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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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The coefficient of thermal expansion is defined by<br />

the coefficient of thermal expansion in Eq. (1.2-15)<br />

is used for gases and liquids.<br />

The coefficient of thermal expansion is an intensive<br />

quantity and is usually positive.<br />

That is, if the temperature is raised the volume<br />

usually increases.<br />

There are a few systems with negative values of<br />

the coefficient of thermal expansion. For<br />

example, liquid water has a negative value of α<br />

between 0 ◦ C and 3.98 ◦ C. In this range of<br />

temperature the volume of a sample of water<br />

decreases if the temperature is raised.<br />

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