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ISSN 1862-5258<br />

Sep/Oct<br />

<strong>05</strong> | <strong>2017</strong><br />

Highlights<br />

Fibres & Textiles | 14<br />

Beauty & Healthcare | 32<br />

Basics<br />

Land use | 43<br />

NORTH AMERICA-<br />

Special<br />

bioplastics MAGAZINE Vol. 12<br />

Cover Story:<br />

C , M, Y, K<br />

Meet ICBP 10, 0, 80,0<br />

Malaysia‘s Bioplastics<br />

C, M, Y, K<br />

0, 0, 0, 0<br />

Industry Anchor |10<br />

C, M, Y , K<br />

45, 0,90, 0<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

... is read in 92 countries


INTEGRALLY SUSTAINABLE<br />

Speick Natural cosmetics chose Braskem’s biobased Green PE (distributed by FKuR)<br />

for its Speick Organic 3.0 shower gel and body lotion. Bottle, closure and label<br />

consist of one and the same material and therefore are easy to recycle.<br />

The sugar cane used for the Green PE production is cultivated and harvested<br />

in Brazil according to the sustainable resource and social management<br />

guidelines of ProForest.<br />

With this concept, Speick is complementing its line of holistic natural<br />

cosmetics. Speick’s formula is readily biodegradable, palm oil-free and<br />

enriched with energized water.<br />

www.speick.de


Editorial<br />

C, M, Y , K<br />

45, 0,90, 0<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

C, M, Y, K<br />

0, 0, 0, 0<br />

dear<br />

readers<br />

Summer is coming to an end and autumn time is award time, at least for us. And<br />

so, once again, I’m very happy to present the five finalists of the 12 th Global<br />

Bioplastics Award on pages 12-13. The winner will, as always, be announced at<br />

the European Bioplastics Conference on November 28 in Berlin, Germany.<br />

Other highlight topics of this issue are Fibres & Textiles and the application<br />

field of Beauty & Healthcare. Also, a different perspective is given on the question<br />

of Land use / Land availability on page 43 in the Basics Section.<br />

In our geographical focus in this issue we look to North America.<br />

As always, we’ve provided you, our readers, with news about trends,<br />

developments and applications, plus critical context and information in the form<br />

of reports and opinions.<br />

We’ve also got a few events we’d like you to pencil in for next year, including<br />

the 5 th PLA World congress in May, which, as always, will be held in Munich, in<br />

Germany and the 1 st PHA platform World Congress, which is scheduled to take<br />

place in September 2018, in Cologne. We are happy to have Jan Ravenstijn as<br />

our co-organisator. Stay tuned for more information on both these conferences<br />

in our coming issues.<br />

Before then, however, we’re hoping for the opportunity to see you at one or<br />

the other of the various trade shows and conferences that are taking place this fall, with as<br />

high point, of course the European Bioplastics Conference. We’re looking forward to it, as<br />

we hope you are too.<br />

Until then, please enjoy the autumn - and have a great time reading this latest issue of<br />

bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

bioplastics MAGAZINE Vol. 12<br />

ISSN 1862-5258<br />

... is read in 92 countries<br />

Sep/Oct<br />

<strong>05</strong> | <strong>2017</strong><br />

Highlights<br />

Fibres & Textiles | 14<br />

Beauty & Healthcare | 34<br />

Basics<br />

Land use | 43<br />

Cover Story:<br />

Meet ICBP<br />

Malaysia‘s Bioplastics<br />

Industry Anchor |10<br />

C , M, Y, K<br />

10, 0, 80,0<br />

In this issue we have a closer look to North America.<br />

However, even if Mexico is part of “North America”,<br />

we unfortunately do not have any editorial contribution<br />

from Mexico.<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 3


Content<br />

Imprint<br />

Sep / Oct <strong>05</strong>|<strong>2017</strong><br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Cover Story<br />

10 Meet ICBP<br />

Events<br />

11 5 th PLA World Congress<br />

47 1 st PHA platform World Congress<br />

Award<br />

12 12 th Bioplastics Award<br />

Fibers & Textiles<br />

14 Yarns from biobased Polymers<br />

17 Advances in textile applications<br />

for biobased polyamide<br />

18 Stable ring spinning process for poly<br />

lactic acid (PLA) staple fibre yarns<br />

Production<br />

24 Reducing PLA production cost<br />

Materials<br />

30 New compostable PHA based<br />

compound from Canada<br />

3 Editorial<br />

5 News<br />

26 Application News<br />

45 10 years ago<br />

50 Glossary<br />

54 Suppliers Guide<br />

57 Event Calendar<br />

58 Companies in this issue<br />

Beauty & Healthcare<br />

32 The power of packaging<br />

34 PolyBioSkin<br />

36 Stronger superabsorbent<br />

biopolymers for baby care<br />

37 Bioplastic microbeads for cosmetics<br />

Politics<br />

38 biodegradable plastics in<br />

the circular economy<br />

From Science and Research<br />

40 Turning waste into PHA bioplastics<br />

Opinion<br />

42 Biodegradable plastics<br />

Basics<br />

43 Land Use<br />

48 Biodegradation<br />

Brand Owner<br />

44 Mars<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

s.brangenberg@samsales.de<br />

Chris Shaw (English language)<br />

Chris Shaw Media Ltd<br />

Media Sales Representative<br />

phone: +44 (0) 1270 522130<br />

mobile: +44 (0) 7983 967471<br />

and Michael Thielen (see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3,400 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not<br />

necessarily reflect those of Polymedia<br />

Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via mt@<br />

bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in bioplastic envelopes<br />

sponsored by Biotec Biologische Naturverpackungen,<br />

Emmerich, Germany<br />

Cover-Ad<br />

ICBP, Indochine Bio Plastiques<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

DuPont and ADM win<br />

5 th Annual Innovation in<br />

Bioplastics Award<br />

The Bioplastics Division, a part of the Plastics Industry<br />

Association (PLASTICS), recently announced DuPont<br />

Industrial Biosciences and Archer Daniels Midland (ADM)<br />

as the winners of the <strong>2017</strong> Innovation in Bioplastics Award.<br />

The two companies developed a method to produce furan<br />

dicarboxylic methyl ester (FDME), a biobased monomer,<br />

from fructose derived from corn starch. This is the fifthannual<br />

Innovation in Bioplastics Award, an honor that goes<br />

to companies applying bioplastics to innovative, purposeful<br />

product design.<br />

The new FDME-producing technology is more<br />

sustainable and results in higher yields and lower energy<br />

and capital expenditures than traditional conversion<br />

methods. Biobased FDME has the potential to replace<br />

petroleum-based materials in many applications with<br />

high performance, renewable materials in industries like<br />

packaging, textiles and plastics engineering.<br />

“The breakthrough process developed by DuPont and ADM<br />

provides a simpler, more efficient approach to producing<br />

FDME that will make bioplastics a competitive option in<br />

more applications across various industries,” said Patrick<br />

Krieger, assistant director of regulatory and technical affairs<br />

at PLASTICS. “We are excited to honour a partnership that<br />

has opened the door to new possibilities for bioplastics.”<br />

One of the first materials under development using the<br />

new FDME process is polytrimethylene furandicarboxylate<br />

(PTF), a 100 % renewable and recyclable polymer with<br />

improved gas barrier properties that can be used to improve<br />

shelf life and lighten the weight of products in the beverage<br />

packaging industry. With lighter plastic bottles that offer<br />

a high gas barrier, costs to the transporter and negative<br />

environmental impacts would decrease on a global scale.<br />

“This molecule is a game-changing platform technology.<br />

It will enable cost-efficient production of a variety of<br />

renewable, high-performance chemicals and polymers<br />

with applications across a broad range of industries—<br />

including textiles, auto parts, food packaging and more,”<br />

said Michael Saltzberg, global business director for<br />

biomaterials at DuPont. “A demonstration plant for the<br />

technology in Decatur, Illinois will be online later this year,<br />

and we look forward to making this breakthrough a reality<br />

on a commercial scale.”<br />

“This project is a great example of how ADM is able<br />

to create value by providing innovative new sustainable<br />

solutions that address unmet needs for customers,” said<br />

Paul Bloom, vice president, process and chemical research<br />

for ADM. “Our unique partnership with DuPont is helping<br />

bring an innovative new product to customers that uses<br />

renewable feedstocks but also helps improve performance,<br />

and we are excited about the team’s continued progress as<br />

we near completion of construction of the demonstration<br />

project.” MT<br />

www.plasticsindustry.org<br />

Bio-on creates five<br />

new business units<br />

Bio-on (Bologna, Italy) recently announced the creation<br />

of five new Business Units (BU) to speed up its<br />

response to the growing demand for PHAs. The new<br />

divisions will enable more effective and faster development<br />

of new materials from biopolymers and new<br />

applications.<br />

"We decided to set up these five new Business Units to<br />

rapidly meet the enormous number of requests from<br />

all over the world for our revolutionary technology,"<br />

says Marco Astorri, Chairman and CEO of Bio-on. "This<br />

move will create more independent and more efficient<br />

departments to deal with special industrial production<br />

(Bio-on Plants); Cosmetic, Nanomedicine & Smart<br />

Materials (CNS); Recovery and Fermentation (RAF);<br />

Engineering (ENG) and Structural Materials Development<br />

(SMD)."<br />

Every year, 300 million tonnes of polluting plastic<br />

are produced and sold and thousands of types of oilbased<br />

polymers are made for myriad uses. Each of<br />

these is called a product grade and each one comes<br />

with its own technical data sheet. In recent months,<br />

and particularly since the recent presentation of Bioon's<br />

<strong>2017</strong>-2020 industrial plan released in November<br />

2016, Bio-on’s technicians have developed hundreds of<br />

new grades to replace existing high-pollution plastics.<br />

But, more importantly and surprisingly, there has been<br />

an exponential increase in the number of international<br />

patent applications submitted by Bio-on in high added<br />

value sectors unthinkable until as recently as last year.<br />

"Our goal," continues Marco Astorri, "is to develop<br />

as many products and agreements as possible in a<br />

rapidly changing scenario. And since Bio-on's Minerv<br />

polyhydroxyalkanoates can already be used in cuttingedge<br />

applications, unthinkable for conventional plastics,<br />

we had to speed up our response to market demand in a<br />

personalised way whilst continuing to provide a high level<br />

of service. The new Business Units meet this requirement."<br />

Bio-on Plants, the production BU, will be based in<br />

Castel San Pietro Terme, outside Bologna, Italy, where<br />

an innovative plant is being built, controlled by Bio-on,<br />

that will produce micro bioplastics for cosmetics. The<br />

RAF (Recovery and Fermentation) and CNS (Cosmetic<br />

Nanomedicine & Smart Materials) business units<br />

will also be based here. The latter will be equipped<br />

with laboratories and a business centre on two floors<br />

in the area opposite the Bio-on Plants facility. It is<br />

expected to open in early 2018. The SMD BU (Structural<br />

Materials Development) will further develop the current<br />

Bentivoglio (Bologna) site, in operation since 2016,<br />

with new spaces for studying and developing structural<br />

materials. The ENG BU (engineering) will be based at<br />

Bio-on in Via Santa Margherita al Colle in Bologna and<br />

will develop projects for the construction and assistance<br />

of licensed plants. MT<br />

www.bio-on.it<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Bio-additives for biodegradable plastic bottles<br />

Earlier this summer, the Citruspack project, a combination of circular economy and packaging, was launched at the Aitiip<br />

Technology Centre in Zaragoza, Spain.<br />

The project aims to process plant by-products, using these to derive natural additives to reinforce 100% biodegradable<br />

plastic bottles and containers. These will then be valorised in a number of new value chains.<br />

This project is coordinated by Aitiip and accounts with the partnership of AMC Innova Juice And Drinks S.L. (Spain), EROSKI<br />

(Spain), OWS Nv (Belgium), Plastipolis (France) and TECOS (Slovenia).<br />

At the end of the project, the researchers and participating companies aim to offer three solutions for the packaging and<br />

cosmetic sectors. The juice bottles will be the first demonstrator product.<br />

The bottles will be blow-moulded and must meet “very<br />

serious technical requirements”, as well as being biobased<br />

and eco-friendly, said Carolina Peñalva, project coordinator<br />

and the responsible person for packaging at Aitiip. "We want<br />

to test and quantify the acceptance of consumers during the<br />

project to reach the market.”<br />

Citruspack is part of the LIFE Program, which is the<br />

only financial instrument of the European Union dedicated<br />

exclusively to the environment. Its overall objective for<br />

the period 2004-2020 is to contribute to the sustainable<br />

development and achievement of the objectives and targets<br />

of the Europe 2020 Strategy and the relevant Union strategies<br />

and plans on environment and climate. This year it is<br />

celebrating its 25th anniversary. MT<br />

jal@aitiip.com<br />

WUR and Vredestein develop tyre made of<br />

rubber from dandelions<br />

Vredestein showed a prototype of its Fortezza Flower Power at the Eurobike exhibition in Friedrichshafen in August. This<br />

innovative road tyre is made of rubber extracted from the roots of dandelions. The prototype is the result of a EU joint initiative<br />

in which Vredestein and Wageningen University & Research (WUR) take part, called DRIVE4EU.<br />

Dandelion tyres<br />

The prototype is the first bicycle tyre in the world produced with natural rubber extracted from the roots of the Russian<br />

dandelion (Taraxacum koksaghyz). This particular series of prototype tyres were made with rubber extracted from plants<br />

grown and harvested in the Netherlands.<br />

Vredestein has worked closely together with WUR to develop this special natural rubber, make production viable and test<br />

various compounds. Each improvement in the process of rubber extraction has also led to a direct enhancement of the quality<br />

of the rubber. As a result, the special compound now used as a test on the Fortezza Flower Power prototype, provides better<br />

grip than traditional compounds. This is directly related to the higher concentration of natural resin in this particular variant of<br />

natural rubber. Studies are currently exploring whether this tyre can be mass produced in the future.<br />

DRIVE4EU<br />

Apollo Vredestein (the parent company of the Vredestein brand) is one of the industrial<br />

partners taking part in DRIVE4EU, a European research project which focuses on<br />

developing the production of natural rubber and inulin from Russian dandelion. The project<br />

is coordinated by Wageningen University & Research. The aim is to explore ways to make<br />

the European countries less dependent on imports of natural rubber in the near future,<br />

partly as a response to the looming worldwide shortage of rubber.<br />

www.wur.nl<br />

6 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


News<br />

<strong>2017</strong> Biocomposites Innovation Awards<br />

finalists revealed<br />

The finalists for the <strong>2017</strong> Biocomposites Innovation Awards have<br />

been announced by Germany-based nova-Institute. Six entries<br />

were selected out of a field of thirteen candidates by the advisory<br />

board earlier this month. Three will emerge victorious at the<br />

Biocomposites Conference (Dec. 6 and 7 in Cologne, Germany).<br />

Each of the finalists will be given a ten-minute slot to pitch<br />

their innovation at the close of the first day of the conference.<br />

Then the audience will choose the three winners, who will<br />

be presented with their awards at the Innovation Award<br />

Ceremony later that evening.<br />

The finalists are, in no particular order of ranking:<br />

A fully bio-based pedestrian bridge developed at the<br />

Eindhoven University of Technology in the Netherlands and<br />

installed by biocomposite pioneer NPSP (Netherlands). Flax<br />

and hemp fibres, which ensure the strength of the structure,<br />

are combined with a bio-based epoxy resin. Polylactic<br />

acid (PLA) bio-foam provides the core. A vacuum infusion<br />

production process is used: Layers of natural fibres are glued<br />

around a laser-cut shape of bio-foam.<br />

BASF & Sonae Arauco Deutschland (Germany) entered with<br />

an innovative 3D mouldable MDF styled as the new woodbased<br />

material for the furniture industry. It is a thermoplastic,<br />

processable and storage-stable composite which can be<br />

produced on existing MDF production lines. Due to the<br />

increased mouldability of the composite, new design options<br />

are possible. The resin system is offered formaldehyde free.<br />

Mass produced boats are typically made of fossil-based resins,<br />

glass fibres and plastic foam. By contrast, 80% of the GreenBente24<br />

from GreenBoats (Germany) is made from renewable materials<br />

such as flax, cork and bio-based epoxy resin. The boat has the<br />

same weight and stiffness as a standard boat, yet achieves an 80%<br />

reduction in its carbon footprint and is thermally recyclable.<br />

The Stratos passive – sandwich window scantling system<br />

by G.S. Stemeseder (Austria) is a combination of a foamed PP<br />

and wood composite material with solid wooden elements.<br />

The system was developed for the production of passive house<br />

windows. The required specific heat conductivity and Uf-value<br />

of ≤ 0.8 W/m 2 K were achieved by a reduction in density of<br />

approximately 50%. The components are produced with standard<br />

machinery and wood industry tools of the wood industry.<br />

From OWI (Germany) comes an injection-moulded classroom<br />

seat shell. The polypropylene (PP) and wood-based granulates<br />

were developed by Linotech GmbH (Germany). The chair is soft<br />

and warm to the touch while maintaining standard PP chair<br />

requirements regarding flexibility and notch impact strength.<br />

It withstands upholstery staples and stress load cycles.<br />

As one of the oldest known fasteners in the world, the<br />

wooden nail would seem to have reach its evolutionary peak<br />

some millennia ago. Raimund Beck Nageltechnik (Austria)<br />

however, has now developed collated wooden nails for use<br />

with pneumatic nailers. The LignoLoc fasteners do not<br />

require pre-drilling and achieve their holding power because<br />

of a natural welding effect with the base wood.<br />

biocompositescc.com<br />

Braskem and A. Schulman partner on a<br />

sustainable solution for rotomolding processes<br />

Braskem, the largest petrochemical company in the<br />

Americas, has entered into a partnership with A. Schulman,<br />

Inc., a leading global producer of high-performance<br />

plastic compounds and resins, to produce and market a<br />

new sustainable solution for the rotomoulding process.<br />

Braskem identified a market demand for more<br />

sustainable solutions in rotomolded products, and<br />

developed a solution to enable the rotational molding of<br />

general-purpose parts, with applications ranging from<br />

toys and furniture to agricultural tools that can contain<br />

more than 50% of Green Plastic in their composition.<br />

The new Green Polyethylene rotomoulding grade will<br />

be brought to the market by Schulman and feature the I’m<br />

green seal, marking it as a sustainable product that can<br />

contribute to the reduction of greenhouse gas emissions.<br />

A. Schulman, which contributes to the partnership<br />

through its industrial and commercial expertise in<br />

serving clients directly with products that meet market<br />

needs, will introduce the product at Rotoplas <strong>2017</strong>, the<br />

largest trade fair of the rotomolding industry, which<br />

takes place from September 26-28 in the United States.<br />

“The partnership with A. Schulman will benefit a market<br />

that requires innovative products. The new compound<br />

is another step of the petrochemical industry towards<br />

reinforcing the commitment of companies to new solutions<br />

that help to reduce greenhouse gas emissions,” said Gustavo<br />

Sergi, Director of Renewable Chemicals at Braskem.<br />

“A. Schulman is honored to have a long-standing<br />

collaborative relationship with Braskem and we are equally<br />

pleased to play a part in helping drive green innovation<br />

the specialty chemical industry and specifically for the<br />

rotomolding market,” said Gustavo Perez, Senior Vice<br />

President and General Manager – Latin America, A. Schulman.<br />

www.braskem.com | www.aschulman.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 7


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Eastman licenses proprietary<br />

