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ISSN 1862-5258<br />

Nov / Dec<br />

<strong>06</strong> | <strong>2018</strong><br />

Compostable<br />

sanitary napkin<br />

project wins<br />

13th Global<br />

Bioplastics Award<br />

| 10<br />

bioplastics MAGAZINE Vol. 13<br />

Highlights<br />

Bioplastics from waste streams | 20<br />

Films, flexibles, bags | 12<br />

... is read in 92 countries


BIO-FLEX ®<br />

AS VERSATILE AS YOUR REQUIREMENTS<br />

Biobased up to 85 %<br />

Certifi ed home compostable<br />

Certifi ed industrial compostable<br />

Heat resistant<br />

Food contact approved<br />

Easy processable on existing equipment


Editorial<br />

dear<br />

readers<br />

As you read these lines, the 13 th European Bioplastics Conference in Berlin is over<br />

or – for some of you – still going on. And as always, we are grateful to European<br />

Bioplastics for giving us the opportunity to present the Annual Global Bioplastics<br />

Award at this prestigious event. For those of you who missed it, turn to page 10,<br />

where we present this year’s winner. We had already reported about the project<br />

earlier this year, and it so happened that the development was anonymously<br />

proposed for the award – and won.<br />

Films, Flexibles, Bags is traditionally the first highlight topic of every December<br />

issue of bioplastics MAGAZINE. And the other this year is Bioplastics made from<br />

waste streams.<br />

It is also interesting to see that in the aftermath of our 1 st PHA platform World<br />

Congress , the response continues. A group of four experts have now come<br />

together to found GO!PHA - the Global Organization for PHA - a global initiative to<br />

accelerate the development of the PHA-platform industry.<br />

As always, we’ve rounded up some of the most recent news items on materials<br />

and applications to keep you abreast of the latest innovations and ongoing<br />

advances in the world of bioplastics.<br />

Lastly, I’d like to remind you of the 3 rd bio!PAC conference on biobased<br />

packaging in Düsseldorf next May – the call for papers is still open. If you have<br />

an interesting topic to report on, please let us know. The same goes for the<br />

first international bio!TOY conference. At the end of March, we are going to bring<br />

together raw material suppliers and toy manufacturers in Nürnberg, Germany, the Toy<br />

City. See pages 11 and 13 for details.<br />

Let me take this opportunity to wish you all a relaxing time over the holidays as this<br />

year comes to an end. Together with you, our readers, we look forward with confidence<br />

to a new year of challenges, innovations - and events. On our calendar, we’ve already<br />

marked down Chinaplas, taking place next year at a new location in Guangzhou and<br />

of course the K’show in Düsseldorf in October and a host of other events. We’ll be<br />

covering as many of these events as possible - and we hope to see you there, too.<br />

Until then, please enjoy reading bioplastics MAGAZINE.<br />

bioplastics MAGAZINE Vol. 13<br />

ISSN 1862-5258<br />

Compostable<br />

sanitary napkin<br />

project wins<br />

13th Global<br />

Bioplastics Award<br />

| 10<br />

Highlights<br />

Bioplastics from waste streams | 20<br />

Films, flexibles, bags | 12<br />

Nov / Dec<br />

<strong>06</strong> | <strong>2018</strong><br />

... is read in 92 countries<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Michael Thielen<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 3


Content<br />

Imprint<br />

Nov / Dec <strong>06</strong>|<strong>2018</strong><br />

3 Editorial<br />

5 News<br />

10 Events<br />

36 Application News<br />

41 Brand Owner<br />

45 10 years ago<br />

46 Basics<br />

50 Suppliers Guide<br />

53 Event Calendar<br />

54 Companies in this issue<br />

Bioplastics Award<br />

10 And the winner is..<br />

Films/Flexibles/Bags<br />

12 What’s new for cellulose based films<br />

14 That’s not my bag<br />

From Science & Research<br />

18 PLA in the post-consumer-recycling stream<br />

28 Improved biobased fibres for clothing applications<br />

29 New method for high yield FDCS production<br />

30 Compostable plastics behaviour<br />

42 Land use<br />

Report<br />

32 Go!PHA<br />

39 Tui-Cruises<br />

Bioplastics from waste streams<br />

20 Waste cooking oil as source for PHA<br />

22 Is Algae a sustainable feedstock<br />

24 Valorizing side stream<br />

Materials<br />

26 Calcium Carbonate opens new<br />

opportunities for the use of PLA<br />

Applications<br />

34 PLA in the fridge<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41<strong>06</strong>6 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

sb@bioplasticsmagazine.com<br />

Michael Thielen (English Language)<br />

(see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3.400 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(169 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not<br />

necessarily reflect those of Polymedia<br />

Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped sponsored bioplastic<br />

envelopes<br />

Cover<br />

Aakar Innovations<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

Novamont opened new<br />

Origo-Bi production site<br />

News<br />

The official inauguration of Mater-Biopolymer, Novamont’s newly refurbished<br />

site for the production of its biodegradable biopolyester Origo-Bi, took place on<br />

19 October, in Patrica, Italy.<br />

At the end of the preceding "The Regeneration continues" conference, the guests,<br />

including representatives of institutions, local administrations, universities and<br />

research and industrial partners of the Group, were given a tour of the plant to have<br />

an opportunity to take a closer look at the production process.<br />

In line with Novamont’s strategy of revitalizing sites that have become old and<br />

obsolete, the new Mater-Biopolymer has been converted from a former PET<br />

production plant into a modern facility for the production of biopolyesters based<br />

on renewable raw materials, using a more sustainable and low-emission process.<br />

The highly efficient plant is equipped with a complex system of utilities to minimize<br />

costs and waste through the recovery and enhancement of waste. In 2016, the site<br />

started the construction of a waste water distillation section from the process that<br />

made it possible to recover the tetrahydrofuran (THF) that is generated during the<br />

polymerization reaction, which, once distilled, is destined for the chemical and<br />

pharmaceutical industries, among other things. MT<br />

www.novamont.com<br />

Think Sustainable<br />

M·VERA ®<br />

Bioplastics<br />

With our M·VERA® range of<br />

biobased and biodegradable<br />

plastics (certified according<br />

to EN 13432), we provide you<br />

with customised solutions<br />

for your application:<br />

• Film<br />

Such as shopping bags,<br />

fruit and vegetable bags<br />

or agricultural films<br />

• Injection Moulding<br />

Such as packaging, coffee<br />

capsules, cutlery and others<br />

• Color, Carbon Black and<br />

Additive Masterbatches<br />

Our team of highly experienced<br />

plastic specialists is pleased to<br />

help you – contact us!<br />

Braskem joins Europe’s Bio-based<br />

Industries Consortium (BIC)<br />

Chemicals company Braskem announces it has joined European network Biobased<br />

Industries Consortium (BIC) as a full member.<br />

BIC represents the private sector in the Bio-based Industries Joint Undertaking<br />

(BBI JU), a public-private partnership (PPP) with the EU worth €3.7 billion. By<br />

joining BIC, Braskem has become part of a wider network committed to bringing<br />

bio-based products to market.<br />

Established as a pillar of the European Commission Bioeconomy Strategy, BBI JU<br />

operates under EU research and innovation programme Horizon 2020. It supports<br />

the development and production of bio-based products in Europe via biorefining<br />

research and demonstration projects, including large-scale commercialisation,<br />

through investment in innovative manufacturing facilities and processes. MT<br />

www.braskem.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne · Nattermannallee 1<br />

50829 Cologne · Germany<br />

Phone: +49 221 88 8894-00<br />

Fax: +49 221 88 88 94-99<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Unilever and Bio-on work together<br />

Unilever (headquartered in Rotterdam, The Netherlands)<br />

and Bio-on (Bologna, Italy) recently announced the start of a<br />

strategic partnership to develop, produce and sell personal<br />

hygiene and care products that guarantee a smaller or no<br />

environmental impact. Using patented bio-technologies<br />

for natural, biodegradable microplastics (PHA) production,<br />

Unilever and Bio-on are taking an important step towards<br />

building a more sustainable economy and more responsible<br />

consumption in the personal care sector.<br />

This collaboration is designed to meet the demands<br />

of consumers, who are increasingly concerned about<br />

sustainability and making purchasing choices that respect<br />

the environment, whilst making the most of the skills and<br />

excellence at both companies.<br />

Unilever's knowledge and large-scale presence on the<br />

personal care market with noted brands such as Mentadent,<br />

Dove, Zendium, Glysolid, and Sunsilk, teams up with the<br />

exclusive know-how of Bio-on, specialised in biotechnologies<br />

applied to widely used materials, to create completely natural<br />

products and solutions.<br />

"For Unilever, developing a partnership with such an<br />

excellent Italian company as Bio-on is an important step<br />

towards the goals we have set ourselves with the Unilever<br />

Sustainable Living Plan, primarily to halve the environmental<br />

impact of our products by 2030," claims Fulvio Guarneri,<br />

Chairman & CEO of Unilever Italia. "This collaboration<br />

makes us very proud because it is one of the most important<br />

examples through which Unilever is making concrete moves<br />

towards sustainability in our business strategy."<br />

"Research into innovative products and cutting-edge<br />

formulations that respect the environment and people is<br />

now a priority in the personal care sector," explains Marco<br />

Astorri, Chairman and CEO of Bio-on. "We are very pleased<br />

to work alongside such a major player as Unilever, with<br />

which we will have the great opportunity to introduce real<br />

sustainable innovation whilst reaching an increasingly broad<br />

consumer base." Bio-on will work with Unilever through two<br />

new companies, which will focus 100% on exploiting exclusive<br />

technologies to develop, produce and supply personal care<br />

products. MT<br />

www.bio-on.it | www.unilever.it<br />

Dupont completes expansion of Sorona production<br />

DuPont Industrial Biosciences has completed the expansion<br />

of their Kinston, NC manufacturing facility, which produces<br />

bio-based, high-performance DuPont Sorona ® polymers<br />

From the expansion, DuPont has increased the facility’s<br />

capacity to produce Sorona polymer by 25%. This investment<br />

is reflective of the growing demand for Sorona polymer<br />

throughout the carpet and apparel markets and an emerging<br />

global focus on building the circular economy.<br />

“This expansion is a direct result of the significant growth<br />

in global demand for Sorona polymer and a testament to<br />

DuPont’s commitment to manufacturing innovative products in<br />

North Carolina,” says Michael Saltzberg, Ph.D., global business<br />

director of DuPont Biomaterials. “We are grateful for the support<br />

from partners that made this project possible including: Lenoir<br />

County Economic Development, North Carolina Community<br />

College System, Lenoir Community College, Duke Energy<br />

Corporation, North Carolina Department of Commerce and<br />

North Carolina Department of Transportation.”<br />

DuPont Sorona polymer is made from 37 % renewable<br />

plant-based ingredients and has many versatile applications.<br />

As compared to similar materials, like nylon 6, Sorona<br />

polymer uses 30 % less energy and releases 63 % fewer<br />

greenhouse gas emissions. In addition to reducing its reliance<br />

on fossil fuels, Sorona polymer combines eco-efficiency with<br />

function, as its high-performance qualities can be used in<br />

a variety of applications. Fibers made with Sorona polymer<br />

exhibit exceptional softness, inherent stain resistance and<br />

uncompromising durability, offering a sustainable, highperforming<br />

material option for customers throughout the<br />

supply chain.<br />

DuPont Industrial Biosciences employs more than 90<br />

workers in Kinston through the manufacturing of Sorona<br />

polymer. With the startup of the line, four additional employees<br />

also are being recruited. MT<br />

tinyurl.com/sorona<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

6 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

EU Parliament's single-use plastics ban -<br />

Bioplastics can provide an alternative, EUBP says<br />

The European Parliament recently approved its report on the draft Directive on Marine Pollution and Single-use Plastics.<br />

“European Bioplastics fully supports the transition from a linear to a circular economy. Bioplastics enable more sustainable<br />

solutions for a range of products“, says François de Bie, Chairman of European Bioplastics (EUBP).“We agree on the importance<br />

of reducing single-use plastic products where feasible, but hygiene and food safety cannot be compromised. With regard to<br />

some of the concerned single-use products – such as e.g. plates and cutlery –, biodegradable certified compostable plastics<br />

provide an organically recyclable alternative“.<br />

EUBP considers the Parliament’s decision to restrict the use of single-use cutlery and plates as not sufficiently considering<br />

the reality of food consumption in Europe. In certain closed-loop contexts, such as canteens, air travel, or sport and music<br />

events, these are an indispensable and efficient solution to guarantee safety and hygiene for food and drinks while ensuring at<br />

the same time waste collection and recycling.<br />

Biodegradable certified compostable plastics fulfil Europe’s rigorous requirements and standards for health and safety and<br />

can be recycled organically together with the food waste.<br />

EUBP fully supports the Parliament’s suggestion to restrict products made from oxo-degradable plastics, which is in line<br />

with earlier statements by the Parliament and the European Commission in the context of the EU Plastics Strategy.<br />

Concerning biodegradability in the marine environment, EUBP stresses that it is an interesting property. However, it needs<br />

to be clearly defined for which materials, products and under which circumstances this property is of added value. Improving<br />

waste management on land and building efficient mechanical and organic recycling infrastructures across Europe remain a<br />

priority when it comes to fighting marine pollution.<br />

EUBP looks forward to further constructive discussions with the European Commission, the Parliament, and the Council<br />

during the upcoming trilogues in order to realise a truly sustainable, no-litter, circular economy for Europe. MT<br />

www.european-bioplastics.org<br />

HIGH WE DRIVE THROUGHPUT. THE<br />

DIAMEETS CIRCULAR ECONOMY. QUALITY.<br />

Whether it is inhouse, postconsumer<br />

or bottle recycling:<br />

you can only close loops in a<br />

precise and profitable way if<br />

machines are perfectly tuned<br />

for the respective application.<br />

Count on the number 1<br />

technology from EREMA<br />

when doing so: over 5000<br />

of our machines and systems<br />

produce around 14 million<br />

tonnes of high-quality pellets<br />

like this every year –<br />

in a highly efficient and<br />

energy-saving way.<br />

That’s Careformance!<br />

CAREFORMANCE<br />

We care about your performance.<br />

1710013ERE_ins_bioplastics magazine.indd 1 bioplastics MAGAZINE 18.10.17 [<strong>06</strong>/18] Vol. 14:313 7


News<br />

thyssenkrupp commissions first commercial<br />

PLA plant for COFCO in China<br />

To reduce reliance on petroleum-based plastics,<br />

thyssenkrupp has developed a manufacturing process<br />

for the bioplastic PLA. The world’s first commercial plant<br />

based on the patented PLAneo ® technology recently started<br />

production in Changchun, China. It is operated by the Jilin<br />

COFCO Biomaterial Corporation, a subsidiary of COFCO,<br />

China’s largest food and beverage group. The new plant with<br />

an initial capacity of 10,000 tonnes, produces all standard PLA<br />

types, among other things for the production of eco-friendly<br />

packaging, fibers, textiles and engineering plastics.<br />

the technology, thyssenkrupp’s subsidiary Uhde Inventa-<br />

Fischer profited from decades of expertise gained from the<br />

construction of more than 400 polymerization plants and<br />

extensive experience in the scale-up of new technologies.<br />

For the new plant in Changchun thyssenkrupp provided<br />

the engineering, key plant components and supervision of<br />

construction and commissioning. MT<br />

www.thyssenkrupp-industrial-solutions.com<br />

Sami Pelkonen, CEO of the Electrolysis & Polymers<br />

Technologies business unit of thyssenkrupp Industrial<br />

Solutions: “The bioplastics market will continue to grow in the<br />

coming years, not least due to the increasing environmental<br />

awareness of industry, governments and consumers. With our<br />

PLAneo technology we want to do our bit to make the plastics<br />

sector more sustainable and resource-friendly. With it we<br />

enable our customers to produce high-quality bioplastics with<br />

a wide range of properties – at a price that is competitive with<br />

conventional plastics.”<br />

PLAneo technology converts lactic acid into PLA in a<br />

particularly efficient and resource friendly way. Another<br />

advantage is its transferability to large-scale plants with<br />

capacities of up to 100,000 tons per year. In developing<br />

Neste and Clariant will collaborate<br />

Neste, the world’s leading provider of sustainable renewable<br />

diesel and an expert in delivering drop-in renewable chemical<br />

solutions, and Clariant, a world leader in specialty chemicals,<br />

have signed an agreement to collaborate on the development<br />

of new sustainable material solutions targeted at a range of<br />

industries.<br />

In the first phase of the partnership, the companies will<br />

start replacing fossil-based ethylene and propylene used in<br />

Clariant’s top-quality hot-melt adhesives, with monomers<br />

derived from renewable feedstock. This is enabled by turning<br />

Neste’s renewable hydrocarbons – produced 100 % from<br />

renewable raw materials, such as waste and residue fats and<br />

oils as well as vegetable oils – into ethylene and propylene for<br />

Clariant’s products.<br />

In a later phase, the companies will also develop other<br />

sustainable additive solutions derived from renewable raw<br />

materials for plastics and coatings applications. This will<br />

enable the two companies to help various sustainabilityfocused<br />

brand owners – such as those producing furniture,<br />

sporting goods, hygiene products, electronics, and cars – to<br />

increase their bio-based offering while also reducing crude oil<br />

dependency and climate emissions.<br />

“We are proud to join forces with Clariant, one of the<br />

most innovative players in the specialty chemicals industry.<br />

Collaboration marks an essential step forward in Neste’s<br />

quest to become a preferred partner as a provider of<br />

sustainable chemicals solutions for forerunner brands”, says<br />

Peter Vanacker, President & CEO from Neste.<br />

“Combining Clariant’s in-depth knowhow in the varying<br />

applications of adhesives, plastics, and coatings, with Neste’s<br />

extensive knowledge and experience in working with biobased<br />

materials to produce a variety of drop-in renewable<br />

solutions, enables both companies to develop their sustainable<br />

material offering to provide maximum added value not only<br />

to sustainable brands in varying industries but also to their<br />

customers,” Vanacker adds.<br />

“For society, our environment, and future generations, it is<br />

our responsibility to improve sustainability performance and<br />

reduce our carbon footprint and dependency on crude oil. As<br />

a result of Clariant’s partnership with Neste, we can progress<br />

our goal to become a true sustainable solution provider in<br />

the additive market, offering our customers products and<br />

solutions that can make a positive contribution towards their<br />

targets and enhance end applications,” continues Gloria<br />

Glang, Vice President, Head of Global Advanced Surface<br />

Solutions Business at Clariant. MT<br />

www.neste.com | www.clariant.com<br />

8 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of the past two months.<br />

The story that got the most clicks from the visitors to<br />

bioplasticsmagazine.com was:<br />

re:thinking<br />

plastic<br />

UK judge finds the case for oxo-degradable plastic ‘compelling’<br />

(05 November <strong>2018</strong>)<br />

In a further twist of the oxy-degradable plastics saga, Symphony Environmental<br />

Technologies PLC today (5th November <strong>2018</strong>) heard the news that lawyer and<br />

former deputy Judge of the High Court in England, Peter Susman QC, has declared<br />

the scientific case for oxo-biodegradable technologies to be “clear and compelling”.<br />

