Issue 06/2018
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ISSN 1862-5258<br />
Nov / Dec<br />
<strong>06</strong> | <strong>2018</strong><br />
Compostable<br />
sanitary napkin<br />
project wins<br />
13th Global<br />
Bioplastics Award<br />
| 10<br />
bioplastics MAGAZINE Vol. 13<br />
Highlights<br />
Bioplastics from waste streams | 20<br />
Films, flexibles, bags | 12<br />
... is read in 92 countries
BIO-FLEX ®<br />
AS VERSATILE AS YOUR REQUIREMENTS<br />
Biobased up to 85 %<br />
Certifi ed home compostable<br />
Certifi ed industrial compostable<br />
Heat resistant<br />
Food contact approved<br />
Easy processable on existing equipment
Editorial<br />
dear<br />
readers<br />
As you read these lines, the 13 th European Bioplastics Conference in Berlin is over<br />
or – for some of you – still going on. And as always, we are grateful to European<br />
Bioplastics for giving us the opportunity to present the Annual Global Bioplastics<br />
Award at this prestigious event. For those of you who missed it, turn to page 10,<br />
where we present this year’s winner. We had already reported about the project<br />
earlier this year, and it so happened that the development was anonymously<br />
proposed for the award – and won.<br />
Films, Flexibles, Bags is traditionally the first highlight topic of every December<br />
issue of bioplastics MAGAZINE. And the other this year is Bioplastics made from<br />
waste streams.<br />
It is also interesting to see that in the aftermath of our 1 st PHA platform World<br />
Congress , the response continues. A group of four experts have now come<br />
together to found GO!PHA - the Global Organization for PHA - a global initiative to<br />
accelerate the development of the PHA-platform industry.<br />
As always, we’ve rounded up some of the most recent news items on materials<br />
and applications to keep you abreast of the latest innovations and ongoing<br />
advances in the world of bioplastics.<br />
Lastly, I’d like to remind you of the 3 rd bio!PAC conference on biobased<br />
packaging in Düsseldorf next May – the call for papers is still open. If you have<br />
an interesting topic to report on, please let us know. The same goes for the<br />
first international bio!TOY conference. At the end of March, we are going to bring<br />
together raw material suppliers and toy manufacturers in Nürnberg, Germany, the Toy<br />
City. See pages 11 and 13 for details.<br />
Let me take this opportunity to wish you all a relaxing time over the holidays as this<br />
year comes to an end. Together with you, our readers, we look forward with confidence<br />
to a new year of challenges, innovations - and events. On our calendar, we’ve already<br />
marked down Chinaplas, taking place next year at a new location in Guangzhou and<br />
of course the K’show in Düsseldorf in October and a host of other events. We’ll be<br />
covering as many of these events as possible - and we hope to see you there, too.<br />
Until then, please enjoy reading bioplastics MAGAZINE.<br />
bioplastics MAGAZINE Vol. 13<br />
ISSN 1862-5258<br />
Compostable<br />
sanitary napkin<br />
project wins<br />
13th Global<br />
Bioplastics Award<br />
| 10<br />
Highlights<br />
Bioplastics from waste streams | 20<br />
Films, flexibles, bags | 12<br />
Nov / Dec<br />
<strong>06</strong> | <strong>2018</strong><br />
... is read in 92 countries<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Michael Thielen<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 3
Content<br />
Imprint<br />
Nov / Dec <strong>06</strong>|<strong>2018</strong><br />
3 Editorial<br />
5 News<br />
10 Events<br />
36 Application News<br />
41 Brand Owner<br />
45 10 years ago<br />
46 Basics<br />
50 Suppliers Guide<br />
53 Event Calendar<br />
54 Companies in this issue<br />
Bioplastics Award<br />
10 And the winner is..<br />
Films/Flexibles/Bags<br />
12 What’s new for cellulose based films<br />
14 That’s not my bag<br />
From Science & Research<br />
18 PLA in the post-consumer-recycling stream<br />
28 Improved biobased fibres for clothing applications<br />
29 New method for high yield FDCS production<br />
30 Compostable plastics behaviour<br />
42 Land use<br />
Report<br />
32 Go!PHA<br />
39 Tui-Cruises<br />
Bioplastics from waste streams<br />
20 Waste cooking oil as source for PHA<br />
22 Is Algae a sustainable feedstock<br />
24 Valorizing side stream<br />
Materials<br />
26 Calcium Carbonate opens new<br />
opportunities for the use of PLA<br />
Applications<br />
34 PLA in the fridge<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
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phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
sb@bioplasticsmagazine.com<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 3.400 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
92 countries.<br />
Every effort is made to verify all Information<br />
published, but Polymedia Publisher<br />
cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
arise as a result.<br />
All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
www.bioplasticsmagazine.com are strictly<br />
covered by copyright. No part of this<br />
publication may be reproduced, copied,<br />
scanned, photographed and/or stored<br />
in any form, including electronic format,<br />
without the prior consent of the publisher.<br />
Opinions expressed in articles do not<br />
necessarily reflect those of Polymedia<br />
Publisher.<br />
bioplastics MAGAZINE welcomes contributions<br />
for publication. Submissions are<br />
accepted on the basis of full assignment<br />
of copyright to Polymedia Publisher GmbH<br />
unless otherwise agreed in advance and in<br />
writing. We reserve the right to edit items<br />
for reasons of space, clarity or legality.<br />
Please contact the editorial office via<br />
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The fact that product names may not be<br />
identified in our editorial as trade marks<br />
is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped sponsored bioplastic<br />
envelopes<br />
Cover<br />
Aakar Innovations<br />
Follow us on twitter:<br />
http://twitter.com/bioplasticsmag<br />
Like us on Facebook:<br />
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daily upated news at<br />
www.bioplasticsmagazine.com<br />
Novamont opened new<br />
Origo-Bi production site<br />
News<br />
The official inauguration of Mater-Biopolymer, Novamont’s newly refurbished<br />
site for the production of its biodegradable biopolyester Origo-Bi, took place on<br />
19 October, in Patrica, Italy.<br />
At the end of the preceding "The Regeneration continues" conference, the guests,<br />
including representatives of institutions, local administrations, universities and<br />
research and industrial partners of the Group, were given a tour of the plant to have<br />
an opportunity to take a closer look at the production process.<br />
In line with Novamont’s strategy of revitalizing sites that have become old and<br />
obsolete, the new Mater-Biopolymer has been converted from a former PET<br />
production plant into a modern facility for the production of biopolyesters based<br />
on renewable raw materials, using a more sustainable and low-emission process.<br />
The highly efficient plant is equipped with a complex system of utilities to minimize<br />
costs and waste through the recovery and enhancement of waste. In 2016, the site<br />
started the construction of a waste water distillation section from the process that<br />
made it possible to recover the tetrahydrofuran (THF) that is generated during the<br />
polymerization reaction, which, once distilled, is destined for the chemical and<br />
pharmaceutical industries, among other things. MT<br />
www.novamont.com<br />
Think Sustainable<br />
M·VERA ®<br />
Bioplastics<br />
With our M·VERA® range of<br />
biobased and biodegradable<br />
plastics (certified according<br />
to EN 13432), we provide you<br />
with customised solutions<br />
for your application:<br />
• Film<br />
Such as shopping bags,<br />
fruit and vegetable bags<br />
or agricultural films<br />
• Injection Moulding<br />
Such as packaging, coffee<br />
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• Color, Carbon Black and<br />
Additive Masterbatches<br />
Our team of highly experienced<br />
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help you – contact us!<br />
Braskem joins Europe’s Bio-based<br />
Industries Consortium (BIC)<br />
Chemicals company Braskem announces it has joined European network Biobased<br />
Industries Consortium (BIC) as a full member.<br />
BIC represents the private sector in the Bio-based Industries Joint Undertaking<br />
(BBI JU), a public-private partnership (PPP) with the EU worth €3.7 billion. By<br />
joining BIC, Braskem has become part of a wider network committed to bringing<br />
bio-based products to market.<br />
Established as a pillar of the European Commission Bioeconomy Strategy, BBI JU<br />
operates under EU research and innovation programme Horizon 2020. It supports<br />
the development and production of bio-based products in Europe via biorefining<br />
research and demonstration projects, including large-scale commercialisation,<br />
through investment in innovative manufacturing facilities and processes. MT<br />
www.braskem.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne · Nattermannallee 1<br />
50829 Cologne · Germany<br />
Phone: +49 221 88 8894-00<br />
Fax: +49 221 88 88 94-99<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Unilever and Bio-on work together<br />
Unilever (headquartered in Rotterdam, The Netherlands)<br />
and Bio-on (Bologna, Italy) recently announced the start of a<br />
strategic partnership to develop, produce and sell personal<br />
hygiene and care products that guarantee a smaller or no<br />
environmental impact. Using patented bio-technologies<br />
for natural, biodegradable microplastics (PHA) production,<br />
Unilever and Bio-on are taking an important step towards<br />
building a more sustainable economy and more responsible<br />
consumption in the personal care sector.<br />
This collaboration is designed to meet the demands<br />
of consumers, who are increasingly concerned about<br />
sustainability and making purchasing choices that respect<br />
the environment, whilst making the most of the skills and<br />
excellence at both companies.<br />
Unilever's knowledge and large-scale presence on the<br />
personal care market with noted brands such as Mentadent,<br />
Dove, Zendium, Glysolid, and Sunsilk, teams up with the<br />
exclusive know-how of Bio-on, specialised in biotechnologies<br />
applied to widely used materials, to create completely natural<br />
products and solutions.<br />
"For Unilever, developing a partnership with such an<br />
excellent Italian company as Bio-on is an important step<br />
towards the goals we have set ourselves with the Unilever<br />
Sustainable Living Plan, primarily to halve the environmental<br />
impact of our products by 2030," claims Fulvio Guarneri,<br />
Chairman & CEO of Unilever Italia. "This collaboration<br />
makes us very proud because it is one of the most important<br />
examples through which Unilever is making concrete moves<br />
towards sustainability in our business strategy."<br />
"Research into innovative products and cutting-edge<br />
formulations that respect the environment and people is<br />
now a priority in the personal care sector," explains Marco<br />
Astorri, Chairman and CEO of Bio-on. "We are very pleased<br />
to work alongside such a major player as Unilever, with<br />
which we will have the great opportunity to introduce real<br />
sustainable innovation whilst reaching an increasingly broad<br />
consumer base." Bio-on will work with Unilever through two<br />
new companies, which will focus 100% on exploiting exclusive<br />
technologies to develop, produce and supply personal care<br />
products. MT<br />
www.bio-on.it | www.unilever.it<br />
Dupont completes expansion of Sorona production<br />
DuPont Industrial Biosciences has completed the expansion<br />
of their Kinston, NC manufacturing facility, which produces<br />
bio-based, high-performance DuPont Sorona ® polymers<br />
From the expansion, DuPont has increased the facility’s<br />
capacity to produce Sorona polymer by 25%. This investment<br />
is reflective of the growing demand for Sorona polymer<br />
throughout the carpet and apparel markets and an emerging<br />
global focus on building the circular economy.<br />
“This expansion is a direct result of the significant growth<br />
in global demand for Sorona polymer and a testament to<br />
DuPont’s commitment to manufacturing innovative products in<br />
North Carolina,” says Michael Saltzberg, Ph.D., global business<br />
director of DuPont Biomaterials. “We are grateful for the support<br />
from partners that made this project possible including: Lenoir<br />
County Economic Development, North Carolina Community<br />
College System, Lenoir Community College, Duke Energy<br />
Corporation, North Carolina Department of Commerce and<br />
North Carolina Department of Transportation.”<br />
DuPont Sorona polymer is made from 37 % renewable<br />
plant-based ingredients and has many versatile applications.<br />
As compared to similar materials, like nylon 6, Sorona<br />
polymer uses 30 % less energy and releases 63 % fewer<br />
greenhouse gas emissions. In addition to reducing its reliance<br />
on fossil fuels, Sorona polymer combines eco-efficiency with<br />
function, as its high-performance qualities can be used in<br />
a variety of applications. Fibers made with Sorona polymer<br />
exhibit exceptional softness, inherent stain resistance and<br />
uncompromising durability, offering a sustainable, highperforming<br />
material option for customers throughout the<br />
supply chain.<br />
DuPont Industrial Biosciences employs more than 90<br />
workers in Kinston through the manufacturing of Sorona<br />
polymer. With the startup of the line, four additional employees<br />
also are being recruited. MT<br />
tinyurl.com/sorona<br />
Magnetic<br />
for Plastics<br />
www.plasticker.com<br />
• International Trade<br />
in Raw Materials, Machinery & Products Free of Charge.<br />
• Daily News<br />
from the Industrial Sector and the Plastics Markets.<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives, Machinery & Equipment, Subcontractors<br />
and Services.<br />
• Job Market<br />
for Specialists and Executive Staff in the Plastics Industry.<br />
Up-to-date • Fast • Professional<br />
6 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
daily upated news at<br />
www.bioplasticsmagazine.com<br />
News<br />
EU Parliament's single-use plastics ban -<br />
Bioplastics can provide an alternative, EUBP says<br />
The European Parliament recently approved its report on the draft Directive on Marine Pollution and Single-use Plastics.<br />
“European Bioplastics fully supports the transition from a linear to a circular economy. Bioplastics enable more sustainable<br />
solutions for a range of products“, says François de Bie, Chairman of European Bioplastics (EUBP).“We agree on the importance<br />
of reducing single-use plastic products where feasible, but hygiene and food safety cannot be compromised. With regard to<br />
some of the concerned single-use products – such as e.g. plates and cutlery –, biodegradable certified compostable plastics<br />
provide an organically recyclable alternative“.<br />
EUBP considers the Parliament’s decision to restrict the use of single-use cutlery and plates as not sufficiently considering<br />
the reality of food consumption in Europe. In certain closed-loop contexts, such as canteens, air travel, or sport and music<br />
events, these are an indispensable and efficient solution to guarantee safety and hygiene for food and drinks while ensuring at<br />
the same time waste collection and recycling.<br />
Biodegradable certified compostable plastics fulfil Europe’s rigorous requirements and standards for health and safety and<br />
can be recycled organically together with the food waste.<br />
EUBP fully supports the Parliament’s suggestion to restrict products made from oxo-degradable plastics, which is in line<br />
with earlier statements by the Parliament and the European Commission in the context of the EU Plastics Strategy.<br />
Concerning biodegradability in the marine environment, EUBP stresses that it is an interesting property. However, it needs<br />
to be clearly defined for which materials, products and under which circumstances this property is of added value. Improving<br />
waste management on land and building efficient mechanical and organic recycling infrastructures across Europe remain a<br />
priority when it comes to fighting marine pollution.<br />
EUBP looks forward to further constructive discussions with the European Commission, the Parliament, and the Council<br />
during the upcoming trilogues in order to realise a truly sustainable, no-litter, circular economy for Europe. MT<br />
www.european-bioplastics.org<br />
HIGH WE DRIVE THROUGHPUT. THE<br />
DIAMEETS CIRCULAR ECONOMY. QUALITY.<br />
Whether it is inhouse, postconsumer<br />
or bottle recycling:<br />
you can only close loops in a<br />
precise and profitable way if<br />
machines are perfectly tuned<br />
for the respective application.<br />
Count on the number 1<br />
technology from EREMA<br />
when doing so: over 5000<br />
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produce around 14 million<br />
tonnes of high-quality pellets<br />
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That’s Careformance!<br />
CAREFORMANCE<br />
We care about your performance.<br />
1710013ERE_ins_bioplastics magazine.indd 1 bioplastics MAGAZINE 18.10.17 [<strong>06</strong>/18] Vol. 14:313 7
News<br />
thyssenkrupp commissions first commercial<br />
PLA plant for COFCO in China<br />
To reduce reliance on petroleum-based plastics,<br />
thyssenkrupp has developed a manufacturing process<br />
for the bioplastic PLA. The world’s first commercial plant<br />
based on the patented PLAneo ® technology recently started<br />
production in Changchun, China. It is operated by the Jilin<br />
COFCO Biomaterial Corporation, a subsidiary of COFCO,<br />
China’s largest food and beverage group. The new plant with<br />
an initial capacity of 10,000 tonnes, produces all standard PLA<br />
types, among other things for the production of eco-friendly<br />
packaging, fibers, textiles and engineering plastics.<br />
the technology, thyssenkrupp’s subsidiary Uhde Inventa-<br />
Fischer profited from decades of expertise gained from the<br />
construction of more than 400 polymerization plants and<br />
extensive experience in the scale-up of new technologies.<br />
For the new plant in Changchun thyssenkrupp provided<br />
the engineering, key plant components and supervision of<br />
construction and commissioning. MT<br />
www.thyssenkrupp-industrial-solutions.com<br />
Sami Pelkonen, CEO of the Electrolysis & Polymers<br />
Technologies business unit of thyssenkrupp Industrial<br />
Solutions: “The bioplastics market will continue to grow in the<br />
coming years, not least due to the increasing environmental<br />
awareness of industry, governments and consumers. With our<br />
PLAneo technology we want to do our bit to make the plastics<br />
sector more sustainable and resource-friendly. With it we<br />
enable our customers to produce high-quality bioplastics with<br />
a wide range of properties – at a price that is competitive with<br />
conventional plastics.”<br />
PLAneo technology converts lactic acid into PLA in a<br />
particularly efficient and resource friendly way. Another<br />
advantage is its transferability to large-scale plants with<br />
capacities of up to 100,000 tons per year. In developing<br />
Neste and Clariant will collaborate<br />
Neste, the world’s leading provider of sustainable renewable<br />
diesel and an expert in delivering drop-in renewable chemical<br />
solutions, and Clariant, a world leader in specialty chemicals,<br />
have signed an agreement to collaborate on the development<br />
of new sustainable material solutions targeted at a range of<br />
industries.<br />
In the first phase of the partnership, the companies will<br />
start replacing fossil-based ethylene and propylene used in<br />
Clariant’s top-quality hot-melt adhesives, with monomers<br />
derived from renewable feedstock. This is enabled by turning<br />
Neste’s renewable hydrocarbons – produced 100 % from<br />
renewable raw materials, such as waste and residue fats and<br />
oils as well as vegetable oils – into ethylene and propylene for<br />
Clariant’s products.<br />
In a later phase, the companies will also develop other<br />
sustainable additive solutions derived from renewable raw<br />
materials for plastics and coatings applications. This will<br />
enable the two companies to help various sustainabilityfocused<br />
brand owners – such as those producing furniture,<br />
sporting goods, hygiene products, electronics, and cars – to<br />
increase their bio-based offering while also reducing crude oil<br />
dependency and climate emissions.<br />
“We are proud to join forces with Clariant, one of the<br />
most innovative players in the specialty chemicals industry.<br />
Collaboration marks an essential step forward in Neste’s<br />
quest to become a preferred partner as a provider of<br />
sustainable chemicals solutions for forerunner brands”, says<br />
Peter Vanacker, President & CEO from Neste.<br />
“Combining Clariant’s in-depth knowhow in the varying<br />
applications of adhesives, plastics, and coatings, with Neste’s<br />
extensive knowledge and experience in working with biobased<br />
materials to produce a variety of drop-in renewable<br />
solutions, enables both companies to develop their sustainable<br />
material offering to provide maximum added value not only<br />
to sustainable brands in varying industries but also to their<br />
customers,” Vanacker adds.<br />
“For society, our environment, and future generations, it is<br />
our responsibility to improve sustainability performance and<br />
reduce our carbon footprint and dependency on crude oil. As<br />
a result of Clariant’s partnership with Neste, we can progress<br />
our goal to become a true sustainable solution provider in<br />
the additive market, offering our customers products and<br />
solutions that can make a positive contribution towards their<br />
targets and enhance end applications,” continues Gloria<br />
Glang, Vice President, Head of Global Advanced Surface<br />
Solutions Business at Clariant. MT<br />