FDCA technology to Origin Materials<br />

Eastman Chemical Company and Origin Materials<br />

(formerly known as Micromidas) have entered into a<br />

non-exclusive license agreement for Eastman to license<br />

its proprietary 2,5-Furandicarboxylic Acid (“FDCA”) and<br />

FDCA derivatives production technology from renewable<br />

resources to Origin Materials.<br />

Origin also recently purchased an oxidation pilot plant<br />

from Eastman that will enable Sacramento-based company<br />

to demonstrate the licensed technology. Terms of the<br />

license agreement and pilot plant sale were not disclosed.<br />

FDCA has been identified by the U.S. Department of<br />

Energy as one of the top 12 bio-based building blocks, and<br />

can be converted into a number of high-value chemicals or<br />

materials. FDCA can be used to produce polymer resins,<br />

films, and fibers and as a building block for plasticizers.<br />

The largest initial FDCA applications are expected to be to<br />

make 100 percent bio-based plastics, such as polyethylene<br />

furanoate (PEF) for beverage containers and food packaging.<br />

Eastman has developed key technologies for economically<br />

competitive conversion of 5-(hydroxymethyl) furfural (5-<br />

HMF) and its derivatives to crude FDCA, polymer grade<br />

FDCA and polymer grade dimethylfuran-2,5-dicarboxylate<br />

(DMF). Eastman’s technology is broadly flexible in terms of<br />

feedstocks and provides efficient production of crude FDCA,<br />

polymer grade FDCA and polymer grade DMF.<br />

“Eastman’s technology provides robust and multiple<br />

integrated engineering options for commercialization,”<br />

said Eastman’s Damon Warmack, senior vice president of<br />

Corporate Development and Chemical Intermediates. “This<br />

agreement leverages the world-class FDCA production<br />

technologies we have developed over the last several years.”<br />

Eastman is actively pursuing a broad intellectual property<br />

strategy with dozens of U.S. and foreign patents awarded<br />

or pending.<br />

John Bissell, CEO of Origin Materials, said the company<br />

is excited bythe opportunities created by this licensing<br />

agreement. “This technology will enable us to produce<br />

FDCA monomer, which can then be used by our customers<br />

to develop PEF bottles, films and other plastics from our<br />

intermediate chemicals,” said Bissell. MT<br />

http://vercet.natureworksllc.com<br />

Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of<br />

the past two months. The story that got the most clicks<br />

from the visitors to bioplasticsmagazine.com was:<br />

PLA that can take the heat (01 Sept <strong>2017</strong>)<br />

Fibers of a corn-derived, biodegradable plastic<br />

developed at the University of Nebraska-Lincoln.<br />

Nebraska researchers and their colleagues have<br />

demonstrated a new technique for improving the<br />

properties of bio-plastic that could also streamline<br />

its manufacturing, making it more competitive with<br />

petroleumb<br />

a s e d<br />

counterparts.<br />

Introducing<br />

a simple<br />

step to the<br />

production of<br />

plantderived,<br />

biodegrada-ble plastic could im-prove its properties<br />

while overcoming obstacles to manufacturing it<br />

commercially, says new research from the University of<br />

Nebraska-Lincoln and Jiangnan University...<br />

more at https://tinyurl.com/news-<strong>2017</strong>0901<br />

8 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />

HEXPOL TPE<br />

green@hexpolTPE.com<br />

www.hexpolTPE.com


io CAR<br />

says<br />

THANK YOU...<br />

...to all of the attendees,<br />

sponsors, and speakers<br />

who participated in<br />

bio!car <strong>2017</strong><br />

www.bio-car.info<br />

Media Partner supported by co-organized by<br />

1 st Media Partner<br />

Institut<br />

für Ökologie und Innovation<br />

by decision of the<br />

German Bundestag<br />

in cooperation with<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 9


Cover Story<br />

Advertorial<br />

INDOCIHINE BIO PLASTIQUES (ICBP) SDN. BHD.<br />

C, M, Y , K<br />

45, 0,90, 0<br />

C , M, Y, K<br />

10, 0, 80,0<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

C, M, Y, K<br />

0, 0, 0, 0<br />

ICBP<br />

BIO RESIN<br />

COMPARISAN<br />

PETROLEUM<br />

RESIN<br />

Yes Biodegradable No<br />

Yes Renewable Resources No<br />

Lower (50%<br />

Electicity Saving)<br />

Processing Temperature Higher<br />

Lower Carbon Footprint (CO2) Higher<br />

Lower<br />

Greenhouse<br />

Gas Emissions (GHG)<br />

Higher<br />

Safe for Food<br />

Contact Under<br />

US FDA & REACH<br />

Standards<br />

Toxic to humans and<br />

environment<br />

Harmful


organized by<br />

5 th PLA World Congress<br />

29-30 MAY* 2018 MUNICH › GERMANY<br />

is a versatile bioplastics raw<br />

PLA material from renewable resources.<br />

It is being used for films and rigid packaging,<br />

for fibres in woven and non-woven applications.<br />

Automotive industry and consumer electronics<br />

are thoroughly investigating and even already<br />

applying PLA. New methods of polymerizing,<br />

compounding or blending of PLA have broadened<br />

the range of properties and thus the range<br />

of possible applications.<br />

That‘s why bioplastics MAGAZINE is now<br />

organizing the 5 th PLA World Congress on:<br />

29-30 May* 2018 in Munich / Germany<br />

Experts from all involved fields will share their<br />

knowledge and contribute to a comprehensive<br />

overview of today‘s opportunities and challenges<br />

and discuss the possibilities, limitations<br />

and future prospects of PLA for all kind of<br />

applications. Like the three congresses<br />

the 5 th PLA World Congress will also offer<br />

excellent networking opportunities for all<br />

delegates and speakers as well as exhibitors<br />

of the table-top exhibition.<br />

The team of bioplastics MAGAZINE is looking<br />

forward to seeing you in Munich.<br />

The conference will comprise high class presentations on<br />

› Latest developments<br />

› Market overview<br />

call for papers now open<br />

› High temperature behaviour<br />

› Blends and comounds<br />

› Additives / Colorants<br />

› Applications (film and rigid packaging, textile,<br />

automotive,electronics, toys, and many more)<br />

Sponsor:<br />

Contact us at: mt@bioplasticsmagazine.com<br />

for exhibition and sponsoring opportunities<br />

www.pla-world-congress.com<br />

* date subject to changes<br />

› Fibers, fabrics, textiles, nonwovens<br />

› Reinforcements<br />

› End of life options<br />

(recycling,composting, incineration etc)<br />

Supported by:


Award<br />

The 12 th<br />

Bioplastics<br />

Award<br />

Presenting the<br />

five finalists<br />

bioplastics MAGAZINE is honoured<br />

to present the five finalists<br />

for the 12 th Global Bioplastics<br />

Award. Five judges from<br />

the academic world, the press and<br />

industry associations from America,<br />

Europe and Asia have again<br />

reviewed many really interesting<br />

proposals. On these two pages<br />

we present details of the five most<br />

promising submissions.<br />

The Global Bioplastics Award<br />

recognises innovation, success and<br />

achievements by manufacturers,<br />

processors, brand owners, or<br />

users of bioplastic materials. To<br />

be eligible for consideration in<br />

the awards scheme the proposed<br />

company, product, or service<br />

should have been developed or<br />

have been on the market during<br />

2016 or <strong>2017</strong>.<br />

The following companies/<br />

products are shortlisted (without<br />

any ranking) and from these<br />

five finalists the winner will<br />

be announced during the 12 th<br />

European Bioplastics Conference<br />

on November 28 th , 2016 in Berlin,<br />

Germany.<br />

Biobrush (Germany)<br />

Bioplastic toothbrush made of<br />

wood scraps<br />

Biobrush turns wood scraps into<br />

toothbrushes. The handle as well as the<br />

packaging are made from bioplastics<br />

based on cellulose made of the wood<br />

waste from sustainable forestry. The<br />

bristles are made of 100 % renewable<br />

polyamide, the main component is<br />

castor oil, without harmful emollients.<br />

The toothbrushes are clearly designed<br />

and available at a fair price.<br />

Making sustainable products<br />

accessible to as many people as<br />

possible is a key factor in the concept<br />

of Biobrush. The company, therefore,<br />

strives to maintain fair pricing.<br />

The manufacturing of the colour<br />

master batches is adapted to the<br />

bioplastic and contains carefully<br />

selected pigments, in which the<br />

concentration of heavy metal is way<br />

below threshold value.<br />

Producing sustainable products, is<br />

not just about replacing the conventional<br />

by eco. All aspects of the product - its<br />

function, nature and composition,<br />

pricing, sales approach and packaging<br />

- need reassessment. Biobrush<br />

toothbrushes combine features relevant<br />

to state-of-the-art dental care with a<br />

clear design, using resource saving<br />

and trend-setting materials: bioplastic<br />

and packaging based on cellulose and<br />

bristles derived from castor oil. The<br />

practical and home compostable sidesealed<br />

pouch contains only essential<br />

product information.<br />

Biobrush represents a holistic<br />

approach: Product biobased.<br />

Biodegradable, but not marketed as<br />

to be composted… The bristles not yet<br />

biodegradable, but 100 % biobased.<br />

Packaging, biobased and compostable.<br />

Looking outside the box (across the<br />

German borders) in countries where<br />

waste disposal is not as advanced…<br />

biodegradability may be an advantage in<br />

the long term.<br />

www.biobrush-berlin.com<br />

MAIP (Italy)<br />

I am NATURE : the first Bio-<br />

Technopolymer<br />

I am NATURE is a special PHBHbased<br />

compound, available in tailor made<br />

grades and suitable for high temperature<br />

applications. It offers a sustainable solution<br />

preserving the technical properties of a<br />

traditional thermoplastic material.<br />

Maip has developed different bioplastics<br />

that are sold under the name of I am<br />

NATURE for several years. These PHBH<br />

based grades are compounded with<br />

natural fillers and additives of vegetal<br />

origin as well as functional components<br />

for specific requirements.<br />

For a new series of switch cover frames<br />

that should have an advanced design and<br />

a remarkable environment sustainability<br />

connotation, ABB was looking for a<br />

bioplastic material that could replace<br />

technopolymers such as ABS or PC/<br />

ABS. In a joint development ABB and<br />

Maip succeeded in creating a special I am<br />

NATURE grade that is suitable to satisfy<br />

all the multiple requirements of the<br />

component. The new compound exhibits<br />

particular properties such as high<br />

dimensional stability, thermal resistance<br />

(about 130 °C), superior UV and light<br />

resistance, easy colourability and easy<br />

mouldability in multi cavity moulds.<br />

Easy processability and specific electric<br />

features such as for example a glow wire<br />

of 650 °C at 2 mm.<br />

The most severe test of all, the scratch<br />

resistance, led to the development of special<br />

grades that show surprising mar / scratch<br />

resistance values also in case of matte textures.<br />

The main properties that were achieved,<br />

allow the definition of the new I am<br />

NATURE as an actual Bio-Technopolymer<br />

that also allows to eliminate the painting<br />

(because of its good mass colourability)<br />

dramatically reducing the carbon footprint<br />

of the component.<br />

The switch covers were officially<br />

introduced to the market in Europe in<br />

September <strong>2017</strong>.<br />

www.maipsrl.com<br />

12 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Award<br />

TU/e Technische Universiteit Eindhoven<br />

(The Netherlands)<br />

Fully biobased pedestrian bridge<br />

A fully biobased pedestrian bridge, the<br />

first in the world, has been realised at the<br />

TU/e campus, Eindhoven, Netherlands,<br />

spanning the river Dommel. After<br />

researching and testing various biobased<br />

material properties and optimising<br />

alternative structural designs, the bridge<br />

has been produced with the help of<br />

many students in all stages of design<br />

and production, using only biobased<br />

materials.<br />

The bridge, first in its kind, has been<br />

made fully out of biobased materials:<br />

Flax and hemp fibres provide the<br />

strength, combined in a biobased epoxy<br />

resin, round an internal core of PLA<br />

bio-foam. The PLA foam is used as lost<br />

formwork for the structural biobased<br />

composite skin. As the whole bridge was<br />

transported to its final location and put<br />

in place in one peace, lightweight was a<br />

very important issue<br />

After a successful loadtest for<br />

the building inspection of the city of<br />

Eindhoven (5,0 kN/m 2 ), the bridge was<br />

installed in the Dutch Design week,<br />

last October, 2016. The project is the<br />

result of a research collaboration of the<br />

universities in Eindhoven and Delft as<br />

well as the Centre for Biobased Economy<br />

and the company NPSP bv. With High<br />

Tech Glass sensor technology the bridge<br />

is now monitored during use.<br />

A unique material combination of<br />

natural reinforcing fibres, a biobased<br />

epoxy-resin around a core of PLA foam…<br />

in a unique application sector: Building<br />

and construction. The project shows<br />

exemplary what can be achieved with<br />

bioplastics in clever combinations.<br />

www.tue.nl<br />

Adidas and Amsilk (Germany)<br />

Futurecraft Biofabric shoe<br />

The adidas Futurecraft Biofabric<br />

shoe features an upper made from<br />

100% Biosteel ® fibre, a nature-based<br />

and completely biodegradable highperformance<br />

fibre, developed by the<br />

biotech company AMSilk (Planegg,<br />

Germany). The material offers a unique<br />

combination of properties that are<br />

crucial in performance, such as being<br />

15% lighter in weight than conventional<br />

synthetic fibres as well as having the<br />

potential to be the strongest fully natural<br />

material available.<br />

In addition, Biosteel fibre also<br />

provides a far more sustainable<br />

offering. According to Amsilk, who have<br />

invested more than 200.000 bioengineer<br />

man hours and know-how into their<br />

products the fibres are made of 100 %<br />

nature based biopolymers, are 100 %<br />

vegan and biodegradable. The world’s<br />

first artificial silk fibre is entirely made<br />

of recombinant spider silk proteins.The<br />

Technical University of Munich’s website<br />

says the world’s first artificial silk fibre is<br />

entirely made of recombinant spider silk<br />

proteins. And io9.gizmodo.com unveils<br />

this: The company’s process uses<br />

genetically engineered E. coli samples<br />

to express silk protein derived from<br />

the DNA of the European garden cross<br />

spider, and is capable of generating<br />

about 20 different silk grades from four<br />

silk varieties<br />

Being 100% biodegradable in a fully<br />

natural process, the Biosteel fiber also<br />

provides a sustainable offering. This<br />

continues adidas’ journey of sustainable<br />

innovation – from a starting point of<br />

virgin plastics, to recycled plastics,<br />

to its partnership with Parley for the<br />

Oceans and now a totally new frontier<br />

of investing in solutions that leverage<br />

science and nature as an integral part<br />

of innovation.<br />

www.adidas-group.com | www.amsilk.com<br />

ICEE Containers (Australia)<br />

Foldable, reusable insulating box<br />

Since commercial production<br />

of expandable polystyrene in 1952<br />

the industry worldwide has been<br />

attempting to mould a durable, living<br />

hinge in particle foam. ICEE’s patented<br />

innovation means insulated boxes are<br />

no longer disadvantaged by their bulk<br />

as they can now be economically stored<br />

and transported flat, making them easy<br />

to return for reuse or recycling.<br />

ICEE has successfully moulded a<br />

living hinge in various particle foams<br />

including BASF’s ecovio ® a plant based<br />

compostable biofoam. The superior<br />

insulating and cushioning properties of<br />

particle foam makes them ideal for the<br />

expanding ecommerce grocery market,<br />

paddock to plate and the traditional<br />

markets such as pharmaceuticals,<br />

fresh produce and seafood.<br />

There are growing concerns<br />

surrounding food waste globally and<br />

ICEE’s insulated suite of boxes keeps<br />

perishable fresh without the need<br />

for refrigerated vehicles which is<br />

particularly advantageous in developing<br />

countries where food waste is highest.<br />

ICEE is a member of United Nations<br />

initiative Save Food (save-food.org)<br />

committed to reducing food loss<br />

sustained in the supply chain.<br />

ICEE’s fold flat insulated boxes<br />

are 98% air, 100% recyclable and<br />

now available in compostable plant<br />

based biofoam. They’re able to deliver<br />

perishables in unrefrigerated vehicles<br />

making the boxes ideal for disruptive<br />

delivery options such as Uber, bicycles,<br />

couriers, taxi apps, drones etc further<br />

adding to their attractive eco-friendly<br />

footprint.<br />

Capturing new markets and<br />

reducing food waste in countries with<br />

unsophisticated logistics by protecting<br />

food from bruising and climate stress in<br />

a biofoam box is a compelling story.<br />

www.iceefoldingbox.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 13


Fibers & Textiles<br />

Yarns from biobased polymers<br />

Sustainable options for technical textiles<br />

The need to reduce CO 2<br />

emissions and to become independent<br />

of fossil-based fibre products motivated PHP<br />

Fibers (Wuppertal, Germany) to search for bio-based<br />

alternatives.<br />

The company’s investigations revealed two potential<br />

candidates, both of which are thermoplastic polymers<br />

suitable for fibre spinning.<br />

Biobased and biodegradable high-tenacity<br />

polyester yarn (PLA)<br />

PHP’s polyester yarn Diolen ® 150BT is based on PLA and<br />

thus 100% biobased and biodegradable under industrial<br />

composting conditions. The polyester yarn exhibits low<br />

moisture absorption and provides good UV stability as well<br />

as low flammability.<br />

Compared to textile yarns, Diolen 150BT demonstrates<br />

superior tensile performance. It is therefore an option for<br />

a variety of sustainable applications. Examples are the<br />

substitution for non-biodegradable fixtures in agricultural<br />

and horticultural environments or sustainable packaging<br />

reinforcement for paper-based adhesive tapes<br />

Enka ® BIO – Biobased high-tenacity polyamide<br />

yarn<br />

For existing technical fibre applications, it would be<br />

particularly advantageous if yarns manufactured from<br />

biobased polymers could be considered as so-called drop<br />

in alternatives for current fossil-based products. In this<br />

case, similar processing conditions could be used without<br />

the need to make significant adaptions. In comparison to<br />

fossil-based PA 6.6 polymer, the bio-based PA 4.10 polymer<br />

was found to provide a very good match:<br />

The melting temperature and glass transition temperature<br />

of PA 4.10 are at the level of PA 6.6. But Polyamide 4.10<br />

offers weight advantages due to its lower density. It picks<br />

up less moisture compared to PA 6.6 and it provides a 40 %<br />

higher tensile modulus under humid storage conditions.<br />

The material is 70 % bio-based.<br />

Technical biobased PA 4.10 yarn vs. technical<br />

fossil-based PA 6.6 yarn<br />

Spinning evaluations carried out on an industrial scale<br />

proved that the biobased PA 4.10 polymer can be converted<br />

into technical multifilament yarns.<br />

The tensile characteristics were found to be largely<br />

comparable to those of fossil-based PA 6.6 technical yarns.<br />

At low elongation rates, the modulus of biobased PA<br />

4.10 yarn is certainly at the level of PA 6.6. The Elongation<br />

at break is higher and the breaking force is slightly lower<br />

compared to PA 6.6.<br />

In Mechanical Rubber Goods application PA 4.10 yarns/<br />

cords provide good adhesion characteristics to rubber and<br />

fatigue resistance at the level of reference PA 6.6.<br />

PHP Fibers demonstrated that biobased technical<br />

polyester (PLA) and polyamide fibres can compete with<br />

or even outperform standard fossil- based polyester and<br />

polyamide fibres. MT<br />

www.php-fibers.com<br />

Polymer properties of biobased PLA polymer vs. fossil-based PET polymer<br />

*) Sources: Mary Ann Liebert, Inc. Vol.6, no.4, August 2010, Industrial Biotechnology, Natureworks<br />

Polymer<br />

Melting<br />

Temperature,<br />

Tm<br />

°C<br />

Glass<br />

Transition<br />

Temperature,<br />

Tg<br />

°C<br />

Density<br />

g/cm³<br />

Moisture<br />

Uptake at<br />

50 % RH*<br />

%<br />

Tensile<br />

Modulus dry*<br />

MPa<br />

Tensile<br />

Modulus<br />

conditioned<br />

50 % RH*<br />

MPa<br />

Biobased<br />

content<br />

%<br />

CO 2<br />

Emission*<br />

kg CO 2<br />

eq / kg<br />

polymer<br />

PLA 160 – 180 55 – 60 1.24 0.2 2900 – 3000 n.a. 100 0.6<br />

PET 250 – 260 70 1.38 0.4 2800 – 3100 n.a. 0 3.4<br />

Polymer properties of biobased PA 4.10 vs. fossil-based PA 6.6<br />

*) Sources: DSM primary data for PA 4.10 (EcoPaXX), Plastics Europe eco-profiles for PA 6.6<br />

Polymer<br />

Melting<br />

Temperature,<br />

Tm<br />

°C<br />

Glass<br />

Transition<br />

Temperature,<br />

Tg<br />

°C<br />

Density<br />

g/cm³<br />

Moisture<br />

Uptake at<br />

50 % RH*<br />

%<br />

Tensile<br />

Modulus dry*<br />

MPa<br />

Tensile<br />

Modulus<br />

conditioned<br />

50 % RH*<br />

MPa<br />

Biobased<br />

content<br />

%<br />

CO 2<br />

Emission*<br />

kg CO 2<br />

eq / kg<br />

polymer<br />

Bio PA 4.10 250 70 1.09 1.9 3100 1750 70 0<br />

PA 6.6 255 74 1.14 2.7 3250 1250 0 6.4<br />

14 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Fibers & Textiles<br />

The biodegradation after storage under composting conditions in<br />

accordance to EN 14046:2003 was determined by ITV Denkendorf,<br />

Germany.<br />

start 5 weeks 8 weeks<br />

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110 pages full<br />

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ISBN 978-3-<br />

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‘Basics‘ book<br />

on bioplastics<br />

This book, created and published by Polymedia<br />

Publisher, maker of bioplastics MAGAZINE<br />

is available in English and German language<br />

(German now in the second, revised edition).<br />

Tenacity (cN/tex)<br />

40<br />

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The book is intended to offer a rapid and uncomplicated<br />

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the opportunity to dig deeply into the subject, such as students<br />

or those just joining this industry, and lay readers. It gives<br />

an introduction to plastics and bioplastics, explains which<br />

renewable resources can be used to produce bioplastics,<br />

what types of bioplastic exist, and which ones are already on<br />

the market. Further aspects, such as market development,<br />

the agricultural land required, and waste disposal, are also<br />

examined.<br />

An extensive index allows the reader to find specific aspects<br />

quickly, and is complemented by a comprehensive literature<br />

list and a guide to sources of additional information on the<br />

Internet.<br />

Elongation (%)<br />

Technical PLA yarn - Diolen 150BT<br />

Textile PLA yarn*<br />

*) Source “Polylactic acid fibres”,<br />

D W FARRINGTON et al., NatureWorks LLC<br />

The author Michael Thielen is editor and publisher<br />

bioplastics MAGAZINE. He is a qualified machinery design<br />

engineer with a degree in plastics technology from the RWTH<br />

University in Aachen. He has written several books on the<br />

subject of blow-moulding technology and disseminated his<br />

knowledge of plastics in numerous presentations, seminars,<br />

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by phone +49 2161 6884463 or by e-mail<br />

books@bioplasticsmagazine.com<br />

Or subscribe and get it as a free gift<br />

(see page 57 for details, outside German y only)<br />

Elongation (%)


