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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of

Reaction of Organocuprates Stereochemistry of 1,4-addition • Note that the 4-methylcyclohexenone gives preferentially the trans-product. • In this case, the reaction proceeds via a conformation with the Me group being pseudoaxial due to A 1,2 strain. • addition of organocuprates to enones followed by alkylation of resultant enolates generates 2 C-C bonds in a single reaction

Reaction of Organocuprates Stereochemistry of 1,4-addition • Alkylation of an enolate proceeds via an early, hence a reactant-like, transition state. • Thus, steric factors in the ground state play an important role.

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