Issue 05/2017
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ISSN 1862-5258<br />
Sep/Oct<br />
<strong>05</strong> | <strong>2017</strong><br />
Highlights<br />
Fibres & Textiles | 14<br />
Beauty & Healthcare | 32<br />
Basics<br />
Land use | 43<br />
NORTH AMERICA-<br />
Special<br />
bioplastics MAGAZINE Vol. 12<br />
Cover Story:<br />
C , M, Y, K<br />
Meet ICBP 10, 0, 80,0<br />
Malaysia‘s Bioplastics<br />
C, M, Y, K<br />
0, 0, 0, 0<br />
Industry Anchor |10<br />
C, M, Y , K<br />
45, 0,90, 0<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
... is read in 92 countries
INTEGRALLY SUSTAINABLE<br />
Speick Natural cosmetics chose Braskem’s biobased Green PE (distributed by FKuR)<br />
for its Speick Organic 3.0 shower gel and body lotion. Bottle, closure and label<br />
consist of one and the same material and therefore are easy to recycle.<br />
The sugar cane used for the Green PE production is cultivated and harvested<br />
in Brazil according to the sustainable resource and social management<br />
guidelines of ProForest.<br />
With this concept, Speick is complementing its line of holistic natural<br />
cosmetics. Speick’s formula is readily biodegradable, palm oil-free and<br />
enriched with energized water.<br />
www.speick.de
Editorial<br />
C, M, Y , K<br />
45, 0,90, 0<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
C, M, Y, K<br />
0, 0, 0, 0<br />
dear<br />
readers<br />
Summer is coming to an end and autumn time is award time, at least for us. And<br />
so, once again, I’m very happy to present the five finalists of the 12 th Global<br />
Bioplastics Award on pages 12-13. The winner will, as always, be announced at<br />
the European Bioplastics Conference on November 28 in Berlin, Germany.<br />
Other highlight topics of this issue are Fibres & Textiles and the application<br />
field of Beauty & Healthcare. Also, a different perspective is given on the question<br />
of Land use / Land availability on page 43 in the Basics Section.<br />
In our geographical focus in this issue we look to North America.<br />
As always, we’ve provided you, our readers, with news about trends,<br />
developments and applications, plus critical context and information in the form<br />
of reports and opinions.<br />
We’ve also got a few events we’d like you to pencil in for next year, including<br />
the 5 th PLA World congress in May, which, as always, will be held in Munich, in<br />
Germany and the 1 st PHA platform World Congress, which is scheduled to take<br />
place in September 2018, in Cologne. We are happy to have Jan Ravenstijn as<br />
our co-organisator. Stay tuned for more information on both these conferences<br />
in our coming issues.<br />
Before then, however, we’re hoping for the opportunity to see you at one or<br />
the other of the various trade shows and conferences that are taking place this fall, with as<br />
high point, of course the European Bioplastics Conference. We’re looking forward to it, as<br />
we hope you are too.<br />
Until then, please enjoy the autumn - and have a great time reading this latest issue of<br />
bioplastics MAGAZINE.<br />
Sincerely yours<br />
Michael Thielen<br />
bioplastics MAGAZINE Vol. 12<br />
ISSN 1862-5258<br />
... is read in 92 countries<br />
Sep/Oct<br />
<strong>05</strong> | <strong>2017</strong><br />
Highlights<br />
Fibres & Textiles | 14<br />
Beauty & Healthcare | 34<br />
Basics<br />
Land use | 43<br />
Cover Story:<br />
Meet ICBP<br />
Malaysia‘s Bioplastics<br />
Industry Anchor |10<br />
C , M, Y, K<br />
10, 0, 80,0<br />
In this issue we have a closer look to North America.<br />
However, even if Mexico is part of “North America”,<br />
we unfortunately do not have any editorial contribution<br />
from Mexico.<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 3
Content<br />
Imprint<br />
Sep / Oct <strong>05</strong>|<strong>2017</strong><br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Cover Story<br />
10 Meet ICBP<br />
Events<br />
11 5 th PLA World Congress<br />
47 1 st PHA platform World Congress<br />
Award<br />
12 12 th Bioplastics Award<br />
Fibers & Textiles<br />
14 Yarns from biobased Polymers<br />
17 Advances in textile applications<br />
for biobased polyamide<br />
18 Stable ring spinning process for poly<br />
lactic acid (PLA) staple fibre yarns<br />
Production<br />
24 Reducing PLA production cost<br />
Materials<br />
30 New compostable PHA based<br />
compound from Canada<br />
3 Editorial<br />
5 News<br />
26 Application News<br />
45 10 years ago<br />
50 Glossary<br />
54 Suppliers Guide<br />
57 Event Calendar<br />
58 Companies in this issue<br />
Beauty & Healthcare<br />
32 The power of packaging<br />
34 PolyBioSkin<br />
36 Stronger superabsorbent<br />
biopolymers for baby care<br />
37 Bioplastic microbeads for cosmetics<br />
Politics<br />
38 biodegradable plastics in<br />
the circular economy<br />
From Science and Research<br />
40 Turning waste into PHA bioplastics<br />
Opinion<br />
42 Biodegradable plastics<br />
Basics<br />
43 Land Use<br />
48 Biodegradation<br />
Brand Owner<br />
44 Mars<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
s.brangenberg@samsales.de<br />
Chris Shaw (English language)<br />
Chris Shaw Media Ltd<br />
Media Sales Representative<br />
phone: +44 (0) 1270 522130<br />
mobile: +44 (0) 7983 967471<br />
and Michael Thielen (see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 3,400 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
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bioplastics MAGAZINE is read in<br />
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All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
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Opinions expressed in articles do not<br />
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bioplastics MAGAZINE tries to use British<br />
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information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped in bioplastic envelopes<br />
sponsored by Biotec Biologische Naturverpackungen,<br />
Emmerich, Germany<br />
Cover-Ad<br />
ICBP, Indochine Bio Plastiques<br />
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www.bioplasticsmagazine.com<br />
News<br />
DuPont and ADM win<br />
5 th Annual Innovation in<br />
Bioplastics Award<br />
The Bioplastics Division, a part of the Plastics Industry<br />
Association (PLASTICS), recently announced DuPont<br />
Industrial Biosciences and Archer Daniels Midland (ADM)<br />
as the winners of the <strong>2017</strong> Innovation in Bioplastics Award.<br />
The two companies developed a method to produce furan<br />
dicarboxylic methyl ester (FDME), a biobased monomer,<br />
from fructose derived from corn starch. This is the fifthannual<br />
Innovation in Bioplastics Award, an honor that goes<br />
to companies applying bioplastics to innovative, purposeful<br />
product design.<br />
The new FDME-producing technology is more<br />
sustainable and results in higher yields and lower energy<br />
and capital expenditures than traditional conversion<br />
methods. Biobased FDME has the potential to replace<br />
petroleum-based materials in many applications with<br />
high performance, renewable materials in industries like<br />
packaging, textiles and plastics engineering.<br />
“The breakthrough process developed by DuPont and ADM<br />
provides a simpler, more efficient approach to producing<br />
FDME that will make bioplastics a competitive option in<br />
more applications across various industries,” said Patrick<br />
Krieger, assistant director of regulatory and technical affairs<br />
at PLASTICS. “We are excited to honour a partnership that<br />
has opened the door to new possibilities for bioplastics.”<br />
One of the first materials under development using the<br />
new FDME process is polytrimethylene furandicarboxylate<br />
(PTF), a 100 % renewable and recyclable polymer with<br />
improved gas barrier properties that can be used to improve<br />
shelf life and lighten the weight of products in the beverage<br />
packaging industry. With lighter plastic bottles that offer<br />
a high gas barrier, costs to the transporter and negative<br />
environmental impacts would decrease on a global scale.<br />
“This molecule is a game-changing platform technology.<br />
It will enable cost-efficient production of a variety of<br />
renewable, high-performance chemicals and polymers<br />
with applications across a broad range of industries—<br />
including textiles, auto parts, food packaging and more,”<br />
said Michael Saltzberg, global business director for<br />
biomaterials at DuPont. “A demonstration plant for the<br />
technology in Decatur, Illinois will be online later this year,<br />
and we look forward to making this breakthrough a reality<br />
on a commercial scale.”<br />
“This project is a great example of how ADM is able<br />
to create value by providing innovative new sustainable<br />
solutions that address unmet needs for customers,” said<br />
Paul Bloom, vice president, process and chemical research<br />
for ADM. “Our unique partnership with DuPont is helping<br />
bring an innovative new product to customers that uses<br />
renewable feedstocks but also helps improve performance,<br />
and we are excited about the team’s continued progress as<br />
we near completion of construction of the demonstration<br />
project.” MT<br />
www.plasticsindustry.org<br />
Bio-on creates five<br />
new business units<br />
Bio-on (Bologna, Italy) recently announced the creation<br />
of five new Business Units (BU) to speed up its<br />
response to the growing demand for PHAs. The new<br />
divisions will enable more effective and faster development<br />
of new materials from biopolymers and new<br />
applications.<br />
"We decided to set up these five new Business Units to<br />
rapidly meet the enormous number of requests from<br />
all over the world for our revolutionary technology,"<br />
says Marco Astorri, Chairman and CEO of Bio-on. "This<br />
move will create more independent and more efficient<br />
departments to deal with special industrial production<br />
(Bio-on Plants); Cosmetic, Nanomedicine & Smart<br />
Materials (CNS); Recovery and Fermentation (RAF);<br />
Engineering (ENG) and Structural Materials Development<br />
(SMD)."<br />
Every year, 300 million tonnes of polluting plastic<br />
are produced and sold and thousands of types of oilbased<br />
polymers are made for myriad uses. Each of<br />
these is called a product grade and each one comes<br />
with its own technical data sheet. In recent months,<br />
and particularly since the recent presentation of Bioon's<br />
<strong>2017</strong>-2020 industrial plan released in November<br />
2016, Bio-on’s technicians have developed hundreds of<br />
new grades to replace existing high-pollution plastics.<br />
But, more importantly and surprisingly, there has been<br />
an exponential increase in the number of international<br />
patent applications submitted by Bio-on in high added<br />
value sectors unthinkable until as recently as last year.<br />
"Our goal," continues Marco Astorri, "is to develop<br />
as many products and agreements as possible in a<br />
rapidly changing scenario. And since Bio-on's Minerv<br />
polyhydroxyalkanoates can already be used in cuttingedge<br />
applications, unthinkable for conventional plastics,<br />
we had to speed up our response to market demand in a<br />
personalised way whilst continuing to provide a high level<br />
of service. The new Business Units meet this requirement."<br />
Bio-on Plants, the production BU, will be based in<br />
Castel San Pietro Terme, outside Bologna, Italy, where<br />
an innovative plant is being built, controlled by Bio-on,<br />
that will produce micro bioplastics for cosmetics. The<br />
RAF (Recovery and Fermentation) and CNS (Cosmetic<br />
Nanomedicine & Smart Materials) business units<br />
will also be based here. The latter will be equipped<br />
with laboratories and a business centre on two floors<br />
in the area opposite the Bio-on Plants facility. It is<br />
expected to open in early 2018. The SMD BU (Structural<br />
Materials Development) will further develop the current<br />
Bentivoglio (Bologna) site, in operation since 2016,<br />
with new spaces for studying and developing structural<br />
materials. The ENG BU (engineering) will be based at<br />
Bio-on in Via Santa Margherita al Colle in Bologna and<br />
will develop projects for the construction and assistance<br />
of licensed plants. MT<br />
www.bio-on.it<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Bio-additives for biodegradable plastic bottles<br />
Earlier this summer, the Citruspack project, a combination of circular economy and packaging, was launched at the Aitiip<br />
Technology Centre in Zaragoza, Spain.<br />
The project aims to process plant by-products, using these to derive natural additives to reinforce 100% biodegradable<br />
plastic bottles and containers. These will then be valorised in a number of new value chains.<br />
This project is coordinated by Aitiip and accounts with the partnership of AMC Innova Juice And Drinks S.L. (Spain), EROSKI<br />
(Spain), OWS Nv (Belgium), Plastipolis (France) and TECOS (Slovenia).<br />
At the end of the project, the researchers and participating companies aim to offer three solutions for the packaging and<br />
cosmetic sectors. The juice bottles will be the first demonstrator product.<br />
The bottles will be blow-moulded and must meet “very<br />
serious technical requirements”, as well as being biobased<br />
and eco-friendly, said Carolina Peñalva, project coordinator<br />
and the responsible person for packaging at Aitiip. "We want<br />
to test and quantify the acceptance of consumers during the<br />
project to reach the market.”<br />
Citruspack is part of the LIFE Program, which is the<br />
only financial instrument of the European Union dedicated<br />
exclusively to the environment. Its overall objective for<br />
the period 2004-2020 is to contribute to the sustainable<br />
development and achievement of the objectives and targets<br />
of the Europe 2020 Strategy and the relevant Union strategies<br />
and plans on environment and climate. This year it is<br />
celebrating its 25th anniversary. MT<br />
jal@aitiip.com<br />
WUR and Vredestein develop tyre made of<br />
rubber from dandelions<br />
Vredestein showed a prototype of its Fortezza Flower Power at the Eurobike exhibition in Friedrichshafen in August. This<br />
innovative road tyre is made of rubber extracted from the roots of dandelions. The prototype is the result of a EU joint initiative<br />
in which Vredestein and Wageningen University & Research (WUR) take part, called DRIVE4EU.<br />
Dandelion tyres<br />
The prototype is the first bicycle tyre in the world produced with natural rubber extracted from the roots of the Russian<br />
dandelion (Taraxacum koksaghyz). This particular series of prototype tyres were made with rubber extracted from plants<br />
grown and harvested in the Netherlands.<br />
Vredestein has worked closely together with WUR to develop this special natural rubber, make production viable and test<br />
various compounds. Each improvement in the process of rubber extraction has also led to a direct enhancement of the quality<br />
of the rubber. As a result, the special compound now used as a test on the Fortezza Flower Power prototype, provides better<br />
grip than traditional compounds. This is directly related to the higher concentration of natural resin in this particular variant of<br />
natural rubber. Studies are currently exploring whether this tyre can be mass produced in the future.<br />
DRIVE4EU<br />
Apollo Vredestein (the parent company of the Vredestein brand) is one of the industrial<br />
partners taking part in DRIVE4EU, a European research project which focuses on<br />
developing the production of natural rubber and inulin from Russian dandelion. The project<br />
is coordinated by Wageningen University & Research. The aim is to explore ways to make<br />
the European countries less dependent on imports of natural rubber in the near future,<br />
partly as a response to the looming worldwide shortage of rubber.<br />
www.wur.nl<br />
6 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
News<br />
<strong>2017</strong> Biocomposites Innovation Awards<br />
finalists revealed<br />
The finalists for the <strong>2017</strong> Biocomposites Innovation Awards have<br />
been announced by Germany-based nova-Institute. Six entries<br />
were selected out of a field of thirteen candidates by the advisory<br />
board earlier this month. Three will emerge victorious at the<br />
Biocomposites Conference (Dec. 6 and 7 in Cologne, Germany).<br />
Each of the finalists will be given a ten-minute slot to pitch<br />
their innovation at the close of the first day of the conference.<br />
Then the audience will choose the three winners, who will<br />
be presented with their awards at the Innovation Award<br />
Ceremony later that evening.<br />
The finalists are, in no particular order of ranking:<br />
A fully bio-based pedestrian bridge developed at the<br />
Eindhoven University of Technology in the Netherlands and<br />
installed by biocomposite pioneer NPSP (Netherlands). Flax<br />
and hemp fibres, which ensure the strength of the structure,<br />
are combined with a bio-based epoxy resin. Polylactic<br />
acid (PLA) bio-foam provides the core. A vacuum infusion<br />
production process is used: Layers of natural fibres are glued<br />
around a laser-cut shape of bio-foam.<br />
BASF & Sonae Arauco Deutschland (Germany) entered with<br />
an innovative 3D mouldable MDF styled as the new woodbased<br />
material for the furniture industry. It is a thermoplastic,<br />
processable and storage-stable composite which can be<br />
produced on existing MDF production lines. Due to the<br />
increased mouldability of the composite, new design options<br />
are possible. The resin system is offered formaldehyde free.<br />
Mass produced boats are typically made of fossil-based resins,<br />
glass fibres and plastic foam. By contrast, 80% of the GreenBente24<br />
from GreenBoats (Germany) is made from renewable materials<br />
such as flax, cork and bio-based epoxy resin. The boat has the<br />
same weight and stiffness as a standard boat, yet achieves an 80%<br />
reduction in its carbon footprint and is thermally recyclable.<br />
The Stratos passive – sandwich window scantling system<br />
by G.S. Stemeseder (Austria) is a combination of a foamed PP<br />
and wood composite material with solid wooden elements.<br />
The system was developed for the production of passive house<br />
windows. The required specific heat conductivity and Uf-value<br />
of ≤ 0.8 W/m 2 K were achieved by a reduction in density of<br />
approximately 50%. The components are produced with standard<br />
machinery and wood industry tools of the wood industry.<br />
From OWI (Germany) comes an injection-moulded classroom<br />
seat shell. The polypropylene (PP) and wood-based granulates<br />
were developed by Linotech GmbH (Germany). The chair is soft<br />
and warm to the touch while maintaining standard PP chair<br />
requirements regarding flexibility and notch impact strength.<br />
It withstands upholstery staples and stress load cycles.<br />
As one of the oldest known fasteners in the world, the<br />
wooden nail would seem to have reach its evolutionary peak<br />
some millennia ago. Raimund Beck Nageltechnik (Austria)<br />
however, has now developed collated wooden nails for use<br />
with pneumatic nailers. The LignoLoc fasteners do not<br />
require pre-drilling and achieve their holding power because<br />
of a natural welding effect with the base wood.<br />
biocompositescc.com<br />
Braskem and A. Schulman partner on a<br />
sustainable solution for rotomolding processes<br />
Braskem, the largest petrochemical company in the<br />
Americas, has entered into a partnership with A. Schulman,<br />
Inc., a leading global producer of high-performance<br />
plastic compounds and resins, to produce and market a<br />
new sustainable solution for the rotomoulding process.<br />
Braskem identified a market demand for more<br />
sustainable solutions in rotomolded products, and<br />
developed a solution to enable the rotational molding of<br />
general-purpose parts, with applications ranging from<br />
toys and furniture to agricultural tools that can contain<br />
more than 50% of Green Plastic in their composition.<br />
The new Green Polyethylene rotomoulding grade will<br />
be brought to the market by Schulman and feature the I’m<br />
green seal, marking it as a sustainable product that can<br />
contribute to the reduction of greenhouse gas emissions.<br />
A. Schulman, which contributes to the partnership<br />
through its industrial and commercial expertise in<br />
serving clients directly with products that meet market<br />
needs, will introduce the product at Rotoplas <strong>2017</strong>, the<br />
largest trade fair of the rotomolding industry, which<br />
takes place from September 26-28 in the United States.<br />
“The partnership with A. Schulman will benefit a market<br />
that requires innovative products. The new compound<br />
is another step of the petrochemical industry towards<br />
reinforcing the commitment of companies to new solutions<br />
that help to reduce greenhouse gas emissions,” said Gustavo<br />
Sergi, Director of Renewable Chemicals at Braskem.<br />
“A. Schulman is honored to have a long-standing<br />
collaborative relationship with Braskem and we are equally<br />
pleased to play a part in helping drive green innovation<br />
the specialty chemical industry and specifically for the<br />
rotomolding market,” said Gustavo Perez, Senior Vice<br />
President and General Manager – Latin America, A. Schulman.<br />
www.braskem.com | www.aschulman.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 7
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Eastman licenses proprietary<br />
FDCA technology to Origin Materials<br />
Eastman Chemical Company and Origin Materials<br />
(formerly known as Micromidas) have entered into a<br />
non-exclusive license agreement for Eastman to license<br />
its proprietary 2,5-Furandicarboxylic Acid (“FDCA”) and<br />
FDCA derivatives production technology from renewable<br />
resources to Origin Materials.<br />
Origin also recently purchased an oxidation pilot plant<br />
from Eastman that will enable Sacramento-based company<br />
to demonstrate the licensed technology. Terms of the<br />
license agreement and pilot plant sale were not disclosed.<br />
FDCA has been identified by the U.S. Department of<br />
Energy as one of the top 12 bio-based building blocks, and<br />
can be converted into a number of high-value chemicals or<br />
materials. FDCA can be used to produce polymer resins,<br />
films, and fibers and as a building block for plasticizers.<br />
The largest initial FDCA applications are expected to be to<br />
make 100 percent bio-based plastics, such as polyethylene<br />
furanoate (PEF) for beverage containers and food packaging.<br />
Eastman has developed key technologies for economically<br />
competitive conversion of 5-(hydroxymethyl) furfural (5-<br />
HMF) and its derivatives to crude FDCA, polymer grade<br />
FDCA and polymer grade dimethylfuran-2,5-dicarboxylate<br />
(DMF). Eastman’s technology is broadly flexible in terms of<br />
feedstocks and provides efficient production of crude FDCA,<br />
polymer grade FDCA and polymer grade DMF.<br />
“Eastman’s technology provides robust and multiple<br />
integrated engineering options for commercialization,”<br />
said Eastman’s Damon Warmack, senior vice president of<br />
Corporate Development and Chemical Intermediates. “This<br />
agreement leverages the world-class FDCA production<br />
technologies we have developed over the last several years.”<br />
Eastman is actively pursuing a broad intellectual property<br />
strategy with dozens of U.S. and foreign patents awarded<br />
or pending.<br />
John Bissell, CEO of Origin Materials, said the company<br />
is excited bythe opportunities created by this licensing<br />
agreement. “This technology will enable us to produce<br />
FDCA monomer, which can then be used by our customers<br />
to develop PEF bottles, films and other plastics from our<br />
intermediate chemicals,” said Bissell. MT<br />
http://vercet.natureworksllc.com<br />
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of<br />
the past two months. The story that got the most clicks<br />
from the visitors to bioplasticsmagazine.com was:<br />
PLA that can take the heat (01 Sept <strong>2017</strong>)<br />
Fibers of a corn-derived, biodegradable plastic<br />
developed at the University of Nebraska-Lincoln.<br />
Nebraska researchers and their colleagues have<br />
demonstrated a new technique for improving the<br />
properties of bio-plastic that could also streamline<br />
its manufacturing, making it more competitive with<br />
petroleumb<br />
a s e d<br />
counterparts.<br />
Introducing<br />
a simple<br />
step to the<br />
production of<br />
plantderived,<br />
biodegrada-ble plastic could im-prove its properties<br />
while overcoming obstacles to manufacturing it<br />
commercially, says new research from the University of<br />
Nebraska-Lincoln and Jiangnan University...<br />
more at https://tinyurl.com/news-<strong>2017</strong>0901<br />
8 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />
HEXPOL TPE<br />
green@hexpolTPE.com<br />
www.hexpolTPE.com
io CAR<br />
says<br />
THANK YOU...<br />
...to all of the attendees,<br />
sponsors, and speakers<br />
who participated in<br />
bio!car <strong>2017</strong><br />
www.bio-car.info<br />
Media Partner supported by co-organized by<br />
1 st Media Partner<br />
Institut<br />
für Ökologie und Innovation<br />
by decision of the<br />
German Bundestag<br />
in cooperation with<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 9
Cover Story<br />
Advertorial<br />
INDOCIHINE BIO PLASTIQUES (ICBP) SDN. BHD.<br />
C, M, Y , K<br />
45, 0,90, 0<br />
C , M, Y, K<br />
10, 0, 80,0<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
C, M, Y, K<br />
0, 0, 0, 0<br />
ICBP<br />
BIO RESIN<br />
COMPARISAN<br />
PETROLEUM<br />
RESIN<br />
Yes Biodegradable No<br />
Yes Renewable Resources No<br />
Lower (50%<br />
Electicity Saving)<br />
Processing Temperature Higher<br />
Lower Carbon Footprint (CO2) Higher<br />
Lower<br />
Greenhouse<br />
Gas Emissions (GHG)<br />
Higher<br />