Fibers & Textiles<br />

Comfort beyond words<br />

SOLOTEX ® , a partly biobased polyester-fibre (polytrimethylene<br />

terephthalate – PTT) by Teijin Frontier Co. Ltd., Tokyo,<br />

Japan, provides a soft, stretchy texture with gentle<br />

cushioning and offers vivid colors. These advantages could<br />

never be achieved with conventional polyester, polyurethane, or<br />

nylon alone. The many superb characteristics of Solotex derive<br />

from its spring-like, helical molecular structure. The material<br />

is also easy to combine with other fibers, bringing out the characteristics<br />

of the other fiber while adding a new texture and<br />

new functionality. Solotex is a fiber with unlimited potential to<br />

make textile products<br />

more comfortable<br />

to wear or<br />

Fossil-fuel derived<br />

Bio-derived<br />

use.<br />

Seven defining<br />

characteristics of<br />

Solotex derive<br />

Terephthalic acid<br />

from the unique<br />

molecular structure<br />

of the fiber.<br />

The molecules<br />

form a flexible spring-like helix that makes the fiber soft, light,<br />

stretchy, and shape-stable.<br />

Plant-based eco-friendly ingredients<br />

Biomass-derived, plant-based ingredients are used for 37%<br />

of the polymers (Fig 1) that make up Solotex. The fabric thus<br />

reduces consumption of fossil fuels, and helps cut down on<br />

greenhouse gases. Solotex is an eco-friendly fiber that is kind<br />

to people and on the environment.<br />

Super soft feel and smoothness for comfort<br />

The touch of the PTT fibres feels even softer than luxury<br />

cashmere wool. Smooth against the skin, it is more comfortable<br />

to wear than any fiber that has come before. Blending with other<br />

fibers does not affect its superb softness, while maintaining the<br />

beneficial qualities of the blended fibers.<br />

Keeps its shape to look great<br />

A spring-like, helical molecular structure provides form<br />

stability to spring back into shape even with movement. The<br />

fiber resists wrinkles and does not easily get stretched out from<br />

repeated bending at the knee or elbow, maintaining a beautiful<br />

shape at all times. There is also little shrinkage or stretch<br />

even after repeated machine washings and tumble drying,<br />

demonstrating superb dimensional stability.<br />

Stretchiness that feels great, with no stress<br />

Solotex is surprisingly free of any feeling of pressure, even<br />

following the lines of the body. It expands and contracts in any<br />

direction with the body’s movement, feeling truly comfortable<br />

and allowing for free movement. The fibre is ideal for tightfitting<br />

bottom wear and active clothing.<br />

HOOC COOH + HOCH2CH2CH2OH OOC COOCH2CH2CH2 n<br />

1,3-propanediol<br />

(PDO)<br />

Fig.1: 37% bio-derived. *Testing performed using radiocarbon 14 C dating.<br />

Harmonizes<br />

well with<br />

other fibers<br />

for even<br />

greater<br />

potential<br />

Teijin’s PTT<br />

fibres are easy<br />

to combine with<br />

other fibers.<br />

They are highly compatible with both synthetic and natural<br />

fibers, for blending as desired. The fiber will add a soft texture to<br />

improve the feel against the skin, and it provides superb stretch<br />

and recovery from elongation. It is possible to add new texture<br />

and new functionality while bringing out the characteristics of<br />

the blended fiber.<br />

The ideal cushioning with fluffy rebound<br />

Maintains bounce even after repeated compressions and<br />

quickly recovers its fluffy volume. Because of its high durability,<br />

Solotex retains its unique texture for a long time. These<br />

characteristics are best utilized in insulated coats, pillows,<br />

futons, and other items with filling.<br />

Deep, vivid colors that last<br />

Outstanding color development is a key element for fashion<br />

applications. Solotex is very easy to dye, producing deep, vivid<br />

colors with a high-grade feel even when processing at lower<br />

temperatures than conventional methods. Extremely colorfast<br />

for long-lasting dyed color that won’t fade. MT<br />

www.solotex.net<br />

Polytrimethylene terephthalate<br />

(PTT)<br />

Table 1<br />

Solotex Polyester Nylon 6.6<br />

The Positioning<br />

of SOLOTEX ®<br />

Polyester<br />

Shape-Retention<br />

Tenacity (cN/dtex 2.8-3.5 3.7-4.4 4.1-4.5<br />

Elongation (%) 45-53 30-38 32-44<br />

Initial Young’s<br />

modulus (cN/dtex)<br />

20 97 31<br />

Tensile recovery (%) 67-88 29 62<br />

Boiling water<br />

shrinkage (%)<br />

7-9 7 13<br />

Melting point (°C) 230 254 253<br />

Deterioration of<br />

strength due to<br />

weather exposure<br />

Negtigible Negligible<br />

Slight deterioration,<br />

some yellowing<br />

Stretch<br />

Polyutethane<br />

Nylon<br />

Soft Texture<br />

16 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Fibers & Textiles<br />

Advances in textile<br />

applications for<br />

biobased polyamide<br />

By:<br />

Howard Chou<br />

Director of R&D<br />

Cathay Industrial Biotech,<br />

Shanghai, China,<br />

Cathay Industrial Biotech (CIB), Shanghai, China, developed<br />

proprietary technology to commercially produce<br />

biobased pentamethylenediamine (DN5), in order to<br />

address the growing demand for innovative new materials.<br />

DN5 is a unique five-carbon platform chemical and an alternative<br />

to hexamethylenediamine (HMDA), a six-carbon<br />

platform chemical used in the production of polymers, such<br />

as polyamide 66 and hexamethylene diisocyanate (HDI). Although<br />

DN5 and HMDA only differ by one carbon length, this<br />

difference creates significant potential for the development<br />

of new polymers with innovative properties.<br />

One polymer CIB developed using its DN5 technology is a<br />

biobased polyamide PA56 named Terryl ® . The Terryl polymer<br />

consists of an odd-numbered repeating unit, instead of the<br />

even-numbered repeating unit found in polyamides 6 and<br />

66. However, the crystalline structure of Terryl prefers an<br />

α-like structure that is more similar to polyamide 66 than<br />

polyamide 6, which exists in both an α and a γ-form. As<br />

a result, Terryl shares many of the stiffness, tensile and<br />

flexural modulus, and wear resistance advantages found in<br />

polyamide 66. Unlike polyamide 66 where 100 % of the interchain<br />

hydrogen bonds can form, Terryl forms a structure<br />

where at most 50% of the inter-chain hydrogen bonds can<br />

form. Another difference of importance is that Terryl has<br />

a unique ratio of carbon, nitrogen, oxygen, and hydrogen<br />

(CNOH). The CNOH ratio found in Terryl contains a higher<br />

proportion of nitrogen compared to polyamides 6 and 66,<br />

which have the same CNOH ratio. The higher nitrogen<br />

content increases the limiting oxygen index of Terryl fibres,<br />

making them more flame retardant.<br />

The scientists at CIB and its collaborators discovered that<br />

the differences in the molecular structure described above<br />

translate to fibres with novel properties. For example, Terryl<br />

has a lower initial modulus compared to the traditional fibres<br />

made from polyamide 6 and 66 (Figure 1). A monofilament<br />

of Terryl with a denier per filament (dpf) 1 of 1.5 has an initial<br />

modulus similar to that of wool, which means that Terryl<br />

feels significantly softer than traditional synthetic fibres.<br />

Furthermore, the elastic recovery rate of Terryl is higher<br />

than that of traditional PA6/PA66 fibres on the market<br />

(Figure 2). Lastly, Terryl shows improved dyeing capabilities,<br />

and can be dyed at lower temperatures and with less dye<br />

(Figure 3) without sacrificing any dyeing performance.<br />

The unique properties of Terryl has garnered a significant<br />

amount of interest from the market. As a result, Terryl<br />

was voted as the “Most Popular Fibre Product” at the Yarn<br />

Expo in Shanghai on March <strong>2017</strong>, receiving 39% of the votes<br />

casted. In addition to Terryl, CIB is also exploring other new<br />

fibres by combining DN5 with its long-chain dicarboxylic<br />

acid platform. The successful trials with local textile<br />

spinners recently makes CIB confident that it will bring a<br />

new class of materials to the market, following the opening<br />

of its new production plant at Xinjiang, which will have an<br />

annual capacity of 50,000 tonnes of DN5 and 100,000 tonnes<br />

of polyamides.<br />

1: denier = gram per 9000 meter, so dpf 1.5 means one<br />

filament weighs 1.5 gram per 9000 m<br />

www.cathaybiotech.com/en/<br />

48 —<br />

46 —<br />

44 —<br />

Initial Modulus (cN/dtex) Elastic Recovery (%) Elastic Recovery (%)<br />

100 —<br />

25 —<br />

80 —<br />

20 —<br />

42 —<br />

40 —<br />

38 —<br />

36 —<br />

60 —<br />

40 —<br />

20 —<br />

15 —<br />

10 —<br />

5 —<br />

0 —<br />

0 2 3 4 8<br />

34 —<br />

Terryl<br />

PA6<br />

PA66<br />

0 —<br />

Terryl PA6/PA66 Terryl PA6/PA66<br />

10% elongation 20% elongation<br />

Terryl<br />

PA6<br />

PA66<br />

Figure 1: Terryl is softer<br />

than existing synthetic fibers<br />

Figure 2: Terryl has better elastic recovery<br />

than existing synthetic fibers<br />

Figure 3: Terryl uses less dye to achieve<br />

the same dyeing performance<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 17


Fibres & Textiles<br />

Stable ring spinning process<br />

for PLA staple fibre yarns<br />

This article presents the current state of the project<br />

SPEY which aims to establish poly lactic acid (PLA)<br />

staple fibre yarns in home textiles or in technical applications<br />

using a methodological approach and process<br />

analysis. The goal of the performed process analysis is<br />

the avoidance of degradation phenomena during the ring<br />

spinning process. At the current state of the project, Ring<br />

spinning yarn of 100 % PLA was successfully produced. A<br />

production speed of v pr<br />

= 23 m/min combined with a twist<br />

factor of α m<br />

= 100 T/m lead to a stable process without yarn<br />

breakage. The resulting yarn count is T t<br />

= 25 tex. This article<br />

provides an overview of the results from the ring spinning<br />

trials with experimental PLA filaments and presents optimised<br />

production parameters for the stable production of<br />

100 % PLA ring spinning yarn.<br />

Introduction<br />

Currently, Europe consumes more than 6 million tonnes<br />

of textile fibres 34 % for clothing, 27 % for housing and<br />

carpeting, 38 % for other industrial technical usages [1]. The<br />

European textile and clothing industry has a longstanding<br />

tradition of leadership in terms of innovation, fashion and<br />

creativity. Even though the European textile and clothing<br />

industry increasingly encounters fierce global competition<br />

and significant relocation of manufacturing to low-wage<br />

countries - with 165 billion EUR turnover - it continues to<br />

represent one of Europe’s major industrial sectors [2].<br />

Today, the European textile industry is challenged to make<br />

a radical shift towards innovative and high-value added<br />

products to counter the competition with low-wage countries.<br />

At the same time, European industry is looking to find links to<br />

the environment-concerned customers via the increased use<br />

of renewable and recyclable as well as recycled materials.<br />

PLA is at the moment produced from starch (corn) or from<br />

sugar (sugarbeet). The fibre products are highly smooth and<br />

completely non-irritating to the skin, while being 100 %<br />

biodegradable and compostable. PLA staple fibres are a<br />

possible alternative as a substitution of existing synthetic<br />

fibre products. The replacement of oil based polymers by<br />

biobased alternatives is a topic that is regarded with high<br />

priority in textile innovation programs. PLA offers additional<br />

end-of-life possibilities. It is known and demonstrated that<br />

PLA can be recycled via melt processing and due to the<br />

low melting temperature and the limited water-uptake the<br />

process has a low cost and offers high quality products. Also<br />

hydrolysis to feedstock (monomers) is possible. In contrast<br />

with most oil based polymers, PLA can be composted or used<br />

in biogas installations. At medium term, the market potential<br />

is estimated to the production of 40,000 t/a for PLA and PLA<br />

blended yarns with a volume of appr. 140 Million EUR/a all<br />

over Europe when comparable properties of existing yarns<br />

are reached. Moreover, there’s not much oil occurrence in<br />

Europe but enough area for cultivable land for food and crop<br />

for technical use. The industry of agriculture and forestry are<br />

offered alternative production and income possibilities.<br />

The project Spun EcoYarn (SPEY, AiF Cornet 153 EN)<br />

contributes to a greener environment. Depending on the crop<br />

used 3.3 up to 6 tonnes of PLA can be produced per hectare<br />

crop yield. This is very efficient compared to the production<br />

of about 1 tonne of cotton per hectare. During 2012, 190,000<br />

tonnes of PET fibres were produced just in Germany [3]. The<br />

total energy consumption to produce PLA is about 50 % lower<br />

than for PES (Fig 1., top) and as a consequence also the total<br />

emission of greenhouse gases is about 60 % lower for PLA<br />

than for PES (Fig. 1, bottom).<br />

SPEY aims to establish poly lactic acid (PLA) staple fibre<br />

yarns in home textiles e. g. upholstery fabrics, bedding<br />

textiles, matrass thickening, in technical applications e.<br />

g. work wear and medical textiles using a methodological<br />

approach and process analysis, with the goal of avoiding<br />

degradation phenomena.<br />

The aim of this project is to develop the technology and<br />

expertise to economically produce PLA based spun yarns and<br />

blended spun yarns with properties comparable to existing<br />

PET alternatives. It is targeted to develop in commercially<br />

available conditions, high quality bio-based spun yarns with a<br />

high durability (long life time). To reach this goal the polymer<br />

recipe is modified by additives and process parameters for<br />

melt spinning as well as end spinning for high quality yarns<br />

are defined.<br />

Implementation<br />

Aim of the current work package within the SPEY project is<br />

the production of staple fibre yarns of commercially available<br />

PLA and of experimental PLA by Centexbel. Also, spinning<br />

methods for processing PLA are optimised and PLA staple<br />

fibre yarns with improved properties are developed. PET<br />

(Table 1) based ring yarns will be the benchmark for the<br />

development of the PLA staple fibre yarns. The main target is<br />

to reach a breaking tenacity in the range of 16 – 30 cN/tex [5].<br />

The experimental PLA filaments are cut and texturated<br />

at the user committee member (UCM) of the company<br />

Barnet Europe GmbH & Co. KG, Aachen, Germany. Spin<br />

finish application is performed by the UCM Bozzetto GmbH,<br />

Krefeld, Germany. At ITA the fibres are processed into a sliver<br />

and send to the UCM member Schlafhorst, branch office of<br />

Saurer Germany GmbH & Co. KG, for ring spinning.<br />

18 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Fibres & Textiles<br />

By:<br />

Vadim Tenner 1 , Marie-Isabel Popzyk 1 ,<br />

Yves-Simon Gloy 1 , Raf Van Olmen 2 , Thomas Gries 1<br />

1<br />

Institut für Textiltechnik der RWTH Aachen<br />

University, Aachen, Germany<br />

2<br />

Centexbel, Gent, Belgium<br />

www.ita.rwth-aachen.de<br />

Fig. 1: Energy consumption and<br />

greenhouse gas emission of PLA and PET [4]<br />

100,00<br />

80,00<br />

60,00<br />

40,00<br />

20,00<br />

0,00<br />

Production energy consumption in MJ/kg<br />

PES<br />

-50%<br />

PLA<br />

PLA<br />

PES<br />

4,00<br />

3,00<br />

2,00<br />

1,00<br />

0,00<br />

100,00 100,00<br />

Results<br />

80,00<br />

60,00<br />

In the following, the results from the laboratory<br />

40,00<br />

analysis 20,00 of the produced ring spinning yarns<br />

0,00 of 0,00 100 % PLA are presented. The used batch<br />

PES PES<br />

PLA PLA<br />

of experimental PLA was not applied with an<br />

additional spin finish since spinning trials<br />

showed no necessity for a second spin finish.<br />

Stable spinning processes for ring spinning are<br />

achieved and a factorial design is carried out.<br />

Fibre properties after different processing steps<br />

are shown in Table 2. The laboratory results show,<br />

that the produced sliver contains fibres of 35.99<br />

± 10.41 mm length. The PET fibres, which are<br />

the benchmark, have a 3-times as high tenacity<br />

F t<br />

= 76.61 cN/tex and only half the elongation at<br />

break ε b<br />

= 18.55 %.<br />

Ring spinning<br />

80,00<br />

60,00<br />

40,00<br />

20,00<br />

Production energy energy consumption in MJ/kg in MJ/kg<br />

Ring spinning is performed using a 100 % PLA<br />

sliver. The machine settings including a factorial<br />

design are shown in Table 3.<br />

The ring spinning results have high standard<br />

deviations due to manual spinning preparation<br />

and no significance is discernible. Owing to limited<br />

fibre amounts of around 4-8 kg of each batch an<br />

industrial carding machine is not suitable and a<br />

laboratory carding machine has to be used. This<br />

laboratory carding machine only produces nonwovens<br />

and no slivers. The non-wovens are folded<br />

to slivers of1 m and a weigth of 30 g. Due to this<br />

discontinuous process the sliver pieces have to<br />

be joined. Especially within its connecting areas,<br />

thick and thins places occur in the final sliver. An<br />

autoleveller gillbox can limit thin and thick places<br />

in a sliver to a certain amount but the unevenness<br />

in the slivers is too high for the autoleveller gill to<br />

fully reconcile it.<br />

Due to the manual spinning preparation, two<br />

rovings were fed in simultaneosly into the drafting<br />

unit, in order to increase the evenness of the sliver.<br />

The trials were carried out in an air-conditioned<br />

hall at a room temperature of T = 25 °C and a<br />

relative humidity of ρ = 47 %. Within the trials,<br />

it was proved that ring spinning yarn with 100 %<br />

PLA is possible at v pr<br />

= 10 m/min. Frequent yarn<br />

breakage and no stable ring spinning process<br />

occurred at a production speed of v pr<br />

= 15 m/min<br />

and the twist factor α m<br />

= 80 T/m.<br />

PLA PLA<br />

PES PES<br />

4,00 4,00<br />

3,00 3,00<br />

2,00 2,00<br />

1,00 1,00<br />

0,00 0,00<br />

Table 1: Properties of cotton and PES as benchmark<br />

Specific<br />

gravity<br />

[g/cm³]<br />

Tenacity<br />

[cN/tex]<br />

Moisture<br />

content<br />

[%]<br />

Melting<br />

point [°C]<br />

Elastic<br />

recovery<br />

[5 %<br />

strain]<br />

Cotton 1.39 45 – 55 0.2 – 0.4 255 – 265 65<br />

PES 1.52 20 – 40 7 – 8 - 52<br />

Table 2: Fibre properties of Batch 03 after different processing steps<br />

Processing step<br />

Staple fibre<br />

length L sf<br />

[mm]<br />

Tenacity F f<br />

[cN/tex]<br />

Elongation at<br />

break ε b<br />

[%]<br />

Filament - 27.94 ± 5.44 40.34 ± 10.41<br />

Cut/crimped 41.53 ± 5.57 23,95 ± 5.15 38.81 ± 13.04<br />

Sliver (carding) 35.99 ± 10.41 24.45 ± 5.75 39.16 ± 10.18<br />

Table 3: Machine and processing parameters for ring yarn from<br />

batch 03 (factorial design)<br />

Machine Zinser Impact 72<br />

Ring traveller HEL 1 hr EMT SS 1/0<br />

Production<br />

rate<br />

[m/min] 15 20 25<br />

Twisting<br />

factor α m<br />

[T/m] 80 100 80 100 80 100<br />

Yarn count<br />

T t<br />

[tex] 24.8 21.2 24.<strong>05</strong> 24.4 - 28.2<br />

Tenacity F f<br />

[cN/tex] 12.16 12.96 13.78 12.6 - 10.8<br />

Elongation ε [%] 21.3 21.8 22.7 21.6 - 21.6<br />

Evenness<br />

CVm<br />

Production greenhouse gas gas in CO in 2<br />

CO eg./kg 2<br />

eg./kg<br />

PES PES<br />

-60%<br />

PLA PLA<br />

[%] 21.2 23.2 20.2 20.7 - 19.4<br />

Hairiness H - 10.76 8.99 - 8.14 - 8.26<br />

PLA PLA<br />

PES PES<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 19


Fibres & Textiles<br />

Batch 03 while setting up a twist factor to α m<br />

= 80 T/m reaches given<br />

values of T t<br />

= 25 tex most closely. The necessary yarn count is reached at a<br />

production speed of v pr<br />

= 20 m/min. (Fig. 2)<br />

The measured elongation values show a high variation (Fig. 3) and no<br />

link between elongation and production speed can be determined. At<br />

twist factor of α m<br />

= 80 T/m and a production speed of v pr<br />

= 23 m/min a high<br />

amount of yarn breakage occurred. Therefore is it recommended to use a<br />

higher twist factor of α m<br />

= 100 T/m<br />

Fig. 3: Elongation of ring<br />

spinning yarn from batch 03<br />

29,0 —<br />

27,0 —<br />

25,0 —<br />

23,0 —<br />

21,0 —<br />

19,0 —<br />

Measuring<br />

head =<br />

10 N<br />

Clip type =<br />

4g<br />

Clamping<br />

length =<br />

50 mm<br />

V prüf =<br />

50 mm/min<br />

≙ 0,50 cN/tex<br />

The count-related tenacity of batch 03 ring spun yarn has rather high<br />

deviations for all different yarns. The reason for this is the unevenness of<br />

the sliver which is immanent to the manual production step.<br />

17,0—<br />

0,0 —<br />

α m<br />

= 80<br />

α m<br />

= 100<br />

Decrease in<br />

force =<br />

50 %<br />

V pr<br />

The hairiness of the ring spun yarn from batch 03 is shown in Fig. 5. At a<br />

twist factor α m<br />

= 80 T/m, a value of 10.7 is achieved. The higher twist factor<br />

of α m<br />

= 100 T/m and the production speed of v pr<br />

= 20 m/min achieve the<br />

recommended minimal hairiness of H = 8.14.<br />

Due to the manual production of the sliver, the evenness of ring spun yarn<br />

of batch 03 reaches values of CVm = 26.9 %. Batch 03 shows decreasing<br />

CVm-Values, independent from the twisting factor, with increasing<br />

production rate.<br />

Conclusion and outlook<br />

PLA staple fibres are a possible alternative as a substitution of existing<br />

synthetic fibre products. At the current state of the project, Ring spinning<br />

yarn of 100 % PLA was successfully produced. The article presents the<br />

results from the laboratory analysis of the produced ring spinning yarn. A<br />

yarn count of T t<br />

= 25 tex was achieved with optimised production parameters.<br />

The scientific findings from the performed experiments suggest that the<br />

higher twist factor α m<br />

= 100 T/m and production speed of v pr<br />

= 20 m/min are<br />

good production parameters to achieve the yarn properties which the SPEY<br />

project aims for. Further experiments on ring and rotor spinning machines<br />

and the production of a woven fabric with the experimental PLA yarns will<br />

be performed in <strong>2017</strong>.<br />

Acknowledgement<br />

Fig. 4: Count-related tenacity of<br />

ring spinning yarn from batch 03<br />

18,0 —<br />

17,0 —<br />

16,0 —<br />

15,0 —<br />

14,0 —<br />

13,0 —<br />

12,0 —<br />

11,0 —<br />

10,0 —<br />

9,0 —<br />

0,0 —<br />

α m<br />

= 80<br />

Fig. 5: Hairiness of ring<br />

spinning yarn from batch 03<br />

α m<br />

= 100<br />

15 m/min<br />

20 m/min<br />

23 m/min<br />

Measuring<br />

head =<br />

10 N<br />

Clip type =<br />

4g<br />

Clamping<br />

length =<br />

50 mm<br />

V prüf =<br />

50 mm/min<br />

≙ 0,50 cN/tex<br />

Decrease in<br />

force =<br />

50 %<br />

V pr<br />

15 m/min<br />

20 m/min<br />

23 m/min<br />

Grateful acknowledgement goes to the research association<br />

Forschungskuratorium Textil e. V., a branch of the German Federation of<br />

Industrial Research Associations (AiF), for the financial funding — through<br />

