Hóa học phức chất
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Mét sè d¹ng lai ho¸ obitan th−êng gÆp vµ cÊu<br />
tróc h×nh häc cña phøc chÊt<br />
Sè phèi<br />
trÝ<br />
D¹ng lai<br />
ho¸<br />
CÊu h×nh cña<br />
phøc chÊt<br />
VÝ dô<br />
2 sp Th¼ng [Cu(NH 3 ) 2 ] + , [CuCl 2 ] - [Ag(NH 3 ) 2 ] + ,<br />
[Ag(CN) 2 ] - ,<br />
4 sp 3 Tø diÖn [Zn(NH 3 ) 4 ] 2+ , [ZnCl 4 ] 2- , [BF 4 ] - ,<br />
[Be(OH) 4 ] 2-, [Hg(CN) 4 ] 2-<br />
4 dsp 2 Vu«ng ph¼ng [PtCl 4 ] 2- , [Ni(CN) 4 ] 2- , [Cu(NH 3 ) 4 ] 2+<br />
6 d 2 sp 3 B¸t diÖn [Co(NH 3 ) 6 ] 3+ , [Fe(CN) 6 ] 3-<br />
6 sp 3 d 2 B¸t diÖn [CoF 6 ] 3- , [PtCl 6 ] 2- ,<br />
[Al(H 2 O) 2 (OH) 4 ] - , [SnCl 6 ] 2- ,
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