Chemwatch Australian MSDS 31-6618 - FUJIFILM Australia

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Chemwatch Australian MSDS 31-6618 - FUJIFILM Australia

FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 1 of 8Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM CN-16Q NQ2-R PART ASYNONYMS"Product Code: 850045 750004", "CAT No.: 850183, 750183, ", "850045, 750004", "Item Codes: 391029, 390432", "CN-16Q NQ2-Rs"PRODUCT USE■ Used according to manufacturer's directions.Part A of a 2 part system.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISKRisk CodesRisk PhrasesR36/38 • Irritating to eyes and skin.R43• May cause SENSITISATION by skin contact.R52/53 • Harmful to aquatic organisms, may cause long- term adverseeffects in the aquatic environment.SAFETYSafety CodesS23Safety Phrases• Do not breathe gas/fumes/vapour/spray.continued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 3 of 8Section 5 - FIRE FIGHTING MEASURESFIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves in the event of a fire.• Prevent, by any means available, spillage from entering drains or water courses.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• The material is not readily combustible under normal conditions.• However, it will break down under fire conditions and the organic component may burn.• Not considered to be a significant fire risk.• Heat may cause expansion or decomposition with violent rupture of containers.Decomposes on heating and produces toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), otherpyrolysis products typical of burning organic material.May emit poisonous fumes.FIRE INCOMPATIBILITY■ None known.HAZCHEMNoneSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS■ Moderate hazard.• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.• DO NOT allow clothing wet with material to stay in contact with skin.SUITABLE CONTAINER• Polyethylene or polypropylene container.• Packing as recommended by manufacturer.• Check all containers are clearly labelled and free from leaks.STORAGE INCOMPATIBILITY■ Salts of ethylenediaminetetraacetic acid (EDTA):• should not come into contact with strong oxidisers• are incompatible with metals such as zinc, aluminum, carbon steel, copper, copper alloys, galvanized metals and nickel.• in contact with metals, such as aluminum, may generate flammable hydrogen gas• in contact with bases, may evolve hydrogen and oxygen.• Contact with acids produces toxic fumes.STORAGE REQUIREMENTS• Store in original containers.• Keep containers securely sealed.• Store in a cool, dry, well-ventilated area.• Store away from incompatible materials and foodstuff containers.continued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 4 of 8Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our records• ammonium bromide: CAS:12124- 97- 9• EDTA disodium salt: CAS:139- 33- 3 CAS:69772- 70- 9• 2, 2' - bis(dimethylamino)diethyl disulfide dihydrochloride: CAS:17339- 60- 5• water: CAS:7732- 18- 5MATERIAL DATA2,2'-BIS(DIMETHYLAMINO)DIETHYL DISULFIDE DIHYDROCHLORIDE:AMMONIUM BROMIDE:EDTA DISODIUM SALT:FUJIFILM CN-16Q NQ2-R PART A:■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat.Historically occupational exposure standards for these irritants have been based on observation of workers' responses to variousairborne concentrations.2,2'-BIS(DIMETHYLAMINO)DIETHYL DISULFIDE DIHYDROCHLORIDE:AMMONIUM BROMIDE:EDTA DISODIUM SALT:■ It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which thereis evidence of health effects at airborne concentrations encountered in the workplace.At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animalexperiments or clinical experience).NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.WATER:■ No exposure limits set by NOHSC or ACGIH.PERSONAL PROTECTIONRESPIRATOR•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.NOTE:• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity.OTHER• Overalls.• P.V.C. apron.• Barrier cream.continued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 5 of 8Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION• Skin cleansing cream.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEColourless liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) >100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not AvailableDecomposition Temp (°C) Not Available pH (as supplied) 4.2Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.213Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not AvailableSection 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Accidental ingestion of the material may be damaging to the health of the individual.Bromide poisoning causes intense vomiting so the dose is often removed. Effects include drowsiness, irritability, inco-ordination,vertigo, confusion, mania, hallucinations and coma. Other effects include skin rash, nervous system symptoms, sensorydisturbances and increased spinal fluid pressure. They have been used as sedatives and depress the central nervous system.Toxicity is increased if dietary chloride is reduced. Repeated ingestion can cause a syndrome with acne, confusion, irritability,tremor, memory loss, weight loss, headache, slurred speech, delusions, stupor, psychosis and coma.Large doses of ammonia or injected ammonium salts may produce diarrhoea and may be sufficiently absorbed to produce increasedproduction of urine and systemic poisoning. Symptoms include weakening of facial muscle, tremor, anxiety, reduced muscle and limbcontrol.EYE■ This material can cause eye irritation and damage in some persons.SKIN■ This material can cause inflammation of the skin oncontact in some persons.The material may accentuate any pre-existing dermatitis condition.