A commentary by bioplastics MAGAZINE.<br />

Produced<br />

exclusively from<br />

pure plant-based,<br />

renewable<br />

resources!<br />

Biome Bioplastics'<br />

educational channel<br />

Biome Bioplastics, Southampton, UK, has launched a digital educational channel,<br />

#ThinkBioplastic. The platform aims to help government, media and the public<br />

better understand the complexities of plastics and plastic pollution and learn more<br />

about available alternatives.<br />

#ThinkBioplastic will share content about the whole plastic life cycle (production,<br />

use and disposal) and investigate the science behind recent plastic’s headlines.<br />

It will highlight the role of bioplastic in reducing the negative impact of polymer<br />

manufacture and disposal. All content will be in an easily digestible form.<br />

Biome Bioplastics CEO Paul Mines explains the motivation behind the channel:<br />

“The recent extensive coverage on plastic, while increasing awareness of the<br />

problem, has also increased people’s confusion about the existing solutions. We<br />

decided to take the matter into our own hands and form a necessary back-to-basic<br />

approach that puts the emphasis on science and fact. We hope to cut through some<br />

of the noise in this debate and empower people to make their own choices.”<br />

The channel has already received support from experts in the biobased industry.<br />

Professor Adrian Higson, Director at NNFCC, said the #ThinkBioplastic platform<br />

will help inform individuals about the ‘already available solutions’ to the plastic<br />

problem. He added: “In turn, this can shine a new light on the opportunity that<br />

biobased and biodegradable plastics represent, to shift towards a sustainable<br />

bioeconomy - a move that could eliminate dependency on fossil fuels.”<br />

#ThinkBioplastic will also be working with ambassadors, such as award-winning<br />

wildlife photographer Sue Flood, who has spent almost 30 years as a wildlife<br />

filmmaker and photographer, among others as a member of the team that produced<br />

the acclaimed Blue Planet and Planet Earth documentaries. MT<br />

www.thinkbioplastic.com<br />

Our premium range from<br />

renewable raw materials<br />

With Joma Nature® we offer a select<br />

range of our Spice Grinders and our<br />

Securibox® as an environmentally<br />

conscious alternative to conventional<br />

products – sustainable and CO 2-neutral.<br />

For our environment, we aim to<br />

protect our natural surroundings<br />

and secure a livable world for our<br />

children.<br />

www.jomapackaging.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 9


Award<br />

And the winner is ...<br />

The 13 th Global Bioplastics Award <strong>2018</strong> was<br />

given to Aakar Innovations for their biobased<br />

sanitary pads for girls and women in rural India<br />

Aakar Innovations Pvt. Ltd. from Belapur, Mumbai,<br />

India developed a fully compostable sanitary pad for<br />

girls and women in rural India. The pads are manufactured<br />

in local decentralized workshop locations by the local<br />

women of the region.<br />

Arunachalam Murugananphan is the social entrepreneur<br />

that made this all happen and received the innovation<br />

award from the President of India. Aakar Innovations<br />

follows in those pioneering footsteps and takes it a step<br />

further by introducing the element of environmental and<br />

social responsibility. Using biobased and fully compostable<br />

materials, Aakar is manufacturing sanitary pads using<br />

rural, low cost manufacturing and also providing jobs to<br />

women in rural villages.<br />

Aakar is a hybrid social enterprise that enables women<br />

to produce and distribute affordable, high-quality, 100 %<br />

compostable sanitary napkins within their communities<br />

while simultaneously raising awareness and sensitization<br />

of menstrual hygiene management. That’s why Aakar<br />

launched a 100 % compostable sanitary pad under the<br />

brand name Anandi.<br />

Anandi is a 100 % compostable sanitary napkin using<br />

biobased compostable polymer film. It uses virgin soft<br />

pine wood pulp containing more than 97 % of cellulose and<br />

hemi-cellulose. The wood pulp as used has pure cellulose<br />

materials with complete uniformity of fibers allowing it to<br />

decompose easily. Activated by an only eco-friendly ozone<br />

treatment process and using compostable bioplastic. The<br />

root sources of the material used is from naturally available<br />

corn starch.<br />

The judges were impressed with the holistic concept,<br />

addressing the social, economic and environmental<br />

elements at the same time. A perfect example of what<br />

sustainability is all about! It is tangible, helping millions<br />

of women in rural India, and shows how bioplastics can<br />

advance the cause of environmental and social justice in a<br />

responsible manner. All bioplastic components are certified<br />

compostable as per EN 13432 or ASTM D6400. A certification<br />

for soil degradability is being awaited and will complete a<br />

truly remarkable story of empowerment, social justice and<br />

environmental responsibility<br />

The prize was awarded to the winning company on<br />

December 4 th , <strong>2018</strong> during the 13 th European Bioplastics<br />

Conference in Berlin, Germany. MT<br />

www.aakarinnovations.com<br />

10 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Events<br />

bioplastics MAGAZINE presents a first of its kind:<br />

call for papers<br />

Conference on Biobased Materials in Toy Applications<br />

27 - 28 March 2019 - Nürnberg, Germany<br />

The biobased polymer supply chain meets the toy maker industry and trade.<br />

• More than 20 presentations with focus on suitable materials and user experiences<br />

• Background information on regulation / policy, and funding opportunities in EU<br />

• Table-top exhibition of business and technology leaders<br />

• Time and atmosphere supporting business development through dialog<br />

• Media and PR programme to spread the news<br />

• Supported by the German Toy Maker Association DVSI<br />

Driving innovation, sustainability and product safety to the next level.<br />

Explore new ways with biobased plastics.<br />

Confirmed speakers include:<br />

Lego, Bioseries, Bioblo, eKoala, Braskem, FKuR, Tecnaro, Hexpol TPE,<br />

nova-Institute and DVSI<br />

Call for Papers is still open. For updated information and opportunities on programme,<br />

exhibiting, sponsoring, etc. visit the website or contact mt@bioplasticsmagazine.com<br />

Gold Sponsor<br />

Silver Sponsor<br />

Coorganized by<br />

Innovation Consulting Harald Kaeb<br />

supported by<br />

Media Partner<br />

1 st Media Partner<br />

#bio-toy<br />

www.bio-toy.info


Films/Flexibles/Bags<br />

What’s new in<br />

cellulose based films<br />

When Futamura<br />

acquired its<br />

cellulose films<br />

business in 2016, including<br />

the trademark brands<br />

Cellophane and NatureFlex, the<br />

business was already braced for positive change,<br />

with early investment from owners Futamura, the cellulose<br />

films business based in Wigton (Cumbria, UK) and Tecumseh<br />

(Kansas, USA), strengthened its core production facilities<br />

and planned for strategic growth. Then who could have<br />

foreseen that the broadcast of one BBC nature documentary,<br />

Sir David Attenborough’s Blue Planet II, would put the<br />

metaphorical cat amongst the pigeons (or catfish amongst<br />

the shrimp?) turning this plastic world as we know it upside<br />

down and placing a spotlight on bio-material alternatives to<br />

single-use conventional plastics.<br />

Traditionally, renewable and compostable NatureFlex<br />

films are in popular with ethical companies wanting to do<br />

the right thing with their packaging, and increasingly from<br />

new business start-ups who want to get their sustainable<br />

packaging journey kicked off on the right foot, right through<br />

to retailers and large brand owners who are more and more<br />

considering bio-alternatives to conventional plastic films<br />

for main stream brands.<br />

NatureFlex is ideal for flexible applications packaging<br />

fresh produce, as well as dry products such as tea and<br />

coffee. However, there are great success stories when<br />

laminated to other bio-materials such as; The Curiosity<br />

Co. bacon, which has received much attention following<br />

the launch of the UK’s first so-called PLASTIC FREE ® aisle<br />

at the Thornton’s Budgens Bellsize park store in early<br />

November. In addition to bacon packs, NatureFlex was<br />

used by Budgen’s to replace cling film for wrapping their<br />

deli cheese, and could be found in numerous flexible packs<br />

in store ranging from the recently launched Two Farmer’s<br />

crisp range to Tea Pigs.<br />

The Plastic Free Trustmark, created by A Plastic Planet,<br />

states in its criteria that a flexible package must be certified<br />

to the EN13432 standard and / or TÜV Austria Home<br />

compost, making NatureFlex the ideal solution either<br />

on its own or laminated to other certified compostable<br />

biomaterials.<br />

Other applications using NatureFlex films include<br />

pouches, cereal liners, coffee capsules (lidding), and<br />

sachets for tea, coffee, herbs and spices and flow wraps for<br />

chocolate bars, overwrap for yeast, tea cartons and many<br />

more everyday items. MT<br />

www.futamuragroup.com<br />

12 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Automotive Events<br />

bioplastics MAGAZINE presents:<br />

bio PAC<br />

call for papers<br />

Conference on Biobased Packaging<br />

28 - 29 May 2019 - Düsseldorf, Germany<br />

Biobased packaging<br />

» can be recyclable and/or compostable<br />

» fits into the circular economy of the future<br />

» is made from renewable resources or waste streams<br />

» can offer environmental benefits in the end-of-life phase<br />

» can offer innovative features and beneficial barrier properties<br />

» can help to reduce the depletion of finite fossil resources and CO 2<br />

emissions<br />

That‘s why bioplastics MAGAZINE (in cooperation with Green Serendipity) is now<br />

organizing the third edition of<br />

bio PAC<br />

The 2 day-conference will be held on the<br />

28 th and 29 th of May 2019 in Düssseldorf, Germany<br />

Confirmed speakers include:<br />

BASF (Martin Bussmann), Ecoplaza (Steven Iijzerman),<br />

FKuR (Patrick Zimmermann), Novamont (Albertro Castellanza),<br />

Green Serendipity (Caroli Buitenhuis), Bio4pack (Patrick Gerritsen),<br />

Braskem (Marco Jansen), nova-Institute (Michael Carus),<br />

European Bioplastics, narocon (Harald Kaeb)<br />

Call for Papers is still open: Please send your proposal to mt@bioplasticsmagazine.com<br />

supported by<br />

Coorganized by<br />

Gold Sponsor<br />

1 st Media Partner<br />

Media Partner<br />

#bio-pac<br />

www.bio-pac.info


Films/Flexibles/Bags<br />

That’s not my bag –<br />

or is it?<br />

Certified compostable film applications with multiple benefits<br />

and different mechanical and thermal properties. The main<br />

application areas are films for organic waste bags, fruit<br />

and vegetable bags and dual-use bags (first for shopping,<br />

then for organic waste), multilayer packaging materials,<br />

and agricultural films. The certified compostable, partly<br />

biobased plastics are in no way inferior to conventional<br />

materials: they are just as effective and resistant, can be<br />

processed with conventional machinery, and are ideal for<br />

developing innovative solutions.<br />

ecovio F is suitable for producing compostable multilayer films<br />

with good barrier properties for packaging applications like coffee<br />

capsule pouches.<br />

Lightweight, tear-resistant and waterproof – thanks to<br />

their exceptional properties, plastic bags and films<br />

make our lives easier. But when it comes to biowaste<br />

collection, they can contribute to the formation of microplastic<br />

when disposed of together with organic waste. The<br />

EU commission estimates that the recycling rates for thin<br />

plastic bags will not rise above 10 % by 2020. For all applications<br />

that cannot be recycled mechnically, BASF offers the<br />

certified compostable plastic ecovio ® . It can be used to produce<br />

compostable blown films, thermoformable flat films<br />

or multilayer films, for applications as diverse as shopping<br />

bags, food packaging and agricultural films.<br />

Plastic bags and films help to keep food fresh, are a<br />

convenient way of carrying our shopping, and ensure<br />

that waste is disposed of hygienically. But when it comes<br />

to disposal, they cannot always be easily separated into<br />

their individual components for mechanical recycling.<br />

In addition, society is increasingly looking for alternative<br />

product solutions which are environmentally sustainable<br />

but are still just as convenient.<br />

With ecovio, which is made from the compostable and<br />

biodegradable BASF plastic ecoflex ® and polylactic acid<br />

(PLA), BASF developed in 20<strong>06</strong> a biodegradable plastic<br />

which is certified to EN13432 for industrial composting.<br />

Since then a broad range of different ecovio grades has been<br />

introduced into the market, with varying biobased contents<br />

Kitchen and food waste can be hygienically collected in<br />

organic waste bags made from ecovio F, then turned into<br />

compost in industrial composting facilities along with the<br />

bag. Thanks to its good resistance to moisture, liquid does<br />

not leak through, so there is no need to wash out the compost<br />

bin. Because of the material’s excellent tensile strength and<br />

hence load-carrying capacity ecovio F can also be employed<br />

to make shopping bags. They are strong enough to be<br />

reused several times before finally being used as organic<br />

waste bags. Bags and pouches made from ecovio can be<br />

both welded and printed, so they can be clearly labeled as<br />

compostable, for example.<br />

Fruit and vegetable bags made of ecovio are more than<br />

simple carrier bags, too. The blown films can be extruded in<br />

the range from 10 to 12µm. They can be reused as organic<br />

waste bags and thus improve the collection and recovery of<br />

organic food waste. The bags possess high tear and wear<br />

Fruit and vegetable bags made of ecovio possess high tear and<br />

wear stability, are approved for food contact and reduce food<br />

losses due to their good breathability.<br />

14 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Films/Flexibles/Bags<br />

By:<br />

Martin Bussmann, Jörg Auffermann, Dirk Stärke<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Conventional mulch films made of polyethylene (PE) have to<br />

be collected from the fields and recycled after harvesting.<br />

Because of earth and plant remnants sticking to the films<br />

recycling is more difficult or even impossible. Mulch films<br />

made of ecovio M2351 are completely and biologically<br />

degraded by microorganisms like bacteria and fungi that<br />

exist naturally in the soil. Farmers can simply plow the<br />

ecovio mulch films back into the ground along with the<br />

plant debris. This saves time and money.<br />

ecovio M2351 is a ready-to-use compound that can<br />

be processed into soil-biodegradable mulch films on<br />

conventional PE film extrusion lines without the need for<br />

any additional slip or anti-block agents. Because of the<br />

material’s excellent mechanical properties, down-gauging<br />

up to 12, 10 and 8 μm thickness is possible.<br />

Bags made from ecovio can be both welded and printed, so they<br />

can be clearly labeled as compostable, for example.<br />

After more than ten years’ product development, versatile<br />

film applications for different industry sectors can be made<br />

of certified compostable plastics like ecovio. They benefit<br />

from the optimum balance of easy processing, tailormade<br />

material properties and the promotion of a circular<br />

economy.<br />

www.ecovio.basf.com<br />

stability, are approved for food contact and reduce food losses<br />

due to the good breathability of the material. The ecovio bags<br />

also comply with the recent standards in France and Italy for<br />

compostable fruit and vegetable bags made of renewable<br />

resources. In France, for example, single-use plastic bags<br />

that are thinner than 50 µm have to consist of at least 40 %<br />

of renewable resources and be home-compostable. Thus<br />

bags made of ecovio support a safer, cleaner and easier<br />

food waste collection, closing the loop of the food value<br />

chain.<br />

ecovio F is also suitable for producing compostable<br />

multilayer films with good barrier properties for packaging<br />

applications. The bioplastic, which is approved for direct and<br />

indirect food contact, is used as the sealing layer. The other<br />

film layers are also made from compostable materials such<br />

as cellophane. In order to ensure that the entire packaging<br />

can be disposed of together with the food waste and given<br />

to industrial composting, a holistic approach is possible:<br />

so, for example, closures and vent valves can also be<br />

produced from ecovio. Recycling food waste in this way is<br />

more resource-friendly than incinerating it or sending it to<br />

landfill.<br />

Films are not only employed for bags and packaging,<br />

they also have applications in agriculture and horticulture.<br />

Here, mulch films are used to increase the yield, speed<br />

up harvesting as well as to save water and herbicides.<br />

Mulch films made of ecovio M2351 are completey and biologically<br />

degraded by microorganisms like bacteria and fungi that exist<br />

naturally in the soil.<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 15


IN THE CIRCULAR ECONOMY,<br />

NOTHING IS WASTED,<br />

EVERYTHING IS TRANSFORMED.<br />

We are moved by improving people’s lives through<br />

sustainable solutions in chemicals and plastics.<br />

HERE IS WHAT BRASKEM<br />

IS COMMITTED TO DOING TOGETHER:<br />

That is why the transition to a Circular Economy—<br />

where everything can be used and reused in a<br />

continuous cycle—moves us to action. And it<br />

starts with education on how we produce and how<br />

Optimize<br />

the design of plastic<br />

products with our<br />

clients and partners<br />

for more efficient<br />

recycling and reuse.<br />

Continue<br />

investing in the<br />

development of<br />

renewable-based<br />

plastic products.<br />

we consume in society.<br />

We know that plastic is essential for our quality<br />

of life, from providing agricultural productivity to<br />

ensuring food safety and hospital hygiene. We also<br />

Develop and<br />

support new<br />

technologies<br />

and methodologies<br />

for recycling.<br />

Promote<br />

conscious<br />

consumption<br />

and recycling<br />

programs.<br />

know that plastic should be used sustainably—<br />

either reused, recycled or reclaimed.<br />

Braskem believes in the strength of this movement<br />

and invites everyone to join us. Each one of us has<br />

a role to play.<br />

Get to know our positioning in full<br />

braskem.com/circulareconomy<br />

Expand<br />

the studies<br />

on Life Cycle<br />

Assessment and<br />

environmental<br />

and climate<br />

impacts<br />

of plastic.<br />

Support<br />

private,<br />

governmental<br />

and academic<br />

partnershipsaimed<br />

at understanding,<br />

preventing<br />

and solving<br />

the problem<br />

of marine<br />

waste.<br />

Support<br />

the measurement<br />

and reporting<br />

of recycling<br />

rates on plastic<br />

packages.<br />

Encourage<br />

comprehensive<br />

science-based<br />

policies to understand<br />

the origins of and to<br />

prevent marine<br />

waste, and to improve<br />

the management of<br />

solid waste overall,<br />

particularly<br />

of plastic.<br />

PASSION FOR TRANSFORMING<br />

16 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


©<br />

©<br />

-Institut.eu | <strong>2018</strong><br />

-Institut.eu | 2017<br />

Full study available at www.bio-based.eu/reports<br />

Full study available at www.bio-based.eu/reports<br />

©<br />

-Institut.eu | 2017<br />

Full study available at www.bio-based.eu/markets<br />

Bio- and CO 2 -based Polymers & Building Blocks<br />

The best market reports available<br />

Data for<br />

2017<br />

Bio-based Building Blocks<br />

and Polymers – Global Capacities<br />

and Trends 2017-2022<br />

Bio-based polymers:<br />

Evolution of worldwide production capacities from 2011 to 2022<br />

Million Tonnes<br />

6<br />

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2011<br />

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Authors: Raj Chinthapalli, Michael Carus, Wolfgang Baltus,<br />

Doris de Guzman, Harald Käb, Achim Raschka, Jan Ravenstijn,<br />

<strong>2018</strong><br />

This and other reports on the bio-based economy are available at<br />

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Commercialisation updates on<br />

