Views
1 year ago

2007_6_Nr6_EEMJ

Iurascu et al.

Iurascu et al. /Environmental Engineering and Management Journal 6 (2007), 6, 479-482 Fe (OH) 2+ + hν = Fe 2+ + HO . (2) Despite its effectiveness, the homogeneous photo- Fenton process has an important drawback for practical application to large water flow rates, caused by sludge formation in the final neutralization step (Siminiceanu, 2003). Therefore, new heterogeneous Fe-based catalysts have been prepared and tested (Carriazo et al., 2003; Feng et al., 2006; Iurascu et al., 2006; Sum et al., 2005; Timofeeva et al., 2005). Sum et al. (2005) prepared a new laponite clay-based Fe nanocomposite as heterogeneous photo- Fenton catalyst, and tested it in the mineralization process of an azo- dye Acid Black 1 (AB 1) in water , in the presence of H 2 O 2 and UV light. Under the optimal reaction conditions found by the authors (0.1 mM AB1, 6.4 mM H 2 O 2 , 1.0 g catalyst/L, pH3, 8W UV-C) they achieved a complete discoloration and a 90% mineralization after 90 min reaction time, and a complete TOC removal after 4 cycles of 2h reaction time. These encouraging results determined the authors of the present paper to prepare a similar catalyst and to test it in process of the degradation of phenol in water. 2. Experimental The synthetic laponite clay (laponite RD) was supplied by Bresciani S.R.L. and used as starting material to prepare a series of Fe-Lap-RD catalysts. The laponite RD powder has a specific area of 370 m 2 /g. The rest of the chemicals employed in the experiments were supplied by Merck (H 2 SO 4 98% and H 2 O 2 35%), Sigma-Aldrich (Na 2 CO 3, KI, KH 2 PO 4 , NaOH, phenol and Fe (NO 3 ) 3 ⋅9H 2 O). The water used was of Milli-Q quality. A series of Fe-Lap-RD catalysts were prepared through a reaction between a solution of iron salt and a dispersion of laponite RD clay. Firstly an aqueous dispersion of laponite RD clay was prepared by adding 2 g laponite RD to 100 mL H 2 O under vigorous stirring. Secondly, sodium carbonate was added slowly as a powder into a vigorously stirred 0.2 M solution of iron nitrate such that a molar ratio of 1:1 for [Na + ]/[Fe 3+ ] was established. The obtained solution was added very slowly into the dispersion of laponite clay prepared in the first step until a ratio of 11 mmol Fe 3+ per gram clay was achieved. The suspension was stirred 2 h and then divided into two portions. One portion was kept in an oven at 373 K for two days. For simplicity this portion will be referred as “thermally aged” (TA). Another portion, referred as “without thermal aging” (WTA) was stirred for two days at room temperature to allow sufficient intercalation of the clay. After that, the precipitate of each portion was collected by centrifugation and washed several times with deionised water to ensure that all the Na + ions were removed. The recoveries were dried at a temperature of 373 K for 24 h and further divided into four equal portions. The two portions underwent a calcination process at different temperatures for 24 h. The calcination temperatures were 523, 623, 723, and 823 K. For simplicity, the clays will be referred as: WTA- T for the clays obtained without thermal aging and TA-T for the clays prepared by thermal aging; T represents the calcination temperature used in this study: 523, 623, 723, and 823 K The characterization of catalyst samples by chemical analysis, SEM/EDS, XRD and DTA was described in a previous paper (Iurascu et al., 2006). The photocatalytic activity of each pillared clay was evaluated in the process of mineralization and conversion of a 0.1 mM phenol solution in the presence of 5 mM H 2 O 2 , 1 g/L catalyst and UV irradiation using a Unilux Philips lamp (15W UV-C, λ=254 nm). Irradiation was carried out in magnetically stirred, cylindrical Pyrex quartz cell (4 cm diameter, 2,3 cm height) containing 10 mL solution, at room temperature. The pH was adjusted to 3 using a H 2 SO 4 solution. This is the optimal pH in the homogeneous photo-Fenton process (Siminiceanu, 2003). The start of the reaction was considered to be the moment when the cell was put under the UV-C lamp. After irradiation the catalyst was separated from the solution by filtration with Hydrophilic PTFE Millex-LCR filter (pore diameter 0.45x10 -9 m). The conversion of phenol was measured using a Merck-Hitachi HPLC. The column used was a RP- C18 LichroCARP (Merck, length 125 mm, diameter 4mm) packed with Li-Chrospher 100 RP-18 (5x10 -9 m diameter). Isocratic elution was performed with a 30/70 mixture of acetonitrile/aqueous phosphate buffer (0.05 M, pH 2.8). The mineralization of phenol was measured using a Shimadzu TOC 5000 Analyzer. The leaching iron (Fe 3+ and Fe 2+ ) from the catalysts was measured using a UVVIS Cary 100 Scan spectrophotometer and a Merck reagent Spectroquant. The experimental determinations were carried out at a wavelength of 565 nm. Because the reaction was still going on after the irradiation time was over, it was necessary to use a stopping reagent, which contained 0.1M Na 2 SO 3 , 0,1M KH 2 PO 4 , 0,1M KI and 0,05M NaOH. The stopping reagent was injected in the sample solution immediately after filtration, using a 1:1 volumetric ratio. After the selection of the pillared clay with the best activity and the smallest quantity of leached iron, the influences of several parameters over photo-activity such as UV light wavelength, initial concentration of phenol, initial concentration of H 2 O 2 , initial catalyst dose and initial pH, were studied. 3. Result and discussion The results are presented under the form of the kinetic curves C Ph versus time, or X Ph versus time. The conversion degree of the phenol X Ph has been calculated with Eq. (3): X Ph = 1- C Ph / C o Ph (3) 480 4

