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Cu_Zn_Organometallics

its all about organometallic chemistry of zinc and copper metal

Reaction of Organozinc

Reaction of Organozinc compounds Directed Simmons-Smith Cyclopropanation • A particularly interesting aspect of the Simmons-Smith reaction is the stereoelectronic control exhibited by proximal OH, OR groups, which favor cyclopropanation to occur from the same face of the double bond as the oxy substituents. • order of decreasing directive effects : OH > OR > C=O

Reaction of Organozinc compounds Transmetalation • Although the C–Zn bond is rather unreactive toward electrophiles such as aldehydes, ketones, esters, and nitriles, it undergoes transmetalations with many transition metal complexes to furnish new organometallics capable of reacting with a variety of electrophilic substrate. • See the use in Coupling reactions later in the course.

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