sewer aid f.a.

zep.ee

sewer aid f.a.

DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 1/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011* 1 Identification of the substance/mixture and of the company/undertaking· Product identifier· Trade name: ZEP SEWER AID FA· Article number: 080· Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the preparation Tube cleaner/ pipe cleaning agent· Details of the supplier of the safety data sheet· Manufacturer/Supplier:ZEP ITALIA s.r.l.Via Nettunense Km. 25.000IT-04011 APRILIA (LT)Tel. +39.06926691 / Fax. +39.06.92747061sito: www.zepitalia.itMade inZep Inc.1310 Seaboard Industrial Blvd.Atlanta, GA 303181-877-I-BUY-ZEP (428-9937)· Further information obtainable from:Technical products departmentZEP ITALIA SRLe-mail: info@zepitalia.it· Emergency telephone number:Estonia: +372 5030592Italy: Niguarda Hospital Milano, Tel: +39 0266101029France: Centre anti poison, Orfila, Tel : 014425959Belgique: Centre anti poison/Antigif Centrum Tel: 0702452452 Hazards identification· Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008GHS03 flame over circleOx. Sol. 2H272 May intensify fire; oxidiser.GHS05 corrosionSkin Corr. 1A H314 Causes severe skin burns and eye damage.GHS07STOT SE 3 H335 May cause respiratory irritation.· Classification according to Directive 67/548/EEC or Directive 1999/45/ECC; CorrosiveR35: Causes severe burns.Xn; HarmfulR22: Harmful if swallowed.O; OxidisingR8: Contact with combustible material may cause fire.(Contd. on page 2)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 2/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FA(Contd. of page 1)· Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version.· Classification system:The classification is according to the latest editions of the EU-lists, and extended by company and literaturedata.· Label elements· Hazard-determining components of labelling:sodium hydroxide· Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives / Ordinance on HazardousMaterials 67/548/CEE, 199/45/CE· Code letter and hazard designation of product:C CorrosiveO Oxidising· Hazard-determining components of labelling:sodium nitrate, containing in the dry statemore than 16,3 per cent by weight of nitrogensodium hydroxide· Risk phrases:8 Contact with combustible material may cause fire.22 Harmful if swallowed.35 Causes severe burns.· Safety phrases:7/8 Keep container tightly closed and dry.17 Keep away from combustible material.20 When using do not eat or drink.22 Do not breathe dust.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.36/37/39 Wear suitable protective clothing, gloves and eye/face protection.· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.3 Composition/information on ingredients· Description: Mixture of substances listed below with nonhazardous additions.· Dangerous components:CAS: 1310-73-2 sodium hydroxideEINECS: 215-185-5 C R35Skin Corr. 1A, H314CAS: 7631-99-4EINECS: 231-554-3CAS: 7429-90-5EINECS: 231-072-3sodium nitrate, containing in the dry statemore than 16,3 per cent by weightof nitrogenXn R22; Xi R36/37/38; O R8Ox. Sol. 2, H272; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3,H335aluminium powder (pyrophoric)F R11-15Flam. Sol. 1, H228; Water-react. 2, H26125-50%25-50%5-10%(Contd. on page 3)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 3/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FACAS: 497-19-8EINECS: 207-838-8sodium carbonateXi R36Eye Irrit. 2, H319(Contd. of page 2)1-5%· Ingredients according to detergents regulation 648/2004/ECalifatic hydrocarbon < 5%· Additional information: For the wording of the listed risk phrases refer to section 16.4 First aid measures· Description of first aid measures· General information:Immediately remove any clothing soiled by the product.Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48hours after the accident.· After inhalation: In case of unconsciousness place patient stably in side position for transportation.· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing:Call for a doctor immediately.Drink plenty of water and provide fresh air. Call for a doctor immediately.· Information for doctor:· Most important symptoms and effects, both acute and delayed No further relevant information available.· Indication of any immediate medical attention and special treatment neededNo further relevant information available.5 Firefighting measures· Extinguishing media· Suitable extinguishing agents:CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.· Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.· Advice for firefighters· Protective equipment: Mouth respiratory protective device.6 Accidental release measures· Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.Wear protective equipment. Keep unprotected persons away.· Environmental precautions: Do not allow to enter sewers/ surface or ground water.· Methods and material for containment and cleaning up:Use neutralizing agent.Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.· Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.GB(Contd. on page 4)