www.neste.com | www.clariant.com<br />
8 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of the past two months.<br />
The story that got the most clicks from the visitors to<br />
bioplasticsmagazine.com was:<br />
re:thinking<br />
plastic<br />
UK judge finds the case for oxo-degradable plastic ‘compelling’<br />
(05 November <strong>2018</strong>)<br />
In a further twist of the oxy-degradable plastics saga, Symphony Environmental<br />
Technologies PLC today (5th November <strong>2018</strong>) heard the news that lawyer and<br />
former deputy Judge of the High Court in England, Peter Susman QC, has declared<br />
the scientific case for oxo-biodegradable technologies to be “clear and compelling”.<br />
A commentary by bioplastics MAGAZINE.<br />
Produced<br />
exclusively from<br />
pure plant-based,<br />
renewable<br />
resources!<br />
Biome Bioplastics'<br />
educational channel<br />
Biome Bioplastics, Southampton, UK, has launched a digital educational channel,<br />
#ThinkBioplastic. The platform aims to help government, media and the public<br />
better understand the complexities of plastics and plastic pollution and learn more<br />
about available alternatives.<br />
#ThinkBioplastic will share content about the whole plastic life cycle (production,<br />
use and disposal) and investigate the science behind recent plastic’s headlines.<br />
It will highlight the role of bioplastic in reducing the negative impact of polymer<br />
manufacture and disposal. All content will be in an easily digestible form.<br />
Biome Bioplastics CEO Paul Mines explains the motivation behind the channel:<br />
“The recent extensive coverage on plastic, while increasing awareness of the<br />
problem, has also increased people’s confusion about the existing solutions. We<br />
decided to take the matter into our own hands and form a necessary back-to-basic<br />
approach that puts the emphasis on science and fact. We hope to cut through some<br />
of the noise in this debate and empower people to make their own choices.”<br />
The channel has already received support from experts in the biobased industry.<br />
Professor Adrian Higson, Director at NNFCC, said the #ThinkBioplastic platform<br />
will help inform individuals about the ‘already available solutions’ to the plastic<br />
problem. He added: “In turn, this can shine a new light on the opportunity that<br />
biobased and biodegradable plastics represent, to shift towards a sustainable<br />
bioeconomy - a move that could eliminate dependency on fossil fuels.”<br />
#ThinkBioplastic will also be working with ambassadors, such as award-winning<br />
wildlife photographer Sue Flood, who has spent almost 30 years as a wildlife<br />
filmmaker and photographer, among others as a member of the team that produced<br />
the acclaimed Blue Planet and Planet Earth documentaries. MT<br />
www.thinkbioplastic.com<br />
Our premium range from<br />
renewable raw materials<br />
With Joma Nature® we offer a select<br />
range of our Spice Grinders and our<br />
Securibox® as an environmentally<br />
conscious alternative to conventional<br />
products – sustainable and CO 2-neutral.<br />
For our environment, we aim to<br />
protect our natural surroundings<br />
and secure a livable world for our<br />
children.<br />
www.jomapackaging.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 9
Award<br />
And the winner is ...<br />
The 13 th Global Bioplastics Award <strong>2018</strong> was<br />
given to Aakar Innovations for their biobased<br />
sanitary pads for girls and women in rural India<br />
Aakar Innovations Pvt. Ltd. from Belapur, Mumbai,<br />
India developed a fully compostable sanitary pad for<br />
girls and women in rural India. The pads are manufactured<br />
in local decentralized workshop locations by the local<br />
women of the region.<br />
Arunachalam Murugananphan is the social entrepreneur<br />
that made this all happen and received the innovation<br />
award from the President of India. Aakar Innovations<br />
follows in those pioneering footsteps and takes it a step<br />
further by introducing the element of environmental and<br />
social responsibility. Using biobased and fully compostable<br />
materials, Aakar is manufacturing sanitary pads using<br />
rural, low cost manufacturing and also providing jobs to<br />
women in rural villages.<br />
Aakar is a hybrid social enterprise that enables women<br />
to produce and distribute affordable, high-quality, 100 %<br />
compostable sanitary napkins within their communities<br />
while simultaneously raising awareness and sensitization<br />
of menstrual hygiene management. That’s why Aakar<br />
launched a 100 % compostable sanitary pad under the<br />
brand name Anandi.<br />
Anandi is a 100 % compostable sanitary napkin using<br />
biobased compostable polymer film. It uses virgin soft<br />
pine wood pulp containing more than 97 % of cellulose and<br />
hemi-cellulose. The wood pulp as used has pure cellulose<br />
materials with complete uniformity of fibers allowing it to<br />
decompose easily. Activated by an only eco-friendly ozone<br />
treatment process and using compostable bioplastic. The<br />
root sources of the material used is from naturally available<br />
corn starch.<br />
The judges were impressed with the holistic concept,<br />
addressing the social, economic and environmental<br />
elements at the same time. A perfect example of what<br />
sustainability is all about! It is tangible, helping millions<br />
of women in rural India, and shows how bioplastics can<br />
advance the cause of environmental and social justice in a<br />
responsible manner. All bioplastic components are certified<br />
compostable as per EN 13432 or ASTM D6400. A certification<br />
for soil degradability is being awaited and will complete a<br />
truly remarkable story of empowerment, social justice and<br />
environmental responsibility<br />
The prize was awarded to the winning company on<br />
December 4 th , <strong>2018</strong> during the 13 th European Bioplastics<br />
Conference in Berlin, Germany. MT<br />
www.aakarinnovations.com<br />
10 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12
Events<br />
bioplastics MAGAZINE presents a first of its kind:<br />
call for papers<br />
Conference on Biobased Materials in Toy Applications<br />
27 - 28 March 2019 - Nürnberg, Germany<br />
The biobased polymer supply chain meets the toy maker industry and trade.<br />
• More than 20 presentations with focus on suitable materials and user experiences<br />
• Background information on regulation / policy, and funding opportunities in EU<br />
• Table-top exhibition of business and technology leaders<br />
• Time and atmosphere supporting business development through dialog<br />
• Media and PR programme to spread the news<br />
• Supported by the German Toy Maker Association DVSI<br />
Driving innovation, sustainability and product safety to the next level.<br />
Explore new ways with biobased plastics.<br />
Confirmed speakers include:<br />
Lego, Bioseries, Bioblo, eKoala, Braskem, FKuR, Tecnaro, Hexpol TPE,<br />
nova-Institute and DVSI<br />
Call for Papers is still open. For updated information and opportunities on programme,<br />
exhibiting, sponsoring, etc. visit the website or contact mt@bioplasticsmagazine.com<br />
Gold Sponsor<br />
Silver Sponsor<br />
Coorganized by<br />
Innovation Consulting Harald Kaeb<br />
supported by<br />
Media Partner<br />
1 st Media Partner<br />
#bio-toy<br />
www.bio-toy.info
Films/Flexibles/Bags<br />
What’s new in<br />
cellulose based films<br />
When Futamura<br />
acquired its<br />
cellulose films<br />
business in 2016, including<br />
the trademark brands<br />
Cellophane and NatureFlex, the<br />
business was already braced for positive change,<br />
with early investment from owners Futamura, the cellulose<br />
films business based in Wigton (Cumbria, UK) and Tecumseh<br />
(Kansas, USA), strengthened its core production facilities<br />
and planned for strategic growth. Then who could have<br />
foreseen that the broadcast of one BBC nature documentary,<br />
Sir David Attenborough’s Blue Planet II, would put the<br />
metaphorical cat amongst the pigeons (or catfish amongst<br />
the shrimp?) turning this plastic world as we know it upside<br />
down and placing a spotlight on bio-material alternatives to<br />
single-use conventional plastics.<br />
Traditionally, renewable and compostable NatureFlex<br />
films are in popular with ethical companies wanting to do<br />
the right thing with their packaging, and increasingly from<br />
new business start-ups who want to get their sustainable<br />
packaging journey kicked off on the right foot, right through<br />
to retailers and large brand owners who are more and more<br />
considering bio-alternatives to conventional plastic films<br />
for main stream brands.<br />
NatureFlex is ideal for flexible applications packaging<br />
fresh produce, as well as dry products such as tea and<br />
coffee. However, there are great success stories when<br />
laminated to other bio-materials such as; The Curiosity<br />
Co. bacon, which has received much attention following<br />
the launch of the UK’s first so-called PLASTIC FREE ® aisle<br />
at the Thornton’s Budgens Bellsize park store in early<br />
November. In addition to bacon packs, NatureFlex was<br />
used by Budgen’s to replace cling film for wrapping their<br />
deli cheese, and could be found in numerous flexible packs<br />
in store ranging from the recently launched Two Farmer’s<br />
crisp range to Tea Pigs.<br />
The Plastic Free Trustmark, created by A Plastic Planet,<br />
states in its criteria that a flexible package must be certified<br />
to the EN13432 standard and / or TÜV Austria Home<br />
compost, making NatureFlex the ideal solution either<br />
on its own or laminated to other certified compostable<br />
biomaterials.<br />
Other applications using NatureFlex films include<br />
pouches, cereal liners, coffee capsules (lidding), and<br />
sachets for tea, coffee, herbs and spices and flow wraps for<br />
chocolate bars, overwrap for yeast, tea cartons and many<br />
more everyday items. MT<br />
www.futamuragroup.com<br />
12 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Automotive Events<br />
bioplastics MAGAZINE presents:<br />
bio PAC<br />
call for papers<br />
Conference on Biobased Packaging<br />
28 - 29 May 2019 - Düsseldorf, Germany<br />
Biobased packaging<br />
» can be recyclable and/or compostable<br />
» fits into the circular economy of the future<br />
» is made from renewable resources or waste streams<br />
» can offer environmental benefits in the end-of-life phase<br />
» can offer innovative features and beneficial barrier properties<br />
» can help to reduce the depletion of finite fossil resources and CO 2<br />
emissions<br />
That‘s why bioplastics MAGAZINE (in cooperation with Green Serendipity) is now<br />
organizing the third edition of<br />
bio PAC<br />
The 2 day-conference will be held on the<br />
28 th and 29 th of May 2019 in Düssseldorf, Germany<br />
Confirmed speakers include:<br />
BASF (Martin Bussmann), Ecoplaza (Steven Iijzerman),<br />
FKuR (Patrick Zimmermann), Novamont (Albertro Castellanza),<br />
Green Serendipity (Caroli Buitenhuis), Bio4pack (Patrick Gerritsen),<br />
Braskem (Marco Jansen), nova-Institute (Michael Carus),<br />
European Bioplastics, narocon (Harald Kaeb)<br />
Call for Papers is still open: Please send your proposal to mt@bioplasticsmagazine.com<br />
supported by<br />
Coorganized by<br />
Gold Sponsor<br />
1 st Media Partner<br />
Media Partner<br />
#bio-pac<br />
www.bio-pac.info
Films/Flexibles/Bags<br />
That’s not my bag –<br />
or is it?<br />
Certified compostable film applications with multiple benefits<br />
and different mechanical and thermal properties. The main<br />
application areas are films for organic waste bags, fruit<br />
and vegetable bags and dual-use bags (first for shopping,<br />
then for organic waste), multilayer packaging materials,<br />
and agricultural films. The certified compostable, partly<br />
biobased plastics are in no way inferior to conventional<br />
materials: they are just as effective and resistant, can be<br />
processed with conventional machinery, and are ideal for<br />
developing innovative solutions.<br />
ecovio F is suitable for producing compostable multilayer films<br />
with good barrier properties for packaging applications like coffee<br />
capsule pouches.<br />
Lightweight, tear-resistant and waterproof – thanks to<br />
their exceptional properties, plastic bags and films<br />
make our lives easier. But when it comes to biowaste<br />
collection, they can contribute to the formation of microplastic<br />
when disposed of together with organic waste. The<br />
EU commission estimates that the recycling rates for thin<br />
plastic bags will not rise above 10 % by 2020. For all applications<br />
that cannot be recycled mechnically, BASF offers the<br />
certified compostable plastic ecovio ® . It can be used to produce<br />
compostable blown films, thermoformable flat films<br />
or multilayer films, for applications as diverse as shopping<br />
bags, food packaging and agricultural films.<br />
Plastic bags and films help to keep food fresh, are a<br />
convenient way of carrying our shopping, and ensure<br />
that waste is disposed of hygienically. But when it comes<br />
to disposal, they cannot always be easily separated into<br />
their individual components for mechanical recycling.<br />
In addition, society is increasingly looking for alternative<br />
product solutions which are environmentally sustainable<br />
but are still just as convenient.<br />
With ecovio, which is made from the compostable and<br />
biodegradable BASF plastic ecoflex ® and polylactic acid<br />
(PLA), BASF developed in 20<strong>06</strong> a biodegradable plastic<br />
which is certified to EN13432 for industrial composting.<br />
Since then a broad range of different ecovio grades has been<br />
introduced into the market, with varying biobased contents<br />
Kitchen and food waste can be hygienically collected in<br />
organic waste bags made from ecovio F, then turned into<br />
compost in industrial composting facilities along with the<br />
bag. Thanks to its good resistance to moisture, liquid does<br />
not leak through, so there is no need to wash out the compost<br />
bin. Because of the material’s excellent tensile strength and<br />
hence load-carrying capacity ecovio F can also be employed<br />
to make shopping bags. They are strong enough to be<br />
reused several times before finally being used as organic<br />
waste bags. Bags and pouches made from ecovio can be<br />
both welded and printed, so they can be clearly labeled as<br />
compostable, for example.<br />
Fruit and vegetable bags made of ecovio are more than<br />
simple carrier bags, too. The blown films can be extruded in<br />
the range from 10 to 12µm. They can be reused as organic<br />
waste bags and thus improve the collection and recovery of<br />
organic food waste. The bags possess high tear and wear<br />
Fruit and vegetable bags made of ecovio possess high tear and<br />
wear stability, are approved for food contact and reduce food<br />
losses due to their good breathability.<br />
14 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Films/Flexibles/Bags<br />
By:<br />
Martin Bussmann, Jörg Auffermann, Dirk Stärke<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Conventional mulch films made of polyethylene (PE) have to<br />
be collected from the fields and recycled after harvesting.<br />
Because of earth and plant remnants sticking to the films<br />
recycling is more difficult or even impossible. Mulch films<br />
made of ecovio M2351 are completely and biologically<br />
degraded by microorganisms like bacteria and fungi that<br />
exist naturally in the soil. Farmers can simply plow the<br />
ecovio mulch films back into the ground along with the<br />
plant debris. This saves time and money.<br />
ecovio M2351 is a ready-to-use compound that can<br />
be processed into soil-biodegradable mulch films on<br />
conventional PE film extrusion lines without the need for<br />
any additional slip or anti-block agents. Because of the<br />
material’s excellent mechanical properties, down-gauging<br />
up to 12, 10 and 8 μm thickness is possible.<br />
Bags made from ecovio can be both welded and printed, so they<br />
can be clearly labeled as compostable, for example.<br />
After more than ten years’ product development, versatile<br />
film applications for different industry sectors can be made<br />
of certified compostable plastics like ecovio. They benefit<br />
from the optimum balance of easy processing, tailormade<br />
material properties and the promotion of a circular<br />
economy.<br />
www.ecovio.basf.com<br />
stability, are approved for food contact and reduce food losses<br />
due to the good breathability of the material. The ecovio bags<br />
also comply with the recent standards in France and Italy for<br />
compostable fruit and vegetable bags made of renewable<br />
resources. In France, for example, single-use plastic bags<br />
that are thinner than 50 µm have to consist of at least 40 %<br />
of renewable resources and be home-compostable. Thus<br />
bags made of ecovio support a safer, cleaner and easier<br />
food waste collection, closing the loop of the food value<br />
chain.<br />
ecovio F is also suitable for producing compostable<br />
multilayer films with good barrier properties for packaging<br />
applications. The bioplastic, which is approved for direct and<br />
indirect food contact, is used as the sealing layer. The other<br />
film layers are also made from compostable materials such<br />
as cellophane. In order to ensure that the entire packaging<br />
can be disposed of together with the food waste and given<br />
to industrial composting, a holistic approach is possible:<br />
so, for example, closures and vent valves can also be<br />
produced from ecovio. Recycling food waste in this way is<br />
more resource-friendly than incinerating it or sending it to<br />
landfill.<br />
Films are not only employed for bags and packaging,<br />
they also have applications in agriculture and horticulture.<br />
Here, mulch films are used to increase the yield, speed<br />
up harvesting as well as to save water and herbicides.<br />
Mulch films made of ecovio M2351 are completey and biologically<br />
degraded by microorganisms like bacteria and fungi that exist<br />
naturally in the soil.<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 15
IN THE CIRCULAR ECONOMY,<br />
NOTHING IS WASTED,<br />
EVERYTHING IS TRANSFORMED.<br />
We are moved by improving people’s lives through<br />
sustainable solutions in chemicals and plastics.<br />
HERE IS WHAT BRASKEM<br />
IS COMMITTED TO DOING TOGETHER:<br />
That is why the transition to a Circular Economy—<br />
where everything can be used and reused in a<br />
continuous cycle—moves us to action. And it<br />
starts with education on how we produce and how<br />
Optimize<br />
the design of plastic<br />
products with our<br />
clients and partners<br />
for more efficient<br />
recycling and reuse.<br />
Continue<br />
investing in the<br />
development of<br />
renewable-based<br />
plastic products.<br />
we consume in society.<br />
We know that plastic is essential for our quality<br />
of life, from providing agricultural productivity to<br />
ensuring food safety and hospital hygiene. We also<br />
Develop and<br />
support new<br />
technologies<br />
and methodologies<br />
for recycling.<br />
Promote<br />
conscious<br />
consumption<br />
and recycling<br />
programs.<br />
know that plastic should be used sustainably—<br />
either reused, recycled or reclaimed.<br />
Braskem believes in the strength of this movement<br />
and invites everyone to join us. Each one of us has<br />
a role to play.<br />
Get to know our positioning in full<br />
braskem.com/circulareconomy<br />
Expand<br />
the studies<br />
on Life Cycle<br />
Assessment and<br />
environmental<br />
and climate<br />
impacts<br />
of plastic.<br />
Support<br />
private,<br />
governmental<br />
and academic<br />
partnershipsaimed<br />
at understanding,<br />
preventing<br />
and solving<br />
the problem<br />
of marine<br />
waste.<br />
Support<br />
the measurement<br />
and reporting<br />
of recycling<br />
rates on plastic<br />
packages.<br />
Encourage<br />
comprehensive<br />
science-based<br />
policies to understand<br />
the origins of and to<br />
prevent marine<br />
waste, and to improve<br />
the management of<br />
solid waste overall,<br />
particularly<br />
of plastic.<br />
PASSION FOR TRANSFORMING<br />
16 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
©<br />
©<br />
-Institut.eu | <strong>2018</strong><br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/reports<br />
Full study available at www.bio-based.eu/reports<br />
©<br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/markets<br />
Bio- and CO 2 -based Polymers & Building Blocks<br />
The best market reports available<br />
Data for<br />
2017<br />
Bio-based Building Blocks<br />
and Polymers – Global Capacities<br />
and Trends 2017-2022<br />
Bio-based polymers:<br />
Evolution of worldwide production capacities from 2011 to 2022<br />
Million Tonnes<br />
6<br />
5<br />
4<br />
3<br />
Dedicated<br />
Drop-in<br />
Smart Drop-in<br />
without<br />
bio-based PUR<br />
2<br />
1<br />
2011<br />
2012 2013 2014 2015 2016 2017 <strong>2018</strong> 2019 2020 2021 2022<br />
18-05-22<br />
Authors: Raj Chinthapalli, Michael Carus, Wolfgang Baltus,<br />
Doris de Guzman, Harald Käb, Achim Raschka, Jan Ravenstijn,<br />
<strong>2018</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Commercialisation updates on<br />
bio-based building blocks<br />
Standards and labels for<br />
bio-based products<br />
Bio-based polymers, a revolutionary change<br />
Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />
and polymers based on FDCA and SA: Latest developments,<br />
producers, drivers and lessons learnt<br />
million t/a<br />
Selected bio-based building blocks: Evolution of worldwide<br />
production capacities from 2011 to 2021<br />
3,5<br />
actual data<br />
forecast<br />
3<br />
2,5<br />
Bio-based polymers, a<br />
revolutionary change<br />
2<br />
1,5<br />
Jan Ravenstijn 2017<br />
1<br />
0,5<br />
Picture: Gehr Kunststoffwerk<br />
2011<br />
2012<br />
2013<br />
2014<br />
2015 2016 2017 <strong>2018</strong> 2019 2020<br />
2021<br />
L-LA<br />
Succinic<br />
acid<br />
Epichlorohydrin<br />
1,4-BDO<br />
MEG<br />
2,5-FDCA<br />