AiF-CORNET — of the research project AiF-No. 153 EN SPEY. Grateful<br />

acknowledgement goes also to the company Schlafhorst, branch office of<br />

Saurer Germany GmbH & Co. KG, for providing their expertise and assets<br />

for performing the ring spinning trials.<br />

References:<br />

[1] Euratex, The EU-27 Textile and Clothing Industry in the year 2012, May 2013<br />

[2] Position of the European Textile and clothing industry and its applied research community<br />

on support for SME Research & Innovation under Horizon 2020. Euratex, March 2012<br />

[3] IVC Jahresbroschüre 2013 Chemiefaserzahlen und Baumwolle-Wolle<br />

11,5 —<br />

11,0 —<br />

10,5 —<br />

10,0 —<br />

9,5 —<br />

9,0 —<br />

8,5 —<br />

8,0 —<br />

7,5 —<br />

0,0 —<br />

α m<br />

= 80<br />

α m<br />

= 100<br />

V prüf =<br />

50 mm/min<br />

t prüf =<br />

1 min<br />

Principle:<br />

optical<br />

V pr<br />

15 m/min<br />

20 m/min<br />

23 m/min<br />

[4] http://www.natureworksllc.com/the-ingeo-journey/Eco-Profile-and-LCA/Eco-Profile.<br />

aspx#GHG<br />

[5] Uster statistics, http://www.uster.com/en/service/uster-statistics/, visited on May 27th, 2014<br />

www.ita.rwth-aachen.de<br />

Fig. 2: 29,0 —<br />

Yarn count<br />

28,0 —<br />

of ring<br />

spinning<br />

27,0 —<br />

yarn from 26,0 —<br />

batch 03<br />

25,0 —<br />

24,0 —<br />

23,0 —<br />

F V<br />

=<br />

0,5 cN/tex<br />

Reel length =<br />

10 m<br />

Figure 4.1 Evenness of ring<br />

spinning yarn from batch 03<br />

31,0 —<br />

29,0 —<br />

27,0 —<br />

25,0 —<br />

23,0 —<br />

21,0 —<br />

V prüf =<br />

100 mm/min<br />

t prüf =<br />

1 min<br />

Principle:<br />

capacitive<br />

22,0 —<br />

19,0 —<br />

21,0 —<br />

V pr<br />

17,0—<br />

V pr<br />

20,0—<br />

0,0 —<br />

α m<br />

= 80<br />

α m<br />

= 100<br />

15 m/min<br />

20 m/min<br />

23 m/min<br />

0,0 —<br />

α m<br />

= 80<br />

α m<br />

= 100<br />

15 m/min<br />

20 m/min<br />

23 m/min<br />

20 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Industrial Solutions<br />

Polylactide Technology<br />

Uhde Inventa Fischer Polycondensation Technologies has expanded its product portfolio to<br />

include the innovative state-of-the-art PLAneo ® process for a sustainable polymer. The<br />

feedstock for our PLA process is lactic acid, which can be produced from local agricultural<br />

products containing starch or sugar. The application range of PLA is similar to that of polymers<br />

based on fossil resources as its physical properties can be tailored to meet packaging, textile<br />

and other requirements. www.uhde-inventa-fischer.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 21


Fibres & Textiles<br />

The FIBFAB project<br />

New biodegradable fibres from renewable<br />

sources for fabrics with advanced properties<br />

The FIBFAB project, coordinated by AIMPLAS (Valencia,<br />

Spain), will allow obtaining sustainable textile fibres<br />

to replace polyester with advantages such as higher<br />

breathability, lower weight, better tinting and UV ray resistance.<br />

The new fabrics can be easily recycled at the end of<br />

their life, since they do not contain blends of natural and<br />

synthetic fabrics. They may even be composted thanks to<br />

their biodegradability.<br />

Around one million tonnes of fabrics used for clothing<br />

applications are produced each year in Europe by yarn<br />

spinning combining natural fibres (such as cotton or wool)<br />

and synthetic fibres (such as polyester). These blends of<br />

natural fibres and synthetics are generally prepared to<br />

improve comfort and durability aspects of the end products.<br />

However, these standard fabrics are complex to recycle<br />

after their use since both types of fibres are intermingled<br />

and cannot be separated again.<br />

Companies in the textile industry are challenged today<br />

to make a radical shift towards innovative and high added<br />

value products to counter the competition with low-wage<br />

countries. In this context, the FIBFAB project has been<br />

initiated to successfully launch and industrialize the<br />

production of biodegradable and sustainable polylactic<br />

acid (PLA) based fabrics (wool/PLA and cotton/PLA) for<br />

the applications in casual (menswear and womenswear),<br />

protective and workwear clothing, and to overcome the<br />

current limitations of PLA fibres as a real alternative to<br />

current fabrics (wool and cotton combined with polyester<br />

fibres). This improvement will be carried out by applying<br />

the knowhow and methodology developed in prior European<br />

projects BIOFIBROCAR and BIOAGROTEX.<br />

More breathability, lower weight, better tinting<br />

and UV rays resistance<br />

The main objectives of the FIBFAB project are: to<br />

obtain a final clothing product 100 % biobased and<br />

biodegradable that meets the mechanical and performance<br />

requirements of the textile sector in correspondence with<br />

the final applications. Besides, it is expected to improve<br />

the current poor thermal resistance of PLA fibres to meet<br />

the requirements in several clothing applications by the<br />

technology developed in previous EU projects to enhance<br />

the final PLA crystallinity.<br />

Regarding the PLA fibre manufacturing process, the<br />

processing parameters will be optimized to have thinner<br />

fibres (less than 3 dtex) and especially the mechanical<br />

spinning process (friction control in ring spinning) to be able<br />

to spin PLA blend fibres at higher speeds. This will allow<br />

the introduction to the textile market yarns and fabrics<br />

produced from PLA fibres and cotton or wool with important<br />

advantages, such as better breathability, better hydrophilic<br />

properties to make easier the tinting process, a higher<br />

resistance to degradation by UV rays, low smoke production<br />

and flammability and lower density than PES, what causes<br />

a lower fabric weight.<br />

This project has received funding from the European<br />

Union’s Horizon 2020 Fast Track Innovation Pilot programme<br />

(H2020-FTIPilot-2016-1) under grant agreement No<br />

737882. This project has a duration of 24 months and these<br />

are the participant companies: CENTEXBEL, DS Fibres<br />

(Belgium), Yünsa (Turkey) and SINTEX (Czech Republic).<br />

Together with AIMPLAS, these consortium members<br />

cover the entire textile value chain, from fibre production<br />

to clothing manufacturing, thus ensuring the industrial<br />

implementation of PLA fibres.<br />

The FIBFAB project is one of the 15 funded projects of a<br />

total of 280 projects proposals that were submitted in the<br />

fifth round of the scheme. From these 15 projects, only four<br />

include Spanish partners in their consortiums and FIBFAB<br />

is the first project in the Valencian Community to be funded<br />

in this programme. MT<br />

http://fibfab-project.eu<br />

In each season two different collections are prepared for all<br />

customers by following key fashion terms of American &<br />

European trends.<br />

Fibre spinning<br />

22 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Automotive<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 23


Production<br />

Reducing PLA production cost<br />

Earlier this year at a bioplastics conference in Bangkok,<br />

“Jem’s Law” about the growth of the PLA market was<br />

presented. Jem’s Law basically says that PLA volumes<br />

doubled every 3 to 4 years in the past and therefore will<br />

continue to do so in the future. With some knowledge of<br />

the actual production capacities one can calculate that the<br />

PLA market will be around 600,000 t/a in 2022 / 2023. All<br />

in all, this would mean that there is a need for 5 additional<br />

PLA plants with a capacity of 75,000 t/a until 2022. This is a<br />

promising perspective, not only for an engineering company<br />

like Uhde Inventa-Fischer, a subsidiary of thyssenkrupp<br />

Industrial Solutions. Even though all forecasts have to<br />

be treated with the necessary caution, Jem’s Law can be<br />

considered fairly realistic compared with earlier ones about<br />

the markets for bioplastics.<br />

PLA economics: size, price, efficiency<br />

If PLA plants are to be built in the future, economics<br />

will of course play a crucial role. Besides the well-known<br />

factors of plant size (the bigger the better) and feedstock<br />

prices (the lower the better), raw material conversion –<br />

which determines specific feedstock demand – must not be<br />

neglected.<br />

What factors influence the conversion of lactic acid to PLA?<br />

One is the formation of side-products. In the case of PLA,<br />

provided one uses the right catalyst, this is comparatively<br />

low. In practice more than 95 % of what is theoretically<br />

possible can be converted into lactide and polylactide.<br />

Unwanted meso-lactide increases production<br />

cost<br />

But lactic acid is an optical active substance with a<br />

L(+)- and a D(-)-configuration, and three different types<br />

(enantiomers) of lactides: L-lactide, D-lactide and mesolactide.<br />

Each one results in different PLAs in terms of<br />

properties and processing behavior. The repartition of the<br />

enantiomers in the lactide feedstock determines PLA<br />

properties like crystallinity/crystallization time to a major<br />

extent and consequently also heat distortion temperature<br />

and hydrolysis resistance.<br />

What’s more, the lactide composition cannot be adjusted<br />

to the desired level without separation of meso-lactide, the<br />

lactide enantiomer with a L(+)- and a D(-)-configuration.<br />

Using optically pure L(+)-lactic acid is not sufficient to<br />

obtain an optically pure lactide. Racemization of L-lactide<br />

(or D-lactide), mainly during depolymerization of lactic acid<br />

polycondensate to lactide, leads to the formation of mesolactide.<br />

In many applications a small percentage of mesolactide<br />

is advantageous. But there are also applications<br />

where meso-lactide should be as low as possible. And it<br />

appears that their share is growing, for example in durables<br />

and most fibers, or if high heat is required. In general more<br />

meso-lactide is produced than is needed.<br />

This raises the question of what to do with the surplus<br />

meso-lactide. To write it off as a loss is not an option as<br />

this would increase production cost severely. Fig. 1 shows<br />

production cost as a function of raw material conversion.<br />

A loss of 10 % due to racemization leads to a decrease<br />

in conversion from 96 % to 83 % which in turn increases<br />

production cost by more than 12 % (all calculations based<br />

on Uhde Inventa-Fischer’s PLAneo ® technology for an<br />

industrial scale plant on a European price basis).<br />

Selling or downgrading back to lactic acid have<br />

drawbacks.<br />

A better option is to hydrolyze meso-lactide back to<br />

lactic acid. Technically this is not a challenge. But due to<br />

its racemic nature the quality of the lactic acid is lower<br />

than the feedstock lactic acid. It goes without saying that<br />

the conversion of a high grade lactic acid into a low grade<br />

one is economically unfavorable. Besides bad economics a<br />

producer of PLA has the drawback of having to deal with two<br />

completely different markets – selling PLA on the one hand<br />

120%<br />

Fig 1: Production cost as a function of raw material conversion<br />

VAC<br />

Fig 2: Process flow diagram of<br />

thyssenkrupp’s PLAneo process<br />

Increase in Production Cost<br />

115%<br />

110%<br />

1<strong>05</strong>%<br />

100%<br />

Crude<br />

Lactide<br />

Meso-Lactide<br />

Purrification<br />

PLAneo ®<br />

95%<br />

75%<br />

80% 85% 90% 95% 100%<br />

Lactic Acid Conversion: Percentage of theoretical maximum<br />

L-Lactide<br />

Purrification<br />

Ring Opening<br />

Polymerisation<br />

Demonomerisation<br />

24 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Production<br />

By:<br />

Udo Mühlbauer<br />

thyssenkrupp Industrial Solutions<br />

Uhde Inventa-Fischer GmbH<br />

Berlin, Germany<br />

and lactic acid for example to the cosmetics industry on the<br />

other (unless he is already a lactic acid producer).<br />

An even better option would be to sell meso-lactide as a<br />

chemical intermediate or monomer for different applications<br />

and to different markets – with the aim of achieving higher<br />

prices. As meso-lactide has not existed as a commercial<br />

product before, there is no established market. New<br />

applications have to be developed and markets have to be<br />

found. Whether these markets will develop and to what size<br />

remains to be seen.<br />

Using polymerized meso-lactide to form a single<br />

product: PLAneo<br />

The solution that Uhde Inventa-Fischer has developed<br />

initially appears obvious: like L-lactide, meso-lactide is<br />

purified and polymerized. This is easier said than done. Beside<br />

the fact that meso-lactide is much more sensitive to sidereactions<br />

than usual polymer-grade lactide, the molecular<br />

weight of poly-meso-lactide has to be comparatively high in<br />

order to obtain good mechanical properties. Both facts add<br />

up to stringent requirements for the purity of polymer-grade<br />

meso-lactide.<br />

The second step of the PLAneo technology is not as obvious.<br />

Instead of producing a second polymer, which would have<br />

limited possible application due to its amorphous nature,<br />

polymeso-lactide is blended with the main crystallizable<br />

PLA-melt, both polymerized continuously in parallel lines,<br />

to give one product.<br />

Optimized yield, same product properties<br />

The resulting polymer maintains all relevant mechanical,<br />

optical and physical properties: tensile strength, E-modulus,<br />

crystallization behavior and melting point do not change.<br />

Only the b*-value of the PLA pellets is slightly increased.<br />

This holds true irrespective of whether distillation or<br />

crystallization is used to purify the main lactide stream.<br />

Processing of PLAneo PLA is just as straightforward as<br />

standard PLA.<br />

Applying separate polymerization of meso-lactide and<br />

L-Lactide and blending it afterwards means no meso-lactide<br />

has to be discarded or used in a less economical way. The<br />

specific demand of lactic acid converges to its theoretical<br />

minimum of 1.25 kg per kg of PLA.<br />

Nobody knows exactly how the PLA market will develop.<br />

We will see whether Jem’s law will continue to prove<br />

true in the future and how many new plants will come on<br />

stream. But the ones using technology that maximizes<br />

raw material yield will definitely have an advantage.<br />

www.uhde-inventa-fischer.com<br />

201 200<br />

Fig 3: Comparison of PLA properties with and without<br />

amorphous PLA contingent<br />

D-<br />

Content<br />

[%]<br />

Intrinsic<br />

Viscosity<br />

[dl/g]<br />

Residual<br />

Monomer<br />

[%]<br />

Tm<br />

[°C]<br />

b*-<br />

Value<br />

[-]<br />

Haze<br />

[%]<br />

159 160<br />

4069<br />

3881<br />

cPLA PLAneo ® bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 25<br />

Fig 4: Comparison of BOPLA film<br />

properties with and without<br />

amorphous PLA contingent<br />

4201 4265 96<br />

113<br />

85<br />

100<br />

PLA 2 1.87 < 0.02 162 4 0.38<br />

PLAneo 5 1.87 < 0.02 162 6 0.35<br />

MD TD MD TD<br />

MD TD<br />

Tensile Strength<br />

[N/mm²]<br />

E-Modulus [N/mm²]<br />

Elongation at<br />

Break[%]


Application AutomotiveNews<br />

Grasping at bioplastic straw<br />

Switzerland’s Sukano, a leading producer of additive and<br />

colour masterbatches and compounds for polyester and<br />

specialty resins, and NatureWorks have collaborated on the<br />

development of an eco-friendly material suitable for making<br />

drinking straws from.<br />

Formerly made of paper, modern day straws, are mainly<br />

made from polypropylene and present a variety of technical<br />

challenges for alternative new materials seeking to bring<br />

new functionality.<br />

For example, the narrow, U-shaped straws for juice boxes<br />

must be articulated and have a high flexibility modulus. During<br />

manufacturing, edges must be cut smoothly to prevent<br />

unsafe sharp or rough rims, while visual aesthetics, such as<br />

transparency, are also critical. These are just a few of the<br />

many specifications new materials must meet for adoption<br />

into this market application.<br />

The demand for disposable straws is expected to grow,<br />

driven in part by consumer demand for convenience, meals<br />

on the go, and the consumption of specialty drinks – hence<br />

the potential for materials that provide complete, responsible<br />

lifecycle solutions while providing the desired functionality<br />

is huge.<br />

So, when Sukano and PLA manufacturer NatureWorks,<br />

got together, a new, broad market opportunity was born.<br />

Bioplastics like polylactic acid (PLA) have long been<br />

viewed as sustainable in sourcing, manufacture and afteruse<br />

– but, until today, they were unable to meet the market’s<br />

performance requirements to replace the use of polypropylene<br />

in this application. Sukano masterbatches reduce<br />

the brittleness of PLA, which allows precise cutting during<br />

production and avoids splintering and rough edges. Combining<br />

melt enhancer additives in Ingeo-based PLA masterbatches,<br />

Sukano’s concentrates promote dimensional<br />

stability and greater flexibility without cracking at temperatures<br />

of 110° to 120°C. The additive masterbatches formulations<br />

are also designed to maintain the high transparency<br />

required in straws.<br />

“We are thrilled that this collaboration between key players<br />

in the value chain allows us to bring an innovative alternative<br />

to the market. Using our combined experience, we<br />

are able to modify Ingeo PLA to customize its performance<br />

for a new end market – providing benefits to consumers and<br />

companies,” said Alessandra Funcia, Head of Marketing at<br />

Sukano.<br />

“At NatureWorks, we are helping to rethink plastics. The<br />

replacement of conventional oil-based polypropylene by Ingeo<br />

in drinking straws is just one example of how bioplastics<br />

can help address sustainability, while still providing the<br />

high-performance material required for this application,”<br />

concluded Steve Davies, Commercial Director – Nature-<br />

Works Performance Packaging. MT<br />

www.natureworksllc.com | www.sukano.com<br />

First meal set<br />

Beatrice and Daniele Radaelli, founders of eKoala (Cavenago di Brianza, Italy), have decided to look at the world of plastic<br />

materials from a different point of view, driven by liability and environmental sustainability. “When both my brother and I became<br />

parents we soon understood the limits and the dark sides of traditional plastic and we started looking for new materials that<br />

could have the same glamour of those colourful plastic granules which stimulated our fantasy as kids, but at the same time,<br />

could be safe for our children and for the environment they would live in. After months of research we finally found what we<br />

were looking for…”<br />

The bioplastics of eKoala are based on Novamont’s Materbi and do not<br />

contain any toxic substances and are biodegradable. They are the ideal<br />

products for those who consider responsibility as a key factor for their buying<br />

behaviour and choose to leave a better world to future generations. “We put<br />

our childrenshealth first”, as Beatrice put it. Babies and kids are the weakest<br />

link but also the future of our planet. For this reason, eKoala uses only natural<br />

raw materials free from any toxic substance.<br />

One of the products recently added to their range of bioplastics products is<br />

the eKeat – First Meal Set. Other products include drinking cups, teethers and<br />

more. MT<br />

www.ekoala.eu<br />

26 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Application Automotive News<br />

Organic chair<br />

The new Kartell Organic Chair uses a revolutionary new<br />

organic plastic material to create a sustainable item of<br />

furniture that is high quality and highly creative.<br />

Designed by Antonio Citterio (Italian architect, furniture<br />

designer and industrial designer who lives and works in<br />

Milan), Kartell’s Organic Chair is made from BIODURA, a<br />

PHA-based material from Sabio Materials (Italy) obtained<br />

from renewable raw materials. The raw material is organic in<br />

nature and comes from renewable plant-based sources that<br />

will not disrupt food production.<br />

The material is a result of different processes that make it a<br />

very high-quality compound that Kartell has injection moulded<br />

just like other plastics: a first in the world of furniture.<br />

Kartell has therefore come up with a sustainable design<br />

in line with its industrial philosophy based on the concept of<br />

quality and durability. Ideally, at the end of its working life,<br />

in the right conditions, the Organic Chair can re-enter the<br />

biological cycle or biodegrade.<br />

Organic Chair is perfect for both indoor and outdoor use<br />

as it is extremely durable, which also makes it perfect for the<br />

contract market. MT<br />

www.spacefurniture.com.au/kartell.html<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 27


