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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of

Reaction of Organocuprates Epoxide cleavage reactions (cont’d) • Stereospecific S N 2 opening of cyclic epoxides with cyanocuprates furnishes, after workup, the trans-2-hydroxyalkylated products.

Reaction of Organocuprates Epoxide cleavage reactions (cont’d) • However, the unsaturated epoxide reacts with cyanocuprates via an anti-S N 2-type mechanism. Directed epoxidation of the resultant allylic alcoholate produces a hydroxy epoxide containing 4 stereodefined carbon centers.

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