal can, lined metal pail/ can.• Plastic pail.• Polyliner drum.• Packing as recommended by manufacturer.For low viscosity materials• Drums and jerricans must be of the non-removable head type.• Where a can is to be used as an inner package, the can must have a screwed enclosure.


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 4 of 9Section 7 - HANDLING AND STORAGESTORAGE INCOMPATIBILITY• Inorganic acids are generally soluble in water with the release of hydrogen ions. The resulting solutions have pH's of lessthan 7.0.• Inorganic acids neutralise chemical bases (for example: amines and inorganic hydroxides) to form salts - neutralisation cangenerate dangerously large amounts of heat in small spaces.• The dissolution of inorganic acids in water or the dilution of their concentrated solutions with additional water may generatesignificant heat.• The addition of water to inorganic acids often generates sufficient heat in the small region of mixing to cause some of thewater to boil explosively. The resulting "bumping" can spatter the acid.• Avoid strong bases.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSSource Material TWA TWA STEL STEL Peak Peak TWA Notesppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC__________ __________ ______ ______ ______ ______ ______ ______ ______ ______Australia (Sulphuric acid) 1 3ExposureStandardsThe following materials had no OELs on our records• periodic acid: CAS:10450- 60- 9MATERIAL DATAPERIODIC ACID:SULFURIC ACID:Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historicallyoccupational exposure standards for these irritants have been based on observation of workers' responses to various airborneconcentrations.CPS STENCIL REMOVER CONCENTRATE 1:20/30, 1:50:None assigned. Refer to individual constituents.PERIODIC ACID:It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there isevidence of health effects at airborne concentrations encountered in the workplace.At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animalexperiments or clinical experience).NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.SULFURIC ACID:NOTE: Detector tubes for sulfuric acid, measuring in excess of 1 mg/m3, are commercially available.Based on controlled inhalation studies the TLV-TWA is thought to be protective against the significant risk of pulmonaryirritation and incorporates a margin of safety so as to prevent injury to the skin and teeth seen in battery workers acclimatisedto workplace concentrations of 16 mg/m3.PERSONAL PROTECTIONRESPIRATOR•Type E-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)continued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 5 of 9Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEYE• Chemical goggles.• Full face shield may be required for supplementary but never for primary protection of eyes• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.• When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.NOTE:• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.The selection of the suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves andhas to be observed when making a final choice.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEAcidic liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Corrosive.Acid.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) 100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not AvailableDecomposition Temp (°C) Not Available pH (as supplied) 2Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.25Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not Availablecontinued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 6 of 9Section 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Contact with alkaline material liberates heat.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus. Immediate pain anddifficulties in swallowing and speaking may also be evident. Swelling of the epiglottis may make it difficult to breathe whichmay result in suffocation. More severe exposure may result in vomiting blood and thick mucus, shock, abnormally low bloodpressure, fluctuating pulse, shallow respiration and clammy skin, inflammation of stomach wall, and rupture of oesophagealtissue. Untreated shock may eventually result in kidney failure. Severe cases may result in perforation of the stomach andabdominal cavity with consequent infection, rigidity and fever. There may be severe narrowing of the oesophageal or pyloricsphincters; this may occur immediately or after a delay of weeks to years. There may be coma and convulsions, followed by deathdue to infection of the abdominal cavity, kidneys or lungs.Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs. Chronic exposure may inflame the skin orconjunctiva.EYE■ The material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.If applied to the eyes, this material causes severe eye damage.Direct eye contact with acid corrosives may produce pain, tears, sensitivity to light and burns. Mild burns of the epitheliagenerally recover rapidly and completely. Severe burns produce long-lasting and possibly irreversible damage. The appearance ofthe burn may not be apparent for several weeks after the initial contact. The cornea may ultimately become deeply opaqueresulting in blindness.SKIN■ The material can produce chemical burns following direct contactwith the skin.Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly withthe formation of scar tissue.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.INHALED■ Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may beharmful.Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage. There may bedizziness, headache, nausea and weakness. Swelling of the lungs can occur, either immediately or after a delay; symptoms of thisinclude chest tightness, shortness of breath, frothy phlegm and cyanosis. Lack of oxygen can cause death hours after onset.CHRONIC HEALTH EFFECTS■ Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in themouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.Gastrointestinal disturbances may also occur. Chronic exposures may result in dermatitis and/or conjunctivitis.Studies show that inhaling this substance for over a long period (e.g. in an occupational setting) may increase the risk ofcancer.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some personscompared to the general population.Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs. Chronic exposure may inflame the skin orconjunctiva.Iodine and iodides, may give rise to local allergic reactions such as hives, rupture of skin blood vessels, pain in joints ordiseases of the lymph nodes.Strong inorganic acid mists containing sulfuric acid can cause cancer.Iodine and iodides cause goitre and diminished as well as increased activity of the thyroid gland. A toxic syndrome resultingfrom chronic iodide overdose and from repeated administration of small amounts of iodine is characterised by excessive salivacontinued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 7 of 9Section 11 - TOXICOLOGICAL INFORMATIONproduction, head cold, sneezing, conjunctivitis, headache, fever, laryngitis, inflammation of the bronchi and mouth cavity,inflamed parotid gland, and various skin rashes. Swelling and inflammation of the throat, irritated and swollen eyes and lungswelling may also occur. Swelling of the glottis, necessitating a tracheotomy has been reported. Use of iodides in pregnancy cancause foetal death, severe goitre, hypothyroidism and the cretinoid appearance of the newborn.TOXICITY AND IRRITATION■ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels ofhighly irritating compound.CARCINOGENsulfuric acid International Agency for Group 1Research on Cancer (IARC) -Agents Reviewed by the IARCMonographsSKINsulfuric acid GESAMP/EHS Composite List - GESAMP Hazard D1: skin 3CProfilesirritation/corrosionSection 12 - ECOLOGICAL INFORMATIONThis material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilperiodic acid No Data No Data No Data No DataAvailable Available Available Availablesulfuric acid No Data No Data LOW No DataAvailable Available AvailableSection 13 - DISPOSAL CONSIDERATIONS■ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer tolaws operating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.• Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-limefollowed by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in alicenced apparatus (after admixture with suitable combustible material).• Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water. Observe all label safeguardsuntil containers are cleaned and destroyed.Section 14 - TRANSPORTATION INFORMATIONLabels Required: CORROSIVEcontinued...