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.continued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 6 of 8Section 11 - TOXICOLOGICAL INFORMATIONINHALED■ Not normally a hazard due to non-volatile nature of product.The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation(as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced followingexposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and thatsuitable control measures be used in an occupational setting.CHRONIC HEALTH EFFECTS■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.Chronic intoxication with ionic bromides, historically, has resulted from medical use of bromides but not from environmental oroccupational exposure; depression, hallucinosis, and schizophreniform psychosis can be seen in the absence of other signs ofintoxication. Bromides may also induce sedation, irritability, agitation, delirium, memory loss, confusion, disorientation,forgetfulness (aphasias), dysarthria, weakness, fatigue, vertigo, stupor, coma, decreased appetite, nausea and vomiting,diarrhoea, hallucinations, an acne like rash on the face, legs and trunk, known as bronchoderma (seen in 25-30% of case involvingbromide ion), and a profuse discharge from the nostrils (coryza).TOXICITY AND IRRITATION■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesisof contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simplydetermined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it areequally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one withstronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances arenoteworthy if they produce an allergic test reaction in more than 1% of the persons tested.No significant acute toxicological data identified in literature search.Section 12 - ECOLOGICAL INFORMATIONHarmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/Soilammonium bromide No Data No DataAvailableAvailableEDTA disodium salt LOW No Data LOW MEDAvailable2, 2' - No Data No Databis(dimethylamino)diethyl Available Availabledisulfide dihydrochlorideSection 13 - DISPOSAL CONSIDERATIONS• Containers may still present a chemical hazard/ danger when empty.• Return to supplier for reuse/ recycling if possible.Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to lawsoperating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.continued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 7 of 8Section 13 - DISPOSAL CONSIDERATIONS• Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration ina licenced apparatus (after admixture with suitable combustible material).• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:None (ADG7)NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDGSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientsammonium bromide (CAS: 12124-97-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicinesand Poisons (SUSMP) - Schedule 4","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","OECD List of High ProductionVolume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway","OSPAR National List of Candidates forSubstitution – United Kingdom","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not beenestablished"EDTA disodium salt (CAS: 139-33-3,69772-70-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV) Chemicals"2,2'-bis(dimethylamino)diethyl disulfide dihydrochloride (CAS: 17339-60-5) is found on thefollowing regulatory lists;"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic watersupply - inorganic chemicals)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambientenvironmental standards (STOCK - inorganic chemicals)","Australia - Australian Capital Territory - Environment ProtectionRegulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)","Australia -Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm(IRRIG)","Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken tocause environmental harm (STOCK)","Australia Drinking Water Guideline Values For Physical and Chemical Characteristics","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established"water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECDList of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"No data for Fujifilm CN-16Q NQ2-R Part A (CW: 31-6618)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesEDTA disodium salt 139- 33- 3 Xn; R22INGREDIENTS WITH MULTIPLE CAS NUMBERSIngredient NameCASEDTA disodium salt 139- 33- 3, 69772- 70- 9■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whethercontinued...


FUJIFILM CN-16Q NQ2-R PART AChemwatch Independent Material Safety Data SheetIssue Date: 4-Jul-2012 CHEMWATCH 31-6618X9317SP(cs)Version No:2.1.1.1CD 2012/2 Page 8 of 8Section 16 - OTHER INFORMATIONthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 4-Jul-2012Print Date: 4-Jul-2012This is the end of the MSDS.


