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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of

Reaction of Organocuprates Acylation • reaction of organocopper reagents with acid chlorides affords corresponding ketones in high yields. Retrosynthetically, the reaction amounts to an alkylation of a carboxylic acid. • In the presence of a catalytic amount of CuI, Grignard reagents convert acid chlorides chemoselectively to the corresponding ketones via a transiently formed cuprate reagent, which reacts competitively with the initial Grignard

Reaction of Organocuprates Epoxide cleavage reactions • R 2 Cu(CN)Li 2 reagents: among the mildest and most efficient reagents available for generating C-C bonds by way of epoxide cleavage using organocopper chemistry. • nucleophilic addition occurs at the less sterically hindered carbon of the oxirane ring

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