Safe for Food<br />
Contact Under<br />
US FDA & REACH<br />
Standards<br />
Toxic to humans and<br />
environment<br />
Harmful
organized by<br />
5 th PLA World Congress<br />
29-30 MAY* 2018 MUNICH › GERMANY<br />
is a versatile bioplastics raw<br />
PLA material from renewable resources.<br />
It is being used for films and rigid packaging,<br />
for fibres in woven and non-woven applications.<br />
Automotive industry and consumer electronics<br />
are thoroughly investigating and even already<br />
applying PLA. New methods of polymerizing,<br />
compounding or blending of PLA have broadened<br />
the range of properties and thus the range<br />
of possible applications.<br />
That‘s why bioplastics MAGAZINE is now<br />
organizing the 5 th PLA World Congress on:<br />
29-30 May* 2018 in Munich / Germany<br />
Experts from all involved fields will share their<br />
knowledge and contribute to a comprehensive<br />
overview of today‘s opportunities and challenges<br />
and discuss the possibilities, limitations<br />
and future prospects of PLA for all kind of<br />
applications. Like the three congresses<br />
the 5 th PLA World Congress will also offer<br />
excellent networking opportunities for all<br />
delegates and speakers as well as exhibitors<br />
of the table-top exhibition.<br />
The team of bioplastics MAGAZINE is looking<br />
forward to seeing you in Munich.<br />
The conference will comprise high class presentations on<br />
› Latest developments<br />
› Market overview<br />
call for papers now open<br />
› High temperature behaviour<br />
› Blends and comounds<br />
› Additives / Colorants<br />
› Applications (film and rigid packaging, textile,<br />
automotive,electronics, toys, and many more)<br />
Sponsor:<br />
Contact us at: mt@bioplasticsmagazine.com<br />
for exhibition and sponsoring opportunities<br />
www.pla-world-congress.com<br />
* date subject to changes<br />
› Fibers, fabrics, textiles, nonwovens<br />
› Reinforcements<br />
› End of life options<br />
(recycling,composting, incineration etc)<br />
Supported by:
Award<br />
The 12 th<br />
Bioplastics<br />
Award<br />
Presenting the<br />
five finalists<br />
bioplastics MAGAZINE is honoured<br />
to present the five finalists<br />
for the 12 th Global Bioplastics<br />
Award. Five judges from<br />
the academic world, the press and<br />
industry associations from America,<br />
Europe and Asia have again<br />
reviewed many really interesting<br />
proposals. On these two pages<br />
we present details of the five most<br />
promising submissions.<br />
The Global Bioplastics Award<br />
recognises innovation, success and<br />
achievements by manufacturers,<br />
processors, brand owners, or<br />
users of bioplastic materials. To<br />
be eligible for consideration in<br />
the awards scheme the proposed<br />
company, product, or service<br />
should have been developed or<br />
have been on the market during<br />
2016 or <strong>2017</strong>.<br />
The following companies/<br />
products are shortlisted (without<br />
any ranking) and from these<br />
five finalists the winner will<br />
be announced during the 12 th<br />
European Bioplastics Conference<br />
on November 28 th , 2016 in Berlin,<br />
Germany.<br />
Biobrush (Germany)<br />
Bioplastic toothbrush made of<br />
wood scraps<br />
Biobrush turns wood scraps into<br />
toothbrushes. The handle as well as the<br />
packaging are made from bioplastics<br />
based on cellulose made of the wood<br />
waste from sustainable forestry. The<br />
bristles are made of 100 % renewable<br />
polyamide, the main component is<br />
castor oil, without harmful emollients.<br />
The toothbrushes are clearly designed<br />
and available at a fair price.<br />
Making sustainable products<br />
accessible to as many people as<br />
possible is a key factor in the concept<br />
of Biobrush. The company, therefore,<br />
strives to maintain fair pricing.<br />
The manufacturing of the colour<br />
master batches is adapted to the<br />
bioplastic and contains carefully<br />
selected pigments, in which the<br />
concentration of heavy metal is way<br />
below threshold value.<br />
Producing sustainable products, is<br />
not just about replacing the conventional<br />
by eco. All aspects of the product - its<br />
function, nature and composition,<br />
pricing, sales approach and packaging<br />
- need reassessment. Biobrush<br />
toothbrushes combine features relevant<br />
to state-of-the-art dental care with a<br />
clear design, using resource saving<br />
and trend-setting materials: bioplastic<br />
and packaging based on cellulose and<br />
bristles derived from castor oil. The<br />
practical and home compostable sidesealed<br />
pouch contains only essential<br />
product information.<br />
Biobrush represents a holistic<br />
approach: Product biobased.<br />
Biodegradable, but not marketed as<br />
to be composted… The bristles not yet<br />
biodegradable, but 100 % biobased.<br />
Packaging, biobased and compostable.<br />
Looking outside the box (across the<br />
German borders) in countries where<br />
waste disposal is not as advanced…<br />
biodegradability may be an advantage in<br />
the long term.<br />
www.biobrush-berlin.com<br />
MAIP (Italy)<br />
I am NATURE : the first Bio-<br />
Technopolymer<br />
I am NATURE is a special PHBHbased<br />
compound, available in tailor made<br />
grades and suitable for high temperature<br />
applications. It offers a sustainable solution<br />
preserving the technical properties of a<br />
traditional thermoplastic material.<br />
Maip has developed different bioplastics<br />
that are sold under the name of I am<br />
NATURE for several years. These PHBH<br />
based grades are compounded with<br />
natural fillers and additives of vegetal<br />
origin as well as functional components<br />
for specific requirements.<br />
For a new series of switch cover frames<br />
that should have an advanced design and<br />
a remarkable environment sustainability<br />
connotation, ABB was looking for a<br />
bioplastic material that could replace<br />
technopolymers such as ABS or PC/<br />
ABS. In a joint development ABB and<br />
Maip succeeded in creating a special I am<br />
NATURE grade that is suitable to satisfy<br />
all the multiple requirements of the<br />
component. The new compound exhibits<br />
particular properties such as high<br />
dimensional stability, thermal resistance<br />
(about 130 °C), superior UV and light<br />
resistance, easy colourability and easy<br />
mouldability in multi cavity moulds.<br />
Easy processability and specific electric<br />
features such as for example a glow wire<br />
of 650 °C at 2 mm.<br />
The most severe test of all, the scratch<br />
resistance, led to the development of special<br />
grades that show surprising mar / scratch<br />
resistance values also in case of matte textures.<br />
The main properties that were achieved,<br />
allow the definition of the new I am<br />
NATURE as an actual Bio-Technopolymer<br />
that also allows to eliminate the painting<br />
(because of its good mass colourability)<br />
dramatically reducing the carbon footprint<br />
of the component.<br />
The switch covers were officially<br />
introduced to the market in Europe in<br />
September <strong>2017</strong>.<br />
www.maipsrl.com<br />
12 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Award<br />
TU/e Technische Universiteit Eindhoven<br />
(The Netherlands)<br />
Fully biobased pedestrian bridge<br />
A fully biobased pedestrian bridge, the<br />
first in the world, has been realised at the<br />
TU/e campus, Eindhoven, Netherlands,<br />
spanning the river Dommel. After<br />
researching and testing various biobased<br />
material properties and optimising<br />
alternative structural designs, the bridge<br />
has been produced with the help of<br />
many students in all stages of design<br />
and production, using only biobased<br />
materials.<br />
The bridge, first in its kind, has been<br />
made fully out of biobased materials:<br />
Flax and hemp fibres provide the<br />
strength, combined in a biobased epoxy<br />
resin, round an internal core of PLA<br />
bio-foam. The PLA foam is used as lost<br />
formwork for the structural biobased<br />
composite skin. As the whole bridge was<br />
transported to its final location and put<br />
in place in one peace, lightweight was a<br />
very important issue<br />
After a successful loadtest for<br />
the building inspection of the city of<br />
Eindhoven (5,0 kN/m 2 ), the bridge was<br />
installed in the Dutch Design week,<br />
last October, 2016. The project is the<br />
result of a research collaboration of the<br />
universities in Eindhoven and Delft as<br />
well as the Centre for Biobased Economy<br />
and the company NPSP bv. With High<br />
Tech Glass sensor technology the bridge<br />
is now monitored during use.<br />
A unique material combination of<br />
natural reinforcing fibres, a biobased<br />
epoxy-resin around a core of PLA foam…<br />
in a unique application sector: Building<br />
and construction. The project shows<br />
exemplary what can be achieved with<br />
bioplastics in clever combinations.<br />
www.tue.nl<br />
Adidas and Amsilk (Germany)<br />
Futurecraft Biofabric shoe<br />
The adidas Futurecraft Biofabric<br />
shoe features an upper made from<br />
100% Biosteel ® fibre, a nature-based<br />
and completely biodegradable highperformance<br />
fibre, developed by the<br />
biotech company AMSilk (Planegg,<br />
Germany). The material offers a unique<br />
combination of properties that are<br />
crucial in performance, such as being<br />
15% lighter in weight than conventional<br />
synthetic fibres as well as having the<br />
potential to be the strongest fully natural<br />
material available.<br />
In addition, Biosteel fibre also<br />
provides a far more sustainable<br />
offering. According to Amsilk, who have<br />
invested more than 200.000 bioengineer<br />
man hours and know-how into their<br />
products the fibres are made of 100 %<br />
nature based biopolymers, are 100 %<br />
vegan and biodegradable. The world’s<br />
first artificial silk fibre is entirely made<br />
of recombinant spider silk proteins.The<br />
Technical University of Munich’s website<br />
says the world’s first artificial silk fibre is<br />
entirely made of recombinant spider silk<br />
proteins. And io9.gizmodo.com unveils<br />
this: The company’s process uses<br />
genetically engineered E. coli samples<br />
to express silk protein derived from<br />
the DNA of the European garden cross<br />
spider, and is capable of generating<br />
about 20 different silk grades from four<br />
silk varieties<br />
Being 100% biodegradable in a fully<br />
natural process, the Biosteel fiber also<br />
provides a sustainable offering. This<br />
continues adidas’ journey of sustainable<br />
innovation – from a starting point of<br />
virgin plastics, to recycled plastics,<br />
to its partnership with Parley for the<br />
Oceans and now a totally new frontier<br />
of investing in solutions that leverage<br />
science and nature as an integral part<br />
of innovation.<br />
www.adidas-group.com | www.amsilk.com<br />
ICEE Containers (Australia)<br />
Foldable, reusable insulating box<br />
Since commercial production<br />
of expandable polystyrene in 1952<br />
the industry worldwide has been<br />
attempting to mould a durable, living<br />
hinge in particle foam. ICEE’s patented<br />
innovation means insulated boxes are<br />
no longer disadvantaged by their bulk<br />
as they can now be economically stored<br />
and transported flat, making them easy<br />
to return for reuse or recycling.<br />
ICEE has successfully moulded a<br />
living hinge in various particle foams<br />
including BASF’s ecovio ® a plant based<br />
compostable biofoam. The superior<br />
insulating and cushioning properties of<br />
particle foam makes them ideal for the<br />
expanding ecommerce grocery market,<br />
paddock to plate and the traditional<br />
markets such as pharmaceuticals,<br />
fresh produce and seafood.<br />
There are growing concerns<br />
surrounding food waste globally and<br />
ICEE’s insulated suite of boxes keeps<br />
perishable fresh without the need<br />
for refrigerated vehicles which is<br />
particularly advantageous in developing<br />
countries where food waste is highest.<br />
ICEE is a member of United Nations<br />
initiative Save Food (save-food.org)<br />
committed to reducing food loss<br />
sustained in the supply chain.<br />
ICEE’s fold flat insulated boxes<br />
are 98% air, 100% recyclable and<br />
now available in compostable plant<br />
based biofoam. They’re able to deliver<br />
perishables in unrefrigerated vehicles<br />
making the boxes ideal for disruptive<br />
delivery options such as Uber, bicycles,<br />
couriers, taxi apps, drones etc further<br />
adding to their attractive eco-friendly<br />
footprint.<br />
Capturing new markets and<br />
reducing food waste in countries with<br />
unsophisticated logistics by protecting<br />
food from bruising and climate stress in<br />
a biofoam box is a compelling story.<br />
www.iceefoldingbox.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 13
Fibers & Textiles<br />
Yarns from biobased polymers<br />
Sustainable options for technical textiles<br />
The need to reduce CO 2<br />
emissions and to become independent<br />
of fossil-based fibre products motivated PHP<br />
Fibers (Wuppertal, Germany) to search for bio-based<br />
alternatives.<br />
The company’s investigations revealed two potential<br />
candidates, both of which are thermoplastic polymers<br />
suitable for fibre spinning.<br />
Biobased and biodegradable high-tenacity<br />
polyester yarn (PLA)<br />
PHP’s polyester yarn Diolen ® 150BT is based on PLA and<br />
thus 100% biobased and biodegradable under industrial<br />
composting conditions. The polyester yarn exhibits low<br />
moisture absorption and provides good UV stability as well<br />
as low flammability.<br />
Compared to textile yarns, Diolen 150BT demonstrates<br />
superior tensile performance. It is therefore an option for<br />
a variety of sustainable applications. Examples are the<br />
substitution for non-biodegradable fixtures in agricultural<br />
and horticultural environments or sustainable packaging<br />
reinforcement for paper-based adhesive tapes<br />
Enka ® BIO – Biobased high-tenacity polyamide<br />
yarn<br />
For existing technical fibre applications, it would be<br />
particularly advantageous if yarns manufactured from<br />
biobased polymers could be considered as so-called drop<br />
in alternatives for current fossil-based products. In this<br />
case, similar processing conditions could be used without<br />
the need to make significant adaptions. In comparison to<br />
fossil-based PA 6.6 polymer, the bio-based PA 4.10 polymer<br />
was found to provide a very good match:<br />
The melting temperature and glass transition temperature<br />
of PA 4.10 are at the level of PA 6.6. But Polyamide 4.10<br />
offers weight advantages due to its lower density. It picks<br />
up less moisture compared to PA 6.6 and it provides a 40 %<br />
higher tensile modulus under humid storage conditions.<br />
The material is 70 % bio-based.<br />
Technical biobased PA 4.10 yarn vs. technical<br />
fossil-based PA 6.6 yarn<br />
Spinning evaluations carried out on an industrial scale<br />
proved that the biobased PA 4.10 polymer can be converted<br />
into technical multifilament yarns.<br />
The tensile characteristics were found to be largely<br />
comparable to those of fossil-based PA 6.6 technical yarns.<br />
At low elongation rates, the modulus of biobased PA<br />
4.10 yarn is certainly at the level of PA 6.6. The Elongation<br />
at break is higher and the breaking force is slightly lower<br />
compared to PA 6.6.<br />
In Mechanical Rubber Goods application PA 4.10 yarns/<br />
cords provide good adhesion characteristics to rubber and<br />
fatigue resistance at the level of reference PA 6.6.<br />
PHP Fibers demonstrated that biobased technical<br />
polyester (PLA) and polyamide fibres can compete with<br />
or even outperform standard fossil- based polyester and<br />
polyamide fibres. MT<br />
www.php-fibers.com<br />
Polymer properties of biobased PLA polymer vs. fossil-based PET polymer<br />
*) Sources: Mary Ann Liebert, Inc. Vol.6, no.4, August 2010, Industrial Biotechnology, Natureworks<br />
Polymer<br />
Melting<br />
Temperature,<br />
Tm<br />
°C<br />
Glass<br />
Transition<br />
Temperature,<br />
Tg<br />
°C<br />
Density<br />
g/cm³<br />
Moisture<br />
Uptake at<br />
50 % RH*<br />
%<br />
Tensile<br />
Modulus dry*<br />
MPa<br />
Tensile<br />
Modulus<br />
conditioned<br />
50 % RH*<br />
MPa<br />
Biobased<br />
content<br />
%<br />
CO 2<br />
Emission*<br />
kg CO 2<br />
eq / kg<br />
polymer<br />
PLA 160 – 180 55 – 60 1.24 0.2 2900 – 3000 n.a. 100 0.6<br />
PET 250 – 260 70 1.38 0.4 2800 – 3100 n.a. 0 3.4<br />
Polymer properties of biobased PA 4.10 vs. fossil-based PA 6.6<br />
*) Sources: DSM primary data for PA 4.10 (EcoPaXX), Plastics Europe eco-profiles for PA 6.6<br />
Polymer<br />
Melting<br />
Temperature,<br />
Tm<br />
°C<br />
Glass<br />
Transition<br />
Temperature,<br />
Tg<br />
°C<br />
Density<br />
g/cm³<br />
Moisture<br />
Uptake at<br />
50 % RH*<br />
%<br />
Tensile<br />
Modulus dry*<br />
MPa<br />
Tensile<br />
Modulus<br />
conditioned<br />
50 % RH*<br />
MPa<br />
Biobased<br />
content<br />
%<br />
CO 2<br />
Emission*<br />
kg CO 2<br />
eq / kg<br />
polymer<br />
Bio PA 4.10 250 70 1.09 1.9 3100 1750 70 0<br />
PA 6.6 255 74 1.14 2.7 3250 1250 0 6.4<br />
14 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Fibers & Textiles<br />
The biodegradation after storage under composting conditions in<br />
accordance to EN 14046:2003 was determined by ITV Denkendorf,<br />
Germany.<br />
start 5 weeks 8 weeks<br />
start 5 weeks 8 weeks<br />
110 pages full<br />
color, paperback<br />
ISBN 978-3-<br />
9814981-1-0:<br />
Bioplastics<br />
ISBN 978-3-<br />
9814981-2-7:<br />
Biokunststoffe<br />
2. überarbeitete<br />
Auflage<br />
‘Basics‘ book<br />
on bioplastics<br />
This book, created and published by Polymedia<br />
Publisher, maker of bioplastics MAGAZINE<br />
is available in English and German language<br />
(German now in the second, revised edition).<br />
Tenacity (cN/tex)<br />
40<br />
30<br />
20<br />
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The book is intended to offer a rapid and uncomplicated<br />
introduction into the subject of bioplastics, and is aimed at all<br />
interested readers, in particular those who have not yet had<br />
the opportunity to dig deeply into the subject, such as students<br />
or those just joining this industry, and lay readers. It gives<br />
an introduction to plastics and bioplastics, explains which<br />
renewable resources can be used to produce bioplastics,<br />
what types of bioplastic exist, and which ones are already on<br />
the market. Further aspects, such as market development,<br />
the agricultural land required, and waste disposal, are also<br />
examined.<br />
An extensive index allows the reader to find specific aspects<br />
quickly, and is complemented by a comprehensive literature<br />
list and a guide to sources of additional information on the<br />
Internet.<br />
Elongation (%)<br />
Technical PLA yarn - Diolen 150BT<br />
Textile PLA yarn*<br />
*) Source “Polylactic acid fibres”,<br />
D W FARRINGTON et al., NatureWorks LLC<br />
The author Michael Thielen is editor and publisher<br />
bioplastics MAGAZINE. He is a qualified machinery design<br />
engineer with a degree in plastics technology from the RWTH<br />
University in Aachen. He has written several books on the<br />
subject of blow-moulding technology and disseminated his<br />
knowledge of plastics in numerous presentations, seminars,<br />
guest lectures and teaching assignments.<br />
Tenacity (cN/tex)<br />
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Order now for € 18.65 or US-$ 25.00 (+<br />
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by phone +49 2161 6884463 or by e-mail<br />
books@bioplasticsmagazine.com<br />
Or subscribe and get it as a free gift<br />
(see page 57 for details, outside German y only)<br />
Elongation (%)
Fibers & Textiles<br />
Comfort beyond words<br />
SOLOTEX ® , a partly biobased polyester-fibre (polytrimethylene<br />
terephthalate – PTT) by Teijin Frontier Co. Ltd., Tokyo,<br />
Japan, provides a soft, stretchy texture with gentle<br />
cushioning and offers vivid colors. These advantages could<br />
never be achieved with conventional polyester, polyurethane, or<br />
nylon alone. The many superb characteristics of Solotex derive<br />
from its spring-like, helical molecular structure. The material<br />
is also easy to combine with other fibers, bringing out the characteristics<br />
of the other fiber while adding a new texture and<br />
new functionality. Solotex is a fiber with unlimited potential to<br />
make textile products<br />
more comfortable<br />
to wear or<br />
Fossil-fuel derived<br />
Bio-derived<br />
use.<br />
Seven defining<br />
characteristics of<br />
Solotex derive<br />
Terephthalic acid<br />
from the unique<br />
molecular structure<br />
of the fiber.<br />
The molecules<br />
form a flexible spring-like helix that makes the fiber soft, light,<br />
stretchy, and shape-stable.<br />
Plant-based eco-friendly ingredients<br />
Biomass-derived, plant-based ingredients are used for 37%<br />
of the polymers (Fig 1) that make up Solotex. The fabric thus<br />
reduces consumption of fossil fuels, and helps cut down on<br />
greenhouse gases. Solotex is an eco-friendly fiber that is kind<br />
to people and on the environment.<br />
Super soft feel and smoothness for comfort<br />
The touch of the PTT fibres feels even softer than luxury<br />
cashmere wool. Smooth against the skin, it is more comfortable<br />
to wear than any fiber that has come before. Blending with other<br />
fibers does not affect its superb softness, while maintaining the<br />
beneficial qualities of the blended fibers.<br />
Keeps its shape to look great<br />
A spring-like, helical molecular structure provides form<br />
stability to spring back into shape even with movement. The<br />
fiber resists wrinkles and does not easily get stretched out from<br />
repeated bending at the knee or elbow, maintaining a beautiful<br />
shape at all times. There is also little shrinkage or stretch<br />
even after repeated machine washings and tumble drying,<br />
demonstrating superb dimensional stability.<br />
Stretchiness that feels great, with no stress<br />
Solotex is surprisingly free of any feeling of pressure, even<br />
following the lines of the body. It expands and contracts in any<br />
direction with the body’s movement, feeling truly comfortable<br />
and allowing for free movement. The fibre is ideal for tightfitting<br />
bottom wear and active clothing.<br />
HOOC COOH + HOCH2CH2CH2OH OOC COOCH2CH2CH2 n<br />
1,3-propanediol<br />
(PDO)<br />
Fig.1: 37% bio-derived. *Testing performed using radiocarbon 14 C dating.<br />
Harmonizes<br />
well with<br />
other fibers<br />
for even<br />
greater<br />
potential<br />
Teijin’s PTT<br />
fibres are easy<br />
to combine with<br />
other fibers.<br />
They are highly compatible with both synthetic and natural<br />
fibers, for blending as desired. The fiber will add a soft texture to<br />
improve the feel against the skin, and it provides superb stretch<br />
and recovery from elongation. It is possible to add new texture<br />
and new functionality while bringing out the characteristics of<br />
the blended fiber.<br />
The ideal cushioning with fluffy rebound<br />
Maintains bounce even after repeated compressions and<br />
quickly recovers its fluffy volume. Because of its high durability,<br />
Solotex retains its unique texture for a long time. These<br />
characteristics are best utilized in insulated coats, pillows,<br />
futons, and other items with filling.<br />
Deep, vivid colors that last<br />
Outstanding color development is a key element for fashion<br />
applications. Solotex is very easy to dye, producing deep, vivid<br />
colors with a high-grade feel even when processing at lower<br />
temperatures than conventional methods. Extremely colorfast<br />
for long-lasting dyed color that won’t fade. MT<br />
www.solotex.net<br />
Polytrimethylene terephthalate<br />
(PTT)<br />
Table 1<br />
Solotex Polyester Nylon 6.6<br />
The Positioning<br />
of SOLOTEX ®<br />
Polyester<br />
Shape-Retention<br />
Tenacity (cN/dtex 2.8-3.5 3.7-4.4 4.1-4.5<br />
Elongation (%) 45-53 30-38 32-44<br />
Initial Young’s<br />
modulus (cN/dtex)<br />
20 97 31<br />
Tensile recovery (%) 67-88 29 62<br />
Boiling water<br />
shrinkage (%)<br />
7-9 7 13<br />
Melting point (°C) 230 254 253<br />
Deterioration of<br />
strength due to<br />
weather exposure<br />
Negtigible Negligible<br />
Slight deterioration,<br />
some yellowing<br />
Stretch<br />
Polyutethane<br />
Nylon<br />
Soft Texture<br />
16 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Fibers & Textiles<br />
Advances in textile<br />
applications for<br />
biobased polyamide<br />
By:<br />
Howard Chou<br />
Director of R&D<br />
Cathay Industrial Biotech,<br />
Shanghai, China,<br />
Cathay Industrial Biotech (CIB), Shanghai, China, developed<br />
proprietary technology to commercially produce<br />
biobased pentamethylenediamine (DN5), in order to<br />
address the growing demand for innovative new materials.<br />
DN5 is a unique five-carbon platform chemical and an alternative<br />
to hexamethylenediamine (HMDA), a six-carbon<br />
platform chemical used in the production of polymers, such<br />
as polyamide 66 and hexamethylene diisocyanate (HDI). Although<br />
DN5 and HMDA only differ by one carbon length, this<br />
difference creates significant potential for the development<br />
of new polymers with innovative properties.<br />
One polymer CIB developed using its DN5 technology is a<br />
biobased polyamide PA56 named Terryl ® . The Terryl polymer<br />
consists of an odd-numbered repeating unit, instead of the<br />
even-numbered repeating unit found in polyamides 6 and<br />
66. However, the crystalline structure of Terryl prefers an<br />
α-like structure that is more similar to polyamide 66 than<br />
polyamide 6, which exists in both an α and a γ-form. As<br />
a result, Terryl shares many of the stiffness, tensile and<br />
flexural modulus, and wear resistance advantages found in<br />