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 1 of 9Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEFUJIFILM CN-16Q NQ2-R PART BSYNONYMS"Product Code: 850045 750005", "CAT No.: 750184, 750005, 850045", "Item Codes: 391029, 390432", "CN-16Q NQ2-Rs"PROPER SHIPPING NAMECORROSIVE LIQUID, N.O.S.(contains EDTA ferric ammonium salt)PRODUCT USE■ Used according to manufacturer's directions.Part B of a 2 part system.SUPPLIERCompany: FUJIFILM Australia Pty LtdAddress:114 Old Pittwater RoadBrookvaleNSW, 2100AustraliaTelephone: +61 2 9466 2600Emergency Tel: +61 1800 039 008Emergency Tel: +61 3 9573 3112Fax: +61 2 9938 1975Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4RISKRisk CodesRisk PhrasesR36/38 • Irritating to eyes and skin.R43• May cause SENSITISATION by skin contact.R52• Harmful to aquatic organisms.continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 2 of 9Section 2 - HAZARDS IDENTIFICATIONSAFETYSafety CodesS23S24S25S37S39S40S26S46S60Safety Phrases• Do not breathe gas/fumes/vapour/spray.• Avoid contact with skin.• Avoid contact with eyes.• Wear suitable gloves.• Wear eye/face protection.• To clean the floor and all objects contaminated by this material, use water.• In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label).• This material and its container must be disposed of as hazardous waste.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN %EDTA ferric ammonium salt 21265-50-9 15-30ammonium bromide 12124-97-9 10-20ammonium nitrate 6484-52-2 1-5EDTA tetraammonium salt 22473-78-5 0.1-1water 7732-18-5 50-70Section 4 - FIRST AID MEASURESSWALLOWED• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration.• Observe the patient carefully.• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally liftingthe upper and lower lids.• Seek medical attention without delay; if pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear.• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.INHALED• If fumes, aerosols or combustion products are inhaled remove from contaminated area.• Other measures are usually unnecessary.• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semirecumbentposture) and must be kept under medical observation even if no symptoms are (yet) manifested.• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivativemay be considered.NOTES TO PHYSICIAN■ Treat symptomatically.For acute or short term repeated exposures to iron and its derivatives:• Always treat symptoms rather than history.• In general, however, toxic doses exceed 20 mg/kg of ingested material (as elemental iron) with lethal doses exceeding 180 mg/kg.• Control of iron stores depend on variation in absorption rather than excretion. Absorption occurs through aspiration, ingestionand burned skin.• Hepatic damage may progress to failure with hypoprothrombinaemia and hypoglycaemia. Hepatorenal syndrome may occur.Treatment of intoxication by the bromide ion includes hydration, the maintenance of mild water diuresis, and sodium, or evenbetter, ammonium chloride (10-15 gm. daily in divided doses) with an osmotic or high ceiling diuretic.continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 3 of 9Section 4 - FIRST AID MEASURESIn acute poisoning the stomach should be emptied by aspiration and lavage and sodium chloride given by intravenous infusion.Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA■ The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing mediawhich may be used. Choice of extinguishing media should take into account surrounding areas.Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may producefloating layers of combustible substances.In such an event consider:• foam.FIRE FIGHTING• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.• Use fire fighting procedures suitable for surrounding area.FIRE/EXPLOSION HAZARD• The material is not readily combustible under normal conditions.• However, it will break down under fire conditions and the organic component may burn.• Not considered to be a significant fire risk.• Heat may cause expansion or decomposition with violent rupture of containers.Decomposes on heating and produces toxic fumes of: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typicalof burning organic material.May emit corrosive fumes.FIRE INCOMPATIBILITY■ None known.HAZCHEM2XSection 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge ordisposal of material.• Check regularly for spills and leaks.• Clean up all spills immediately.• Avoid breathing vapours and contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Contain and absorb spill with sand, earth, inert material or vermiculite.MAJOR SPILLS• Clear area of personnel and move upwind.• Alert Fire Brigade and tell them location and nature of hazard.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING• DO NOT allow clothing wet with material to stay in contact with skin.• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Avoid contact with moisture.SUITABLE CONTAINER• Lined metal can, lined metal pail/ can.continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 4 of 9Section 7 - HANDLING AND STORAGE• Plastic pail.• Polyliner drum.• Packing as recommended by manufacturer.For low viscosity materials• Drums and jerricans must be of the non-removable head type.• Where a can is to be used as an inner package, the can must have a screwed enclosure.