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Standards and labels for<br />

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Bio-based polymers, a revolutionary change<br />

Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />

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million t/a<br />

Selected bio-based building blocks: Evolution of worldwide<br />

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3,5<br />

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Bio-based polymers, a<br />

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2<br />

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1<br />

0,5<br />

Picture: Gehr Kunststoffwerk<br />

2011<br />

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L-LA<br />

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Epichlorohydrin<br />

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MEG<br />

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1,3-PDO<br />

acid<br />

11-Aminoundecanoic acid<br />

MPG<br />

DDDA<br />

Lactide<br />

Adipic<br />

acid<br />

E-mail: j.ravenstijn@kpnmail.nl<br />

Mobile: +31.6.2247.8593<br />

Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

July 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />

nova-Institut GmbH, Germany<br />

May 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />

April 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Policies impacting bio-based<br />

plastics market development<br />

and plastic bags legislation in Europe<br />

Asian markets for bio-based chemical<br />

building blocks and polymers<br />

Market study on the consumption<br />

of biodegradable and compostable<br />

plastic products in Europe<br />

2015 and 2020<br />

Share of Asian production capacity on global production by polymer in 2016<br />

100%<br />

A comprehensive market research report including<br />

consumption figures by polymer and application types<br />

as well as by geography, plus analyses of key players,<br />

relevant policies and legislation and a special feature on<br />

biodegradation and composting standards and labels<br />

80%<br />

60%<br />

Bestsellers<br />

40%<br />

20%<br />

0%<br />

PBS(X)<br />

APC –<br />

cyclic<br />

PA<br />

PET<br />

PTT<br />

PBAT<br />

Starch<br />

Blends<br />

PHA<br />

PLA<br />

PE<br />

Disposable<br />

tableware<br />

Biowaste<br />

bags<br />

Carrier<br />

bags<br />

Rigid<br />

packaging<br />

Flexible<br />

packaging<br />

Authors: Dirk Carrez, Clever Consult, Belgium<br />

Jim Philp, OECD, France<br />

Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

Lara Dammer & Michael Carus, nova-Institute, Germany<br />

March 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />

Lara Dammer, Michael Carus (nova-Institute)<br />

April 2016<br />

The full market study (more than 300 slides, 3,500€) is available at<br />

bio-based.eu/top-downloads.<br />

www.bio-based.eu/reports<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 17


From Science & Research<br />

PLA in the post-consumerrecycling<br />

stream<br />

The constant increase in global production capacities<br />

of biobased plastics [1] results in a variety of products<br />

made of biobased plastics that reach the established<br />

disposal streams as post-consumer wastes after being<br />

used. In Germany, one of these disposal streams is the collection<br />

and disposal of lightweight packaging waste by the<br />

yellow bin or the yellow bag system. KNOTEN WEIMAR and<br />

TU Chemnitz have investigated the behaviour of biobased<br />

plastic products in the sorting of lightweight packaging<br />

wastes at operating plants and pointed out possible options<br />

for material recycling. The research project was carried<br />

out on behalf of the German Federal Ministry of Food and<br />

Agriculture (BMEL) and funded by the project management<br />

organization Fachagentur für nachwachsende Rohstoffe<br />

(FNR) [2].<br />

The scheme in Fig. 1 gives an overview of the various<br />

disposal routes and the recycling and disposing processes<br />

of various packaging waste as well as the recyclable<br />

material fractions produced. Products made of biobased<br />

plastics can also be integrated into this system.<br />

Sensor-based sorting with near-infrared (NIR) devices<br />

is a key element of modern sorting plants and enables the<br />

sorting of different types of plastics.<br />

Drop-in solutions such as biobased PET and PE, are<br />

sorted out together with conventional equivalents.<br />

However, biobased novel plastics (e.g. PLA, PLA blends or<br />

starch based materials) can also be detected and sorted out<br />

due to their characteristic NIR spectra.<br />

It can be concluded that the sorting of e.g. PLA blends as<br />

representatives of biobased novel plastics as single fraction<br />

is technologically viable. Impurities of the sorted fractions<br />

can thus be kept to a minimum.<br />

In preparation for a practical field test in a conventional<br />

sorting plant, the NIR spectra of several different PLA<br />

blends (plastic yoghurt cups, sheets but also dishes, cups<br />

and bottles) were scanned in the existing NIR devices.<br />

In order to determine the current initial quantity, a sorting<br />

test was first run for lightweight packaging sorting with<br />

approx. 25 tonnes of lightweight packaging input material.<br />

The result showed that the current quantity of products<br />

made from PLA/PLA blends and starch blends in all of the<br />

analysed material streams is predominantly below 1.1 ‰.<br />

A further sorting test (three subtests) investigated the<br />

detectability and sortability or material output of PLA<br />

products/wastes at an operating plant in more detail.<br />

The goal was to determine where PLA materials remain<br />

under unchanged sorting conditions (without positive<br />

sorting of PLA or without activating the PLA spectrum on<br />

the NIR devices) and to test the detectability and sortability<br />

of PLA materials from the post-consumer stream. Cups,<br />

forks and dessert cups were used as PLA input material.<br />

Subsequent to material mixing (Fig. 2) the material was<br />

fed into the sorting process.<br />

Three sorting tests were carried out (see above), the<br />

Fig. 1<br />

Disposal paths and recycling, reutilization and disposal processes of separate packaging wastes<br />

Taking back systems for packaging waste<br />

Deposit systems<br />

PET -Bottles<br />

Light weight packaging via dual systems (yellow bin/bag)<br />

e.g. cups, bowls, bottles, films etc.<br />

Sorting -/Pre-treatment plants (Disposal company), Sorting dry<br />

Process steps a.o. crushing, sieving, metal separation, sensor-based sorting (NIR), air separation, manual control<br />

Products: relevant enriched reusable materials<br />

(incl. impurities caused by sorting performance, material-compounds / -mixtures, residues and pollutants)*<br />

PET PS PE / PP Films MP RDF** Residues<br />

Final recipient plant, Conditioning wet-dry-<br />

Process steps (per material): a.o metal separation,<br />

sensor-based sorting (NIR), crushing, washing,<br />

sink-float separation (separation by density), drying, if any extruding<br />

Sinking<br />

fraction<br />

(ρ > 1)<br />

e.g. PET<br />

Swimming<br />

fraction<br />

Sinking<br />

fraction<br />

e.g. PE / PP<br />

Swimming<br />

fraction<br />

(ρ < 1)<br />

Final recipient plant,<br />

Conditioning dry<br />

Process steps (per material):<br />

a.o. metal separation, crushing,<br />

sieving, air separation, sorting,<br />

if any agglomeration<br />

e.g. Mixed plastics (MKS)<br />

Thermal<br />

treatment<br />

(MVA )<br />

PET<br />

a.o. residues<br />

a.o. residues<br />

PE / PP<br />

z.B. PO<br />

Recyclates,<br />

e.g. PET, PO, PS<br />

(material recycling)<br />

Reductant, gases<br />

and oils<br />

(raw material recycling<br />

e.g. steel plant)<br />

Fuel<br />

(energetic<br />

utilisation e.g.<br />

cement and CHP<br />

station)<br />

Energy<br />

(disposal,<br />

if possible<br />

energetic<br />

utilisation***)<br />

*Specification for individual recyclable material available; **classification as final recipient plant for RDF-production; ***MVA if possible energetic utilisation<br />

18 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


From Science & Research<br />

By:<br />

Jasmin Bauer,Carola Westphalen<br />

KNOTEN WEIMAR<br />

Internationale Transferstelle Umwelttechnologien GmbH<br />

Weimar, Germany<br />

Tobias Hartmann, Roman Rinberg,,Lothar Kroll<br />

Technische Universität Chemnitz<br />

Chemnitz, Germany<br />

material first underwent the automated sorting process<br />

and was then manually separated from the fractions.<br />

The following results were achieved:<br />

• Detecting and, in particular, separation of PLA materials<br />

as individual material fraction in a state-of-the-art plant<br />

is possible.<br />

• Sorting under normal conditions for lightweight<br />

packaging (PLA detection not active) approx. 9 % of the<br />

PLA input goes into the PVC fraction. Hence, PLA is<br />

classified as PVC if no PLA spectrum is active.<br />

• Small scale adaption was made by adjusting the plant<br />

technology by scanning the PLA spectra.<br />

• Positive sorting on PLA results in a sorting rate of 55%.<br />

• Positive sorting on PLA+PE/PP extracted 46% of PLA<br />

input.<br />

The generated test material (PLA fraction) was grinded,<br />

washed and the grist was purified to 90 % PLA with the help<br />

of Hamos GmbH (Penzberg, Germany) in the company’s<br />

own pilot plant. The purification took place in three stages:<br />

air separation, metal separation and plastic-plastic<br />

separation. The main contamination after the cleaning<br />

process was adhesive label residues from the yoghurt cup.<br />

As not enough input material was available for the final<br />

regranulation on an industrial plant, a test material (~ 0.8 t)<br />

Fig. 2 Input material (left), automated sorting process (right)<br />

was mixed analogous to the purified fraction. This grist<br />

was regranulated at Sysplast GmbH&Co. KG in Nürnberg,<br />

Germany on a Coperion ZSK 50MC with an Ettlingen rotary<br />

filter ERF (sieve width 250 µm) with throughputs of up to 400 kg<br />

per hour. The impurities were separated effectively and a<br />

green regranulate was obtained (see Fig. 3).<br />

The mechanical testing revealed the following losses<br />

with regard to the virgin material (Ingeo 2003D from<br />

NatureWorks):<br />

Young’s modulus -1 %<br />

tensile strength -24 %<br />

Charpy unnotched -31 %<br />

Charpy notched -17.4 %<br />

All the tests and results mentioned, as well as further<br />

experiments on the recycling of PLA, including a life cycle<br />

assessment, are detailed in the final report of the research<br />

alliance “Nachhaltige Verwertungsstrategien für Produkte<br />

und Abfälle aus biobasierten Kunststoffen” funded by<br />

BMEL in which eight partners from science and industry<br />

participated [3]. A quick overview of the most important<br />

results, as well as further links to the joint project and the<br />

partners, are summarised in the results paper “PLA in the<br />

waste stream” (download link see [4]).<br />

References:<br />

[1] European Bioplastics, nova-Institut (2017). www.biobased.eu/markets<br />

[2] https://www.fnr.de/index.php?id=11150&fkz=22019212<br />

[3] https://www.european-bioplastics.org/pla-in-the-waste-stream/<br />

[4] https://www.umsicht.fraunhofer.de/content/dam/umsicht/en/<br />

documents/press-releases/2017/pla-in-the-waste-stream.pdf<br />

www.bionet.net | www.leichtbau.tu-chemnitz.de<br />

Fig. 3: seperates impurities (left) and green PLA regranulate (right)<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 19


Bioplastics from waste streams<br />

By:<br />

Vlaďka Matušková<br />

Project Manager<br />

NAFIGATE Corporation, a.s.<br />

Prague, Czech Republic<br />

Waste Cooking<br />

Oil as a Source<br />

for PHA<br />

Low quality waste cooking oil (WCO) has traditionally<br />

been regarded as a low-value waste product, unfit for<br />

further use. Not by Czech company NAFIGATE Corporation,<br />

however, whose Hydal Biotechnology uses 100 % waste in<br />

the form of waste cooking oil to produce fully biodegradable<br />

PHA biopolymer. The company uses oil also as a source of<br />

energy, making biopolymer significantly more affordable<br />

than bioplastics manufactured from the so-called firstgeneration<br />

feedstock, such as corn or sugar cane. Hence,<br />

the technology is Zero Waste with 50 % less energy<br />

consumption than conventional polyethylene (PE).<br />

Nafigate Corporation’s innovative and patented Hydal<br />

biotechnology has won global acclaim, earning, for example,<br />

the 2015 Frost and Sullivan Technology Innovation Award,<br />

Seal of Excellence, as well as being named one of the Top 10<br />

products in China. It is a technology for upcycling: it takes<br />

a waste product and transforms this into a completely<br />

different product – a biopolymer. The company’s strategy<br />

is based on a production system that is aimed at closing<br />

the loop, in line with the key principle of the concept of the<br />

Circular Economy, which is to retain the value of a material<br />

as long as possible within the cycle.<br />

Moreover, the environmental aspects of this breakthrough<br />

technology have been analysed with the help of Life Cycle<br />

Assessment (LCA), the only tool to objectively assess the<br />

impacts of Hydal PHA manufacturing on the environment.<br />

Due to the Zero Waste production system and use of waste<br />

material, the LCA demonstrated a significant positive effect<br />

of the production of PHB polymers from Waste Cooking<br />

Oil using Hydal’s environmental biotechnology. Compared<br />

to polymers made from first generation feedstock and<br />

conventional polyethylene, Hydal PHA production does<br />

not result in the depletion of natural resources, has a<br />

smaller CO 2<br />

footprint and is not associated with ecotoxicity,<br />

freshwater toxicity, acidification, eutrophication and other<br />

negative environmental impacts.<br />

The final biopolymer can be used in various fields,<br />

including for bioplastics production. Another key area is<br />

the cosmetics industry, for which Hydal PHA provides ideal<br />

properties. Hydal PHA is offered in the form of a whole<br />

range of P3HB particles with a nano surface area of up to<br />

8 m 2 /g. According to the certified analysis, the purity of the<br />

final biopolymer – P3HB or PHBV – is higher than 99 %,<br />

with a high molecular weight. Recently, the company in<br />

cooperation with Nafigate Cosmetics launched a new<br />

product - Coconut shower peeling milk, in which microbeads<br />

have been replaced with Hydal P3HB. As a new cosmetics<br />

eco-design concept, it is being market under the name<br />

“Dedicated to You and Nature” to reflect its biodegradable<br />

and biocompatible properties.<br />

PHA can be also used in the medical sector, since P3HB<br />

particles of varying sizes are able to act as transport<br />

systems for active substances. P3HB is additionally<br />

approved for medical purposes by the FDA. Hydal PHA<br />

enables the production of microfibres with a nano surface<br />

area of 30-40 m 2 /g.<br />

Agriculture is another area, in which Hydal PHA may find<br />

application. Hydal PHA-based enhanced efficiency fertiliser<br />

represents controlled-release fertilizers, which gradually<br />

supply the nutrients to the soil. This controlled-release<br />

technology results in some 50 % less fertiliser being<br />

needed compared to conventional methods (fertilizers<br />

are coated with PHA). Furthermore, waste biomass from<br />

the production process offers another source for fertiliser<br />

manufacturing, while last but not least, phosphorus from<br />

the production process can be recycled.<br />

www.nafigate.com<br />

20 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Bioplastics from waste streams<br />

Life Cycle Assessment on PHB production from Used Cooking Oil<br />

100<br />

80<br />

60<br />

40<br />

20<br />

-0<br />

-20<br />

-40<br />

-60<br />

-80<br />

-100<br />

Abiotic<br />

depletion<br />

Abiotic<br />

depletion<br />

(fossil fuels)<br />

Global<br />

warming<br />

(GWP 100a)<br />

Global<br />

warming<br />

(GWP 100a)<br />

Human<br />

toxicity<br />

Fresh water<br />

aquatic<br />

ecotox.<br />

Marine<br />

aquatic<br />

ecotoxicity<br />

Terrestrial<br />

ecotoxicity<br />

Photochemical<br />

oxidation<br />

Acidification<br />

Eutrophication<br />

PHB LDPE, granulate Polylactide, granulate<br />

Method: CML-IA baseline V3.05/EU25/Characterization<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 21


Bioplastics from waste streams<br />

Is Algae a sustainable<br />

feedstock for bioplastics?<br />

As demand for bioplastics grows, the industry is starting<br />

to feel the challenge of finding sustainable biofeedstock.<br />

Algae appears to be a promising source<br />

[1]. Algae can be both grown commercially, or harvested<br />

from commercial and industrial processes, such as water<br />

treatment.<br />

Growing algae commercially for bioplastics<br />

applications<br />

Algae is already commercially grown for nutraceuticals<br />

(e.g. Omega 3 EPA/DHA), cosmetics, food and animal feed<br />

supplements, according to Barry Cohen, President of The<br />

National Algae Association (The Woodlands,Texas, USA).<br />

Cohen notes that algae is a microorganism that doubles<br />

in population every couple of days. Cohen estimates that<br />

an algae producer would need only 60 days to cultivate a<br />

particular strain for client review, testing, and certification.<br />

Another 60-90 days may be required to fulfill a large volume<br />

order suitable for bioplastics. Algae strains suitable for<br />

bioplastics have already been proven in the lab.<br />

Cohen notes that the biggest challenge to growing algae<br />

for bioplastics is finding a client who can fund 30-40% of the<br />

contract price upfront to fulfill a large volume order quickly.<br />

The industry is self-funded and even though producers can<br />

scale easily into commercial production, they have limited<br />

resources to bear large volume production expenditures<br />

alone. Partnerships within the greater supply chain will be<br />

required to get commercially-grown algae into large-scale<br />

bioplastics production.<br />

Harvesting algae from existing water treatment<br />

processes<br />

Algae thrives in our wastewater and other high-nutrient<br />

(i.e. polluted) environments. While its presence helps filter<br />

harmful nutrients out of the water, its overgrowth in nutrientrich<br />

conditions is also a menace [2] to freshwater supplies.<br />

There is a rising demand to contain algae overgrowth<br />

in waterways and reduce the water nutrient levels that<br />

support algae. This can be done while harvesting algae to<br />

generate feedstock for bioplastics and other applications.<br />

Two innovative start-ups are seizing this opportunity:<br />

Working with a wastewater treatment byproduct<br />

Kelvin Okamoto is the Founder and CEO of Gen3Bio<br />

(West Lafayette, Indiana, USA), an innovative company<br />

that converts algae into biofeedstock for resale using a<br />

proprietary blend of enzymes. Okamoto noted that Gen3Bio<br />

harvests the algae from treatment processes that filter<br />

problematic nutrients from wastewater.<br />

Gen3Bio has a mobile pilot facility that hooks into the<br />

nutrient removal systems at wastewater treatment plants,<br />

utilizing its own blends of algae to do the job. Gen3Bio then<br />

harvests the spent algae for processing and resale. The<br />

company plans to share a percentage of net revenue from<br />

the sale of the resulting algae biofeedstock with wastewater<br />

facilities.<br />

The main outputs of Gen3Bio’s operation include sugars,<br />

fats, and proteins from the spent algae. Gen3Bio ferments<br />

sugars extracted from the algae to produce succinic acid.<br />

Succinic acid (cf. bM 03/2013) has multiple uses; among<br />

them, it is a common ingredient in the production of<br />

polybutylene succinate (PBS) (cf. bM 05/2016 and [3, 4]).<br />

PBS is a biodegradable thermoplastic with properties<br />

similar to polypropylene. It is sometimes blended with PLA.<br />

It can be used for the production of both durables (e.g.<br />

fishnets, automotive composites) and non-durables (e.g.<br />

food packaging, disposable cups).<br />

Harvesting algae out of our water supply<br />

While Gen3Bio harvests spent algae from a wastewater<br />

treatment process, Omega Material Sciences filters<br />

problematic algae directly out of the water. Omega Material<br />

Sciences (Lakeland, Florida Area, USA) is an R&D lab that<br />

is working on a large-scale source of algae feedstock for<br />

bioplastics. Its founder, Keith Ervin, has developed a water<br />

treatment media to safely extract algae blooms from both<br />

freshwater and wastewater at high volumes.<br />

Ervin notes that traditional approaches to algae<br />

remediation cannot generate biofeedstock at meaningful<br />

scales because they kill off algae, leading the organism<br />

to emit toxins into the water upon their demise. Ervin’s<br />

method leads to chemical and mechanical separation<br />

of algae blooms from water, making it safe and effective<br />

in producing clean water and harvesting the algae at a<br />

commercial scale.<br />

Ervin has received significant attention from the water<br />

treatment community for his technology. Building the<br />

infrastructure to harvest his algae at scale to feed the<br />

demand for bioplastics will require collaboration and<br />

investment across industries, however. Ervin is looking for<br />

partners and stakeholders to make this happen.<br />

Algae-based materials may already be in your<br />

shoes<br />

Algae is already making an appearance in consumer<br />

products. Algix, a company located in Meridian, Mississippi,<br />

USA, has been producing a plastic composite out of algae<br />

for some years. The algae is combined with traditional<br />

plastics to create Algix’ Solaplast line of resins, which are<br />

approximately 45 % algae. Ryan Hunt, Co-Founder and CTO<br />

at Algix, stated that the algae acts as a biobased filler in<br />

the Solaplast resins, lowering the environmental footprint<br />

of the resulting composite.<br />

22 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Bioplastics from waste streams<br />

