Radical Cations
Radical Cations
Radical Cations
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n-C-C •+ Bond Dissociation<br />
� To drive the reaction, the electrophore must be highly prone to oxidation or the resulting radical<br />
must be stabilized by a moiety on the molecule<br />
N<br />
H<br />
N<br />
H<br />
N<br />
CO 2Me<br />
V<br />
N<br />
Et<br />
H<br />
CHO 2Me<br />
Et<br />
anode,<br />
2,6-lutidine<br />
MeCN,<br />
Et 4NClO 4<br />
NaBH 4<br />
N<br />
H<br />
V<br />
N<br />
H<br />
N<br />
N<br />
CO 2Me<br />
CO2Me Et<br />
Et<br />
Et<br />
AcO<br />
MeO 2C<br />
N<br />
N<br />
H<br />
OH Me<br />
N<br />
H<br />
M. J. Gašić et al. J. Chem. Soc. Chem. Comm. 1993, 1496.<br />
N<br />
N<br />
CO 2Me<br />
–e –<br />
N<br />
Et<br />
CO 2Me<br />
OMe<br />
Et
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