Application News<br />

Pet food bags<br />

Midwestern Pet Foods is<br />

packaging its newly launched<br />

Earthborn Holistic Venture line in<br />

sustainable packaging produced<br />

by Peel Plastics Products Ltd.,<br />

utilizing Braskem’s I’m Green TM<br />

biobased polyethylene (PE).<br />

In an effort to mitigate the carbon footprint associated with<br />

its product, Peel Plastics has chosen to use biobased PE to<br />

manufactures the new Earthborn Holistic Venture pet food<br />

bags.<br />

The company said it was “very happy” to partner with<br />

Midwestern Pet Foods, a long-standing customer, and with<br />

Braskem, in its striving to as focus on “advanced solutions for<br />

sourcing renewable packaging materials”.<br />

Consumer response to the new PlantBag, said Jeff Nunn,<br />

Midwestern Pet Foods President, has been overwhelmingly<br />

enthusiastic.”<br />

According to Gustavo Sergi, Renewables Director at<br />

Braskem, North America is gaining momentum in terms<br />

of its use of sustainable green PE. “It is encouraging that<br />

North America is catching up to other regions of the world<br />

with visionary companies such as Midwestern Pet Foods and<br />

Peel Plastics taking the lead to a more sustainable consumer<br />

lifestyle,” he said.<br />

“Stay tuned, you will only see more of these launches in the<br />

coming months and years.”<br />

www.braskem.com<br />

Bioplastic toys<br />

Plasto, a toy company<br />

in Finland has over 60<br />

years of experience in<br />

manufacturing high quality<br />

plastic toys. Their focus is<br />

very strong on safety and<br />

durability. Furthermore,<br />

they are extremely focused<br />

on environmental values. For several decades they have<br />

been using recycled plastic from their own production in<br />

order not to waste any material and they keep on investing<br />

more to save the environment and be good to nature. In<br />

spring <strong>2017</strong>, Plasto launched their own I’m Green toy<br />

range. All the toys in this range are over 90 % biobased.<br />

The raw material which is used derives from sugar cane.<br />

By doing this, Plasto will significantly reduce the carbon<br />

footprint of its toys as well as the use of fossil resources.<br />

For every kg of I’m Green Polyethylene used in Plastos’<br />

toys more than 5 kg of CO 2<br />

is saved. The toys are food<br />

contact safe and dishwasher safe. At the end of their life<br />

cycle they can be recycled and the raw material can be<br />

reused which is in accordance with Plasto’s philosophy.<br />

The I’m Green toys have been extremely well received.<br />

For Christmas Plasto will be expanding it’s range with<br />

new items.<br />

”Our I’m Green toy range has been extremely well<br />

received by our customers. We have expanded our I’m<br />

Green range with crane and fire truck already for this<br />

Christmas. We are proud to offer a sustainable choice,”<br />

says Kennet Berndtsson, Managing Director at Plasto.<br />

MT<br />

www.braskem.com | www.fkur.com | www.plasto.fi<br />

PHA for eyeglass frames<br />

Bio-on, (Bologny, Italy) recently announced a partnership<br />

with Kering Eyewear to develop new materials based on<br />

Minerv PHAs. “This is the first time in the world that a<br />

company in the eyewear industry has decided to carry out<br />

research with our biopolymers,” explains Marco Astorri,<br />

Chairman and CEO of Bio-on.<br />

Kering Eyewear’s aim is to make an active contribution<br />

to the development of an innovative and sustainable<br />

business model, providing its team of designers with a<br />

series of cutting-edge materials to broaden their creative<br />

possibilities, setting new trends in the luxury and sport &<br />

lifestyle segments. Researchers from the two companies<br />

will collaborate to design, certify and put on the market new<br />

eco-sustainable materials to be integrated with the use of<br />

cellulose acetate, one of the most common materials used<br />

in the majority of the eyewear products on the market to<br />

date.<br />

“We are proud to be the first in the world to use our<br />

PHAs biopolymer together with such a prestigious and<br />

internationally renowned company as Kering Eyewear.<br />

Thanks to this collaboration, we are launching a new era<br />

in the eyewear world,” says Marco Astorri. “The union<br />

of creativity and technology will give rise to items with<br />

absolutely innovative characteristics. Our laboratories and<br />

scientists will develop a vast range of new formulations,<br />

giving free rein to the creativity of the most discerning<br />

designers.”<br />

“The partnership with Bio-on represents a tangible<br />

sign of Kering Eyewear’s attention to sustainability and its<br />

desire to bring innovation to a consolidated industry. In our<br />

Group,” explains Roberto Vedovotto, Chairman and CEO<br />

of Kering Eyewear, “we strongly<br />

believe that ‘sustainable business<br />

is smart business’. The materials<br />

developed by Bio-on, 100% natural<br />

and biodegradable, will be a<br />

revolution in the eyewear industry<br />

and completely dovetail our unique<br />

approach to the market, as well as<br />

our desire to offer increasingly high<br />

quality and innovative products. In<br />

the luxury sector, sustainability and<br />

environmental awareness are no<br />

longer an option, they are a must.”<br />

MT<br />

www.bio-on.it | www.kering.com<br />

Roberto Vedovotto<br />

(Photo: Albrecht Fuchs)<br />

28 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Application News<br />

Your city - your cup<br />

Coffee to take away<br />

or beer in the stadium<br />

- we like to drink on the<br />

go. Usually such a drink<br />

comes in plastic or paper<br />

cups. Reusable cups can<br />

be reused very often (up<br />

to 500 times - or more)<br />

and are therefore more<br />

environmentally friendly<br />

(says DUH, Deutsche<br />

Umwelthilfe). Even the<br />

environmental impact of its production is comparatively<br />

low over the entire product life cycle.<br />

That is why the German company Bunzl from Marl<br />

initiated the Düsseldorf Becher (Düsseldorf Cup), a system<br />

of reusable cups that can be purchased in one store and<br />

returned in another. A total of 80 stores already participate<br />

in the system, including bakeries, cafés and restaurants.<br />

And what makes the Düsseldorf Cup special is the<br />

material. The 350ml cup is made of CPLA. Since PLA is not<br />

a heat-resistant product, for CPLA talc powder is added<br />

and helps the PLA to crystallize. This the C stands for<br />

crystallized PLA. CPLA consists of 70-80 % of PLA and 20-<br />

30 % of talc powder. The cups are biodegradable according<br />

to EN13432 without the release of pollutants, however,<br />

not home compostable. It is BPA-free. The cup shows a<br />

high temperature resistance range: -20 °C - 100 °C. It is<br />

microwaveable and dishwasher safe. MT<br />

www.bunzl.de<br />

The partners are spread all over Düsseldorf , Germany<br />

(Source: Google MyMaps)<br />

How about going bio?<br />

For almost every conventional plastic, there is a bioplastic alternative.<br />

Our PLA masterbatches can help introduce PLA into your portfolio.<br />

Make the switch today.<br />

www.sukano.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 29


Materials<br />

New compostable PHA<br />

based compound from Canada<br />

Bosk Bioproducts offers a new generation of<br />

“Clean Plastic”<br />

For more than 10 years, researchers at the INRS in Quebec<br />

(Canada) have been developing a biotechnology to<br />

produce PHA (polyhydroxy alkanoate), a biopolymer that<br />

can replace conventional plastic. What makes Bosk’s Clean<br />

plastic so different? The PHA is produced from by-products<br />

from the Pulp and paper industry. Bosk’s objective is to ensure<br />

accessibility to the objects of everyday life without jeopardizing<br />

the sustainability of the planet. Recently at BIO <strong>2017</strong>, Bosk<br />

presented its clean plastic business model regrouping different<br />

lines of compounds dedicated to the plastic industry and<br />

consumers wanting sustainable products.<br />

Regen, compounds for plastic truly compostable<br />

As we speak, the only solution that avoids the accumulation<br />

of plastics is composting. The Regen compounds series<br />

of Bosk’s bioplastic is fully compostable. Based on Bosk’s<br />

proprietary PHA, and a choice of eco-friendly ingredients, the<br />

Regen compounds can be used for finished products from<br />

standard processes like injection, extrusion or thermoforming.<br />

These Regen compounds can finally meet the most stringent<br />

requirements in terms of standards for composting. At the<br />

end of their useful life, objects made with Bosk’s Regen<br />

compounds can be designed to be thrown into industrial or<br />

home composting facilities. This sustainable method of plastic<br />

disposal promotes by natural processes the regeneration of<br />

plastic components in nutrients and other constituents into<br />

our environment without toxic impact.<br />

Compostable, but also durable<br />

No need to worry about product durability. PHA adds a<br />

clever blend of ingredients to meet consumer demands<br />

while ensuring compostability at home or at industrial sites.<br />

Degradation begins only when the object is in contact with<br />

the natural bacteria living in the soil and the time required<br />

for degradation can be as short as a few weeks up to a few<br />

months.<br />

Plastic designed to reduce our impact on the<br />

environment<br />

Moreover, in order to obtain the most natural product and<br />

reduce its impact on the environment, this new generation<br />

of plastic does not originate from GMOs nor does it contains<br />

toxic additives such as BPA and phtalates. When compared to<br />

the production of conventional plastic, this bioplastic makes it<br />

possible to reduce the carbon footprint. And here’s the icing<br />

on the cake: the raw material of this plastic is an untapped<br />

by-product of the pulp and paper industry. Bosk makes no<br />

Life cycle of Bosk’s compostable<br />

plastic finished products<br />

pulp and<br />

paper mill<br />

(partner)<br />

PHA<br />

compostable<br />

plastic<br />

compound<br />

(BOSK)<br />

compostable<br />

plastic<br />

manufacturer<br />

(partner)<br />

compostable<br />

plastic<br />

finished<br />

product<br />

PHA plant<br />

(BOSK)<br />

composting at the<br />

end of the life<br />

of the product<br />

retailer /<br />

consumer<br />

30 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Materials<br />

By:<br />

Paul Boudreault<br />

CEO<br />

Bosk Bioproducts<br />

Quebéc, Canada<br />

compromises. Both the product and the production process<br />

are developed to reduce their impact on the environment.<br />

The goal is to create plastic products that meet the growing<br />

demand from new eco-conscious consumers.<br />

Bosk’s PHA production capacity based on the pulp<br />

and paper industry<br />

Production capacity of Bosk’s PHA is based on the pulp and<br />

paper industry’s investments in product diversification. Bosk<br />

is in discussions with a major P&P company in Canada to<br />

sub-licence the technology and start PHA production. It will be<br />

possible to have a PHA production facility at any P&P mill. “We<br />

are evaluating PHA production facilities to implement in the<br />

next two years from 3,000 and up to 25,000 tonnes/years with<br />

our first P&P partner” said Paul Boudreault, CEO of Bosk at<br />

BIO-<strong>2017</strong> in Montreal. By integrating the technology in existing<br />

P&P mills, it reduces by far capital investment needs and<br />

production costs required for conventional PHA production.<br />

Having developed expertise in compounding this new PHA,<br />

Bosk is now developing customer interest to ensure a market<br />

destination for finished compounds and plastic products. This<br />

new Value-chain model allows Bosk to reduce the distance<br />

between the PHA producer and the eco-conscious consumer.<br />

www.bosk-bioproducts.com/<br />

European Bioplastics<br />

12 TH CONFERENCE<br />

Making the difference<br />

28/29 November <strong>2017</strong><br />

maritim proArte Hotel<br />

Berlin<br />

@EUBioplastics #eubpconf<strong>2017</strong><br />

www.european-bioplastics.org/conference bioplastics MAGAZINE [04/17] Vol. 12 31


Beauty & Healthcare<br />

The power of packaging –<br />

sharpen your USP<br />

In comparison to previous years, the ecological and environmental<br />

awareness of consumers has increased which<br />

makes them think even more carefully before they decide<br />

to buy a product. Ingredients, sustainability, waste reduction<br />

and separation are considered more often. Consumers are<br />

looking at the composition and prefer e.g. shampoos without<br />

silicone or skin care products without mineral oils or<br />

micro plastics. Natural cosmetics are a life style statement<br />

and express the customer´s personality and individuality.<br />

Packaging made from renewable resources not only help<br />

to implement a holistic sustainable approach, which distinguishes<br />

respective brands from cosmetics wrapped in traditional<br />

plastics, but also increase the perception of value.<br />

Traditionally, a huge range of polymers are used for<br />

cosmetic packaging. Bottles are mainly made from HDPE,<br />

sometimes from PP while high transparent materials such<br />

as Polyesters or Polyamides are suitable for jars. As the<br />

packaging is the figurehead of each brand and product,<br />

surface finishing, haptics and visual appearance are key<br />

factors aside from mechanical or barrier properties.<br />

In some cosmetic packaging, several different plastics<br />

are combined in order to meet respective requirements. In<br />

terms of cosmetic bottles for instance, PE is used for the<br />

hollow part, PP for the cap and even the label is made from<br />

a different material or material combination. In order to<br />

increase the recyclability of such a product while being in<br />

accordance with a circular economy, more mono materials<br />

should be used. The product solution of Speick´s Natural<br />

Cosmetics (Leinfelden-Echterdingen, Germany) follows<br />

this logic trend in a smart way by using Green PE for all<br />

three parts of the packaging and therefore enables ease of<br />

recycling.<br />

Of course, raw material costs can be higher compared to<br />

existing fossil based polymers being used. But, is a cheap<br />

price really a unique selling proposition (USP)? Usually<br />

such products are easily replaced by a competitor who<br />

is able to produce at an even lower cost. To stay ahead of<br />

competition respective marketing and sales strategies are<br />

needed which are increasingly more independent from the<br />

price driven argumentations. A USP needs to be evaluated<br />

and communicated clearly to end consumers. In order to<br />

help consumers identify truly sustainable products and<br />

avoid greenwashing it is possible to verify and confirm the<br />

bio-based content of packaging by external institutions.<br />

The packaging is then clearly labelled with appropriate<br />

certificates or seals. A clear and logical message with high<br />

transparency for the end user is the key for success. This<br />

message can be clearly communicated with biopolymers.<br />

Speick Natural Cosmetics recently chose Braskem´s<br />

I´m green PE for their packaging: “Environmental and<br />

social criteria play a key role in the selection of our raw<br />

materials and packaging. Our products shall be thoroughly<br />

sustainable. It is not easy to substitute plastic wrapping but<br />

we were consequently looking for a possibility to act more<br />

environmental friendly in this case. This is why we are using<br />

bottles made of sugar cane based bioplastics for our Speick<br />

Organic 3.0 product range and we are very pleased with it.<br />

The numerous awards for our product confirm that we are<br />

on the right track.” says Anke Boy, responsible for Marketing<br />

and Product Management of Speick Natural Cosmetics.<br />

As a distribution partner for Braskem S.A. FKuR (Willich,<br />

Germany) is able to offer their „I´m green“polyethylene. Its<br />

properties are identical to conventional PE which makes<br />

The packaging<br />

delivers what<br />

your products<br />

promise:<br />

Cosmetic jars<br />

made from<br />

Biograde offer<br />

a high quality,<br />

pleasant feel<br />

and complement<br />

the message of<br />

a sustainable<br />

cosmetic brand<br />

in a natural way.<br />

32 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Beauty & Healthcare<br />

By:<br />

Patrick Zimmermann,<br />

Director Marketing & Sales<br />

Annette Schuster,<br />

Marketing & Communications Manager<br />

FKuR Kunststoff<br />

Willich, Germany<br />

it very easy for packaging manufacturers to shift from<br />

conventional to bio-based PE because it is not necessary to<br />

change any tool or machine settings. The same also applies<br />

for recycling. Green PE can be recycled with regular PE<br />

without affecting the recycling chain.<br />

The broad portfolio of FKuR offers solutions for bottles,<br />

tubes, films and jars that can be produced using either<br />

renewable or biodegradable plastics. Biobased and<br />

biodegradable materials such as Bio-Flex ® and Biograde ®<br />

are very versatile in their technical performance and<br />

processing methods. Such materials are suitable for cast<br />

film extrusion with subsequent thermoforming and injection<br />

moulding applications. Because of their different haptics,<br />

end consumers will immediately notice the difference<br />

compared to existing oil based materials. Additionally<br />

Green PE, Terralene PP (a partly bio-based PP blend) or<br />

Terraprene (a bio-based TPE) can replace their existing oil<br />

based counterparts easily.<br />

Speick Natural Cosmetics won several international awards<br />

for their integrally sustainable concept including products and<br />

packaging, amongst others, Vivaness Best New Product <strong>2017</strong>,<br />

Green Product Award <strong>2017</strong> and Sustainable Beauty Award 2016<br />

(Foto: SPEICK Naturkosmetik)<br />

www.speick.de | www.fkur.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 33


Beauty & Healthcare<br />

PolyBioSkin The future of biopolymers for<br />

skin-contact healthcare, sanitary, and personal care products<br />

Biopolymers not only reduce our dependency on finite<br />

fossil resources but can also offer higher versatility<br />

in comparison to conventional polymers when<br />

it comes to the possible end-of-life options for products.<br />

Especially for short-term single use products, this endof-life<br />

versatility can be a key sustainability factor. A lot of<br />

large-volume single-use disposable products such as diapers<br />

are currently treated in energy recovery or end up in<br />

landfills. Their reliance on the combination of a number of<br />

different materials as well as their after-use contamination<br />

prevents them from being fully or partially recycled. Most<br />

commercial diapers, for example, use polyolefin topsheets,<br />

and many cosmetic and biomedical skin-contact applications<br />

also still rely on conventional plastic films, which is<br />

one reason for their poor position in the waste management<br />

hierarchy (fig. 1).<br />

Another drawback of the conventional plastic materials<br />

currently used in these types of skin-contact applications<br />

is their tendency to cause skin irritations, inflammations,<br />

and even intolerances. Biopolymers and other bio-based<br />

substances on the other hand offer a high degree of<br />

biocompatibility and other unique features but are still<br />

hugely under-exploited in this field.<br />

PolyBioSkin, a Horizon2020 project coordinated by Spainbased<br />

advanced engineering SME IRIS, aims to develop<br />

both optimal biopolymers and processes for the sanitary,<br />

biomedical, and cosmetic sectors. PolyBioSkin is funded by<br />

the Bio-based Industries Joint Undertaking, a public-private<br />

partnership between the EU and the Bio-based Industries<br />

Consortium with the goal of realising the full potential of the<br />

bioeconomy in Europe to reduce its dependency on fossilbased<br />

products, tackle climate change challenges, and lead<br />

to greener and more environmentally friendly growth.<br />

PolyBioSkin will deliver: (i) A biodegradable diaper<br />

consisting of an antimicrobial bio-based topsheet beneficial<br />

for the skin and a bio-based superabsorbent layer; (ii) novel<br />

facial beauty masks based on textiles or films made from<br />

bio-based and biodegradable polymers and impregnated<br />

with molecules beneficial for the skin; (iii) nano-structured<br />

highly skin-compatible non-woven textiles for wound<br />

dressings. To achieve the ambitious goal of greatly advancing<br />

the use of biopolymers in selected skin-contact applications<br />

and improving both their performance and sustainability, 12<br />

partners from 7 countries are collaborating in this 3-year<br />

project.<br />

The selection of bio-based materials for the project<br />

combines formulations based on engineered biopolymers<br />

like polylactic acid (PLA) with naturally available ones like<br />

polyhydroxyalkanoates (PHAs) or chitin, with a significant<br />

bio-based carbon content above 90 % according to<br />

ASTM D6866, all of which are biodegradable in industrial<br />

composting.<br />

There are already some efforts to introduce PLA, the<br />

biodegradable polymer with the largest market share,<br />

which is also biocompatible and therefore, used in several<br />

biomedical applications but also in diapers as an alternative<br />

to polyethylene top-sheets. In fact, PLA being an aliphatic<br />

polyester offers the same functionality as diaper topsheets<br />

made from PE, i.e. keeping the skin dry, while at the same<br />

time featuring an improved biocompatibility. PolyBioSkin<br />

will drive this development also by additivating PLA<br />

with chitin nanofibrils in order to provide PLA films with<br />

excellent antimicrobial properties and avoid skin irritations.<br />

Furthermore, natural absorbent cores based on modified<br />

cellulose and starch will substitute the generally used<br />

acrylic petrochemical absorbents.<br />

Chitin is a polysaccharide present in the skeletons of<br />

insects and the shells of crustaceans and readily available<br />

from food industry processing waste (for instance sea<br />

food waste). Chitin and its derived biopolymer chitosan<br />

have shown excellent techno-functional properties in<br />

different fields, for example for edible coatings with good<br />

gas barrier properties, antimicrobial properties for wound<br />

care, skin hydration and repairing in cosmetic application<br />

or biostimulants for plants. Besides, in its nanofibril form,<br />

chitin has been reported to be a potent skin inflammation<br />

suppressant to be applied, for example, against atopic<br />

dermatitis. This feature is of huge relevance for all skincontact<br />

applications pursued in the project.<br />

Another very versatile group of emerging biopolyesters<br />

are polyhydroxyalkanoates (PHAs). They can be synthesised<br />

directly in the cells of a number of microorganisms and<br />

the exacted polymer structure and molecular weight can<br />

vary greatly depending on the microorganism nature and<br />

culture conditions. As such, PHAs structure can be different<br />

in terms of content of comonomers (3-hydroxybutyric<br />

acid, 4-hydroxybutyric acid, 3-hydroxyvaleric acid, etc.)<br />

or molecular weight, which in turn can lead to flexible or<br />

rigid plastics and to different possibilities of processing in<br />

conventional industrial machines. Among the commercially<br />

available PHAs, most are from Gram negative bacteria.<br />

Despite their unique biocompatibility and even, in some<br />

cases, inherent antibacterial properties, PHAs from<br />

Gram positive bacteria are still not commercially utilized.<br />

Especially in the case of wound dressings, such new<br />

materials could help to avoid immune reactivity and<br />

maximise skin regeneration potential.<br />

In PolyBioSkin, not only the materials themselves will<br />

be optimised, but also process-driven structuring will be<br />

given special attention to obtain films, fibres, and nonwoven<br />

textiles with properties tailored to each of the<br />

PolyBioSkin target applications. Indeed, a nanofibrous<br />

morphology is known to result in a much faster liquidity<br />

absorption than the regular bulk properties of the same<br />

polymer, leading to optimal resource efficiency. As such,<br />

PolyBioSkin aims at developing high quality products<br />

by utilising the most advanced polymer conversion<br />

techniques, such as electrohydrodynamic processing,<br />

tailored surface modification, and the latest developments<br />

in nanotechnology.<br />

34 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Beauty & Healthcare<br />