By:<br />

Joanna Malaczynski<br />

Consultant<br />

DESi Potential<br />

Bend, Oregon, USA<br />

Algix’ daughter company, Bloom, converts the algae<br />

composite into an EVA foam that can be used in consumer<br />

goods. Bloom’s algae foam can already be found in some<br />

flip flops, running shoes, and even surfboard traction pads.<br />

The company is launching products with companies such as<br />

Adidas, Altra Running, BOGS, Clark’s, Toms, Vivobarefoot<br />

(see p. 35, EcoAlf, Billabong, Saola, TenTree, Red Wings,<br />

Slater Design, Surftech, Biota and Chippewa.<br />

Hunt noted that most of the algae used by his company<br />

is a wastewater treatment by-product. Algix likes working<br />

with wastewater algae because it contains high levels of<br />

proteins, that can be used as building-blocks for certain<br />

bioplastics. Hunt noted that algae living in nutrient rich<br />

conditions, such as wastewater and our overly-fertilized<br />

waterways [5], is especially productive in producing these<br />

proteins.<br />

Is algae suitable for food-grade plastics?<br />

Algae could be an effective biofeedstock for food-grade<br />

plastics. Many American commercial algae growers already<br />

produce a food-grade product for other markets. With<br />

the right business partner, they could shift to food-grade<br />

production for bioplastics. Companies who work with<br />

wastewater algae, on the other hand, have yet to seek FDA<br />

approval for food-grade use, and it remains to be seen to<br />

what extent this would be a viable proposition for them.<br />

An emerging Oregon start-up, AlgoteK, has produced<br />

an algae-based food-grade film, sourcing its algae from<br />

China. The AlgoteK film degrades in contact with water,<br />

which makes it suitable for certain single-use applications.<br />

David Crinnion, Co-Founder of AlgoteK, noted that he<br />

is committed to working with the biobased material in<br />

its purest form because it is easily compostable and biodegradeable.<br />

AlgoteK recently caught the interest of a local<br />

chocolate manufacturer, which is interested in utilizing<br />

AlgoteK’s algae-based material for its packaging.<br />

Gen3Bio Pilot Plant Equipment<br />

Billabon flipflops<br />

References<br />

[1] https://www.fastcompany.com/90154210/the-creators-of-this-algaeplastic-want-to-start-a-maker-revolution<br />

[2] https://www.epa.gov/nutrientpollution/harmful-algal-blooms<br />

[3] https://www.m-chemical.co.jp/en/products/departments/mcc/<br />

sustainable/product/1201025_7964.html<br />

[4] http://www.succinity.com/polybutylene-succinate<br />

[5] http://news.wfsu.org/post/engineering-bioplastics-firms-debut-cuttingedge-algae-removal-process<br />

SlaterDesign Algae Traction Pad<br />

Vivobarefoot Ultra Bloom<br />

running shoes<br />

https://desipotential.com | www.gen3bio.com | http://algix.com |<br />

https://bloomfoam.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 23


Bioplastics from waste streams<br />

Valorizing<br />

Plant pots<br />

Biodegradable plastic pipe (Heijmans)<br />

Rodenburg Biopolymers’ activities started in 1945,<br />

trading plant-derived products for various industries.<br />

Soon Arie Rodenburg added side stream<br />

activities, by buying defects from potato sorters. This<br />

was when the long-term relationship with potato side<br />

streams started. Who would have known that a forage<br />

business would turn into Bioplastics half a century later?<br />

Collaboration<br />

In the 1960’s, Rodenburg started working together<br />

with French Fry Factories and pioneered in collecting<br />

and valorizing industrial side streams. Rodenburg was<br />

characterized by tight collaborations and innovation<br />

on every step in the value chain. At the beginning of<br />

the chain, the processes of the factories needed to<br />

be adjusted to make the collection of side streams<br />

possible. Rodenburg introduced new innovative<br />

processing techniques, like grinding the steam peels.<br />

At the end of the chain, Rodenburg created a market<br />

for its products and revolutionized the forage industry.<br />

This was also the start of its R&D activities. The various<br />

side streams were split and tested for optimal results<br />

on different cattle species. Aaik Rodenburg recalled:<br />

“We partnered up and started a bull farming business<br />

to raise top quality cattle on our side stream products.<br />

This way we could optimize the valorization processes<br />

and show our customers excellent quality meat.”<br />

During these decades Rodenburg built the bedrock<br />

and the fundamentals for the business. Collaboration<br />

and innovation are still King for success at Rodenburg<br />

Biopolymers.<br />

Innovation<br />

In the year 2000, Aaik Rodenburg made a turnaround<br />

to Biodegradable polymers, in cooperation<br />

with Wageningen ATO (Food and Biobased Research).<br />

Building further on the essence of the company; the<br />

valorization of co-products and waste streams. An<br />

intensive period of R&D followed, with many obstacles<br />

to overcome. Resulting in various certified and awardwinning<br />

biodegradable products. For example, the<br />

biobased packaging material for Mars’ candy bars,<br />

awarded with the 11th Global Bioplastics Award by<br />

bioplastics MAGAZINE.<br />

These innovations took time, flexibility and continuous<br />

improvement. “We were so proud to produce our first,<br />

biodegradable plant pots,” Aaik recounted. “During<br />

the opening of our new factory, we handed out dozens<br />

of those with a flower in it. Unfortunately, the product<br />

appeared to evoke a special reaction from dogs; diggingup<br />

the pots and ruin the gardens. Other uncalculated<br />

side-effects were the increasing odor over time and the<br />

violets changing their color. Apparently, the protein in<br />

the potato was the culprit.”<br />

Biodegradable plastic pipe (Heijmans)<br />

Drawing from this anecdote, it shows the persistence<br />

and grit needed to achieve the desired products,<br />

24 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


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side streams<br />

even before entering the market. “We have 50 Years of<br />

experience in valorizing side streams, strong in-house R&D<br />

and a track record in co-creation. Still, every innovation<br />

involves a lean, innovative approach and customization,”<br />

said Thijs Rodenburg, CEO of the company. The violets are<br />

still standing in the office as a reminder for that, next to<br />

Mars’ packaging.<br />

TRANSITION<br />

During the last decade, there has been a change in<br />

business needs, manufacturing demands and ethical<br />

standards. However, the customer is still not ready to pay<br />

the premium for innovative processes or biodegradable<br />

materials. Rodenburg Biopolymers found the gap: value<br />

adding propositions and unique product performances.<br />

Thijs Rodenburg: “Two years ago, we produced<br />

biodegradable plant support sticks. We hoped customers<br />

would embrace the cradle to cradle or biodegradable<br />

concept. Unfortunately, we could not compete with the<br />

cheaper, plastic alternatives. We continued R&D with our<br />

partners Growfun and Wageningen University and looked<br />

for the right proposition to reach our target audience. We<br />

found a way to add fertilizer to the sticks, so not only would<br />

they provide support, but also feed the plant nutrition over<br />

time. This product was launched at the Royal FloraHolland<br />

Trade Fair this year, under the brand Voodstock, with great<br />

success.”<br />

According to Rodenburg, the market is in transition. It is<br />

only a matter of time before the mass will embrace bioplastics<br />

as a sustainable alternative. And waste streams will play an<br />

important role as a feedstock. MT<br />

www.biopolymers.nl<br />

from left: Thijs, Joost and Aaik Rodenburg,<br />

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71. Jahrgang, Juni <strong>2018</strong><br />

<strong>06</strong>| <strong>2018</strong><br />

Volume 13, June <strong>2018</strong><br />

3| <strong>2018</strong><br />

Volume 9, April <strong>2018</strong><br />

2| <strong>2018</strong><br />

info@gupta-verlag.de · www.gupta-verlag.com<br />

Stay informed with our free newsletters:<br />

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bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 25


Materials<br />

Modified Calcium Carbonate<br />

opens new opportunities for<br />

the use of PLA<br />

P<br />

olylactic Acid (PLA) is one of the fastest growing<br />

biobased polymers on the market. Processors have<br />

tried to use Calcium Carbonate to improve properties<br />

and the cost structure, as is common in conventional<br />

polymers. Omya gained experience showing that conventional<br />

Calcium Carbonate can lead to the degradation of<br />

PLA and PLA / PBAT blends used in products such as cups,<br />

trays, lids and bags. Omya followed market demand to develop<br />

a new type of Calcium Carbonate that does not cause<br />

PLA degradation.<br />

Introduction<br />

PLA is a bio-polyester which degrades when processed<br />

with moisture due to hydrolysis. Calcium Carbonate is by<br />

nature a somewhat hygroscopic material and carries a<br />

certain amount of moisture on its surface and in its crystal<br />

structures.<br />

In 1952, Omya launched the first surface-treated Calcium<br />

Carbonate with reduced moisture adsorption. Today it<br />

is common to use surface-treated calcium carbonate in<br />

all types of polymer applications to prevent processing<br />

problems and surface defects on the final products. The<br />

most common surface treatment materials are based on<br />

fatty acids, such as stearic acid. With such a treatment,<br />

a good reduction of the moisture uptake on the Calcium<br />

Carbonate can be observed, but it ultimately causes<br />

hydrolysis in PLA.<br />

With the development of Omya Smartfill ® technology, the<br />

situation has changed. It is now possible to add 40 % or<br />

more of Calcium Carbonate in films, sheets or injection<br />

molded parts without causing significant hydrolysis<br />

while improving important properties such as elongation,<br />

stiffness and impact.<br />

Product Evaluation<br />

Melt flow rate is considered a good indicator of polymer<br />

chains degradation: As PLA degradation increases, it is<br />

expected that the melt flow rate of the polymer or compound<br />

would increase too.<br />

Table 2 shows the difference between conventionally<br />

treated Omyacarb ® 1T and Omya Smartfill after preparing<br />

a 40 % Calcium Carbonate compound with Natureworks<br />

Ingeo 2003D. The compounding line is a continuous<br />

kneader without vacuum degassing and only pre-dried<br />

PLA was used. The results show that using a conventional<br />

Calcium Carbonate, such as Omyacarb 1T, MFR increased<br />

significantly, which means that important polymer<br />

degradation has taken place during processing. In contrast,<br />

Omya Smartfill does not show signs of degradation and<br />

kept the melt flow on the same level as virgin PLA.<br />

A more common technology for processing PLA is twinscrew<br />

compounding with the ability to extract water by<br />

vacuum degassing. Table 3 shows that in these processing<br />

conditions, the melt flow rate increase with Omyacarb 1T<br />

was more limited but still not satisfactory. The use of Omya<br />

Smartfill led again to a significantly lower MFR and matched<br />

the viscosity of unfilled PLA.<br />

Omya Smartfill does not require pre-drying or<br />

venting when compounding<br />

To test the effect of Calcium Carbonate on PLA properties,<br />

a 300mm working width laboratory casting line was used to<br />

make 800 µm PLA sheets with different Calcium Carbonate<br />

loadings.<br />

Fig 1 and Fig 2 show the same typical property changes<br />

Calcium Carbonate provides in PLA as expected with<br />

Calcium Carbonate addition in conventional thermoplastic<br />

polymers. Yield strength decreases, and stiffness increases<br />

with increasing Calcium Carbonate concentration.<br />

After sheet production, part of it was cut into small pieces<br />

to check the extent of degradation. This was done after the<br />

second heat history through MFR measurement (Fig 3). The<br />

results clearly show that Omya Smartfill does not cause<br />

additional PLA degradation, whereas Omyacarb 1T causes<br />

heavy degradation, which can make polymer processing<br />

difficult.<br />

In many polymers, the elongation at break is reduced<br />

due to the addition of mineral additives. Surprisingly Omya<br />

Smartfill added to PLA boosts the ultimate elongation. Fig 4<br />

shows a strong increase in elongation at break achieved<br />

when adding Omya Smartfill with a maximum at around<br />

20 % addition but even at 40 % addition elongation is far<br />

higher than for virgin PLA. This proves that Omya Smartfill<br />

increases stiffness and elasticity simultaneously and<br />

allows a processor to achieve high filler levels with superior<br />

mechanical properties. This effect can be seen also when<br />

adding Omyacarb 1T but to a much less extent, which could<br />

be related to degradation.<br />

Similar injection molding tests show comparable<br />

improvements and an increased impact strength on top, but<br />

there are additional benefits that contribute to overall cost<br />

savings when using 40 % Omya Smartfill, including:<br />

• 12 % lower specific heat capacity<br />

• 78 % higher thermal conductivity<br />

• 60 % higher thermal diffusivity<br />

• 89 % opacity at 30 % filler level without the use of<br />

titanium dioxide<br />

26 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


By:<br />

4500<br />

4000<br />

3500<br />

3000<br />

2500<br />

2000<br />

1500<br />

1000<br />

500<br />

0<br />

1000<br />

500<br />

0<br />

100% PLA 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya Smartfill<br />

20% Omyacarb 1T<br />

Matthias Welker, Michael Knerr, Karsten 100% Schulz PLA 10% Omya Smartfill<br />

Omya International AG<br />

20% Omya Smartfill 40% Omya Smartfill<br />

Oftringen, Switzerland<br />

20% Omyacarb 1T<br />

Physical properties help to increase productivity. When 30<br />

using Omya Smartfill in thermoforming or injection<br />

20<br />

molding, less energy is needed for heating and cooling and<br />

10<br />

lower cycle times can be achieved. Elongation at Break in MD [%]<br />

80<br />

70<br />

60<br />

50<br />

40<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

100<br />

90<br />

80<br />

70<br />

60<br />

100 50<br />

40 90<br />

30 80<br />

20 70<br />

10 60<br />

50 0<br />

Tensile Strength at Yield in MD [N/mm 2 ]<br />

Tensile Strength at Yield in MD [N/mm 2 ]<br />

10<br />

0<br />

100% PLA 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya Smartfill<br />

20% Omyacarb 1T<br />

0<br />

100<br />

100% PLA 10% Omya Smartfill<br />

Omya Smartfill is always the right choice when conventional<br />

Tensile Modulus MD [N/mm 2 ]<br />

90<br />

20% Omya Smartfill 40% Omya Smartfill<br />

Calcium Carbonate causes 80polymer degradation due to<br />

5000 20% Omyacarb 1T<br />

hydrolysis. It is EU 10/201170<br />

and FDA approved for food<br />

4500<br />

contact, it meets composting 60requirements and has passed<br />

4000<br />

50<br />

3500<br />

the ecotoxicity test. The material Elongation is supplied at Break as a powder in MD [%]<br />

40<br />

3000 Tensile Modulus MD [N/mm 2 ]<br />

and needs to be<br />

100<br />

pre-dispersed in a compound before being<br />

30<br />

2500 5000<br />

used on conventional 90 single 20 screw extrusion lines.<br />

2000 4500<br />

80<br />

10<br />

1500 4000<br />

Omya recently<br />

70<br />

received an<br />

0<br />

Innovator Award from the<br />

1000 3500<br />

Sustainable Packaging 60 Coalition (SPC) 100% as PLA a member 10% Omya 3000 500 Smartfill<br />

of PepsiCo’s Supply 50 Chain Partnership to 20% deliver Omya Smartfill a new 40% Omya 2500 Smartfill 0<br />

40<br />

20% Omyacarb 1T<br />

2000<br />

100% PLA 10% Omya Smartfill<br />

biobased film package to market. The outcome of a<br />

30<br />

1500<br />

20% Omya Smartfill 40% Omya Smartfill<br />

Partnership Innovator Award was one of a select few entries<br />

70 20% Omyacarb 1T<br />

20<br />

1000<br />

chosen for advancing 10 the state of sustainable packaging.<br />

500<br />

60<br />

Fig 2<br />

NatureWorks, Danimer 0 Scientific, Berry Global, Johnson-<br />

0<br />

50<br />

Bryce and PepsiCo also received 100% an PLA award. 10% Omya Smartfill<br />

100% PLA 10% Omya 80 Smartfill<br />

www.omya.com<br />

20% Omya Smartfill 40% Omya Smartfill<br />

40 20% Omya Smartfill 40% Omya Smartfill<br />

20% Omyacarb 1T<br />

70<br />

20% Omyacarb 1T<br />

30 MFR @ 210C/2.16kg [g/10min]<br />

60<br />

70<br />

20<br />

50<br />

Table 1: Moisture adsorption of common calcium carbonate<br />

grades and Omya Smartfill 55 - OM (mg/g, upon relative humidity<br />

change from 10% rH to 85 % rH at 23 °C)<br />

Calcium Carbonate<br />

Conventional un-treated<br />

Conventional treated<br />

Omya Smartfill 55-OM<br />

Moisture Adsorption<br />

1580 ppm<br />

750 ppm<br />

390 ppm<br />

Table 2: MFR (210°C/ 2.16kg [g/10min]) (without degassing)<br />

MFR<br />

100% PLA Ingeo 2003D 6<br />

60% PLA + 40% Omyacarb 1T 49<br />

60% PLA + 40% Omya Smartfill 5<br />

Table 3: MFR (210°C/ 2.16kg [g/10min]) (with degassing)<br />

MFR<br />

100% PLA Ingeo 2003D 6<br />

60% PLA + 40% Omyacarb 1T 25<br />

60% PLA + 40% Omya Smartfill 6<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

40<br />

30<br />

20<br />

10<br />

0<br />

Fig 1<br />

MFR @ 210C/2.16kg [g/10min]<br />

40 80<br />

30 70<br />

Tensile Strength at Y<br />

100% PLA 20 60 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya Smartfill<br />