Ethylene<br />
D-LA<br />
Sebacic<br />
1,3-PDO<br />
acid<br />
11-Aminoundecanoic acid<br />
MPG<br />
DDDA<br />
Lactide<br />
Adipic<br />
acid<br />
E-mail: j.ravenstijn@kpnmail.nl<br />
Mobile: +31.6.2247.8593<br />
Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
July 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />
April 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Policies impacting bio-based<br />
plastics market development<br />
and plastic bags legislation in Europe<br />
Asian markets for bio-based chemical<br />
building blocks and polymers<br />
Market study on the consumption<br />
of biodegradable and compostable<br />
plastic products in Europe<br />
2015 and 2020<br />
Share of Asian production capacity on global production by polymer in 2016<br />
100%<br />
A comprehensive market research report including<br />
consumption figures by polymer and application types<br />
as well as by geography, plus analyses of key players,<br />
relevant policies and legislation and a special feature on<br />
biodegradation and composting standards and labels<br />
80%<br />
60%<br />
Bestsellers<br />
40%<br />
20%<br />
0%<br />
PBS(X)<br />
APC –<br />
cyclic<br />
PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
Blends<br />
PHA<br />
PLA<br />
PE<br />
Disposable<br />
tableware<br />
Biowaste<br />
bags<br />
Carrier<br />
bags<br />
Rigid<br />
packaging<br />
Flexible<br />
packaging<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
Lara Dammer, Michael Carus (nova-Institute)<br />
April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
bio-based.eu/top-downloads.<br />
www.bio-based.eu/reports<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 17
From Science & Research<br />
PLA in the post-consumerrecycling<br />
stream<br />
The constant increase in global production capacities<br />
of biobased plastics [1] results in a variety of products<br />
made of biobased plastics that reach the established<br />
disposal streams as post-consumer wastes after being<br />
used. In Germany, one of these disposal streams is the collection<br />
and disposal of lightweight packaging waste by the<br />
yellow bin or the yellow bag system. KNOTEN WEIMAR and<br />
TU Chemnitz have investigated the behaviour of biobased<br />
plastic products in the sorting of lightweight packaging<br />
wastes at operating plants and pointed out possible options<br />
for material recycling. The research project was carried<br />
out on behalf of the German Federal Ministry of Food and<br />
Agriculture (BMEL) and funded by the project management<br />
organization Fachagentur für nachwachsende Rohstoffe<br />
(FNR) [2].<br />
The scheme in Fig. 1 gives an overview of the various<br />
disposal routes and the recycling and disposing processes<br />
of various packaging waste as well as the recyclable<br />
material fractions produced. Products made of biobased<br />
plastics can also be integrated into this system.<br />
Sensor-based sorting with near-infrared (NIR) devices<br />
is a key element of modern sorting plants and enables the<br />
sorting of different types of plastics.<br />
Drop-in solutions such as biobased PET and PE, are<br />
sorted out together with conventional equivalents.<br />
However, biobased novel plastics (e.g. PLA, PLA blends or<br />
starch based materials) can also be detected and sorted out<br />
due to their characteristic NIR spectra.<br />
It can be concluded that the sorting of e.g. PLA blends as<br />
representatives of biobased novel plastics as single fraction<br />
is technologically viable. Impurities of the sorted fractions<br />
can thus be kept to a minimum.<br />
In preparation for a practical field test in a conventional<br />
sorting plant, the NIR spectra of several different PLA<br />
blends (plastic yoghurt cups, sheets but also dishes, cups<br />
and bottles) were scanned in the existing NIR devices.<br />
In order to determine the current initial quantity, a sorting<br />
test was first run for lightweight packaging sorting with<br />
approx. 25 tonnes of lightweight packaging input material.<br />
The result showed that the current quantity of products<br />
made from PLA/PLA blends and starch blends in all of the<br />
analysed material streams is predominantly below 1.1 ‰.<br />
A further sorting test (three subtests) investigated the<br />
detectability and sortability or material output of PLA<br />
products/wastes at an operating plant in more detail.<br />
The goal was to determine where PLA materials remain<br />
under unchanged sorting conditions (without positive<br />
sorting of PLA or without activating the PLA spectrum on<br />
the NIR devices) and to test the detectability and sortability<br />
of PLA materials from the post-consumer stream. Cups,<br />
forks and dessert cups were used as PLA input material.<br />
Subsequent to material mixing (Fig. 2) the material was<br />
fed into the sorting process.<br />
Three sorting tests were carried out (see above), the<br />
Fig. 1<br />
Disposal paths and recycling, reutilization and disposal processes of separate packaging wastes<br />
Taking back systems for packaging waste<br />
Deposit systems<br />
PET -Bottles<br />
Light weight packaging via dual systems (yellow bin/bag)<br />
e.g. cups, bowls, bottles, films etc.<br />
Sorting -/Pre-treatment plants (Disposal company), Sorting dry<br />
Process steps a.o. crushing, sieving, metal separation, sensor-based sorting (NIR), air separation, manual control<br />
Products: relevant enriched reusable materials<br />
(incl. impurities caused by sorting performance, material-compounds / -mixtures, residues and pollutants)*<br />
PET PS PE / PP Films MP RDF** Residues<br />
Final recipient plant, Conditioning wet-dry-<br />
Process steps (per material): a.o metal separation,<br />
sensor-based sorting (NIR), crushing, washing,<br />
sink-float separation (separation by density), drying, if any extruding<br />
Sinking<br />
fraction<br />
(ρ > 1)<br />
e.g. PET<br />
Swimming<br />
fraction<br />
Sinking<br />
fraction<br />
e.g. PE / PP<br />
Swimming<br />
fraction<br />
(ρ < 1)<br />
Final recipient plant,<br />
Conditioning dry<br />
Process steps (per material):<br />
a.o. metal separation, crushing,<br />
sieving, air separation, sorting,<br />
if any agglomeration<br />
e.g. Mixed plastics (MKS)<br />
Thermal<br />
treatment<br />
(MVA )<br />
PET<br />
a.o. residues<br />
a.o. residues<br />
PE / PP<br />
z.B. PO<br />
Recyclates,<br />
e.g. PET, PO, PS<br />
(material recycling)<br />
Reductant, gases<br />
and oils<br />
(raw material recycling<br />
e.g. steel plant)<br />
Fuel<br />
(energetic<br />
utilisation e.g.<br />
cement and CHP<br />
station)<br />
Energy<br />
(disposal,<br />
if possible<br />
energetic<br />
utilisation***)<br />
*Specification for individual recyclable material available; **classification as final recipient plant for RDF-production; ***MVA if possible energetic utilisation<br />
18 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
From Science & Research<br />
By:<br />
Jasmin Bauer,Carola Westphalen<br />
KNOTEN WEIMAR<br />
Internationale Transferstelle Umwelttechnologien GmbH<br />
Weimar, Germany<br />
Tobias Hartmann, Roman Rinberg,,Lothar Kroll<br />
Technische Universität Chemnitz<br />
Chemnitz, Germany<br />
material first underwent the automated sorting process<br />
and was then manually separated from the fractions.<br />
The following results were achieved:<br />
• Detecting and, in particular, separation of PLA materials<br />
as individual material fraction in a state-of-the-art plant<br />
is possible.<br />
• Sorting under normal conditions for lightweight<br />
packaging (PLA detection not active) approx. 9 % of the<br />
PLA input goes into the PVC fraction. Hence, PLA is<br />
classified as PVC if no PLA spectrum is active.<br />
• Small scale adaption was made by adjusting the plant<br />
technology by scanning the PLA spectra.<br />
• Positive sorting on PLA results in a sorting rate of 55%.<br />
• Positive sorting on PLA+PE/PP extracted 46% of PLA<br />
input.<br />
The generated test material (PLA fraction) was grinded,<br />
washed and the grist was purified to 90 % PLA with the help<br />
of Hamos GmbH (Penzberg, Germany) in the company’s<br />
own pilot plant. The purification took place in three stages:<br />
air separation, metal separation and plastic-plastic<br />
separation. The main contamination after the cleaning<br />
process was adhesive label residues from the yoghurt cup.<br />
As not enough input material was available for the final<br />
regranulation on an industrial plant, a test material (~ 0.8 t)<br />
Fig. 2 Input material (left), automated sorting process (right)<br />
was mixed analogous to the purified fraction. This grist<br />
was regranulated at Sysplast GmbH&Co. KG in Nürnberg,<br />
Germany on a Coperion ZSK 50MC with an Ettlingen rotary<br />
filter ERF (sieve width 250 µm) with throughputs of up to 400 kg<br />
per hour. The impurities were separated effectively and a<br />
green regranulate was obtained (see Fig. 3).<br />
The mechanical testing revealed the following losses<br />
with regard to the virgin material (Ingeo 2003D from<br />
NatureWorks):<br />
Young’s modulus -1 %<br />
tensile strength -24 %<br />
Charpy unnotched -31 %<br />
Charpy notched -17.4 %<br />
All the tests and results mentioned, as well as further<br />
experiments on the recycling of PLA, including a life cycle<br />
assessment, are detailed in the final report of the research<br />
alliance “Nachhaltige Verwertungsstrategien für Produkte<br />
und Abfälle aus biobasierten Kunststoffen” funded by<br />
BMEL in which eight partners from science and industry<br />
participated [3]. A quick overview of the most important<br />
results, as well as further links to the joint project and the<br />
partners, are summarised in the results paper “PLA in the<br />
waste stream” (download link see [4]).<br />
References:<br />
[1] European Bioplastics, nova-Institut (2017). www.biobased.eu/markets<br />
[2] https://www.fnr.de/index.php?id=11150&fkz=22019212<br />
[3] https://www.european-bioplastics.org/pla-in-the-waste-stream/<br />
[4] https://www.umsicht.fraunhofer.de/content/dam/umsicht/en/<br />
documents/press-releases/2017/pla-in-the-waste-stream.pdf<br />
www.bionet.net | www.leichtbau.tu-chemnitz.de<br />
Fig. 3: seperates impurities (left) and green PLA regranulate (right)<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 19
Bioplastics from waste streams<br />
By:<br />
Vlaďka Matušková<br />
Project Manager<br />
NAFIGATE Corporation, a.s.<br />
Prague, Czech Republic<br />
Waste Cooking<br />
Oil as a Source<br />
for PHA<br />
Low quality waste cooking oil (WCO) has traditionally<br />
been regarded as a low-value waste product, unfit for<br />
further use. Not by Czech company NAFIGATE Corporation,<br />
however, whose Hydal Biotechnology uses 100 % waste in<br />
the form of waste cooking oil to produce fully biodegradable<br />
PHA biopolymer. The company uses oil also as a source of<br />
energy, making biopolymer significantly more affordable<br />
than bioplastics manufactured from the so-called firstgeneration<br />
feedstock, such as corn or sugar cane. Hence,<br />
the technology is Zero Waste with 50 % less energy<br />
consumption than conventional polyethylene (PE).<br />
Nafigate Corporation’s innovative and patented Hydal<br />
biotechnology has won global acclaim, earning, for example,<br />
the 2015 Frost and Sullivan Technology Innovation Award,<br />
Seal of Excellence, as well as being named one of the Top 10<br />
products in China. It is a technology for upcycling: it takes<br />
a waste product and transforms this into a completely<br />
different product – a biopolymer. The company’s strategy<br />
is based on a production system that is aimed at closing<br />
the loop, in line with the key principle of the concept of the<br />
Circular Economy, which is to retain the value of a material<br />
as long as possible within the cycle.<br />
Moreover, the environmental aspects of this breakthrough<br />
technology have been analysed with the help of Life Cycle<br />
Assessment (LCA), the only tool to objectively assess the<br />
impacts of Hydal PHA manufacturing on the environment.<br />
Due to the Zero Waste production system and use of waste<br />
material, the LCA demonstrated a significant positive effect<br />
of the production of PHB polymers from Waste Cooking<br />
Oil using Hydal’s environmental biotechnology. Compared<br />
to polymers made from first generation feedstock and<br />
conventional polyethylene, Hydal PHA production does<br />
not result in the depletion of natural resources, has a<br />
smaller CO 2<br />
footprint and is not associated with ecotoxicity,<br />
freshwater toxicity, acidification, eutrophication and other<br />
negative environmental impacts.<br />
The final biopolymer can be used in various fields,<br />
including for bioplastics production. Another key area is<br />
the cosmetics industry, for which Hydal PHA provides ideal<br />
properties. Hydal PHA is offered in the form of a whole<br />
range of P3HB particles with a nano surface area of up to<br />
8 m 2 /g. According to the certified analysis, the purity of the<br />
final biopolymer – P3HB or PHBV – is higher than 99 %,<br />
with a high molecular weight. Recently, the company in<br />
cooperation with Nafigate Cosmetics launched a new<br />
product - Coconut shower peeling milk, in which microbeads<br />
have been replaced with Hydal P3HB. As a new cosmetics<br />
eco-design concept, it is being market under the name<br />
“Dedicated to You and Nature” to reflect its biodegradable<br />
and biocompatible properties.<br />
PHA can be also used in the medical sector, since P3HB<br />
particles of varying sizes are able to act as transport<br />
systems for active substances. P3HB is additionally<br />
approved for medical purposes by the FDA. Hydal PHA<br />
enables the production of microfibres with a nano surface<br />
area of 30-40 m 2 /g.<br />
Agriculture is another area, in which Hydal PHA may find<br />
application. Hydal PHA-based enhanced efficiency fertiliser<br />
represents controlled-release fertilizers, which gradually<br />
supply the nutrients to the soil. This controlled-release<br />
technology results in some 50 % less fertiliser being<br />
needed compared to conventional methods (fertilizers<br />
are coated with PHA). Furthermore, waste biomass from<br />
the production process offers another source for fertiliser<br />
manufacturing, while last but not least, phosphorus from<br />
the production process can be recycled.<br />
www.nafigate.com<br />
20 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Bioplastics from waste streams<br />
Life Cycle Assessment on PHB production from Used Cooking Oil<br />
100<br />
80<br />
60<br />
40<br />
20<br />
-0<br />
-20<br />
-40<br />
-60<br />
-80<br />
-100<br />
Abiotic<br />
depletion<br />
Abiotic<br />
depletion<br />
(fossil fuels)<br />
Global<br />
warming<br />
(GWP 100a)<br />
Global<br />
warming<br />
(GWP 100a)<br />
Human<br />
toxicity<br />
Fresh water<br />
aquatic<br />
ecotox.<br />
Marine<br />
aquatic<br />
ecotoxicity<br />
Terrestrial<br />
ecotoxicity<br />
Photochemical<br />
oxidation<br />
Acidification<br />
Eutrophication<br />
PHB LDPE, granulate Polylactide, granulate<br />
Method: CML-IA baseline V3.05/EU25/Characterization<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 21
Bioplastics from waste streams<br />
Is Algae a sustainable<br />
feedstock for bioplastics?<br />
As demand for bioplastics grows, the industry is starting<br />
to feel the challenge of finding sustainable biofeedstock.<br />
Algae appears to be a promising source<br />
[1]. Algae can be both grown commercially, or harvested<br />
from commercial and industrial processes, such as water<br />
treatment.<br />
Growing algae commercially for bioplastics<br />
applications<br />
Algae is already commercially grown for nutraceuticals<br />
(e.g. Omega 3 EPA/DHA), cosmetics, food and animal feed<br />
supplements, according to Barry Cohen, President of The<br />
National Algae Association (The Woodlands,Texas, USA).<br />
Cohen notes that algae is a microorganism that doubles<br />
in population every couple of days. Cohen estimates that<br />
an algae producer would need only 60 days to cultivate a<br />
particular strain for client review, testing, and certification.<br />
Another 60-90 days may be required to fulfill a large volume<br />
order suitable for bioplastics. Algae strains suitable for<br />
bioplastics have already been proven in the lab.<br />
Cohen notes that the biggest challenge to growing algae<br />
for bioplastics is finding a client who can fund 30-40% of the<br />
contract price upfront to fulfill a large volume order quickly.<br />
The industry is self-funded and even though producers can<br />
scale easily into commercial production, they have limited<br />
resources to bear large volume production expenditures<br />
alone. Partnerships within the greater supply chain will be<br />
required to get commercially-grown algae into large-scale<br />
bioplastics production.<br />
Harvesting algae from existing water treatment<br />
processes<br />
Algae thrives in our wastewater and other high-nutrient<br />
(i.e. polluted) environments. While its presence helps filter<br />
harmful nutrients out of the water, its overgrowth in nutrientrich<br />
conditions is also a menace [2] to freshwater supplies.<br />
There is a rising demand to contain algae overgrowth<br />
in waterways and reduce the water nutrient levels that<br />
support algae. This can be done while harvesting algae to<br />
generate feedstock for bioplastics and other applications.<br />
Two innovative start-ups are seizing this opportunity:<br />
Working with a wastewater treatment byproduct<br />
Kelvin Okamoto is the Founder and CEO of Gen3Bio<br />
(West Lafayette, Indiana, USA), an innovative company<br />
that converts algae into biofeedstock for resale using a<br />
proprietary blend of enzymes. Okamoto noted that Gen3Bio<br />
harvests the algae from treatment processes that filter<br />
problematic nutrients from wastewater.<br />
Gen3Bio has a mobile pilot facility that hooks into the<br />
nutrient removal systems at wastewater treatment plants,<br />
utilizing its own blends of algae to do the job. Gen3Bio then<br />
harvests the spent algae for processing and resale. The<br />
company plans to share a percentage of net revenue from<br />
the sale of the resulting algae biofeedstock with wastewater<br />
facilities.<br />
The main outputs of Gen3Bio’s operation include sugars,<br />
fats, and proteins from the spent algae. Gen3Bio ferments<br />
sugars extracted from the algae to produce succinic acid.<br />
Succinic acid (cf. bM 03/2013) has multiple uses; among<br />
them, it is a common ingredient in the production of<br />
polybutylene succinate (PBS) (cf. bM 05/2016 and [3, 4]).<br />
PBS is a biodegradable thermoplastic with properties<br />
similar to polypropylene. It is sometimes blended with PLA.<br />
It can be used for the production of both durables (e.g.<br />
fishnets, automotive composites) and non-durables (e.g.<br />
food packaging, disposable cups).<br />
Harvesting algae out of our water supply<br />
While Gen3Bio harvests spent algae from a wastewater<br />
treatment process, Omega Material Sciences filters<br />
problematic algae directly out of the water. Omega Material<br />
Sciences (Lakeland, Florida Area, USA) is an R&D lab that<br />
is working on a large-scale source of algae feedstock for<br />
bioplastics. Its founder, Keith Ervin, has developed a water<br />
treatment media to safely extract algae blooms from both<br />
freshwater and wastewater at high volumes.<br />
Ervin notes that traditional approaches to algae<br />
remediation cannot generate biofeedstock at meaningful<br />
scales because they kill off algae, leading the organism<br />
to emit toxins into the water upon their demise. Ervin’s<br />
method leads to chemical and mechanical separation<br />
of algae blooms from water, making it safe and effective<br />
in producing clean water and harvesting the algae at a<br />
commercial scale.<br />
Ervin has received significant attention from the water<br />
treatment community for his technology. Building the<br />
infrastructure to harvest his algae at scale to feed the<br />
demand for bioplastics will require collaboration and<br />
investment across industries, however. Ervin is looking for<br />
partners and stakeholders to make this happen.<br />
Algae-based materials may already be in your<br />
shoes<br />
Algae is already making an appearance in consumer<br />
products. Algix, a company located in Meridian, Mississippi,<br />
USA, has been producing a plastic composite out of algae<br />
for some years. The algae is combined with traditional<br />
plastics to create Algix’ Solaplast line of resins, which are<br />
approximately 45 % algae. Ryan Hunt, Co-Founder and CTO<br />
at Algix, stated that the algae acts as a biobased filler in<br />
the Solaplast resins, lowering the environmental footprint<br />
of the resulting composite.<br />
22 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Bioplastics from waste streams<br />
By:<br />
Joanna Malaczynski<br />
Consultant<br />
DESi Potential<br />
Bend, Oregon, USA<br />
Algix’ daughter company, Bloom, converts the algae<br />
composite into an EVA foam that can be used in consumer<br />
goods. Bloom’s algae foam can already be found in some<br />
flip flops, running shoes, and even surfboard traction pads.<br />
The company is launching products with companies such as<br />
Adidas, Altra Running, BOGS, Clark’s, Toms, Vivobarefoot<br />
(see p. 35, EcoAlf, Billabong, Saola, TenTree, Red Wings,<br />
Slater Design, Surftech, Biota and Chippewa.<br />
Hunt noted that most of the algae used by his company<br />
is a wastewater treatment by-product. Algix likes working<br />
with wastewater algae because it contains high levels of<br />
proteins, that can be used as building-blocks for certain<br />
bioplastics. Hunt noted that algae living in nutrient rich<br />
conditions, such as wastewater and our overly-fertilized<br />
waterways [5], is especially productive in producing these<br />
proteins.<br />
Is algae suitable for food-grade plastics?<br />
Algae could be an effective biofeedstock for food-grade<br />
plastics. Many American commercial algae growers already<br />
produce a food-grade product for other markets. With<br />
the right business partner, they could shift to food-grade<br />
production for bioplastics. Companies who work with<br />
wastewater algae, on the other hand, have yet to seek FDA<br />