By:<br />

Elodie Bugnicourt and Rosa Arias<br />

Innovació i Recerca Industrial i Sostenible (IRIS)<br />

Castelldefels, Spain<br />

Maria-Beatrice Coltelli and Serena Danti<br />

Consorzio Interuniversitario Nazionale per la<br />

Scienza e Tecnologia dei Materiali (INSTM)<br />

University of Pisa, Pisa, Italy<br />

Götz Ahrens,<br />

Project Manager<br />

European Bioplastics<br />

Berlin, Germany<br />

Thanks to the use of electrical forces, based on liquid<br />

atomisation, electrospinning enables the production of<br />

short to continuous fibres or particles. It is an extremely<br />

versatile and promising technology as it can lead to<br />

structures with variable density based on suspensions of<br />

different materials and even to core shells. The controlled<br />

release of active ingredients can be achieved through a<br />

porous structure of the matrix at the nano to micro scale<br />

produced through electrospinning. In PolyBioSkin, the<br />

biopolymer non-wovens embedding antimicrobial and antiinflammatory<br />

substances such as chitin will be based on<br />

electrospun nanofibre meshes.<br />

PolyBioSkin will boost the use of biopolymers that offer<br />

unique antimicrobial, antioxidant, absorbence, and skin<br />

biocompatibility properties for high performance skincontact<br />

applications. This will be demonstrated in diaper,<br />

facial beauty mask, and wound dressing applications. The<br />

use of PolyBioSkin’s innovative materials in these widely<br />

used products will result in enhanced quality of life and<br />

wellbeing of EU citizens, reduced environmental impact,<br />

and more environmentally friendly end-of-life options for<br />

skin-contact products.<br />

Fig. 1: Diapers, facial beauty masks, and wound dressings in the<br />

European Waste Hierarchy<br />

Current Scenario<br />

WASTE MANAGEMENT<br />

Waste Reduction<br />

Reuse<br />

Recycling/Composting<br />

Energy Recovery<br />

Landfill<br />

POLYBIOSKIN innovation<br />

The PolyBioSkin consortium combines the expertise of<br />

twelve partners from seven European countries, including<br />

five partners from academia and technology institutes:<br />

Consorzio Interuniversitario Nazionale per la Scienza e<br />

Tecnologia dei Materiali (INSTM, Italy), the University of<br />

Westminster (UK), Association pour la recherche et le<br />

developpement des methodes et processus industriels<br />

(ARMINES, France), Tehnoloski Fakultet Novi Sad (Serbia)<br />

and University of Gent (Belgium); six industry participants<br />

(SMEs): Innovació i Recerca Sostenible (IRIS, Spain, project<br />

coordinator), Bioinicia (Spain), Fibroline (France), Texol<br />

(Italy), Mavi Sud (Italy) and Exergy (UK), as well as the<br />

European Bioplastics association (Germany).<br />

PolyBioSkin has received funding from the Bio-based<br />

Industries Joint Undertaking under the European Union’s<br />

Horizon 2020 research and innovation programme under<br />

grant agreement No. 745839.<br />

www.polybioskin.eu<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 35


Beauty & Healthcare<br />

Stronger superabsorbent<br />

biopolymers for baby care<br />

Ecovia Renewables, Inc. and their research and development<br />

team in Ann Arbor, Michigan are working to<br />

develop a suite of polyglutamic acid (PGA) biopolymers<br />

from their patented EcoSynth fermentation process. Their<br />

objective: to produce biodegradable, non-toxic, and highperforming<br />

superabsorbent polymers (SAPs) at competitive<br />

costs. Ecovia’s PGA SAPs can be used as thickeners for<br />

cosmetics, soil amendments for agriculture, and absorbent<br />

cores for hygiene products, to name a few applications.<br />

“It was a tough realization,” Drew Hertig, Chief Business<br />

Officer of Ecovia recalls. “We interviewed parent after<br />

parent. Nobody wanted to pay more than a dime extra to<br />

switch to a biobased diaper that couldn’t live up to the<br />

performance of traditional diapers.”<br />

The solution? Develop a scalable process that, at<br />

large volumes, reduces the manufacturing cost of high<br />

performing materials previously too expensive to use in<br />

hygienic products. This concept allows for cost savings<br />

without sacrificing performance.<br />

Dr. Nina Lin and Dr. Jeremy Minty of the University of<br />

Michigan Dept. of Chemical Engineering capitalized on<br />

their research in constructing microbial ecosystems to<br />

form the basis of the EcoSynth platform. Demonstrating<br />

success at small scales, Minty and his team work around<br />

the clock applying their platform to produce low-cost PGA, a<br />

naturally occurring (and edible) biopolymer, from renewable<br />

sources like waste glycerol.<br />

“We are looking at application areas that can benefit both<br />

the end-user and the environment, all while maintaining<br />

profitability and economics of scale,” said Jeremy Minty,<br />

Co-Founder and President. “Our long term vision is to<br />

replace hundreds of synthetic polymer products with costcompetitive<br />

PGA.”<br />

One such area is baby care, where thousands of tonnes<br />

of synthetic polymers are used and thrown away every day.<br />

As the diapers pile up so do the expenses. As a result,<br />

parents often have to choose between cost and performance<br />

for diapers that are biobased and non-toxic for their baby<br />

and the environment. Finding the right diaper at the right<br />

price has led to an influx of experts catering to the demand<br />

of concerned parents.<br />

The result? A plethora of information and opportunities<br />

for consumer research. Thought leaders and rating sites<br />

like Rodale’s Organic Life and Baby Gear Lab have made<br />

it easy for parents and parents-to-be to consider all their<br />

options for adoption.<br />

Most parents agree that for the superabsorbent material<br />

that makes up the core of diapers—averaging 10g per<br />

diaper—performance is key. Rigorous tests are performed<br />

including absorbency under load, free swell, and centrifuge<br />

retention capacity. Many more tests are kept confidential<br />

by the market leaders for benchmarking internal products.<br />

The winners are usually traditional diapers.<br />

Traditional diapers incorporate synthetic polymers like<br />

polyacrylic acid and its derivatives. These SAPs continue<br />

to outperform most biobased polymer substitutes like<br />

polysaccharides (i.e. starches and celluloses). As a result,<br />

the material in the diaper core often limits sustainability<br />

certifications.<br />

However, the bar is rising. Biodegradability tests,<br />

including ISO, ASTM, and OECD testing methods are no<br />

longer enough for eco-brands to differentiate themselves.<br />

Leading brands are looking to improve their sustainability<br />

certifications, striving to reach the highest level possible,<br />

such as Cradle-to-Cradle Gold status, and Nordic Swan,<br />

which examines CO 2<br />

emissions throughout the product<br />

lifecycle.<br />

“At the end of the day we hope to look back and think we<br />

made it one step closer to fulfilling our mission,” Mr. Hertig<br />

concludes, “having nature work for us so that we can give<br />

back.” MT<br />

www.ecoviarenewables.com<br />

Linear gamma-poly glutamic acid (PGA). Biobased and nontoxic,<br />

linear PGA can be crosslinked and derivatized into<br />

superabsorbent materials. Image brightened for contrast.<br />

36 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Beauty & Healthcare<br />

Bioplastic<br />

microbeads<br />

for cosmetics<br />

Few are aware that many cosmetics pollute the rivers and<br />

seas due to the presence of microscopic particles of oilbased<br />

and non-biodegradable plastic (polyethylene, polypropylene<br />

and other types of polymers). To solve this problem<br />

and make every beauty product environmentally friendly, Bioon<br />

developed and patented a revolutionary, innovative solution<br />

in 2016 based on the bioplastic Minerv PHAs, which is<br />

made from renewable and biodegradable plant sources. The<br />

new formulation, called Minerv Bio Cosmetics (type C1), is<br />

designed to make microbeads suitable for the cosmetics industry.<br />

The plastic micro particles (known as microbeads) currently<br />

used as thickeners or stabilisers in such widely used products<br />

as lipstick, lip gloss, mascara, eye-liner, nail polish, creams,<br />

shampoo, foam bath and even toothpaste pollute the<br />

environment because once they are rinsed off after use, they<br />

become a permanent part of the natural cycle: plankton in the<br />

rivers and seas swallow these microscopic plastic particles and<br />

thus introduce them into the food chain. The level of pollution<br />

is so serious that the USA government has decided to bring in<br />

a law (Microbead-Free Waters Act of 2015) banning the use of<br />

oil-based polymers in body care products. This decision was<br />

recently followed by other countries. The theme is also the<br />

subject of many awareness campaigns around the world and<br />

is one of the focuses of Clean Seas recently launched by the<br />

United Nations.<br />

Institutions and consumers alike are increasingly aware of<br />

the issue but often limit their concern to scrub beads, which<br />

though small fall within the visible range. The greater danger<br />

arises from what cannot be seen, i.e. texturizing powder. These<br />

micro powders invisible to the naked eye (10 µm) are made<br />

from oil-based plastic (methacrylates and polyamides) and are<br />

inserted into almost all formulations to change the sensory<br />

characteristics of the product.<br />

The new cosmetic grades of bioplastic developed by Bio-on<br />

contain highly spherical micro powders with a diameter between<br />

5 and 20 µm, with a porous or hollow structure to guarantee<br />

high absorption of oil and sebum. The special characteristics<br />

of these powders are further enriched by exceptional optical<br />

qualities such as a soft focus effect, which reduces the effect of<br />

wrinkles, making the skin brighter and less greasy.<br />

The use in cosmetics products of Minerv Bio Cosmetics<br />

bioplastic eliminates all pollutants because the micro particles<br />

of bioplastic are naturally biodegradable in water and, therefore,<br />

do not enter the food chain. What is more, the biopolymer<br />

developed at the Bio-on laboratories actually decomposes into<br />

a nutrient for some micro-organisms and plants present in<br />

nature. The benefit for the environment is therefore two-fold.<br />

“Our biopolymer is surprisingly versatile,” explains Paolo<br />

Saettone, head of Bio-on’s cosmetics department, “and<br />

performs at the very peak of its category, without taking into<br />

account its unparalleled biodegradability and non-toxicity,<br />

which truly sets it apart.”<br />

“From now on, cosmetics companies will have the chance<br />

to safeguard the environment and make their products 100 %<br />

ecological,” explains Marco Astorri, Chairman and CEO of Bioon<br />

S.p.A., “while retaining their performance and effectiveness.<br />

Here too, Bio-on bioplastic demonstrates that it can replace<br />

conventional oil-based plastic in terms of performance,<br />

thermo-mechanical properties and versatility.”<br />

Earlier this year, Bio-on had started to build a new plant to<br />

produce the Minerv Bio Cosmetics microbeads.<br />

The innovative plant, due to be completed by the end of this<br />

year and beginning production in 2018 thanks to a 15 million<br />

EUR investment, will employ approximately 40 people. The plant<br />

will occupy an area of 30,000 m 2 , 3,700 of which is covered and<br />

6,000 land for development, and will have a production capacity<br />

of 1,000 tonnes per year expandable to 2,000. It will be equipped<br />

with state-of-the-art technologies and the most advanced<br />

research laboratories, where Bio-on will test and develop new<br />

types of PHAs bioplastic using agricultural and agro-industrial<br />

waste as raw material. Bio-on also demonstrates its focus on<br />

sustainability in its choice of site, opting to convert a former<br />

factory in Castel San Pietro Terme near Bologna, meaning no<br />

new land is wasted.<br />

“We are pleased because so far we have obtained the<br />

necessary authorisations to begin construction on schedule,”<br />

explains Marco Astorri.”We expect to keep to that set down<br />

in our Industrial Plan which takes us through to 2020. We<br />

are also extremely proud,” adds Astorri, “because thanks to<br />

our technology the cosmetics sector can now take a ‘green’<br />

turn that millions of consumers around the world have been<br />

demanding for some time.” MT<br />

www.bio-on.it<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 37


Politics<br />

Biodegradable plastics in the<br />

Circular Economy in Europe<br />

At the beginning of this year, the European Commission<br />

published its EU Roadmap for a Strategy on Plastics in a<br />

Circular Economy. In the Roadmap, the Commission has<br />

given priority to assess how to decarbonize the plastics<br />

economy and to increase efficiency of waste management<br />

with a strong focus on recycling of plastic in order to help<br />

the transition from a linear to a circular economy model.<br />

European Bioplastics (EUBP), the association representing<br />

the interest of the bioplastics industry in Europe, welcomes<br />

this clear focus in the roadmap, and hopes that this will<br />

remain a main pillar of the upcoming Strategy on Plastics<br />

in order to address some of the most pressing challenges<br />

of our time, namely climate change and resource efficiency.<br />

One important point missing in the roadmap, however,<br />

is the need to consider recycling as both, organic and<br />

mechanic recycling. Only if the separate collection of biowaste<br />

and organic recycling is encouraged, the quality<br />

of other waste streams as well as the efficiency of waste<br />

management altogether can be increased. Organic recycling<br />

(industrial composting and anaerobic digestion) is a wellestablished<br />

industrial process ensuring the circular use for<br />

biodegradable plastics while creating a strong secondary<br />

raw material market and opportunity for renewable energy<br />

generation.<br />

In the context of the EU Plastics Strategy and the Circular<br />

Economy Package, biodegradable plastics can play an<br />

essential part in putting the envisioned circularity model<br />

into practice. Discussing biodegradation of plastics only<br />

from a ‘leakage-into-the-environment’ point of view will<br />

not help to implement sound circular waste management.<br />

EUBP therefore calls on the European Commission to focus<br />

on circularity when discussing biodegradation of plastics<br />

and to consider organic recycling and proven products and<br />

applications for biodegradable products that are certified<br />

according to harmonised standards (EN 13432) and labelled<br />

accordingly.<br />

Not all packaging should or can be made from<br />

biodegradable plastics. But there are several key<br />

products and applications that can amplify the benefits<br />

and contributions of biodegradable plastics to a circular<br />

economy. The following list can contribute to a more<br />

concrete discussion and can show that biodegradable<br />

plastics help to prevent and reduce waste.<br />

Compostable bio-waste bags, fruit & vegetable<br />

bags, lightweight carrier bags<br />

Compostable bio-waste plastic bags support the separate<br />

collection of organic waste. They are a convenient, clean,<br />

and hygienic tool, which helps households to collect more<br />

kitchen and garden waste while reducing the misthrow rate<br />

of conventional plastics in organic waste streams. Likewise,<br />

compostable fruit and vegetable bags and lightweight<br />

carrier bags first serve as a convenient way for shoppers to<br />

carry home groceries and can afterwards be used to collect<br />

biodegradable kitchen and food waste.<br />

By:<br />

Hasso von Pogrell<br />

Managing Director,<br />

When discussing biodegradation of plastics and the<br />

circular economy today, considerations should focus<br />

on organic recycling as an existing and proven concept.<br />

Harmonised and accepted standards, certification schemes,<br />

and labels for industrial compostable plastics already exist.<br />

Such materials, combined with accurate information for<br />

consumers on how to dispose of the waste correctly, have<br />

proven to help collect more bio-waste for organic recycling<br />

and, that way, divert it from landfills or reduce contamination<br />

with biodegradable waste in mechanical recycling streams.<br />

European Bioplastics e.V.<br />

Berlin, Germany<br />

Compostable<br />

light-weight fruit and<br />

vegetable bag photo:<br />

Unicoop<br />

38 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Buss Laboratory Kneader MX 30-22<br />

Compostable fruit labels<br />

Using fruit labels made from conventional, nonbiodegradable<br />

plastics causes significant amounts of<br />

plastic to be discarded in bio-waste bins, as consumers will<br />

rarely remove these labels from fruit peels before disposing<br />

them in the bio-waste. Compostable fruit labels can remain<br />

attached to and be discarded together with fruit peels<br />

without introducing impurities to the bio-waste stream.<br />

Coffee capsules and tea bags<br />

After they have been used, the organic content (coffee<br />

or tea residues) and the capsules or bags are difficult to<br />

separate, leading to confusion about the appropriate way<br />

of disposal as well as misthrows. Coffee capsules and tea<br />

bags made from fully compostable plastics provide the<br />

same performance while offering an alternative that can<br />

be organically recycled together with the organic content.<br />

Coffee and tea waste are highly desired in industrial<br />

composting plants as they stimulate microbial activity in the<br />

composting process.<br />

Buss Kneader Technology<br />

Compostable coffee<br />

capsules from Original<br />

Food tested and certified<br />

according to EN1342<br />

photo: Original Food GmbH<br />

Thin film applications for fruit and vegetable<br />

packaging<br />

Food that has past its expiry date and is packed in<br />

conventional plastic packaging is usually not separated<br />

from its packaging. The plastic packaging, together with<br />

its contents, is usually either thrown into the bio-waste<br />

bin, where it constitutes an impurity, or the biodegradable<br />

food content still inside the packaging ends up in the<br />

residual waste bin and is no longer available for organic<br />

recycling and thus wasted as a possible valuable resource.<br />

Compostable plastic packaging can help to solve this<br />

problem as it can be discarded and recycled together<br />

with its organic contents. When discussing these specific<br />

applications in the context of a circular economy, EUBP<br />

recommends focussing on highly food-contaminated<br />

thin film packaging applications with a thickness below<br />

100 microns such as fruit and vegetable packaging (e.g.<br />

cucumber wrappings, flow packs).<br />

Leading Compounding Technology<br />

for heat and shear sensitive plastics<br />

For more than 60 years Buss Kneader technology<br />

has been the benchmark for continuous preparation<br />

of heat and shear sensitive compounds –<br />

a respectable track record that predestines this<br />

technology for processing biopolymers such<br />

as PLA and PHA.<br />

> Uniform and controlled shear mixing<br />

> Extremely low temperature profile<br />

> Precise temperature control<br />

> High filler loadings<br />

www.european-bioplastics.org<br />

Buss AG<br />

Switzerland<br />

www.busscorp.com<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 39


News Automotive from Science and Research<br />

Turning industrial waste into PHA bioplastics<br />

Dr. Damian Laird and Dr. Leonie Hughes, researchers<br />

from the School of Engineering<br />

and Information Technology (Murdoch University,<br />

Perth, Australia) have been investigating<br />

an environmentally friendly solution for the use of<br />

oxalate, one of the major waste products of the alumina<br />

industry.<br />

“We are interested in finding a use for carbonbased<br />

industrial waste, which is currently<br />

stockpiled or is difficult to treat,” Dr Laird said. “By<br />

upcycling the carbon from a waste stream, we are<br />

able to avoid the production of carbon dioxide whilst<br />

creating something useful.”<br />

After sourcing an initial bacterial culture from<br />

a local wastewater treatment plant, the team<br />

created a synthetic wastewater to understand the<br />

conditions required for bacteria to convert the oxalate waste product into the biodegradable plastic (polyhydroxybutyrate (PHB).<br />

The research team is now identifying the suite of bacteria that can work in the process and examining ways to increase the<br />

amount of oxalate that is converted.<br />

“We are taking inspiration from the production of bioplastic from food waste and applying it to a toxic by-product of the<br />

alumina industry,” Dr Hughes said.<br />

“This will be a naturally produced plastic that is biocompatible and completely biodegradable, and one of our goals is to 3D<br />

print products for the medical industry such as stents and sutures.”<br />

The team is also collaborating with Murdoch University’s Algae Research and Development Centre to look at using<br />

cyanobacteria (blue-green algae), organisms that have a blend of bacteria and algae, to find a way to accelerate the process.<br />

“Eventually we envision this bioplastic production forming part of an integrated biorefinery at Murdoch University,” Dr Hughes<br />

said.<br />

This research was recently published in the Journal of Environmental Chemical Engineering and can be read here<br />

tinyurl.com/ybfcsgm7.<br />

www.murdoch.edu.au<br />

Turning brewery waste into PHA bioplastics<br />

Brewers’ spent grain (BSG in industrial terms) is a waste stream that every brewery generates in abundance. Approx. 85 %<br />

of an average microbrewery’s solid waste is BSG. In many cases it is simply dumped into landfills. The correct way, as to the<br />

Brewers Association’s guidance for environmentally friendly modes of disposal would be to feed BSG to cows, to turn it into<br />

biofuel, compost it or mill it into baking flour. However, for cost and other reasons this is seldom done. Christopher M. Thomas,<br />

a post-doctoral researcher at the State University of New York pondered about using this BSG to make bioplastic, namely<br />

PHA. In Sierra, the national magazine of the Sierra Club, Thomas<br />

said: “You’re diverting waste from landfills, and you’re creating a<br />

biodegradable packaging. And it’s degradable in all environments,<br />

no matter where it goes—freshwater, saltwater, or sewage.”<br />

BSG offers all the components you need, Thomas said. These<br />

are for example polysaccharides, long molecules that when broken<br />

into simple sugar molecules using enzymes or acid, they become<br />

bacterial food. As known from PHAs, special bacteria use this<br />

food as energy reserve: polyhydroxyalkanoates (PHA), which can<br />

be extracted from the microbes and convertied and compounded<br />

into mouldable plastic resins.<br />

www.sierraclub.org<br />

40 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


©<br />

-Institut.eu | <strong>2017</strong><br />

Full study available at www.bio-based.eu/reports<br />

©<br />

-Institut.eu | 2016<br />

Full study available at www.bio-based.eu/markets<br />

©<br />

-Institut.eu | <strong>2017</strong><br />

Full study available at www.bio-based.eu/markets<br />

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May <strong>2017</strong><br />

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Data for<br />

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Download this study and further nova market studies at:<br />

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bioplastics MAGAZINE [02/17] Vol. 12 41


Opinion<br />

Biodegradable plastics needed<br />

to increase recycling efficiency<br />

In the light of the current debates and consultations on the<br />

upcoming EU Strategy on Plastics and the revision of the EU<br />

waste legislation, European Bioplastics (EUBP), the association<br />

for the bioplastics industry in Europe, echoes the call for<br />

greater investments in the implementation of separate recycling<br />

streams, made by the association of Plastics Recyclers<br />

Europe (PRE) earlier this week. In a press release, PRE calls<br />

for the development of separate recycling streams for biodegradable<br />

plastics to improve waste management efficiency<br />

throughout Europe. EUBP supports these efforts to ensure<br />

a high quality of recycled plastics. In order to implement a<br />

circular economy throughout Europe and to achieve higher<br />

recycling rates, stronger investments in the modernisation<br />

of the waste management infrastructure, including separate<br />

mechanical and organic recycling streams, are needed.<br />

Biodegradable plastics help to reduce contamination<br />

of mechanical recycling streams by facilitating separate<br />

collection of biowaste and therefore diverting organic waste<br />

from other recycling streams. Organic recycling is a wellestablished<br />

industrial process ensuring the circular use for<br />

biodegradable plastics while creating a strong secondary<br />

raw material market and opportunity for renewable energy<br />

generation. Numerous beacon projects throughout Europe<br />

demonstrate the positive effects of compostable bags on the<br />

efficiency and quality of separate organic waste collection,<br />

including in the cities of Milan, Munich, and Paris.<br />

Currently, the share of biodegradable plastics designed<br />

for organic recycling sold in the EU is comparatively small.<br />

Therefore, the potential of misthrows by the consumer to<br />

reach a critical volume that could impact the quality of<br />

mechanical recycling streams is an unreasonable assumption<br />

at this point in time. This has also been tested and confirmed<br />

in a recent study by the University of Wageningen, which<br />

analysed biodegradable plastics in mechanical recycling<br />

streams and detected levels not higher than 0.3%. When<br />

tested within the EU FP7 Open-Bio project, Wageningen<br />

Food & Biobased Research found that there were no negative<br />

effects on the properties of recycled film products containing<br />

starch film and PLA film recyclates. If biodegradable plastic<br />

products do, however, enter mechanical recycling streams,<br />

they can easily be sorted out. Research by Knoten Weimar,<br />

a scientific knowledge-cluster and institute at the Bauhaus-<br />

University Weimar focussed on optimising utilities and waste<br />

infrastructures, shows that available sorting technologies<br />

such as NIR (near infrared) can easily detect biodegradable<br />

plastic materials such as PLA (polylactic acid), PBAT<br />

(polybutylene adipate terephthalate), and other starch or<br />

cellulose based materials.<br />

On the other hand, however, contamination of organic waste<br />

streams by misthrows of non-biodegradable plastics is high<br />

and constitutes a real problem for composting facilities and<br />

negatively affects the quality of compost. This problem can<br />

only be tackled by establishing mandatory separate collection<br />

of organic waste supported and facilitated by the use of<br />

biodegradable plastic bags and packaging and accompanied<br />

by consumer education and information on correct ways of<br />

organic and mechanic recycling.<br />

EUBP urges all involved stakeholders to consider recycling<br />

as both mechanical and organic recycling and to contemplate<br />

the corresponding plastic materials in this context.<br />

Furthermore, investments into sound waste management<br />

infrastructure across Europe as well as comprehensive<br />

projects to increase the consumers’ knowledge about correct<br />

disposal need to be considered. Only then, recycling can<br />

become more efficient, contamination can be limited, and a<br />

strong secondary raw material market in a circular economy<br />

will flourish.<br />

For more information, please see the following expert<br />

statements and studies on this issue:<br />

• Wageningen Food & Biobased Research (<strong>2017</strong>): Biobased<br />

and biodegradable plastics – Facts and Figures<br />

tinyurl.com/ydaufx38<br />

• Knoten Weimar: Entsorgungswege und<br />

Verwertungsoptionen von Produkten aus biobasierten<br />

Polymeren des post-consumer Bereichs (German only)<br />

tinyurl.com/y9xkhnwa<br />

www.european-bioplastics.org<br />

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42 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Basics<br />