10<br />

20% Omyacarb 1T 50<br />

40 0<br />

30<br />

100% PLA<br />

20% Omya Smartfill<br />

20<br />

20% Omyacarb 1T<br />

10<br />

100% PLA 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya 0Smartfill<br />

20% Omyacarb 1T<br />

Elongation at Break in MD [%]<br />

Fig 3: MFR after sheet production<br />

Elongation at Break in MD [%]<br />

100% PLA 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya Smartfill<br />

20% Omyacarb 1T<br />

100% PLA 10% Omya Smartfill<br />

20% Omya Smartfill 40% Omya Smartfill<br />

20% Omyacarb 1T<br />

Fig 4: Impact of calcium carbonate<br />

to elasticity<br />

Materials<br />

Tensile Strength at Y<br />

70<br />

60<br />

50<br />

100% PLA<br />

20% Omya Smartfill<br />

20% Omyacarb 1T<br />

MFR @<br />

MFR<br />

40<br />

70<br />

30<br />

60<br />

20<br />

50<br />

10<br />

40<br />

0<br />

bioplastics MAGAZINE 30 [<strong>06</strong>/18] Vol. 13 27<br />

100% P


From Science & Research<br />

Improved biobased fibres<br />

for clothing applications<br />

Polylactic acid (PLA) is a material obtained from renewable<br />

resources, suitable for obtaining melt-processable fibres. It<br />

combines ecological advantages with a good performance in<br />

textiles. PLA successfully bridges the gap between synthetic and<br />

natural fibres and finds a wide range of uses, but despite their<br />

benefits, most commercial PLA grades do not yet fulfil all the mechanical<br />

and thermal requirements for some textile applications.<br />

In order to solve these limitations, the European project FIBFAB<br />

has been working on the development of a new bio-compound<br />

that fulfils the desired properties for textile clothing applications<br />

as well as the suitability to be used in industrial fibre production.<br />

The project FIBFAB aims to industrialize and successfully launch<br />

the production of biobased and sustainable PLA-based fabrics<br />

(wool/PLA and cotton/PLA) for applications in casual, protective<br />

and workwear clothing and to overcome the current limitations of<br />

PLA fibres as a real alternative to current fabrics (wool and cotton<br />

combined with polyester (PES) fibres). The targets of the project<br />

are:<br />

• To obtain a final 100 % biobased clothing product that meets<br />

the mechanical performance requirements of the textile sector.<br />

Sample<br />

Standard /<br />

Method<br />

MFI<br />

(g/10 min)<br />

210°C; 2,16 kg<br />

UNE-EN ISO<br />

1133-2: 2012<br />

VICAT B50 (°C) Crystallinity (%)<br />

UNE-EN ISO<br />

3<strong>06</strong>: 2015<br />

DSC,<br />

Platen Press<br />

PLA 6201 D 25 55-60 25.40<br />

PLA 6100 D 24 55-60 -<br />

PLA 6260 D 65 - -<br />

Target<br />

properties<br />

15-30 > 90 -<br />

FibFab<br />

compound<br />

22.8 ± 0.7 92.7 ± 0.4 47.08<br />

By:<br />

Nuria López Aznar<br />

Senior Polymer Researcher<br />

AIMPLAS (Plastics Technology Centre)<br />

Paterna, Spain<br />

With this compound developed, fibres and some<br />

final products such T-shirts were obtained.<br />

• To improve the current poor thermal resistance of PLA fibres<br />

to meet the requirements in several clothing applications. The<br />

thermal resistance of PLA fibres achieved are higher than<br />

90°C.<br />

• To improve the extrusion process for PLA fibres to be able<br />

to obtain fine fibres (less than 3 dtex) and especially the<br />

mechanical spinning process (friction control in ring spinning)<br />

to be able to spin PLA blend fibres at higher speeds.<br />

• To reduce the market dependence on fibre and textile imports<br />

(mainly PES products) and improve the competitiveness of the<br />

textile sector by creating a new concept of clothing that fits the<br />

expectations of customers with high ecological awareness.<br />

• To introduce yarns and fabrics produced from PLA fibres<br />

and cotton or wool into the textile market. Due to the<br />

chemical nature of PLA, it has been proven that it has better<br />

breathability, hydrophilic properties, UV resistance, low smoke<br />

production and flammability and also lower density than PES.<br />

The compound development, in which AIMPLAS (Paterna,<br />

Spain) is the main responsible, has included a mix of different<br />

commercial PLAs with some additives such as nucleants,<br />

processing aids and hydrolysis stabilizers.<br />

From the results of the characterization of the compounds<br />

developed, it was possible to achieve the targets regarding viscosity,<br />

thermal resistance, crystallinity, hydrolytic behaviour, mechanical<br />

properties and shrinkage, as well as good processability, obtaining<br />

fibres with less than 3 dtex.<br />

The table shows some of the main properties studied and<br />

compares some commercial PLAs and the compound developed<br />

within the project FIBFAB.<br />

FIBFAB is a two-year project funded by the EU’s<br />

Horizon 2020 Research and Innovation programme<br />

under grant agreement No 737882, in which AIMPLAS<br />

(Plastics Technology Centre) is the coordinator.<br />

Together with the rest of the consortium (Centexbel,<br />

D.S. Fibres, Yünsa and Sintex), these members<br />

cover the textile value chain, from fibre production to<br />

product manufacturing, thus ensuring the industrial<br />

implementation of PLA fibres for clothing.<br />

fibfab-project.eu/ | www.aimplas.es<br />

28 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


From Science & Research<br />

New<br />

method<br />

for high<br />

yield FDCS<br />

production<br />

enables large-scale<br />

production of bio-based<br />

plastic bottles<br />

S<br />

cientists have discovered a novel method to synthesize<br />

furan-2,5-dicarboxylic acid (FDCA) in a high yield from a glucose<br />

derivative of non-food plant cellulose, paving the way for<br />

replacing petroleum-derived terephthalic acid with biomaterials in<br />

plastic bottle applications.<br />

The chemical industry is under pressure to establish energyefficient<br />

chemical procedures that do not generate by-products, and<br />

using renewable resources wherever possible. Scientists believe<br />

that if resources from non-food plants can be used without putting<br />

a burden on the environment, it will help sustain existing social<br />

systems.<br />

It has been reported that various useful polymers can be<br />

synthesized from 5-(hydroxymethyl)furfural (HMF), the biomaterial<br />

used in this study. A high yield of FDCA can be obtained when HMF<br />

is oxidized in a diluted solution under 2 wt % with various supported<br />

metal catalysts. However, a major stumbling block to industrial<br />

application lies with the use of a concentrated solution of 10-20 wt %,<br />

which is essential for efficient and scalable production of FDCA in the<br />

chemical industry. When HMF was simply oxidized in a concentrated<br />

solution (10 wt %), the FDCA yield was only around 30 %, and a large<br />

amount of solid by-products was formed simultaneously. This is due<br />

to complex side reactions induced from HMF itself.<br />

In the study published in Angewandte Chemie International Edition<br />

[1], a Japan-Netherland research team led by Associate Professor<br />

Kiyotaka Nakajima at Hokkaido University and Professor Emiel<br />

J.M. Hensen at Eindhoven University of Technology succeeded in<br />

suppressing the side reactions and producing FDCA with high yields<br />

from concentrated HMF solutions (10~20 wt %) without by-products<br />

formation. Specifically, they first acetalized HMF with 1,3-propanediol<br />

to protect by-product-inducing formyl groups and then oxidized<br />

HMF-acetal with a supported Au catalyst.<br />

About 80 % of 1,3-propanediol used to protect formyl groups<br />

can be reused for the subsequent reactions. In addition, drastic<br />

improvement in the substrate concentration reduces the amount<br />

of solvents used in the production process. Kiyotaka Nakajima<br />

says “It is significant that our method can reduce the total energy<br />

consumption required for complex work-up processes to isolate the<br />

reaction product.”<br />

“These results represent a significant advance over the current<br />

state of the art, overcoming an inherent limitation of the oxidation of<br />

HMF to an important monomer for biopolymer production. Controlling<br />

the reactivity of formyl group could open the door for the production<br />

of commodity chemicals from sugar-based biomaterials,” says<br />

Kiyotaka Nakajima. This study was conducted jointly with Mitsubishi<br />

Chemical Corporation. MT<br />

[1] Kim M., et al., Aerobic oxidation of HMF-cyclic acetal enables selective FDCA<br />

formation with CEO2-supported Au catalyst, Angewandte Chemie International<br />

Edition, May 14, <strong>2018</strong>. DOI: 10.1002/anie.<strong>2018</strong>05457<br />

www.global.hokudai.ac.jp<br />

Conventional methods produce<br />

by-products making large-scale<br />

FDCA production difficult, while this<br />

new method yields FDCA efficiently<br />

without by-products formation [1].<br />

HO O O<br />

O<br />

PD-HMF<br />

cat. Au-CeO 2<br />

Selectivity: 91 %<br />

(20 wt% concentration)<br />

Acetal protection suppresses byproduct<br />

formation<br />

HO<br />

O<br />

O<br />

FDCA<br />

Byproduct<br />

O<br />

OH<br />

cat. Au-CeO 2<br />

Selectivity: 28 %<br />

(10 wt% concentration)<br />

Major pathway<br />

(10 wt% concentration)<br />

HO O O<br />

HMF<br />

H<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 29


From Science & Research<br />

Compostable polymers are increasingly found in applications<br />

such as packaging, disposable nonwovens and<br />

hygiene products, consumer goods and agricultural<br />

products. A wide variety of compostable polymers have been<br />

developed, derived both from petrochemical and renewable<br />

sources. But, what do we know about how these materials behave<br />

in other environments or conditions outside of industrial<br />

composting facilities?<br />

In <strong>2018</strong>, the European Parliament introduced the new<br />

‘European Strategy for Plastics in a Circular Economy’, in<br />

which the opportunities and risks associated with the growing<br />

use of plastics with biodegradable properties, have also been<br />

acknowledged. In the absence of clear labelling or marking<br />

for consumers and without suitable waste collection and<br />

treatment options, these plastics could aggravate the leakage<br />

of plastics into the environment and cause mechanical<br />

recycling problems. On the other hand, the European Strategy<br />

states that biodegradable plastics can certainly have a role in<br />

some applications, and that innovation efforts in this field are<br />

welcome but that the behaviour and consequences of their<br />

biodegradability must be demonstrated.<br />

This article will present the main findings of a study on<br />

the degree of disintegration of a compostable polymer and<br />

a visual analysis of the material degradation in different<br />

environmental conditions. It will present different tests<br />

carried out under industrial composting conditions, home<br />

compost conditions, composting conditions in a lab-scale test<br />

(aggressive synthetic solid) and in soil (natural environment) at<br />

two different temperatures. Furthermore, the ecotoxicological<br />

effects of the environment after the disintegration process<br />

was evaluated to obtain a full understanding of the behaviour<br />

of these polymers.<br />

The present study revealed that two main aspects determine<br />

the degree of disintegration of a compostable biopolymer<br />

(PLA and PBTA blend): on the one hand, the aggressiveness<br />

of the medium (microbial activity) and on the other hand, the<br />

temperature.<br />

The most aggressive medium, an enriched synthetic solid,<br />

gave rise to average disintegration degrees of 96.09 %, followed<br />

by natural compost of vegetable origin and a normalized soil,<br />

thus reaching disintegration degrees of 87.76 % and 72.05 %<br />

respectively at thermophilic temperature (58 ºC).<br />

By:<br />

Elena Domínguez<br />

Researcher, Sustainability and Industrial Recovery department<br />

AIMPLAS<br />

Paterna, Valencia, Spain<br />

Compostable<br />

plastics’<br />

behaviour in<br />

different<br />

environmental<br />

conditions<br />

Figure 1. Degree of disintegration of the<br />

material tested in different environments and<br />

thermophilic conditions (58 ºC)<br />

Figure 2. Degree of disintegration of the material<br />

tested in different environments and mesophilic<br />

conditions (25 ºC)<br />

58ºC day 7 day 37 day 69 day 90<br />

25ºC day 7 day 90<br />

Synthetic Solid<br />

Synthetic Solid<br />

Normalized<br />

Soil<br />

Normalized<br />

Soil<br />

Compost<br />

Compost<br />

30 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


From Science & Research<br />

At a mesophilic temperature of 25 ºC , the materials did not<br />

achieve degradation in any of the environments studied.<br />

In this study, the ecotoxicological effects were evaluated in a<br />

fast-growing plant species (Ray Grass) from the media where<br />

disintegration had occurred. None of the media in which the<br />

polymeric material had disintegrated produced a toxic effect<br />

on the species in question and the vegetal biomass reached a<br />

germination and growth rate of over 90 % with respect to the<br />

reference substrate.<br />

A limitation in the use of bioplastics is the existing confusion<br />

about the behaviour of materials in different conditions. An<br />

industrially compostable material is not necessarily able to<br />

biodegrade under other temperature conditions or in other<br />

environmental conditions. Currently, there are international<br />

schemes for the certification of biodegradable materials in<br />

different environments that may cause confusion in this sector.<br />

These schemes guarantee to customers the biodegradability<br />

of a material in certain conditions according to international<br />

standards.<br />

In order to enable the correct communication of<br />

biodegradable polymers through product ecolabelling, there<br />

are different standards of biodegradation determination<br />

in different environments (compost, soil, etc.), which have<br />

been used to create certification schemes that specify the<br />

requirements to be met in order to attain the corresponding<br />

certificate and product labelling.<br />

Manufacturers and suppliers in Europe have relied on<br />

the neutral and independent certifications by DIN CERTCO<br />

and TÜV Austria for many years. Certifications from these<br />

agencies send a message to consumers about the quality<br />

of the products and can serve as guidance when making<br />

purchasing decisions.<br />

These independent bodies are able to specify the correct<br />

biodegradation environment for final products thanks to<br />

verification marks.<br />

The most common ecolabel assigned is that of compostability<br />

in industrial facilities (at a temperature of approximately 60 ºC).<br />

The aforementioned bodies grant their own compostability<br />

ecolabels together with European Bioplastics association’s<br />

Seedling compostability mark. Both marks, can be used<br />

individually, alternatively or simultaneously, and document the<br />

biodegradability, among other aspects, of a final product or<br />

material in industrial composting facilities.<br />

A material that is compostable in industrial composting<br />

facilities will not necessarily compost in home composting<br />

conditions, where, among other things, the temperature<br />

is considerably lower (approximately 25 ºC). Different certificates<br />

are obtainable for different conditions and<br />

environments: biodegradable materials and products can<br />

be certified as degradable in soil, saltwater or fresh water.<br />

Any supplier who invests in adding this functionality to their<br />

product or packaging should have the opportunity to have<br />

this information verified according to international standards,<br />

obviously without encouraging consumers to litter.<br />

Biodegradability in the soil offers huge benefits for<br />

agricultural and horticultural products, as they can be left<br />

to break down in situ after being used. In <strong>2018</strong>, standard<br />

EN 17033 [1] was developed, which outlines the requirements<br />

to be met by agricultural mulch films, an application in which<br />

biodegradability in soil entails the end of life of materials, thus<br />

reducing soil contamination due to mismanagement on the<br />

part of humans.<br />

AIMPLAS, the Plastics Technology Centre, based in Spain,<br />

is now in the process of becoming a laboratory recognized by<br />

TÜV Austria, after which it will support the manufacturers in<br />

the verification process required for the different ecolabels,<br />

evaluating the requirements necessary to fulfil each point<br />

of the certification schemes according to international<br />

regulations.<br />

Furthermore, as a quality aspect, Aimplas has a testing<br />

laboratory accredited by ENAC with accreditation no 56/LE156<br />

in conformity with the EN ISO/IEC 17025 standard. Moreover,<br />

Aimplas has the highest number of ENAC accreditations for<br />

plastics according to the ISO 17025 standard at national level.<br />

ENAC accreditations are recognized in over 50 countries,<br />

since it is a signatory of the Mutual Recognition Agreements<br />

arranged at an international level among accreditation bodies<br />

all over the world. These agreements include practically the<br />

whole of the EU, USA, Canada, Japan, China and Australia,<br />

among others.<br />

[1] EN 17033: <strong>2018</strong>. Plastics - Biodegradable mulch films for use in agriculture<br />

and horticulture - Requirements and test methods.<br />

www.aimplas.es<br />

Figure 4. AIMPLAS’ equipment for simulation of<br />

conditions of biodegradation or disintegration<br />

tests.<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 31


Report<br />

GO!PHA<br />

Introduction of the Global Organization for PHA<br />

F<br />

ollowing a successful conclusion of 1 st PHA platform<br />

world congress, in September <strong>2018</strong>, a group of four<br />

experts conceived the idea of establishing a global initiative<br />

to accelerate the development of the PHA-platform<br />

industry by sharing experiences, knowledge and developments,<br />

and by communicating objectively towards policy<br />

development organizations, NGOs, OEMs/Brand Owners,<br />

plastics processors and the general public, and to facilitate<br />

joint development initiatives. The result is GO!PHA, a Global<br />

Organization for PHA, an initiative of Jan Ravenstijn, Rick<br />

Passenier (PACE), Anindya Mukherjee (i2i Consulting) and<br />

Michael Carus (nova-Institut).<br />

Polyhydroxyalkanoate polymers (PHAs) provide a unique<br />

opportunity as a solution for reducing greenhouse gases and<br />

environmental plastics pollution and offer numerous design<br />

opportunities in the new global plastics ecosystem. However,<br />

legislators, brand owners and the common public are largely<br />

unaware of the potential benefits and as of today commercial<br />

success has been limited.<br />

The founding members of Go!PHA believe that significant<br />

effort is needed to highlight and promote the benefits of PHAs<br />

to the global consumer community, OEMs/Brand Owners<br />

and plastics processors on PHA’s durability, sustainability<br />

and its impact on accelerating The Circular Economy via<br />

growing demand for a range of sustainable, high-quality<br />

and competitive products and materials based on renewable<br />

feedstocks and offering diverse end-of-life options.<br />

With this article, Go!PHA is presenting the start and<br />

general outline of the Global Organization for PHA; GO!PHA,<br />

and would like to invite interested stakeholders to share their<br />

feedback and support for this initiative.<br />

The Global Organization for PHA<br />

The Global Organization for PHA will serve the entire<br />

PHA-platform industry and its downstream markets in<br />

demonstrating its benefits and encouraging the development<br />

and commercialization of PHA polymers as new solutions<br />

and as a beneficial alternative to existing petroleum polymers<br />

and plastics, by engaging in three major areas:<br />

• Communication, policy and legislation<br />

Educating key public and private stakeholders about the<br />

benefits of PHA-polymers, by developing objective technical,<br />

environmental and pre-commercial communication.<br />

Advocating legislative and market adoption drivers and<br />

identifying and overcoming barriers for further PHApolymers<br />

adoption, by actively representing the industry<br />

interests in key global and local forums.<br />

• Market proliferation<br />

Improving market perception about the application<br />

development options and multiplying on success, by<br />

showcasing best practices. Creating an informative channel<br />

to present the realm of product and application development<br />

options and to develop objective inter-material replacement<br />

data. Create a forum to allow members to help match market<br />

demand and supply, and application development.<br />

• Technical and scientific knowledge development<br />

Accelerating the implementation of technical and scientific<br />

developments across the industry, by sharing processes,<br />

methods and tools to improve the overall PHA-polymer<br />

competitiveness. Facilitating pre-competitive research and<br />

create a forum for development partnerships on matters of<br />

common interest.<br />

Structure<br />

The Global PHA Organization will be a non-profit<br />

organization, backed by its members, with a lean<br />

management structure. It will have a global scope and the<br />

organization aims to have representation/ambassadors at all<br />

geographic locations. For the daily support, management,<br />

on- and offline representation and ancillary expenses, an<br />

initial annual budget requirement of approximately 300,000<br />

EUR is foreseen.<br />

Engagement<br />

GO!PHA welcomes all parties that want to support and/or<br />

to join efforts in developing, producing and commercializing<br />

PHA polymers, from feedstock to product to end-oflife.<br />

Membership provides access to the global PHA<br />

community, workshops and knowledge sharing, technical<br />

and commercial communication towards public and private<br />

stakeholders, involvement in product assessments and sideby-side<br />

comparisons, case studies and position papers and<br />

concrete project and partnership opportunities.<br />

Membership options and financial contributions will be<br />

based on engagement level, in two brackets:<br />

• General membership fee (discriminating small and<br />

medium sized enterprises, governmental and nongovernmental<br />

organizations and multi-national<br />

companies)<br />

• Project related fees for involvement in particular<br />

programs and projects<br />

Additionally, the organization will propose founding member<br />

contributions for establishing the organization, sponsorship<br />

packages and donations from various stakeholders.<br />

Next steps<br />

The Global Organization for PHA will be shaped in the<br />

coming months with a targeted formal establishment date<br />

in Q1-2019. The team has scheduled the following process:<br />

• December <strong>2018</strong>: gathering feedback on function,<br />

structure and support<br />

32 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Report<br />

Rick Passenier (PACE)<br />

Anindya Mukherjee<br />

(i2i Consulting)<br />

By:<br />

Rick Passenier<br />

PACE<br />

Amsterdam, The Netherlands<br />

• December <strong>2018</strong>-January 2019: formal proposal and request<br />

for support<br />

• February 2019: first-members-meeting to shape the<br />

foundation<br />

• February 2019: formal foundation of the organization.<br />

The founding members kindly ask all interested stakeholders<br />

to provide feedback, ideas, questions and support, before<br />

December 14 th , <strong>2018</strong> to the contacts published at the website<br />