polyamide 66. Unlike polyamide 66 where 100 % of the interchain<br />
hydrogen bonds can form, Terryl forms a structure<br />
where at most 50% of the inter-chain hydrogen bonds can<br />
form. Another difference of importance is that Terryl has<br />
a unique ratio of carbon, nitrogen, oxygen, and hydrogen<br />
(CNOH). The CNOH ratio found in Terryl contains a higher<br />
proportion of nitrogen compared to polyamides 6 and 66,<br />
which have the same CNOH ratio. The higher nitrogen<br />
content increases the limiting oxygen index of Terryl fibres,<br />
making them more flame retardant.<br />
The scientists at CIB and its collaborators discovered that<br />
the differences in the molecular structure described above<br />
translate to fibres with novel properties. For example, Terryl<br />
has a lower initial modulus compared to the traditional fibres<br />
made from polyamide 6 and 66 (Figure 1). A monofilament<br />
of Terryl with a denier per filament (dpf) 1 of 1.5 has an initial<br />
modulus similar to that of wool, which means that Terryl<br />
feels significantly softer than traditional synthetic fibres.<br />
Furthermore, the elastic recovery rate of Terryl is higher<br />
than that of traditional PA6/PA66 fibres on the market<br />
(Figure 2). Lastly, Terryl shows improved dyeing capabilities,<br />
and can be dyed at lower temperatures and with less dye<br />
(Figure 3) without sacrificing any dyeing performance.<br />
The unique properties of Terryl has garnered a significant<br />
amount of interest from the market. As a result, Terryl<br />
was voted as the “Most Popular Fibre Product” at the Yarn<br />
Expo in Shanghai on March <strong>2017</strong>, receiving 39% of the votes<br />
casted. In addition to Terryl, CIB is also exploring other new<br />
fibres by combining DN5 with its long-chain dicarboxylic<br />
acid platform. The successful trials with local textile<br />
spinners recently makes CIB confident that it will bring a<br />
new class of materials to the market, following the opening<br />
of its new production plant at Xinjiang, which will have an<br />
annual capacity of 50,000 tonnes of DN5 and 100,000 tonnes<br />
of polyamides.<br />
1: denier = gram per 9000 meter, so dpf 1.5 means one<br />
filament weighs 1.5 gram per 9000 m<br />
www.cathaybiotech.com/en/<br />
48 —<br />
46 —<br />
44 —<br />
Initial Modulus (cN/dtex) Elastic Recovery (%) Elastic Recovery (%)<br />
100 —<br />
25 —<br />
80 —<br />
20 —<br />
42 —<br />
40 —<br />
38 —<br />
36 —<br />
60 —<br />
40 —<br />
20 —<br />
15 —<br />
10 —<br />
5 —<br />
0 —<br />
0 2 3 4 8<br />
34 —<br />
Terryl<br />
PA6<br />
PA66<br />
0 —<br />
Terryl PA6/PA66 Terryl PA6/PA66<br />
10% elongation 20% elongation<br />
Terryl<br />
PA6<br />
PA66<br />
Figure 1: Terryl is softer<br />
than existing synthetic fibers<br />
Figure 2: Terryl has better elastic recovery<br />
than existing synthetic fibers<br />
Figure 3: Terryl uses less dye to achieve<br />
the same dyeing performance<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 17
Fibres & Textiles<br />
Stable ring spinning process<br />
for PLA staple fibre yarns<br />
This article presents the current state of the project<br />
SPEY which aims to establish poly lactic acid (PLA)<br />
staple fibre yarns in home textiles or in technical applications<br />
using a methodological approach and process<br />
analysis. The goal of the performed process analysis is<br />
the avoidance of degradation phenomena during the ring<br />
spinning process. At the current state of the project, Ring<br />
spinning yarn of 100 % PLA was successfully produced. A<br />
production speed of v pr<br />
= 23 m/min combined with a twist<br />
factor of α m<br />
= 100 T/m lead to a stable process without yarn<br />
breakage. The resulting yarn count is T t<br />
= 25 tex. This article<br />
provides an overview of the results from the ring spinning<br />
trials with experimental PLA filaments and presents optimised<br />
production parameters for the stable production of<br />
100 % PLA ring spinning yarn.<br />
Introduction<br />
Currently, Europe consumes more than 6 million tonnes<br />
of textile fibres 34 % for clothing, 27 % for housing and<br />
carpeting, 38 % for other industrial technical usages [1]. The<br />
European textile and clothing industry has a longstanding<br />
tradition of leadership in terms of innovation, fashion and<br />
creativity. Even though the European textile and clothing<br />
industry increasingly encounters fierce global competition<br />
and significant relocation of manufacturing to low-wage<br />
countries - with 165 billion EUR turnover - it continues to<br />
represent one of Europe’s major industrial sectors [2].<br />
Today, the European textile industry is challenged to make<br />
a radical shift towards innovative and high-value added<br />
products to counter the competition with low-wage countries.<br />
At the same time, European industry is looking to find links to<br />
the environment-concerned customers via the increased use<br />
of renewable and recyclable as well as recycled materials.<br />
PLA is at the moment produced from starch (corn) or from<br />
sugar (sugarbeet). The fibre products are highly smooth and<br />
completely non-irritating to the skin, while being 100 %<br />
biodegradable and compostable. PLA staple fibres are a<br />
possible alternative as a substitution of existing synthetic<br />
fibre products. The replacement of oil based polymers by<br />
biobased alternatives is a topic that is regarded with high<br />
priority in textile innovation programs. PLA offers additional<br />
end-of-life possibilities. It is known and demonstrated that<br />
PLA can be recycled via melt processing and due to the<br />
low melting temperature and the limited water-uptake the<br />
process has a low cost and offers high quality products. Also<br />
hydrolysis to feedstock (monomers) is possible. In contrast<br />
with most oil based polymers, PLA can be composted or used<br />
in biogas installations. At medium term, the market potential<br />
is estimated to the production of 40,000 t/a for PLA and PLA<br />
blended yarns with a volume of appr. 140 Million EUR/a all<br />
over Europe when comparable properties of existing yarns<br />
are reached. Moreover, there’s not much oil occurrence in<br />
Europe but enough area for cultivable land for food and crop<br />
for technical use. The industry of agriculture and forestry are<br />
offered alternative production and income possibilities.<br />
The project Spun EcoYarn (SPEY, AiF Cornet 153 EN)<br />
contributes to a greener environment. Depending on the crop<br />
used 3.3 up to 6 tonnes of PLA can be produced per hectare<br />
crop yield. This is very efficient compared to the production<br />
of about 1 tonne of cotton per hectare. During 2012, 190,000<br />
tonnes of PET fibres were produced just in Germany [3]. The<br />
total energy consumption to produce PLA is about 50 % lower<br />
than for PES (Fig 1., top) and as a consequence also the total<br />
emission of greenhouse gases is about 60 % lower for PLA<br />
than for PES (Fig. 1, bottom).<br />
SPEY aims to establish poly lactic acid (PLA) staple fibre<br />
yarns in home textiles e. g. upholstery fabrics, bedding<br />
textiles, matrass thickening, in technical applications e.<br />
g. work wear and medical textiles using a methodological<br />
approach and process analysis, with the goal of avoiding<br />
degradation phenomena.<br />
The aim of this project is to develop the technology and<br />
expertise to economically produce PLA based spun yarns and<br />
blended spun yarns with properties comparable to existing<br />
PET alternatives. It is targeted to develop in commercially<br />
available conditions, high quality bio-based spun yarns with a<br />
high durability (long life time). To reach this goal the polymer<br />
recipe is modified by additives and process parameters for<br />
melt spinning as well as end spinning for high quality yarns<br />
are defined.<br />
Implementation<br />
Aim of the current work package within the SPEY project is<br />
the production of staple fibre yarns of commercially available<br />
PLA and of experimental PLA by Centexbel. Also, spinning<br />
methods for processing PLA are optimised and PLA staple<br />
fibre yarns with improved properties are developed. PET<br />
(Table 1) based ring yarns will be the benchmark for the<br />
development of the PLA staple fibre yarns. The main target is<br />
to reach a breaking tenacity in the range of 16 – 30 cN/tex [5].<br />
The experimental PLA filaments are cut and texturated<br />
at the user committee member (UCM) of the company<br />
Barnet Europe GmbH & Co. KG, Aachen, Germany. Spin<br />
finish application is performed by the UCM Bozzetto GmbH,<br />
Krefeld, Germany. At ITA the fibres are processed into a sliver<br />
and send to the UCM member Schlafhorst, branch office of<br />
Saurer Germany GmbH & Co. KG, for ring spinning.<br />
18 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Fibres & Textiles<br />
By:<br />
Vadim Tenner 1 , Marie-Isabel Popzyk 1 ,<br />
Yves-Simon Gloy 1 , Raf Van Olmen 2 , Thomas Gries 1<br />
1<br />
Institut für Textiltechnik der RWTH Aachen<br />
University, Aachen, Germany<br />
2<br />
Centexbel, Gent, Belgium<br />
www.ita.rwth-aachen.de<br />
Fig. 1: Energy consumption and<br />
greenhouse gas emission of PLA and PET [4]<br />
100,00<br />
80,00<br />
60,00<br />
40,00<br />
20,00<br />
0,00<br />
Production energy consumption in MJ/kg<br />
PES<br />
-50%<br />
PLA<br />
PLA<br />
PES<br />
4,00<br />
3,00<br />
2,00<br />
1,00<br />
0,00<br />
100,00 100,00<br />
Results<br />
80,00<br />
60,00<br />
In the following, the results from the laboratory<br />
40,00<br />
analysis 20,00 of the produced ring spinning yarns<br />
0,00 of 0,00 100 % PLA are presented. The used batch<br />
PES PES<br />
PLA PLA<br />
of experimental PLA was not applied with an<br />
additional spin finish since spinning trials<br />
showed no necessity for a second spin finish.<br />
Stable spinning processes for ring spinning are<br />
achieved and a factorial design is carried out.<br />
Fibre properties after different processing steps<br />
are shown in Table 2. The laboratory results show,<br />
that the produced sliver contains fibres of 35.99<br />
± 10.41 mm length. The PET fibres, which are<br />
the benchmark, have a 3-times as high tenacity<br />
F t<br />
= 76.61 cN/tex and only half the elongation at<br />
break ε b<br />
= 18.55 %.<br />
Ring spinning<br />
80,00<br />
60,00<br />
40,00<br />
20,00<br />
Production energy energy consumption in MJ/kg in MJ/kg<br />
Ring spinning is performed using a 100 % PLA<br />
sliver. The machine settings including a factorial<br />
design are shown in Table 3.<br />
The ring spinning results have high standard<br />
deviations due to manual spinning preparation<br />
and no significance is discernible. Owing to limited<br />
fibre amounts of around 4-8 kg of each batch an<br />
industrial carding machine is not suitable and a<br />
laboratory carding machine has to be used. This<br />
laboratory carding machine only produces nonwovens<br />
and no slivers. The non-wovens are folded<br />
to slivers of1 m and a weigth of 30 g. Due to this<br />
discontinuous process the sliver pieces have to<br />
be joined. Especially within its connecting areas,<br />
thick and thins places occur in the final sliver. An<br />
autoleveller gillbox can limit thin and thick places<br />
in a sliver to a certain amount but the unevenness<br />
in the slivers is too high for the autoleveller gill to<br />
fully reconcile it.<br />
Due to the manual spinning preparation, two<br />
rovings were fed in simultaneosly into the drafting<br />
unit, in order to increase the evenness of the sliver.<br />
The trials were carried out in an air-conditioned<br />
hall at a room temperature of T = 25 °C and a<br />
relative humidity of ρ = 47 %. Within the trials,<br />
it was proved that ring spinning yarn with 100 %<br />
PLA is possible at v pr<br />
= 10 m/min. Frequent yarn<br />
breakage and no stable ring spinning process<br />
occurred at a production speed of v pr<br />
= 15 m/min<br />
and the twist factor α m<br />
= 80 T/m.<br />
PLA PLA<br />
PES PES<br />
4,00 4,00<br />
3,00 3,00<br />
2,00 2,00<br />
1,00 1,00<br />
0,00 0,00<br />
Table 1: Properties of cotton and PES as benchmark<br />
Specific<br />
gravity<br />
[g/cm³]<br />
Tenacity<br />
[cN/tex]<br />
Moisture<br />
content<br />
[%]<br />
Melting<br />
point [°C]<br />
Elastic<br />
recovery<br />
[5 %<br />
strain]<br />
Cotton 1.39 45 – 55 0.2 – 0.4 255 – 265 65<br />
PES 1.52 20 – 40 7 – 8 - 52<br />
Table 2: Fibre properties of Batch 03 after different processing steps<br />
Processing step<br />
Staple fibre<br />
length L sf<br />
[mm]<br />
Tenacity F f<br />
[cN/tex]<br />
Elongation at<br />
break ε b<br />
[%]<br />
Filament - 27.94 ± 5.44 40.34 ± 10.41<br />
Cut/crimped 41.53 ± 5.57 23,95 ± 5.15 38.81 ± 13.04<br />
Sliver (carding) 35.99 ± 10.41 24.45 ± 5.75 39.16 ± 10.18<br />
Table 3: Machine and processing parameters for ring yarn from<br />
batch 03 (factorial design)<br />
Machine Zinser Impact 72<br />
Ring traveller HEL 1 hr EMT SS 1/0<br />
Production<br />
rate<br />
[m/min] 15 20 25<br />
Twisting<br />
factor α m<br />
[T/m] 80 100 80 100 80 100<br />
Yarn count<br />
T t<br />
[tex] 24.8 21.2 24.<strong>05</strong> 24.4 - 28.2<br />
Tenacity F f<br />
[cN/tex] 12.16 12.96 13.78 12.6 - 10.8<br />
Elongation ε [%] 21.3 21.8 22.7 21.6 - 21.6<br />
Evenness<br />
CVm<br />
Production greenhouse gas gas in CO in 2<br />
CO eg./kg 2<br />
eg./kg<br />
PES PES<br />
-60%<br />
PLA PLA<br />
[%] 21.2 23.2 20.2 20.7 - 19.4<br />
Hairiness H - 10.76 8.99 - 8.14 - 8.26<br />
PLA PLA<br />
PES PES<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 19
Fibres & Textiles<br />
Batch 03 while setting up a twist factor to α m<br />
= 80 T/m reaches given<br />
values of T t<br />
= 25 tex most closely. The necessary yarn count is reached at a<br />
production speed of v pr<br />
= 20 m/min. (Fig. 2)<br />
The measured elongation values show a high variation (Fig. 3) and no<br />
link between elongation and production speed can be determined. At<br />
twist factor of α m<br />
= 80 T/m and a production speed of v pr<br />
= 23 m/min a high<br />
amount of yarn breakage occurred. Therefore is it recommended to use a<br />
higher twist factor of α m<br />
= 100 T/m<br />
Fig. 3: Elongation of ring<br />
spinning yarn from batch 03<br />
29,0 —<br />
27,0 —<br />
25,0 —<br />
23,0 —<br />
21,0 —<br />
19,0 —<br />
Measuring<br />
head =<br />
10 N<br />
Clip type =<br />
4g<br />
Clamping<br />
length =<br />
50 mm<br />
V prüf =<br />
50 mm/min<br />
≙ 0,50 cN/tex<br />
The count-related tenacity of batch 03 ring spun yarn has rather high<br />
deviations for all different yarns. The reason for this is the unevenness of<br />
the sliver which is immanent to the manual production step.<br />
17,0—<br />
0,0 —<br />
α m<br />
= 80<br />
α m<br />
= 100<br />
Decrease in<br />
force =<br />
50 %<br />
V pr<br />
The hairiness of the ring spun yarn from batch 03 is shown in Fig. 5. At a<br />
twist factor α m<br />
= 80 T/m, a value of 10.7 is achieved. The higher twist factor<br />
of α m<br />
= 100 T/m and the production speed of v pr<br />
= 20 m/min achieve the<br />
recommended minimal hairiness of H = 8.14.<br />
Due to the manual production of the sliver, the evenness of ring spun yarn<br />
of batch 03 reaches values of CVm = 26.9 %. Batch 03 shows decreasing<br />
CVm-Values, independent from the twisting factor, with increasing<br />
production rate.<br />
Conclusion and outlook<br />
PLA staple fibres are a possible alternative as a substitution of existing<br />
synthetic fibre products. At the current state of the project, Ring spinning<br />
yarn of 100 % PLA was successfully produced. The article presents the<br />
results from the laboratory analysis of the produced ring spinning yarn. A<br />
yarn count of T t<br />
= 25 tex was achieved with optimised production parameters.<br />
The scientific findings from the performed experiments suggest that the<br />
higher twist factor α m<br />
= 100 T/m and production speed of v pr<br />
= 20 m/min are<br />
good production parameters to achieve the yarn properties which the SPEY<br />
project aims for. Further experiments on ring and rotor spinning machines<br />
and the production of a woven fabric with the experimental PLA yarns will<br />
be performed in <strong>2017</strong>.<br />
Acknowledgement<br />
Fig. 4: Count-related tenacity of<br />
ring spinning yarn from batch 03<br />
18,0 —<br />
17,0 —<br />
16,0 —<br />
15,0 —<br />
14,0 —<br />
13,0 —<br />
12,0 —<br />
11,0 —<br />
10,0 —<br />
9,0 —<br />
0,0 —<br />
α m<br />
= 80<br />
Fig. 5: Hairiness of ring<br />
spinning yarn from batch 03<br />
α m<br />
= 100<br />
15 m/min<br />
20 m/min<br />
23 m/min<br />
Measuring<br />
head =<br />
10 N<br />
Clip type =<br />
4g<br />
Clamping<br />
length =<br />
50 mm<br />
V prüf =<br />
50 mm/min<br />
≙ 0,50 cN/tex<br />
Decrease in<br />
force =<br />
50 %<br />
V pr<br />
15 m/min<br />
20 m/min<br />
23 m/min<br />
Grateful acknowledgement goes to the research association<br />
Forschungskuratorium Textil e. V., a branch of the German Federation of<br />
Industrial Research Associations (AiF), for the financial funding — through<br />
AiF-CORNET — of the research project AiF-No. 153 EN SPEY. Grateful<br />
acknowledgement goes also to the company Schlafhorst, branch office of<br />
Saurer Germany GmbH & Co. KG, for providing their expertise and assets<br />
for performing the ring spinning trials.<br />
References:<br />
[1] Euratex, The EU-27 Textile and Clothing Industry in the year 2012, May 2013<br />
[2] Position of the European Textile and clothing industry and its applied research community<br />
on support for SME Research & Innovation under Horizon 2020. Euratex, March 2012<br />
[3] IVC Jahresbroschüre 2013 Chemiefaserzahlen und Baumwolle-Wolle<br />
11,5 —<br />
11,0 —<br />
10,5 —<br />
10,0 —<br />
9,5 —<br />
9,0 —<br />
8,5 —<br />
8,0 —<br />
7,5 —<br />
0,0 —<br />
α m<br />
= 80<br />
α m<br />
= 100<br />
V prüf =<br />
50 mm/min<br />
t prüf =<br />
1 min<br />
Principle:<br />
optical<br />
V pr<br />
15 m/min<br />
20 m/min<br />
23 m/min<br />
[4] http://www.natureworksllc.com/the-ingeo-journey/Eco-Profile-and-LCA/Eco-Profile.<br />
aspx#GHG<br />
[5] Uster statistics, http://www.uster.com/en/service/uster-statistics/, visited on May 27th, 2014<br />
www.ita.rwth-aachen.de<br />
Fig. 2: 29,0 —<br />
Yarn count<br />
28,0 —<br />
of ring<br />
spinning<br />
27,0 —<br />
yarn from 26,0 —<br />
batch 03<br />
25,0 —<br />
24,0 —<br />
23,0 —<br />
F V<br />
=<br />
0,5 cN/tex<br />
Reel length =<br />
10 m<br />
Figure 4.1 Evenness of ring<br />
spinning yarn from batch 03<br />
31,0 —<br />
29,0 —<br />
27,0 —<br />
25,0 —<br />
23,0 —<br />
21,0 —<br />
V prüf =<br />
100 mm/min<br />
t prüf =<br />
1 min<br />
Principle:<br />
capacitive<br />
22,0 —<br />
19,0 —<br />
21,0 —<br />
V pr<br />
17,0—<br />
V pr<br />
20,0—<br />
0,0 —<br />
α m<br />
= 80<br />
α m<br />
= 100<br />
15 m/min<br />
20 m/min<br />
23 m/min<br />
0,0 —<br />
α m<br />
= 80<br />
α m<br />
= 100<br />
15 m/min<br />
20 m/min<br />
23 m/min<br />
20 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Industrial Solutions<br />
Polylactide Technology<br />
Uhde Inventa Fischer Polycondensation Technologies has expanded its product portfolio to<br />
include the innovative state-of-the-art PLAneo ® process for a sustainable polymer. The<br />
feedstock for our PLA process is lactic acid, which can be produced from local agricultural<br />
products containing starch or sugar. The application range of PLA is similar to that of polymers<br />
based on fossil resources as its physical properties can be tailored to meet packaging, textile<br />
and other requirements. www.uhde-inventa-fischer.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 21
Fibres & Textiles<br />
The FIBFAB project<br />
New biodegradable fibres from renewable<br />
sources for fabrics with advanced properties<br />
The FIBFAB project, coordinated by AIMPLAS (Valencia,<br />
Spain), will allow obtaining sustainable textile fibres<br />
to replace polyester with advantages such as higher<br />
breathability, lower weight, better tinting and UV ray resistance.<br />
The new fabrics can be easily recycled at the end of<br />
their life, since they do not contain blends of natural and<br />
synthetic fabrics. They may even be composted thanks to<br />
their biodegradability.<br />
Around one million tonnes of fabrics used for clothing<br />
applications are produced each year in Europe by yarn<br />
spinning combining natural fibres (such as cotton or wool)<br />
and synthetic fibres (such as polyester). These blends of<br />
natural fibres and synthetics are generally prepared to<br />
improve comfort and durability aspects of the end products.<br />
However, these standard fabrics are complex to recycle<br />
after their use since both types of fibres are intermingled<br />
and cannot be separated again.<br />
Companies in the textile industry are challenged today<br />
to make a radical shift towards innovative and high added<br />
value products to counter the competition with low-wage<br />
countries. In this context, the FIBFAB project has been<br />
initiated to successfully launch and industrialize the<br />
production of biodegradable and sustainable polylactic<br />
acid (PLA) based fabrics (wool/PLA and cotton/PLA) for<br />
the applications in casual (menswear and womenswear),<br />
protective and workwear clothing, and to overcome the<br />
current limitations of PLA fibres as a real alternative to<br />
current fabrics (wool and cotton combined with polyester<br />
fibres). This improvement will be carried out by applying<br />
the knowhow and methodology developed in prior European<br />
projects BIOFIBROCAR and BIOAGROTEX.<br />
More breathability, lower weight, better tinting<br />
and UV rays resistance<br />
The main objectives of the FIBFAB project are: to<br />
obtain a final clothing product 100 % biobased and<br />
biodegradable that meets the mechanical and performance<br />
requirements of the textile sector in correspondence with<br />
the final applications. Besides, it is expected to improve<br />
the current poor thermal resistance of PLA fibres to meet<br />
the requirements in several clothing applications by the<br />
technology developed in previous EU projects to enhance<br />
the final PLA crystallinity.<br />
Regarding the PLA fibre manufacturing process, the<br />
processing parameters will be optimized to have thinner<br />
fibres (less than 3 dtex) and especially the mechanical<br />
spinning process (friction control in ring spinning) to be able<br />
to spin PLA blend fibres at higher speeds. This will allow<br />
the introduction to the textile market yarns and fabrics<br />
produced from PLA fibres and cotton or wool with important<br />
advantages, such as better breathability, better hydrophilic<br />
properties to make easier the tinting process, a higher<br />
resistance to degradation by UV rays, low smoke production<br />
and flammability and lower density than PES, what causes<br />
a lower fabric weight.<br />
This project has received funding from the European<br />
Union’s Horizon 2020 Fast Track Innovation Pilot programme<br />
(H2020-FTIPilot-2016-1) under grant agreement No<br />
737882. This project has a duration of 24 months and these<br />
are the participant companies: CENTEXBEL, DS Fibres<br />
(Belgium), Yünsa (Turkey) and SINTEX (Czech Republic).<br />
Together with AIMPLAS, these consortium members<br />
cover the entire textile value chain, from fibre production<br />
to clothing manufacturing, thus ensuring the industrial<br />
implementation of PLA fibres.<br />
The FIBFAB project is one of the 15 funded projects of a<br />
total of 280 projects proposals that were submitted in the<br />
fifth round of the scheme. From these 15 projects, only four<br />
include Spanish partners in their consortiums and FIBFAB<br />
is the first project in the Valencian Community to be funded<br />
in this programme. MT<br />
http://fibfab-project.eu<br />
In each season two different collections are prepared for all<br />
customers by following key fashion terms of American &<br />
European trends.<br />
Fibre spinning<br />
22 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Automotive<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 23
Production<br />
Reducing PLA production cost<br />
Earlier this year at a bioplastics conference in Bangkok,<br />
“Jem’s Law” about the growth of the PLA market was<br />
presented. Jem’s Law basically says that PLA volumes<br />
doubled every 3 to 4 years in the past and therefore will<br />
continue to do so in the future. With some knowledge of<br />
the actual production capacities one can calculate that the<br />
PLA market will be around 600,000 t/a in 2022 / 2023. All<br />
in all, this would mean that there is a need for 5 additional<br />
PLA plants with a capacity of 75,000 t/a until 2022. This is a<br />
promising perspective, not only for an engineering company<br />
like Uhde Inventa-Fischer, a subsidiary of thyssenkrupp<br />
Industrial Solutions. Even though all forecasts have to<br />
be treated with the necessary caution, Jem’s Law can be<br />
considered fairly realistic compared with earlier ones about<br />
the markets for bioplastics.<br />
PLA economics: size, price, efficiency<br />
If PLA plants are to be built in the future, economics<br />
will of course play a crucial role. Besides the well-known<br />
factors of plant size (the bigger the better) and feedstock<br />
prices (the lower the better), raw material conversion –<br />
which determines specific feedstock demand – must not be<br />
neglected.<br />
What factors influence the conversion of lactic acid to PLA?<br />
One is the formation of side-products. In the case of PLA,<br />
provided one uses the right catalyst, this is comparatively<br />
low. In practice more than 95 % of what is theoretically<br />
possible can be converted into lactide and polylactide.<br />
Unwanted meso-lactide increases production<br />
cost<br />
But lactic acid is an optical active substance with a<br />
L(+)- and a D(-)-configuration, and three different types<br />
(enantiomers) of lactides: L-lactide, D-lactide and mesolactide.<br />
Each one results in different PLAs in terms of<br />