Land use<br />

Just how much land is required to<br />

produce bioplastics?<br />

By:<br />

Constance Ißbrücker<br />

Head of Environmental Affairs<br />

European Bioplastics<br />

Berlin, Germany<br />

Global land area<br />

G13.4 billion ha = 100 %<br />

Finite fossil oil resources and climate change constitute two<br />

broadly acknowledged challenges for society in the coming<br />

decades. Bioplastics, which are derived fully or in part from<br />

renewable, plant-based resources, have the unique advantage<br />

over conventional plastics to reduce the dependency on fossil<br />

resources and to reduce greenhouse gas emissions.<br />

Today, bioplastics are predominantly produced from agrobased<br />

feedstock, i.e. plants that are rich in carbohydrates,<br />

such as corn or sugarcane. At the same time, the bioplastics<br />

industry is investing in the research and development to<br />

diversify the availability of biogenic feedstock for the production<br />

of based plastics. The industry particularly aims to further<br />

develop fermentation technologies that enable the utilisation<br />

of ligno-cellulosic feedstock sources, for example non-food<br />

crops or agricultural waste materials.<br />

There are various ways to ensure a sufficient supply of<br />

biomass for the production for food, feed, and industrial/<br />

material uses (including bioplastics) now and in future. These<br />

include:<br />

1. Broadening the base of feedstock: The bioplastics<br />

industry is currently working mostly with agro-based<br />

feedstock. Several projects, however, are already looking into<br />

using plant residues or other ligno-cellulosic feedstock.<br />

2. Increasing yields: Increasing the efficiency of<br />

industrial conversion of raw materials into feedstock, for<br />

example by using optimised yeasts or bacteria and optimised<br />

physical and chemical processes that would increase the total<br />

availability of resources.<br />

3. Taking fallow land into production: There is still<br />

plenty of arable land in various geographical regions available<br />

for production, even in the European Union (see separate box)<br />

Pasture<br />

3.5 billion ha<br />

= 26.1 %<br />

lobal agricultural area<br />

Arable land*<br />

1.4 billion ha<br />

= 10.4 %<br />

5 billion ha = 36.5 %<br />

Food & Feed<br />

1.24 billion ha<br />

= 9.25 %<br />

Graph<br />

courtesy<br />

IfBB [1]<br />

Bioplastics<br />

2015: 750 000 ha = 0.0<strong>05</strong>6 %<br />

2020: 1 784 000 ha = 0.0133 %<br />

Material use<br />

106 million ha = 0.79 %<br />

Biofuels<br />

53 million ha = 0.39 %<br />

Latest numbers by the IfBB Hanover published in 2016<br />

show that the area used to produce so-called new economy<br />

bioplastics was 0.0<strong>05</strong>6 % of the global agricultural area<br />

in 2015. Considering continued high growth-rates of the<br />

bioplastics market over the next years, this share would<br />

increase to 0.0133 % of the agricultural area by 2020. The<br />

approach of the IfBB is considered to be a conservative one,<br />

as entire plants are allocated for the calculation, and a tenyear<br />

average value considering harvest fluctuation as well as<br />

full utilisation of plant capacities is being assumed. Not all<br />

experts agree to this approach and suggest considering for<br />

example more detailed allocation values for the crop usage<br />

and the yield average values, since not necessarily all parts<br />

of the plant are used to produce bioplastics. However, all<br />

experts agree on one important point, namely the fact that<br />

the actual amount of land used for bioplastics is very low<br />

compared to the land used to produce food and feed, which<br />

shows that there is no competition between using biomass<br />

for the production for bioplastics and using biomass the<br />

production of food and feed.<br />

After all, responsibly sourced and monitored (i.e.<br />

sustainable) food crops are still the main feedstock option for<br />

bioplastics, since they are more land-efficient than non-food<br />

crops due to highly efficient agricultural processes. What is<br />

more, the use of bi-products of these food crops (i.e. lignocellulosic<br />

feedstocks) in based industries allows to increase<br />

resource efficiency even more. There is even evidence that<br />

the industrial and material use of biomass may in fact serve<br />

as a stabilizer for food prices, providing farmers with more<br />

secure markets and thereby leading to more sustainable<br />

production. Independent third party certification schemes for<br />

sustainable sourcing and responsible agricultural practices<br />

do already exist and can help to take social, environmental<br />

and economic criteria into account and to ensure that<br />

bioplastics are a purely beneficial innovation.<br />

[1] N.N.: Biopolymers – facts and statistics; Institute for Bioplastics and<br />

Biocomposites, 2016<br />

www.european-bioplastics.org<br />

Info:<br />

Different sources come up with varying figures for „free“ arable<br />

land, the French National Institute For Agricultural Research gives<br />

2.6 billion hectares of untapped potential (article in ParisTech,<br />

2011), the nova-Institute calculates 570 million hectares based on<br />

figures of OECD and FAO (2009). The bottom line – there is an ample<br />

amount of unused land available.<br />

http://tinyurl.com/bioplastic-facts<br />

* Also includes area growing permanent crops as well as approx.<br />

1 % fallow land. Abandoned land resulting from shifting<br />

cultivation is not included.<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 43


Brand Owner<br />

Brand-Owner’s perspective<br />

on bioplastics and how to<br />

unleash its full potential<br />

More and more technical aspects are well within the comfort zone of the<br />

bioplastic industry enabling the disruptive innovations our societies and<br />

environment need. However, successful innovations are<br />

as much business as technology driven. Having a great<br />

idea is one thing, launching a proposition and get it to<br />

market another.<br />

So, quite often a biobased product is desirable<br />

and even technically feasible. But bringing such a<br />

(often) small scale innovation to market is something else. Before<br />

economies of scale can be unlocked, there is this difficult phase<br />

during which advocacy and government support are needed. The biobased<br />

industry could help to open up discussions with the governmental<br />

institutes like the EU to create funding programs around this.<br />

Dennis van Eeten,<br />

Packaging Innovation and (Interim) Design Manager<br />

MARS CHOCOLATE EUROPE & EURASIA<br />

Besides the boost for a first launch it would also be very beneficial if the European<br />

legislation around bioplastics would be harmonised. This includes, icons for biocertificates,<br />

end-of-life rules (what can I put in my green bin and what not) and of<br />

course a harmonised EPR fee across all countries (in Europe).<br />

www.mars.com<br />

Report<br />

Polit<br />

Bioplastics Survey<br />

In this edition of our series ”special focus on certain geographical<br />

areas” we have a closer look to North America.<br />

This time, however, we did not conduct our little non-representative<br />

survey ourselves. We are grateful to the Plastics<br />

Industry Assiciaton (PLASTICS), to grant permission<br />

to publish some results of a survey they did in May 2016. In<br />

this national poll of 1,107 adults throughout the USA were<br />

asked. The results show a margin of error of +/- 3.07 % at<br />

the 95 % confidence interval. Below we publish an excerpt<br />

of the survey that is related to bioplastics.<br />

Being asked how familiar they were about a type of<br />

plastics called “bioplastics,” which are either made from<br />

biobased materials like sugar cane or cornstarch or are<br />

capable of biodegrading 27 % responded with “Yes” (defined<br />

as somewhat or very familiar). 39 % were unsure and the<br />

rest (34 %) said they were very unfamiliar with the terms.<br />

The next question addressed the purchase behavior. More<br />

or less half of the interviewed citizens committed they would<br />

be willing to pay a little bit more for an item that was made<br />

from bioplastics. The other 50 % said that they were not.<br />

The U.S. Department of Agriculture initiated the<br />

BioPreferred programme which includes a BioPreferred<br />

Seal (cf. bM 01/2011), which verifies the percentage of<br />

biologically grown ingredients in a consumer or wholesale<br />

product. Asked if they had ever seen this logo, 14 %<br />

responded with “Yes”, while the other 86 % were at least not<br />

sure or responded with “No”.<br />

The last question addressed the purchase behavior<br />

after having seen the USDA BioPreferred Seal. “When<br />

considering a plastic product for purchase, would seeing<br />

a USDA BioPreferred Seal on that product make you more<br />

likely to buy that product?” was positively responded by<br />

57 %. The remaining 43 % wouldn’t.<br />

The source of the data can be found here:<br />

https://tinyurl.com/bio-marketwatch. MT<br />

www<br />

www<br />

www<br />

www<br />

44 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />

30 bio


Automotive<br />

10<br />

Years ago<br />

Published in<br />

bioplastics<br />

MAGAZINE<br />

Rhodes Yepsen, Executive Director of the<br />

Biodegradable Products Institute (BPI), said in<br />

September <strong>2017</strong>:<br />

The topics presented 10 years ago continue to be important in North<br />

America, albeit with significant progress made. It’s no longer just Wal-<br />

Mart that has aggressive packaging goals, but other major retailers and<br />

restaurants as well, including a focus on consumer-oriented education,<br />

such as the How2Recycle and How2Compost labels.<br />

As for state legislation, California’s labelling law has helped clean up bad<br />

actors from the market, and became the basis for a model rule for other<br />

states, with Maryland adopting a similar law in <strong>2017</strong>.<br />

Municipal interest in food scraps and compostable products is also at<br />

an all-time high, with hundreds of communities across the US and Canada<br />

offering residential and commercial food scraps collection, and New York City<br />

on track to become the world’s largest program.<br />

Avoiding methane generation is still a big driver, but so is the soil<br />

connection, returning valuable materials back to the land in the form of<br />

compost. Findacomposter.com has gone through several updates, as has<br />

BPI’s database of certified products (products.bpiworld.org), which is now<br />

searchable by keyword.<br />

As was the case 10 years ago, compostable product companies are at the<br />

forefront of the discussion on policies for diverting organics from landfill, and<br />

we expect them to continue to play a leading role for the next decade as well.<br />

http://tinyurl.com/northamerica2007<br />

ics<br />

What’s happening in the<br />

New World?<br />

New Legislation in California<br />

.bpiworld.org<br />

.biocycle.net<br />

.findacomposter.com<br />

.beps.org<br />

Article contributed by Steven Mojo,<br />

Executive Director of the<br />

Biodegradable Products Institute (BPI),<br />

New York, NY, USA<br />

I<br />

t is truly a new world in North America, as the<br />

pace of organics diversion continues to increase.<br />

Discussions around the issues of sustainability,<br />

increasing use of renewable resources<br />

and greenhouse gas reductions are coming to the<br />

forefront.<br />

Retailer Concerns about Packaging<br />

In late 20<strong>05</strong>, Wal-Mart announced its sustainability<br />

drive focused on three aggressive goals:<br />

1. “To Be Supplied 100% By Renewable Energy”:<br />

2. ”To Create Zero Waste”:<br />

3. ”To Sell Products That Sustain Our Resources<br />

& Environment”:<br />

As part of this effort, Wal-Mart has developed a<br />

“scorecard” for packaging and is asking suppliers<br />

to document the use of recyclable and compostable<br />

packaging (via ASTM D6400) and to verify the<br />

use of renewable feedstocks (using ASTM D6866).<br />

This scorecard came on-line in March 2007 and<br />

manufacturers will be feeding it data throughout<br />

this year.<br />

Wal-Mart’s efforts, like Sainsbury’s in the UK,<br />

call attention to the growing array of new materials<br />

available to packagers around the globe. At the<br />

same time, packagers are starting to inquire about<br />

BPI certification and the benefits of the BPI Compostable<br />

Logo. Also, manufacturers are striving to<br />

increase the percentage of renewably based materials,<br />

in order to help reduce their environmental<br />

footprint and earn credits from Wal-Mart.<br />

The BPI and its members are immersed in the<br />

issues of renewable resources, compostability and<br />

biodegradability for almost a decade. As such, they<br />

are in a position to help Wal-Mart and others understand<br />

the importance of using ASTM Test Methods<br />

and Specifications for verifying claims.<br />

This project is a “work in progress”. It will continue<br />

to evolve as technology and properties improve<br />

and importantly will impact suppliers, consumers<br />

and everyone in between.<br />

California continues to set the pace in the area of<br />

compostables. Last year, Governor Schwarzenegger<br />

signed labeling legislation which restricts the<br />

use of the terms “biodegradable”, “compostable”<br />

and “degradable” on plastic food containers to<br />

only those products that meet ASTM D6400. This<br />

legislation is similar to the one passed in 2004 for<br />

labelling on plastic bags. Both of the new laws<br />

are designed to address the abuse and misuse of<br />

these terms and the resulting confusion.<br />

New Ordinances in San Francisco<br />

In 2006, San Francisco passed ordinance No<br />

295-06 which bans the use of polystyrene food<br />

service packaging and mandates the use of compostable<br />

or recyclable alternatives, if their additional<br />

costs are within 15% of non-compostable<br />

or non-recyclable alternatives. This ordinance<br />

is designed to help minimize the waste going to<br />

landfills from these operations. Also, this ordinance<br />

takes advantage of the City’s well developed<br />

recycling and composting infrastructure for<br />

businesses and households.<br />

On March 27, 2007, San Francisco passed an<br />

ordinance mandating the use of compostable<br />

plastic bags or recyclable kraft paper bags by<br />

large food chains and pharmacies. Given the city’s<br />

widespread organic collection system, the compostable<br />

bags can serve two purposes. First they<br />

will bring home the groceries and then will have<br />

a second life as a liner for residential “kitchen<br />

catchers”. The new law takes effect by the end of<br />

this year.<br />

Food Scrap Diversion Programs Grow<br />

More communities, especially in Eastern Canada<br />

and on the West Coast are implementing food<br />

scrap diversion efforts. Portland (Oregon) and<br />

Seattle (Washington), join the ranks of San Francisco<br />

and Oakland, (California) in implementing<br />

commercial collection programs and in some<br />

communities’ residential ones as well. In the<br />

Canadian province of Ontario organics diversion<br />

efforts are beginning to “skyrocket” according to<br />

one BPI member.<br />

These are driven by the dual goals of continuing<br />

to increase the overall diversion rate from landfills<br />

as well as to reduce greenhouse gas emissions<br />

from landfills. For example, in the US, landfills<br />

are the single largest of anthropomorphic<br />

methane releases into the atmosphere, according<br />

to the US Environmental Protection Agency. Further<br />

the same study shows that landfills are the<br />

number 4 contributor of global warming gases.<br />

Findacomposter.com introduced<br />

The BPI and BioCycle magazine from Emmaus<br />

(Pennsylvania) are joint sponsors of a<br />

new website dedicated to increasing the awareness<br />

of composting in the US. The new site<br />

“findacomposter.com” was debuted in April 2007<br />

at the BioCycle West Coast Conference in San Diego<br />

(California). The site will provide consumers<br />

information about food scrap collection programs<br />

near them and will be available for all to use at<br />

no charge. Composters can participate at no cost<br />

and all entries will be verified by BioCycle. The BPI<br />

and its members are proud to be the first sponsor<br />

to support this effort and to help put composting<br />

on the map.<br />

The BPI and BEPS team up on<br />

a meeting in October, 2007<br />

The BEPS and BPI are jointly sponsoring a<br />

conference from Oct. 17-19th in Vancouver,<br />

Washington. This meeting will combine presentations<br />

and discussions on biodegradable and<br />

renewable materials from both academia and<br />

industry. Presenters are being lined up from<br />

North America, Europe and Asia. The conference<br />

will be a “zero waste” event. It is being held at<br />

the Hilton Hotel, which has been cited for sustainable<br />

practices and it will have an active food<br />

scrap diversion effort by the end of the summer.<br />

Learn more about the conference at beps.org<br />

bioplastics MAGAZINE [02/07] Vol. 2 31<br />

plastics MAGAZINE [02/07] Vol. 2<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 45


©<br />

3,5<br />

actual data<br />

3<br />

2,5<br />

2<br />

1,5<br />

1<br />

0,5<br />

2011 2012 2013<br />

L-LA<br />

Epichlorohydrin<br />

Succinic<br />

1,4-BDO<br />

acid<br />

-Institut.eu | <strong>2017</strong><br />

forecast<br />

2014 2015 2016 <strong>2017</strong> 2018 2019 2020 2021<br />

Sebacic<br />

MEG<br />

Ethylene<br />

1,3-PDO<br />

MPG<br />

Lactide<br />

acid<br />

2,5-FDCA D-LA<br />

11-Aminoundecanoic acid<br />

Adipic<br />

DDDA<br />

acid<br />

Full study available at www.bio-based.eu/reports<br />

©<br />

100%<br />

80%<br />

60%<br />

40%<br />

20%<br />

0%<br />

-Institut.eu | <strong>2017</strong><br />

PBS(X)<br />

APC –<br />

cyclic<br />

PA<br />

PET<br />

PTT<br />

PBAT<br />

Starch<br />

Blends<br />

PHA<br />

PLA<br />

PE<br />

Full study available at www.bio-based.eu/markets<br />

©<br />

10<br />

5<br />

actual data<br />

0<br />

2011 2012<br />

PUR<br />

PA<br />

-Institut.eu | 2016<br />

2% of total<br />

polymer capacity,<br />

€13 billion turnover<br />

2013 2014 2015 2016<br />

Epoxies PET<br />

CA<br />

PBS<br />

PBAT PHA<br />

<strong>2017</strong><br />

Starch<br />

Blends<br />

EPDM<br />

2018 2019 2020 2021<br />

PLA<br />

PE<br />

PTT<br />

APC<br />

PEF<br />

Full study available at www.bio-based.eu/markets<br />

Largest biocomposites<br />

conference in <strong>2017</strong><br />

Organiser<br />

www.nova-institut.eu<br />

Picture © clockwise from top left: photo and design by colorFabb,<br />

Faurecia, photo by colorFabb / design by LeFabshop, Coperion<br />

Biocomposites Conference Cologne<br />

7 th Conference on Wood and Natural Fibre Composites<br />

6 – 7 December <strong>2017</strong>, Maternushaus, Germany<br />

Contact: Dr. Asta Partanen | +49 (0)151 – 1113 0128 | asta.partanen@nova-institut.de | www.biocompositescc.com<br />

Bio-based Polymers & Building Blocks<br />

The best market reports available<br />

Data for<br />

2016<br />

Commercialisation updates on<br />

bio-based building blocks<br />

Standards and labels for<br />

bio-based products<br />

Bio-based polymers, a revolutionary change<br />

Bio-based Building Blocks<br />

and Polymers<br />

Selected bio-based building blocks: Evolution of worldwide<br />

production capacities from 2011 to 2021<br />

Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />

and polymers based on FDCA and SA: Latest developments,<br />

producers, drivers and lessons learnt<br />

Global Capacities and Trends 2016 – 2021<br />

million t/a<br />

Bio-based polymers, a<br />

revolutionary change<br />

million t/a<br />

Bio-based polymers: Evolution of worldwide<br />

production capacities from 2011 to 2021<br />

Jan Ravenstijn <strong>2017</strong><br />

E-mail: j.ravenstijn@kpnmail.nl<br />

Mobile: +31.6.2247.8593<br />

Picture: Gehr Kunststoffwerk<br />

Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

July <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />

nova-Institut GmbH, Germany<br />

May <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />

April <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Florence Aeschelmann (nova-Institute),<br />

Michael Carus (nova-institute) and ten renowned international experts<br />

February <strong>2017</strong><br />

This is the short version of the market study (249 pages, € 2,000).<br />

Both are available at www.bio-based.eu/reports.<br />

Policies impacting bio-based<br />

plastics market development<br />

and plastic bags legislation in Europe<br />

Asian markets for bio-based chemical<br />

building blocks and polymers<br />

Brand Views and Adoption of<br />

Bio-based Polymers<br />

Market study on the consumption<br />

of biodegradable and compostable<br />

plastic products in Europe<br />

2015 and 2020<br />

Share of Asian production capacity on global production by polymer in 2016<br />

A comprehensive market research report including<br />

consumption figures by polymer and application types<br />

as well as by geography, plus analyses of key players,<br />

relevant policies and legislation and a special feature on<br />

biodegradation and composting standards and labels<br />

Bestsellers<br />

Disposable<br />

tableware<br />

Biowaste<br />

bags<br />

Carrier<br />

bags<br />

Rigid<br />

packaging<br />

Flexible<br />

packaging<br />

Authors: Dirk Carrez, Clever Consult, Belgium<br />

Jim Philp, OECD, France<br />

Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

Lara Dammer & Michael Carus, nova-Institute, Germany<br />

March <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

January 2016<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />

Lara Dammer, Michael Carus (nova-Institute)<br />

April 2016<br />

The full market study (more than 300 slides, 3,500€) is available at<br />

bio-based.eu/top-downloads.<br />

46 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12<br />

www.bio-based.eu/reports


call for papers now open!<br />

Save the Date<br />

04-<strong>05</strong> Sep 2018<br />

Cologne, Germany<br />

www.pha-world-congress.com<br />

PHA (Poly-Hydroxy-Alkanoates or polyhydroxy fatty acids) is a family of biobased polyesters. As in many<br />

mammals, including humans, that hold energy reserves in the form of body fat there are also bacteria that<br />

hold intracellular reserves of polyhydroxy alkanoates. Here the micro-organisms store a particularly high level<br />

of energy reserves (up to 80% of their own body weight) for when their sources of nutrition become scarce.<br />