CPS Stencil Remover Concentrate 1:20/30, 1:50Chemwatch Material Safety Data SheetIssue Date: 20-Apr-2012 CHEMWATCH 4601-699317SPVersion No:6.1.1.1Page 8 of 9Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:2X (ADG7)Land Transport UNDG:Class or division: 8 Subsidiary risk: NoneUN No.: 3264 UN packing group: IIIShipping Name:CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (containsperiodic acid and sulfuric acid)Air Transport IATA:ICAO/IATA Class: 8 ICAO/IATA Subrisk: NoneUN/ID Number: 3264 Packing Group: IIISpecial provisions:A3A803Cargo OnlyPacking Instructions: 856 Maximum Qty/Pack: 60 LPassenger and CargoPassenger and CargoPacking Instructions: 852 Maximum Qty/Pack: 5 LPassenger and Cargo Limited QuantityPassenger and Cargo Limited QuantityPacking Instructions: Y841 Maximum Qty/Pack: 1 LShipping name:CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(contains periodic acid and sulfuric acid)Maritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: NoneUN Number: 3264 Packing Group: IIIEMS Number: F-A,S-B Special provisions: 223 274Limited Quantities: 5 LShipping name:CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.(contains periodic acid and sulfuric acid)Section 15 - REGULATORY INFORMATIONIndications of Danger:C CorrosivePOISONS SCHEDULENoneREGULATIONSRegulations for ingredientsperiodic acid (CAS: 10450-60-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)"sulfuric acid (CAS: 7664-93-9) is found on the following regulatory lists;"Australia Council of Australian Governments (COAG) Chemicals of Security Concern", "Australia Customs (Prohibited Exports)Regulations 1958 - Schedule 9 Precursor substances - Part 2", "Australia Exposure Standards", "Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)", "Australia Illicit Drug Reagents/Essential Chemicals - Category III","Australia Inventory of Chemical Substances (AICS)", "Australia National Pollutant Inventory", "Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)", "Australia Standard for the Uniform Scheduling ofMedicines and Poisons (SUSMP) - Appendix F (Part 3)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Schedule 6", "GESAMP/EHS Composite List - GESAMP Hazard Profiles", "IMO IBC Code Chapter 17: Summary of minimumrequirements", "IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk", "International Agency forResearch on Cancer (IARC) - Agents Reviewed by the IARC Monographs", "International Air Transport Association (IATA) DangerousGoods Regulations", "International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger andCargo Aircraft", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of HighProduction Volume (HPV) Chemicals", "OSPAR National List of Candidates for Substitution – United Kingdom", "United NationsConvention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances - Table II", "United Nations List of Precursorsand Chemicals Frequently used in the Illicit Manufacture of Narcotic Drugs and Psychotropic Substances Under InternationalControl (Red List) - Table II"No data for CPS Stencil Remover Concentrate 1:20/30, 1:50 (CW: 4601-69)continued...

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