approval for food-grade use, and it remains to be seen to<br />
what extent this would be a viable proposition for them.<br />
An emerging Oregon start-up, AlgoteK, has produced<br />
an algae-based food-grade film, sourcing its algae from<br />
China. The AlgoteK film degrades in contact with water,<br />
which makes it suitable for certain single-use applications.<br />
David Crinnion, Co-Founder of AlgoteK, noted that he<br />
is committed to working with the biobased material in<br />
its purest form because it is easily compostable and biodegradeable.<br />
AlgoteK recently caught the interest of a local<br />
chocolate manufacturer, which is interested in utilizing<br />
AlgoteK’s algae-based material for its packaging.<br />
Gen3Bio Pilot Plant Equipment<br />
Billabon flipflops<br />
References<br />
[1] https://www.fastcompany.com/90154210/the-creators-of-this-algaeplastic-want-to-start-a-maker-revolution<br />
[2] https://www.epa.gov/nutrientpollution/harmful-algal-blooms<br />
[3] https://www.m-chemical.co.jp/en/products/departments/mcc/<br />
sustainable/product/1201025_7964.html<br />
[4] http://www.succinity.com/polybutylene-succinate<br />
[5] http://news.wfsu.org/post/engineering-bioplastics-firms-debut-cuttingedge-algae-removal-process<br />
SlaterDesign Algae Traction Pad<br />
Vivobarefoot Ultra Bloom<br />
running shoes<br />
https://desipotential.com | www.gen3bio.com | http://algix.com |<br />
https://bloomfoam.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 23
Bioplastics from waste streams<br />
Valorizing<br />
Plant pots<br />
Biodegradable plastic pipe (Heijmans)<br />
Rodenburg Biopolymers’ activities started in 1945,<br />
trading plant-derived products for various industries.<br />
Soon Arie Rodenburg added side stream<br />
activities, by buying defects from potato sorters. This<br />
was when the long-term relationship with potato side<br />
streams started. Who would have known that a forage<br />
business would turn into Bioplastics half a century later?<br />
Collaboration<br />
In the 1960’s, Rodenburg started working together<br />
with French Fry Factories and pioneered in collecting<br />
and valorizing industrial side streams. Rodenburg was<br />
characterized by tight collaborations and innovation<br />
on every step in the value chain. At the beginning of<br />
the chain, the processes of the factories needed to<br />
be adjusted to make the collection of side streams<br />
possible. Rodenburg introduced new innovative<br />
processing techniques, like grinding the steam peels.<br />
At the end of the chain, Rodenburg created a market<br />
for its products and revolutionized the forage industry.<br />
This was also the start of its R&D activities. The various<br />
side streams were split and tested for optimal results<br />
on different cattle species. Aaik Rodenburg recalled:<br />
“We partnered up and started a bull farming business<br />
to raise top quality cattle on our side stream products.<br />
This way we could optimize the valorization processes<br />
and show our customers excellent quality meat.”<br />
During these decades Rodenburg built the bedrock<br />
and the fundamentals for the business. Collaboration<br />
and innovation are still King for success at Rodenburg<br />
Biopolymers.<br />
Innovation<br />
In the year 2000, Aaik Rodenburg made a turnaround<br />
to Biodegradable polymers, in cooperation<br />
with Wageningen ATO (Food and Biobased Research).<br />
Building further on the essence of the company; the<br />
valorization of co-products and waste streams. An<br />
intensive period of R&D followed, with many obstacles<br />
to overcome. Resulting in various certified and awardwinning<br />
biodegradable products. For example, the<br />
biobased packaging material for Mars’ candy bars,<br />
awarded with the 11th Global Bioplastics Award by<br />
bioplastics MAGAZINE.<br />
These innovations took time, flexibility and continuous<br />
improvement. “We were so proud to produce our first,<br />
biodegradable plant pots,” Aaik recounted. “During<br />
the opening of our new factory, we handed out dozens<br />
of those with a flower in it. Unfortunately, the product<br />
appeared to evoke a special reaction from dogs; diggingup<br />
the pots and ruin the gardens. Other uncalculated<br />
side-effects were the increasing odor over time and the<br />
violets changing their color. Apparently, the protein in<br />
the potato was the culprit.”<br />
Biodegradable plastic pipe (Heijmans)<br />
Drawing from this anecdote, it shows the persistence<br />
and grit needed to achieve the desired products,<br />
24 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
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side streams<br />
even before entering the market. “We have 50 Years of<br />
experience in valorizing side streams, strong in-house R&D<br />
and a track record in co-creation. Still, every innovation<br />
involves a lean, innovative approach and customization,”<br />
said Thijs Rodenburg, CEO of the company. The violets are<br />
still standing in the office as a reminder for that, next to<br />
Mars’ packaging.<br />
TRANSITION<br />
During the last decade, there has been a change in<br />
business needs, manufacturing demands and ethical<br />
standards. However, the customer is still not ready to pay<br />
the premium for innovative processes or biodegradable<br />
materials. Rodenburg Biopolymers found the gap: value<br />
adding propositions and unique product performances.<br />
Thijs Rodenburg: “Two years ago, we produced<br />
biodegradable plant support sticks. We hoped customers<br />
would embrace the cradle to cradle or biodegradable<br />
concept. Unfortunately, we could not compete with the<br />
cheaper, plastic alternatives. We continued R&D with our<br />
partners Growfun and Wageningen University and looked<br />
for the right proposition to reach our target audience. We<br />
found a way to add fertilizer to the sticks, so not only would<br />
they provide support, but also feed the plant nutrition over<br />
time. This product was launched at the Royal FloraHolland<br />
Trade Fair this year, under the brand Voodstock, with great<br />
success.”<br />
According to Rodenburg, the market is in transition. It is<br />
only a matter of time before the mass will embrace bioplastics<br />
as a sustainable alternative. And waste streams will play an<br />
important role as a feedstock. MT<br />
www.biopolymers.nl<br />
from left: Thijs, Joost and Aaik Rodenburg,<br />
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71. Jahrgang, Juni <strong>2018</strong><br />
<strong>06</strong>| <strong>2018</strong><br />
Volume 13, June <strong>2018</strong><br />
3| <strong>2018</strong><br />
Volume 9, April <strong>2018</strong><br />
2| <strong>2018</strong><br />
info@gupta-verlag.de · www.gupta-verlag.com<br />
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bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 25
Materials<br />
Modified Calcium Carbonate<br />
opens new opportunities for<br />
the use of PLA<br />
P<br />
olylactic Acid (PLA) is one of the fastest growing<br />
biobased polymers on the market. Processors have<br />
tried to use Calcium Carbonate to improve properties<br />
and the cost structure, as is common in conventional<br />
polymers. Omya gained experience showing that conventional<br />
Calcium Carbonate can lead to the degradation of<br />
PLA and PLA / PBAT blends used in products such as cups,<br />
trays, lids and bags. Omya followed market demand to develop<br />
a new type of Calcium Carbonate that does not cause<br />
PLA degradation.<br />
Introduction<br />
PLA is a bio-polyester which degrades when processed<br />
with moisture due to hydrolysis. Calcium Carbonate is by<br />
nature a somewhat hygroscopic material and carries a<br />
certain amount of moisture on its surface and in its crystal<br />
structures.<br />
In 1952, Omya launched the first surface-treated Calcium<br />
Carbonate with reduced moisture adsorption. Today it<br />
is common to use surface-treated calcium carbonate in<br />
all types of polymer applications to prevent processing<br />
problems and surface defects on the final products. The<br />
most common surface treatment materials are based on<br />
fatty acids, such as stearic acid. With such a treatment,<br />
a good reduction of the moisture uptake on the Calcium<br />
Carbonate can be observed, but it ultimately causes<br />
hydrolysis in PLA.<br />
With the development of Omya Smartfill ® technology, the<br />
situation has changed. It is now possible to add 40 % or<br />
more of Calcium Carbonate in films, sheets or injection<br />
molded parts without causing significant hydrolysis<br />
while improving important properties such as elongation,<br />
stiffness and impact.<br />
Product Evaluation<br />
Melt flow rate is considered a good indicator of polymer<br />
chains degradation: As PLA degradation increases, it is<br />
expected that the melt flow rate of the polymer or compound<br />
would increase too.<br />
Table 2 shows the difference between conventionally<br />
treated Omyacarb ® 1T and Omya Smartfill after preparing<br />
a 40 % Calcium Carbonate compound with Natureworks<br />
Ingeo 2003D. The compounding line is a continuous<br />
kneader without vacuum degassing and only pre-dried<br />
PLA was used. The results show that using a conventional<br />
Calcium Carbonate, such as Omyacarb 1T, MFR increased<br />
significantly, which means that important polymer<br />
degradation has taken place during processing. In contrast,<br />
Omya Smartfill does not show signs of degradation and<br />
kept the melt flow on the same level as virgin PLA.<br />
A more common technology for processing PLA is twinscrew<br />
compounding with the ability to extract water by<br />
vacuum degassing. Table 3 shows that in these processing<br />
conditions, the melt flow rate increase with Omyacarb 1T<br />
was more limited but still not satisfactory. The use of Omya<br />
Smartfill led again to a significantly lower MFR and matched<br />
the viscosity of unfilled PLA.<br />
Omya Smartfill does not require pre-drying or<br />
venting when compounding<br />
To test the effect of Calcium Carbonate on PLA properties,<br />
a 300mm working width laboratory casting line was used to<br />
make 800 µm PLA sheets with different Calcium Carbonate<br />
loadings.<br />
Fig 1 and Fig 2 show the same typical property changes<br />
Calcium Carbonate provides in PLA as expected with<br />
Calcium Carbonate addition in conventional thermoplastic<br />
polymers. Yield strength decreases, and stiffness increases<br />
with increasing Calcium Carbonate concentration.<br />
After sheet production, part of it was cut into small pieces<br />
to check the extent of degradation. This was done after the<br />
second heat history through MFR measurement (Fig 3). The<br />
results clearly show that Omya Smartfill does not cause<br />
additional PLA degradation, whereas Omyacarb 1T causes<br />
heavy degradation, which can make polymer processing<br />
difficult.<br />
In many polymers, the elongation at break is reduced<br />
due to the addition of mineral additives. Surprisingly Omya<br />
Smartfill added to PLA boosts the ultimate elongation. Fig 4<br />
shows a strong increase in elongation at break achieved<br />
when adding Omya Smartfill with a maximum at around<br />
20 % addition but even at 40 % addition elongation is far<br />
higher than for virgin PLA. This proves that Omya Smartfill<br />
increases stiffness and elasticity simultaneously and<br />
allows a processor to achieve high filler levels with superior<br />
mechanical properties. This effect can be seen also when<br />
adding Omyacarb 1T but to a much less extent, which could<br />
be related to degradation.<br />
Similar injection molding tests show comparable<br />
improvements and an increased impact strength on top, but<br />
there are additional benefits that contribute to overall cost<br />
savings when using 40 % Omya Smartfill, including:<br />
• 12 % lower specific heat capacity<br />
• 78 % higher thermal conductivity<br />
• 60 % higher thermal diffusivity<br />
• 89 % opacity at 30 % filler level without the use of<br />
titanium dioxide<br />
26 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
By:<br />
4500<br />
4000<br />
3500<br />
3000<br />
2500<br />
2000<br />
1500<br />
1000<br />
500<br />
0<br />
1000<br />
500<br />
0<br />
100% PLA 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya Smartfill<br />
20% Omyacarb 1T<br />
Matthias Welker, Michael Knerr, Karsten 100% Schulz PLA 10% Omya Smartfill<br />
Omya International AG<br />
20% Omya Smartfill 40% Omya Smartfill<br />
Oftringen, Switzerland<br />
20% Omyacarb 1T<br />
Physical properties help to increase productivity. When 30<br />
using Omya Smartfill in thermoforming or injection<br />
20<br />
molding, less energy is needed for heating and cooling and<br />
10<br />
lower cycle times can be achieved. Elongation at Break in MD [%]<br />
80<br />
70<br />
60<br />
50<br />
40<br />
80<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
100<br />
90<br />
80<br />
70<br />
60<br />
100 50<br />
40 90<br />
30 80<br />
20 70<br />
10 60<br />
50 0<br />
Tensile Strength at Yield in MD [N/mm 2 ]<br />
Tensile Strength at Yield in MD [N/mm 2 ]<br />
10<br />
0<br />
100% PLA 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya Smartfill<br />
20% Omyacarb 1T<br />
0<br />
100<br />
100% PLA 10% Omya Smartfill<br />
Omya Smartfill is always the right choice when conventional<br />
Tensile Modulus MD [N/mm 2 ]<br />
90<br />
20% Omya Smartfill 40% Omya Smartfill<br />
Calcium Carbonate causes 80polymer degradation due to<br />
5000 20% Omyacarb 1T<br />
hydrolysis. It is EU 10/201170<br />
and FDA approved for food<br />
4500<br />
contact, it meets composting 60requirements and has passed<br />
4000<br />
50<br />
3500<br />
the ecotoxicity test. The material Elongation is supplied at Break as a powder in MD [%]<br />
40<br />
3000 Tensile Modulus MD [N/mm 2 ]<br />
and needs to be<br />
100<br />
pre-dispersed in a compound before being<br />
30<br />
2500 5000<br />
used on conventional 90 single 20 screw extrusion lines.<br />
2000 4500<br />
80<br />
10<br />
1500 4000<br />
Omya recently<br />
70<br />
received an<br />
0<br />
Innovator Award from the<br />
1000 3500<br />
Sustainable Packaging 60 Coalition (SPC) 100% as PLA a member 10% Omya 3000 500 Smartfill<br />
of PepsiCo’s Supply 50 Chain Partnership to 20% deliver Omya Smartfill a new 40% Omya 2500 Smartfill 0<br />
40<br />
20% Omyacarb 1T<br />
2000<br />
100% PLA 10% Omya Smartfill<br />
biobased film package to market. The outcome of a<br />
30<br />
1500<br />
20% Omya Smartfill 40% Omya Smartfill<br />
Partnership Innovator Award was one of a select few entries<br />
70 20% Omyacarb 1T<br />
20<br />
1000<br />
chosen for advancing 10 the state of sustainable packaging.<br />
500<br />
60<br />
Fig 2<br />
NatureWorks, Danimer 0 Scientific, Berry Global, Johnson-<br />
0<br />
50<br />
Bryce and PepsiCo also received 100% an PLA award. 10% Omya Smartfill<br />
100% PLA 10% Omya 80 Smartfill<br />
www.omya.com<br />
20% Omya Smartfill 40% Omya Smartfill<br />
40 20% Omya Smartfill 40% Omya Smartfill<br />
20% Omyacarb 1T<br />
70<br />
20% Omyacarb 1T<br />
30 MFR @ 210C/2.16kg [g/10min]<br />
60<br />
70<br />
20<br />
50<br />
Table 1: Moisture adsorption of common calcium carbonate<br />
grades and Omya Smartfill 55 - OM (mg/g, upon relative humidity<br />
change from 10% rH to 85 % rH at 23 °C)<br />
Calcium Carbonate<br />
Conventional un-treated<br />
Conventional treated<br />
Omya Smartfill 55-OM<br />
Moisture Adsorption<br />
1580 ppm<br />
750 ppm<br />
390 ppm<br />
Table 2: MFR (210°C/ 2.16kg [g/10min]) (without degassing)<br />
MFR<br />
100% PLA Ingeo 2003D 6<br />
60% PLA + 40% Omyacarb 1T 49<br />
60% PLA + 40% Omya Smartfill 5<br />
Table 3: MFR (210°C/ 2.16kg [g/10min]) (with degassing)<br />
MFR<br />
100% PLA Ingeo 2003D 6<br />
60% PLA + 40% Omyacarb 1T 25<br />
60% PLA + 40% Omya Smartfill 6<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
40<br />
30<br />
20<br />
10<br />
0<br />
Fig 1<br />
MFR @ 210C/2.16kg [g/10min]<br />
40 80<br />
30 70<br />
Tensile Strength at Y<br />
100% PLA 20 60 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya Smartfill<br />
10<br />
20% Omyacarb 1T 50<br />
40 0<br />
30<br />
100% PLA<br />
20% Omya Smartfill<br />
20<br />
20% Omyacarb 1T<br />
10<br />
100% PLA 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya 0Smartfill<br />
20% Omyacarb 1T<br />
Elongation at Break in MD [%]<br />
Fig 3: MFR after sheet production<br />
Elongation at Break in MD [%]<br />
100% PLA 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya Smartfill<br />
20% Omyacarb 1T<br />
100% PLA 10% Omya Smartfill<br />
20% Omya Smartfill 40% Omya Smartfill<br />
20% Omyacarb 1T<br />
Fig 4: Impact of calcium carbonate<br />
to elasticity<br />
Materials<br />
Tensile Strength at Y<br />
70<br />
60<br />
50<br />
100% PLA<br />
20% Omya Smartfill<br />
20% Omyacarb 1T<br />
MFR @<br />
MFR<br />
40<br />
70<br />
30<br />
60<br />
20<br />
50<br />
10<br />
40<br />
0<br />
bioplastics MAGAZINE 30 [<strong>06</strong>/18] Vol. 13 27<br />
100% P
From Science & Research<br />
Improved biobased fibres<br />
for clothing applications<br />
Polylactic acid (PLA) is a material obtained from renewable<br />
resources, suitable for obtaining melt-processable fibres. It<br />
combines ecological advantages with a good performance in<br />
textiles. PLA successfully bridges the gap between synthetic and<br />
natural fibres and finds a wide range of uses, but despite their<br />
benefits, most commercial PLA grades do not yet fulfil all the mechanical<br />
and thermal requirements for some textile applications.<br />
In order to solve these limitations, the European project FIBFAB<br />
has been working on the development of a new bio-compound<br />
that fulfils the desired properties for textile clothing applications<br />
as well as the suitability to be used in industrial fibre production.<br />
The project FIBFAB aims to industrialize and successfully launch<br />
the production of biobased and sustainable PLA-based fabrics<br />
(wool/PLA and cotton/PLA) for applications in casual, protective<br />
and workwear clothing and to overcome the current limitations of<br />
PLA fibres as a real alternative to current fabrics (wool and cotton<br />
combined with polyester (PES) fibres). The targets of the project<br />
are:<br />
• To obtain a final 100 % biobased clothing product that meets<br />
the mechanical performance requirements of the textile sector.<br />
Sample<br />
Standard /<br />
Method<br />
MFI<br />
(g/10 min)<br />
210°C; 2,16 kg<br />
UNE-EN ISO<br />
1133-2: 2012<br />
VICAT B50 (°C) Crystallinity (%)<br />
UNE-EN ISO<br />
3<strong>06</strong>: 2015<br />
DSC,<br />
Platen Press<br />
PLA 6201 D 25 55-60 25.40<br />
PLA 6100 D 24 55-60 -<br />
PLA 6260 D 65 - -<br />
Target<br />
properties<br />
15-30 > 90 -<br />
FibFab<br />
compound<br />
22.8 ± 0.7 92.7 ± 0.4 47.08<br />
By:<br />
Nuria López Aznar<br />
Senior Polymer Researcher<br />
AIMPLAS (Plastics Technology Centre)<br />
Paterna, Spain<br />
With this compound developed, fibres and some<br />
final products such T-shirts were obtained.<br />
• To improve the current poor thermal resistance of PLA fibres<br />
to meet the requirements in several clothing applications. The<br />
thermal resistance of PLA fibres achieved are higher than<br />
90°C.<br />
• To improve the extrusion process for PLA fibres to be able<br />
to obtain fine fibres (less than 3 dtex) and especially the<br />
mechanical spinning process (friction control in ring spinning)<br />
to be able to spin PLA blend fibres at higher speeds.<br />
• To reduce the market dependence on fibre and textile imports<br />
(mainly PES products) and improve the competitiveness of the<br />
textile sector by creating a new concept of clothing that fits the<br />
expectations of customers with high ecological awareness.<br />
• To introduce yarns and fabrics produced from PLA fibres<br />
and cotton or wool into the textile market. Due to the<br />
chemical nature of PLA, it has been proven that it has better<br />
breathability, hydrophilic properties, UV resistance, low smoke<br />
production and flammability and also lower density than PES.<br />
The compound development, in which AIMPLAS (Paterna,<br />
Spain) is the main responsible, has included a mix of different<br />
commercial PLAs with some additives such as nucleants,<br />
processing aids and hydrolysis stabilizers.<br />
From the results of the characterization of the compounds<br />
developed, it was possible to achieve the targets regarding viscosity,<br />
thermal resistance, crystallinity, hydrolytic behaviour, mechanical<br />
properties and shrinkage, as well as good processability, obtaining<br />
fibres with less than 3 dtex.<br />
The table shows some of the main properties studied and<br />
compares some commercial PLAs and the compound developed<br />
within the project FIBFAB.<br />
FIBFAB is a two-year project funded by the EU’s<br />
Horizon 2020 Research and Innovation programme<br />
under grant agreement No 737882, in which AIMPLAS<br />
(Plastics Technology Centre) is the coordinator.<br />
Together with the rest of the consortium (Centexbel,<br />
D.S. Fibres, Yünsa and Sintex), these members<br />
cover the textile value chain, from fibre production to<br />
product manufacturing, thus ensuring the industrial<br />
implementation of PLA fibres for clothing.<br />
fibfab-project.eu/ | www.aimplas.es<br />
28 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
From Science & Research<br />
New<br />
method<br />
for high<br />
yield FDCS<br />
production<br />
enables large-scale<br />
production of bio-based<br />
plastic bottles<br />
S<br />
cientists have discovered a novel method to synthesize<br />
furan-2,5-dicarboxylic acid (FDCA) in a high yield from a glucose<br />
derivative of non-food plant cellulose, paving the way for<br />
replacing petroleum-derived terephthalic acid with biomaterials in<br />
plastic bottle applications.<br />
The chemical industry is under pressure to establish energyefficient<br />
chemical procedures that do not generate by-products, and<br />
using renewable resources wherever possible. Scientists believe<br />
that if resources from non-food plants can be used without putting<br />
a burden on the environment, it will help sustain existing social<br />
systems.<br />
It has been reported that various useful polymers can be<br />
synthesized from 5-(hydroxymethyl)furfural (HMF), the biomaterial<br />