properties and processing behavior. The repartition of the<br />
enantiomers in the lactide feedstock determines PLA<br />
properties like crystallinity/crystallization time to a major<br />
extent and consequently also heat distortion temperature<br />
and hydrolysis resistance.<br />
What’s more, the lactide composition cannot be adjusted<br />
to the desired level without separation of meso-lactide, the<br />
lactide enantiomer with a L(+)- and a D(-)-configuration.<br />
Using optically pure L(+)-lactic acid is not sufficient to<br />
obtain an optically pure lactide. Racemization of L-lactide<br />
(or D-lactide), mainly during depolymerization of lactic acid<br />
polycondensate to lactide, leads to the formation of mesolactide.<br />
In many applications a small percentage of mesolactide<br />
is advantageous. But there are also applications<br />
where meso-lactide should be as low as possible. And it<br />
appears that their share is growing, for example in durables<br />
and most fibers, or if high heat is required. In general more<br />
meso-lactide is produced than is needed.<br />
This raises the question of what to do with the surplus<br />
meso-lactide. To write it off as a loss is not an option as<br />
this would increase production cost severely. Fig. 1 shows<br />
production cost as a function of raw material conversion.<br />
A loss of 10 % due to racemization leads to a decrease<br />
in conversion from 96 % to 83 % which in turn increases<br />
production cost by more than 12 % (all calculations based<br />
on Uhde Inventa-Fischer’s PLAneo ® technology for an<br />
industrial scale plant on a European price basis).<br />
Selling or downgrading back to lactic acid have<br />
drawbacks.<br />
A better option is to hydrolyze meso-lactide back to<br />
lactic acid. Technically this is not a challenge. But due to<br />
its racemic nature the quality of the lactic acid is lower<br />
than the feedstock lactic acid. It goes without saying that<br />
the conversion of a high grade lactic acid into a low grade<br />
one is economically unfavorable. Besides bad economics a<br />
producer of PLA has the drawback of having to deal with two<br />
completely different markets – selling PLA on the one hand<br />
120%<br />
Fig 1: Production cost as a function of raw material conversion<br />
VAC<br />
Fig 2: Process flow diagram of<br />
thyssenkrupp’s PLAneo process<br />
Increase in Production Cost<br />
115%<br />
110%<br />
1<strong>05</strong>%<br />
100%<br />
Crude<br />
Lactide<br />
Meso-Lactide<br />
Purrification<br />
PLAneo ®<br />
95%<br />
75%<br />
80% 85% 90% 95% 100%<br />
Lactic Acid Conversion: Percentage of theoretical maximum<br />
L-Lactide<br />
Purrification<br />
Ring Opening<br />
Polymerisation<br />
Demonomerisation<br />
24 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Production<br />
By:<br />
Udo Mühlbauer<br />
thyssenkrupp Industrial Solutions<br />
Uhde Inventa-Fischer GmbH<br />
Berlin, Germany<br />
and lactic acid for example to the cosmetics industry on the<br />
other (unless he is already a lactic acid producer).<br />
An even better option would be to sell meso-lactide as a<br />
chemical intermediate or monomer for different applications<br />
and to different markets – with the aim of achieving higher<br />
prices. As meso-lactide has not existed as a commercial<br />
product before, there is no established market. New<br />
applications have to be developed and markets have to be<br />
found. Whether these markets will develop and to what size<br />
remains to be seen.<br />
Using polymerized meso-lactide to form a single<br />
product: PLAneo<br />
The solution that Uhde Inventa-Fischer has developed<br />
initially appears obvious: like L-lactide, meso-lactide is<br />
purified and polymerized. This is easier said than done. Beside<br />
the fact that meso-lactide is much more sensitive to sidereactions<br />
than usual polymer-grade lactide, the molecular<br />
weight of poly-meso-lactide has to be comparatively high in<br />
order to obtain good mechanical properties. Both facts add<br />
up to stringent requirements for the purity of polymer-grade<br />
meso-lactide.<br />
The second step of the PLAneo technology is not as obvious.<br />
Instead of producing a second polymer, which would have<br />
limited possible application due to its amorphous nature,<br />
polymeso-lactide is blended with the main crystallizable<br />
PLA-melt, both polymerized continuously in parallel lines,<br />
to give one product.<br />
Optimized yield, same product properties<br />
The resulting polymer maintains all relevant mechanical,<br />
optical and physical properties: tensile strength, E-modulus,<br />
crystallization behavior and melting point do not change.<br />
Only the b*-value of the PLA pellets is slightly increased.<br />
This holds true irrespective of whether distillation or<br />
crystallization is used to purify the main lactide stream.<br />
Processing of PLAneo PLA is just as straightforward as<br />
standard PLA.<br />
Applying separate polymerization of meso-lactide and<br />
L-Lactide and blending it afterwards means no meso-lactide<br />
has to be discarded or used in a less economical way. The<br />
specific demand of lactic acid converges to its theoretical<br />
minimum of 1.25 kg per kg of PLA.<br />
Nobody knows exactly how the PLA market will develop.<br />
We will see whether Jem’s law will continue to prove<br />
true in the future and how many new plants will come on<br />
stream. But the ones using technology that maximizes<br />
raw material yield will definitely have an advantage.<br />
www.uhde-inventa-fischer.com<br />
201 200<br />
Fig 3: Comparison of PLA properties with and without<br />
amorphous PLA contingent<br />
D-<br />
Content<br />
[%]<br />
Intrinsic<br />
Viscosity<br />
[dl/g]<br />
Residual<br />
Monomer<br />
[%]<br />
Tm<br />
[°C]<br />
b*-<br />
Value<br />
[-]<br />
Haze<br />
[%]<br />
159 160<br />
4069<br />
3881<br />
cPLA PLAneo ® bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 25<br />
Fig 4: Comparison of BOPLA film<br />
properties with and without<br />
amorphous PLA contingent<br />
4201 4265 96<br />
113<br />
85<br />
100<br />
PLA 2 1.87 < 0.02 162 4 0.38<br />
PLAneo 5 1.87 < 0.02 162 6 0.35<br />
MD TD MD TD<br />
MD TD<br />
Tensile Strength<br />
[N/mm²]<br />
E-Modulus [N/mm²]<br />
Elongation at<br />
Break[%]
Application AutomotiveNews<br />
Grasping at bioplastic straw<br />
Switzerland’s Sukano, a leading producer of additive and<br />
colour masterbatches and compounds for polyester and<br />
specialty resins, and NatureWorks have collaborated on the<br />
development of an eco-friendly material suitable for making<br />
drinking straws from.<br />
Formerly made of paper, modern day straws, are mainly<br />
made from polypropylene and present a variety of technical<br />
challenges for alternative new materials seeking to bring<br />
new functionality.<br />
For example, the narrow, U-shaped straws for juice boxes<br />
must be articulated and have a high flexibility modulus. During<br />
manufacturing, edges must be cut smoothly to prevent<br />
unsafe sharp or rough rims, while visual aesthetics, such as<br />
transparency, are also critical. These are just a few of the<br />
many specifications new materials must meet for adoption<br />
into this market application.<br />
The demand for disposable straws is expected to grow,<br />
driven in part by consumer demand for convenience, meals<br />
on the go, and the consumption of specialty drinks – hence<br />
the potential for materials that provide complete, responsible<br />
lifecycle solutions while providing the desired functionality<br />
is huge.<br />
So, when Sukano and PLA manufacturer NatureWorks,<br />
got together, a new, broad market opportunity was born.<br />
Bioplastics like polylactic acid (PLA) have long been<br />
viewed as sustainable in sourcing, manufacture and afteruse<br />
– but, until today, they were unable to meet the market’s<br />
performance requirements to replace the use of polypropylene<br />
in this application. Sukano masterbatches reduce<br />
the brittleness of PLA, which allows precise cutting during<br />
production and avoids splintering and rough edges. Combining<br />
melt enhancer additives in Ingeo-based PLA masterbatches,<br />
Sukano’s concentrates promote dimensional<br />
stability and greater flexibility without cracking at temperatures<br />
of 110° to 120°C. The additive masterbatches formulations<br />
are also designed to maintain the high transparency<br />
required in straws.<br />
“We are thrilled that this collaboration between key players<br />
in the value chain allows us to bring an innovative alternative<br />
to the market. Using our combined experience, we<br />
are able to modify Ingeo PLA to customize its performance<br />
for a new end market – providing benefits to consumers and<br />
companies,” said Alessandra Funcia, Head of Marketing at<br />
Sukano.<br />
“At NatureWorks, we are helping to rethink plastics. The<br />
replacement of conventional oil-based polypropylene by Ingeo<br />
in drinking straws is just one example of how bioplastics<br />
can help address sustainability, while still providing the<br />
high-performance material required for this application,”<br />
concluded Steve Davies, Commercial Director – Nature-<br />
Works Performance Packaging. MT<br />
www.natureworksllc.com | www.sukano.com<br />
First meal set<br />
Beatrice and Daniele Radaelli, founders of eKoala (Cavenago di Brianza, Italy), have decided to look at the world of plastic<br />
materials from a different point of view, driven by liability and environmental sustainability. “When both my brother and I became<br />
parents we soon understood the limits and the dark sides of traditional plastic and we started looking for new materials that<br />
could have the same glamour of those colourful plastic granules which stimulated our fantasy as kids, but at the same time,<br />
could be safe for our children and for the environment they would live in. After months of research we finally found what we<br />
were looking for…”<br />
The bioplastics of eKoala are based on Novamont’s Materbi and do not<br />
contain any toxic substances and are biodegradable. They are the ideal<br />
products for those who consider responsibility as a key factor for their buying<br />
behaviour and choose to leave a better world to future generations. “We put<br />
our childrenshealth first”, as Beatrice put it. Babies and kids are the weakest<br />
link but also the future of our planet. For this reason, eKoala uses only natural<br />
raw materials free from any toxic substance.<br />
One of the products recently added to their range of bioplastics products is<br />
the eKeat – First Meal Set. Other products include drinking cups, teethers and<br />
more. MT<br />
www.ekoala.eu<br />
26 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Application Automotive News<br />
Organic chair<br />
The new Kartell Organic Chair uses a revolutionary new<br />
organic plastic material to create a sustainable item of<br />
furniture that is high quality and highly creative.<br />
Designed by Antonio Citterio (Italian architect, furniture<br />
designer and industrial designer who lives and works in<br />
Milan), Kartell’s Organic Chair is made from BIODURA, a<br />
PHA-based material from Sabio Materials (Italy) obtained<br />
from renewable raw materials. The raw material is organic in<br />
nature and comes from renewable plant-based sources that<br />
will not disrupt food production.<br />
The material is a result of different processes that make it a<br />
very high-quality compound that Kartell has injection moulded<br />
just like other plastics: a first in the world of furniture.<br />
Kartell has therefore come up with a sustainable design<br />
in line with its industrial philosophy based on the concept of<br />
quality and durability. Ideally, at the end of its working life,<br />
in the right conditions, the Organic Chair can re-enter the<br />
biological cycle or biodegrade.<br />
Organic Chair is perfect for both indoor and outdoor use<br />
as it is extremely durable, which also makes it perfect for the<br />
contract market. MT<br />
www.spacefurniture.com.au/kartell.html<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 27
Application News<br />
Pet food bags<br />
Midwestern Pet Foods is<br />
packaging its newly launched<br />
Earthborn Holistic Venture line in<br />
sustainable packaging produced<br />
by Peel Plastics Products Ltd.,<br />
utilizing Braskem’s I’m Green TM<br />
biobased polyethylene (PE).<br />
In an effort to mitigate the carbon footprint associated with<br />
its product, Peel Plastics has chosen to use biobased PE to<br />
manufactures the new Earthborn Holistic Venture pet food<br />
bags.<br />
The company said it was “very happy” to partner with<br />
Midwestern Pet Foods, a long-standing customer, and with<br />
Braskem, in its striving to as focus on “advanced solutions for<br />
sourcing renewable packaging materials”.<br />
Consumer response to the new PlantBag, said Jeff Nunn,<br />
Midwestern Pet Foods President, has been overwhelmingly<br />
enthusiastic.”<br />
According to Gustavo Sergi, Renewables Director at<br />
Braskem, North America is gaining momentum in terms<br />
of its use of sustainable green PE. “It is encouraging that<br />
North America is catching up to other regions of the world<br />
with visionary companies such as Midwestern Pet Foods and<br />
Peel Plastics taking the lead to a more sustainable consumer<br />
lifestyle,” he said.<br />
“Stay tuned, you will only see more of these launches in the<br />
coming months and years.”<br />
www.braskem.com<br />
Bioplastic toys<br />
Plasto, a toy company<br />
in Finland has over 60<br />
years of experience in<br />
manufacturing high quality<br />
plastic toys. Their focus is<br />
very strong on safety and<br />
durability. Furthermore,<br />
they are extremely focused<br />
on environmental values. For several decades they have<br />
been using recycled plastic from their own production in<br />
order not to waste any material and they keep on investing<br />
more to save the environment and be good to nature. In<br />
spring <strong>2017</strong>, Plasto launched their own I’m Green toy<br />
range. All the toys in this range are over 90 % biobased.<br />
The raw material which is used derives from sugar cane.<br />
By doing this, Plasto will significantly reduce the carbon<br />
footprint of its toys as well as the use of fossil resources.<br />
For every kg of I’m Green Polyethylene used in Plastos’<br />
toys more than 5 kg of CO 2<br />
is saved. The toys are food<br />
contact safe and dishwasher safe. At the end of their life<br />
cycle they can be recycled and the raw material can be<br />
reused which is in accordance with Plasto’s philosophy.<br />
The I’m Green toys have been extremely well received.<br />
For Christmas Plasto will be expanding it’s range with<br />
new items.<br />
”Our I’m Green toy range has been extremely well<br />
received by our customers. We have expanded our I’m<br />
Green range with crane and fire truck already for this<br />
Christmas. We are proud to offer a sustainable choice,”<br />
says Kennet Berndtsson, Managing Director at Plasto.<br />
MT<br />
www.braskem.com | www.fkur.com | www.plasto.fi<br />
PHA for eyeglass frames<br />
Bio-on, (Bologny, Italy) recently announced a partnership<br />
with Kering Eyewear to develop new materials based on<br />
Minerv PHAs. “This is the first time in the world that a<br />
company in the eyewear industry has decided to carry out<br />
research with our biopolymers,” explains Marco Astorri,<br />
Chairman and CEO of Bio-on.<br />
Kering Eyewear’s aim is to make an active contribution<br />
to the development of an innovative and sustainable<br />
business model, providing its team of designers with a<br />
series of cutting-edge materials to broaden their creative<br />
possibilities, setting new trends in the luxury and sport &<br />
lifestyle segments. Researchers from the two companies<br />
will collaborate to design, certify and put on the market new<br />
eco-sustainable materials to be integrated with the use of<br />
cellulose acetate, one of the most common materials used<br />
in the majority of the eyewear products on the market to<br />
date.<br />
“We are proud to be the first in the world to use our<br />
PHAs biopolymer together with such a prestigious and<br />
internationally renowned company as Kering Eyewear.<br />
Thanks to this collaboration, we are launching a new era<br />
in the eyewear world,” says Marco Astorri. “The union<br />
of creativity and technology will give rise to items with<br />
absolutely innovative characteristics. Our laboratories and<br />
scientists will develop a vast range of new formulations,<br />
giving free rein to the creativity of the most discerning<br />
designers.”<br />
“The partnership with Bio-on represents a tangible<br />
sign of Kering Eyewear’s attention to sustainability and its<br />
desire to bring innovation to a consolidated industry. In our<br />
Group,” explains Roberto Vedovotto, Chairman and CEO<br />
of Kering Eyewear, “we strongly<br />
believe that ‘sustainable business<br />
is smart business’. The materials<br />
developed by Bio-on, 100% natural<br />
and biodegradable, will be a<br />
revolution in the eyewear industry<br />
and completely dovetail our unique<br />
approach to the market, as well as<br />
our desire to offer increasingly high<br />
quality and innovative products. In<br />
the luxury sector, sustainability and<br />
environmental awareness are no<br />
longer an option, they are a must.”<br />
MT<br />
www.bio-on.it | www.kering.com<br />
Roberto Vedovotto<br />
(Photo: Albrecht Fuchs)<br />
28 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Application News<br />
Your city - your cup<br />
Coffee to take away<br />
or beer in the stadium<br />
- we like to drink on the<br />
go. Usually such a drink<br />
comes in plastic or paper<br />
cups. Reusable cups can<br />
be reused very often (up<br />
to 500 times - or more)<br />
and are therefore more<br />
environmentally friendly<br />
(says DUH, Deutsche<br />
Umwelthilfe). Even the<br />
environmental impact of its production is comparatively<br />
low over the entire product life cycle.<br />
That is why the German company Bunzl from Marl<br />
initiated the Düsseldorf Becher (Düsseldorf Cup), a system<br />
of reusable cups that can be purchased in one store and<br />
returned in another. A total of 80 stores already participate<br />
in the system, including bakeries, cafés and restaurants.<br />
And what makes the Düsseldorf Cup special is the<br />
material. The 350ml cup is made of CPLA. Since PLA is not<br />
a heat-resistant product, for CPLA talc powder is added<br />
and helps the PLA to crystallize. This the C stands for<br />
crystallized PLA. CPLA consists of 70-80 % of PLA and 20-<br />
30 % of talc powder. The cups are biodegradable according<br />
to EN13432 without the release of pollutants, however,<br />
not home compostable. It is BPA-free. The cup shows a<br />
high temperature resistance range: -20 °C - 100 °C. It is<br />
microwaveable and dishwasher safe. MT<br />
www.bunzl.de<br />
The partners are spread all over Düsseldorf , Germany<br />
(Source: Google MyMaps)<br />
How about going bio?<br />
For almost every conventional plastic, there is a bioplastic alternative.<br />
Our PLA masterbatches can help introduce PLA into your portfolio.<br />
Make the switch today.<br />
www.sukano.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 29
Materials<br />
New compostable PHA<br />
based compound from Canada<br />
Bosk Bioproducts offers a new generation of<br />
“Clean Plastic”<br />
For more than 10 years, researchers at the INRS in Quebec<br />
(Canada) have been developing a biotechnology to<br />
produce PHA (polyhydroxy alkanoate), a biopolymer that<br />
can replace conventional plastic. What makes Bosk’s Clean<br />
plastic so different? The PHA is produced from by-products<br />
from the Pulp and paper industry. Bosk’s objective is to ensure<br />
accessibility to the objects of everyday life without jeopardizing<br />
the sustainability of the planet. Recently at BIO <strong>2017</strong>, Bosk<br />
presented its clean plastic business model regrouping different<br />
lines of compounds dedicated to the plastic industry and<br />
consumers wanting sustainable products.<br />
Regen, compounds for plastic truly compostable<br />
As we speak, the only solution that avoids the accumulation<br />
of plastics is composting. The Regen compounds series<br />
of Bosk’s bioplastic is fully compostable. Based on Bosk’s<br />
proprietary PHA, and a choice of eco-friendly ingredients, the<br />
Regen compounds can be used for finished products from<br />
standard processes like injection, extrusion or thermoforming.<br />
These Regen compounds can finally meet the most stringent<br />
requirements in terms of standards for composting. At the<br />
end of their useful life, objects made with Bosk’s Regen<br />
compounds can be designed to be thrown into industrial or<br />
home composting facilities. This sustainable method of plastic<br />
disposal promotes by natural processes the regeneration of<br />
plastic components in nutrients and other constituents into<br />
our environment without toxic impact.<br />
Compostable, but also durable<br />
No need to worry about product durability. PHA adds a<br />
clever blend of ingredients to meet consumer demands<br />
while ensuring compostability at home or at industrial sites.<br />
Degradation begins only when the object is in contact with<br />
the natural bacteria living in the soil and the time required<br />
for degradation can be as short as a few weeks up to a few<br />
months.<br />
Plastic designed to reduce our impact on the<br />
environment<br />
Moreover, in order to obtain the most natural product and<br />
reduce its impact on the environment, this new generation<br />
of plastic does not originate from GMOs nor does it contains<br />
toxic additives such as BPA and phtalates. When compared to<br />
the production of conventional plastic, this bioplastic makes it<br />
possible to reduce the carbon footprint. And here’s the icing<br />
on the cake: the raw material of this plastic is an untapped<br />
by-product of the pulp and paper industry. Bosk makes no<br />
Life cycle of Bosk’s compostable<br />
plastic finished products<br />
pulp and<br />
paper mill<br />
(partner)<br />
PHA<br />
compostable<br />
plastic<br />
compound<br />
(BOSK)<br />
compostable<br />
plastic<br />
manufacturer<br />
(partner)<br />
compostable<br />
plastic<br />
finished<br />
product<br />
PHA plant<br />
(BOSK)<br />
composting at the<br />
end of the life<br />
of the product<br />
retailer /<br />
consumer<br />
30 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Materials<br />
By:<br />
Paul Boudreault<br />
CEO<br />
Bosk Bioproducts<br />
Quebéc, Canada<br />
compromises. Both the product and the production process<br />
are developed to reduce their impact on the environment.<br />
The goal is to create plastic products that meet the growing<br />
demand from new eco-conscious consumers.<br />
Bosk’s PHA production capacity based on the pulp<br />
and paper industry<br />
Production capacity of Bosk’s PHA is based on the pulp and<br />
paper industry’s investments in product diversification. Bosk<br />
is in discussions with a major P&P company in Canada to<br />
sub-licence the technology and start PHA production. It will be<br />
possible to have a PHA production facility at any P&P mill. “We<br />
are evaluating PHA production facilities to implement in the<br />
next two years from 3,000 and up to 25,000 tonnes/years with<br />
our first P&P partner” said Paul Boudreault, CEO of Bosk at<br />
BIO-<strong>2017</strong> in Montreal. By integrating the technology in existing<br />
P&P mills, it reduces by far capital investment needs and<br />
production costs required for conventional PHA production.<br />
Having developed expertise in compounding this new PHA,<br />
Bosk is now developing customer interest to ensure a market<br />
destination for finished compounds and plastic products. This<br />
new Value-chain model allows Bosk to reduce the distance<br />
between the PHA producer and the eco-conscious consumer.<br />
www.bosk-bioproducts.com/<br />
European Bioplastics<br />
12 TH CONFERENCE<br />
Making the difference<br />
28/29 November <strong>2017</strong><br />
maritim proArte Hotel<br />
Berlin<br />
@EUBioplastics #eubpconf<strong>2017</strong><br />
www.european-bioplastics.org/conference bioplastics MAGAZINE [04/17] Vol. 12 31
Beauty & Healthcare<br />
The power of packaging –<br />
sharpen your USP<br />
In comparison to previous years, the ecological and environmental<br />
awareness of consumers has increased which<br />
makes them think even more carefully before they decide<br />
to buy a product. Ingredients, sustainability, waste reduction<br />
and separation are considered more often. Consumers are<br />
looking at the composition and prefer e.g. shampoos without<br />
silicone or skin care products without mineral oils or<br />
micro plastics. Natural cosmetics are a life style statement<br />
and express the customer´s personality and individuality.<br />
Packaging made from renewable resources not only help<br />
to implement a holistic sustainable approach, which distinguishes<br />
respective brands from cosmetics wrapped in traditional<br />
plastics, but also increase the perception of value.<br />
Traditionally, a huge range of polymers are used for<br />
cosmetic packaging. Bottles are mainly made from HDPE,<br />
sometimes from PP while high transparent materials such<br />
as Polyesters or Polyamides are suitable for jars. As the<br />
packaging is the figurehead of each brand and product,<br />
surface finishing, haptics and visual appearance are key<br />
factors aside from mechanical or barrier properties.<br />
In some cosmetic packaging, several different plastics<br />
are combined in order to meet respective requirements. In<br />
terms of cosmetic bottles for instance, PE is used for the<br />
hollow part, PP for the cap and even the label is made from<br />
a different material or material combination. In order to<br />
increase the recyclability of such a product while being in<br />
accordance with a circular economy, more mono materials<br />
should be used. The product solution of Speick´s Natural<br />