www.gopha.org<br />

Platform activities<br />

Jan Ravenstijn<br />

Michael Carus<br />

(nova-Institut)<br />

External communication<br />

and recommendations<br />

Objective and pre-commercial<br />

data generation<br />

Communication, policy<br />

and legislation<br />

Lobby and influence Clear<br />

and collective voice<br />

Market proliferation<br />

Education<br />

Showcasing<br />

Design tools<br />

Technical & scientific<br />

knowledge development<br />

Exploration<br />

Joint development<br />

Project and partnership<br />

facilitation<br />

nova-Institute Events in <strong>2018</strong>/2019<br />

1 – 2 October <strong>2018</strong> · Maritim Hotel, Cologne, Germany<br />

www.REFAB.info<br />

6 – 8 November <strong>2018</strong> · Messe Stuttgart, Germany<br />

www.composites-europe.com<br />

20 – 21 March 2019 · Maternushaus, Cologne, Germany<br />

www.co2-chemistry.eu<br />

16 th International Conference<br />

of the European Industrial<br />

Hemp Association<br />

June 5 th – 6 th 2019<br />

15-16 May 2019 · Maternushaus, Cologne, Germany<br />

www.bio-based-conference.com<br />

5-6 June 2019 · Maternushaus, Cologne, Germany<br />

www.eiha-conference.org<br />

Contact: Mr. Dominik Vogt, +49 (0) 2233 48 14 49, dominik.vogt@nova-institut.de · All conferences at www.bio-based.eu<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 33


Applications<br />

PLA in the fridge<br />

Electrolux builds the world’s first bioplastic concept refrigerator<br />

By: Michael Thielen<br />

E<br />

arlier this year Electrolux, headquartered in Stockholm,<br />

Sweden, introduced a refrigerator prototype in<br />

which all the visible plastic parts were made of Ingeo<br />

PLA compounds. On the sidelines of the Innovation Takes<br />

Root conference in San Diego, bioplastics MAGAZINE talked<br />

to Marco Garilli, Innovation Expert-Polymers at Electrolux’<br />

Global Connectivity & Technology Center (Porcia, Italy)<br />

Sustainability is a top priority at Electrolux and the<br />

company is recognized as sustainability leader within their<br />

industry of household appliances (Industry Leader in Dow<br />

Jones Sustainability Index for 12 years in a row). Through<br />

their brands, including Electrolux, AEG, Anova, Frigidaire,<br />

Westinghouse and Zanussi, the company sells more than 60<br />

million household and professional products in more than 150<br />

markets every year.<br />

“Sustainability is part of the Electrolux business strategy<br />

and we are dedicated to innovate for more sustainable<br />

products and to reduce our carbon footprint. This (refrigerator)<br />

prototype is unique and helps us deliver on our purpose to<br />

shape living for the better,” said Henrik Sundström, Vice<br />

President Sustainability at Electrolux, in a press release<br />

announcing the product.<br />

According to Marco Garilli, Electrolux has adopted a 360°<br />

approach toward making its full range of appliances more<br />

sustainable. “This includes, for example, the energy and<br />

water consumption of our products,” he explained. “We have<br />

professional dishwashers consuming only 0.4 liters of water<br />

per rack. But it also includes the choice and use of materials,<br />

which are equally valuable resources.”<br />

A fundamental part of Electrolux effort to fulfill its<br />

sustainability ambitions is to offer more sustainable products,<br />

creating better experiences for the consumers as well as<br />

contributing to a better society.<br />

Back in the 1990s, Electrolux had already implemented lifecycle<br />

analysis as a means to assess the environmental impacts<br />

associated with all the stages of a product’s life and this has<br />

become more and more a key step in the development of new<br />

products. This evaluation is not only about the environmental<br />

impact, but also includes how a particular development would<br />

affect the manufacturing processes and the cost structure.<br />

As part of this approach, the company started to explore<br />

which materials could be replaced by other, or new materials:<br />

fossil-based materials, recyclable materials and biobased<br />

materials.<br />

“This also meant that we needed to pick the right partners<br />

and the right moment to enter into specific developments”,<br />

Marco said, “And NatureWorks was such a partner.”<br />

As Electrolux manufactures their own parts in house, they<br />

know the production processes involved. They first needed to<br />

establish whether their manufacturing systems could cope<br />

with any new materials.<br />

For the refrigerators in this case study, Electrolux wanted<br />

to replace the material used to produce the thermoformed<br />

liners (hitherto made from either high-impact polystyrene<br />

HIPS or ABS) and the transparent PS door shelves.<br />

Together with NatureWorks (Minnetonka, Minneapolis, USA)<br />

Ingeo PLA compounds were developed for these applications.<br />

The PLA could be processed without any modifications to<br />

Electrolux’ manufacturing lines. “We found out that the<br />

higher melt strength of PLA compared to HIPS offers further<br />

advantages, such as an improved homogeneity of the wall<br />

thickness of the thermoformed component.” Marco pointed<br />

out. “In addition, the inherent stiffness of PLA provides<br />

additional structural integrity.”<br />

In addition to its biobased origin, PLA offered several<br />

performance advantages over polystyrene (transparent PS<br />

as well as HIPS). The first, said Marco, is the significantly<br />

higher gloss which leads to a more aesthetical appearance.<br />

Furthermore, the chemical resistance, for example, against<br />

food oils and fats, was found to be very good. In terms of<br />

mechanical properties, the PLA also showed a number of<br />

advantages, for example in the enhanced impact properties for<br />

the transparent shelves in the refrigerator doors. Marco: ”We<br />

were surprised that the PLA, which is said to be rather brittle,<br />

performed slightly better than the transparent PS.” Another<br />

advantage of PLA over ABS to be investigated is the resistance<br />

to yellowing (UV resistance). In addition, NatureWorks’ Ingeo<br />

PLA systems do not contain any chemicals of concern.<br />

Electrolux has already committed to materials efficiency<br />

through the use of post-consumer recycled plastics, such<br />

as Carborec ® , a plastic compound based on recycled<br />

polypropylene, extending the lifetime of plastic coming from<br />

non-renewable resources. The bioplastic refrigerator is still in<br />

development and there is currently no timeframe set for when<br />

the product will be officially launched on the market.<br />

However, in the aforementioned press release, Jan<br />

Brockmann, Chief Operations Officer at Electrolux , said: “We<br />

are very excited and proud to have developed the world’s first<br />

bioplastic concept fridge, which is truly groundbreaking. Our<br />

ambition is to develop even more innovative, sustainable home<br />

appliances that we might see on the market in the future”.<br />

www.electroluxgroup.com<br />

(©liz linder photography)<br />

34 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Applications<br />

Industrial Solutions for Polymer Plants<br />

Polylactide Technology<br />

Uhde Inventa Fischer Polycondensation Technologies has expanded its product portfolio to<br />

include the innovative state-of-the-art PLAneo ® process for a sustainable polymer. The<br />

feedstock for our PLA process is lactic acid, which can be produced from local agricultural<br />

products containing starch or sugar. The application range of PLA is similar to that of polymers<br />

based on fossil resources as its physical properties can be tailored to meet packaging, textile<br />

and other requirements. www.uhde-inventa-fischer.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 35