Phenol degradation in water through a heterogeneous photo-Fenton process where C 0 Ph is the initial molar concentration of the phenol, and C Ph is the molar concentration of the residual phenol at a given time. 3.1. Influence of the light source 3.3. Influence of initial phenol concentration in water The influence of the initial phenol concentration is illustrated in the Fig. 3. Fig. 1 presents the influence of the light source on the phenol conversion, at different catalyst doses, and the other constant factors ( C 0 Ph = 1 mM; C 0 H2O2 = 50 mM, pH3; T= 303 K). The low pressure mercury lamp emitting UV-C of 254 nm was more effective than the lamp emitting UV-A. Fig.3. Influence of the initial phenol concentration (catalyst dose of 1g/L; C 0 H2O2 = 50 mM, pH3; T= 303 K 3.4. Influence of hydrogen peroxide dose Fig.1. Influence of light source (C 0 Ph = 1 mM; C 0 H2O2 = 50 mM, pH3; T= 303 K) Fig. 4 presents sections at constant reaction time of the kinetic curves. The results show that for a solution with 1mM phenol the optimal dose is of 50 mM hydrogen peroxide. 3.2. Influence of the catalyst dose Fig. 2 presents the results for different catalyst doses with a UV-A lamp of 40 W and the other constant factors (C 0 Ph = 1 mM; C 0 H2O2 = 50 mM, pH3; T= 303 K). The best results have been obtained with a dose of 1g catalyst/ L. Fig.4. Influence of the hydrogen peroxide dose at different reaction time (C0Ph = 1 mM; catalyst dose of 1g/L, pH3; T= 303 K) 3.5. Influence of pH Fig.2. Influence of catalyst dose on the phenol conversion. ( C 0 Ph = 1 mM; C 0 H2O2 = 50 mM, pH3; T= 303 K) The results, represented in Fig. 5, have shown that the maximal conversion could be obtained with a pH between 2.5 and 3.0. This is in accordance with previous experimental and theoretical studies on homogeneous photo-Fenton process. 481

technical guidance documents - Institute for Health and Consumer ...
Proceedings 會 刊 - SCCAEPA SPONSORS
Proceedings 會 刊 - SCCAEPA SPONSORS
Researches - "Intersections" International Journal
Tri-Service Remedial Project Manager's Guide for Ecological Risk ...
Science Technology PowerPoint
ALcontrol Laboratories - Petroleumclub.ro
NASA Engineering & Safety Center NESC - NASA Risk ...
the prevention of oral and dental diseases in romania - European ...
MATHEMATICAL MODELS for ENGINEERING ... - Wseas.us
ADVANCES in ENVIRONMENTAL - Wseas.us
Journal information in easy print format (PDF) - Inderscience ...
mathematical_methods.. - WSEAS
mapa refacuta gata - Csinvest.ro
Download publication - The International Potash Institute
Editorial & Advisory Board - Acta Technica Corviniensis
european computing - Wseas.us
Mathematical Methods and Computational Techniques in ... - WSEAS
CTE Professional Organization Perspective - ACTE