Cosmetics (Leinfelden-Echterdingen, Germany) follows<br />
this logic trend in a smart way by using Green PE for all<br />
three parts of the packaging and therefore enables ease of<br />
recycling.<br />
Of course, raw material costs can be higher compared to<br />
existing fossil based polymers being used. But, is a cheap<br />
price really a unique selling proposition (USP)? Usually<br />
such products are easily replaced by a competitor who<br />
is able to produce at an even lower cost. To stay ahead of<br />
competition respective marketing and sales strategies are<br />
needed which are increasingly more independent from the<br />
price driven argumentations. A USP needs to be evaluated<br />
and communicated clearly to end consumers. In order to<br />
help consumers identify truly sustainable products and<br />
avoid greenwashing it is possible to verify and confirm the<br />
bio-based content of packaging by external institutions.<br />
The packaging is then clearly labelled with appropriate<br />
certificates or seals. A clear and logical message with high<br />
transparency for the end user is the key for success. This<br />
message can be clearly communicated with biopolymers.<br />
Speick Natural Cosmetics recently chose Braskem´s<br />
I´m green PE for their packaging: “Environmental and<br />
social criteria play a key role in the selection of our raw<br />
materials and packaging. Our products shall be thoroughly<br />
sustainable. It is not easy to substitute plastic wrapping but<br />
we were consequently looking for a possibility to act more<br />
environmental friendly in this case. This is why we are using<br />
bottles made of sugar cane based bioplastics for our Speick<br />
Organic 3.0 product range and we are very pleased with it.<br />
The numerous awards for our product confirm that we are<br />
on the right track.” says Anke Boy, responsible for Marketing<br />
and Product Management of Speick Natural Cosmetics.<br />
As a distribution partner for Braskem S.A. FKuR (Willich,<br />
Germany) is able to offer their „I´m green“polyethylene. Its<br />
properties are identical to conventional PE which makes<br />
The packaging<br />
delivers what<br />
your products<br />
promise:<br />
Cosmetic jars<br />
made from<br />
Biograde offer<br />
a high quality,<br />
pleasant feel<br />
and complement<br />
the message of<br />
a sustainable<br />
cosmetic brand<br />
in a natural way.<br />
32 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Beauty & Healthcare<br />
By:<br />
Patrick Zimmermann,<br />
Director Marketing & Sales<br />
Annette Schuster,<br />
Marketing & Communications Manager<br />
FKuR Kunststoff<br />
Willich, Germany<br />
it very easy for packaging manufacturers to shift from<br />
conventional to bio-based PE because it is not necessary to<br />
change any tool or machine settings. The same also applies<br />
for recycling. Green PE can be recycled with regular PE<br />
without affecting the recycling chain.<br />
The broad portfolio of FKuR offers solutions for bottles,<br />
tubes, films and jars that can be produced using either<br />
renewable or biodegradable plastics. Biobased and<br />
biodegradable materials such as Bio-Flex ® and Biograde ®<br />
are very versatile in their technical performance and<br />
processing methods. Such materials are suitable for cast<br />
film extrusion with subsequent thermoforming and injection<br />
moulding applications. Because of their different haptics,<br />
end consumers will immediately notice the difference<br />
compared to existing oil based materials. Additionally<br />
Green PE, Terralene PP (a partly bio-based PP blend) or<br />
Terraprene (a bio-based TPE) can replace their existing oil<br />
based counterparts easily.<br />
Speick Natural Cosmetics won several international awards<br />
for their integrally sustainable concept including products and<br />
packaging, amongst others, Vivaness Best New Product <strong>2017</strong>,<br />
Green Product Award <strong>2017</strong> and Sustainable Beauty Award 2016<br />
(Foto: SPEICK Naturkosmetik)<br />
www.speick.de | www.fkur.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 33
Beauty & Healthcare<br />
PolyBioSkin The future of biopolymers for<br />
skin-contact healthcare, sanitary, and personal care products<br />
Biopolymers not only reduce our dependency on finite<br />
fossil resources but can also offer higher versatility<br />
in comparison to conventional polymers when<br />
it comes to the possible end-of-life options for products.<br />
Especially for short-term single use products, this endof-life<br />
versatility can be a key sustainability factor. A lot of<br />
large-volume single-use disposable products such as diapers<br />
are currently treated in energy recovery or end up in<br />
landfills. Their reliance on the combination of a number of<br />
different materials as well as their after-use contamination<br />
prevents them from being fully or partially recycled. Most<br />
commercial diapers, for example, use polyolefin topsheets,<br />
and many cosmetic and biomedical skin-contact applications<br />
also still rely on conventional plastic films, which is<br />
one reason for their poor position in the waste management<br />
hierarchy (fig. 1).<br />
Another drawback of the conventional plastic materials<br />
currently used in these types of skin-contact applications<br />
is their tendency to cause skin irritations, inflammations,<br />
and even intolerances. Biopolymers and other bio-based<br />
substances on the other hand offer a high degree of<br />
biocompatibility and other unique features but are still<br />
hugely under-exploited in this field.<br />
PolyBioSkin, a Horizon2020 project coordinated by Spainbased<br />
advanced engineering SME IRIS, aims to develop<br />
both optimal biopolymers and processes for the sanitary,<br />
biomedical, and cosmetic sectors. PolyBioSkin is funded by<br />
the Bio-based Industries Joint Undertaking, a public-private<br />
partnership between the EU and the Bio-based Industries<br />
Consortium with the goal of realising the full potential of the<br />
bioeconomy in Europe to reduce its dependency on fossilbased<br />
products, tackle climate change challenges, and lead<br />
to greener and more environmentally friendly growth.<br />
PolyBioSkin will deliver: (i) A biodegradable diaper<br />
consisting of an antimicrobial bio-based topsheet beneficial<br />
for the skin and a bio-based superabsorbent layer; (ii) novel<br />
facial beauty masks based on textiles or films made from<br />
bio-based and biodegradable polymers and impregnated<br />
with molecules beneficial for the skin; (iii) nano-structured<br />
highly skin-compatible non-woven textiles for wound<br />
dressings. To achieve the ambitious goal of greatly advancing<br />
the use of biopolymers in selected skin-contact applications<br />
and improving both their performance and sustainability, 12<br />
partners from 7 countries are collaborating in this 3-year<br />
project.<br />
The selection of bio-based materials for the project<br />
combines formulations based on engineered biopolymers<br />
like polylactic acid (PLA) with naturally available ones like<br />
polyhydroxyalkanoates (PHAs) or chitin, with a significant<br />
bio-based carbon content above 90 % according to<br />
ASTM D6866, all of which are biodegradable in industrial<br />
composting.<br />
There are already some efforts to introduce PLA, the<br />
biodegradable polymer with the largest market share,<br />
which is also biocompatible and therefore, used in several<br />
biomedical applications but also in diapers as an alternative<br />
to polyethylene top-sheets. In fact, PLA being an aliphatic<br />
polyester offers the same functionality as diaper topsheets<br />
made from PE, i.e. keeping the skin dry, while at the same<br />
time featuring an improved biocompatibility. PolyBioSkin<br />
will drive this development also by additivating PLA<br />
with chitin nanofibrils in order to provide PLA films with<br />
excellent antimicrobial properties and avoid skin irritations.<br />
Furthermore, natural absorbent cores based on modified<br />
cellulose and starch will substitute the generally used<br />
acrylic petrochemical absorbents.<br />
Chitin is a polysaccharide present in the skeletons of<br />
insects and the shells of crustaceans and readily available<br />
from food industry processing waste (for instance sea<br />
food waste). Chitin and its derived biopolymer chitosan<br />
have shown excellent techno-functional properties in<br />
different fields, for example for edible coatings with good<br />
gas barrier properties, antimicrobial properties for wound<br />
care, skin hydration and repairing in cosmetic application<br />
or biostimulants for plants. Besides, in its nanofibril form,<br />
chitin has been reported to be a potent skin inflammation<br />
suppressant to be applied, for example, against atopic<br />
dermatitis. This feature is of huge relevance for all skincontact<br />
applications pursued in the project.<br />
Another very versatile group of emerging biopolyesters<br />
are polyhydroxyalkanoates (PHAs). They can be synthesised<br />
directly in the cells of a number of microorganisms and<br />
the exacted polymer structure and molecular weight can<br />
vary greatly depending on the microorganism nature and<br />
culture conditions. As such, PHAs structure can be different<br />
in terms of content of comonomers (3-hydroxybutyric<br />
acid, 4-hydroxybutyric acid, 3-hydroxyvaleric acid, etc.)<br />
or molecular weight, which in turn can lead to flexible or<br />
rigid plastics and to different possibilities of processing in<br />
conventional industrial machines. Among the commercially<br />
available PHAs, most are from Gram negative bacteria.<br />
Despite their unique biocompatibility and even, in some<br />
cases, inherent antibacterial properties, PHAs from<br />
Gram positive bacteria are still not commercially utilized.<br />
Especially in the case of wound dressings, such new<br />
materials could help to avoid immune reactivity and<br />
maximise skin regeneration potential.<br />
In PolyBioSkin, not only the materials themselves will<br />
be optimised, but also process-driven structuring will be<br />
given special attention to obtain films, fibres, and nonwoven<br />
textiles with properties tailored to each of the<br />
PolyBioSkin target applications. Indeed, a nanofibrous<br />
morphology is known to result in a much faster liquidity<br />
absorption than the regular bulk properties of the same<br />
polymer, leading to optimal resource efficiency. As such,<br />
PolyBioSkin aims at developing high quality products<br />
by utilising the most advanced polymer conversion<br />
techniques, such as electrohydrodynamic processing,<br />
tailored surface modification, and the latest developments<br />
in nanotechnology.<br />
34 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Beauty & Healthcare<br />
By:<br />
Elodie Bugnicourt and Rosa Arias<br />
Innovació i Recerca Industrial i Sostenible (IRIS)<br />
Castelldefels, Spain<br />
Maria-Beatrice Coltelli and Serena Danti<br />
Consorzio Interuniversitario Nazionale per la<br />
Scienza e Tecnologia dei Materiali (INSTM)<br />
University of Pisa, Pisa, Italy<br />
Götz Ahrens,<br />
Project Manager<br />
European Bioplastics<br />
Berlin, Germany<br />
Thanks to the use of electrical forces, based on liquid<br />
atomisation, electrospinning enables the production of<br />
short to continuous fibres or particles. It is an extremely<br />
versatile and promising technology as it can lead to<br />
structures with variable density based on suspensions of<br />
different materials and even to core shells. The controlled<br />
release of active ingredients can be achieved through a<br />
porous structure of the matrix at the nano to micro scale<br />
produced through electrospinning. In PolyBioSkin, the<br />
biopolymer non-wovens embedding antimicrobial and antiinflammatory<br />
substances such as chitin will be based on<br />
electrospun nanofibre meshes.<br />
PolyBioSkin will boost the use of biopolymers that offer<br />
unique antimicrobial, antioxidant, absorbence, and skin<br />
biocompatibility properties for high performance skincontact<br />
applications. This will be demonstrated in diaper,<br />
facial beauty mask, and wound dressing applications. The<br />
use of PolyBioSkin’s innovative materials in these widely<br />
used products will result in enhanced quality of life and<br />
wellbeing of EU citizens, reduced environmental impact,<br />
and more environmentally friendly end-of-life options for<br />
skin-contact products.<br />
Fig. 1: Diapers, facial beauty masks, and wound dressings in the<br />
European Waste Hierarchy<br />
Current Scenario<br />
WASTE MANAGEMENT<br />
Waste Reduction<br />
Reuse<br />
Recycling/Composting<br />
Energy Recovery<br />
Landfill<br />
POLYBIOSKIN innovation<br />
The PolyBioSkin consortium combines the expertise of<br />
twelve partners from seven European countries, including<br />
five partners from academia and technology institutes:<br />
Consorzio Interuniversitario Nazionale per la Scienza e<br />
Tecnologia dei Materiali (INSTM, Italy), the University of<br />
Westminster (UK), Association pour la recherche et le<br />
developpement des methodes et processus industriels<br />
(ARMINES, France), Tehnoloski Fakultet Novi Sad (Serbia)<br />
and University of Gent (Belgium); six industry participants<br />
(SMEs): Innovació i Recerca Sostenible (IRIS, Spain, project<br />
coordinator), Bioinicia (Spain), Fibroline (France), Texol<br />
(Italy), Mavi Sud (Italy) and Exergy (UK), as well as the<br />
European Bioplastics association (Germany).<br />
PolyBioSkin has received funding from the Bio-based<br />
Industries Joint Undertaking under the European Union’s<br />
Horizon 2020 research and innovation programme under<br />
grant agreement No. 745839.<br />
www.polybioskin.eu<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 35
Beauty & Healthcare<br />
Stronger superabsorbent<br />
biopolymers for baby care<br />
Ecovia Renewables, Inc. and their research and development<br />
team in Ann Arbor, Michigan are working to<br />
develop a suite of polyglutamic acid (PGA) biopolymers<br />
from their patented EcoSynth fermentation process. Their<br />
objective: to produce biodegradable, non-toxic, and highperforming<br />
superabsorbent polymers (SAPs) at competitive<br />
costs. Ecovia’s PGA SAPs can be used as thickeners for<br />
cosmetics, soil amendments for agriculture, and absorbent<br />
cores for hygiene products, to name a few applications.<br />
“It was a tough realization,” Drew Hertig, Chief Business<br />
Officer of Ecovia recalls. “We interviewed parent after<br />
parent. Nobody wanted to pay more than a dime extra to<br />
switch to a biobased diaper that couldn’t live up to the<br />
performance of traditional diapers.”<br />
The solution? Develop a scalable process that, at<br />
large volumes, reduces the manufacturing cost of high<br />
performing materials previously too expensive to use in<br />
hygienic products. This concept allows for cost savings<br />
without sacrificing performance.<br />
Dr. Nina Lin and Dr. Jeremy Minty of the University of<br />
Michigan Dept. of Chemical Engineering capitalized on<br />
their research in constructing microbial ecosystems to<br />
form the basis of the EcoSynth platform. Demonstrating<br />
success at small scales, Minty and his team work around<br />
the clock applying their platform to produce low-cost PGA, a<br />
naturally occurring (and edible) biopolymer, from renewable<br />
sources like waste glycerol.<br />
“We are looking at application areas that can benefit both<br />
the end-user and the environment, all while maintaining<br />
profitability and economics of scale,” said Jeremy Minty,<br />
Co-Founder and President. “Our long term vision is to<br />
replace hundreds of synthetic polymer products with costcompetitive<br />
PGA.”<br />
One such area is baby care, where thousands of tonnes<br />
of synthetic polymers are used and thrown away every day.<br />
As the diapers pile up so do the expenses. As a result,<br />
parents often have to choose between cost and performance<br />
for diapers that are biobased and non-toxic for their baby<br />
and the environment. Finding the right diaper at the right<br />
price has led to an influx of experts catering to the demand<br />
of concerned parents.<br />
The result? A plethora of information and opportunities<br />
for consumer research. Thought leaders and rating sites<br />
like Rodale’s Organic Life and Baby Gear Lab have made<br />
it easy for parents and parents-to-be to consider all their<br />
options for adoption.<br />
Most parents agree that for the superabsorbent material<br />
that makes up the core of diapers—averaging 10g per<br />
diaper—performance is key. Rigorous tests are performed<br />
including absorbency under load, free swell, and centrifuge<br />
retention capacity. Many more tests are kept confidential<br />
by the market leaders for benchmarking internal products.<br />
The winners are usually traditional diapers.<br />
Traditional diapers incorporate synthetic polymers like<br />
polyacrylic acid and its derivatives. These SAPs continue<br />
to outperform most biobased polymer substitutes like<br />
polysaccharides (i.e. starches and celluloses). As a result,<br />
the material in the diaper core often limits sustainability<br />
certifications.<br />
However, the bar is rising. Biodegradability tests,<br />
including ISO, ASTM, and OECD testing methods are no<br />
longer enough for eco-brands to differentiate themselves.<br />
Leading brands are looking to improve their sustainability<br />
certifications, striving to reach the highest level possible,<br />
such as Cradle-to-Cradle Gold status, and Nordic Swan,<br />
which examines CO 2<br />
emissions throughout the product<br />
lifecycle.<br />
“At the end of the day we hope to look back and think we<br />
made it one step closer to fulfilling our mission,” Mr. Hertig<br />
concludes, “having nature work for us so that we can give<br />
back.” MT<br />
www.ecoviarenewables.com<br />
Linear gamma-poly glutamic acid (PGA). Biobased and nontoxic,<br />
linear PGA can be crosslinked and derivatized into<br />
superabsorbent materials. Image brightened for contrast.<br />
36 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Beauty & Healthcare<br />
Bioplastic<br />
microbeads<br />
for cosmetics<br />
Few are aware that many cosmetics pollute the rivers and<br />
seas due to the presence of microscopic particles of oilbased<br />
and non-biodegradable plastic (polyethylene, polypropylene<br />
and other types of polymers). To solve this problem<br />
and make every beauty product environmentally friendly, Bioon<br />
developed and patented a revolutionary, innovative solution<br />
in 2016 based on the bioplastic Minerv PHAs, which is<br />
made from renewable and biodegradable plant sources. The<br />
new formulation, called Minerv Bio Cosmetics (type C1), is<br />
designed to make microbeads suitable for the cosmetics industry.<br />
The plastic micro particles (known as microbeads) currently<br />
used as thickeners or stabilisers in such widely used products<br />
as lipstick, lip gloss, mascara, eye-liner, nail polish, creams,<br />
shampoo, foam bath and even toothpaste pollute the<br />
environment because once they are rinsed off after use, they<br />
become a permanent part of the natural cycle: plankton in the<br />
rivers and seas swallow these microscopic plastic particles and<br />
thus introduce them into the food chain. The level of pollution<br />
is so serious that the USA government has decided to bring in<br />
a law (Microbead-Free Waters Act of 2015) banning the use of<br />
oil-based polymers in body care products. This decision was<br />
recently followed by other countries. The theme is also the<br />
subject of many awareness campaigns around the world and<br />
is one of the focuses of Clean Seas recently launched by the<br />
United Nations.<br />
Institutions and consumers alike are increasingly aware of<br />
the issue but often limit their concern to scrub beads, which<br />
though small fall within the visible range. The greater danger<br />
arises from what cannot be seen, i.e. texturizing powder. These<br />
micro powders invisible to the naked eye (10 µm) are made<br />
from oil-based plastic (methacrylates and polyamides) and are<br />
inserted into almost all formulations to change the sensory<br />
characteristics of the product.<br />
The new cosmetic grades of bioplastic developed by Bio-on<br />
contain highly spherical micro powders with a diameter between<br />
5 and 20 µm, with a porous or hollow structure to guarantee<br />
high absorption of oil and sebum. The special characteristics<br />
of these powders are further enriched by exceptional optical<br />
qualities such as a soft focus effect, which reduces the effect of<br />
wrinkles, making the skin brighter and less greasy.<br />
The use in cosmetics products of Minerv Bio Cosmetics<br />
bioplastic eliminates all pollutants because the micro particles<br />
of bioplastic are naturally biodegradable in water and, therefore,<br />
do not enter the food chain. What is more, the biopolymer<br />
developed at the Bio-on laboratories actually decomposes into<br />
a nutrient for some micro-organisms and plants present in<br />
nature. The benefit for the environment is therefore two-fold.<br />
“Our biopolymer is surprisingly versatile,” explains Paolo<br />
Saettone, head of Bio-on’s cosmetics department, “and<br />
performs at the very peak of its category, without taking into<br />
account its unparalleled biodegradability and non-toxicity,<br />
which truly sets it apart.”<br />
“From now on, cosmetics companies will have the chance<br />
to safeguard the environment and make their products 100 %<br />
ecological,” explains Marco Astorri, Chairman and CEO of Bioon<br />
S.p.A., “while retaining their performance and effectiveness.<br />
Here too, Bio-on bioplastic demonstrates that it can replace<br />
conventional oil-based plastic in terms of performance,<br />
thermo-mechanical properties and versatility.”<br />
Earlier this year, Bio-on had started to build a new plant to<br />
produce the Minerv Bio Cosmetics microbeads.<br />
The innovative plant, due to be completed by the end of this<br />
year and beginning production in 2018 thanks to a 15 million<br />
EUR investment, will employ approximately 40 people. The plant<br />
will occupy an area of 30,000 m 2 , 3,700 of which is covered and<br />
6,000 land for development, and will have a production capacity<br />
of 1,000 tonnes per year expandable to 2,000. It will be equipped<br />
with state-of-the-art technologies and the most advanced<br />
research laboratories, where Bio-on will test and develop new<br />
types of PHAs bioplastic using agricultural and agro-industrial<br />
waste as raw material. Bio-on also demonstrates its focus on<br />
sustainability in its choice of site, opting to convert a former<br />
factory in Castel San Pietro Terme near Bologna, meaning no<br />
new land is wasted.<br />
“We are pleased because so far we have obtained the<br />
necessary authorisations to begin construction on schedule,”<br />
explains Marco Astorri.”We expect to keep to that set down<br />
in our Industrial Plan which takes us through to 2020. We<br />
are also extremely proud,” adds Astorri, “because thanks to<br />
our technology the cosmetics sector can now take a ‘green’<br />
turn that millions of consumers around the world have been<br />
demanding for some time.” MT<br />
www.bio-on.it<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 37
Politics<br />
Biodegradable plastics in the<br />
Circular Economy in Europe<br />
At the beginning of this year, the European Commission<br />
published its EU Roadmap for a Strategy on Plastics in a<br />
Circular Economy. In the Roadmap, the Commission has<br />
given priority to assess how to decarbonize the plastics<br />
economy and to increase efficiency of waste management<br />
with a strong focus on recycling of plastic in order to help<br />
the transition from a linear to a circular economy model.<br />
European Bioplastics (EUBP), the association representing<br />
the interest of the bioplastics industry in Europe, welcomes<br />
this clear focus in the roadmap, and hopes that this will<br />
remain a main pillar of the upcoming Strategy on Plastics<br />
in order to address some of the most pressing challenges<br />
of our time, namely climate change and resource efficiency.<br />
One important point missing in the roadmap, however,<br />
is the need to consider recycling as both, organic and<br />
mechanic recycling. Only if the separate collection of biowaste<br />
and organic recycling is encouraged, the quality<br />
of other waste streams as well as the efficiency of waste<br />
management altogether can be increased. Organic recycling<br />
(industrial composting and anaerobic digestion) is a wellestablished<br />
industrial process ensuring the circular use for<br />
biodegradable plastics while creating a strong secondary<br />
raw material market and opportunity for renewable energy<br />
generation.<br />
In the context of the EU Plastics Strategy and the Circular<br />
Economy Package, biodegradable plastics can play an<br />
essential part in putting the envisioned circularity model<br />
into practice. Discussing biodegradation of plastics only<br />
from a ‘leakage-into-the-environment’ point of view will<br />
not help to implement sound circular waste management.<br />
EUBP therefore calls on the European Commission to focus<br />
on circularity when discussing biodegradation of plastics<br />
and to consider organic recycling and proven products and<br />
applications for biodegradable products that are certified<br />
according to harmonised standards (EN 13432) and labelled<br />
accordingly.<br />
Not all packaging should or can be made from<br />
biodegradable plastics. But there are several key<br />
products and applications that can amplify the benefits<br />
and contributions of biodegradable plastics to a circular<br />
economy. The following list can contribute to a more<br />
concrete discussion and can show that biodegradable<br />
plastics help to prevent and reduce waste.<br />
Compostable bio-waste bags, fruit & vegetable<br />
bags, lightweight carrier bags<br />
Compostable bio-waste plastic bags support the separate<br />
collection of organic waste. They are a convenient, clean,<br />
