Chemwatch Australian MSDS 32-0742 - FUJIFILM Australia

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Chemwatch Australian MSDS 32-0742 - FUJIFILM Australia

FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 1 of 7Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM LP-D3RWSSYNONYMS"Product Codes: 855259/858259, ", "850259, 858259"PROPER SHIPPING NAMEPOTASSIUM HYDROXIDE SOLUTIONPRODUCT USEDeveloper replenisher for thermal positive type presensitised plate.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISKRisk CodesRisk PhrasesR36/38 • Irritating to eyes and skin.SAFETYSafety CodesS24S25S37Safety Phrases• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable gloves.continued...


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 2 of 7Section 2 - HAZARDS IDENTIFICATIONS39S40S26S46S60• Wear eye/face protection.• To clean the floor and all objects contaminated by this material, use water.• In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label).• This material and its container must be disposed of as hazardous waste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %2- naphthol, ethoxylated 35545-57-4 3-7potassium hydroxide 1310-58-3 80Section 4 - FIRST AID MEASURESSWALLOWED• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally liftingthe upper and lower lids.• Seek medical attention without delay; if pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear.• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.INHALED• If fumes, aerosols or combustion products are inhaled remove from contaminated area.• Other measures are usually unnecessary.• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semirecumbentposture) and must be kept under medical observation even if no symptoms are (yet) manifested.• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivativemay be considered.NOTES TO PHYSICIAN■ Treat symptomatically.Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing mediawhich may be used. Choice of extinguishing media should take into account surrounding areas.Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may producefloating layers of combustible substances.In such an event consider:• foam.FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.continued...


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 3 of 7Section 5 - FIRE FIGHTING MEASURES• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• The material is not readily combustible under normal conditions.• However, it will break down under fire conditions and the organic component may burn.• Not considered to be a significant fire risk.• Heat may cause expansion or decomposition with violent rupture of containers.Decomposes on heating and produces toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), otherpyrolysis products typical of burning organic material.May emit corrosive fumes.FIRE INCOMPATIBILITY■ None known.HAZCHEM2RSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge ordisposal of material.• Check regularly for spills and leaks.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with moisture.SUITABLE CONTAINER• Lined metal can, lined metal pail/ can.• Plastic pail.• Polyliner drum.• Packing as recommended by manufacturer.For low viscosity materials• Drums and jerricans must be of the non-removable head type.• Where a can is to be used as an inner package, the can must have a screwed enclosure.


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 4 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• 2- naphthol, ethoxylated: CAS:35545- 57- 4• water: CAS:7732- 18- 5MATERIAL DATAFUJIFILM LP-D3RWS:POTASSIUM HYDROXIDE:■ for potassium hydroxide:The TLV-TWA is protective against respiratory tract irritation produced at higher concentrations.2-NAPHTHOL, ETHOXYLATED:■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat.Historically occupational exposure standards for these irritants have been based on observation of workers' responses to variousairborne concentrations.It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there isevidence of health effects at airborne concentrations encountered in the workplace.At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animalexperiments or clinical experience).NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.WATER:■ No exposure limits set by NOHSC or ACGIH.PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.The selection of the suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves andhas to be observed when making a final choice.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:continued...


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 5 of 7Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONProcess controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEClear light strawish alkaline liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Corrosive.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Applicable Viscosity Not AvailableBoiling Range (°C) ~100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not AvailableDecomposition Temp (°C) Not Available pH (as supplied) 12.9Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) ~2.0 @ 20CUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.014Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not AvailableSection 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Accidental ingestion of the material may be damaging to the health of the individual.EYE■ This material can cause eye irritation and damage in some persons.SKIN■ This material can cause inflammation of the skin oncontact in some persons.The material may accentuate any pre-existing dermatitis condition.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.INHALED■ The material is not thought to produce either adverse health effects or irritation of the respiratory tract followinginhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been producedfollowing exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimumand that suitable control measures be used in an occupational setting.Not normally a hazard due to non-volatile nature of product.CHRONIC HEALTH EFFECTS■ Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.continued...


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 6 of 7Section 11 - TOXICOLOGICAL INFORMATIONTOXICITY AND IRRITATION■ No significant acute toxicological data identified in literature search.Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels ofhighly irritating compound.Section 12 - ECOLOGICAL INFORMATIONThis material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soil2- naphthol, ethoxylated No Data No DataAvailableAvailablepotassium hydroxide No Data No Data LOWAvailableAvailableSection 13 - DISPOSAL CONSIDERATIONS■ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer tolaws operating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.• Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation followed by: burial in a landfillspecifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (afteradmixture with suitable combustible material)• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.Section 14 - TRANSPORTATION INFORMATIONLabels Required: CORROSIVEHAZCHEM:2R (ADG7)ADG7:Class or Division: 8 Subsidiary Risk: NoneUN No.: 1814 Packing Group: IIISpecial Provision: 223 Limited Quantity: 5 LPortable Tanks & Bulk T4 Portable Tanks & Bulk TP1Containers -Containers - SpecialInstruction:Provision:Packagings & IBCs - None Packagings & IBCs - P001 IBC03 LP01Packing Instruction:Special PackingProvision:Name and Description: POTASSIUM HYDROXIDE SOLUTIONLand Transport UNDG:Class or division: 8 Subsidiary risk: Nonecontinued...


FUJIFILM LP-D3RWSChemwatch Independent Material Safety Data SheetIssue Date: 25-Jul-2012 CHEMWATCH 32-0742X9317SPVersion No:2.1.1.1CD 2012/2 Page 7 of 7Section 14 - TRANSPORTATION INFORMATIONUN No.: 1814 UN packing group: IIIShipping Name:POTASSIUM HYDROXIDE SOLUTIONAir Transport IATA:ICAO/IATA Class: 8 ICAO/IATA Subrisk: NoneUN/ID Number: 1814 Packing Group: IIISpecial provisions:A3Shipping name:POTASSIUM HYDROXIDE SOLUTIONMaritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: NoneUN Number: 1814 Packing Group: IIIEMS Number: F- A, S- B Special provisions: 223Limited Quantities:5 LShipping name:POTASSIUM HYDROXIDE SOLUTIONPOISONS SCHEDULE S5REGULATIONSRegulations for ingredientsSection 15 - REGULATORY INFORMATION2-naphthol, ethoxylated (CAS: 35545-57-4) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory"potassium hydroxide (CAS: 1310-58-3) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix C","Australia Standard for the Uniform Scheduling of Medicines and Poisons(SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for theUniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","CODEX General Standard for Food Additives (GSFA) - AdditivesPermitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP","OECD List of High Production Volume(HPV) Chemicals"water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECDList of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"No data for Fujifilm LP-D3RWS (CW: 32-0742)Section 16 - OTHER INFORMATION■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 25-Jul-2012Print Date: 25-Jul-2012This is the end of the MSDS.

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