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 5 of 9Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].HANDS/FEET• Wear chemical protective gloves, eg. PVC.• Wear safety footwear or safety gumboots, eg. Rubber.NOTE:• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexterity.OTHER• Overalls.• PVC Apron.• PVC protective suit may be required if exposure severe.• Eyewash unit.ENGINEERING CONTROLS■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilationthat strategically "adds" and "removes" air in the work environment.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEDar red liquid with no odour; mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Corrosive.State Liquid Molecular Weight Not ApplicableMelting Range (°C) Not Available Viscosity Not AvailableBoiling Range (°C) >100 Solubility in water (g/L) MiscibleFlash Point (°C) Not Applicable pH (1% solution) Not AvailableDecomposition Temp (°C) Not Available pH (as supplied) 6.1Autoignition Temp (°C) Not Applicable Vapour Pressure (kPa) Not AvailableUpper Explosive Limit (%) Not Applicable Specific Gravity (water=1) 1.237Lower Explosive Limit (%) Not Applicable Relative Vapour Density Not Available(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not AvailableSection 10 - STABILITY AND REACTIVITYCONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 6 of 9Section 10 - STABILITY AND REACTIVITY• Hazardous polymerisation will not occur.For incompatible materials - refer to Section 7 - Handling and Storage.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTSSWALLOWED■ Accidental ingestion of the material may be damaging to the health of the individual.Large doses of ammonia or injected ammonium salts may produce diarrhoea and may be sufficiently absorbed to produce increasedproduction of urine and systemic poisoning. Symptoms include weakening of facial muscle, tremor, anxiety, reduced muscle and limbcontrol.EYE■ This material can cause eye irritation and damage in some persons.SKIN■ This material can cause inflammation of the skin oncontact in some persons.The material may accentuate any pre-existing dermatitis condition.Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.INHALED■ The material is not thought to produce either adverse health effects or irritation of the respiratory tract followinginhalation (as classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been producedfollowing exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimumand that suitable control measures be used in an occupational setting.Not normally a hazard due to non-volatile nature of product.CHRONIC HEALTH EFFECTS■ Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupationalexposure.There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby.Chronic intoxication with ionic bromides, historically, has resulted from medical use of bromides but not from environmental oroccupational exposure; depression, hallucinosis, and schizophreniform psychosis can be seen in the absence of other signs ofintoxication. Bromides may also induce sedation, irritability, agitation, delirium, memory loss, confusion, disorientation,forgetfulness (aphasias), dysarthria, weakness, fatigue, vertigo, stupor, coma, decreased appetite, nausea and vomiting,diarrhoea, hallucinations, an acne like rash on the face, legs and trunk, known as bronchoderma (seen in 25-30% of case involvingbromide ion), and a profuse discharge from the nostrils (coryza).Injection of EDTA and it salts can cause severe kidney damage with tissue death and internal bleeding, bone marrow depression andcritically low levels of calcium.TOXICITY AND IRRITATION■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesisof contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions,e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not simplydetermined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it areequally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one withstronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances arenoteworthy if they produce an allergic test reaction in more than 1% of the persons tested.No significant acute toxicological data identified in literature search.Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a nonallergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels ofhighly irritating compound.For ethylenediaminetetraacetic acid (EDTA) and its salts:EDTA is a strong organic acid (approximately 1000 times stronger than acetic acid). It has a high affinity for alkaline-earthions (for example, calcium and magnesium) and heavy-metal ions (for example, lead and mercury).continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 7 of 9Section 12 - ECOLOGICAL INFORMATIONHarmful to aquatic organisms.This material and its container must be disposed of as hazardous waste.EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation MobilityWater/SoilEDTA ferric ammonium salt No Data No DataAvailableAvailableammonium bromide No Data No DataAvailableAvailableammonium nitrate No Data No Data LOWAvailableAvailableEDTA tetraammonium salt No Data No Data LOWAvailableAvailableSection 13 - DISPOSAL CONSIDERATIONS• Containers may still present a chemical hazard/ danger when empty.• Return to supplier for reuse/ recycling if possible.Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used tostore the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.