and hygienic tool, which helps households to collect more<br />
kitchen and garden waste while reducing the misthrow rate<br />
of conventional plastics in organic waste streams. Likewise,<br />
compostable fruit and vegetable bags and lightweight<br />
carrier bags first serve as a convenient way for shoppers to<br />
carry home groceries and can afterwards be used to collect<br />
biodegradable kitchen and food waste.<br />
By:<br />
Hasso von Pogrell<br />
Managing Director,<br />
When discussing biodegradation of plastics and the<br />
circular economy today, considerations should focus<br />
on organic recycling as an existing and proven concept.<br />
Harmonised and accepted standards, certification schemes,<br />
and labels for industrial compostable plastics already exist.<br />
Such materials, combined with accurate information for<br />
consumers on how to dispose of the waste correctly, have<br />
proven to help collect more bio-waste for organic recycling<br />
and, that way, divert it from landfills or reduce contamination<br />
with biodegradable waste in mechanical recycling streams.<br />
European Bioplastics e.V.<br />
Berlin, Germany<br />
Compostable<br />
light-weight fruit and<br />
vegetable bag photo:<br />
Unicoop<br />
38 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Buss Laboratory Kneader MX 30-22<br />
Compostable fruit labels<br />
Using fruit labels made from conventional, nonbiodegradable<br />
plastics causes significant amounts of<br />
plastic to be discarded in bio-waste bins, as consumers will<br />
rarely remove these labels from fruit peels before disposing<br />
them in the bio-waste. Compostable fruit labels can remain<br />
attached to and be discarded together with fruit peels<br />
without introducing impurities to the bio-waste stream.<br />
Coffee capsules and tea bags<br />
After they have been used, the organic content (coffee<br />
or tea residues) and the capsules or bags are difficult to<br />
separate, leading to confusion about the appropriate way<br />
of disposal as well as misthrows. Coffee capsules and tea<br />
bags made from fully compostable plastics provide the<br />
same performance while offering an alternative that can<br />
be organically recycled together with the organic content.<br />
Coffee and tea waste are highly desired in industrial<br />
composting plants as they stimulate microbial activity in the<br />
composting process.<br />
Buss Kneader Technology<br />
Compostable coffee<br />
capsules from Original<br />
Food tested and certified<br />
according to EN1342<br />
photo: Original Food GmbH<br />
Thin film applications for fruit and vegetable<br />
packaging<br />
Food that has past its expiry date and is packed in<br />
conventional plastic packaging is usually not separated<br />
from its packaging. The plastic packaging, together with<br />
its contents, is usually either thrown into the bio-waste<br />
bin, where it constitutes an impurity, or the biodegradable<br />
food content still inside the packaging ends up in the<br />
residual waste bin and is no longer available for organic<br />
recycling and thus wasted as a possible valuable resource.<br />
Compostable plastic packaging can help to solve this<br />
problem as it can be discarded and recycled together<br />
with its organic contents. When discussing these specific<br />
applications in the context of a circular economy, EUBP<br />
recommends focussing on highly food-contaminated<br />
thin film packaging applications with a thickness below<br />
100 microns such as fruit and vegetable packaging (e.g.<br />
cucumber wrappings, flow packs).<br />
Leading Compounding Technology<br />
for heat and shear sensitive plastics<br />
For more than 60 years Buss Kneader technology<br />
has been the benchmark for continuous preparation<br />
of heat and shear sensitive compounds –<br />
a respectable track record that predestines this<br />
technology for processing biopolymers such<br />
as PLA and PHA.<br />
> Uniform and controlled shear mixing<br />
> Extremely low temperature profile<br />
> Precise temperature control<br />
> High filler loadings<br />
www.european-bioplastics.org<br />
Buss AG<br />
Switzerland<br />
www.busscorp.com<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 39
News Automotive from Science and Research<br />
Turning industrial waste into PHA bioplastics<br />
Dr. Damian Laird and Dr. Leonie Hughes, researchers<br />
from the School of Engineering<br />
and Information Technology (Murdoch University,<br />
Perth, Australia) have been investigating<br />
an environmentally friendly solution for the use of<br />
oxalate, one of the major waste products of the alumina<br />
industry.<br />
“We are interested in finding a use for carbonbased<br />
industrial waste, which is currently<br />
stockpiled or is difficult to treat,” Dr Laird said. “By<br />
upcycling the carbon from a waste stream, we are<br />
able to avoid the production of carbon dioxide whilst<br />
creating something useful.”<br />
After sourcing an initial bacterial culture from<br />
a local wastewater treatment plant, the team<br />
created a synthetic wastewater to understand the<br />
conditions required for bacteria to convert the oxalate waste product into the biodegradable plastic (polyhydroxybutyrate (PHB).<br />
The research team is now identifying the suite of bacteria that can work in the process and examining ways to increase the<br />
amount of oxalate that is converted.<br />
“We are taking inspiration from the production of bioplastic from food waste and applying it to a toxic by-product of the<br />
alumina industry,” Dr Hughes said.<br />
“This will be a naturally produced plastic that is biocompatible and completely biodegradable, and one of our goals is to 3D<br />
print products for the medical industry such as stents and sutures.”<br />
The team is also collaborating with Murdoch University’s Algae Research and Development Centre to look at using<br />
cyanobacteria (blue-green algae), organisms that have a blend of bacteria and algae, to find a way to accelerate the process.<br />
“Eventually we envision this bioplastic production forming part of an integrated biorefinery at Murdoch University,” Dr Hughes<br />
said.<br />
This research was recently published in the Journal of Environmental Chemical Engineering and can be read here<br />
tinyurl.com/ybfcsgm7.<br />
www.murdoch.edu.au<br />
Turning brewery waste into PHA bioplastics<br />
Brewers’ spent grain (BSG in industrial terms) is a waste stream that every brewery generates in abundance. Approx. 85 %<br />
of an average microbrewery’s solid waste is BSG. In many cases it is simply dumped into landfills. The correct way, as to the<br />
Brewers Association’s guidance for environmentally friendly modes of disposal would be to feed BSG to cows, to turn it into<br />
biofuel, compost it or mill it into baking flour. However, for cost and other reasons this is seldom done. Christopher M. Thomas,<br />
a post-doctoral researcher at the State University of New York pondered about using this BSG to make bioplastic, namely<br />
PHA. In Sierra, the national magazine of the Sierra Club, Thomas<br />
said: “You’re diverting waste from landfills, and you’re creating a<br />
biodegradable packaging. And it’s degradable in all environments,<br />
no matter where it goes—freshwater, saltwater, or sewage.”<br />
BSG offers all the components you need, Thomas said. These<br />
are for example polysaccharides, long molecules that when broken<br />
into simple sugar molecules using enzymes or acid, they become<br />
bacterial food. As known from PHAs, special bacteria use this<br />
food as energy reserve: polyhydroxyalkanoates (PHA), which can<br />
be extracted from the microbes and convertied and compounded<br />
into mouldable plastic resins.<br />
www.sierraclub.org<br />
40 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
©<br />
-Institut.eu | <strong>2017</strong><br />
Full study available at www.bio-based.eu/reports<br />
©<br />
-Institut.eu | 2016<br />
Full study available at www.bio-based.eu/markets<br />
©<br />
-Institut.eu | <strong>2017</strong><br />
Full study available at www.bio-based.eu/markets<br />
Bio-based Polymers & Building Blocks<br />
The best market reports available<br />
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July <strong>2017</strong><br />
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Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
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May <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
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April <strong>2017</strong><br />
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www.bio-based.eu/reports<br />
Data for<br />
2016<br />
Policies impacting bio-based<br />
plastics market development<br />
and plastic bags legislation in Europe<br />
Bio-based Building Blocks<br />
and Polymers<br />
Global Capacities and Trends 2016 – 2021<br />
Asian markets for bio-based chemical<br />
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Share of Asian production capacity on global production by polymer in 2016<br />
Bio-based polymers: Evolution of worldwide<br />
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5<br />
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0<br />
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PUR<br />
PA<br />
Epoxies<br />
PBS<br />
PET<br />
PBAT<br />
CA<br />
PHA<br />
Starch<br />
Blends<br />
EPDM<br />
PLA<br />
APC<br />
PE<br />
PEF<br />
PTT<br />
0%<br />
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APC –<br />
cyclic<br />
PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
Blends<br />
PHA<br />
PLA<br />
PE<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Florence Aeschelmann (nova-Institute),<br />
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February <strong>2017</strong><br />
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Brand Views and Adoption of<br />
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Market study on the consumption<br />
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A comprehensive market research report including<br />
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WPC/NFC Market Study 2014-10 (Update 2015-06)<br />
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January 2016<br />
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Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
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April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
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Authors: Michael Carus, Dr. Asta Eder, Lara Dammer, Dr. Hans Korte, Lena Scholz,<br />
Roland Essel, Elke Breitmayer, Martha Barth<br />
First version 2014-03, Update 2015-06<br />
Download this study and further nova market studies at:<br />
www.bio-based.eu/markets<br />
www.bio-based.eu/reports<br />
bioplastics MAGAZINE [02/17] Vol. 12 41
Opinion<br />
Biodegradable plastics needed<br />
to increase recycling efficiency<br />
In the light of the current debates and consultations on the<br />
upcoming EU Strategy on Plastics and the revision of the EU<br />
waste legislation, European Bioplastics (EUBP), the association<br />
for the bioplastics industry in Europe, echoes the call for<br />
greater investments in the implementation of separate recycling<br />
streams, made by the association of Plastics Recyclers<br />
Europe (PRE) earlier this week. In a press release, PRE calls<br />
for the development of separate recycling streams for biodegradable<br />
plastics to improve waste management efficiency<br />
throughout Europe. EUBP supports these efforts to ensure<br />
a high quality of recycled plastics. In order to implement a<br />
circular economy throughout Europe and to achieve higher<br />
recycling rates, stronger investments in the modernisation<br />
of the waste management infrastructure, including separate<br />
mechanical and organic recycling streams, are needed.<br />
Biodegradable plastics help to reduce contamination<br />
of mechanical recycling streams by facilitating separate<br />
collection of biowaste and therefore diverting organic waste<br />
from other recycling streams. Organic recycling is a wellestablished<br />
industrial process ensuring the circular use for<br />
biodegradable plastics while creating a strong secondary<br />
raw material market and opportunity for renewable energy<br />
generation. Numerous beacon projects throughout Europe<br />
demonstrate the positive effects of compostable bags on the<br />
efficiency and quality of separate organic waste collection,<br />
including in the cities of Milan, Munich, and Paris.<br />
Currently, the share of biodegradable plastics designed<br />
for organic recycling sold in the EU is comparatively small.<br />
Therefore, the potential of misthrows by the consumer to<br />
reach a critical volume that could impact the quality of<br />
mechanical recycling streams is an unreasonable assumption<br />
at this point in time. This has also been tested and confirmed<br />
in a recent study by the University of Wageningen, which<br />
analysed biodegradable plastics in mechanical recycling<br />
streams and detected levels not higher than 0.3%. When<br />
tested within the EU FP7 Open-Bio project, Wageningen<br />
Food & Biobased Research found that there were no negative<br />
effects on the properties of recycled film products containing<br />
starch film and PLA film recyclates. If biodegradable plastic<br />
products do, however, enter mechanical recycling streams,<br />
they can easily be sorted out. Research by Knoten Weimar,<br />
a scientific knowledge-cluster and institute at the Bauhaus-<br />
University Weimar focussed on optimising utilities and waste<br />
infrastructures, shows that available sorting technologies<br />
such as NIR (near infrared) can easily detect biodegradable<br />
plastic materials such as PLA (polylactic acid), PBAT<br />
(polybutylene adipate terephthalate), and other starch or<br />
cellulose based materials.<br />
On the other hand, however, contamination of organic waste<br />
streams by misthrows of non-biodegradable plastics is high<br />
and constitutes a real problem for composting facilities and<br />
negatively affects the quality of compost. This problem can<br />
only be tackled by establishing mandatory separate collection<br />
of organic waste supported and facilitated by the use of<br />
biodegradable plastic bags and packaging and accompanied<br />
by consumer education and information on correct ways of<br />
organic and mechanic recycling.<br />
EUBP urges all involved stakeholders to consider recycling<br />
as both mechanical and organic recycling and to contemplate<br />
the corresponding plastic materials in this context.<br />
Furthermore, investments into sound waste management<br />
infrastructure across Europe as well as comprehensive<br />
projects to increase the consumers’ knowledge about correct<br />
disposal need to be considered. Only then, recycling can<br />
become more efficient, contamination can be limited, and a<br />
strong secondary raw material market in a circular economy<br />
will flourish.<br />
For more information, please see the following expert<br />
statements and studies on this issue:<br />
• Wageningen Food & Biobased Research (<strong>2017</strong>): Biobased<br />
and biodegradable plastics – Facts and Figures<br />
tinyurl.com/ydaufx38<br />
• Knoten Weimar: Entsorgungswege und<br />
Verwertungsoptionen von Produkten aus biobasierten<br />
Polymeren des post-consumer Bereichs (German only)<br />
tinyurl.com/y9xkhnwa<br />
www.european-bioplastics.org<br />
Magnetic<br />
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www.plasticker.com<br />
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• Job Market<br />
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Up-to-date • Fast • Professional<br />
42 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Basics<br />
Land use<br />
Just how much land is required to<br />
produce bioplastics?<br />
By:<br />
Constance Ißbrücker<br />
Head of Environmental Affairs<br />
European Bioplastics<br />
Berlin, Germany<br />
Global land area<br />
G13.4 billion ha = 100 %<br />
Finite fossil oil resources and climate change constitute two<br />
broadly acknowledged challenges for society in the coming<br />
decades. Bioplastics, which are derived fully or in part from<br />
renewable, plant-based resources, have the unique advantage<br />
over conventional plastics to reduce the dependency on fossil<br />
resources and to reduce greenhouse gas emissions.<br />
Today, bioplastics are predominantly produced from agrobased<br />
feedstock, i.e. plants that are rich in carbohydrates,<br />
such as corn or sugarcane. At the same time, the bioplastics<br />
industry is investing in the research and development to<br />
diversify the availability of biogenic feedstock for the production<br />
of based plastics. The industry particularly aims to further<br />
develop fermentation technologies that enable the utilisation<br />
of ligno-cellulosic feedstock sources, for example non-food<br />
crops or agricultural waste materials.<br />
There are various ways to ensure a sufficient supply of<br />
biomass for the production for food, feed, and industrial/<br />
material uses (including bioplastics) now and in future. These<br />
include:<br />
1. Broadening the base of feedstock: The bioplastics<br />
industry is currently working mostly with agro-based<br />
feedstock. Several projects, however, are already looking into<br />
using plant residues or other ligno-cellulosic feedstock.<br />
2. Increasing yields: Increasing the efficiency of<br />
industrial conversion of raw materials into feedstock, for<br />
example by using optimised yeasts or bacteria and optimised<br />
physical and chemical processes that would increase the total<br />
availability of resources.<br />
3. Taking fallow land into production: There is still<br />
plenty of arable land in various geographical regions available<br />
for production, even in the European Union (see separate box)<br />
Pasture<br />
3.5 billion ha<br />
= 26.1 %<br />
lobal agricultural area<br />
Arable land*<br />
1.4 billion ha<br />
= 10.4 %<br />
5 billion ha = 36.5 %<br />
Food & Feed<br />
1.24 billion ha<br />
= 9.25 %<br />
Graph<br />
courtesy<br />
IfBB [1]<br />
Bioplastics<br />
2015: 750 000 ha = 0.0<strong>05</strong>6 %<br />
2020: 1 784 000 ha = 0.0133 %<br />
Material use<br />
106 million ha = 0.79 %<br />
Biofuels<br />
53 million ha = 0.39 %<br />
Latest numbers by the IfBB Hanover published in 2016<br />
show that the area used to produce so-called new economy<br />
bioplastics was 0.0<strong>05</strong>6 % of the global agricultural area<br />
in 2015. Considering continued high growth-rates of the<br />
bioplastics market over the next years, this share would<br />
increase to 0.0133 % of the agricultural area by 2020. The<br />
approach of the IfBB is considered to be a conservative one,<br />
as entire plants are allocated for the calculation, and a tenyear<br />
average value considering harvest fluctuation as well as<br />
full utilisation of plant capacities is being assumed. Not all<br />
experts agree to this approach and suggest considering for<br />
example more detailed allocation values for the crop usage<br />
and the yield average values, since not necessarily all parts<br />
of the plant are used to produce bioplastics. However, all<br />
experts agree on one important point, namely the fact that<br />
the actual amount of land used for bioplastics is very low<br />
compared to the land used to produce food and feed, which<br />
shows that there is no competition between using biomass<br />
for the production for bioplastics and using biomass the<br />
production of food and feed.<br />
After all, responsibly sourced and monitored (i.e.<br />
sustainable) food crops are still the main feedstock option for<br />
bioplastics, since they are more land-efficient than non-food<br />
crops due to highly efficient agricultural processes. What is<br />
more, the use of bi-products of these food crops (i.e. lignocellulosic<br />
feedstocks) in based industries allows to increase<br />
resource efficiency even more. There is even evidence that<br />
the industrial and material use of biomass may in fact serve<br />
as a stabilizer for food prices, providing farmers with more<br />
secure markets and thereby leading to more sustainable<br />
production. Independent third party certification schemes for<br />
sustainable sourcing and responsible agricultural practices<br />
do already exist and can help to take social, environmental<br />
and economic criteria into account and to ensure that<br />
bioplastics are a purely beneficial innovation.<br />
[1] N.N.: Biopolymers – facts and statistics; Institute for Bioplastics and<br />
Biocomposites, 2016<br />
www.european-bioplastics.org<br />
Info:<br />
Different sources come up with varying figures for „free“ arable<br />
land, the French National Institute For Agricultural Research gives<br />
2.6 billion hectares of untapped potential (article in ParisTech,<br />
2011), the nova-Institute calculates 570 million hectares based on<br />
figures of OECD and FAO (2009). The bottom line – there is an ample<br />
amount of unused land available.<br />
http://tinyurl.com/bioplastic-facts<br />
* Also includes area growing permanent crops as well as approx.<br />
1 % fallow land. Abandoned land resulting from shifting<br />
cultivation is not included.<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 43
Brand Owner<br />
Brand-Owner’s perspective<br />
on bioplastics and how to<br />
unleash its full potential<br />
More and more technical aspects are well within the comfort zone of the<br />
bioplastic industry enabling the disruptive innovations our societies and<br />
environment need. However, successful innovations are<br />
as much business as technology driven. Having a great<br />
idea is one thing, launching a proposition and get it to<br />
market another.<br />
So, quite often a biobased product is desirable<br />
and even technically feasible. But bringing such a<br />
(often) small scale innovation to market is something else. Before<br />
economies of scale can be unlocked, there is this difficult phase<br />
during which advocacy and government support are needed. The biobased<br />
industry could help to open up discussions with the governmental<br />
institutes like the EU to create funding programs around this.<br />
Dennis van Eeten,<br />
Packaging Innovation and (Interim) Design Manager<br />
MARS CHOCOLATE EUROPE & EURASIA<br />
Besides the boost for a first launch it would also be very beneficial if the European<br />
legislation around bioplastics would be harmonised. This includes, icons for biocertificates,<br />
end-of-life rules (what can I put in my green bin and what not) and of<br />
course a harmonised EPR fee across all countries (in Europe).<br />
www.mars.com<br />
Report<br />
Polit<br />
Bioplastics Survey<br />
In this edition of our series ”special focus on certain geographical<br />
areas” we have a closer look to North America.<br />
This time, however, we did not conduct our little non-representative<br />
survey ourselves. We are grateful to the Plastics<br />
Industry Assiciaton (PLASTICS), to grant permission<br />
to publish some results of a survey they did in May 2016. In<br />
this national poll of 1,107 adults throughout the USA were<br />
asked. The results show a margin of error of +/- 3.07 % at<br />
the 95 % confidence interval. Below we publish an excerpt<br />
of the survey that is related to bioplastics.<br />
Being asked how familiar they were about a type of<br />
plastics called “bioplastics,” which are either made from<br />
biobased materials like sugar cane or cornstarch or are<br />
capable of biodegrading 27 % responded with “Yes” (defined<br />
as somewhat or very familiar). 39 % were unsure and the<br />
rest (34 %) said they were very unfamiliar with the terms.<br />
The next question addressed the purchase behavior. More<br />
or less half of the interviewed citizens committed they would<br />
be willing to pay a little bit more for an item that was made<br />
from bioplastics. The other 50 % said that they were not.<br />
The U.S. Department of Agriculture initiated the<br />
BioPreferred programme which includes a BioPreferred<br />
Seal (cf. bM 01/2011), which verifies the percentage of<br />
biologically grown ingredients in a consumer or wholesale<br />
product. Asked if they had ever seen this logo, 14 %<br />
responded with “Yes”, while the other 86 % were at least not<br />
sure or responded with “No”.<br />
The last question addressed the purchase behavior<br />
after having seen the USDA BioPreferred Seal. “When<br />
considering a plastic product for purchase, would seeing<br />
a USDA BioPreferred Seal on that product make you more<br />
likely to buy that product?” was positively responded by<br />
57 %. The remaining 43 % wouldn’t.<br />
The source of the data can be found here:<br />
https://tinyurl.com/bio-marketwatch. MT<br />
www<br />
www<br />
www<br />
www<br />
44 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />
30 bio
Automotive<br />
10<br />
Years ago<br />
Published in<br />
bioplastics<br />
MAGAZINE<br />
Rhodes Yepsen, Executive Director of the<br />
Biodegradable Products Institute (BPI), said in<br />
September <strong>2017</strong>:<br />
The topics presented 10 years ago continue to be important in North<br />
America, albeit with significant progress made. It’s no longer just Wal-<br />
Mart that has aggressive packaging goals, but other major retailers and<br />
restaurants as well, including a focus on consumer-oriented education,<br />
such as the How2Recycle and How2Compost labels.<br />
As for state legislation, California’s labelling law has helped clean up bad<br />
actors from the market, and became the basis for a model rule for other<br />
states, with Maryland adopting a similar law in <strong>2017</strong>.<br />
Municipal interest in food scraps and compostable products is also at<br />
an all-time high, with hundreds of communities across the US and Canada<br />
offering residential and commercial food scraps collection, and New York City<br />
on track to become the world’s largest program.<br />
Avoiding methane generation is still a big driver, but so is the soil<br />
connection, returning valuable materials back to the land in the form of<br />
compost. Findacomposter.com has gone through several updates, as has<br />