Examples for such Polyhydroxyalkanoates are PHB, PHV, PHBV, PHBH and many more. That’s why we speak<br />

about the PHA platform.<br />

This PHA-platform is made up of a large variety of bioplastics raw materials made from many different renewable<br />

resources. Depending on the type of PHA, they can be used for applications in films and rigid packaging,<br />

biomedical applications, automotive, consumer electronics, appliances, toys, glues, adhesives, paints, coatings,<br />

fibers for woven and non-woven and inks. So PHAs cover a broad range of properties and applications.<br />

That’s why bioplastics MAGAZINE and Jan Ravenstijn are now organizing the 1 st PHA-platform World Congress on<br />

4-5 September 2018 in Cologne / Germany.<br />

This congress will address the progress, challenges and market opportunities for the formation of this new polymer<br />

platform in the world. Every step in the value chain will be addressed. Raw materials, polymer manufacturing,<br />

compounding, polymer processing, applications, opportunities and end-of-life options will be discussed by parties<br />

active in each of these areas. Progress in underlying technology challenges will also be addressed.<br />

Platinum Sponsor:<br />

organized by<br />

Co-organized by Jan Ravenstijn


Basics<br />

Biodegradation<br />

Bioplastics and their behaviour in different biodegradation environments<br />

The efficient management of plastic waste plays a key<br />

role within the circular economy. Good waste management<br />

requires the implementation of the waste hierarchy,<br />

as set out by EU legislation in the form of Directive<br />

2008/98/CE [1], which aims to encourage solutions providing<br />

a better environmental result. The waste hierarchy sets<br />

out the following hierarchy of steps for prioritising waste<br />

management practices: (1) prevention; (2) preparation for<br />

reutilisation; (3) recycling; (4) other kind of recovery, such<br />

as energy recovery; and (5) disposal, such as in the case<br />

of landfilling. Moreover, the package of circular economy<br />

measures adopted by the European Union requires that<br />

waste be transformed into resources again, so they can be<br />

returned cyclically to the productive system, until reaching<br />

the very ambitious target of “zero waste” to landfill (European<br />

Commission, 2014). Thus, the end of life of plastics<br />

continues to be a controversial point, since landfilling is still<br />

a common practice. In the year 2014, 31 % of the post-consumer<br />

plastic waste generated in Europe went to landfill.<br />

The situation in Spain is even more unfavourable: here, just<br />

over 50% of all post-consumer plastic waste ends up in a<br />

landfill [2]<br />

These decisions, combined with the push towards<br />

creating a sustainable environment - in addition to a desire<br />

to get away from landfilling and to reduce the amount of<br />

litter in the environment – have led to heightened interest in<br />

the production of bioplastics.<br />

Biodegradable plastics are considered to be eco-friendly<br />

materials. In recent years, they have been promoted in the<br />

market as substitutes for conventional plastics in specific<br />

applications in which biodegradability, as an end-of-life<br />

solution, provides environmental benefits. However, we<br />

must not forget their limitations regarding manufacturing<br />

costs, mechanical properties or variable biodegradability<br />

behaviour depending on the aggressiveness of the<br />

different media, and focus the efforts on the research and<br />

development of solutions and improvements.<br />

There are several important factors affecting the<br />

process or mechanism of biodegradation of biodegradable<br />

plastics. On the one hand, the chemical structure, the<br />

polymeric chain, crystallinity or complexity of the polymeric<br />

formulation are key points to be studied. In this way, the<br />

specific functional groups of the polymeric chain that<br />

forms the bioplastic are selected by certain enzymes and<br />

processed by them to trigger what is known as “material<br />

biodegradation”. We can say that, normally, polymers with<br />

short chains and more abundant amorphous area are more<br />

susceptible to being biologically degraded.<br />

On the other hand, the different environments in<br />

which biodegradable plastics initiate the biodegradation<br />

processes, must be studied. In this case, pH, temperature<br />

and the presence of oxygen and microbial content are the<br />

most significant factors in determining the aggressiveness<br />

level, depending on the conditions under which the material<br />

undergoes biodegradation. In such a reaction, the carbon<br />

that is a part of the material’s polymeric chains will, in<br />

the presence of biomass and hence of microorganisms,<br />

temperature, light and water, turn into CO 2<br />

and new<br />

biomass.<br />

The different possibilities that can occur regarding<br />

environment are, among others: compost, natural, soil,<br />

soil with normalized characteristics according to the test<br />

standards, fresh water, seawater or sewage sludge. This<br />

window of environments represents the existence of a<br />

wide range of very different conditions when studying the<br />

biodegradability of materials.<br />

More specifically and bearing in mind the possibility of<br />

recovering the plastic materials at the end of their shelf<br />

life, the medium offering this possibility is compost. The<br />

composting process is defined as the complete biological<br />

recovering process, aerobic (in presence of oxygen) and<br />

exothermal (with an increase of the temperature) of waste<br />

fermentation in controlled conditions whose result is the<br />

obtaining of CO 2<br />

, water and fertilizer or compost where<br />

wastes are not visually distinguishable and do not produce<br />

eco-toxicological effects in the environment.<br />

With regard to composting, it is important to highlight<br />

the difference between industrial composting and home<br />

composting due to the temperature difference in both<br />

processes (58 ºC in the case of industrial composting and<br />

below 30 ºC in the case of home composting) that makes a<br />

material to biodegrade faster in an industrial facility than<br />

home composting.<br />

If we analyse another key factor, such as the presence of<br />

microorganisms, the most important role is played by fungi.<br />

The presence of fungi is needed for a good biodegradation<br />

process. However, they can only be found in compost and<br />

soil, although they are more abundant in compost and<br />

less in soil. Both compost and soil have high microbial and<br />

populations that biodegrade bioplastic materials and a high<br />

diversity that is not found in other environments such as<br />

fresh water and seawater (aquatic ecosystems), so this<br />

environment is less aggressive.<br />

Therefore, an estimation of the aggressiveness of different<br />

environments can be given and we can affirm that the most<br />

active environment is compost, followed by soil, fresh water,<br />

seawater and finally ambient and landfill conditions (this<br />

last option must be ruled out if we talk about efficient waste<br />

management) [3].<br />

In order to calculate the percentage of biodegradability<br />

that a specific material has reached in an environment,<br />

there are lab-scale tests that evaluate parameters such as<br />

the amount of carbon dioxide generated when subjecting<br />

plastic materials to certain conditions. This parameter is<br />

an indirect measurement of the amount of carbon from<br />

the polymeric chain that is transformed into carbon dioxide<br />

by the mechanism of biodegradability. Based on this<br />

measurement, different standards have been developed<br />

with which the different biodegradation environments must<br />

48 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


Basics<br />

By:<br />

Elena Domínguez Solera<br />

Sustainability and Industrial Recovery Department,<br />

AIMPLAS<br />

Valencia, Spain<br />

comply. Thus, for example, the standard EN ISO 14855 [4],<br />

sets out a method to determine the final biodegradability<br />

percentage of a plastic material. The material is subjected<br />

to controlled composting conditions (58 ºC and 50 %<br />

of humidity) using generated and automatic carbon<br />

dioxide detection methods, such as infrared detection or<br />

gravimetric methods of carbon dioxide absorption in certain<br />

substances. Likewise, there are standards that simulate a<br />

medium at an environmental temperature of 25 ºC, where<br />

plastic materials are subject to the presence of a natural<br />

or normalized soil, as in the standard EN ISO 17556 [5]<br />

or to 30 ºC in a natural aqueous medium, normalized or<br />

in other environments rich in microorganisms, such as<br />

sewage sludge, as in the standard EN ISO 14852, which sets<br />

out the testing procedure to determine the final aerobic<br />

biodegradability in aqueous medium [6].<br />

It is essential to establish in each case what we want to<br />

analyse, in which environments and under what conditions,<br />

in order to determine the behaviour of plastics and their<br />

utility in different applications.<br />

AIMPLAS, has been committed to this vision for<br />

more than 20 years, and besides having developed and<br />

taken part in different projects in the field of bioplastics,<br />

continues to opt for them regarding biodegradability<br />

tests in different environments. The institute has taken a<br />

further step by becoming the first Spanish laboratory to<br />

earn ENAC accreditation (National Accreditation Body)<br />

for tests determining the final aerobic biodegradability in<br />

composting conditions (EN ISO 14855-1), soil (EN ISO 17556)<br />

and tests determining the degree of disintegration of plastic<br />

materials under simulated composting conditions in a<br />

laboratory scale (EN ISO 20200 [7]). Thanks to this extension<br />

of the accreditation scope, AIMPLAS is at the forefront of<br />

accredited tests in the field of plastic materials in Europe.<br />

The fact that ENAC is a signatory of all the EA (European<br />

Accreditation), ILAC (International Laboratory Accreditation<br />

Cooperation) and IAF (International Accreditation Forum)<br />

international agreements, is very important Therefore, a<br />

report or certificate issued under ENAC accreditation is<br />

recognized by the other signatories in the entire world and<br />

these agreements act like an international passport for trade.<br />

www.aimplas.es<br />

References:<br />

[1] DIRECTIVE 2008/98/CE OF THE EUROPEAN PARLIAMENT AND THE<br />

COUNCIL of 19 November 2008 on waste and repealing certain<br />

directives.<br />

[2] PlasticsEurope (PEMRG) / Consultic. Plastics - the Facts 2015. An<br />

analysis of European plastics production, demand and waste data.<br />

[3] Challenges and opportunities of biodegradable plastics: A mini review<br />

(Maja Rujnić-Sokele and Ana Pilipović). Waste Management & Research<br />

<strong>2017</strong>, Vol. 35(2) 132–140.<br />

[4] EN ISO 14855-1:2013. Determination of the ultimate aerobic<br />

biodegradability of plastic materials under controlled composting<br />

conditions - Method by analysis of evolved carbon dioxide - Part 1:<br />

General method. Part 2: Gravimetric method.<br />

[5] EN ISO 17556:2013. Plastics. Determination of the ultimate aerobic<br />

biodegradability of plastic materials in soil by measuring the oxygen<br />

demand in a respirometer or the amount of carbon dioxide evolved.<br />

[6] EN ISO 14852:20<strong>05</strong>. Determination of the ultimate aerobic<br />

biodegradability of plastic materials in an aqueous medium - Method by<br />

analysis of evolved carbon dioxide.<br />

[7] EN ISO 20200:2016. Plastics - Determination of the degree of<br />

disintegration of plastic materials under simulated composting<br />

conditions in a laboratory-scale test.<br />

AIMPLAS’ equipment (Plastics Technology Centre) for biodegradability tests in different environments.<br />

bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12 49


Basics<br />

Glossary 4.2 last update issue 02/2016<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM 06/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which – having<br />

a higher growth yield than 1 st and 2 nd generation<br />

feedstock – were given their own category.<br />

It also relates to bioplastics from waste<br />

streams such as CO 2<br />

or methane [bM 02/16]<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM 02/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM <strong>05</strong>/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM <strong>05</strong>/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →Vinçotte who both base<br />

their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM 01/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/06, bM 01/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

50 bioplastics MAGAZINE [04/17] Vol. 12


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM 01/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM 01/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic<br />

acids. The most important cellulose esters<br />

from a technical point of view are cellulose<br />

acetate (CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose<br />

butyrate (CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/06, bM 01/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [04/17] Vol. 12 51


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]. If GM crops are used in bioplastics<br />

production, the multiple-stage processing<br />

and the high heat used to create the<br />

polymer removes all traces of genetic material.<br />

This means that the final bioplastics product<br />

contains no genetic traces. The resulting<br />

bioplastics is therefore well suited to use in<br />

food packaging as it contains no genetically<br />

modified material and cannot interact with<br />

the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5<br />

furandicarboxylic acid (FDCA), produced as an<br />

intermediate when 5-HMF is oxidised. FDCA<br />

is used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14, 02/16]<br />

Home composting | →composting [bM 06/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established<br />

process with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The<br />

criteria for industrial compostability of packaging<br />

have been defined in the EN 13432. Materials<br />

and products complying with this standard<br />

can be certified and subsequently labelled<br />

accordingly [1,7] [bM 06/08, 02/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.01 percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, 01/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM 01/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.[bM 02/16]<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, <strong>05</strong>/14, 01/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM 01/09, <strong>05</strong>/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM <strong>05</strong>/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

52 bioplastics MAGAZINE [04/17] Vol. 12


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM 01/09, 01/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM 01/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → Vinçotte. Bioplastics<br />

products carrying the Seedling fulfil the<br />

criteria laid down in the EN 13432 regarding<br />

industrial compostability. [bM 01/06, 02/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM <strong>05</strong>/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2012<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2010<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2011<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2012<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2010, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2012<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 20<strong>05</strong><br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

[15] ISO 14067 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14021 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [04/17] Vol. 12 53


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

technical.starch@agrana.com<br />

www.agrana.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-9995<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Corbion Purac<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.corbion.com/bioplastics<br />

bioplastics@corbion.com<br />

62 136 Lestrem, France<br />

Tel.: + 33 (0) 3 21 63 36 00<br />

www.roquette-performance-plastics.com<br />

1.2 compounds<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 5190621<br />

Fax.: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2713175<br />

Mob: +86 139<strong>05</strong>253382<br />

lilong_tunhe@163.com<br />

www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

54 bioplastics MAGAZINE [04/17] Vol. 12


Suppliers Guide<br />

1.6 masterbatches<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

weforyou PLA & Applications<br />

office@weforyou.pro<br />

www.weforyou.pro<br />

1.4 starch-based bioplastics<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />

45, 0,90, 0<br />

10, 0, 80,0<br />

(ICBP) C, M, Y, KSDN BHD<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

0, 0, 0, 0<br />

D-09, Jalan Tanjung A/4,<br />

Free Trade Zone<br />

Port of Tanjung Pelepas<br />

81560 Johor, Malaysia<br />

T. +607-507 1585<br />

icbp.bioplastic@gmail.com<br />

www.icbp.com.my<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

6.2 Laboratory Equipment<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4<strong>05</strong>2 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

1.5 PHA<br />

TIPA-Corp. Ltd<br />

Hanagar 3 Hod<br />

Hasharon 4501306, ISRAEL<br />

P.O BOX 7132<br />

Tel: +972-9-779-6000<br />

Fax: +972 -9-7715828<br />

www.tipa-corp.com<br />

4. Bioplastics products<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

9. Services<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

Bio4Pack GmbH<br />

D-48419 Rheine, Germany<br />

Tel.: +49 (0) 5975 955 94 57<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

6. Equipment<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

Fax: +49 (0)208 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

6.1 Machinery & Molds<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

bioplastics MAGAZINE [04/17] Vol. 12 55


Suppliers Guide<br />

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Volume 8, May <strong>2017</strong><br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

9. Services (continued)<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

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For Example:<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

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10.2 Universities<br />

10.3 Other Institutions<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

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41066 Mönchengladbach<br />

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Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

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SEEING POLYMERS<br />

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Biokraftstoffkompatibilität von FKM<br />

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POLYURETHANES MAGAZINE INTERNATIONAL<br />

Trim The Weight,<br />

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Interviews: ISL-Chemie, Dow, Magna, Vencorex<br />

PSE Europe <strong>2017</strong> preview<br />

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CNSL-based polyols<br />

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Strukture le Faserverbundbauteile<br />

PU-basierte Bedachungsmaterialien<br />

Polyole auf CNSL-Basis<br />

Polyesterpolyole<br />

Interview mit G. Burrow, Magna<br />

Führende Köpfe für führende Lösungen<br />

Pultrusion neu gedacht<br />

Relaxed Extrusion<br />

PEEK-PTFE-cg-Materialien<br />

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56 bioplastics MAGAZINE [04/17] Vol. 12<br />

Tel. +49 2102 9345-0 · Fax +49 2102 9345-20<br />

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19.10.<strong>2017</strong> - 21.10.<strong>2017</strong> - San Francisco (CA), USA<br />

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24.11.<strong>2017</strong> - 25.11.<strong>2017</strong> - Bengaluru, India<br />

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12 th European Bioplastics Conference<br />

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Fibres & Textiles | 14<br />

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European Biopolymer Summit<br />

14.02.2018 - 15.02.2018 - Duesseldorf, Germany<br />

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Basics<br />

Land use | 43<br />

CHINAPLAS 2018<br />

The 32nd International Exhibition on Plastics &<br />

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24.04.2018 - 27.04.2018 - Shanghai, China<br />

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bioplastics MAGAZINE Vol. 12<br />

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5 th PLA World Congress<br />

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25.06.2018 - 28.06.2018 - New York City Area, USA<br />

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Mention the promotion code ‘watch‘ or ‘book‘<br />

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Bioplastics Basics. Applications. Markets. for free<br />

1) Offer valid until 31 December <strong>2017</strong><br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [04/17] Vol. 12 57


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

A. Schulman 7<br />

ABB 12<br />

Adidas 13<br />

Agrana 54<br />

AIMPLAS 22, 49<br />

Aitiip 6<br />

AMC Innova Juice & Drinks 6<br />

Amsilk 13<br />

API Applicazioni Plastiche Industriali 54<br />

Archer Daniels Midland 5<br />

ARMINES 35<br />

Barnet Europe 18<br />

BASF 7, 13 54<br />

Beoplast 55<br />

Bio4pack 55<br />

Biobrush 12<br />

Bio-Fed Branch of Akro-Plastic 54<br />

Bio-on 5, 28, 37<br />

Biotec 55<br />

Bosk Bioproducts 30<br />

Bozzetto 18<br />

BPI 45 56<br />

Braskem 7, 28, 32<br />

Bunzl 29<br />

Buss 39, 55<br />

Cathay Industrial Biotech 17<br />

Center for Biobased Economy 13<br />

Centexbel 19, 22<br />

Dr. Heinz Gupta Verlag 56<br />

DS Fibres 22<br />

DuPont 5<br />

Eastman Chemical Company 8<br />

Ecovia Renewables 36<br />

eKoala 26<br />

Erema 55<br />

Eroski 6<br />

European Bioplastics 34, 38, 42, 43 31, 56<br />

Exergy 35<br />

Fakultet Novi Sad 35<br />

Finroline 35<br />

FKuR 32 2, 54<br />

Fraunhofer UMSICHT 55<br />

G.S. Stemeseder 7<br />

Global Biopolymers 54<br />

GRABIO Greentech Corporation 55<br />

Grafe 54, 55<br />

Green Serendipity 56<br />

Greenboats 7<br />

GreenDot Bioplastics 54<br />

Hallink 55<br />

Hexpol TPE 8<br />

ICBP 1, 10, 55<br />

ICEE 13<br />

Indochine Bio Plastiques 1, 10, 55<br />

Infiana Germany 55<br />

INRS 30<br />

Inst. F. Bioplastics & Biocomposites 43 56<br />

Inst. Textiltechnik RWTH Aachen 18<br />

INSTM 34<br />

IRIS 34<br />

Jinhui Zhaolong 23, 54<br />

Kaneka 55<br />

Kartell 27<br />

Kering Eyeware 28<br />

Kingfa 54<br />

Linotech 7<br />

Maip 12<br />

Mars 44<br />

Mavi Sud 35<br />

Michigan State University 56<br />

Microtec 54<br />

Midwestern PET Foods 28<br />

Minima Technology 55<br />

Murdoch Univ. 40<br />

narocon InnovationConsulting 56<br />

NatureWorks 26<br />

Naturtec 55<br />

nova Institute 7 41, 46, 56<br />

Novamont 26 55, 60<br />

NPSP 7, 13<br />

Nurel 54<br />

Origin Materials 8<br />

OWI 7<br />

OWS 6<br />

Peel Plastics Products 28<br />

PHP Fibers 14<br />

Plastic Recyclers Europe 42<br />

plasticker 42<br />

PLASTICS 44<br />

Plastipolis 6<br />

Plasto 28<br />

polymediaconsult 56<br />

President Packaging 55<br />

PTT MCC Biochem 27, 54<br />

Raimund Beck Nageltechnik 7<br />

Roquette 54<br />

Sabio Materials 27<br />

Saida 55<br />

Saurer 18<br />

Schlafhorst 18<br />

Sierra Club 40<br />

Sintex 22<br />

Sonae Arauco 7<br />

Speick Naturkosmetik 32<br />

State Univ. New York 40<br />

Sukano 26 29, 54<br />

Tecnaro 55<br />

Tecos 6<br />

Teijin Frontier 16<br />

Texol 35<br />

thyssenkrupp Industrial Solutions 24<br />

TianAn Biopolymer 55<br />

Tipa 55<br />

Total Corbion PLA 54<br />

TU Eindhoven 7, 13<br />

Uhde Inventa-Fischer 24 21, 55<br />

Univ. Delft 13<br />

Univ. Gent 35<br />

Univ. Stuttgart (IKT) 55<br />

Univ. Westminster 35<br />

Vredestein 6<br />

Wageningen UR 6, 42<br />

Weforyou 36 55<br />

Xinjiang Blue Ridge Tunhe Polyester 22 54<br />

Yönsa 22<br />

Zhejiang Hangzhou Xinfu Pharmaceutical 54<br />

Zhejiang Hisun Biomaterials 33, 54<br />

<strong>Issue</strong><br />

Editorial Planner<br />

Month<br />

Publ.<br />

Date<br />

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<strong>2017</strong>/18<br />

06/<strong>2017</strong> Nov/Dec 04 Dec 17 03 Nov 17 Films/Flexibles/<br />

Bags<br />

Edit. Focus 1 Edit. Focus 2 Edit. Focus 3 Basics<br />

Polyurethanes/<br />

Elastomers/<br />

Rubber<br />

Italy/France<br />

Special<br />

01/2018 Jan/Feb 08 Jan 18 22 Dec 17 Automotive Foam Thailand (t.b.c) t.b.d.<br />

Blown film extrusion<br />

Trade-Fair<br />

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Subject to changes<br />

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58 bioplastics MAGAZINE [<strong>05</strong>/17] Vol. 12


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