Application AutomotiveNews<br />

Peeling milk with P3HB<br />

In October <strong>2018</strong>, the Czech companies NAFIGATE<br />

Cosmetics and NAFIGATE Corporation launched a<br />

new product - Coconut shower peeling milk, in which<br />

microbeads are replaced with Hydal P3HB. The whole<br />

new cosmetics eco-design concept received the name<br />

Dedicated to You and Nature in order<br />

to express its biodegradability and<br />

biocompatibility. Hence, coconut shower<br />

peeling milk represents a circular<br />

revolution in the cosmetics industry. It<br />

is fully biodegradable, waste-free and<br />

harmless to nature.<br />

Microplastics are solid plastic beads of<br />

less than five millimetres. In cosmetics,<br />

they are used as peeling particles in the form of polyethylene<br />

microbeads of less than one millimetre in their largest<br />

dimension that peel off dead skin cells. Once microbeads<br />

are washed off from skin, they get into water, where they<br />

do not biodegrade. Microbeads can cause plastic water<br />

pollution and be harmful to aquatic life because wastewater<br />

treatment plants cannot capture such small particles.<br />

According to various research studies including the results<br />

of the Institute of Hydrodynamics of the Czech Academy of<br />

Sciences, drinking water also contains microplastics.<br />

P3HB biopolymer is processed by the unique Czech<br />

biotechnology HYDAL, which as the first in the world on<br />

industrial scale uses 100 % waste in the<br />

form of waste cooking oil (WCO). Hydal<br />

P3HB is added in the shower peeling milk<br />

in the form of white particles, replacing the<br />

abrasive function of microbeads. Unlike other<br />

abrasive materials utilized in cosmetics,<br />

biopolymer’s properties, such as sharpness<br />

or size, may be modified. In addition, P3HB<br />

as a pure chemical substance allows meeting<br />

the highest hygienist cosmetics standards.<br />

In contrast to other substances, it dissolves in water<br />

completely. According to the company’s tests, biopolymer<br />

biodegrades in wastewater treatment plant within several<br />

days, in the open environment up to several dozen days. It<br />

does not harm nature and provides a solution to one of the<br />

most serious challenges in the cosmetics industry. MT<br />

www.lagranda.it | www.braskem.com<br />

New bio shoe line<br />

Leading global barefoot footwear company<br />

VIVOBAREFOOT, headquartered in London, UK, recently<br />

announced the launch of its new Bio shoe range featuring<br />

Primus Lite Bio, plant-based performance sneakers.<br />

Designed with outdoor performance in mind, the Bio range is<br />

made from a combination of three innovative bio-based<br />

materials that reduce reliance on petrochemicals<br />

and ultimately create more efficient and sustainable<br />

products. Each shoe in Vivobarefoot’s new line is<br />

nearly 50 % plant-based, making it Vivobarefoot’s<br />

latest stride in their quest to use 90 % sustainable<br />

materials across its entire product range by 2020.<br />

The materials used in new Primus Lite Bio<br />

range are produced by DuPont Tate & Lyle Bio<br />

Products, a joint venture between DuPont, a<br />

global science innovator, and Tate & Lyle, a worldleading<br />

renewable food and industrial ingredients<br />

company. Through the use of these renewable, highperformance<br />

materials, Vivobarefoot is able to make<br />

a significant impact on the planet. Every 50,000 pairs of<br />

shoes produced using these materials, equates to saving<br />

greenhouse gas emissions from 247,948 miles driven by an<br />

average passenger vehicle or reducing CO 2<br />

emissions from<br />

11,286 gallons of gasoline consumed.<br />

“We are trying to make a significant impact through<br />

working with game changing brands like Vivobarefoot who<br />

are committed to producing products with fantastic technical<br />

performance and improved sustainability profiles,” stated<br />

Laurie Kronenberg, global marketing director at DuPont<br />

Tate & Lyle Bio Products. “In working with Vivobarefoot on<br />

optimizing their plant-based content throughout the shoe<br />

using various Sorona PTT fiber and Susterra bio-PDObased<br />

solutions it allowed us to model the environmental<br />

reductions in terms of greenhouse gas emissions and<br />

nonrenewable energy on a raw material basis. Now that is<br />

impactful.”<br />

Seventh-generation shoemakers Galahad and Asher Clark<br />

are firm believers that barefoot shoe-making is sustainable<br />

shoe making. The company has already pioneered shoes<br />

made of repurposed algae (Ultra 3 BLOOM) with<br />

each pair recirculating 215 litres of fresh water<br />

back into the natural habitats, and an Eco range<br />

made of 50 % recycled plastic. In 2017, Vivobarefoot<br />

diverted over 2 million plastic bottles from landfills<br />

into barefoot shoes.<br />

“Sustainability is at the core of Vivobarefoot’s<br />

mission and we believe that the perfect shoe has<br />

minimal interference with natural movement and<br />

minimal impact on the environment,” said Asher<br />

Clark, design director at Vivobarefoot. “The new<br />

Primus Bio line champions the future of sustainable<br />

materials and the new opportunities they bring to the<br />

footwear industry.”<br />

The Vivobarefoot Bio range will include the hero<br />

performance shoes Magna Trail Bio, Primus Trail Bio,<br />

Primus Lite Bio and Ultra Bio shoes. The Primus Lite Bio<br />

shoes for example will be available at www.vivobarefoot.<br />

com/us starting June 2019 and priced from $120 to $160. MT<br />

www.vivobarefoot.com/us<br />

36 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Application News<br />

Clipper tea bags<br />

renewably-sourced<br />

Public outcry about and subsequent resistance to tea<br />

bags made with polypropylene has compelled brand<br />

owners to take action. The latest to do so is Clipper Teas,<br />

the tea brand owned by natural and organic food company<br />

Wessanen, Amsterdam, The Netherlands.<br />

The company announced in April of this year that it had<br />

committed to use only fully biodegradable tea bags by<br />

summer <strong>2018</strong>.<br />

It was a little later than that, but on October 20, the<br />

company said it moved all production to ‘plastic-free,<br />

unbleached and non GM (genetically modified) tea bags’,<br />

adding: “And we won’t be going back!”<br />

There will be a transition period of up to a few months<br />

while retailers sell through current stock, said the<br />

company as “we don’t believe in waste”.<br />

According to Clipper, the polypropylene in the tea bag<br />

paper originally served to heat seal the two layers of<br />

the unbleached tea bag paper together. The company<br />

has now developed an alternative tea bag paper, made<br />

from natural, plant based materials – a blend of abaca<br />

(a species of banana), plant cellulose fibres and a PLA<br />

derived from non-GM plant material that helps hold the<br />

paper together. In the past, while aware of the availability<br />

of this plant-based option, Clipper had never used or<br />

considered using PLA, as the corn used as feedstock in<br />

the PLA made by one major manufacturer could be from<br />

GM sources.<br />

Since the official announcement, other producers have<br />

also entered the market, offering PLA guaranteed to be<br />

from a non-GM source and enabling Clipper to make the<br />

switch to a 100% renewably-sourced tea bag paper. To let<br />

consumers know about the change, an on-pack flash will<br />

be rolling out on specific products from January 2019.<br />

COMPEO<br />

Leading compounding technology<br />

for heat- and shear-sensitive plastics<br />

(Photo: Wessanen)<br />

Clipper is claimed to be the world’s largest buyer of<br />

Fairtrade tea. It exports its products to over 50 countries<br />

worldwide. Its parent company, Wessanen UK, is<br />

CarbonNeutral certified. and either directly or through<br />

its subsidiaries, accredited by or a member of a range of<br />

industry bodies and associations including; the Fairtrade<br />

Foundation; the Soil Association; the UK Tea & Infusions<br />

Association, and the Organic Trade Board.MT<br />

www.wessanen.com<br />

Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />

With its new COMPEO Kneader series, BUSS continues<br />

to offer continuous compounding solutions that set the<br />

standard for heat- and shear-sensitive applications, in all<br />

industries, including for biopolymers.<br />

• Moderate, uniform shear rates<br />

• Extremely low temperature profile<br />

• Efficient injection of liquid components<br />

• Precise temperature control<br />

• High filler loadings<br />

www.busscorp.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 37


Application News<br />

Automotive<br />

Pastille bio-polyamide lamp<br />

Wästberg is a Swedish lighting company from Helsingborg,<br />

that aimed at bringing back light to human proximity.<br />

At Orgatec (October <strong>2018</strong>, Cologne Germany) the company<br />

launched a new lamp series made with bio-polyamide. The<br />

lamp was created in collaboration with Sam Hecht and Kim<br />

Colin of London-based studio Industrial Facility and Berlinbased<br />

designer Dirk Winkel.<br />

The lamp w182, called Pastille<br />

is a minimalist light which can<br />

be described as a pure disc of<br />

light attached to a thin line, a<br />

construction that allows a variety<br />

of surfaces to be illuminated.<br />

Different to task lamps that<br />

illuminate in a focused way; or<br />

table and pendant lamps that<br />

provide ambient light, the w182<br />

pastille family of lights sees<br />

environments as surfaces to<br />

softly illuminate, be it a wall, a<br />

floor or a table.<br />

w182 pastille is made of a highperformance<br />

material. A glassfibre reinforced bio-polyamide<br />

that is based on over 60 % renewably biologically sourced<br />

and recyclable material made from castor oil. Its material<br />

provides warmth and strength, making w182 pastille lighter<br />

and easier to adjust from anywhere on the lamp. At the top<br />

of its vertical pole is a single control button.<br />

But the bio-polymaide provides other benefits, too. There<br />

is no metal to be painted to achieve the desired look. The<br />

plastic is dyed with pigments, no touch-ups are needed over<br />

time. “The other thing we discovered is that the bioplastic<br />

is helping us with dissipating heat–like metal,” Hecht says<br />

at fastcompany.com. “That meant we could reduce the heat<br />

sink, which is taking away the heat from the LED, which<br />

reduces weight and cost.”<br />

The glass-reinforced<br />

bioplastic is also cheaper<br />

than metal, without having to<br />

sacrifice any quality to keep the<br />

price down–the studio estimates<br />

it would cost 50 % more in metal.<br />

“Unfortunately the pressures of<br />

price are so huge that normally<br />

the response is to try and<br />

maintain the typology, whether<br />

it’s a chair or lamp, and just<br />

reduce the quality to match the<br />

price,” Hecht says. “What we’re<br />

trying to do is challenge that and<br />

say surely we can use design<br />

and engineering to create something very beautiful that is<br />

affordable but has some decency to it in its materiality.”MT<br />

www.wastberg.com<br />

source: tinyurl.com/bio-pa-lamp<br />

Biodegradable crisps bags made from eucalyptus<br />

Two Farmers, Sean Mason and Mark Green, from<br />

Herefordshire, UK had the vision of making delicious<br />

hand-cooked potato crisps that<br />

celebrate the true flavours of<br />

Herefordshire, whilst protecting<br />

their beloved countryside with a<br />

100% compostable bag.<br />

The crisp bags are available<br />

in two sizes, 40g making them<br />

perfect for snacking and 150g<br />

which makes them perfect for<br />

sharing… if you want to share… .<br />

Available flavours include Hereford Hop Cheese and Onion,<br />

Salt and Cider Vineger, and Hereford Bullshot which features<br />

a hint of Hereford beef.<br />

The packets are made from cellulose and sustainably<br />

grown eucalyptus trees from managed plantations. This<br />

means that they are 100 % compostable and will compost<br />

in a home-composting environment in a little over 26<br />

weeks! Information whether<br />

the packages are certified<br />

compostable were not<br />

disclosed until bioplastics<br />

MAGAZINE went to print.<br />

The founders wrote on<br />

Facebook: “We are proud to<br />

be producing our new range of<br />

crisps in 100 % compostable<br />

packs, a first we think for the<br />

UK and a big step forward in dealing with our waste issues.<br />

Two Farmers co-founder Sean Mason said on the firm’s<br />

website that “a potato merchant inspired him to protect the<br />

countryside around him”. MT<br />

www.twofarmers.co.uk<br />

38 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Report<br />

Cruise entrepreneur switches<br />

to biobased plastics<br />

Biobased plastics are an essential element for plastic-free holidays<br />

Plastic-free holidays on a cruise ship – this was the<br />

vision that led cruise operator TUI Cruises (Kiel,<br />

Germany) to launch their new plastics reduction<br />

program WASTELESS.<br />

Since its founding, the company has worked continuously<br />

to minimize the amount of plastic waste it generates. For<br />

example, all cabins on board have already been equipped<br />

with glass water carafes that can be filled by guests at any<br />

time using the water dispensers in the corridors. This saves<br />

on disposable plastic bottles. Refillable dispensers for<br />

shampoo and shower gel have been installed in the showers<br />

in the cabins of all the new TUI Cruises ships, representing<br />

a saving of some 380,000 disposable packs a year across<br />

the fleet. Further initiatives include eliminating the plastic<br />

wrapped terrycloth slippers provided to guests for use at<br />

the pool or sauna: instead, these will now be conveniently<br />

tucked into the pockets of the bathrobes, saving 250,000<br />

plastic packages per year. The laundry bag for the collection<br />

of dirty laundry will soon be made of biobased plastic based<br />

on sugar cane and starch, yielding an imminent saving of<br />

about 270,000 petroleum-based plastic bags. The impact in<br />

the catering department will be even more impressive: the<br />

first step will be the conversion of the coffee-to-go cups in<br />

the crew area: the inner coating and lids will in future be<br />

made of biobased plastic and no longer of petroleum-based<br />

plastic.<br />

But how is waste in general - and bioplastics, in particular<br />

- treated on board cruise ships? bioplastics MAGAZINE spoke<br />

with Friederike Grönemeyer, Communications Manager<br />

of TUI-Cruises. “We relieve our passengers of the task<br />

of separating waste,” said Friederike. “All garbage is<br />

separated centrally in our garbage room and disposed of<br />

responsibly.” She explained that glass is crushed, cans<br />

and paper are pressed and prepared for disposal on land.<br />

Organic (food) waste is crushed in a so-called pulper, dried<br />

and also composted on land or, diluted with water, disposed<br />

of outside the 12-mile zone in the sea. Some packaging<br />

waste is prepared for recycling or is incinerated clean and<br />

with energy recovery on board in an appropriate energy<br />

plant.<br />

Disposal ashore takes place not only in the home port of<br />

Kiel, but also in larger port cities around the world. “We<br />

make sure we have the right responsible partners there,”<br />

she emphasised. There is always an environmental officer<br />

on board for all these tasks.<br />

“All in all, we achieve an overall recycling rate of 31%,”<br />

says Friederike Grönemeyer.<br />

By the end of 2020, plastic products and non-essential<br />

disposable items will have been phased out and replaced<br />

by renewably-sourced sustainable alternatives, both aboard<br />

the current six ships of the Mein Schiff fleet and on land.<br />

www.tuicruises.com<br />

Info<br />

See a video-clip<br />

(German language) at:<br />

tinyurl.com/tui-wasteless<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 39


40 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Brand Owner<br />

Brand-Owner’s perspective<br />

on bioplastics and how to unleash<br />

its full potential<br />

“We believe the time is now to step up and accelerate, embrace our<br />

responsibility and work with others to engage a radical shift that will help free<br />

the world from packaging waste. We will be acting both at global and local<br />

level to ensure circularity of packaging becomes the new norm. (Today), we are<br />

announcing a series of investments and commitments that – I believe – will have<br />

a concrete impact. These will be amplified as we collaborate with industry-peers,<br />

governments, NGOs, start-ups and the finance sector; harness new technologies<br />

and invest in new solutions.”<br />

And, from a press release: Danone commits to ensure that all its packaging is<br />

designed to be 100 % recyclable, reusable or compostable by 2025. Already 86 %<br />

of our packaging is recyclable, reusable or compostable.<br />

In parallel, we will develop the use of renewable, biobased materials. We have<br />

a joint project with Nestle, PepsiCo and Origin Materials to bring the first 75 %<br />

biobased bottle to commercial scale by 2021, aiming to launch 100 % biobased<br />

bottles by 2025. Find the complete press release at: tinyurl.com/danone<strong>2018</strong><br />

www.danone.com<br />

Emmanuel Faber, Chairman and CEO of Danone<br />

(Photo: creative commons swaf75)<br />

Are you looking for a bio-based food<br />

packaging alternative?<br />

Bio-based multilayer transparent barrier films are now reality. Our masterbatches can<br />

help introduce PLA into your portfolio. Make the switch today.<br />

www.sukano.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 41


From Science & Research<br />

How to<br />

calculate land<br />

use accurately<br />

A sensitivity approach<br />

By:<br />

Christian Schulz, Research associate<br />

Hans-Josef Endres, Head of the institute<br />

Hochschule Hannover,<br />

IfBB – Institute for Bioplastics and Biocomposites<br />

Hannover, Germany<br />

Satisfying (growing) human needs requires efficient use of<br />

limited economic resources. This also applies to the discussion<br />

about the use of available agricultural land, which in<br />

particular bioplastics has increasingly had to face in recent years.<br />

Previous estimates by IfBB - Institute for Bioplastics and Biocomposites,<br />

Hannover, Germany, have already shown that the impact<br />

of producing new generation bioplastics (New Economy such as<br />

PLA, Bio-PE, etc.) based on agricultural raw materials, such as<br />

starch, sugar and vegetable oil, is currently marginal at around<br />

0.05 % in 2017 and probably 0.07 % in 2022 in terms of land use<br />

compared to the global amount of arable land.<br />

Figure 1 shows the development of the global production<br />

capacity of the New Economy bioplastics industry, which currently<br />

stands at around 2.3 million tonnes per year. In comparison, the<br />

amounts of Old Economy bioplastics, such as natural rubber (e.g.<br />

for tires), cellulosics (esp. for non-degradable cigarette filters and<br />

textiles) and linoleum with a total of 17 million tonnes per year<br />

are much larger. Comparing previous land area estimates for both<br />

industries, it can be seen that the production capacity of the Old<br />

Economy is only 7 to 8 times higher than that of the New Economy,<br />

but the supply of raw materials for the Old Economy with a total<br />

of 15 million hectares needs more than 20 times the land area<br />

compared to the New Economy. (Old Economy is not subject of the<br />

considerations, as these bioplastics have been used for more than<br />

100 years and in addition go into applications that are very different<br />

from those of the New Economy).<br />

Despite these differences in size – both being easily marginalized<br />

when comparing to the land use of pastures for grazing of<br />

livestock at 3.5 billion hectares (FAO <strong>2018</strong>) –, plastics from the<br />

New Economy yet had to face up to the question of land use. As<br />

previous assumptions to calculate land use for biobased plastics<br />

in the New Economy have always been estimates made with high<br />

safety factors and using a conservative approach, the following<br />

considerations should indicate which factors are relevant for land<br />

use estimation, how these can be made more realistic and how it<br />

affects the already marginal share of global arable land.<br />

In order to find sensitivities and to compare variations in<br />

results for land use of bioplastics, one needs to know how it<br />

basically was calculated before. This approach has been used as<br />

standard method for European Bioplastics’ annual statistic update<br />

until 2017 and is adapted in this year with more specific data of<br />

bioplastics producers, missing until now in the estimates.<br />

Based on process data from literature, experts and own<br />

calculations, Figure 2 shows a sample process route showing<br />

the manufacturing steps involved from the raw material to<br />

the finished product, specifying the individual process steps,<br />

intermediate products, and input-output streams. PLA is used<br />

here as an example, as it is one of the most important New<br />

Economy bioplastics. This is only one representative of all other<br />

New Economy bioplastics, to which this approach is applied –<br />

each with its own process route.<br />

Production capacities and land use<br />

Old and New Economy bioplastics<br />

Figure 1<br />

New Economy bioplastics global production capacities<br />

12 000 000<br />

Natural rubber<br />

56 000<br />

Linoleum 3<br />

5 000<br />

4 000<br />

4 305<br />

1 740<br />

672 000<br />

New Economy bioplastics 1<br />

2 900 000<br />

Cellulose 2<br />

10 978 000<br />

Natural rubber<br />

140 000<br />

Linoleum 3<br />

in 1 000 t<br />

3 000<br />

2 000<br />

1 000<br />

0<br />

2 028<br />

1 697<br />

737<br />

663<br />

1 034 1 291<br />

2014 2015<br />

2 048<br />

757<br />

1 291<br />

2016<br />

2 274<br />

881<br />

1 393<br />

2017<br />

Forecast<br />

2 565<br />

2022<br />

2 273 000<br />

New Economy bioplastics 1<br />

5 800 000<br />

Cellulose 2<br />

1 PLA, PHA, PTT, PBAT, Starch blends, Drop-Ins (Bio-PE, Bio-PET, Bio-PA) and other<br />

2 Material use excl. paper industry<br />

3 Calculations include linseed oil only<br />

Bio-based/non-biodegradable<br />

Biodegradable<br />

Total capacity<br />

Biopolymers, facts and statistics <strong>2018</strong> – 41<br />

42 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


From Science & Research<br />

To obtain land use data from production capacities in this<br />

bottom-up approach (see Table 1), it needs producer-specific<br />

production capacities of a type of bioplastics to be multiplied by<br />

the output data of the corresponding process routes. If producerspecific<br />

feedstock was known, it was taken into consideration.<br />

In other cases, where these data were missing, only the most<br />

common used crop per material was taken into consideration (e.g.<br />

corn starch for PLA).<br />

For the basic assumptions referring to PLA, previous estimates<br />

of IfBB resulted in a need of 0.37 hectares land for feedstock<br />

cultivation per tonne of material. This is a corn-based, PLAspecific<br />

global average land use factor, for which the following<br />

calculation impact factors (CIF) are assumed.<br />

One obvious impact factor on land use of bioplastics might be<br />

the production capacity itself. According to own research, total<br />

annual installed capacity for PLA worldwide in 2017 was roughly<br />

240,000 tonnes, which gives 88,300 hectares according to the<br />

basic assumptions. However, is relying on the installed capacity<br />

correct? Very few industrial plants run at full degree of capacity<br />

continuously, so an optimistic sensitivity would be 85 % degree of<br />

capacity.<br />

Another impact factor is the region specific yield of a feedstock<br />

in different countries. While for the basic estimation for PLA made<br />

out of corn, a global average yield of 6.5 tonnes of corn per hectare<br />

over the past decade (weighted by production amount) (FAO <strong>2018</strong>),<br />