BPI’s database of certified products (products.bpiworld.org), which is now<br />
searchable by keyword.<br />
As was the case 10 years ago, compostable product companies are at the<br />
forefront of the discussion on policies for diverting organics from landfill, and<br />
we expect them to continue to play a leading role for the next decade as well.<br />
http://tinyurl.com/northamerica2007<br />
ics<br />
What’s happening in the<br />
New World?<br />
New Legislation in California<br />
.bpiworld.org<br />
.biocycle.net<br />
.findacomposter.com<br />
.beps.org<br />
Article contributed by Steven Mojo,<br />
Executive Director of the<br />
Biodegradable Products Institute (BPI),<br />
New York, NY, USA<br />
I<br />
t is truly a new world in North America, as the<br />
pace of organics diversion continues to increase.<br />
Discussions around the issues of sustainability,<br />
increasing use of renewable resources<br />
and greenhouse gas reductions are coming to the<br />
forefront.<br />
Retailer Concerns about Packaging<br />
In late 20<strong>05</strong>, Wal-Mart announced its sustainability<br />
drive focused on three aggressive goals:<br />
1. “To Be Supplied 100% By Renewable Energy”:<br />
2. ”To Create Zero Waste”:<br />
3. ”To Sell Products That Sustain Our Resources<br />
& Environment”:<br />
As part of this effort, Wal-Mart has developed a<br />
“scorecard” for packaging and is asking suppliers<br />
to document the use of recyclable and compostable<br />
packaging (via ASTM D6400) and to verify the<br />
use of renewable feedstocks (using ASTM D6866).<br />
This scorecard came on-line in March 2007 and<br />
manufacturers will be feeding it data throughout<br />
this year.<br />
Wal-Mart’s efforts, like Sainsbury’s in the UK,<br />
call attention to the growing array of new materials<br />
available to packagers around the globe. At the<br />
same time, packagers are starting to inquire about<br />
BPI certification and the benefits of the BPI Compostable<br />
Logo. Also, manufacturers are striving to<br />
increase the percentage of renewably based materials,<br />
in order to help reduce their environmental<br />
footprint and earn credits from Wal-Mart.<br />
The BPI and its members are immersed in the<br />
issues of renewable resources, compostability and<br />
biodegradability for almost a decade. As such, they<br />
are in a position to help Wal-Mart and others understand<br />
the importance of using ASTM Test Methods<br />
and Specifications for verifying claims.<br />
This project is a “work in progress”. It will continue<br />
to evolve as technology and properties improve<br />
and importantly will impact suppliers, consumers<br />
and everyone in between.<br />
California continues to set the pace in the area of<br />
compostables. Last year, Governor Schwarzenegger<br />
signed labeling legislation which restricts the<br />
use of the terms “biodegradable”, “compostable”<br />
and “degradable” on plastic food containers to<br />
only those products that meet ASTM D6400. This<br />
legislation is similar to the one passed in 2004 for<br />
labelling on plastic bags. Both of the new laws<br />
are designed to address the abuse and misuse of<br />
these terms and the resulting confusion.<br />
New Ordinances in San Francisco<br />
In 2006, San Francisco passed ordinance No<br />
295-06 which bans the use of polystyrene food<br />
service packaging and mandates the use of compostable<br />
or recyclable alternatives, if their additional<br />
costs are within 15% of non-compostable<br />
or non-recyclable alternatives. This ordinance<br />
is designed to help minimize the waste going to<br />
landfills from these operations. Also, this ordinance<br />
takes advantage of the City’s well developed<br />
recycling and composting infrastructure for<br />
businesses and households.<br />
On March 27, 2007, San Francisco passed an<br />
ordinance mandating the use of compostable<br />
plastic bags or recyclable kraft paper bags by<br />
large food chains and pharmacies. Given the city’s<br />
widespread organic collection system, the compostable<br />
bags can serve two purposes. First they<br />
will bring home the groceries and then will have<br />
a second life as a liner for residential “kitchen<br />
catchers”. The new law takes effect by the end of<br />
this year.<br />
Food Scrap Diversion Programs Grow<br />
More communities, especially in Eastern Canada<br />
and on the West Coast are implementing food<br />
scrap diversion efforts. Portland (Oregon) and<br />
Seattle (Washington), join the ranks of San Francisco<br />
and Oakland, (California) in implementing<br />
commercial collection programs and in some<br />
communities’ residential ones as well. In the<br />
Canadian province of Ontario organics diversion<br />
efforts are beginning to “skyrocket” according to<br />
one BPI member.<br />
These are driven by the dual goals of continuing<br />
to increase the overall diversion rate from landfills<br />
as well as to reduce greenhouse gas emissions<br />
from landfills. For example, in the US, landfills<br />
are the single largest of anthropomorphic<br />
methane releases into the atmosphere, according<br />
to the US Environmental Protection Agency. Further<br />
the same study shows that landfills are the<br />
number 4 contributor of global warming gases.<br />
Findacomposter.com introduced<br />
The BPI and BioCycle magazine from Emmaus<br />
(Pennsylvania) are joint sponsors of a<br />
new website dedicated to increasing the awareness<br />
of composting in the US. The new site<br />
“findacomposter.com” was debuted in April 2007<br />
at the BioCycle West Coast Conference in San Diego<br />
(California). The site will provide consumers<br />
information about food scrap collection programs<br />
near them and will be available for all to use at<br />
no charge. Composters can participate at no cost<br />
and all entries will be verified by BioCycle. The BPI<br />
and its members are proud to be the first sponsor<br />
to support this effort and to help put composting<br />
on the map.<br />
The BPI and BEPS team up on<br />
a meeting in October, 2007<br />
The BEPS and BPI are jointly sponsoring a<br />
conference from Oct. 17-19th in Vancouver,<br />
Washington. This meeting will combine presentations<br />
and discussions on biodegradable and<br />
renewable materials from both academia and<br />
industry. Presenters are being lined up from<br />
North America, Europe and Asia. The conference<br />
will be a “zero waste” event. It is being held at<br />
the Hilton Hotel, which has been cited for sustainable<br />
practices and it will have an active food<br />
scrap diversion effort by the end of the summer.<br />
Learn more about the conference at beps.org<br />
bioplastics MAGAZINE [02/07] Vol. 2 31<br />
plastics MAGAZINE [02/07] Vol. 2<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 45
©<br />
3,5<br />
actual data<br />
3<br />
2,5<br />
2<br />
1,5<br />
1<br />
0,5<br />
2011 2012 2013<br />
L-LA<br />
Epichlorohydrin<br />
Succinic<br />
1,4-BDO<br />
acid<br />
-Institut.eu | <strong>2017</strong><br />
forecast<br />
2014 2015 2016 <strong>2017</strong> 2018 2019 2020 2021<br />
Sebacic<br />
MEG<br />
Ethylene<br />
1,3-PDO<br />
MPG<br />
Lactide<br />
acid<br />
2,5-FDCA D-LA<br />
11-Aminoundecanoic acid<br />
Adipic<br />
DDDA<br />
acid<br />
Full study available at www.bio-based.eu/reports<br />
©<br />
100%<br />
80%<br />
60%<br />
40%<br />
20%<br />
0%<br />
-Institut.eu | <strong>2017</strong><br />
PBS(X)<br />
APC –<br />
cyclic<br />
PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
Blends<br />
PHA<br />
PLA<br />
PE<br />
Full study available at www.bio-based.eu/markets<br />
©<br />
10<br />
5<br />
actual data<br />
0<br />
2011 2012<br />
PUR<br />
PA<br />
-Institut.eu | 2016<br />
2% of total<br />
polymer capacity,<br />
€13 billion turnover<br />
2013 2014 2015 2016<br />
Epoxies PET<br />
CA<br />
PBS<br />
PBAT PHA<br />
<strong>2017</strong><br />
Starch<br />
Blends<br />
EPDM<br />
2018 2019 2020 2021<br />
PLA<br />
PE<br />
PTT<br />
APC<br />
PEF<br />
Full study available at www.bio-based.eu/markets<br />
Largest biocomposites<br />
conference in <strong>2017</strong><br />
Organiser<br />
www.nova-institut.eu<br />
Picture © clockwise from top left: photo and design by colorFabb,<br />
Faurecia, photo by colorFabb / design by LeFabshop, Coperion<br />
Biocomposites Conference Cologne<br />
7 th Conference on Wood and Natural Fibre Composites<br />
6 – 7 December <strong>2017</strong>, Maternushaus, Germany<br />
Contact: Dr. Asta Partanen | +49 (0)151 – 1113 0128 | asta.partanen@nova-institut.de | www.biocompositescc.com<br />
Bio-based Polymers & Building Blocks<br />
The best market reports available<br />
Data for<br />
2016<br />
Commercialisation updates on<br />
bio-based building blocks<br />
Standards and labels for<br />
bio-based products<br />
Bio-based polymers, a revolutionary change<br />
Bio-based Building Blocks<br />
and Polymers<br />
Selected bio-based building blocks: Evolution of worldwide<br />
production capacities from 2011 to 2021<br />
Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />
and polymers based on FDCA and SA: Latest developments,<br />
producers, drivers and lessons learnt<br />
Global Capacities and Trends 2016 – 2021<br />
million t/a<br />
Bio-based polymers, a<br />
revolutionary change<br />
million t/a<br />
Bio-based polymers: Evolution of worldwide<br />
production capacities from 2011 to 2021<br />
Jan Ravenstijn <strong>2017</strong><br />
E-mail: j.ravenstijn@kpnmail.nl<br />
Mobile: +31.6.2247.8593<br />
Picture: Gehr Kunststoffwerk<br />
Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
July <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />
April <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Florence Aeschelmann (nova-Institute),<br />
Michael Carus (nova-institute) and ten renowned international experts<br />
February <strong>2017</strong><br />
This is the short version of the market study (249 pages, € 2,000).<br />
Both are available at www.bio-based.eu/reports.<br />
Policies impacting bio-based<br />
plastics market development<br />
and plastic bags legislation in Europe<br />
Asian markets for bio-based chemical<br />
building blocks and polymers<br />
Brand Views and Adoption of<br />
Bio-based Polymers<br />
Market study on the consumption<br />
of biodegradable and compostable<br />
plastic products in Europe<br />
2015 and 2020<br />
Share of Asian production capacity on global production by polymer in 2016<br />
A comprehensive market research report including<br />
consumption figures by polymer and application types<br />
as well as by geography, plus analyses of key players,<br />
relevant policies and legislation and a special feature on<br />
biodegradation and composting standards and labels<br />
Bestsellers<br />
Disposable<br />
tableware<br />
Biowaste<br />
bags<br />
Carrier<br />
bags<br />
Rigid<br />
packaging<br />
Flexible<br />
packaging<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March <strong>2017</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
January 2016<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
Lara Dammer, Michael Carus (nova-Institute)<br />
April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
bio-based.eu/top-downloads.<br />
46 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />
www.bio-based.eu/reports
call for papers now open!<br />
Save the Date<br />
04-<strong>05</strong> Sep 2018<br />
Cologne, Germany<br />
www.pha-world-congress.com<br />
PHA (Poly-Hydroxy-Alkanoates or polyhydroxy fatty acids) is a family of biobased polyesters. As in many<br />
mammals, including humans, that hold energy reserves in the form of body fat there are also bacteria that<br />
hold intracellular reserves of polyhydroxy alkanoates. Here the micro-organisms store a particularly high level<br />
of energy reserves (up to 80% of their own body weight) for when their sources of nutrition become scarce.<br />
Examples for such Polyhydroxyalkanoates are PHB, PHV, PHBV, PHBH and many more. That’s why we speak<br />
about the PHA platform.<br />
This PHA-platform is made up of a large variety of bioplastics raw materials made from many different renewable<br />
resources. Depending on the type of PHA, they can be used for applications in films and rigid packaging,<br />
biomedical applications, automotive, consumer electronics, appliances, toys, glues, adhesives, paints, coatings,<br />
fibers for woven and non-woven and inks. So PHAs cover a broad range of properties and applications.<br />
That’s why bioplastics MAGAZINE and Jan Ravenstijn are now organizing the 1 st PHA-platform World Congress on<br />
4-5 September 2018 in Cologne / Germany.<br />
This congress will address the progress, challenges and market opportunities for the formation of this new polymer<br />
platform in the world. Every step in the value chain will be addressed. Raw materials, polymer manufacturing,<br />
compounding, polymer processing, applications, opportunities and end-of-life options will be discussed by parties<br />
active in each of these areas. Progress in underlying technology challenges will also be addressed.<br />
Platinum Sponsor:<br />
organized by<br />
Co-organized by Jan Ravenstijn
Basics<br />
Biodegradation<br />
Bioplastics and their behaviour in different biodegradation environments<br />
The efficient management of plastic waste plays a key<br />
role within the circular economy. Good waste management<br />
requires the implementation of the waste hierarchy,<br />
as set out by EU legislation in the form of Directive<br />
2008/98/CE [1], which aims to encourage solutions providing<br />
a better environmental result. The waste hierarchy sets<br />
out the following hierarchy of steps for prioritising waste<br />
management practices: (1) prevention; (2) preparation for<br />
reutilisation; (3) recycling; (4) other kind of recovery, such<br />
as energy recovery; and (5) disposal, such as in the case<br />
of landfilling. Moreover, the package of circular economy<br />
measures adopted by the European Union requires that<br />
waste be transformed into resources again, so they can be<br />
returned cyclically to the productive system, until reaching<br />
the very ambitious target of “zero waste” to landfill (European<br />
Commission, 2014). Thus, the end of life of plastics<br />
continues to be a controversial point, since landfilling is still<br />
a common practice. In the year 2014, 31 % of the post-consumer<br />
plastic waste generated in Europe went to landfill.<br />
The situation in Spain is even more unfavourable: here, just<br />
over 50% of all post-consumer plastic waste ends up in a<br />
landfill [2]<br />
These decisions, combined with the push towards<br />
creating a sustainable environment - in addition to a desire<br />
to get away from landfilling and to reduce the amount of<br />
litter in the environment – have led to heightened interest in<br />
the production of bioplastics.<br />
Biodegradable plastics are considered to be eco-friendly<br />
materials. In recent years, they have been promoted in the<br />
market as substitutes for conventional plastics in specific<br />
applications in which biodegradability, as an end-of-life<br />
solution, provides environmental benefits. However, we<br />
must not forget their limitations regarding manufacturing<br />
costs, mechanical properties or variable biodegradability<br />
behaviour depending on the aggressiveness of the<br />
different media, and focus the efforts on the research and<br />
development of solutions and improvements.<br />
There are several important factors affecting the<br />
process or mechanism of biodegradation of biodegradable<br />
plastics. On the one hand, the chemical structure, the<br />
polymeric chain, crystallinity or complexity of the polymeric<br />
formulation are key points to be studied. In this way, the<br />
specific functional groups of the polymeric chain that<br />
forms the bioplastic are selected by certain enzymes and<br />
processed by them to trigger what is known as “material<br />
biodegradation”. We can say that, normally, polymers with<br />
short chains and more abundant amorphous area are more<br />
susceptible to being biologically degraded.<br />
On the other hand, the different environments in<br />
which biodegradable plastics initiate the biodegradation<br />
processes, must be studied. In this case, pH, temperature<br />
and the presence of oxygen and microbial content are the<br />
most significant factors in determining the aggressiveness<br />
level, depending on the conditions under which the material<br />
undergoes biodegradation. In such a reaction, the carbon<br />
that is a part of the material’s polymeric chains will, in<br />
the presence of biomass and hence of microorganisms,<br />
temperature, light and water, turn into CO 2<br />
and new<br />
biomass.<br />
The different possibilities that can occur regarding<br />
environment are, among others: compost, natural, soil,<br />
soil with normalized characteristics according to the test<br />
standards, fresh water, seawater or sewage sludge. This<br />
window of environments represents the existence of a<br />
wide range of very different conditions when studying the<br />
biodegradability of materials.<br />
More specifically and bearing in mind the possibility of<br />
recovering the plastic materials at the end of their shelf<br />
life, the medium offering this possibility is compost. The<br />
composting process is defined as the complete biological<br />
recovering process, aerobic (in presence of oxygen) and<br />
exothermal (with an increase of the temperature) of waste<br />
fermentation in controlled conditions whose result is the<br />
obtaining of CO 2<br />
, water and fertilizer or compost where<br />
wastes are not visually distinguishable and do not produce<br />
eco-toxicological effects in the environment.<br />
With regard to composting, it is important to highlight<br />
the difference between industrial composting and home<br />
composting due to the temperature difference in both<br />
processes (58 ºC in the case of industrial composting and<br />
below 30 ºC in the case of home composting) that makes a<br />
material to biodegrade faster in an industrial facility than<br />
home composting.<br />
If we analyse another key factor, such as the presence of<br />
microorganisms, the most important role is played by fungi.<br />
The presence of fungi is needed for a good biodegradation<br />
process. However, they can only be found in compost and<br />
soil, although they are more abundant in compost and<br />
less in soil. Both compost and soil have high microbial and<br />
populations that biodegrade bioplastic materials and a high<br />
diversity that is not found in other environments such as<br />
fresh water and seawater (aquatic ecosystems), so this<br />
environment is less aggressive.<br />
Therefore, an estimation of the aggressiveness of different<br />
environments can be given and we can affirm that the most<br />
active environment is compost, followed by soil, fresh water,<br />
seawater and finally ambient and landfill conditions (this<br />
last option must be ruled out if we talk about efficient waste<br />
management) [3].<br />
In order to calculate the percentage of biodegradability<br />
that a specific material has reached in an environment,<br />
there are lab-scale tests that evaluate parameters such as<br />
the amount of carbon dioxide generated when subjecting<br />
plastic materials to certain conditions. This parameter is<br />
an indirect measurement of the amount of carbon from<br />
the polymeric chain that is transformed into carbon dioxide<br />
by the mechanism of biodegradability. Based on this<br />
measurement, different standards have been developed<br />
with which the different biodegradation environments must<br />
48 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12
Basics<br />
By:<br />
Elena Domínguez Solera<br />
Sustainability and Industrial Recovery Department,<br />
AIMPLAS<br />
Valencia, Spain<br />
comply. Thus, for example, the standard EN ISO 14855 [4],<br />
sets out a method to determine the final biodegradability<br />
percentage of a plastic material. The material is subjected<br />
to controlled composting conditions (58 ºC and 50 %<br />
of humidity) using generated and automatic carbon<br />
dioxide detection methods, such as infrared detection or<br />
gravimetric methods of carbon dioxide absorption in certain<br />
substances. Likewise, there are standards that simulate a<br />
medium at an environmental temperature of 25 ºC, where<br />
plastic materials are subject to the presence of a natural<br />
or normalized soil, as in the standard EN ISO 17556 [5]<br />
or to 30 ºC in a natural aqueous medium, normalized or<br />
in other environments rich in microorganisms, such as<br />
sewage sludge, as in the standard EN ISO 14852, which sets<br />
out the testing procedure to determine the final aerobic<br />
biodegradability in aqueous medium [6].<br />
It is essential to establish in each case what we want to<br />
analyse, in which environments and under what conditions,<br />
in order to determine the behaviour of plastics and their<br />
utility in different applications.<br />
AIMPLAS, has been committed to this vision for<br />
more than 20 years, and besides having developed and<br />
taken part in different projects in the field of bioplastics,<br />
continues to opt for them regarding biodegradability<br />
tests in different environments. The institute has taken a<br />
further step by becoming the first Spanish laboratory to<br />
earn ENAC accreditation (National Accreditation Body)<br />
for tests determining the final aerobic biodegradability in<br />
composting conditions (EN ISO 14855-1), soil (EN ISO 17556)<br />
and tests determining the degree of disintegration of plastic<br />
materials under simulated composting conditions in a<br />
laboratory scale (EN ISO 20200 [7]). Thanks to this extension<br />
of the accreditation scope, AIMPLAS is at the forefront of<br />
accredited tests in the field of plastic materials in Europe.<br />
The fact that ENAC is a signatory of all the EA (European<br />
Accreditation), ILAC (International Laboratory Accreditation<br />
Cooperation) and IAF (International Accreditation Forum)<br />
international agreements, is very important Therefore, a<br />
report or certificate issued under ENAC accreditation is<br />
recognized by the other signatories in the entire world and<br />
these agreements act like an international passport for trade.<br />
www.aimplas.es<br />
References:<br />
[1] DIRECTIVE 2008/98/CE OF THE EUROPEAN PARLIAMENT AND THE<br />
COUNCIL of 19 November 2008 on waste and repealing certain<br />
directives.<br />
[2] PlasticsEurope (PEMRG) / Consultic. Plastics - the Facts 2015. An<br />
analysis of European plastics production, demand and waste data.<br />
[3] Challenges and opportunities of biodegradable plastics: A mini review<br />
(Maja Rujnić-Sokele and Ana Pilipović). Waste Management & Research<br />
<strong>2017</strong>, Vol. 35(2) 132–140.<br />
[4] EN ISO 14855-1:2013. Determination of the ultimate aerobic<br />
biodegradability of plastic materials under controlled composting<br />
conditions - Method by analysis of evolved carbon dioxide - Part 1:<br />
General method. Part 2: Gravimetric method.<br />
[5] EN ISO 17556:2013. Plastics. Determination of the ultimate aerobic<br />
biodegradability of plastic materials in soil by measuring the oxygen<br />
demand in a respirometer or the amount of carbon dioxide evolved.<br />
[6] EN ISO 14852:20<strong>05</strong>. Determination of the ultimate aerobic<br />
biodegradability of plastic materials in an aqueous medium - Method by<br />
analysis of evolved carbon dioxide.<br />
[7] EN ISO 20200:2016. Plastics - Determination of the degree of<br />
disintegration of plastic materials under simulated composting<br />
conditions in a laboratory-scale test.<br />
AIMPLAS’ equipment (Plastics Technology Centre) for biodegradability tests in different environments.<br />
bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 49
Basics<br />
Glossary 4.2 last update issue 02/2016<br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
such as PLA (Polylactide) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
1 st Generation feedstock | Carbohydrate rich<br />
plants such as corn or sugar cane that can<br />
also be used as food or animal feed are called<br />
food crops or 1 st generation feedstock. Bred<br />
my mankind over centuries for highest energy<br />
efficiency, currently, 1 st generation feedstock<br />
is the most efficient feedstock for the production<br />
of bioplastics as it requires the least<br />
amount of land to grow and produce the highest<br />
yields. [bM 04/09]<br />
2 nd Generation feedstock | refers to feedstock<br />
not suitable for food or feed. It can be either<br />
non-food crops (e.g. cellulose) or waste materials<br />
from 1 st generation feedstock (e.g.<br />
waste vegetable oil). [bM 06/11]<br />
3 rd Generation feedstock | This term currently<br />
relates to biomass from algae, which – having<br />
a higher growth yield than 1 st and 2 nd generation<br />
feedstock – were given their own category.<br />
It also relates to bioplastics from waste<br />
streams such as CO 2<br />
or methane [bM 02/16]<br />
Aerobic digestion | Aerobic means in the<br />
presence of oxygen. In →composting, which is<br />
an aerobic process, →microorganisms access<br />
the present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material<br />
to energy, CO 2<br />
, water and cell biomass,<br />
whereby part of the energy of the organic material<br />
is released as heat. [bM 03/07, bM 02/09]<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />
Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without<br />
practically releasing any heat. The biogas can<br />
be treated in a Combined Heat and Power<br />
Plant (CHP), producing electricity and heat, or<br />
can be upgraded to bio-methane [14] [bM 06/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight<br />
(biopolymer, monomer is →Glucose) [bM <strong>05</strong>/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose) [bM <strong>05</strong>/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from →biomass. A material or<br />
product made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radio carbon dating method)<br />
that adheres to the technical specifications as<br />
