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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Preparations

Preparations Grignard-Copper(I) reagents • Cu-catalyzed alkylation of organomagnesium reagents by RBr and RI in the presence of NMP (N-methylpyrrolidinone, a nontoxic, polar, aprotic solvent) represents an attractive alternative to the classical cuprate alkylation reaction. • Only a slight excess of the Grignard reagent is required, and the reaction tolerates keto, ester, amide and nitrile groups. This method is especially suited for large-scale preparations.

Reaction of Organocuprates Substitution of alkyl halides • coupling of a primary alkyl iodide with an organocuprate is more economical when using a heterocuprate than a homocuprate.

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