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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of

Reaction of Organocuprates Conjugate Addition • Conjugate addition is an important C–C bond formation • Organometallic reagents may add in a 1,2- or 1,4-manner to α,β-unsaturated carbonyl compounds.

Reaction of Organocuprates Conjugate Addition (cont’d) • 1,4-Addition (conjugate addition) is most successful with “soft” (relatively nonbasic) nucleophiles such as –C≡N, RNH 2 , RNH, RSH, enolates derived from β-dicarbonyl compounds, and organocuprates. • 1,2-Addition is most successful with “hard” (relatively basic) nucleophiles such as hydride, organolithiums, and Grignard

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