used in this study. A high yield of FDCA can be obtained when HMF<br />
is oxidized in a diluted solution under 2 wt % with various supported<br />
metal catalysts. However, a major stumbling block to industrial<br />
application lies with the use of a concentrated solution of 10-20 wt %,<br />
which is essential for efficient and scalable production of FDCA in the<br />
chemical industry. When HMF was simply oxidized in a concentrated<br />
solution (10 wt %), the FDCA yield was only around 30 %, and a large<br />
amount of solid by-products was formed simultaneously. This is due<br />
to complex side reactions induced from HMF itself.<br />
In the study published in Angewandte Chemie International Edition<br />
[1], a Japan-Netherland research team led by Associate Professor<br />
Kiyotaka Nakajima at Hokkaido University and Professor Emiel<br />
J.M. Hensen at Eindhoven University of Technology succeeded in<br />
suppressing the side reactions and producing FDCA with high yields<br />
from concentrated HMF solutions (10~20 wt %) without by-products<br />
formation. Specifically, they first acetalized HMF with 1,3-propanediol<br />
to protect by-product-inducing formyl groups and then oxidized<br />
HMF-acetal with a supported Au catalyst.<br />
About 80 % of 1,3-propanediol used to protect formyl groups<br />
can be reused for the subsequent reactions. In addition, drastic<br />
improvement in the substrate concentration reduces the amount<br />
of solvents used in the production process. Kiyotaka Nakajima<br />
says “It is significant that our method can reduce the total energy<br />
consumption required for complex work-up processes to isolate the<br />
reaction product.”<br />
“These results represent a significant advance over the current<br />
state of the art, overcoming an inherent limitation of the oxidation of<br />
HMF to an important monomer for biopolymer production. Controlling<br />
the reactivity of formyl group could open the door for the production<br />
of commodity chemicals from sugar-based biomaterials,” says<br />
Kiyotaka Nakajima. This study was conducted jointly with Mitsubishi<br />
Chemical Corporation. MT<br />
[1] Kim M., et al., Aerobic oxidation of HMF-cyclic acetal enables selective FDCA<br />
formation with CEO2-supported Au catalyst, Angewandte Chemie International<br />
Edition, May 14, <strong>2018</strong>. DOI: 10.1002/anie.<strong>2018</strong>05457<br />
www.global.hokudai.ac.jp<br />
Conventional methods produce<br />
by-products making large-scale<br />
FDCA production difficult, while this<br />
new method yields FDCA efficiently<br />
without by-products formation [1].<br />
HO O O<br />
O<br />
PD-HMF<br />
cat. Au-CeO 2<br />
Selectivity: 91 %<br />
(20 wt% concentration)<br />
Acetal protection suppresses byproduct<br />
formation<br />
HO<br />
O<br />
O<br />
FDCA<br />
Byproduct<br />
O<br />
OH<br />
cat. Au-CeO 2<br />
Selectivity: 28 %<br />
(10 wt% concentration)<br />
Major pathway<br />
(10 wt% concentration)<br />
HO O O<br />
HMF<br />
H<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 29
From Science & Research<br />
Compostable polymers are increasingly found in applications<br />
such as packaging, disposable nonwovens and<br />
hygiene products, consumer goods and agricultural<br />
products. A wide variety of compostable polymers have been<br />
developed, derived both from petrochemical and renewable<br />
sources. But, what do we know about how these materials behave<br />
in other environments or conditions outside of industrial<br />
composting facilities?<br />
In <strong>2018</strong>, the European Parliament introduced the new<br />
‘European Strategy for Plastics in a Circular Economy’, in<br />
which the opportunities and risks associated with the growing<br />
use of plastics with biodegradable properties, have also been<br />
acknowledged. In the absence of clear labelling or marking<br />
for consumers and without suitable waste collection and<br />
treatment options, these plastics could aggravate the leakage<br />
of plastics into the environment and cause mechanical<br />
recycling problems. On the other hand, the European Strategy<br />
states that biodegradable plastics can certainly have a role in<br />
some applications, and that innovation efforts in this field are<br />
welcome but that the behaviour and consequences of their<br />
biodegradability must be demonstrated.<br />
This article will present the main findings of a study on<br />
the degree of disintegration of a compostable polymer and<br />
a visual analysis of the material degradation in different<br />
environmental conditions. It will present different tests<br />
carried out under industrial composting conditions, home<br />
compost conditions, composting conditions in a lab-scale test<br />
(aggressive synthetic solid) and in soil (natural environment) at<br />
two different temperatures. Furthermore, the ecotoxicological<br />
effects of the environment after the disintegration process<br />
was evaluated to obtain a full understanding of the behaviour<br />
of these polymers.<br />
The present study revealed that two main aspects determine<br />
the degree of disintegration of a compostable biopolymer<br />
(PLA and PBTA blend): on the one hand, the aggressiveness<br />
of the medium (microbial activity) and on the other hand, the<br />
temperature.<br />
The most aggressive medium, an enriched synthetic solid,<br />
gave rise to average disintegration degrees of 96.09 %, followed<br />
by natural compost of vegetable origin and a normalized soil,<br />
thus reaching disintegration degrees of 87.76 % and 72.05 %<br />
respectively at thermophilic temperature (58 ºC).<br />
By:<br />
Elena Domínguez<br />
Researcher, Sustainability and Industrial Recovery department<br />
AIMPLAS<br />
Paterna, Valencia, Spain<br />
Compostable<br />
plastics’<br />
behaviour in<br />
different<br />
environmental<br />
conditions<br />
Figure 1. Degree of disintegration of the<br />
material tested in different environments and<br />
thermophilic conditions (58 ºC)<br />
Figure 2. Degree of disintegration of the material<br />
tested in different environments and mesophilic<br />
conditions (25 ºC)<br />
58ºC day 7 day 37 day 69 day 90<br />
25ºC day 7 day 90<br />
Synthetic Solid<br />
Synthetic Solid<br />
Normalized<br />
Soil<br />
Normalized<br />
Soil<br />
Compost<br />
Compost<br />
30 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
From Science & Research<br />
At a mesophilic temperature of 25 ºC , the materials did not<br />
achieve degradation in any of the environments studied.<br />
In this study, the ecotoxicological effects were evaluated in a<br />
fast-growing plant species (Ray Grass) from the media where<br />
disintegration had occurred. None of the media in which the<br />
polymeric material had disintegrated produced a toxic effect<br />
on the species in question and the vegetal biomass reached a<br />
germination and growth rate of over 90 % with respect to the<br />
reference substrate.<br />
A limitation in the use of bioplastics is the existing confusion<br />
about the behaviour of materials in different conditions. An<br />
industrially compostable material is not necessarily able to<br />
biodegrade under other temperature conditions or in other<br />
environmental conditions. Currently, there are international<br />
schemes for the certification of biodegradable materials in<br />
different environments that may cause confusion in this sector.<br />
These schemes guarantee to customers the biodegradability<br />
of a material in certain conditions according to international<br />
standards.<br />
In order to enable the correct communication of<br />
biodegradable polymers through product ecolabelling, there<br />
are different standards of biodegradation determination<br />
in different environments (compost, soil, etc.), which have<br />
been used to create certification schemes that specify the<br />
requirements to be met in order to attain the corresponding<br />
certificate and product labelling.<br />
Manufacturers and suppliers in Europe have relied on<br />
the neutral and independent certifications by DIN CERTCO<br />
and TÜV Austria for many years. Certifications from these<br />
agencies send a message to consumers about the quality<br />
of the products and can serve as guidance when making<br />
purchasing decisions.<br />
These independent bodies are able to specify the correct<br />
biodegradation environment for final products thanks to<br />
verification marks.<br />
The most common ecolabel assigned is that of compostability<br />
in industrial facilities (at a temperature of approximately 60 ºC).<br />
The aforementioned bodies grant their own compostability<br />
ecolabels together with European Bioplastics association’s<br />
Seedling compostability mark. Both marks, can be used<br />
individually, alternatively or simultaneously, and document the<br />
biodegradability, among other aspects, of a final product or<br />
material in industrial composting facilities.<br />
A material that is compostable in industrial composting<br />
facilities will not necessarily compost in home composting<br />
conditions, where, among other things, the temperature<br />
is considerably lower (approximately 25 ºC). Different certificates<br />
are obtainable for different conditions and<br />
environments: biodegradable materials and products can<br />
be certified as degradable in soil, saltwater or fresh water.<br />
Any supplier who invests in adding this functionality to their<br />
product or packaging should have the opportunity to have<br />
this information verified according to international standards,<br />
obviously without encouraging consumers to litter.<br />
Biodegradability in the soil offers huge benefits for<br />
agricultural and horticultural products, as they can be left<br />
to break down in situ after being used. In <strong>2018</strong>, standard<br />
EN 17033 [1] was developed, which outlines the requirements<br />
to be met by agricultural mulch films, an application in which<br />
biodegradability in soil entails the end of life of materials, thus<br />
reducing soil contamination due to mismanagement on the<br />
part of humans.<br />
AIMPLAS, the Plastics Technology Centre, based in Spain,<br />
is now in the process of becoming a laboratory recognized by<br />
TÜV Austria, after which it will support the manufacturers in<br />
the verification process required for the different ecolabels,<br />
evaluating the requirements necessary to fulfil each point<br />
of the certification schemes according to international<br />
regulations.<br />
Furthermore, as a quality aspect, Aimplas has a testing<br />
laboratory accredited by ENAC with accreditation no 56/LE156<br />
in conformity with the EN ISO/IEC 17025 standard. Moreover,<br />
Aimplas has the highest number of ENAC accreditations for<br />
plastics according to the ISO 17025 standard at national level.<br />
ENAC accreditations are recognized in over 50 countries,<br />
since it is a signatory of the Mutual Recognition Agreements<br />
arranged at an international level among accreditation bodies<br />
all over the world. These agreements include practically the<br />
whole of the EU, USA, Canada, Japan, China and Australia,<br />
among others.<br />
[1] EN 17033: <strong>2018</strong>. Plastics - Biodegradable mulch films for use in agriculture<br />
and horticulture - Requirements and test methods.<br />
www.aimplas.es<br />
Figure 4. AIMPLAS’ equipment for simulation of<br />
conditions of biodegradation or disintegration<br />
tests.<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 31
Report<br />
GO!PHA<br />
Introduction of the Global Organization for PHA<br />
F<br />
ollowing a successful conclusion of 1 st PHA platform<br />
world congress, in September <strong>2018</strong>, a group of four<br />
experts conceived the idea of establishing a global initiative<br />
to accelerate the development of the PHA-platform<br />
industry by sharing experiences, knowledge and developments,<br />
and by communicating objectively towards policy<br />
development organizations, NGOs, OEMs/Brand Owners,<br />
plastics processors and the general public, and to facilitate<br />
joint development initiatives. The result is GO!PHA, a Global<br />
Organization for PHA, an initiative of Jan Ravenstijn, Rick<br />
Passenier (PACE), Anindya Mukherjee (i2i Consulting) and<br />
Michael Carus (nova-Institut).<br />
Polyhydroxyalkanoate polymers (PHAs) provide a unique<br />
opportunity as a solution for reducing greenhouse gases and<br />
environmental plastics pollution and offer numerous design<br />
opportunities in the new global plastics ecosystem. However,<br />
legislators, brand owners and the common public are largely<br />
unaware of the potential benefits and as of today commercial<br />
success has been limited.<br />
The founding members of Go!PHA believe that significant<br />
effort is needed to highlight and promote the benefits of PHAs<br />
to the global consumer community, OEMs/Brand Owners<br />
and plastics processors on PHA’s durability, sustainability<br />
and its impact on accelerating The Circular Economy via<br />
growing demand for a range of sustainable, high-quality<br />
and competitive products and materials based on renewable<br />
feedstocks and offering diverse end-of-life options.<br />
With this article, Go!PHA is presenting the start and<br />
general outline of the Global Organization for PHA; GO!PHA,<br />
and would like to invite interested stakeholders to share their<br />
feedback and support for this initiative.<br />
The Global Organization for PHA<br />
The Global Organization for PHA will serve the entire<br />
PHA-platform industry and its downstream markets in<br />
demonstrating its benefits and encouraging the development<br />
and commercialization of PHA polymers as new solutions<br />
and as a beneficial alternative to existing petroleum polymers<br />
and plastics, by engaging in three major areas:<br />
• Communication, policy and legislation<br />
Educating key public and private stakeholders about the<br />
benefits of PHA-polymers, by developing objective technical,<br />
environmental and pre-commercial communication.<br />
Advocating legislative and market adoption drivers and<br />
identifying and overcoming barriers for further PHApolymers<br />
adoption, by actively representing the industry<br />
interests in key global and local forums.<br />
• Market proliferation<br />
Improving market perception about the application<br />
development options and multiplying on success, by<br />
showcasing best practices. Creating an informative channel<br />
to present the realm of product and application development<br />
options and to develop objective inter-material replacement<br />
data. Create a forum to allow members to help match market<br />
demand and supply, and application development.<br />
• Technical and scientific knowledge development<br />
Accelerating the implementation of technical and scientific<br />
developments across the industry, by sharing processes,<br />
methods and tools to improve the overall PHA-polymer<br />
competitiveness. Facilitating pre-competitive research and<br />
create a forum for development partnerships on matters of<br />
common interest.<br />
Structure<br />
The Global PHA Organization will be a non-profit<br />
organization, backed by its members, with a lean<br />
management structure. It will have a global scope and the<br />
organization aims to have representation/ambassadors at all<br />
geographic locations. For the daily support, management,<br />
on- and offline representation and ancillary expenses, an<br />
initial annual budget requirement of approximately 300,000<br />
EUR is foreseen.<br />
Engagement<br />
GO!PHA welcomes all parties that want to support and/or<br />
to join efforts in developing, producing and commercializing<br />
PHA polymers, from feedstock to product to end-oflife.<br />
Membership provides access to the global PHA<br />
community, workshops and knowledge sharing, technical<br />
and commercial communication towards public and private<br />
stakeholders, involvement in product assessments and sideby-side<br />
comparisons, case studies and position papers and<br />
concrete project and partnership opportunities.<br />
Membership options and financial contributions will be<br />
based on engagement level, in two brackets:<br />
• General membership fee (discriminating small and<br />
medium sized enterprises, governmental and nongovernmental<br />
organizations and multi-national<br />
companies)<br />
• Project related fees for involvement in particular<br />
programs and projects<br />
Additionally, the organization will propose founding member<br />
contributions for establishing the organization, sponsorship<br />
packages and donations from various stakeholders.<br />
Next steps<br />
The Global Organization for PHA will be shaped in the<br />
coming months with a targeted formal establishment date<br />
in Q1-2019. The team has scheduled the following process:<br />
• December <strong>2018</strong>: gathering feedback on function,<br />
structure and support<br />
32 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Report<br />
Rick Passenier (PACE)<br />
Anindya Mukherjee<br />
(i2i Consulting)<br />
By:<br />
Rick Passenier<br />
PACE<br />
Amsterdam, The Netherlands<br />
• December <strong>2018</strong>-January 2019: formal proposal and request<br />
for support<br />
• February 2019: first-members-meeting to shape the<br />
foundation<br />
• February 2019: formal foundation of the organization.<br />
The founding members kindly ask all interested stakeholders<br />
to provide feedback, ideas, questions and support, before<br />
December 14 th , <strong>2018</strong> to the contacts published at the website<br />
www.gopha.org<br />
Platform activities<br />
Jan Ravenstijn<br />
Michael Carus<br />
(nova-Institut)<br />
External communication<br />
and recommendations<br />
Objective and pre-commercial<br />
data generation<br />
Communication, policy<br />
and legislation<br />
Lobby and influence Clear<br />
and collective voice<br />
Market proliferation<br />
Education<br />
Showcasing<br />
Design tools<br />
Technical & scientific<br />
knowledge development<br />
Exploration<br />
Joint development<br />
Project and partnership<br />
facilitation<br />
nova-Institute Events in <strong>2018</strong>/2019<br />
1 – 2 October <strong>2018</strong> · Maritim Hotel, Cologne, Germany<br />
www.REFAB.info<br />
6 – 8 November <strong>2018</strong> · Messe Stuttgart, Germany<br />
www.composites-europe.com<br />
20 – 21 March 2019 · Maternushaus, Cologne, Germany<br />
www.co2-chemistry.eu<br />
16 th International Conference<br />
of the European Industrial<br />
Hemp Association<br />
June 5 th – 6 th 2019<br />
15-16 May 2019 · Maternushaus, Cologne, Germany<br />
www.bio-based-conference.com<br />
5-6 June 2019 · Maternushaus, Cologne, Germany<br />
www.eiha-conference.org<br />
Contact: Mr. Dominik Vogt, +49 (0) 2233 48 14 49, dominik.vogt@nova-institut.de · All conferences at www.bio-based.eu<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 33
Applications<br />
PLA in the fridge<br />
Electrolux builds the world’s first bioplastic concept refrigerator<br />
By: Michael Thielen<br />
E<br />
arlier this year Electrolux, headquartered in Stockholm,<br />
Sweden, introduced a refrigerator prototype in<br />
which all the visible plastic parts were made of Ingeo<br />
PLA compounds. On the sidelines of the Innovation Takes<br />
Root conference in San Diego, bioplastics MAGAZINE talked<br />
to Marco Garilli, Innovation Expert-Polymers at Electrolux’<br />
Global Connectivity & Technology Center (Porcia, Italy)<br />
Sustainability is a top priority at Electrolux and the<br />
company is recognized as sustainability leader within their<br />
industry of household appliances (Industry Leader in Dow<br />
Jones Sustainability Index for 12 years in a row). Through<br />
their brands, including Electrolux, AEG, Anova, Frigidaire,<br />
Westinghouse and Zanussi, the company sells more than 60<br />
million household and professional products in more than 150<br />
markets every year.<br />
“Sustainability is part of the Electrolux business strategy<br />
and we are dedicated to innovate for more sustainable<br />
products and to reduce our carbon footprint. This (refrigerator)<br />
prototype is unique and helps us deliver on our purpose to<br />
shape living for the better,” said Henrik Sundström, Vice<br />
President Sustainability at Electrolux, in a press release<br />
announcing the product.<br />
According to Marco Garilli, Electrolux has adopted a 360°<br />
approach toward making its full range of appliances more<br />
sustainable. “This includes, for example, the energy and<br />
water consumption of our products,” he explained. “We have<br />
professional dishwashers consuming only 0.4 liters of water<br />
per rack. But it also includes the choice and use of materials,<br />
which are equally valuable resources.”<br />
A fundamental part of Electrolux effort to fulfill its<br />
sustainability ambitions is to offer more sustainable products,<br />
creating better experiences for the consumers as well as<br />
contributing to a better society.<br />
Back in the 1990s, Electrolux had already implemented lifecycle<br />
analysis as a means to assess the environmental impacts<br />
associated with all the stages of a product’s life and this has<br />
become more and more a key step in the development of new<br />
products. This evaluation is not only about the environmental<br />
impact, but also includes how a particular development would<br />
affect the manufacturing processes and the cost structure.<br />
As part of this approach, the company started to explore<br />
which materials could be replaced by other, or new materials:<br />
fossil-based materials, recyclable materials and biobased<br />
materials.<br />
“This also meant that we needed to pick the right partners<br />
and the right moment to enter into specific developments”,<br />
Marco said, “And NatureWorks was such a partner.”<br />
As Electrolux manufactures their own parts in house, they<br />
know the production processes involved. They first needed to<br />
establish whether their manufacturing systems could cope<br />
with any new materials.<br />
For the refrigerators in this case study, Electrolux wanted<br />
to replace the material used to produce the thermoformed<br />
liners (hitherto made from either high-impact polystyrene<br />
HIPS or ABS) and the transparent PS door shelves.<br />
Together with NatureWorks (Minnetonka, Minneapolis, USA)<br />