corn being grown in the United States in the same period would<br />

yield in 9.5 tonnes per hectare and the same acreage in China<br />

delivered 40 % less of corn (5.5 t / ha). This is even more important,<br />

as corn from USA makes up to 37 % of world’s corn production,<br />

but China, with its significantly lower yield per hectare still ranks at<br />

an important one fifth (20 %) of global corn production. Therefore it<br />

has a decreasing effect on the global average corn yield (6.5 t / ha).<br />

Further impacts derive from natural harvesting fluctuation.<br />

Using single year data leads to tremendous deviation in calculating<br />

PLA land use. Comparing available corn yields between 2002<br />

and 2013 for e.g. corn in the USA shows, that there is a deviation<br />

between minimum and maximum of 3.2 tonnes per hectare<br />

(Average yield: 9.1 t / ha). By using either minimum or maximum<br />

yield data of a given period for calculation will result in this case in<br />

a fluctuation of land use of +43 % or -30 %.<br />

But even when looking at a global average yield for corn, the<br />

choice of a certain decade leads to different results. Using a global<br />

average yield over a mid-term period (10 years) helps to minimize<br />

natural harvesting fluctuation while at the same time provides<br />

data, which are not influenced by single local yield deviations.<br />

When comparing two different time periods (2002 – 2011 and 2003<br />

– 2014), the worldwide general increase in harvesting yields of<br />

corn raised by 2.5 %. For other (food) crops relevant in bioplastics<br />

production, the increase is at the same level or even higher, e.g.<br />

sugar beet (+ 5.9 %), sugar cane (+ 1.9 %) and castor oil (+ 17.1 %).<br />

Advances in crop growing techniques and better feedstock yields<br />

result in a lower land use, which decreases to the same extent<br />

for each bioplastic material. Even without changes in bioplastics<br />

technology (1st, 2nd, 3rd generation), future land use per tonne of<br />

bioplastic material will de facto decrease.<br />

Additional impact factors could arise from the source of<br />

feedstock (e.g. PLA made from sugar cane versus corn starch)<br />

and allocation assumptions. Allocation is in detail also a very<br />

complex topic and would go beyond the scope of this comparison<br />

as there are different factors itself, which can be used. In general,<br />

this would be mass-balanced, energy-balanced or economicbalanced<br />

allocation. In this case, if using residues is being taken<br />

into account, the bioplastic material will only be burdened with<br />

parts of the full impact of its land use. To make a proposal, the<br />

results will cover 30 % use of residues.<br />

Stepping back from the different impact factors and having a<br />

look at the resulting effects on land use of PLA Figure 3 shows<br />

the impact for the recent global capacity of about 240,000 tonnes<br />

for PLA.<br />

If all raw material was from one country (USA), depending on<br />

different yields per year, this amount of PLA land use ranges from<br />

nearly 80,000 up to almost 115,000 hectares. And even using a<br />

global average yield can still cause slight variations, depending<br />

on which time horizon is assumed (± 2,600 hectares). Last<br />

comparison in Figure 3 shows the influence of locally produced<br />

feedstock as displayed here for Chinese and US-American corn,<br />

resulting in a difference of nearly 43,000 hectares.<br />

Figure 4 compares further impact factors concerning a<br />

more realistic degree of plant capacity being used or an overall<br />

Yield [ t PLA/ha]<br />

6<br />

4<br />

2<br />

0<br />

Figure 3 Figure 4<br />

2.7<br />

Land use for PLA derived from corn<br />

Comparing effects of different feedstock impact factors<br />

240,000 t PLA (2017)<br />

2.1<br />

3.0<br />

114,500 ha<br />

88,300 ha 80,000 ha<br />

Base calculation Local harvest<br />

fluctuation (USA)<br />

2.7 2.8<br />

88,300 ha<br />

Time horizon<br />

Global average<br />

2.3<br />

3.9<br />

104,300 ha<br />

USA vs. China<br />

Global / regional<br />

higher is better<br />

85,700 ha 61,500 ha<br />

Base<br />

Low<br />

High<br />

Yield [ t PLA/ha]<br />

8<br />

6<br />

4<br />

2<br />

0<br />

Land use for PLA derived from corn<br />

Comparing effects of various impact factors<br />

2.7 2.7<br />

Base calculation Prod. capacity<br />

85 %<br />

240,000 t PLA (2017)<br />

88,300 ha 75,000 ha 61,500 ha 38,100 ha<br />

3.9<br />

Allocation<br />

overall 30 %<br />

6.3<br />

Source of<br />

feedstock<br />

higher is better<br />

Base<br />

Variations<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 43


From Science & Research<br />

allocation of 30 % and shows land use ranges for PLA capacity<br />

in 2017 from 75,000 hectares down to 38,000 hectares, if another<br />

source of feedstock (sugar cane) would be used.<br />

Summarizing, having single changes in fluctuations and raw<br />

material yield assumptions by each, results in a range between<br />

38,000 and almost 115,000 hectares of land, which is necessary to<br />

produce exactly the same amount of PLA.<br />

Looking at different approaches to feedstock yield and how<br />

it affects land use calculation of recent PLA capacities, there is<br />

a tremendous variation in results to be found. By the means of<br />

feedstock yields, land use ranges from -30 % to +30 % and using<br />

another feedstock source varies results up to -57 % compared to<br />

the base calculation.<br />

Thus, results of land use calculations can range as high as the<br />

amount and range of possible impact factors. This is to be kept in<br />

mind, if not only one but two or more impact factors at the same<br />

time are applied, which will multiply and lead to further increased<br />

ranges. Accumulating all ‘best case’ factors in this scenario would<br />

correspond to a theoretical land use of 25,000 hectares of PLA (-76<br />

% against base calculation).<br />

Now, how do we calculate accurately? Concerning deviations<br />

in results due to differing impact factors and also keeping in<br />

mind, that there is no ‚common sense‘ cut-off-rule for renewable<br />

feedstocks (not even in life cycle assessments), there is still more<br />

work needed on this topic. The shown examples could help to<br />

assess land use of bioplastics in a more realistic approach but as<br />

all data gathered by IfBB is openly accessible, further adaptations<br />

to the calculation of land use can be made individually, if needed.<br />

At this point, it should be mentioned that, despite the negligible<br />

amount of land use, even without a more realistic approach of<br />

calculation, there is no reason for the industry to rest on it. The<br />

pressure on agricultural land in the coming decades due to the<br />

growing world population, the loss and erosion of cultivated land<br />

will increase, and thus bioplastics will not be able to escape<br />

discussion.<br />

But there is a major advantage here: The development of<br />

bioprocessing technology increases the possibility of large-scale<br />

use of alternative renewable raw materials, which can be grown<br />

on barren soils, as well as arising new building blocks and the<br />

decomposition of organic waste streams as the starting point for<br />

the (re-)synthesis of biobased polymers is a foreseeable future.<br />

However, the primary goal for all biobased plastics, as well as<br />

for the plastics industry as a whole, should be to create intelligent<br />

material cycles and to achieve higher recycling rates. If the need<br />

for virgin material was to be reduced effectively, fewer resources<br />

would be needed to keep the plastic circle rolling. Saving raw<br />

materials could also be a way to keep the land use impact of<br />

bioplastics on a low level, when the emerging trend steadies or<br />

increases in the near future, to produce larger quantities of usually<br />

petro-based plastics from now available biobased building blocks<br />

(drop-ins).<br />

More information can be found in IfBB’s annualy updated<br />

publication of Biopolymers. Facts and statistics. It can be<br />

downloaded for free at: bit.ly/factsandstatistics<br />

www.ifbb-hannover.de<br />

Table 1<br />

Material group Producer To tal annual<br />

capacity<br />

[t]<br />

Calculations<br />

PLA<br />

A<br />

B<br />

C<br />

Land use<br />

factor<br />

[ha / t]<br />

Multiplication<br />

Equals<br />

To tal annual<br />

land use<br />

[ha]<br />

240,000 0.368 88,300<br />

Figure 2<br />

Sample process route<br />

select desired feedstock/crop, i.e.<br />

sugar cane or sugar beet<br />

land use for 1 t of<br />

resulting polymer<br />

feedstock/crop<br />

0.09 ha<br />

1 387 m³<br />

Sugar<br />

cane<br />

6.62 t<br />

or<br />

0.09 ha<br />

711 m³<br />

Sugar<br />

beet<br />

5.37 t<br />

water usage for<br />

feedstock/crop amount<br />

raw material<br />

Sugar<br />

0.86 t<br />

(chemical) process<br />

process inputs<br />

H2O<br />

Microorg.<br />

Fermentation<br />

CO2<br />

Filtration<br />

H2O<br />

Microbial<br />

mass<br />

intermediate product<br />

resource has<br />

petro-based origin<br />

1,4-BDO<br />

0.52 t<br />

Succinic<br />

acid *<br />

0.69 t<br />

Esterification<br />

Polycondensation<br />

H2O<br />

0.10 t<br />

H2O<br />

0.10 t<br />

process outputs<br />

PBS<br />

bb SCA<br />

1.00 t<br />

resulting polymer<br />

44 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Automotive<br />

10<br />

Published in<br />

bioplastics MAGAZINE<br />

Years ago<br />

In November <strong>2018</strong>,<br />

Marco Jansen, Commercial<br />

Director Renewable<br />

Chemicals Europe & North<br />

America of Braskem says:<br />

We remain committed to<br />

develop biobased solutions<br />

to offer more sustainable<br />

products for our clients. Earlier<br />

this year we announced<br />

investment into a demo<br />

plant for biobased MEG,<br />

opening a 2 nd biotech lab in<br />

Boston as well as launching<br />

the world’s first biobased<br />

EVA. Biobased Polypropylene<br />

is not yet launched but<br />

remains one of our potential<br />

future sustainable solutions.<br />

tinyurl.com/2008-biopp


Basics<br />

Glossary 4.2 last update issue 02/2016<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM <strong>06</strong>/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which – having<br />

a higher growth yield than 1 st and 2 nd generation<br />

feedstock – were given their own category.<br />

It also relates to bioplastics from waste<br />

streams such as CO 2<br />

or methane [bM 02/16]<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM 02/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM <strong>06</strong>/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM 05/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →Vinçotte who both base<br />

their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM 01/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/<strong>06</strong>, bM 01/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

46 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM 01/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM 01/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic<br />

acids. The most important cellulose esters<br />

from a technical point of view are cellulose<br />

acetate (CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose<br />

butyrate (CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM <strong>06</strong>/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/<strong>06</strong>, bM 01/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 47


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]. If GM crops are used in bioplastics<br />

production, the multiple-stage processing<br />

and the high heat used to create the<br />

polymer removes all traces of genetic material.<br />

This means that the final bioplastics product<br />

contains no genetic traces. The resulting<br />

bioplastics is therefore well suited to use in<br />

food packaging as it contains no genetically<br />

modified material and cannot interact with<br />

the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5<br />

furandicarboxylic acid (FDCA), produced as an<br />

intermediate when 5-HMF is oxidised. FDCA<br />

is used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14, 02/16]<br />

Home composting | →composting [bM <strong>06</strong>/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established<br />

process with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The<br />

criteria for industrial compostability of packaging<br />

have been defined in the EN 13432. Materials<br />

and products complying with this standard<br />

can be certified and subsequently labelled<br />

accordingly [1,7] [bM <strong>06</strong>/08, 02/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.01 percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, 01/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM 01/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.[bM 02/16]<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, 05/14, 01/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM 01/09, 05/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM <strong>06</strong>/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM 05/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

48 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM 01/09, 01/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM 01/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → Vinçotte. Bioplastics<br />

products carrying the Seedling fulfil the<br />

criteria laid down in the EN 13432 regarding<br />

industrial compostability. [bM 01/<strong>06</strong>, 02/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM 05/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2012<br />

[2] ISO 14<strong>06</strong>7. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2010<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2011<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2012<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14<strong>06</strong>4 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 20<strong>06</strong><br />

[10] Terrachoice, 2010, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2012<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 2005<br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> <strong>06</strong>/2009<br />

[15] ISO 14<strong>06</strong>7 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14021 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 49


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

bioplastics.starch@agrana.com<br />

www.agrana.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2716865<br />

Mob: +86 1869940<strong>06</strong>76<br />

maxirong@lanshantunhe.com<br />

http://www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 51<strong>06</strong>63<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.kingfa.com<br />

39 mm<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41<strong>06</strong>6 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-9995<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

Gianeco S.r.l.<br />

Via Magenta 57 10128 Torino - Italy<br />

Tel.+390119370420<br />

info@gianeco.com<br />

www.gianeco.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 519<strong>06</strong>21<br />

Fax.: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh<strong>06</strong>12@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

1.2 compounds<br />

Cardia Bioplastics<br />

Suite 6, 205-211 Forster Rd<br />

Mt. Waverley, VIC, 3149 Australia<br />

Tel. +61 3 85666800<br />

info@cardiabioplastics.com<br />

www.cardiabioplastics.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36<strong>06</strong>5 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

Natureplast – Biopolynov<br />

11 rue François Arago<br />

14123 IFS<br />

Tel: +33 (0)2 31 83 50 87<br />

www.natureplast.eu<br />

50 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


Suppliers Guide<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7<strong>06</strong>2/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TIPA-Corp. Ltd<br />

Hanagar 3 Hod<br />

Hasharon 45013<strong>06</strong>, ISRAEL<br />

P.O BOX 7132<br />

Tel: +972-9-779-6000<br />

Fax: +972 -9-7715828<br />

www.tipa-corp.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

Total Corbion PLA bv<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

Fax.: +31 183 695 604<br />

www.total-corbion.com<br />

pla@total-corbion.com<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 masterbatches<br />

4. Bioplastics products<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

1.4 starch-based bioplastics<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Bio4Pack GmbH<br />

D-48419 Rheine, Germany<br />

Tel.: +49 (0) 5975 955 94 57<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

6.2 Laboratory Equipment<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Albrecht Dinkelaker<br />

Polymer and Product Development<br />

Blumenweg 2<br />

79669 Zell im Wiesental, Germany<br />

Tel.:+49 (0) 7625 91 84 58<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

2. Additives/Secondary raw materials<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6155<br />

Fax: +81-54-623-8623<br />

info_fds@saidagroup.jp<br />

www.saidagroup.jp/fds_en/<br />

7. Plant engineering<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

1.5 PHA<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />

45, 0,90, 0<br />

10, 0, 80,0<br />

(ICBP) C, M, Y, KSDN BHD<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

0, 0, 0, 0<br />

12, Jalan i-Park SAC 3<br />

Senai Airport City<br />

81400 Senai, Johor, Malaysia<br />

Tel. +60 7 5959 159<br />

marketing@icbp.com.my<br />

www.icbp.com.my<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 51


Suppliers Guide<br />

9. Services<br />

‘Basics‘ book<br />

on bioplastics<br />

110 pages full<br />

color, paperback<br />

ISBN 978-3-<br />

9814981-1-0:<br />

Bioplastics<br />

ISBN 978-3-<br />

9814981-2-7:<br />

Biokunststoffe<br />

2. überarbeitete<br />

Auflage<br />

This book, created and published by Polymedia<br />

Publisher, maker of bioplastics MAGAZINE<br />

is available in English and German language<br />

(German now in the second, revised edition).<br />

The book is intended to offer a rapid and uncomplicated<br />

introduction into the subject of bioplastics, and is aimed at all<br />

interested readers, in particular those who have not yet had<br />

the opportunity to dig deeply into the subject, such as students<br />

or those just joining this industry, and lay readers. It gives<br />

an introduction to plastics and bioplastics, explains which<br />

renewable resources can be used to produce bioplastics,<br />

what types of bioplastic exist, and which ones are already on<br />

the market. Further aspects, such as market development,<br />

the agricultural land required, and waste disposal, are also<br />

examined.<br />

An extensive index allows the reader to find specific aspects<br />

quickly, and is complemented by a comprehensive literature<br />

list and a guide to sources of additional information on the<br />

Internet.<br />

The author Michael Thielen is editor and publisher<br />

bioplastics MAGAZINE. He is a qualified machinery design<br />

engineer with a degree in plastics technology from the RWTH<br />

University in Aachen. He has written several books on the<br />

subject of blow-moulding technology and disseminated his<br />

knowledge of plastics in numerous presentations, seminars,<br />

guest lectures and teaching assignments.<br />

Order now for € 18.65 or US-$ 25.00<br />

(+ VAT where applicable, plus shipping and handling,<br />

ask for details) order at www.bioplasticsmagazine.de/<br />

books, by phone +49 2161 6884463 or by e-mail<br />

books@bioplasticsmagazine.com<br />

Or subscribe and get it as a free gift<br />

(see page 53 for details, outside Germany only)<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

9. Services (continued)<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62831<br />

silvia.kliem@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

10.3 Other Institutions<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

www.greenseredipity.nl<br />

52 bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13


... is read in 92 countries<br />

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05 | <strong>2018</strong><br />

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ICBP Bio Resin: Making a Difference | 23<br />

ISSN 1862-5258<br />

Nov / Dec<br />

<strong>06</strong> | <strong>2018</strong><br />

Event<br />

Calendar<br />

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Spritzgießkurs Bioplastics (German language only)<br />

12.09.<strong>2018</strong> - 27.11.<strong>2018</strong> - *** versch. Orte in Deutschland<br />

http://www.bioplasticsmagazine.de/download/Spritzgiesskurs.pdf<br />

13th European Bioplastics Conference<br />

04.12.<strong>2018</strong> - 05.12.<strong>2018</strong> - Berlin, Germany<br />

www.european-bioplastics.org/events/eubp-conference/<br />

22.04.<strong>2018</strong> - Geleen, Niederlande<br />

European Biopolymer Summit 2019<br />

13.02.2019 - 14.02.2019 - Ghent, Belgium<br />

http://www.wplgroup.com/aci/event/biopolymer-conference-europe/<br />

13th Bioplastics Market<br />

12.03.2019 - 13.03.2019 - Bangkok, Thailand<br />

www.cmtevents.com/main.aspx?ev=190310&pu=276943<br />

7th Conference on Carbon Dioxide as Feedstock for<br />

Fuels, Chemistry and Polymers<br />

20.03.2019 - 21.03.2019 - Cologne, Germany<br />

http://co2-chemistry.eu<br />

bio!TOY: biobased materials for toy applications<br />

27.-28.05.2019 - Nürnberg, Germany<br />

www.bio-toy.info<br />

ISSN 1862-5258<br />

Amir bin Abul Hasan Ashari<br />

Managing Director, ICBP<br />

Compostable<br />

sanitary napkin<br />

project wins<br />

13th Global<br />

Bioplastics Award<br />

| 10<br />

Chinaplas 2019<br />

21.05.2019 - 24.05.2019 - Guangzhou, China<br />

http://adsale.hk/1935-CPS19_Bioplastics_EN_500x150<br />

bio!PAC: Conference on biobased packaging<br />

28.-29.05.2019 - Düsseldorf, Germany<br />

www.bio-pac.info<br />

bioplastics MAGAZINE Vol. 13<br />

Highlights<br />

Fibres, Textiles | 24<br />

Elastomers | 38<br />

Basics<br />

Industrial Composting | 43<br />

bioplastics MAGAZINE Vol. 13<br />

Highlights<br />

Bioplastics from waste streams | 20<br />

Films, flexibles, bags | 12<br />

Plastics beyond Petroleum - BioMass & Recycling<br />

25.<strong>06</strong>.2019 - 27.<strong>06</strong>.2019 - New York City Area, USA<br />

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bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 53


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Aakar Innovations 10<br />

Adidas 23<br />

Adsale 40<br />

Agrana Starch Bioplastics 50<br />

Algix 22<br />

AlgoteK 23<br />

Altra Running 23<br />

API 50<br />

BASF 13, 14 50<br />

BeoPlast Besgen 51<br />

Berry Global 27<br />

Billabong 23<br />

Bio4Pack 8 51<br />

BioBlo 11<br />

Bio-Fed Branch of Akro-Plastic 5, 50<br />

Biome Bioplastic 9<br />

Bio-On 6 51<br />

Bioseries 11<br />

Biota 23<br />

Biotec 51<br />

Bloom 23<br />

BOGS 23<br />

BPI 52<br />

Braskem 5, 11, 13, 45 17<br />

Buss 37, 51<br />

Caprowachs, Albrecht Dinkelaker 51<br />

Cardia Bioplastics 50<br />

Centexbel 28<br />

Chinaplas 40<br />

Chippewah 23<br />

Clariant 8<br />

Clark's 23<br />

D.S. Fibres 28<br />

Danimer Scientific 27<br />

Danone 41<br />

DVSI 11<br />

DIN Certco 31<br />

Dr. Heinz Gupta Verlag 25<br />

DuPont 6<br />

EcoAlf 23<br />

Eindhoven Univ. of Tech. 29<br />

eKoala 11<br />

Electrolux 34<br />

Erema 7, 51<br />

European Bioplastics 8, 9, 22, 40 48<br />

European Bioplastics 7, 10, 13 52<br />

Fachagentur Nachwachsende Rohstoffe 18<br />

FKuR 11, 13 2, 50<br />

Fraunhofer UMSICHT 52<br />

Futamura 12<br />

Gen3Bio 22<br />

Gianeco 50<br />

Global Biopolymers 50<br />

GRABIO Greentech Corporation 51<br />

Grafe 50, 51<br />

Green Dot Bioplastics 50<br />

Green Serendipity 13 52<br />

Heijmans 24<br />

Hokkaido Univ. 29<br />

Indochine Bio Plastiques 51<br />

Industrial Facility 38<br />

Infiana Germany 51<br />

Inst. f. Bioplastics & Biocomposites 42 52<br />

Institut f. Kunststofftechnik, Stuttgart 52<br />

Johnson-Bryce 27<br />

Joma 9<br />

Kaneka 51<br />

Kingfa 50<br />

Knoten Weimar 18<br />

Lego 11<br />

Mars 25<br />

Michigan State University 52<br />

Microtec 50<br />

Minima Technology 51<br />

Nafigate 20, 36<br />

narocon InnovationConsulting 11, 13 52<br />

Natureplast-Biopolynov 50<br />

NatureWorks 26, 34<br />

Natur-Tec 51<br />

Neste 8<br />

NNFCC 9<br />

nova-Institute 11, 32 16, 32, 51<br />

Novamont 5, 13 51, 56<br />

Nurel 50<br />

Omega Material Science 22<br />

Omya 26<br />

Pace 32<br />

PepsiCo 27<br />

plasticker 6<br />

polymediaconsult 52<br />

PTT MCC Biochem 50<br />

Red Wings 23<br />

Rodenburg 24<br />

Saida 51<br />

Sintex 28<br />

Slater Design 23<br />

Soala 23<br />

Sukano 41, 50<br />

Surftec 23<br />

Sustainable Packaging Coalition 27<br />

Symphony Environmental 9<br />

Tecnaro 11 51<br />

TenTree 23<br />

The National Algae Association 22<br />

thyssenkrupp 8<br />

TianAn Biopolymer 51<br />

TIPA 51<br />

Tom's 23<br />

Total Corbion PLA 51<br />

TU Chemnitz 18<br />

TUI Cruises 39<br />

TÜV Austria 31<br />

Two Farmers 38<br />

Uhde-Inventa Fischer 8 35, 51<br />

Unilever 6<br />

Univ. Stuttgart (IKT) 52<br />

Vovobarefoot 23, 36<br />

Wageningen ATO 24<br />

Wästberg 38<br />

Wessanen 37<br />

Xinjiang Blue Ridge Tunhe Polyester 50<br />

Yünsa 28<br />

Zeijiang Hisun Biomaterials 21, 51<br />

Zhejiang Hangzhou Xinfu 50<br />

<strong>Issue</strong><br />

Editorial Planner<br />

Month<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

2019<br />

Edit. Focus 1 Edit. Focus 2 Basics<br />

01/2019 Jan/Feb 04 Feb 19 23 Dez 18 Automotive Foams Green public procurement<br />

(update)<br />

Trade-Fair<br />

Specials<br />

Subject to changes<br />

02/2019 Mar/Apr 08 Apr 19 08 Mrz 19 Thermoforming /<br />

Rigid Packaging<br />

Building &<br />

construction<br />

Bioplastics in packaging<br />

(update)<br />

Chinaplas Preview<br />

03/2019 May/Jun 03 Jun 19 03 May 19 Injection moulding Toys Microplastics Chinaplas Review<br />

04/2019 Jul/Aug 05 Aug 19 05 Jul 19 Blow Moulding Biocomposites incl.<br />

thermoset<br />

Home composting<br />

05/2019 Sep/Oct 07 Oct 19 <strong>06</strong> Sep 19 Fiber / Textile /<br />

Nonwoven<br />

Barrier materials<br />

Land use for bioplastics<br />

(update)<br />

K‘2019 Preview<br />

<strong>06</strong>/2019 Nov/Dec 02 Dez 19 01 Nov 19 Films/Flexibles/<br />

Bags<br />

Consumer & office<br />

electronics<br />

Multilayer films<br />

K‘2019 Review<br />

54 bioplastics MAGAZINE [05/18] Vol. 13


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COME TO VISIT US AT<br />

4 • 5 december <strong>2018</strong><br />

TITANIC CHAUSSEE HOTEL BERLIN<br />

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r4_11.<strong>2018</strong>

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