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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Organozinc compounds •

Organozinc compounds • In contrast to the polar nature of C–Li and C–MgX bonds, the C–Zn bond is highly covalent and hence less reactive, allowing the preparation of functionalized derivatives. • The carbon zinc bond is polarized towards carbon due to the differences in electronegativity --- carbon: 2.55 and zinc:1.65 • utilization of organozinc reagents mainly focused around preparation and utilization of functional organozinc compounds in organic syntheses (Reformatsky reaction), cyclopropanation (Simmons-Smith reaction), and transmetalations with transition metals.

Organozinc reagents • The first organozinc ever prepared = diethylzinc (Et 2 Zn), by Edward Frankland in 1849, was also the first ever compound with a metal to carbon sigma bond. • Many organozinc compounds are pyrophoric and therefore difficult to handle. • Organozinc compounds in general are sensitive to oxidation, dissolve in a wide variety of solvents where protic solvents cause decomposition. • In many reactions they are prepared in situ. All reactions require inert atmosphere: N 2 or Ar • The three main classes of organozincs are: organozinc halides R-Zn-X with, diorganozincs R-Zn-R, and lithium zincates or magnesium zincates M + R3Zn - with M = lithium or magnesium

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