Ingeo PLA compounds were developed for these applications.<br />
The PLA could be processed without any modifications to<br />
Electrolux’ manufacturing lines. “We found out that the<br />
higher melt strength of PLA compared to HIPS offers further<br />
advantages, such as an improved homogeneity of the wall<br />
thickness of the thermoformed component.” Marco pointed<br />
out. “In addition, the inherent stiffness of PLA provides<br />
additional structural integrity.”<br />
In addition to its biobased origin, PLA offered several<br />
performance advantages over polystyrene (transparent PS<br />
as well as HIPS). The first, said Marco, is the significantly<br />
higher gloss which leads to a more aesthetical appearance.<br />
Furthermore, the chemical resistance, for example, against<br />
food oils and fats, was found to be very good. In terms of<br />
mechanical properties, the PLA also showed a number of<br />
advantages, for example in the enhanced impact properties for<br />
the transparent shelves in the refrigerator doors. Marco: ”We<br />
were surprised that the PLA, which is said to be rather brittle,<br />
performed slightly better than the transparent PS.” Another<br />
advantage of PLA over ABS to be investigated is the resistance<br />
to yellowing (UV resistance). In addition, NatureWorks’ Ingeo<br />
PLA systems do not contain any chemicals of concern.<br />
Electrolux has already committed to materials efficiency<br />
through the use of post-consumer recycled plastics, such<br />
as Carborec ® , a plastic compound based on recycled<br />
polypropylene, extending the lifetime of plastic coming from<br />
non-renewable resources. The bioplastic refrigerator is still in<br />
development and there is currently no timeframe set for when<br />
the product will be officially launched on the market.<br />
However, in the aforementioned press release, Jan<br />
Brockmann, Chief Operations Officer at Electrolux , said: “We<br />
are very excited and proud to have developed the world’s first<br />
bioplastic concept fridge, which is truly groundbreaking. Our<br />
ambition is to develop even more innovative, sustainable home<br />
appliances that we might see on the market in the future”.<br />
www.electroluxgroup.com<br />
(©liz linder photography)<br />
34 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Applications<br />
Industrial Solutions for Polymer Plants<br />
Polylactide Technology<br />
Uhde Inventa Fischer Polycondensation Technologies has expanded its product portfolio to<br />
include the innovative state-of-the-art PLAneo ® process for a sustainable polymer. The<br />
feedstock for our PLA process is lactic acid, which can be produced from local agricultural<br />
products containing starch or sugar. The application range of PLA is similar to that of polymers<br />
based on fossil resources as its physical properties can be tailored to meet packaging, textile<br />
and other requirements. www.uhde-inventa-fischer.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 35
Application AutomotiveNews<br />
Peeling milk with P3HB<br />
In October <strong>2018</strong>, the Czech companies NAFIGATE<br />
Cosmetics and NAFIGATE Corporation launched a<br />
new product - Coconut shower peeling milk, in which<br />
microbeads are replaced with Hydal P3HB. The whole<br />
new cosmetics eco-design concept received the name<br />
Dedicated to You and Nature in order<br />
to express its biodegradability and<br />
biocompatibility. Hence, coconut shower<br />
peeling milk represents a circular<br />
revolution in the cosmetics industry. It<br />
is fully biodegradable, waste-free and<br />
harmless to nature.<br />
Microplastics are solid plastic beads of<br />
less than five millimetres. In cosmetics,<br />
they are used as peeling particles in the form of polyethylene<br />
microbeads of less than one millimetre in their largest<br />
dimension that peel off dead skin cells. Once microbeads<br />
are washed off from skin, they get into water, where they<br />
do not biodegrade. Microbeads can cause plastic water<br />
pollution and be harmful to aquatic life because wastewater<br />
treatment plants cannot capture such small particles.<br />
According to various research studies including the results<br />
of the Institute of Hydrodynamics of the Czech Academy of<br />
Sciences, drinking water also contains microplastics.<br />
P3HB biopolymer is processed by the unique Czech<br />
biotechnology HYDAL, which as the first in the world on<br />
industrial scale uses 100 % waste in the<br />
form of waste cooking oil (WCO). Hydal<br />
P3HB is added in the shower peeling milk<br />
in the form of white particles, replacing the<br />
abrasive function of microbeads. Unlike other<br />
abrasive materials utilized in cosmetics,<br />
biopolymer’s properties, such as sharpness<br />
or size, may be modified. In addition, P3HB<br />
as a pure chemical substance allows meeting<br />
the highest hygienist cosmetics standards.<br />
In contrast to other substances, it dissolves in water<br />
completely. According to the company’s tests, biopolymer<br />
biodegrades in wastewater treatment plant within several<br />
days, in the open environment up to several dozen days. It<br />
does not harm nature and provides a solution to one of the<br />
most serious challenges in the cosmetics industry. MT<br />
www.lagranda.it | www.braskem.com<br />
New bio shoe line<br />
Leading global barefoot footwear company<br />
VIVOBAREFOOT, headquartered in London, UK, recently<br />
announced the launch of its new Bio shoe range featuring<br />
Primus Lite Bio, plant-based performance sneakers.<br />
Designed with outdoor performance in mind, the Bio range is<br />
made from a combination of three innovative bio-based<br />
materials that reduce reliance on petrochemicals<br />
and ultimately create more efficient and sustainable<br />
products. Each shoe in Vivobarefoot’s new line is<br />
nearly 50 % plant-based, making it Vivobarefoot’s<br />
latest stride in their quest to use 90 % sustainable<br />
materials across its entire product range by 2020.<br />
The materials used in new Primus Lite Bio<br />
range are produced by DuPont Tate & Lyle Bio<br />
Products, a joint venture between DuPont, a<br />
global science innovator, and Tate & Lyle, a worldleading<br />
renewable food and industrial ingredients<br />
company. Through the use of these renewable, highperformance<br />
materials, Vivobarefoot is able to make<br />
a significant impact on the planet. Every 50,000 pairs of<br />
shoes produced using these materials, equates to saving<br />
greenhouse gas emissions from 247,948 miles driven by an<br />
average passenger vehicle or reducing CO 2<br />
emissions from<br />
11,286 gallons of gasoline consumed.<br />
“We are trying to make a significant impact through<br />
working with game changing brands like Vivobarefoot who<br />
are committed to producing products with fantastic technical<br />
performance and improved sustainability profiles,” stated<br />
Laurie Kronenberg, global marketing director at DuPont<br />
Tate & Lyle Bio Products. “In working with Vivobarefoot on<br />
optimizing their plant-based content throughout the shoe<br />
using various Sorona PTT fiber and Susterra bio-PDObased<br />
solutions it allowed us to model the environmental<br />
reductions in terms of greenhouse gas emissions and<br />
nonrenewable energy on a raw material basis. Now that is<br />
impactful.”<br />
Seventh-generation shoemakers Galahad and Asher Clark<br />
are firm believers that barefoot shoe-making is sustainable<br />
shoe making. The company has already pioneered shoes<br />
made of repurposed algae (Ultra 3 BLOOM) with<br />
each pair recirculating 215 litres of fresh water<br />
back into the natural habitats, and an Eco range<br />
made of 50 % recycled plastic. In 2017, Vivobarefoot<br />
diverted over 2 million plastic bottles from landfills<br />
into barefoot shoes.<br />
“Sustainability is at the core of Vivobarefoot’s<br />
mission and we believe that the perfect shoe has<br />
minimal interference with natural movement and<br />
minimal impact on the environment,” said Asher<br />
Clark, design director at Vivobarefoot. “The new<br />
Primus Bio line champions the future of sustainable<br />
materials and the new opportunities they bring to the<br />
footwear industry.”<br />
The Vivobarefoot Bio range will include the hero<br />
performance shoes Magna Trail Bio, Primus Trail Bio,<br />
Primus Lite Bio and Ultra Bio shoes. The Primus Lite Bio<br />
shoes for example will be available at www.vivobarefoot.<br />
com/us starting June 2019 and priced from $120 to $160. MT<br />
www.vivobarefoot.com/us<br />
36 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Application News<br />
Clipper tea bags<br />
renewably-sourced<br />
Public outcry about and subsequent resistance to tea<br />
bags made with polypropylene has compelled brand<br />
owners to take action. The latest to do so is Clipper Teas,<br />
the tea brand owned by natural and organic food company<br />
Wessanen, Amsterdam, The Netherlands.<br />
The company announced in April of this year that it had<br />
committed to use only fully biodegradable tea bags by<br />
summer <strong>2018</strong>.<br />
It was a little later than that, but on October 20, the<br />
company said it moved all production to ‘plastic-free,<br />
unbleached and non GM (genetically modified) tea bags’,<br />
adding: “And we won’t be going back!”<br />
There will be a transition period of up to a few months<br />
while retailers sell through current stock, said the<br />
company as “we don’t believe in waste”.<br />
According to Clipper, the polypropylene in the tea bag<br />
paper originally served to heat seal the two layers of<br />
the unbleached tea bag paper together. The company<br />
has now developed an alternative tea bag paper, made<br />
from natural, plant based materials – a blend of abaca<br />
(a species of banana), plant cellulose fibres and a PLA<br />
derived from non-GM plant material that helps hold the<br />
paper together. In the past, while aware of the availability<br />
of this plant-based option, Clipper had never used or<br />
considered using PLA, as the corn used as feedstock in<br />
the PLA made by one major manufacturer could be from<br />
GM sources.<br />
Since the official announcement, other producers have<br />
also entered the market, offering PLA guaranteed to be<br />
from a non-GM source and enabling Clipper to make the<br />
switch to a 100% renewably-sourced tea bag paper. To let<br />
consumers know about the change, an on-pack flash will<br />
be rolling out on specific products from January 2019.<br />
COMPEO<br />
Leading compounding technology<br />
for heat- and shear-sensitive plastics<br />
(Photo: Wessanen)<br />
Clipper is claimed to be the world’s largest buyer of<br />
Fairtrade tea. It exports its products to over 50 countries<br />
worldwide. Its parent company, Wessanen UK, is<br />
CarbonNeutral certified. and either directly or through<br />
its subsidiaries, accredited by or a member of a range of<br />
industry bodies and associations including; the Fairtrade<br />
Foundation; the Soil Association; the UK Tea & Infusions<br />
Association, and the Organic Trade Board.MT<br />
www.wessanen.com<br />
Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />
With its new COMPEO Kneader series, BUSS continues<br />
to offer continuous compounding solutions that set the<br />
standard for heat- and shear-sensitive applications, in all<br />
industries, including for biopolymers.<br />
• Moderate, uniform shear rates<br />
• Extremely low temperature profile<br />
• Efficient injection of liquid components<br />
• Precise temperature control<br />
• High filler loadings<br />
www.busscorp.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 37
Application News<br />
Automotive<br />
Pastille bio-polyamide lamp<br />
Wästberg is a Swedish lighting company from Helsingborg,<br />
that aimed at bringing back light to human proximity.<br />
At Orgatec (October <strong>2018</strong>, Cologne Germany) the company<br />
launched a new lamp series made with bio-polyamide. The<br />
lamp was created in collaboration with Sam Hecht and Kim<br />
Colin of London-based studio Industrial Facility and Berlinbased<br />
designer Dirk Winkel.<br />
The lamp w182, called Pastille<br />
is a minimalist light which can<br />
be described as a pure disc of<br />
light attached to a thin line, a<br />
construction that allows a variety<br />
of surfaces to be illuminated.<br />
Different to task lamps that<br />
illuminate in a focused way; or<br />
table and pendant lamps that<br />
provide ambient light, the w182<br />
pastille family of lights sees<br />
environments as surfaces to<br />
softly illuminate, be it a wall, a<br />
floor or a table.<br />
w182 pastille is made of a highperformance<br />
material. A glassfibre reinforced bio-polyamide<br />
that is based on over 60 % renewably biologically sourced<br />
and recyclable material made from castor oil. Its material<br />
provides warmth and strength, making w182 pastille lighter<br />
and easier to adjust from anywhere on the lamp. At the top<br />
of its vertical pole is a single control button.<br />
But the bio-polymaide provides other benefits, too. There<br />
is no metal to be painted to achieve the desired look. The<br />
plastic is dyed with pigments, no touch-ups are needed over<br />
time. “The other thing we discovered is that the bioplastic<br />
is helping us with dissipating heat–like metal,” Hecht says<br />
at fastcompany.com. “That meant we could reduce the heat<br />
sink, which is taking away the heat from the LED, which<br />
reduces weight and cost.”<br />
The glass-reinforced<br />
bioplastic is also cheaper<br />
than metal, without having to<br />
sacrifice any quality to keep the<br />
price down–the studio estimates<br />
it would cost 50 % more in metal.<br />
“Unfortunately the pressures of<br />
price are so huge that normally<br />
the response is to try and<br />
maintain the typology, whether<br />
it’s a chair or lamp, and just<br />
reduce the quality to match the<br />
price,” Hecht says. “What we’re<br />
trying to do is challenge that and<br />
say surely we can use design<br />
and engineering to create something very beautiful that is<br />
affordable but has some decency to it in its materiality.”MT<br />
www.wastberg.com<br />
source: tinyurl.com/bio-pa-lamp<br />
Biodegradable crisps bags made from eucalyptus<br />
Two Farmers, Sean Mason and Mark Green, from<br />
Herefordshire, UK had the vision of making delicious<br />
hand-cooked potato crisps that<br />
celebrate the true flavours of<br />
Herefordshire, whilst protecting<br />
their beloved countryside with a<br />
100% compostable bag.<br />
The crisp bags are available<br />
in two sizes, 40g making them<br />
perfect for snacking and 150g<br />
which makes them perfect for<br />
sharing… if you want to share… .<br />
Available flavours include Hereford Hop Cheese and Onion,<br />
Salt and Cider Vineger, and Hereford Bullshot which features<br />
a hint of Hereford beef.<br />
The packets are made from cellulose and sustainably<br />
grown eucalyptus trees from managed plantations. This<br />
means that they are 100 % compostable and will compost<br />
in a home-composting environment in a little over 26<br />
weeks! Information whether<br />
the packages are certified<br />
compostable were not<br />
disclosed until bioplastics<br />
MAGAZINE went to print.<br />
The founders wrote on<br />
Facebook: “We are proud to<br />
be producing our new range of<br />
crisps in 100 % compostable<br />
packs, a first we think for the<br />
UK and a big step forward in dealing with our waste issues.<br />
Two Farmers co-founder Sean Mason said on the firm’s<br />
website that “a potato merchant inspired him to protect the<br />
countryside around him”. MT<br />
www.twofarmers.co.uk<br />
38 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Report<br />
Cruise entrepreneur switches<br />
to biobased plastics<br />
Biobased plastics are an essential element for plastic-free holidays<br />
Plastic-free holidays on a cruise ship – this was the<br />
vision that led cruise operator TUI Cruises (Kiel,<br />
Germany) to launch their new plastics reduction<br />
program WASTELESS.<br />
Since its founding, the company has worked continuously<br />
to minimize the amount of plastic waste it generates. For<br />
example, all cabins on board have already been equipped<br />
with glass water carafes that can be filled by guests at any<br />
time using the water dispensers in the corridors. This saves<br />
on disposable plastic bottles. Refillable dispensers for<br />
shampoo and shower gel have been installed in the showers<br />
in the cabins of all the new TUI Cruises ships, representing<br />
a saving of some 380,000 disposable packs a year across<br />
the fleet. Further initiatives include eliminating the plastic<br />
wrapped terrycloth slippers provided to guests for use at<br />
the pool or sauna: instead, these will now be conveniently<br />
tucked into the pockets of the bathrobes, saving 250,000<br />
plastic packages per year. The laundry bag for the collection<br />
of dirty laundry will soon be made of biobased plastic based<br />
on sugar cane and starch, yielding an imminent saving of<br />
about 270,000 petroleum-based plastic bags. The impact in<br />
the catering department will be even more impressive: the<br />
first step will be the conversion of the coffee-to-go cups in<br />
the crew area: the inner coating and lids will in future be<br />
made of biobased plastic and no longer of petroleum-based<br />
plastic.<br />
But how is waste in general - and bioplastics, in particular<br />
- treated on board cruise ships? bioplastics MAGAZINE spoke<br />
with Friederike Grönemeyer, Communications Manager<br />
of TUI-Cruises. “We relieve our passengers of the task<br />
of separating waste,” said Friederike. “All garbage is<br />
separated centrally in our garbage room and disposed of<br />
responsibly.” She explained that glass is crushed, cans<br />
and paper are pressed and prepared for disposal on land.<br />
Organic (food) waste is crushed in a so-called pulper, dried<br />
and also composted on land or, diluted with water, disposed<br />
of outside the 12-mile zone in the sea. Some packaging<br />
waste is prepared for recycling or is incinerated clean and<br />
with energy recovery on board in an appropriate energy<br />
plant.<br />
Disposal ashore takes place not only in the home port of<br />
Kiel, but also in larger port cities around the world. “We<br />
make sure we have the right responsible partners there,”<br />
she emphasised. There is always an environmental officer<br />
on board for all these tasks.<br />
“All in all, we achieve an overall recycling rate of 31%,”<br />
says Friederike Grönemeyer.<br />
By the end of 2020, plastic products and non-essential<br />
disposable items will have been phased out and replaced<br />
by renewably-sourced sustainable alternatives, both aboard<br />
the current six ships of the Mein Schiff fleet and on land.<br />
www.tuicruises.com<br />
Info<br />
See a video-clip<br />
(German language) at:<br />
tinyurl.com/tui-wasteless<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 39
40 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Brand Owner<br />
Brand-Owner’s perspective<br />
on bioplastics and how to unleash<br />
its full potential<br />
“We believe the time is now to step up and accelerate, embrace our<br />
responsibility and work with others to engage a radical shift that will help free<br />
the world from packaging waste. We will be acting both at global and local<br />
level to ensure circularity of packaging becomes the new norm. (Today), we are<br />
announcing a series of investments and commitments that – I believe – will have<br />
a concrete impact. These will be amplified as we collaborate with industry-peers,<br />
governments, NGOs, start-ups and the finance sector; harness new technologies<br />
and invest in new solutions.”<br />
And, from a press release: Danone commits to ensure that all its packaging is<br />
designed to be 100 % recyclable, reusable or compostable by 2025. Already 86 %<br />
of our packaging is recyclable, reusable or compostable.<br />
In parallel, we will develop the use of renewable, biobased materials. We have<br />
a joint project with Nestle, PepsiCo and Origin Materials to bring the first 75 %<br />
biobased bottle to commercial scale by 2021, aiming to launch 100 % biobased<br />
bottles by 2025. Find the complete press release at: tinyurl.com/danone<strong>2018</strong><br />
www.danone.com<br />
Emmanuel Faber, Chairman and CEO of Danone<br />
(Photo: creative commons swaf75)<br />
Are you looking for a bio-based food<br />
packaging alternative?<br />
Bio-based multilayer transparent barrier films are now reality. Our masterbatches can<br />
help introduce PLA into your portfolio. Make the switch today.<br />
www.sukano.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 41
From Science & Research<br />
How to<br />
calculate land<br />
use accurately<br />
A sensitivity approach<br />
By:<br />
Christian Schulz, Research associate<br />
Hans-Josef Endres, Head of the institute<br />
Hochschule Hannover,<br />
IfBB – Institute for Bioplastics and Biocomposites<br />
Hannover, Germany<br />
Satisfying (growing) human needs requires efficient use of<br />
limited economic resources. This also applies to the discussion<br />
about the use of available agricultural land, which in<br />
particular bioplastics has increasingly had to face in recent years.<br />
Previous estimates by IfBB - Institute for Bioplastics and Biocomposites,<br />
Hannover, Germany, have already shown that the impact<br />
of producing new generation bioplastics (New Economy such as<br />
PLA, Bio-PE, etc.) based on agricultural raw materials, such as<br />
starch, sugar and vegetable oil, is currently marginal at around<br />
0.05 % in 2017 and probably 0.07 % in 2022 in terms of land use<br />
compared to the global amount of arable land.<br />
Figure 1 shows the development of the global production<br />
capacity of the New Economy bioplastics industry, which currently<br />
stands at around 2.3 million tonnes per year. In comparison, the<br />
amounts of Old Economy bioplastics, such as natural rubber (e.g.<br />
for tires), cellulosics (esp. for non-degradable cigarette filters and<br />
textiles) and linoleum with a total of 17 million tonnes per year<br />
are much larger. Comparing previous land area estimates for both<br />
industries, it can be seen that the production capacity of the Old<br />