described in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective<br />
labels. Ideally, meaningful labels should be<br />
based on harmonised standards and a corresponding<br />
certification process by independent<br />
third party institutions. For the property<br />
biobased such labels are in place by certifiers<br />
→DIN CERTCO and →Vinçotte who both base<br />
their certifications on the technical specification<br />
as described in [4,5]<br />
A certification and corresponding label depicting<br />
the biobased mass content was developed<br />
by the French Association Chimie du Végétal<br />
[ACDV].<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method has<br />
been developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1]<br />
[bM 01/07, bM 03/10]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/06, bM 01/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a →life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its →global warmingpotential<br />
[1,2,15]<br />
50 bioplastics MAGAZINE [04/17] Vol. 12
Basics<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For<br />
example, carbon neutrality means that any<br />
CO 2<br />
released when a plant decomposes or<br />
is burnt is offset by an equal amount of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to →biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of →cellulose<br />
[bM 01/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. Cellulose is a polymeric molecule<br />
with very high molecular weight (monomer is<br />
→Glucose), industrial production from wood<br />
or cotton, to manufacture paper, plastics and<br />
fibres [bM 01/10]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic<br />
acids. The most important cellulose esters<br />
from a technical point of view are cellulose<br />
acetate (CA with acetic acid), cellulose propionate<br />
(CP with propionic acid) and cellulose<br />
butyrate (CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Certification | is a process in which materials/products<br />
undergo a string of (laboratory)<br />
tests in order to verify that the fulfil certain<br />
requirements. Sound certification systems<br />
should be based on (ideally harmonised) European<br />
standards or technical specifications<br />
(e.g. by →CEN, USDA, ASTM, etc.) and be<br />
performed by independent third party laboratories.<br />
Successful certification guarantees<br />
a high product safety - also on this basis interconnected<br />
labels can be awarded that help<br />
the consumer to make an informed decision.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM 06/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/06, bM 01/07]<br />
Composting | is the controlled →aerobic, or<br />
oxygen-requiring, decomposition of organic<br />
materials by →microorganisms, under controlled<br />
conditions. It reduces the volume and<br />
mass of the raw materials while transforming<br />
them into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a<br />
managed composting facility is meant (criteria<br />
defined in EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much<br />
higher and kept stable, whereas in the composting<br />
pile temperatures are usually lower,<br />
and less constant as depending on factors<br />
such as weather conditions. Home composting<br />
is a way slower-paced process than<br />
industrial composting. Also a comparatively<br />
smaller volume of waste is involved. [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the cradle (i.e., the extraction of raw materials,<br />
agricultural activities and forestry) up<br />
to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane). Developments to<br />
make terephthalic acid from renewable resources<br />
are under way. Other examples are<br />
polyamides (partly biobased e.g. PA 4.10 or PA<br />
6.10 or fully biobased like PA 5.10 or PA10.10)<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging or a service. [16]<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Enzyme-mediated plastics | are no →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched<br />
with small amounts of an organic additive.<br />
Microorganisms are supposed to consume<br />
these additives and the degradation process<br />
should then expand to the non-biodegradable<br />
PE and thus make the material degrade. After<br />
some time the plastic is supposed to visually<br />
disappear and to be completely converted to<br />
carbon dioxide and water. This is a theoretical<br />
concept which has not been backed up by<br />
any verifiable proof so far. Producers promote<br />
enzyme-mediated plastics as a solution to littering.<br />
As no proof for the degradation process<br />
has been provided, environmental beneficial<br />
effects are highly questionable.<br />
Ethylene | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, monomer of<br />
the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European<br />
Bioplastics today represents the interests<br />
of about 50 member companies throughout<br />
the European Union and worldwide. With<br />
members from the agricultural feedstock,<br />
chemical and plastics industries, as well as<br />
industrial users and recycling companies, European<br />
Bioplastics serves as both a contact<br />
platform and catalyst for advancing the aims<br />
of the growing bioplastics industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF.<br />
The dicarboxylic acid can be used to make →<br />
PEF = polyethylene furanoate, a polyester that<br />
could be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g.<br />
the transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
bioplastics MAGAZINE [04/17] Vol. 12 51
Basics<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain or<br />
consist of such GMOs, or are produced from<br />
GMOs, are called genetically modified (GM)<br />
food or feed [1]. If GM crops are used in bioplastics<br />
production, the multiple-stage processing<br />
and the high heat used to create the<br />
polymer removes all traces of genetic material.<br />
This means that the final bioplastics product<br />
contains no genetic traces. The resulting<br />
bioplastics is therefore well suited to use in<br />
food packaging as it contains no genetically<br />
modified material and cannot interact with<br />
the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different<br />
industries such as bioplastics, packaging,<br />
pharmaceuticals, adhesives and chemicals.<br />
One of the most promising routes is 2,5<br />
furandicarboxylic acid (FDCA), produced as an<br />
intermediate when 5-HMF is oxidised. FDCA<br />
is used to produce PEF, which can substitute<br />
terephthalic acid in polyester, especially polyethylene<br />
terephthalate (PET). [bM 03/14, 02/16]<br />
Home composting | →composting [bM 06/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
Industrial composting | is an established<br />
process with commonly agreed upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised<br />
products to be used in agriculture. The<br />
criteria for industrial compostability of packaging<br />
have been defined in the EN 13432. Materials<br />
and products complying with this standard<br />
can be certified and subsequently labelled<br />
accordingly [1,7] [bM 06/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.01 percent of the<br />
global agricultural area of 5 billion hectares.<br />
It is not yet foreseeable to what extent an increased<br />
use of food residues, non-food crops<br />
or cellulosic biomass (see also →1 st /2 nd /3 rd<br />
generation feedstock) in bioplastics production<br />
might lead to an even further reduced<br />
land use in the future [bM 04/09, 01/14]<br />
LCA | is the compilation and evaluation of the<br />
input, output and the potential environmental<br />
impact of a product system throughout its life<br />
cycle [17]. It is sometimes also referred to as<br />
life cycle analysis, ecobalance or cradle-tograve<br />
analysis. [bM 01/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine<br />
debris originates from a variety of sources.<br />
Shipping and fishing activities are the predominant<br />
sea-based, ineffectively managed<br />
landfills as well as public littering the main<br />
land-based sources. Marine litter can pose a<br />
threat to living organisms, especially due to<br />
ingestion or entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, a number of standardisation<br />
projects are in progress at ISO and ASTM<br />
level. Furthermore, the European project<br />
OPEN BIO addresses the marine biodegradation<br />
of biobased products.[bM 02/16]<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the<br />
system cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input<br />
of biomass in a huge and complex chemical<br />
plant, then mathematically allocating this<br />
biomass input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed [bM 04/14, <strong>05</strong>/14, 01/15]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade!<br />
The underlying technology of oxo-degradability<br />
or oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard<br />
resins, are purported to accelerate the fragmentation<br />
of products made thereof. Oxodegradable<br />
or oxo-fragmentable materials do<br />
not meet accepted industry standards on compostability<br />
such as EN 13432. [bM 01/09, <strong>05</strong>/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM 06/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based and not degradable, used<br />
for e.g. baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol) [bM <strong>05</strong>/10]<br />
PEF | polyethylene furanoate, a polyester<br />
made from monoethylene glycol (MEG) and<br />
→FDCA (2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It<br />
can be a 100% biobased alternative for PET.<br />
PEF also has improved product characteristics,<br />
such as better structural strength and<br />
improved barrier behaviour, which will allow<br />
for the use of PEF bottles in additional applications.<br />
[bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The<br />
polyester is made from monoethylene glycol<br />
(MEG), that can be renewably sourced from<br />
bio-ethanol (sugar cane) and (until now fossil)<br />
terephthalic acid [bM 04/14]<br />
PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />
thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has been<br />
introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the<br />
polyhydroxy fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals,<br />
including humans, that hold energy reserves<br />
in the form of body fat there are also bacteria<br />
that hold intracellular reserves in for of<br />
of polyhydroxy alkanoates. Here the microorganisms<br />
store a particularly high level of<br />
52 bioplastics MAGAZINE [04/17] Vol. 12
Basics<br />
energy reserves (up to 80% of their own body<br />
weight) for when their sources of nutrition become<br />
scarce. By farming this type of bacteria,<br />
and feeding them on sugar or starch (mostly<br />
from maize), or at times on plant oils or other<br />
nutrients rich in carbonates, it is possible to<br />
obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending<br />
on the bacteria and their food, PHAs with<br />
different mechanical properties, from rubbery<br />
soft trough stiff and hard as ABS, can be produced.<br />
Some PHSs are even biodegradable in<br />
soil or in a marine environment<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e. as<br />
laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid.<br />
Modified PLA types can be produced by the<br />
use of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for<br />
use at higher temperatures [13] [bM 01/09, 01/12]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is similarly to PET<br />
produced using terephthalic acid or dimethyl<br />
terephthalate and a diol. In this case it is a<br />
biobased 1,3 propanediol, also known as bio-<br />
PDO [bM 01/13]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed,<br />
but as raw material for industrial products<br />
or to generate energy. The use of renewable<br />
resources by industry saves fossil resources<br />
and reduces the amount of → greenhouse gas<br />
emissions. Biobased plastics are predominantly<br />
made of annual crops such as corn,<br />
cereals and sugar beets or perennial cultures<br />
such as cassava and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resource<br />
efficient economy creates more output<br />
or value with lesser input.<br />
Seedling Logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → Vinçotte. Bioplastics<br />
products carrying the Seedling fulfil the<br />
criteria laid down in the EN 13432 regarding<br />
industrial compostability. [bM 01/06, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM <strong>05</strong>/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the<br />
hydrophilic character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister<br />
G. H. Brundtland. The Brundtland Commission<br />
defined sustainable development as<br />
development that ‘meets the needs of the<br />
present without compromising the ability of<br />
future generations to meet their own needs.’<br />
Sustainability relates to the continuity of economic,<br />
social, institutional and environmental<br />
aspects of human society, as well as the nonhuman<br />
environment).<br />
Sustainable sourcing | of renewable feedstock<br />
for biobased plastics is a prerequisite<br />
for more sustainable products. Impacts such<br />
as the deforestation of protected habitats<br />
or social and environmental damage arising<br />
from poor agricultural practices must<br />
be avoided. Corresponding certification<br />
schemes, such as ISCC PLUS, WLC or Bon-<br />
Sucro, are an appropriate tool to ensure the<br />
sustainable sourcing of biomass for all applications<br />
around the globe.<br />
Sustainability | as defined by European Bioplastics,<br />
has three dimensions: economic, social<br />
and environmental. This has been known<br />
as “the triple bottom line of sustainability”.<br />
This means that sustainable development involves<br />
the simultaneous pursuit of economic<br />
prosperity, environmental protection and social<br />
equity. In other words, businesses have<br />
to expand their responsibility to include these<br />
environmental and social dimensions. Sustainability<br />
is about making products useful to<br />
markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
Vinçotte | independant certifying organisation<br />
for the assessment on the conformity of bioplastics<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2012<br />
[2] ISO 14067. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2010<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2011<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2012<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14064 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 2006<br />
[10] Terrachoice, 2010, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2012<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 20<strong>05</strong><br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />
[15] ISO 14067 onb Corbon Footprint of<br />
Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
bioplastics MAGAZINE [04/17] Vol. 12 53
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
technical.starch@agrana.com<br />
www.agrana.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.comEurope<br />
contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.ecopond.com.cn<br />
FLEX-162 Biodeg. Blown Film Resin!<br />
Bio-873 4-Star Inj. Bio-Based Resin!<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-9995<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-018 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Corbion Purac<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem -<br />
The Netherlands<br />
Tel.: +31 (0)183 695 695<br />
Fax: +31 (0)183 695 604<br />
www.corbion.com/bioplastics<br />
bioplastics@corbion.com<br />
62 136 Lestrem, France<br />
Tel.: + 33 (0) 3 21 63 36 00<br />
www.roquette-performance-plastics.com<br />
1.2 compounds<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
39 mm<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 5190621<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
Green Dot Bioplastics<br />
226 Broadway | PO Box #142<br />
Cottonwood Falls, KS 66845, USA<br />
Tel.: +1 620-273-8919<br />
info@greendotholdings.com<br />
www.greendotpure.com<br />
Sample Charge:<br />
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= 234,00 € per entry/per issue<br />
Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 2713175<br />
Mob: +86 139<strong>05</strong>253382<br />
lilong_tunhe@163.com<br />
www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
54 bioplastics MAGAZINE [04/17] Vol. 12
Suppliers Guide<br />
1.6 masterbatches<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7062/97687-0<br />
www.tecnaro.de<br />
1.3 PLA<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
weforyou PLA & Applications<br />
office@weforyou.pro<br />
www.weforyou.pro<br />
1.4 starch-based bioplastics<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 films<br />
Infiana Germany GmbH & Co. KG<br />
Zweibrückenstraße 15-25<br />
91301 Forchheim<br />
Tel. +49-9191 81-0<br />
Fax +49-9191 81-212<br />
www.infiana.com<br />
INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />
45, 0,90, 0<br />
10, 0, 80,0<br />
(ICBP) C, M, Y, KSDN BHD<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
0, 0, 0, 0<br />
D-09, Jalan Tanjung A/4,<br />
Free Trade Zone<br />
Port of Tanjung Pelepas<br />
81560 Johor, Malaysia<br />
T. +607-507 1585<br />
icbp.bioplastic@gmail.com<br />
www.icbp.com.my<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, COO<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
Molds, Change Parts and Turnkey<br />
Solutions for the PET/Bioplastic<br />
Container Industry<br />
284 Pinebush Road<br />
Cambridge Ontario<br />
Canada N1T 1Z6<br />
Tel. +1 519 624 9720<br />
Fax +1 519 624 9721<br />
info@hallink.com<br />
www.hallink.com<br />
6.2 Laboratory Equipment<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6260<br />
Info2@moda.vg<br />
www.saidagroup.jp<br />
7. Plant engineering<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4<strong>05</strong>2 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 30351, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
1.5 PHA<br />
TIPA-Corp. Ltd<br />
Hanagar 3 Hod<br />
Hasharon 4501306, ISRAEL<br />
P.O BOX 7132<br />
Tel: +972-9-779-6000<br />
Fax: +972 -9-7715828<br />
www.tipa-corp.com<br />
4. Bioplastics products<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31, CH-7013 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
9. Services<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
Bio4Pack GmbH<br />
D-48419 Rheine, Germany<br />
Tel.: +49 (0) 5975 955 94 57<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
President Packaging Ind., Corp.<br />
PLA Paper Hot Cup manufacture<br />
In Taiwan, www.ppi.com.tw<br />
Tel.: +886-6-570-4066 ext.5531<br />
Fax: +886-6-570-4077<br />
sales@ppi.com.tw<br />
6. Equipment<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
Fax: +49 (0)208 8598 1424<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
BeoPlast Besgen GmbH<br />
Bioplastics injection moulding<br />
Industriestraße 64<br />
D-40764 Langenfeld, Germany<br />
Tel. +49 2173 84840-0<br />
info@beoplast.de<br />
www.beoplast.de<br />
6.1 Machinery & Molds<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62814<br />
Linda.Goebel@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
bioplastics MAGAZINE [04/17] Vol. 12 55
Suppliers Guide<br />
www.pu-magazine.com<br />
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Plus, it’s nonflammable and U.S. EPA SNAP-listed.<br />
Learn more at honeywell-blowingagents.com or 1-800-631-8138.<br />
© <strong>2017</strong> Honeywell International Inc. All rights reserved.<br />
5/8/17 10:41 AM<br />
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Volume 8, May <strong>2017</strong><br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
9. Services (continued)<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
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Stay permanently listed in the<br />
Suppliers Guide with your company<br />
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For only 6,– EUR per mm, per issue you<br />
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For Example:<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
10.3 Other Institutions<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
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www.bioplasticsmagazine.com<br />
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Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
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SEEING POLYMERS<br />
WITH DIFFERENT EYES...<br />
Biokraftstoffkompatibilität von FKM<br />
Silica/silane reaction mechanism<br />
self-healing tpu<br />
POLYURETHANES MAGAZINE INTERNATIONAL<br />
Trim The Weight,<br />
Not The Comfort<br />
Interviews: ISL-Chemie, Dow, Magna, Vencorex<br />
PSE Europe <strong>2017</strong> preview<br />
High temperature foam<br />
PIR insulation<br />
CNSL-based polyols<br />
Blowing Agents<br />
FORUM FÜR DIE POLYURETHANINDUSTRIE<br />
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Strukture le Faserverbundbauteile<br />
PU-basierte Bedachungsmaterialien<br />
Polyole auf CNSL-Basis<br />
Polyesterpolyole<br />
Interview mit G. Burrow, Magna<br />
Führende Köpfe für führende Lösungen<br />
Pultrusion neu gedacht<br />
Relaxed Extrusion<br />
PEEK-PTFE-cg-Materialien<br />
Fachmagazin für die Polymerindustrie<br />
Peroxidvernetzung<br />
INNOVATIVE<br />
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Our technical magazines and books create your expertise<br />
56 bioplastics MAGAZINE [04/17] Vol. 12<br />
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biopolymers-bioplastics.conferenceseries.com/<br />
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24.11.<strong>2017</strong> - 25.11.<strong>2017</strong> - Bengaluru, India<br />
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Fibres & Textiles | 14<br />
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European Biopolymer Summit<br />
14.02.2018 - 15.02.2018 - Duesseldorf, Germany<br />
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Basics<br />
Land use | 43<br />
CHINAPLAS 2018<br />
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24.04.2018 - 27.04.2018 - Shanghai, China<br />
adsale.hk/t.aspx?unt=2545-CPS18_Bioplastics_EN_calender<br />
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5 th PLA World Congress<br />
by bioplastics MAGAZINE<br />
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Plastics Tomorrow via Biobased Chemicals &<br />
Recycling<br />
25.06.2018 - 28.06.2018 - New York City Area, USA<br />
http://innoplastsolutions.com/bio.html<br />
+<br />
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BIO World Congress<br />
16.07.2018 - 19.07.2018 - Philadelphia PA, USA<br />
www.bio.org/worldcongress<br />
Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
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bioplastics MAGAZINE [04/17] Vol. 12 57
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
A. Schulman 7<br />
ABB 12<br />
Adidas 13<br />
Agrana 54<br />
AIMPLAS 22, 49<br />
Aitiip 6<br />
AMC Innova Juice & Drinks 6<br />
Amsilk 13<br />
API Applicazioni Plastiche Industriali 54<br />
Archer Daniels Midland 5<br />
ARMINES 35<br />
Barnet Europe 18<br />
BASF 7, 13 54<br />
Beoplast 55<br />
Bio4pack 55<br />
Biobrush 12<br />
Bio-Fed Branch of Akro-Plastic 54<br />
Bio-on 5, 28, 37<br />
Biotec 55<br />
Bosk Bioproducts 30<br />
Bozzetto 18<br />
BPI 45 56<br />
Braskem 7, 28, 32<br />
Bunzl 29<br />
Buss 39, 55<br />
Cathay Industrial Biotech 17<br />
Center for Biobased Economy 13<br />
Centexbel 19, 22<br />
Dr. Heinz Gupta Verlag 56<br />
DS Fibres 22<br />
DuPont 5<br />
Eastman Chemical Company 8<br />
Ecovia Renewables 36<br />
eKoala 26<br />
Erema 55<br />
Eroski 6<br />
European Bioplastics 34, 38, 42, 43 31, 56<br />
Exergy 35<br />
Fakultet Novi Sad 35<br />
Finroline 35<br />
FKuR 32 2, 54<br />
Fraunhofer UMSICHT 55<br />
G.S. Stemeseder 7<br />
Global Biopolymers 54<br />
GRABIO Greentech Corporation 55<br />
Grafe 54, 55<br />
Green Serendipity 56<br />
Greenboats 7<br />
GreenDot Bioplastics 54<br />
Hallink 55<br />
Hexpol TPE 8<br />
ICBP 1, 10, 55<br />
ICEE 13<br />
Indochine Bio Plastiques 1, 10, 55<br />
Infiana Germany 55<br />
INRS 30<br />
Inst. F. Bioplastics & Biocomposites 43 56<br />
Inst. Textiltechnik RWTH Aachen 18<br />
INSTM 34<br />
IRIS 34<br />
Jinhui Zhaolong 23, 54<br />
Kaneka 55<br />
Kartell 27<br />
Kering Eyeware 28<br />
Kingfa 54<br />
Linotech 7<br />
Maip 12<br />
Mars 44<br />
Mavi Sud 35<br />
Michigan State University 56<br />
Microtec 54<br />
Midwestern PET Foods 28<br />
Minima Technology 55<br />
Murdoch Univ. 40<br />
narocon InnovationConsulting 56<br />
NatureWorks 26<br />
Naturtec 55<br />
nova Institute 7 41, 46, 56<br />
Novamont 26 55, 60<br />
NPSP 7, 13<br />
Nurel 54<br />
Origin Materials 8<br />
OWI 7<br />
OWS 6<br />
Peel Plastics Products 28<br />
PHP Fibers 14<br />
Plastic Recyclers Europe 42<br />
plasticker 42<br />
PLASTICS 44<br />
Plastipolis 6<br />
Plasto 28<br />
polymediaconsult 56<br />
President Packaging 55<br />
PTT MCC Biochem 27, 54<br />
Raimund Beck Nageltechnik 7<br />
Roquette 54<br />
Sabio Materials 27<br />
Saida 55<br />
Saurer 18<br />
Schlafhorst 18<br />
Sierra Club 40<br />
Sintex 22<br />
Sonae Arauco 7<br />
Speick Naturkosmetik 32<br />
State Univ. New York 40<br />
Sukano 26 29, 54<br />
Tecnaro 55<br />
Tecos 6<br />
Teijin Frontier 16<br />
Texol 35<br />
thyssenkrupp Industrial Solutions 24<br />
TianAn Biopolymer 55<br />
Tipa 55<br />
Total Corbion PLA 54<br />
TU Eindhoven 7, 13<br />
Uhde Inventa-Fischer 24 21, 55<br />
Univ. Delft 13<br />
Univ. Gent 35<br />
Univ. Stuttgart (IKT) 55<br />
Univ. Westminster 35<br />
Vredestein 6<br />
Wageningen UR 6, 42<br />
Weforyou 36 55<br />
Xinjiang Blue Ridge Tunhe Polyester 22 54<br />
Yönsa 22<br />
Zhejiang Hangzhou Xinfu Pharmaceutical 54<br />
Zhejiang Hisun Biomaterials 33, 54<br />
<strong>Issue</strong><br />
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Month<br />
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