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 4/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FA(Contd. of page 3)7 Handling and storage· Handling:· Precautions for safe handlingThorough dedusting.Prevent formation of dust.· Information about fire - and explosion protection: Keep respiratory protective device available.· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.· Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well sealed receptacles.· Specific end use(s) No further relevant information available.* 8 Exposure controls/personal protection· Additional information about design of technical facilities: No further data; see item 7.· Control parameters· Ingredients with limit values that require monitoring at the workplace:1310-73-2 sodium hydroxideWEL Short-term value: 2 mg/m³7429-90-5 aluminium powder (pyrophoric)WEL Long-term value: 10* 4** mg/m³*inhalable dust **respirable dust· Additional information: The lists valid during the making were used as basis.· Exposure controls· Personal protective equipment:· General protective and hygienic measures:Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes and skin.· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective device.· Protection of hands:Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.Protective glovesThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.(Contd. on page 5)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 5/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FA(Contd. of page 4)· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.· Eye protection:Tightly sealed goggles* 9 Physical and chemical properties· Information on basic physical and chemical properties· General Information· Appearance:Form:Colour:SolidWhitishWhith Blue parts· Odour: Characteristic· Odour threshold: Not determined.· pH-value: Not applicable.· Change in conditionMelting point/Melting range: Undetermined.Boiling point/Boiling range: 600°C· Flash point: Not applicable.· Flammability (solid, gaseous): Contact with combustible material may cause fire.· Ignition temperature: 400°C· Decomposition temperature: Not determined.· Self-igniting: Product is not selfigniting.· Danger of explosion: Not determined.· Explosion limits:Lower:Upper:Not determined.Not determined.· Vapour pressure: Not applicable.· Density at 20°C: 1.183 g/cm³· Relative density Not determined.· Vapour density Not applicable.· Evaporation rate Not applicable.· Solubility in / Miscibility withwater:Soluble.· Segregation coefficient (n-octanol/water): Not determined.· Viscosity:Dynamic:Kinematic:Not applicable.Not applicable.· Solvent content:Organic solvents: 0.0 %Water: 0.1 %VOC (EC) 0.00 %(Contd. on page 6)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 6/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FASolids content: 100.0 %· Other information No further relevant information available.(Contd. of page 5)10 Stability and reactivity· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.11 Toxicological information· Information on toxicological effects· Acute toxicity:· LD/LC50 values relevant for classification:1310-73-2 sodium hydroxideOral LD50 2000 mg/kg (rat)7631-99-4 sodium nitrate, containing in the dry statemore than 16,3 per cent by weight of nitrogenOral LD50 3236 mg/kg (rat)· Primary irritant effect:· on the skin: Strong caustic effect on skin and mucous membranes.· on the eye: Strong caustic effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:HarmfulCorrosiveSwallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation ofesophagus and stomach.12 Ecological information· Toxicity· Acquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Additional ecological information:· General notes:Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course or sewagesystem.Must not reach sewage water or drainage ditch undiluted or unneutralized.· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.(Contd. on page 7)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 7/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FA· Other adverse effects No further relevant information available.(Contd. of page 6)13 Disposal considerations· Waste treatment methods· RecommendationMust not be disposed together with household garbage. Do not allow product to reach sewage system.· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.· Recommended cleansing agents: Water, if necessary together with cleansing agents.* 14 Transport information· Land transport ADR/RID (cross-border)· ADR/RID class: 8 Corrosive substances.· Danger code (Kemler): 80· UN-Number: 3262· Packaging group: II· Hazard label: 8· UN proper shipping name: 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (aluminium powder(pyrophoric))· Limited quantities (LQ) LQ23· Tunnel restriction code E· Maritime transport IMDG:· IMDG Class: 8· UN Number: 3262· Label 8· Packaging group: II· EMS Number: F-G,S-L· Marine pollutant: No· Segregation groups Alkalis· Proper shipping name: CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (aluminium powder(pyrophoric))· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: 8· UN/ID Number: 3262· Label 8· Packaging group: II· Proper shipping name: CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (aluminium powder(pyrophoric))(Contd. on page 8)GB


DRSafety data sheetaccording to 1907/2006/EC, Article 31Page 8/8Printing date 08.07.2011 Version number 3Revision: 08.07.2011Trade name: ZEP SEWER AID FA(Contd. of page 7)· UN "Model Regulation": UN3262, CORROSIVE SOLID, BASIC, INORGANIC, N.O.S., 8, II· Special precautions for user Warning: Corrosive substances.· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.* 15 Regulatory information· Safety, health and environmental regulations/legislation specific for the substance or mixture· National regulations:· Other regulations, limitations and prohibitive regulations D.lgs 81/200· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.· Relevant phrasesH228 Flammable solid.H261 In contact with water releases flammable gases.H272 May intensify fire; oxidiser.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.R11 Highly flammable.R15 Contact with water liberates extremely flammable gases.R22 Harmful if swallowed.R35 Causes severe burns.R36 Irritating to eyes.R36/37/38 Irritating to eyes, respiratory system and skin.R8 Contact with combustible material may cause fire.· Department issuing MSDS: Reparto Tecnico divisione Sicurezza prodotti ZEP ITALIA· Contact:FRANCESCA VANNUCCI - e-mail: francesca.vannucci@zepitalia.itALVES COSTANZA - e-mail: alves.costanza@zepitalia.it· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning theInternational Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)ICAO: International Civil Aviation OrganizationICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)GHS: Globally Harmonized System of Classification and Labelling of ChemicalsVOC: Volatile Organic Compounds (USA, EU)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percent· * Data compared to the previous version altered.GB

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