Economy is only 7 to 8 times higher than that of the New Economy,<br />
but the supply of raw materials for the Old Economy with a total<br />
of 15 million hectares needs more than 20 times the land area<br />
compared to the New Economy. (Old Economy is not subject of the<br />
considerations, as these bioplastics have been used for more than<br />
100 years and in addition go into applications that are very different<br />
from those of the New Economy).<br />
Despite these differences in size – both being easily marginalized<br />
when comparing to the land use of pastures for grazing of<br />
livestock at 3.5 billion hectares (FAO <strong>2018</strong>) –, plastics from the<br />
New Economy yet had to face up to the question of land use. As<br />
previous assumptions to calculate land use for biobased plastics<br />
in the New Economy have always been estimates made with high<br />
safety factors and using a conservative approach, the following<br />
considerations should indicate which factors are relevant for land<br />
use estimation, how these can be made more realistic and how it<br />
affects the already marginal share of global arable land.<br />
In order to find sensitivities and to compare variations in<br />
results for land use of bioplastics, one needs to know how it<br />
basically was calculated before. This approach has been used as<br />
standard method for European Bioplastics’ annual statistic update<br />
until 2017 and is adapted in this year with more specific data of<br />
bioplastics producers, missing until now in the estimates.<br />
Based on process data from literature, experts and own<br />
calculations, Figure 2 shows a sample process route showing<br />
the manufacturing steps involved from the raw material to<br />
the finished product, specifying the individual process steps,<br />
intermediate products, and input-output streams. PLA is used<br />
here as an example, as it is one of the most important New<br />
Economy bioplastics. This is only one representative of all other<br />
New Economy bioplastics, to which this approach is applied –<br />
each with its own process route.<br />
Production capacities and land use<br />
Old and New Economy bioplastics<br />
Figure 1<br />
New Economy bioplastics global production capacities<br />
12 000 000<br />
Natural rubber<br />
56 000<br />
Linoleum 3<br />
5 000<br />
4 000<br />
4 305<br />
1 740<br />
672 000<br />
New Economy bioplastics 1<br />
2 900 000<br />
Cellulose 2<br />
10 978 000<br />
Natural rubber<br />
140 000<br />
Linoleum 3<br />
in 1 000 t<br />
3 000<br />
2 000<br />
1 000<br />
0<br />
2 028<br />
1 697<br />
737<br />
663<br />
1 034 1 291<br />
2014 2015<br />
2 048<br />
757<br />
1 291<br />
2016<br />
2 274<br />
881<br />
1 393<br />
2017<br />
Forecast<br />
2 565<br />
2022<br />
2 273 000<br />
New Economy bioplastics 1<br />
5 800 000<br />
Cellulose 2<br />
1 PLA, PHA, PTT, PBAT, Starch blends, Drop-Ins (Bio-PE, Bio-PET, Bio-PA) and other<br />
2 Material use excl. paper industry<br />
3 Calculations include linseed oil only<br />
Bio-based/non-biodegradable<br />
Biodegradable<br />
Total capacity<br />
Biopolymers, facts and statistics <strong>2018</strong> – 41<br />
42 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
From Science & Research<br />
To obtain land use data from production capacities in this<br />
bottom-up approach (see Table 1), it needs producer-specific<br />
production capacities of a type of bioplastics to be multiplied by<br />
the output data of the corresponding process routes. If producerspecific<br />
feedstock was known, it was taken into consideration.<br />
In other cases, where these data were missing, only the most<br />
common used crop per material was taken into consideration (e.g.<br />
corn starch for PLA).<br />
For the basic assumptions referring to PLA, previous estimates<br />
of IfBB resulted in a need of 0.37 hectares land for feedstock<br />
cultivation per tonne of material. This is a corn-based, PLAspecific<br />
global average land use factor, for which the following<br />
calculation impact factors (CIF) are assumed.<br />
One obvious impact factor on land use of bioplastics might be<br />
the production capacity itself. According to own research, total<br />
annual installed capacity for PLA worldwide in 2017 was roughly<br />
240,000 tonnes, which gives 88,300 hectares according to the<br />
basic assumptions. However, is relying on the installed capacity<br />
correct? Very few industrial plants run at full degree of capacity<br />
continuously, so an optimistic sensitivity would be 85 % degree of<br />
capacity.<br />
Another impact factor is the region specific yield of a feedstock<br />
in different countries. While for the basic estimation for PLA made<br />
out of corn, a global average yield of 6.5 tonnes of corn per hectare<br />
over the past decade (weighted by production amount) (FAO <strong>2018</strong>),<br />
corn being grown in the United States in the same period would<br />
yield in 9.5 tonnes per hectare and the same acreage in China<br />
delivered 40 % less of corn (5.5 t / ha). This is even more important,<br />
as corn from USA makes up to 37 % of world’s corn production,<br />
but China, with its significantly lower yield per hectare still ranks at<br />
an important one fifth (20 %) of global corn production. Therefore it<br />
has a decreasing effect on the global average corn yield (6.5 t / ha).<br />
Further impacts derive from natural harvesting fluctuation.<br />
Using single year data leads to tremendous deviation in calculating<br />
PLA land use. Comparing available corn yields between 2002<br />
and 2013 for e.g. corn in the USA shows, that there is a deviation<br />
between minimum and maximum of 3.2 tonnes per hectare<br />
(Average yield: 9.1 t / ha). By using either minimum or maximum<br />
yield data of a given period for calculation will result in this case in<br />
a fluctuation of land use of +43 % or -30 %.<br />
But even when looking at a global average yield for corn, the<br />
choice of a certain decade leads to different results. Using a global<br />
average yield over a mid-term period (10 years) helps to minimize<br />
natural harvesting fluctuation while at the same time provides<br />
data, which are not influenced by single local yield deviations.<br />
When comparing two different time periods (2002 – 2011 and 2003<br />
– 2014), the worldwide general increase in harvesting yields of<br />
corn raised by 2.5 %. For other (food) crops relevant in bioplastics<br />
production, the increase is at the same level or even higher, e.g.<br />
sugar beet (+ 5.9 %), sugar cane (+ 1.9 %) and castor oil (+ 17.1 %).<br />
Advances in crop growing techniques and better feedstock yields<br />
result in a lower land use, which decreases to the same extent<br />
for each bioplastic material. Even without changes in bioplastics<br />
technology (1st, 2nd, 3rd generation), future land use per tonne of<br />
bioplastic material will de facto decrease.<br />
Additional impact factors could arise from the source of<br />
feedstock (e.g. PLA made from sugar cane versus corn starch)<br />
and allocation assumptions. Allocation is in detail also a very<br />
complex topic and would go beyond the scope of this comparison<br />
as there are different factors itself, which can be used. In general,<br />
this would be mass-balanced, energy-balanced or economicbalanced<br />
allocation. In this case, if using residues is being taken<br />
into account, the bioplastic material will only be burdened with<br />
parts of the full impact of its land use. To make a proposal, the<br />
results will cover 30 % use of residues.<br />
Stepping back from the different impact factors and having a<br />
look at the resulting effects on land use of PLA Figure 3 shows<br />
the impact for the recent global capacity of about 240,000 tonnes<br />
for PLA.<br />
If all raw material was from one country (USA), depending on<br />
different yields per year, this amount of PLA land use ranges from<br />
nearly 80,000 up to almost 115,000 hectares. And even using a<br />
global average yield can still cause slight variations, depending<br />
on which time horizon is assumed (± 2,600 hectares). Last<br />
comparison in Figure 3 shows the influence of locally produced<br />
feedstock as displayed here for Chinese and US-American corn,<br />
resulting in a difference of nearly 43,000 hectares.<br />
Figure 4 compares further impact factors concerning a<br />
more realistic degree of plant capacity being used or an overall<br />
Yield [ t PLA/ha]<br />
6<br />
4<br />
2<br />
0<br />
Figure 3 Figure 4<br />
2.7<br />
Land use for PLA derived from corn<br />
Comparing effects of different feedstock impact factors<br />
240,000 t PLA (2017)<br />
2.1<br />
3.0<br />
114,500 ha<br />
88,300 ha 80,000 ha<br />
Base calculation Local harvest<br />
fluctuation (USA)<br />
2.7 2.8<br />
88,300 ha<br />
Time horizon<br />
Global average<br />
2.3<br />
3.9<br />
104,300 ha<br />
USA vs. China<br />
Global / regional<br />
higher is better<br />
85,700 ha 61,500 ha<br />
Base<br />
Low<br />
High<br />
Yield [ t PLA/ha]<br />
8<br />
6<br />
4<br />
2<br />
0<br />
Land use for PLA derived from corn<br />
Comparing effects of various impact factors<br />
2.7 2.7<br />
Base calculation Prod. capacity<br />
85 %<br />
240,000 t PLA (2017)<br />
88,300 ha 75,000 ha 61,500 ha 38,100 ha<br />
3.9<br />
Allocation<br />
overall 30 %<br />
6.3<br />
Source of<br />
feedstock<br />
higher is better<br />
Base<br />
Variations<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 43
From Science & Research<br />
allocation of 30 % and shows land use ranges for PLA capacity<br />
in 2017 from 75,000 hectares down to 38,000 hectares, if another<br />
source of feedstock (sugar cane) would be used.<br />
Summarizing, having single changes in fluctuations and raw<br />
material yield assumptions by each, results in a range between<br />
38,000 and almost 115,000 hectares of land, which is necessary to<br />
produce exactly the same amount of PLA.<br />
Looking at different approaches to feedstock yield and how<br />
it affects land use calculation of recent PLA capacities, there is<br />
a tremendous variation in results to be found. By the means of<br />
feedstock yields, land use ranges from -30 % to +30 % and using<br />
another feedstock source varies results up to -57 % compared to<br />
the base calculation.<br />
Thus, results of land use calculations can range as high as the<br />
amount and range of possible impact factors. This is to be kept in<br />
mind, if not only one but two or more impact factors at the same<br />
time are applied, which will multiply and lead to further increased<br />
ranges. Accumulating all ‘best case’ factors in this scenario would<br />
correspond to a theoretical land use of 25,000 hectares of PLA (-76<br />
% against base calculation).<br />
Now, how do we calculate accurately? Concerning deviations<br />
in results due to differing impact factors and also keeping in<br />
mind, that there is no ‚common sense‘ cut-off-rule for renewable<br />
feedstocks (not even in life cycle assessments), there is still more<br />
work needed on this topic. The shown examples could help to<br />
assess land use of bioplastics in a more realistic approach but as<br />
all data gathered by IfBB is openly accessible, further adaptations<br />
to the calculation of land use can be made individually, if needed.<br />
At this point, it should be mentioned that, despite the negligible<br />
amount of land use, even without a more realistic approach of<br />
calculation, there is no reason for the industry to rest on it. The<br />
pressure on agricultural land in the coming decades due to the<br />
growing world population, the loss and erosion of cultivated land<br />
will increase, and thus bioplastics will not be able to escape<br />
discussion.<br />
But there is a major advantage here: The development of<br />
bioprocessing technology increases the possibility of large-scale<br />
use of alternative renewable raw materials, which can be grown<br />
on barren soils, as well as arising new building blocks and the<br />
decomposition of organic waste streams as the starting point for<br />
the (re-)synthesis of biobased polymers is a foreseeable future.<br />
However, the primary goal for all biobased plastics, as well as<br />
for the plastics industry as a whole, should be to create intelligent<br />
material cycles and to achieve higher recycling rates. If the need<br />
for virgin material was to be reduced effectively, fewer resources<br />
would be needed to keep the plastic circle rolling. Saving raw<br />
materials could also be a way to keep the land use impact of<br />
bioplastics on a low level, when the emerging trend steadies or<br />
increases in the near future, to produce larger quantities of usually<br />
petro-based plastics from now available biobased building blocks<br />
(drop-ins).<br />
More information can be found in IfBB’s annualy updated<br />
publication of Biopolymers. Facts and statistics. It can be<br />
downloaded for free at: bit.ly/factsandstatistics<br />
www.ifbb-hannover.de<br />
Table 1<br />
Material group Producer To tal annual<br />
capacity<br />
[t]<br />
Calculations<br />
PLA<br />
A<br />
B<br />
C<br />
Land use<br />
factor<br />
[ha / t]<br />
Multiplication<br />
Equals<br />
To tal annual<br />
land use<br />
[ha]<br />
240,000 0.368 88,300<br />
Figure 2<br />
Sample process route<br />
select desired feedstock/crop, i.e.<br />
sugar cane or sugar beet<br />
land use for 1 t of<br />
resulting polymer<br />
feedstock/crop<br />
0.09 ha<br />
1 387 m³<br />
Sugar<br />
cane<br />
6.62 t<br />
or<br />
0.09 ha<br />
711 m³<br />
Sugar<br />
beet<br />
5.37 t<br />
water usage for<br />
feedstock/crop amount<br />
raw material<br />
Sugar<br />
0.86 t<br />
(chemical) process<br />
process inputs<br />
H2O<br />
Microorg.<br />
Fermentation<br />
CO2<br />
Filtration<br />
H2O<br />
Microbial<br />
mass<br />
intermediate product<br />
resource has<br />
petro-based origin<br />
1,4-BDO<br />
0.52 t<br />
Succinic<br />
acid *<br />
0.69 t<br />
Esterification<br />
Polycondensation<br />
H2O<br />
0.10 t<br />
H2O<br />
0.10 t<br />
process outputs<br />
PBS<br />
bb SCA<br />
1.00 t<br />
resulting polymer<br />
44 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Automotive<br />
10<br />
Published in<br />
bioplastics MAGAZINE<br />
Years ago<br />
In November <strong>2018</strong>,<br />
Marco Jansen, Commercial<br />
Director Renewable<br />
Chemicals Europe & North<br />
America of Braskem says:<br />
We remain committed to<br />
develop biobased solutions<br />
to offer more sustainable<br />
products for our clients. Earlier<br />
this year we announced<br />
investment into a demo<br />
plant for biobased MEG,<br />
opening a 2 nd biotech lab in<br />
Boston as well as launching<br />
the world’s first biobased<br />
EVA. Biobased Polypropylene<br />
is not yet launched but<br />
remains one of our potential<br />
future sustainable solutions.<br />
tinyurl.com/2008-biopp
Basics<br />
Glossary 4.2 last update issue 02/2016<br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
such as PLA (Polylactide) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
1 st Generation feedstock | Carbohydrate rich<br />
plants such as corn or sugar cane that can<br />
also be used as food or animal feed are called<br />
food crops or 1 st generation feedstock. Bred<br />
my mankind over centuries for highest energy<br />
efficiency, currently, 1 st generation feedstock<br />
is the most efficient feedstock for the production<br />
of bioplastics as it requires the least<br />
amount of land to grow and produce the highest<br />
yields. [bM 04/09]<br />
2 nd Generation feedstock | refers to feedstock<br />
not suitable for food or feed. It can be either<br />
non-food crops (e.g. cellulose) or waste materials<br />
from 1 st generation feedstock (e.g.<br />
waste vegetable oil). [bM <strong>06</strong>/11]<br />
3 rd Generation feedstock | This term currently<br />
relates to biomass from algae, which – having<br />
a higher growth yield than 1 st and 2 nd generation<br />
feedstock – were given their own category.<br />
It also relates to bioplastics from waste<br />
streams such as CO 2<br />
or methane [bM 02/16]<br />
Aerobic digestion | Aerobic means in the<br />
presence of oxygen. In →composting, which is<br />
an aerobic process, →microorganisms access<br />
the present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material<br />
to energy, CO 2<br />
, water and cell biomass,<br />
whereby part of the energy of the organic material<br />
is released as heat. [bM 03/07, bM 02/09]<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />
Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without<br />
practically releasing any heat. The biogas can<br />
be treated in a Combined Heat and Power<br />
Plant (CHP), producing electricity and heat, or<br />
can be upgraded to bio-methane [14] [bM <strong>06</strong>/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight<br />
(biopolymer, monomer is →Glucose) [bM 05/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose) [bM 05/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from →biomass. A material or<br />
product made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radio carbon dating method)<br />
that adheres to the technical specifications as<br />
described in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective<br />
labels. Ideally, meaningful labels should be<br />
based on harmonised standards and a corresponding<br />
certification process by independent<br />
third party institutions. For the property<br />
biobased such labels are in place by certifiers<br />
→DIN CERTCO and →Vinçotte who both base<br />
their certifications on the technical specification<br />
as described in [4,5]<br />
A certification and corresponding label depicting<br />
the biobased mass content was developed<br />
by the French Association Chimie du Végétal<br />
[ACDV].<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method has<br />
been developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1]<br />
[bM 01/07, bM 03/10]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/<strong>06</strong>, bM 01/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a →life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its →global warmingpotential<br />
[1,2,15]<br />
46 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Basics<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For<br />
example, carbon neutrality means that any<br />
CO 2<br />
released when a plant decomposes or<br />
is burnt is offset by an equal amount of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to →biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of →cellulose<br />
[bM 01/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. Cellulose is a polymeric molecule<br />
with very high molecular weight (monomer is<br />
→Glucose), industrial production from wood<br />
or cotton, to manufacture paper, plastics and<br />
fibres [bM 01/10]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic<br />
acids. The most important cellulose esters<br />
from a technical point of view are cellulose<br />
acetate (CA with acetic acid), cellulose propionate<br />
(CP with propionic acid) and cellulose<br />
butyrate (CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Certification | is a process in which materials/products<br />
undergo a string of (laboratory)<br />
tests in order to verify that the fulfil certain<br />
requirements. Sound certification systems<br />
should be based on (ideally harmonised) European<br />
standards or technical specifications<br />
(e.g. by →CEN, USDA, ASTM, etc.) and be<br />
performed by independent third party laboratories.<br />
Successful certification guarantees<br />
a high product safety - also on this basis interconnected<br />
labels can be awarded that help<br />
the consumer to make an informed decision.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM <strong>06</strong>/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/<strong>06</strong>, bM 01/07]<br />
Composting | is the controlled →aerobic, or<br />
oxygen-requiring, decomposition of organic<br />
materials by →microorganisms, under controlled<br />
conditions. It reduces the volume and<br />
mass of the raw materials while transforming<br />
them into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a<br />
managed composting facility is meant (criteria<br />
defined in EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much<br />
higher and kept stable, whereas in the composting<br />
pile temperatures are usually lower,<br />
and less constant as depending on factors<br />
such as weather conditions. Home composting<br />
is a way slower-paced process than<br />
industrial composting. Also a comparatively<br />
smaller volume of waste is involved. [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the cradle (i.e., the extraction of raw materials,<br />
agricultural activities and forestry) up<br />
to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane). Developments to<br />
make terephthalic acid from renewable resources<br />
are under way. Other examples are<br />
polyamides (partly biobased e.g. PA 4.10 or PA<br />
6.10 or fully biobased like PA 5.10 or PA10.10)<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging or a service. [16]<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Enzyme-mediated plastics | are no →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched<br />
with small amounts of an organic additive.<br />
Microorganisms are supposed to consume<br />
these additives and the degradation process<br />
should then expand to the non-biodegradable<br />
PE and thus make the material degrade. After<br />
some time the plastic is supposed to visually<br />
disappear and to be completely converted to<br />
carbon dioxide and water. This is a theoretical<br />
concept which has not been backed up by<br />
any verifiable proof so far. Producers promote<br />
enzyme-mediated plastics as a solution to littering.<br />
As no proof for the degradation process<br />
has been provided, environmental beneficial<br />
effects are highly questionable.<br />
Ethylene | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, monomer of<br />
the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European<br />
Bioplastics today represents the interests<br />
of about 50 member companies throughout<br />
the European Union and worldwide. With<br />
members from the agricultural feedstock,<br />
chemical and plastics industries, as well as<br />