• Where possible retain label warnings and MSDS and observe all notices pertaining to the product.Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to lawsoperating in their area.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction.• DO NOT allow wash water from cleaning or process equipment to enter drains.• It may be necessary to collect all wash water for treatment before disposal.• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.• Where in doubt contact the responsible authority.• Recycle wherever possible.• Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitabletreatment or disposal facility can be identified.• Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation followed by: burial in a landfillspecifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (afteradmixture with suitable combustible material)• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.Section 14 - TRANSPORTATION INFORMATIONLabels Required: CORROSIVEHAZCHEM:2X (ADG7)ADG7:Class or Division: 8 Subsidiary Risk: NoneUN No.: 1760 Packing Group: IIISpecial Provision: 223 274 Limited Quantity: 5 LPortable Tanks & Bulk T7 Portable Tanks & Bulk TP1 TP28Containers -Containers - SpecialInstruction:Provision:Packagings & IBCs - None Packagings & IBCs - P001 IBC03 LP01Packing Instruction:Special PackingProvision:Name and Description: CORROSIVE LIQUID, N.O.S. (contains EDTA ferricammonium salt)continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 8 of 9Section 14 - TRANSPORTATION INFORMATIONLand Transport UNDG:Class or division: 8 Subsidiary risk: NoneUN No.: 1760 UN packing group: IIIShipping Name:CORROSIVE LIQUID, N.O.S. (contains EDTA ferric ammoniumsalt)Air Transport IATA:ICAO/IATA Class: 8 ICAO/IATA Subrisk: NoneUN/ID Number: 1760 Packing Group: IIISpecial provisions:A3A803Shipping name:CORROSIVE LIQUID, N.O.S.(contains EDTA ferric ammonium salt)Maritime Transport IMDG:IMDG Class: 8 IMDG Subrisk: NoneUN Number: 1760 Packing Group: IIIEMS Number: F- A, S- B Special provisions: 223 274Limited Quantities:5 LShipping name:CORROSIVE LIQUID, N.O.S.(contains EDTA ferric ammonium salt)Section 15 - REGULATORY INFORMATIONPOISONS SCHEDULE NoneREGULATIONSRegulations for ingredientsEDTA ferric ammonium salt (CAS: 21265-50-9) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","OECD List of High ProductionVolume (HPV) Chemicals"ammonium bromide (CAS: 12124-97-9) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the UniformScheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicinesand Poisons (SUSMP) - Schedule 4","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","OECD List of High ProductionVolume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway","OSPAR National List of Candidates forSubstitution – United Kingdom","WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not beenestablished"ammonium nitrate (CAS: 6484-52-2) is found on the following regulatory lists;"Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic watersupply - inorganic chemicals)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambientenvironmental standards (STOCK - inorganic chemicals)","Australia - Australian Capital Territory - Environment ProtectionRegulation: Pollutants entering waterways taken to cause environmental harm (Domestic water supply quality)","Australia -Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm(STOCK)","Australia - Western Australia Hazardous Substances Prohibited for Specified Uses or Methods of Handling","AustraliaCouncil of Australian Governments (COAG) Chemicals of Security Concern","Australia Dangerous Goods Code (ADG Code) - Goods TooDangerous To Be Transported","Australia Drinking Water Guideline Values For Physical and Chemical Characteristics","AustraliaHazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","AustraliaStandard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","OECD List of High Production Volume(HPV) Chemicals"EDTA tetraammonium salt (CAS: 22473-78-5) is found on the following regulatory lists;"Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia National Pollutant Inventory","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","OECD List of High ProductionVolume (HPV) Chemicals"water (CAS: 7732-18-5) is found on the following regulatory lists;"Australia Inventory of Chemical Substances (AICS)","International Fragrance Association (IFRA) Survey: Transparency List","OECDList of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution – Norway"No data for Fujifilm CN-16Q NQ2-R Part B (CW: 31-6619)Section 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesEDTA tetraammonium salt 22473- 78- 5 R43continued...


FUJIFILM CN-16Q NQ2-R PART BChemwatch Independent Material Safety Data SheetIssue Date: 19-Apr-2012 CHEMWATCH 31-6619X9317SP(cs)Version No:1CD 2012/2 Page 9 of 9Section 16 - OTHER INFORMATION■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well asindependent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at:www.chemwatch.net/references.■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whetherthe reported Hazards are Risks in the workplace or other settings.This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 19-Apr-2012Print Date: 4-Jul-2012This is the end of the MSDS.

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