industrial users and recycling companies, European<br />
Bioplastics serves as both a contact<br />
platform and catalyst for advancing the aims<br />
of the growing bioplastics industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF.<br />
The dicarboxylic acid can be used to make →<br />
PEF = polyethylene furanoate, a polyester that<br />
could be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g.<br />
the transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 47
Basics<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain or<br />
consist of such GMOs, or are produced from<br />
GMOs, are called genetically modified (GM)<br />
food or feed [1]. If GM crops are used in bioplastics<br />
production, the multiple-stage processing<br />
and the high heat used to create the<br />
polymer removes all traces of genetic material.<br />
This means that the final bioplastics product<br />
contains no genetic traces. The resulting<br />
bioplastics is therefore well suited to use in<br />
food packaging as it contains no genetically<br />
modified material and cannot interact with<br />
the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different<br />
industries such as bioplastics, packaging,<br />
pharmaceuticals, adhesives and chemicals.<br />
One of the most promising routes is 2,5<br />
furandicarboxylic acid (FDCA), produced as an<br />
intermediate when 5-HMF is oxidised. FDCA<br />
is used to produce PEF, which can substitute<br />
terephthalic acid in polyester, especially polyethylene<br />
terephthalate (PET). [bM 03/14, 02/16]<br />
Home composting | →composting [bM <strong>06</strong>/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
Industrial composting | is an established<br />
process with commonly agreed upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised<br />
products to be used in agriculture. The<br />
criteria for industrial compostability of packaging<br />
have been defined in the EN 13432. Materials<br />
and products complying with this standard<br />
can be certified and subsequently labelled<br />
accordingly [1,7] [bM <strong>06</strong>/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.01 percent of the<br />
global agricultural area of 5 billion hectares.<br />
It is not yet foreseeable to what extent an increased<br />
use of food residues, non-food crops<br />
or cellulosic biomass (see also →1 st /2 nd /3 rd<br />
generation feedstock) in bioplastics production<br />
might lead to an even further reduced<br />
land use in the future [bM 04/09, 01/14]<br />
LCA | is the compilation and evaluation of the<br />
input, output and the potential environmental<br />
impact of a product system throughout its life<br />
cycle [17]. It is sometimes also referred to as<br />
life cycle analysis, ecobalance or cradle-tograve<br />
analysis. [bM 01/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine<br />
debris originates from a variety of sources.<br />
Shipping and fishing activities are the predominant<br />
sea-based, ineffectively managed<br />
landfills as well as public littering the main<br />
land-based sources. Marine litter can pose a<br />
threat to living organisms, especially due to<br />
ingestion or entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, a number of standardisation<br />
projects are in progress at ISO and ASTM<br />
level. Furthermore, the European project<br />
OPEN BIO addresses the marine biodegradation<br />
of biobased products.[bM 02/16]<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the<br />
system cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input<br />
of biomass in a huge and complex chemical<br />
plant, then mathematically allocating this<br />
biomass input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed [bM 04/14, 05/14, 01/15]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade!<br />
The underlying technology of oxo-degradability<br />
or oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard<br />
resins, are purported to accelerate the fragmentation<br />
of products made thereof. Oxodegradable<br />
or oxo-fragmentable materials do<br />
not meet accepted industry standards on compostability<br />
such as EN 13432. [bM 01/09, 05/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM <strong>06</strong>/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based and not degradable, used<br />
for e.g. baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol) [bM 05/10]<br />
PEF | polyethylene furanoate, a polyester<br />
made from monoethylene glycol (MEG) and<br />
→FDCA (2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It<br />
can be a 100% biobased alternative for PET.<br />
PEF also has improved product characteristics,<br />
such as better structural strength and<br />
improved barrier behaviour, which will allow<br />
for the use of PEF bottles in additional applications.<br />
[bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The<br />
polyester is made from monoethylene glycol<br />
(MEG), that can be renewably sourced from<br />
bio-ethanol (sugar cane) and (until now fossil)<br />
terephthalic acid [bM 04/14]<br />
PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />
thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has been<br />
introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the<br />
polyhydroxy fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals,<br />
including humans, that hold energy reserves<br />
in the form of body fat there are also bacteria<br />
that hold intracellular reserves in for of<br />
of polyhydroxy alkanoates. Here the microorganisms<br />
store a particularly high level of<br />
48 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Basics<br />
energy reserves (up to 80% of their own body<br />
weight) for when their sources of nutrition become<br />
scarce. By farming this type of bacteria,<br />
and feeding them on sugar or starch (mostly<br />
from maize), or at times on plant oils or other<br />
nutrients rich in carbonates, it is possible to<br />
obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending<br />
on the bacteria and their food, PHAs with<br />
different mechanical properties, from rubbery<br />
soft trough stiff and hard as ABS, can be produced.<br />
Some PHSs are even biodegradable in<br />
soil or in a marine environment<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e. as<br />
laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid.<br />
Modified PLA types can be produced by the<br />
use of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for<br />
use at higher temperatures [13] [bM 01/09, 01/12]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is similarly to PET<br />
produced using terephthalic acid or dimethyl<br />
terephthalate and a diol. In this case it is a<br />
biobased 1,3 propanediol, also known as bio-<br />
PDO [bM 01/13]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed,<br />
but as raw material for industrial products<br />
or to generate energy. The use of renewable<br />
resources by industry saves fossil resources<br />
and reduces the amount of → greenhouse gas<br />
emissions. Biobased plastics are predominantly<br />
made of annual crops such as corn,<br />
cereals and sugar beets or perennial cultures<br />
such as cassava and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resource<br />
efficient economy creates more output<br />
or value with lesser input.<br />
Seedling Logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → Vinçotte. Bioplastics<br />
products carrying the Seedling fulfil the<br />
criteria laid down in the EN 13432 regarding<br />
industrial compostability. [bM 01/<strong>06</strong>, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM 05/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the<br />
hydrophilic character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister<br />
G. H. Brundtland. The Brundtland Commission<br />
defined sustainable development as<br />
development that ‘meets the needs of the<br />
present without compromising the ability of<br />
future generations to meet their own needs.’<br />
Sustainability relates to the continuity of economic,<br />
social, institutional and environmental<br />
aspects of human society, as well as the nonhuman<br />
environment).<br />
Sustainable sourcing | of renewable feedstock<br />
for biobased plastics is a prerequisite<br />
for more sustainable products. Impacts such<br />
as the deforestation of protected habitats<br />
or social and environmental damage arising<br />
from poor agricultural practices must<br />
be avoided. Corresponding certification<br />
schemes, such as ISCC PLUS, WLC or Bon-<br />
Sucro, are an appropriate tool to ensure the<br />
sustainable sourcing of biomass for all applications<br />
around the globe.<br />
Sustainability | as defined by European Bioplastics,<br />
has three dimensions: economic, social<br />
and environmental. This has been known<br />
as “the triple bottom line of sustainability”.<br />
This means that sustainable development involves<br />
the simultaneous pursuit of economic<br />
prosperity, environmental protection and social<br />
equity. In other words, businesses have<br />
to expand their responsibility to include these<br />
environmental and social dimensions. Sustainability<br />
is about making products useful to<br />
markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
Vinçotte | independant certifying organisation<br />
for the assessment on the conformity of bioplastics<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2012<br />
[2] ISO 14<strong>06</strong>7. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2010<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2011<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2012<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14<strong>06</strong>4 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 20<strong>06</strong><br />
[10] Terrachoice, 2010, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2012<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 2005<br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> <strong>06</strong>/2009<br />
[15] ISO 14<strong>06</strong>7 onb Corbon Footprint of<br />
Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 49
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 2716865<br />
Mob: +86 1869940<strong>06</strong>76<br />
maxirong@lanshantunhe.com<br />
http://www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 51<strong>06</strong>63<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
39 mm<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41<strong>06</strong>6 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Sample Charge:<br />
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Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-9995<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
Gianeco S.r.l.<br />
Via Magenta 57 10128 Torino - Italy<br />
Tel.+390119370420<br />
info@gianeco.com<br />
www.gianeco.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-018 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 519<strong>06</strong>21<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.comEurope<br />
contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh<strong>06</strong>12@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
1.2 compounds<br />
Cardia Bioplastics<br />
Suite 6, 205-211 Forster Rd<br />
Mt. Waverley, VIC, 3149 Australia<br />
Tel. +61 3 85666800<br />
info@cardiabioplastics.com<br />
www.cardiabioplastics.com<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36<strong>06</strong>5 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Green Dot Bioplastics<br />
226 Broadway | PO Box #142<br />
Cottonwood Falls, KS 66845, USA<br />
Tel.: +1 620-273-8919<br />
info@greendotholdings.com<br />
www.greendotpure.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
50 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
Suppliers Guide<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7<strong>06</strong>2/97687-0<br />
www.tecnaro.de<br />
1.3 PLA<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TIPA-Corp. Ltd<br />
Hanagar 3 Hod<br />
Hasharon 45013<strong>06</strong>, ISRAEL<br />
P.O BOX 7132<br />
Tel: +972-9-779-6000<br />
Fax: +972 -9-7715828<br />
www.tipa-corp.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
Total Corbion PLA bv<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
Fax.: +31 183 695 604<br />
www.total-corbion.com<br />
pla@total-corbion.com<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 masterbatches<br />
4. Bioplastics products<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
1.4 starch-based bioplastics<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Bio4Pack GmbH<br />
D-48419 Rheine, Germany<br />
Tel.: +49 (0) 5975 955 94 57<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
6.2 Laboratory Equipment<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Albrecht Dinkelaker<br />
Polymer and Product Development<br />
Blumenweg 2<br />
79669 Zell im Wiesental, Germany<br />
Tel.:+49 (0) 7625 91 84 58<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
2. Additives/Secondary raw materials<br />
BeoPlast Besgen GmbH<br />
Bioplastics injection moulding<br />
Industriestraße 64<br />
D-40764 Langenfeld, Germany<br />
Tel. +49 2173 84840-0<br />
info@beoplast.de<br />
www.beoplast.de<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
7. Plant engineering<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 30351, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
1.5 PHA<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 films<br />
INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />
45, 0,90, 0<br />
10, 0, 80,0<br />
(ICBP) C, M, Y, KSDN BHD<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
0, 0, 0, 0<br />
12, Jalan i-Park SAC 3<br />
Senai Airport City<br />
81400 Senai, Johor, Malaysia<br />
Tel. +60 7 5959 159<br />
marketing@icbp.com.my<br />
www.icbp.com.my<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Infiana Germany GmbH & Co. KG<br />
Zweibrückenstraße 15-25<br />
91301 Forchheim<br />
Tel. +49-9191 81-0<br />
Fax +49-9191 81-212<br />
www.infiana.com<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, COO<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima.com<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31, CH-7013 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 51
Suppliers Guide<br />
9. Services<br />
‘Basics‘ book<br />
on bioplastics<br />
110 pages full<br />
color, paperback<br />
ISBN 978-3-<br />
9814981-1-0:<br />
Bioplastics<br />
ISBN 978-3-<br />
9814981-2-7:<br />
Biokunststoffe<br />
2. überarbeitete<br />
Auflage<br />
This book, created and published by Polymedia<br />
Publisher, maker of bioplastics MAGAZINE<br />
is available in English and German language<br />
(German now in the second, revised edition).<br />
The book is intended to offer a rapid and uncomplicated<br />
introduction into the subject of bioplastics, and is aimed at all<br />
interested readers, in particular those who have not yet had<br />
the opportunity to dig deeply into the subject, such as students<br />
or those just joining this industry, and lay readers. It gives<br />
an introduction to plastics and bioplastics, explains which<br />
renewable resources can be used to produce bioplastics,<br />
what types of bioplastic exist, and which ones are already on<br />
the market. Further aspects, such as market development,<br />
the agricultural land required, and waste disposal, are also<br />
examined.<br />
An extensive index allows the reader to find specific aspects<br />
quickly, and is complemented by a comprehensive literature<br />
list and a guide to sources of additional information on the<br />
Internet.<br />
The author Michael Thielen is editor and publisher<br />
bioplastics MAGAZINE. He is a qualified machinery design<br />
engineer with a degree in plastics technology from the RWTH<br />
University in Aachen. He has written several books on the<br />
subject of blow-moulding technology and disseminated his<br />
knowledge of plastics in numerous presentations, seminars,<br />
guest lectures and teaching assignments.<br />
Order now for € 18.65 or US-$ 25.00<br />
(+ VAT where applicable, plus shipping and handling,<br />
ask for details) order at www.bioplasticsmagazine.de/<br />
books, by phone +49 2161 6884463 or by e-mail<br />
books@bioplasticsmagazine.com<br />
Or subscribe and get it as a free gift<br />
(see page 53 for details, outside Germany only)<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
9. Services (continued)<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
10.3 Other Institutions<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
52 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13
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04.12.<strong>2018</strong> - 05.12.<strong>2018</strong> - Berlin, Germany<br />
www.european-bioplastics.org/events/eubp-conference/<br />
22.04.<strong>2018</strong> - Geleen, Niederlande<br />
European Biopolymer Summit 2019<br />
13.02.2019 - 14.02.2019 - Ghent, Belgium<br />
http://www.wplgroup.com/aci/event/biopolymer-conference-europe/<br />
13th Bioplastics Market<br />
12.03.2019 - 13.03.2019 - Bangkok, Thailand<br />
www.cmtevents.com/main.aspx?ev=190310&pu=276943<br />
7th Conference on Carbon Dioxide as Feedstock for<br />
Fuels, Chemistry and Polymers<br />
20.03.2019 - 21.03.2019 - Cologne, Germany<br />
http://co2-chemistry.eu<br />
bio!TOY: biobased materials for toy applications<br />
27.-28.05.2019 - Nürnberg, Germany<br />
www.bio-toy.info<br />
ISSN 1862-5258<br />
Amir bin Abul Hasan Ashari<br />
Managing Director, ICBP<br />
Compostable<br />
sanitary napkin<br />
project wins<br />
13th Global<br />
Bioplastics Award<br />
| 10<br />
Chinaplas 2019<br />
21.05.2019 - 24.05.2019 - Guangzhou, China<br />
http://adsale.hk/1935-CPS19_Bioplastics_EN_500x150<br />
bio!PAC: Conference on biobased packaging<br />
28.-29.05.2019 - Düsseldorf, Germany<br />
www.bio-pac.info<br />
bioplastics MAGAZINE Vol. 13<br />
Highlights<br />
Fibres, Textiles | 24<br />
Elastomers | 38<br />
Basics<br />
Industrial Composting | 43<br />
bioplastics MAGAZINE Vol. 13<br />
Highlights<br />
Bioplastics from waste streams | 20<br />
Films, flexibles, bags | 12<br />
Plastics beyond Petroleum - BioMass & Recycling<br />
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bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 53
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Aakar Innovations 10<br />
Adidas 23<br />
Adsale 40<br />
Agrana Starch Bioplastics 50<br />
Algix 22<br />
AlgoteK 23<br />
Altra Running 23<br />
API 50<br />
BASF 13, 14 50<br />
BeoPlast Besgen 51<br />
Berry Global 27<br />
Billabong 23<br />
Bio4Pack 8 51<br />
BioBlo 11<br />
Bio-Fed Branch of Akro-Plastic 5, 50<br />
Biome Bioplastic 9<br />
Bio-On 6 51<br />
Bioseries 11<br />
Biota 23<br />
Biotec 51<br />
Bloom 23<br />
BOGS 23<br />
BPI 52<br />
Braskem 5, 11, 13, 45 17<br />
Buss 37, 51<br />
Caprowachs, Albrecht Dinkelaker 51<br />
Cardia Bioplastics 50<br />
Centexbel 28<br />
Chinaplas 40<br />
Chippewah 23<br />
Clariant 8<br />
Clark's 23<br />
D.S. Fibres 28<br />
Danimer Scientific 27<br />
Danone 41<br />
DVSI 11<br />
DIN Certco 31<br />
Dr. Heinz Gupta Verlag 25<br />
DuPont 6<br />
EcoAlf 23<br />
Eindhoven Univ. of Tech. 29<br />
eKoala 11<br />
Electrolux 34<br />
Erema 7, 51<br />
European Bioplastics 8, 9, 22, 40 48<br />
European Bioplastics 7, 10, 13 52<br />
Fachagentur Nachwachsende Rohstoffe 18<br />
FKuR 11, 13 2, 50<br />
Fraunhofer UMSICHT 52<br />
Futamura 12<br />
Gen3Bio 22<br />
Gianeco 50<br />
Global Biopolymers 50<br />
GRABIO Greentech Corporation 51<br />
Grafe 50, 51<br />
Green Dot Bioplastics 50<br />
Green Serendipity 13 52<br />
Heijmans 24<br />
Hokkaido Univ. 29<br />
Indochine Bio Plastiques 51<br />
Industrial Facility 38<br />
Infiana Germany 51<br />
Inst. f. Bioplastics & Biocomposites 42 52<br />
Institut f. Kunststofftechnik, Stuttgart 52<br />
Johnson-Bryce 27<br />
Joma 9<br />
Kaneka 51<br />
Kingfa 50<br />
Knoten Weimar 18<br />
Lego 11<br />
Mars 25<br />
Michigan State University 52<br />
Microtec 50<br />
Minima Technology 51<br />
Nafigate 20, 36<br />
narocon InnovationConsulting 11, 13 52<br />
Natureplast-Biopolynov 50<br />
NatureWorks 26, 34<br />
Natur-Tec 51<br />
Neste 8<br />
NNFCC 9<br />
nova-Institute 11, 32 16, 32, 51<br />
Novamont 5, 13 51, 56<br />
Nurel 50<br />
Omega Material Science 22<br />
Omya 26<br />
Pace 32<br />
PepsiCo 27<br />
plasticker 6<br />
polymediaconsult 52<br />
PTT MCC Biochem 50<br />
Red Wings 23<br />
Rodenburg 24<br />
Saida 51<br />
Sintex 28<br />
Slater Design 23<br />
Soala 23<br />
Sukano 41, 50<br />
Surftec 23<br />
Sustainable Packaging Coalition 27<br />
Symphony Environmental 9<br />
Tecnaro 11 51<br />
TenTree 23<br />
The National Algae Association 22<br />
thyssenkrupp 8<br />
TianAn Biopolymer 51<br />
TIPA 51<br />
Tom's 23<br />
Total Corbion PLA 51<br />
TU Chemnitz 18<br />
TUI Cruises 39<br />
TÜV Austria 31<br />
Two Farmers 38<br />
Uhde-Inventa Fischer 8 35, 51<br />
Unilever 6<br />
Univ. Stuttgart (IKT) 52<br />
Vovobarefoot 23, 36<br />
Wageningen ATO 24<br />
Wästberg 38<br />
Wessanen 37<br />
Xinjiang Blue Ridge Tunhe Polyester 50<br />
Yünsa 28<br />
Zeijiang Hisun Biomaterials 21, 51<br />
Zhejiang Hangzhou Xinfu 50<br />
<strong>Issue</strong><br />
Editorial Planner<br />
Month<br />
Publ.<br />
Date<br />
edit/ad/<br />
Deadline<br />
2019<br />
Edit. Focus 1 Edit. Focus 2 Basics<br />
01/2019 Jan/Feb 04 Feb 19 23 Dez 18 Automotive Foams Green public procurement<br />
(update)<br />
Trade-Fair<br />
Specials<br />
Subject to changes<br />
02/2019 Mar/Apr 08 Apr 19 08 Mrz 19 Thermoforming /<br />
Rigid Packaging<br />
Building &<br />
construction<br />
Bioplastics in packaging<br />
(update)<br />
Chinaplas Preview<br />
03/2019 May/Jun 03 Jun 19 03 May 19 Injection moulding Toys Microplastics Chinaplas Review<br />
04/2019 Jul/Aug 05 Aug 19 05 Jul 19 Blow Moulding Biocomposites incl.<br />
thermoset<br />
Home composting<br />
05/2019 Sep/Oct 07 Oct 19 <strong>06</strong> Sep 19 Fiber / Textile /<br />
Nonwoven<br />
Barrier materials<br />
Land use for bioplastics<br />
(update)<br />
K‘2019 Preview<br />
<strong>06</strong>/2019 Nov/Dec 02 Dez 19 01 Nov 19 Films/Flexibles/<br />
Bags<br />
Consumer & office<br />
electronics<br />
Multilayer films<br />
K‘2019 Review<br />
54 bioplastics MAGAZINE [05/18] Vol. 13
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COME TO VISIT US AT<br />
4 • 5 december <strong>2018</strong><br />
TITANIC CHAUSSEE HOTEL BERLIN<br />
EcoComunicazione.it<br />
r4_11.<strong>2018</strong>